BR112014012577A2 - síntese de cristal grande de atividade alta zsm-5 - Google Patents

síntese de cristal grande de atividade alta zsm-5

Info

Publication number
BR112014012577A2
BR112014012577A2 BR112014012577A BR112014012577A BR112014012577A2 BR 112014012577 A2 BR112014012577 A2 BR 112014012577A2 BR 112014012577 A BR112014012577 A BR 112014012577A BR 112014012577 A BR112014012577 A BR 112014012577A BR 112014012577 A2 BR112014012577 A2 BR 112014012577A2
Authority
BR
Brazil
Prior art keywords
zsm
crystals
high activity
source
large crystal
Prior art date
Application number
BR112014012577A
Other languages
English (en)
Portuguese (pt)
Inventor
A Hamilton Merci
Frank Lai Wenyih
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of BR112014012577A2 publication Critical patent/BR112014012577A2/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38Type ZSM-5
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/12After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B01J2229/123After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation in order to deactivate outer surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BR112014012577A 2011-12-01 2012-11-27 síntese de cristal grande de atividade alta zsm-5 BR112014012577A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161565635P 2011-12-01 2011-12-01
PCT/US2012/066588 WO2013081994A1 (en) 2011-12-01 2012-11-27 Synthesis of high activity large crystal zsm-5

Publications (1)

Publication Number Publication Date
BR112014012577A2 true BR112014012577A2 (pt) 2017-06-06

Family

ID=47279156

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014012577A BR112014012577A2 (pt) 2011-12-01 2012-11-27 síntese de cristal grande de atividade alta zsm-5

Country Status (9)

Country Link
US (1) US8900547B2 (https=)
EP (1) EP2785645B1 (https=)
JP (1) JP5990594B2 (https=)
KR (1) KR101858310B1 (https=)
CN (1) CN103958411B (https=)
BR (1) BR112014012577A2 (https=)
CA (1) CA2855875C (https=)
SG (1) SG11201402190SA (https=)
WO (1) WO2013081994A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102220082B1 (ko) * 2019-07-23 2021-02-25 노경태 신규 구조 및 타래형 모폴로지를 갖는 알루미노실리케이트 구조체, 이의 제조방법 및 이를 고정상으로 충진한 hplc 컬럼
CN114426455B (zh) * 2020-09-28 2024-07-23 中国石油化工股份有限公司 一种苯和乙烯烷基化反应
CN114478274B (zh) * 2020-10-27 2024-06-28 中国石油化工股份有限公司 一种制备一乙醇胺并联产二甘醇的方法
CN114620743A (zh) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 一种大晶粒rho-sapo分子筛、其制备方法及其应用
US20240173705A1 (en) * 2021-02-17 2024-05-30 University Of Houston System Synthesis of zeolites with interconnected nanosheets
FR3141080B1 (fr) 2022-10-19 2025-05-02 Arkema France Procédé de synthèse de zéolithe zsm-5 en continu
CN116459786B (zh) * 2023-04-27 2024-12-24 金宏气体股份有限公司 去除八甲基环四硅氧烷中的六甲基环三硅氧烷的吸附剂

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3676063A (en) * 1971-03-11 1972-07-11 Nalco Chemical Co Process for preparing synthetic crystalline zeolitic sodium aluminosilicate
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
NZ193928A (en) 1979-06-11 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
AU559968B2 (en) * 1982-04-29 1987-03-26 Mobil Oil Corp. Controlled morphology high silica zeolites
JPH0227283B2 (ja) * 1982-10-01 1990-06-15 Toray Industries Ketsushoseiaruminoshirikeetozeoraitonoseizoho
US4797267A (en) * 1987-12-23 1989-01-10 Mobil Oil Corporation Method of producing rod-shaped ZSM-5 zeolite
JP2618021B2 (ja) * 1988-10-03 1997-06-11 工業技術院長 真球状ペンタシル型ゼオライト粉体の合成方法
JP2844098B2 (ja) * 1989-12-20 1999-01-06 旭化成工業株式会社 Zsm―5微粒子体の製造法
US5164169A (en) * 1991-06-14 1992-11-17 Mobil Oil Corporation Zeolite Beta
DE69620612T2 (de) * 1995-06-06 2003-02-06 Exxonmobil Oil Corp., Fairfax Grosskristalliner zeolith zsm-5, seine synthese und verwendung
US20020011429A1 (en) * 1997-09-30 2002-01-31 Akira Iino Iron-containing crystalline aluminosilicate
AU2002367444A1 (en) * 2001-05-10 2003-09-29 Akzo Nobel N.V. Continuous process and apparatus for the efficient conversion of inorganic solid particles
JP4541156B2 (ja) * 2002-12-30 2010-09-08 エスケー エナジー 株式会社 有機テンプレートなしで可変温度を用いてzsm−5を製造する方法
KR100528672B1 (ko) * 2002-12-30 2005-11-15 학교법인 건국대학교 유기 템플레이트 배제 하에서 가변 온도를 이용하여zsm-5를 제조하는 방법
SG188173A1 (en) * 2008-02-22 2013-03-28 Exxonmobil Chem Patents Inc Large crystal molecular sieves and their manufacture
CN101722033A (zh) * 2008-10-28 2010-06-09 中国石油化工股份有限公司 核壳型芳烃转化催化剂及其制备方法和用途

Also Published As

Publication number Publication date
EP2785645A1 (en) 2014-10-08
EP2785645B1 (en) 2017-06-14
SG11201402190SA (en) 2014-09-26
CA2855875A1 (en) 2013-06-06
JP2015507591A (ja) 2015-03-12
US8900547B2 (en) 2014-12-02
US20130144100A1 (en) 2013-06-06
CN103958411A (zh) 2014-07-30
JP5990594B2 (ja) 2016-09-14
CA2855875C (en) 2018-08-14
CN103958411B (zh) 2016-08-24
KR20140108665A (ko) 2014-09-12
KR101858310B1 (ko) 2018-05-15
WO2013081994A1 (en) 2013-06-06

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Legal Events

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B11D Dismissal acc. art. 38, par 2 of ipl - failure to pay fee after grant in time