SG11201402190SA - Synthesis of high activity large crystal zsm-5 - Google Patents

Synthesis of high activity large crystal zsm-5

Info

Publication number
SG11201402190SA
SG11201402190SA SG11201402190SA SG11201402190SA SG11201402190SA SG 11201402190S A SG11201402190S A SG 11201402190SA SG 11201402190S A SG11201402190S A SG 11201402190SA SG 11201402190S A SG11201402190S A SG 11201402190SA SG 11201402190S A SG11201402190S A SG 11201402190SA
Authority
SG
Singapore
Prior art keywords
synthesis
high activity
large crystal
crystal zsm
activity large
Prior art date
Application number
SG11201402190SA
Inventor
Wenyih Frank Lai
Merci A Hamilton
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of SG11201402190SA publication Critical patent/SG11201402190SA/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J35/40
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38Type ZSM-5
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/12After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B01J2229/123After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation in order to deactivate outer surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
SG11201402190SA 2011-12-01 2012-11-27 Synthesis of high activity large crystal zsm-5 SG11201402190SA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161565635P 2011-12-01 2011-12-01
PCT/US2012/066588 WO2013081994A1 (en) 2011-12-01 2012-11-27 Synthesis of high activity large crystal zsm-5

Publications (1)

Publication Number Publication Date
SG11201402190SA true SG11201402190SA (en) 2014-09-26

Family

ID=47279156

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201402190SA SG11201402190SA (en) 2011-12-01 2012-11-27 Synthesis of high activity large crystal zsm-5

Country Status (9)

Country Link
US (1) US8900547B2 (en)
EP (1) EP2785645B1 (en)
JP (1) JP5990594B2 (en)
KR (1) KR101858310B1 (en)
CN (1) CN103958411B (en)
BR (1) BR112014012577A2 (en)
CA (1) CA2855875C (en)
SG (1) SG11201402190SA (en)
WO (1) WO2013081994A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102220082B1 (en) * 2019-07-23 2021-02-25 노경태 Aluminosilicates structure with novel structure and wool-like type morphology, manufacturing method thereof and HPLC column packed with the same as stationary phase
CN114426455A (en) * 2020-09-28 2022-05-03 中国石油化工股份有限公司 Benzene and ethylene alkylation reaction
CN114478274A (en) * 2020-10-27 2022-05-13 中国石油化工股份有限公司 Method for preparing monoethanolamine and coproducing diglycol
CN114620743A (en) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 Large-grain RHO-SAPO molecular sieve, and preparation method and application thereof

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3676063A (en) * 1971-03-11 1972-07-11 Nalco Chemical Co Process for preparing synthetic crystalline zeolitic sodium aluminosilicate
US3941871A (en) 1973-11-02 1976-03-02 Mobil Oil Corporation Crystalline silicates and method of preparing the same
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
NZ193928A (en) 1979-06-11 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
AU559968B2 (en) * 1982-04-29 1987-03-26 Mobil Oil Corp. Controlled morphology high silica zeolites
JPH0227283B2 (en) * 1982-10-01 1990-06-15 Toray Industries KETSUSHOSEIA RUMINOSHIRIKEETOZEORAITONOSEIZOHO
US4797267A (en) * 1987-12-23 1989-01-10 Mobil Oil Corporation Method of producing rod-shaped ZSM-5 zeolite
JP2618021B2 (en) * 1988-10-03 1997-06-11 工業技術院長 Method for synthesizing true spherical pentasil type zeolite powder
JP2844098B2 (en) * 1989-12-20 1999-01-06 旭化成工業株式会社 Method for producing ZSM-5 fine particles
US5164169A (en) * 1991-06-14 1992-11-17 Mobil Oil Corporation Zeolite Beta
US6013239A (en) * 1995-06-06 2000-01-11 Mobil Oil Corporation Large crystal ZSM-5, its synthesis and use
US20020011429A1 (en) * 1997-09-30 2002-01-31 Akira Iino Iron-containing crystalline aluminosilicate
EP1385622B1 (en) * 2001-05-10 2014-07-09 Albemarle Netherlands B.V. Continuous process for the efficient conversion of inorganic solid particles
JP4541156B2 (en) * 2002-12-30 2010-09-08 エスケー エナジー 株式会社 Method for producing ZSM-5 using variable temperature without organic template
KR100528672B1 (en) * 2002-12-30 2005-11-15 학교법인 건국대학교 Method for Preparing ZSM-5 Using Variable Temperatures in the Absence of Organic Template
EP2262732B1 (en) * 2008-02-22 2017-05-24 ExxonMobil Chemical Patents Inc. Large crystal molecular sieves and their manufacture
CN101722033A (en) * 2008-10-28 2010-06-09 中国石油化工股份有限公司 Core-shell type aromatic conversion catalyst, preparation method and application thereof

Also Published As

Publication number Publication date
WO2013081994A1 (en) 2013-06-06
EP2785645B1 (en) 2017-06-14
CA2855875A1 (en) 2013-06-06
CN103958411A (en) 2014-07-30
KR20140108665A (en) 2014-09-12
US8900547B2 (en) 2014-12-02
CA2855875C (en) 2018-08-14
JP2015507591A (en) 2015-03-12
BR112014012577A2 (en) 2017-06-06
EP2785645A1 (en) 2014-10-08
US20130144100A1 (en) 2013-06-06
JP5990594B2 (en) 2016-09-14
CN103958411B (en) 2016-08-24
KR101858310B1 (en) 2018-05-15

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