BR112013020709B1 - espuma de poliuretano flexível - Google Patents
espuma de poliuretano flexível Download PDFInfo
- Publication number
- BR112013020709B1 BR112013020709B1 BR112013020709-4A BR112013020709A BR112013020709B1 BR 112013020709 B1 BR112013020709 B1 BR 112013020709B1 BR 112013020709 A BR112013020709 A BR 112013020709A BR 112013020709 B1 BR112013020709 B1 BR 112013020709B1
- Authority
- BR
- Brazil
- Prior art keywords
- isocyanate
- weight
- polyol
- foam
- mdi
- Prior art date
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- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 28
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 28
- 229920005862 polyol Polymers 0.000 claims abstract description 117
- 150000003077 polyols Chemical class 0.000 claims abstract description 117
- 239000012948 isocyanate Substances 0.000 claims abstract description 65
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 65
- 238000006243 chemical reaction Methods 0.000 claims abstract description 25
- 239000003054 catalyst Substances 0.000 claims description 90
- -1 polyoxypropylene Polymers 0.000 claims description 82
- 239000006260 foam Substances 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 56
- 229920000570 polyether Polymers 0.000 claims description 30
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 27
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 24
- 238000007664 blowing Methods 0.000 claims description 23
- 238000001879 gelation Methods 0.000 claims description 20
- 229920001451 polypropylene glycol Polymers 0.000 claims description 18
- 238000007906 compression Methods 0.000 claims description 10
- 230000006835 compression Effects 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 5
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- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 description 36
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 31
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 24
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 20
- 239000000047 product Substances 0.000 description 20
- 150000003512 tertiary amines Chemical class 0.000 description 20
- 229910052757 nitrogen Inorganic materials 0.000 description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 13
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 12
- 239000012973 diazabicyclooctane Substances 0.000 description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 12
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- 239000004814 polyurethane Substances 0.000 description 11
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- 150000001412 amines Chemical class 0.000 description 9
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 9
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- 230000000052 comparative effect Effects 0.000 description 8
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- 239000013500 performance material Substances 0.000 description 8
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 8
- 239000004971 Cross linker Substances 0.000 description 7
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 6
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- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 6
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 5
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 4
- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 description 4
- 239000004970 Chain extender Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
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- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 4
- LNWBFIVSTXCJJG-UHFFFAOYSA-N [diisocyanato(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(N=C=O)(N=C=O)C1=CC=CC=C1 LNWBFIVSTXCJJG-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000001119 stannous chloride Substances 0.000 description 4
- 235000011150 stannous chloride Nutrition 0.000 description 4
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
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- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
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- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- NHWGPUVJQFTOQX-UHFFFAOYSA-N ethyl-[2-[2-[ethyl(dimethyl)azaniumyl]ethyl-methylamino]ethyl]-dimethylazanium Chemical compound CC[N+](C)(C)CCN(C)CC[N+](C)(C)CC NHWGPUVJQFTOQX-UHFFFAOYSA-N 0.000 description 1
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- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
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- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
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- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
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- BOMXDEYUCNKBAO-UHFFFAOYSA-N n,n'-dimethyl-n,n'-di(propan-2-yl)hexane-1,6-diamine Chemical compound CC(C)N(C)CCCCCCN(C)C(C)C BOMXDEYUCNKBAO-UHFFFAOYSA-N 0.000 description 1
- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 description 1
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
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- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
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- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
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- 150000003141 primary amines Chemical class 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
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- 230000009257 reactivity Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
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- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
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- 150000004072 triols Chemical class 0.000 description 1
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- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161442474P | 2011-02-14 | 2011-02-14 | |
| US61/442,474 | 2011-02-14 | ||
| PCT/US2012/024865 WO2012112445A1 (en) | 2011-02-14 | 2012-02-13 | Low density polyurethane foams |
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| BR112013020709A2 BR112013020709A2 (pt) | 2016-10-18 |
| BR112013020709B1 true BR112013020709B1 (pt) | 2020-08-25 |
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| US9382399B2 (en) * | 2011-05-13 | 2016-07-05 | Mas Innovation (Private) Limited | Foam composition and its uses thereof |
| PL2736935T3 (pl) * | 2011-07-26 | 2019-06-28 | Huntsman International Llc | Sposób wytwarzania elastycznej pianki poliuretanowej |
| US10428170B1 (en) * | 2012-07-31 | 2019-10-01 | Huntsman International Llc | Hydrocarbon blown polyurethane foam formulation giving desirable thermal insulation properties |
| US9223846B2 (en) | 2012-09-18 | 2015-12-29 | International Business Machines Corporation | Context-based navigation through a database |
| US9741138B2 (en) | 2012-10-10 | 2017-08-22 | International Business Machines Corporation | Node cluster relationships in a graph database |
| US9069752B2 (en) | 2013-01-31 | 2015-06-30 | International Business Machines Corporation | Measuring and displaying facets in context-based conformed dimensional data gravity wells |
| US9053102B2 (en) | 2013-01-31 | 2015-06-09 | International Business Machines Corporation | Generation of synthetic context frameworks for dimensionally constrained hierarchical synthetic context-based objects |
| US10152526B2 (en) | 2013-04-11 | 2018-12-11 | International Business Machines Corporation | Generation of synthetic context objects using bounded context objects |
| US9195608B2 (en) | 2013-05-17 | 2015-11-24 | International Business Machines Corporation | Stored data analysis |
| MX370742B (es) * | 2013-05-29 | 2019-12-20 | Dow Quim Mexicana S A De C V | Una formulacion para preparar una espuma de poliuretano. |
| US10662277B2 (en) * | 2014-07-28 | 2020-05-26 | Tosoh Corporation | Polyisocyanate composition for producing flexible polyurethane foam, and flexible polyurethane foam production method using same |
| EP3189090B1 (en) * | 2014-09-04 | 2019-10-30 | Dow Global Technologies LLC | Polyurethane mats |
| ES2925710T3 (es) * | 2014-12-10 | 2022-10-19 | Covestro Intellectual Property Gmbh & Co Kg | Procedimiento para la preparación de espumas de poliuretano viscoelásticas |
| JP5812219B1 (ja) * | 2015-04-17 | 2015-11-11 | 東洋インキＳｃホールディングス株式会社 | 接着剤組成物およびそれを用いた積層体 |
| DK3133097T3 (da) * | 2015-08-17 | 2022-12-19 | Evonik Operations Gmbh | Fremstilling af blødt polyurethanskum med forbedret hårdhed |
| EP3356442B1 (en) * | 2015-09-29 | 2020-04-08 | Basf Se | High-resiliency polyurethane foam |
| EP3374409B1 (en) * | 2015-11-12 | 2020-09-09 | Dow Global Technologies LLC | High molecular weight hydrophobic polyol |
| CN106560478A (zh) * | 2016-08-03 | 2017-04-12 | 广州艾科新材料股份有限公司 | 一种高吸水且带泡孔结构聚氨基甲酸酯的配方及制备方法 |
| CN106432677B (zh) * | 2016-09-29 | 2019-07-09 | 上海东大聚氨酯有限公司 | 组合聚醚、聚氨酯原料组合物、仿木材料及制备方法 |
| CN106478913B (zh) * | 2016-09-29 | 2019-10-01 | 上海东大聚氨酯有限公司 | 组合聚醚、聚氨酯泡沫及其原料组合物、制备方法和应用 |
| CN106397710B (zh) * | 2016-09-30 | 2019-01-01 | 上海东大聚氨酯有限公司 | 组合聚醚、聚氨酯原料组合物、泡沫及制备方法 |
| US20210017324A1 (en) * | 2017-11-10 | 2021-01-21 | Dow Global Technologies Llc | Polyurethane foam system |
| MX2020008433A (es) | 2018-02-15 | 2020-09-25 | 3M Innovative Properties Company | Polimero superabsorbente para espumas de poliuretano. |
| CN108409940B (zh) * | 2018-03-14 | 2021-04-27 | 烟台合力聚氨酯有限公司 | 一种用于制备高回弹泡沫的改性mdi的制备方法 |
| EP3892663A1 (en) | 2020-04-09 | 2021-10-13 | Covestro Deutschland AG | Rigid polyurethane foam |
| US20220112326A1 (en) * | 2020-10-12 | 2022-04-14 | Ford Global Technologies, Llc | Renewable-based flexible polyurethane foams |
| CN114380972B (zh) * | 2020-10-20 | 2024-06-14 | 惠彩材料科技(苏州)有限公司 | 一种软质慢回弹聚氨酯泡棉及其制备方法和应用 |
| EP4301799A1 (en) * | 2021-03-05 | 2024-01-10 | Huntsman International LLC | Moulded polyurethane flexible foams having improved demoulding time |
| US12006453B2 (en) | 2021-07-07 | 2024-06-11 | Pittsburgh Plastics Manufacturing, Inc. | Gel elastomer fastening device |
| KR20240040747A (ko) | 2021-08-11 | 2024-03-28 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 고탄력성 폴리우레탄 폼의 제조 공정 |
| US20240372174A1 (en) | 2023-05-03 | 2024-11-07 | Rogers Corporation | Thermal management sheet, method of manufacture, and articles using the same |
| WO2025240836A1 (en) | 2024-05-17 | 2025-11-20 | Rogers Corporation | Sound-absorbing material |
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| US4394491A (en) | 1980-10-08 | 1983-07-19 | The Dow Chemical Company | Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate |
| US5114989A (en) | 1990-11-13 | 1992-05-19 | The Dow Chemical Company | Isocyanate-terminated prepolymer and polyurethane foam prepared therefrom |
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-
2012
- 2012-02-13 CA CA2827211A patent/CA2827211C/en active Active
- 2012-02-13 BR BR112013020709-4A patent/BR112013020709B1/pt active IP Right Grant
- 2012-02-13 CN CN201280018346.3A patent/CN103635503B/zh active Active
- 2012-02-13 AU AU2012217916A patent/AU2012217916B2/en not_active Ceased
- 2012-02-13 US US13/985,505 patent/US9228047B2/en active Active
- 2012-02-13 JP JP2013553636A patent/JP5902719B2/ja not_active Expired - Fee Related
- 2012-02-13 WO PCT/US2012/024865 patent/WO2012112445A1/en not_active Ceased
- 2012-02-13 MX MX2013009361A patent/MX2013009361A/es active IP Right Grant
- 2012-02-13 EP EP12704493.1A patent/EP2675833B8/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP5902719B2 (ja) | 2016-04-13 |
| CA2827211A1 (en) | 2012-08-23 |
| CA2827211C (en) | 2019-05-21 |
| CN103635503B (zh) | 2016-03-09 |
| US9228047B2 (en) | 2016-01-05 |
| EP2675833B1 (en) | 2017-11-01 |
| CN103635503A (zh) | 2014-03-12 |
| EP2675833B8 (en) | 2017-12-13 |
| AU2012217916B2 (en) | 2016-01-21 |
| WO2012112445A1 (en) | 2012-08-23 |
| JP2014506615A (ja) | 2014-03-17 |
| BR112013020709A2 (pt) | 2016-10-18 |
| US20130331473A1 (en) | 2013-12-12 |
| AU2012217916A1 (en) | 2013-08-29 |
| MX2013009361A (es) | 2013-09-26 |
| EP2675833A1 (en) | 2013-12-25 |
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