BR112014010440B1 - método para produzir resina de cloreto de vinila clorado - Google Patents
método para produzir resina de cloreto de vinila clorado Download PDFInfo
- Publication number
- BR112014010440B1 BR112014010440B1 BR112014010440A BR112014010440A BR112014010440B1 BR 112014010440 B1 BR112014010440 B1 BR 112014010440B1 BR 112014010440 A BR112014010440 A BR 112014010440A BR 112014010440 A BR112014010440 A BR 112014010440A BR 112014010440 B1 BR112014010440 B1 BR 112014010440B1
- Authority
- BR
- Brazil
- Prior art keywords
- vinyl chloride
- chloride resin
- ultraviolet
- chlorinated vinyl
- ultraviolet led
- Prior art date
Links
- 239000011347 resin Substances 0.000 title claims abstract description 218
- 229920005989 resin Polymers 0.000 title claims abstract description 218
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 212
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 66
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000000460 chlorine Substances 0.000 claims abstract description 53
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000007900 aqueous suspension Substances 0.000 claims description 31
- 238000000465 moulding Methods 0.000 abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 39
- 239000000047 product Substances 0.000 description 31
- 230000000052 comparative effect Effects 0.000 description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 230000035484 reaction time Effects 0.000 description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- 238000005265 energy consumption Methods 0.000 description 12
- 238000010186 staining Methods 0.000 description 12
- 238000000295 emission spectrum Methods 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000003381 stabilizer Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 9
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 9
- 229910052753 mercury Inorganic materials 0.000 description 9
- 239000002245 particle Substances 0.000 description 8
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 7
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000005297 pyrex Substances 0.000 description 7
- GNELLERHHJENHV-UHFFFAOYSA-N CC=CC=C.CC(=C)C(O)=O.C=Cc1ccccc1 Chemical compound CC=CC=C.CC(=C)C(O)=O.C=Cc1ccccc1 GNELLERHHJENHV-UHFFFAOYSA-N 0.000 description 6
- 238000004040 coloring Methods 0.000 description 6
- 239000000314 lubricant Substances 0.000 description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
- -1 ethylene, propylene, vinyl Chemical group 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000004383 yellowing Methods 0.000 description 5
- 229910000669 Chrome steel Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-M 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC([O-])=O YPIFGDQKSSMYHQ-UHFFFAOYSA-M 0.000 description 1
- 229910002704 AlGaN Inorganic materials 0.000 description 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002455 scale inhibitor Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011243780 | 2011-11-07 | ||
| JP2012022695 | 2012-02-06 | ||
| PCT/JP2012/078368 WO2013069542A1 (ja) | 2011-11-07 | 2012-11-01 | 塩素化塩化ビニル系樹脂の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112014010440A2 BR112014010440A2 (pt) | 2017-04-18 |
| BR112014010440B1 true BR112014010440B1 (pt) | 2020-04-07 |
Family
ID=48289919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112014010440A BR112014010440B1 (pt) | 2011-11-07 | 2012-11-01 | método para produzir resina de cloreto de vinila clorado |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9056959B2 (enExample) |
| EP (1) | EP2778180B1 (enExample) |
| JP (2) | JP5433112B2 (enExample) |
| KR (1) | KR101455791B1 (enExample) |
| CN (1) | CN103930449B (enExample) |
| AU (1) | AU2012336949B2 (enExample) |
| BR (1) | BR112014010440B1 (enExample) |
| CA (1) | CA2854621C (enExample) |
| IN (1) | IN2014DN03471A (enExample) |
| MX (1) | MX2014005583A (enExample) |
| MY (1) | MY177128A (enExample) |
| SG (1) | SG11201402074RA (enExample) |
| TW (1) | TWI452054B (enExample) |
| WO (1) | WO2013069542A1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG11201502965QA (en) * | 2012-10-18 | 2015-05-28 | Reliance Ind Ltd | Halogenation of hydrocarbons |
| TW201444880A (zh) * | 2013-03-29 | 2014-12-01 | Kaneka Corp | 氯化氯乙烯系樹脂之製造裝置及製造方法 |
| CN104395359B (zh) * | 2013-03-29 | 2016-03-16 | 株式会社钟化 | 氯化氯乙烯系树脂的制造方法及制造装置 |
| WO2014178362A1 (ja) * | 2013-05-01 | 2014-11-06 | 株式会社カネカ | 塩素化塩化ビニル系樹脂の製造装置および製造方法 |
| WO2014178374A1 (ja) * | 2013-05-02 | 2014-11-06 | 株式会社カネカ | 塩素化塩化ビニル系樹脂の製造方法 |
| CN105658680A (zh) * | 2013-10-18 | 2016-06-08 | 瑞来斯实业公司 | 烃的聚合 |
| WO2015166388A2 (en) | 2014-05-02 | 2015-11-05 | Reliance Industries Limited | Apparatus for halogenation of polymer |
| US10370463B2 (en) * | 2014-07-22 | 2019-08-06 | Reliance Industries Limited | Process for manufacturing chlorinated polyvinylchloride |
| US10035865B2 (en) * | 2014-07-22 | 2018-07-31 | Reliance Industries Limited | Preparation of chlorinated polyvinyl chloride |
| WO2016075591A1 (en) * | 2014-11-11 | 2016-05-19 | Reliance Industries Limited | Apparatus and process for chlorination of polyvinyl chloride |
| CN105171996A (zh) * | 2015-07-24 | 2015-12-23 | 中山市伯伦克专用化学产品有限公司 | 一种树脂加热机 |
| US10081687B2 (en) * | 2015-07-29 | 2018-09-25 | Reliance Industries Limited | Process for chlorination of a polymer |
| WO2017065224A1 (ja) * | 2015-10-15 | 2017-04-20 | 株式会社カネカ | 塩素化塩化ビニル系樹脂の製造方法 |
| NL2016934B1 (en) * | 2016-06-10 | 2018-01-16 | Fuji Seal Int Inc | Method, apparatus and system for attaching a label on a product |
| KR102684209B1 (ko) * | 2018-12-19 | 2024-07-10 | 한화솔루션 주식회사 | 염소화 폴리염화비닐 수지의 제조 방법 |
| CN113646339B (zh) * | 2019-03-29 | 2022-12-23 | 积水化学工业株式会社 | 氯化聚氯乙烯系树脂 |
| CN110606903A (zh) * | 2019-08-23 | 2019-12-24 | 浙江晟祺实业有限公司 | 一种氯化线型低密度聚乙烯及其制备方法 |
| JPWO2021065946A1 (ja) | 2019-09-30 | 2021-11-25 | 積水化学工業株式会社 | 成形用樹脂組成物及び成形体 |
| KR20210086152A (ko) * | 2019-12-31 | 2021-07-08 | 한화솔루션 주식회사 | 염소화 폴리염화비닐의 제조 방법 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1544752B2 (de) * | 1964-01-10 | 1974-05-30 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von geformten Gebilden aus thermoplastischen Massen auf der Basis von nachchloriertem Polyvinylchlorid |
| GB1131318A (en) * | 1965-11-20 | 1968-10-23 | Shinetsu Chem Ind Co | Heat stabilized polyvinyl chloride compositions |
| US4006126A (en) * | 1966-02-16 | 1977-02-01 | Montecatini Edison S.P.A. | Process for the chlorination of vinyl polymers |
| GB1314434A (en) * | 1969-07-31 | 1973-04-26 | Air Prod & Chem | Post-chlorination of vinyl chloride interpolymers |
| US3862264A (en) * | 1969-08-30 | 1975-01-21 | Yosuhiro Nojima | Chlorinated polyvinyl chloride composition |
| US3725359A (en) * | 1970-12-23 | 1973-04-03 | Stauffer Chemical Co | Fire retardant resin compositions of post-chlorinated vinyl halide-bis(hydrocarbyl) vinylphosphonate copolymers |
| JPS5148795B2 (enExample) * | 1974-05-18 | 1976-12-22 | ||
| US4412898A (en) * | 1980-08-26 | 1983-11-01 | The B.F. Goodrich Company | Process for chlorination of PVC in water without use of swelling agents |
| US4459387A (en) * | 1981-01-26 | 1984-07-10 | The B. F. Goodrich Company | Chlorination of poly(vinyl chloride) in liquid chlorine, and chlorinated poly(vinyl chloride) composition |
| US4350798A (en) * | 1981-01-26 | 1982-09-21 | The B. F. Goodrich Company | Chlorination of poly(vinyl chloride) in liquid chlorine, and chlorinated poly(vinyl chloride) composition |
| JPS63145305A (ja) * | 1986-12-08 | 1988-06-17 | Tokuyama Sekisui Kogyo Kk | 塩素化塩化ビニル系樹脂の製造方法 |
| JPH10279627A (ja) | 1997-04-09 | 1998-10-20 | Tokuyama Sekisui Ind Corp | 塩素化塩化ビニル系樹脂の製造方法 |
| JP3814733B2 (ja) * | 1997-07-29 | 2006-08-30 | 株式会社カネカ | 塩素化塩化ビニル系樹脂の製造方法 |
| JPH1143509A (ja) * | 1997-07-29 | 1999-02-16 | Kanegafuchi Chem Ind Co Ltd | 塩素化塩化ビニル系樹脂の製造方法 |
| JP2002060420A (ja) * | 2000-08-18 | 2002-02-26 | Kanegafuchi Chem Ind Co Ltd | 塩素化塩化ビニル系樹脂の製造方法 |
| WO2002055565A1 (en) | 2001-01-15 | 2002-07-18 | Kaneka Corporation | Method and apparatus for producing chlorinated vinyl chloride resin |
| JP4084981B2 (ja) * | 2002-09-05 | 2008-04-30 | 株式会社カネカ | 塩素化塩化ビニル系樹脂の製造方法 |
| WO2007138075A1 (en) | 2006-05-31 | 2007-12-06 | Calaire Chimie Sas | Method for preparing lamotrigine and its intermediate 2,3-dichlorobenzoyl chloride |
| US20100122224A1 (en) * | 2007-05-03 | 2010-05-13 | Freescale Semiconductor, Inc. | Method and apparatus for designing an integrated circuit |
| EP2170789A1 (en) | 2007-07-20 | 2010-04-07 | Solvay Fluor GmbH | Process for obtaining a purified hydrofluoroalkane |
| WO2009122940A1 (ja) * | 2008-03-31 | 2009-10-08 | 住友精化株式会社 | ピリジンの精製方法および塩素化ピリジンの製造方法 |
| JP2010235487A (ja) | 2009-03-31 | 2010-10-21 | Sekisui Chem Co Ltd | 塩化ビニルモノマーの製造方法及び塩化ビニル樹脂 |
| DE102009020527A1 (de) * | 2009-05-08 | 2010-11-11 | Ehrfeld Mikrotechnik Bts Gmbh | Vorrichtung zur Durchführung photochemischer Prozesse |
| JP2011063551A (ja) * | 2009-09-18 | 2011-03-31 | Sumitomo Seika Chem Co Ltd | ２−クロロピリジンおよび２，６−ジクロロピリジンの製造方法 |
| CN101759823A (zh) | 2010-03-09 | 2010-06-30 | 华东理工大学 | 氯化聚丙烯的光引发制备方法 |
-
2012
- 2012-11-01 SG SG11201402074RA patent/SG11201402074RA/en unknown
- 2012-11-01 US US14/356,307 patent/US9056959B2/en active Active
- 2012-11-01 KR KR1020147010359A patent/KR101455791B1/ko active Active
- 2012-11-01 MY MYPI2014001308A patent/MY177128A/en unknown
- 2012-11-01 WO PCT/JP2012/078368 patent/WO2013069542A1/ja not_active Ceased
- 2012-11-01 CA CA2854621A patent/CA2854621C/en active Active
- 2012-11-01 IN IN3471DEN2014 patent/IN2014DN03471A/en unknown
- 2012-11-01 MX MX2014005583A patent/MX2014005583A/es active IP Right Grant
- 2012-11-01 AU AU2012336949A patent/AU2012336949B2/en active Active
- 2012-11-01 EP EP12848663.6A patent/EP2778180B1/en active Active
- 2012-11-01 CN CN201280054671.5A patent/CN103930449B/zh active Active
- 2012-11-01 JP JP2013531822A patent/JP5433112B2/ja active Active
- 2012-11-01 BR BR112014010440A patent/BR112014010440B1/pt active IP Right Grant
- 2012-11-07 TW TW101141414A patent/TWI452054B/zh active
-
2013
- 2013-10-15 JP JP2013214693A patent/JP2014005475A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2013069542A1 (ja) | 2015-04-02 |
| KR101455791B1 (ko) | 2014-10-28 |
| CN103930449A (zh) | 2014-07-16 |
| EP2778180B1 (en) | 2017-03-29 |
| AU2012336949A1 (en) | 2014-05-29 |
| WO2013069542A1 (ja) | 2013-05-16 |
| MY177128A (en) | 2020-09-07 |
| EP2778180A1 (en) | 2014-09-17 |
| TW201323464A (zh) | 2013-06-16 |
| JP5433112B2 (ja) | 2014-03-05 |
| CA2854621C (en) | 2015-04-28 |
| CA2854621A1 (en) | 2013-05-16 |
| AU2012336949B2 (en) | 2015-01-15 |
| KR20140063845A (ko) | 2014-05-27 |
| US9056959B2 (en) | 2015-06-16 |
| MX2014005583A (es) | 2014-05-30 |
| TWI452054B (zh) | 2014-09-11 |
| SG11201402074RA (en) | 2014-09-26 |
| EP2778180A4 (en) | 2015-06-03 |
| CN103930449B (zh) | 2015-10-21 |
| BR112014010440A2 (pt) | 2017-04-18 |
| JP2014005475A (ja) | 2014-01-16 |
| US20140309325A1 (en) | 2014-10-16 |
| IN2014DN03471A (enExample) | 2015-06-05 |
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