BR112013017258A2 - produtos semiacabados compósitos e peças moldadas produzidas dos mesmos, bem como peças moldadas produzidas diretamente à base de (met) acrilatos hidroxi funcionalizados, que são reticulados por meio de uretodionas de maneira termofixa - Google Patents
produtos semiacabados compósitos e peças moldadas produzidas dos mesmos, bem como peças moldadas produzidas diretamente à base de (met) acrilatos hidroxi funcionalizados, que são reticulados por meio de uretodionas de maneira termofixaInfo
- Publication number
- BR112013017258A2 BR112013017258A2 BR112013017258A BR112013017258A BR112013017258A2 BR 112013017258 A2 BR112013017258 A2 BR 112013017258A2 BR 112013017258 A BR112013017258 A BR 112013017258A BR 112013017258 A BR112013017258 A BR 112013017258A BR 112013017258 A2 BR112013017258 A2 BR 112013017258A2
- Authority
- BR
- Brazil
- Prior art keywords
- meth
- molded parts
- parts produced
- functionalized
- hydroxy
- Prior art date
Links
- 239000002131 composite material Substances 0.000 title abstract 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 title abstract 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 title abstract 2
- 239000011265 semifinished product Substances 0.000 title abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229920000058 polyacrylate Polymers 0.000 abstract 2
- 229920001169 thermoplastic Polymers 0.000 abstract 2
- 239000004416 thermosoftening plastic Substances 0.000 abstract 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- 229920000049 Carbon (fiber) Polymers 0.000 abstract 1
- 230000001133 acceleration Effects 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000004982 aromatic amines Chemical class 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 239000004917 carbon fiber Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- -1 for example Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/30—Wind power
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2926—Coated or impregnated inorganic fiber fabric
- Y10T442/2984—Coated or impregnated carbon or carbonaceous fiber fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2926—Coated or impregnated inorganic fiber fabric
- Y10T442/2992—Coated or impregnated glass fiber fabric
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
produtos semiacabados compósitos e peças moldadas produzidas dos mesmos, bem como peças moldadas produzidas diretamente à base de (met) acrilatos hidroxi funcionalizados, que são reticulados por meio de uretodionas de maneira termofixa a invenção refere-se a um processo para a produção de pré-impregnados de poliuterano estáveis ao armazenamento e a artigos moldados (componentes compósitos) produzidos dos mesmos. para produzir pré-impregnados ou componentes, misturam-se monômeros de (met)acrilato, polímweros de (met)acrilato, monômeros de (met)acrilato hidroxi funcionalizados e/ou polímeros de (met)acrilato hidroxi funcionalizados com materiais de uretodina e, além disso, com aminas aromáticas que aceleram uma polimerização por radicais. essa mistura ou solução é aplicada por processos conhecidos em material de fibra, tal como, por exemplo, fibras de carbono, fibras de vidro ou fibras poliméricas e com o auxílio de iniciadores, tal como, por exemplo, peróxido de dibenzoila, essa é polimerizada à temperatura ambiente ou a temperaturas elevadas. ao invés de uma aceleração de amina e subsequente cura com iniciadores, podem ser aplicados também outros sistemas de endurecimento à temperatura ambiente conhecidos, tais como, por exemplo, sistemas de permaleinato. após a polimerização, por exemplo, à temperatura ambiente ou até 80°c, formam-se termoplásticos ou pré-impregnados termoplásticos, que subsequentemente ainda podem ser moldados. os componentes acrilato hidroxi funcionalizados podem ser reticulados, a seguir, com as uretodionas já presentes no sistema por meio de temperatura elevada. dessa maneira, podem ser produzidos termofixos estáveis à dimensão ou componentes compósitos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011002418 | 2011-01-04 | ||
PCT/EP2011/071450 WO2012093006A1 (de) | 2011-01-04 | 2011-12-01 | Composite-halbzeuge und daraus hergestellte formteile sowie direkt hergestellte formteile auf basis von hydroxyfunktionalisierten (meth) acrylaten, die mittels uretdionen duroplastisch vernetzt werden |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112013017258A2 true BR112013017258A2 (pt) | 2016-10-25 |
Family
ID=45349470
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112013017258A BR112013017258A2 (pt) | 2011-01-04 | 2011-12-01 | produtos semiacabados compósitos e peças moldadas produzidas dos mesmos, bem como peças moldadas produzidas diretamente à base de (met) acrilatos hidroxi funcionalizados, que são reticulados por meio de uretodionas de maneira termofixa |
Country Status (12)
Country | Link |
---|---|
US (1) | US9878500B2 (pt) |
EP (1) | EP2661459B1 (pt) |
JP (1) | JP6092120B2 (pt) |
KR (1) | KR101853155B1 (pt) |
CN (1) | CN103298862B (pt) |
BR (1) | BR112013017258A2 (pt) |
CA (1) | CA2823770A1 (pt) |
ES (1) | ES2589453T3 (pt) |
MX (1) | MX2013007753A (pt) |
RU (1) | RU2013136330A (pt) |
TW (1) | TWI570169B (pt) |
WO (1) | WO2012093006A1 (pt) |
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DE102010001992A1 (de) | 2010-02-16 | 2011-08-18 | Evonik Röhm GmbH, 64293 | Funktionsmaterialien mit steuerbarer Viskosität |
DE102010001987A1 (de) | 2010-02-16 | 2011-08-18 | Evonik Röhm GmbH, 64293 | Funktionsmaterialien mit reversibler Vernetzung |
DE102010040282A1 (de) | 2010-09-06 | 2012-03-08 | Evonik Röhm Gmbh | Funktionsmaterialien mit steuerbarer Viskosität bzw. reversibler Vernetzung über Aza-Diels-Alder-Reaktionen mit Bishydrazonen oder konjugierten Bis-Schiff'schen Basen |
DE102010041247A1 (de) | 2010-09-23 | 2012-03-29 | Evonik Degussa Gmbh | Verfahren zur Herstellung von lagerstabilen Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung in Lösung |
DE102010044025A1 (de) | 2010-11-17 | 2012-05-24 | Evonik Röhm Gmbh | Materialien mit steuerbarem Vernetzungsgrad |
DE102011006163A1 (de) | 2011-03-25 | 2012-09-27 | Evonik Degussa Gmbh | Lagerstabile Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung mit flüssigen Harzkomponenten |
DE102011080131A1 (de) | 2011-07-29 | 2013-01-31 | Evonik Degussa Gmbh | Niedermolekulare Produkte, und deren Verwendung als reversible oder permanente Niedertemperatur-Vernetzer bei Diels-Alder-Reaktionen |
DE102011087226A1 (de) | 2011-11-28 | 2013-05-29 | Evonik Degussa Gmbh | Pseudo-thermoplastische, selbstvernetzende Composites |
DE102013204124A1 (de) * | 2013-03-11 | 2014-09-11 | Evonik Industries Ag | Composite-Halbzeuge und daraus hergestellte Formteile sowie direkt hergestellte Formteile auf Basis von hydroxyfunktionalisierten (Meth)Acrylaten und Uretdionen die mittels Strahlung duroplastisch vernetzt werden |
DE102014207785A1 (de) | 2014-04-25 | 2015-10-29 | Evonik Degussa Gmbh | Verfahren zur Herstellung von lagerstabilen Epoxy-Prepregs und daraus hergestellte Composites auf Basis von radikalisch polymerisierbaren Säuren und Epoxiden |
DE102014208415A1 (de) * | 2014-05-06 | 2015-11-12 | Evonik Degussa Gmbh | Herstellung eines auf Stahl und Polyurethan basierenden Faserverbundbauteils |
DE102014208423A1 (de) | 2014-05-06 | 2015-11-12 | Evonik Degussa Gmbh | Herstellung eines auf Aluminium und Polyurethan basierenden Faserverbundbauteils |
EP2979851A1 (de) * | 2014-07-28 | 2016-02-03 | Evonik Degussa GmbH | Effiziente Herstellung von Composite-Halbzeugen und -Bauteilen im Nasspressverfahren unter Einsatz von hydroxyfunktionalisierten (Meth) Acrylaten, die mittels Isocyanaten oder Uretdionen duroplastisch vernetzt werden |
EP2993202A1 (de) * | 2014-09-08 | 2016-03-09 | Evonik Degussa GmbH | Composite-Halbzeuge und daraus hergestellte Formteile sowie direkt hergestellte Formteile auf Basis von hydroxyfunktionalisierten (Meth)Acrylaten und Uretdionen, die duroplastisch vernetzt werden |
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EP3138685B1 (de) | 2015-09-03 | 2019-02-27 | Evonik Degussa GmbH | Hybridbauteil mit einer lokalen versteifung aus einem zweistufig vernetzten, auf polyurethan basierenden faserverbundwerkstoff |
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CN108368279B (zh) * | 2015-12-15 | 2021-07-16 | 陶氏环球技术有限责任公司 | 用于长丝缠绕的聚氨基甲酸酯基树脂 |
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JP5424644B2 (ja) * | 2005-11-30 | 2014-02-26 | アシュランド・ライセンシング・アンド・インテレクチュアル・プロパティー・エルエルシー | プリプレグおよびそれから調製された現場硬化された堅固な表面 |
PL2032621T3 (pl) * | 2006-06-14 | 2020-02-28 | Huntsman International Llc | Sieciowalne termoplastyczne poliuretany |
DE102009001806A1 (de) | 2009-03-24 | 2010-09-30 | Evonik Degussa Gmbh | Prepregs und daraus bei niedriger Temperatur hergestellte Formkörper |
DE102009001793A1 (de) | 2009-03-24 | 2010-10-07 | Evonik Degussa Gmbh | Prepregs und daraus hergestellte Formkörper |
WO2011087737A2 (en) * | 2009-12-22 | 2011-07-21 | 3M Innovative Properties Company | Polishing pad and method of making the same |
DE102010001992A1 (de) | 2010-02-16 | 2011-08-18 | Evonik Röhm GmbH, 64293 | Funktionsmaterialien mit steuerbarer Viskosität |
DE102010001987A1 (de) | 2010-02-16 | 2011-08-18 | Evonik Röhm GmbH, 64293 | Funktionsmaterialien mit reversibler Vernetzung |
DE102010029355A1 (de) | 2010-05-27 | 2011-12-01 | Evonik Degussa Gmbh | Verfahren zur Herstellung von lagerstabilen Polyurethan-Prepregs und daraus hergestellte Formkörper |
DE102010030233A1 (de) | 2010-06-17 | 2011-12-22 | Evonik Degussa Gmbh | Halbzeug für die Herstellung von Faserverbundbauteilen auf Basis von lagerstabilen Polyurethanzusammensetzungen |
DE102010040282A1 (de) | 2010-09-06 | 2012-03-08 | Evonik Röhm Gmbh | Funktionsmaterialien mit steuerbarer Viskosität bzw. reversibler Vernetzung über Aza-Diels-Alder-Reaktionen mit Bishydrazonen oder konjugierten Bis-Schiff'schen Basen |
DE102010041256A1 (de) | 2010-09-23 | 2012-03-29 | Evonik Degussa Gmbh | Prepregs auf der Basis lagerstabiler reaktiven oder hochreaktiven Polyurethanzusammensetzung mit fixierter Folie sowie die daraus hergestellten Composite-Bauteil |
DE102010044025A1 (de) | 2010-11-17 | 2012-05-24 | Evonik Röhm Gmbh | Materialien mit steuerbarem Vernetzungsgrad |
DE102011080131A1 (de) | 2011-07-29 | 2013-01-31 | Evonik Degussa Gmbh | Niedermolekulare Produkte, und deren Verwendung als reversible oder permanente Niedertemperatur-Vernetzer bei Diels-Alder-Reaktionen |
-
2011
- 2011-12-01 KR KR1020137020559A patent/KR101853155B1/ko active IP Right Grant
- 2011-12-01 BR BR112013017258A patent/BR112013017258A2/pt not_active Application Discontinuation
- 2011-12-01 WO PCT/EP2011/071450 patent/WO2012093006A1/de active Application Filing
- 2011-12-01 US US13/978,059 patent/US9878500B2/en not_active Expired - Fee Related
- 2011-12-01 CA CA 2823770 patent/CA2823770A1/en not_active Abandoned
- 2011-12-01 JP JP2013547830A patent/JP6092120B2/ja not_active Expired - Fee Related
- 2011-12-01 CN CN201180064228.1A patent/CN103298862B/zh not_active Expired - Fee Related
- 2011-12-01 ES ES11796946.9T patent/ES2589453T3/es active Active
- 2011-12-01 EP EP11796946.9A patent/EP2661459B1/de not_active Not-in-force
- 2011-12-01 MX MX2013007753A patent/MX2013007753A/es not_active Application Discontinuation
- 2011-12-01 RU RU2013136330/05A patent/RU2013136330A/ru not_active Application Discontinuation
-
2012
- 2012-01-02 TW TW101100046A patent/TWI570169B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN103298862A (zh) | 2013-09-11 |
TW201245299A (en) | 2012-11-16 |
CA2823770A1 (en) | 2012-07-12 |
ES2589453T3 (es) | 2016-11-14 |
WO2012093006A1 (de) | 2012-07-12 |
EP2661459A1 (de) | 2013-11-13 |
JP2014501838A (ja) | 2014-01-23 |
KR20130140135A (ko) | 2013-12-23 |
JP6092120B2 (ja) | 2017-03-08 |
CN103298862B (zh) | 2017-05-03 |
US9878500B2 (en) | 2018-01-30 |
KR101853155B1 (ko) | 2018-04-27 |
MX2013007753A (es) | 2013-08-15 |
US20130323993A1 (en) | 2013-12-05 |
EP2661459B1 (de) | 2016-06-08 |
RU2013136330A (ru) | 2015-02-10 |
TWI570169B (zh) | 2017-02-11 |
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