BR112013014809B1 - polímero a base de etileno, composição e artigo - Google Patents
polímero a base de etileno, composição e artigo Download PDFInfo
- Publication number
- BR112013014809B1 BR112013014809B1 BR112013014809-8A BR112013014809A BR112013014809B1 BR 112013014809 B1 BR112013014809 B1 BR 112013014809B1 BR 112013014809 A BR112013014809 A BR 112013014809A BR 112013014809 B1 BR112013014809 B1 BR 112013014809B1
- Authority
- BR
- Brazil
- Prior art keywords
- ethylene
- fact
- based polymer
- polymer
- film
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 125
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 85
- 239000005977 Ethylene Substances 0.000 title claims abstract description 85
- 239000000203 mixture Substances 0.000 title claims abstract description 75
- 238000005227 gel permeation chromatography Methods 0.000 claims description 41
- 229920001684 low density polyethylene Polymers 0.000 claims description 30
- 239000004702 low-density polyethylene Substances 0.000 claims description 30
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 239000000155 melt Substances 0.000 claims description 11
- 239000004711 α-olefin Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
- 238000000518 rheometry Methods 0.000 claims description 3
- OYFJQPXVCSSHAI-QFPUQLAESA-N enalapril maleate Chemical compound OC(=O)\C=C/C(O)=O.C([C@@H](C(=O)OCC)N[C@@H](C)C(=O)N1[C@@H](CCC1)C(O)=O)CC1=CC=CC=C1 OYFJQPXVCSSHAI-QFPUQLAESA-N 0.000 claims description 2
- 238000004611 spectroscopical analysis Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 description 49
- 238000000149 argon plasma sintering Methods 0.000 description 46
- 239000000523 sample Substances 0.000 description 45
- 238000006243 chemical reaction Methods 0.000 description 38
- 230000000052 comparative effect Effects 0.000 description 38
- 230000008569 process Effects 0.000 description 30
- 238000004519 manufacturing process Methods 0.000 description 25
- -1 polyethylene Polymers 0.000 description 22
- 238000009472 formulation Methods 0.000 description 21
- 238000010828 elution Methods 0.000 description 19
- 239000004698 Polyethylene Substances 0.000 description 18
- 239000012986 chain transfer agent Substances 0.000 description 18
- 238000002347 injection Methods 0.000 description 18
- 239000007924 injection Substances 0.000 description 18
- 229920000573 polyethylene Polymers 0.000 description 18
- 229920000092 linear low density polyethylene Polymers 0.000 description 17
- 150000002978 peroxides Chemical class 0.000 description 17
- 239000003999 initiator Substances 0.000 description 16
- 239000004707 linear low-density polyethylene Substances 0.000 description 16
- 239000000178 monomer Substances 0.000 description 14
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 13
- 238000004364 calculation method Methods 0.000 description 12
- 238000005259 measurement Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 239000004793 Polystyrene Substances 0.000 description 11
- 230000008602 contraction Effects 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 11
- 229920002223 polystyrene Polymers 0.000 description 11
- 239000011159 matrix material Substances 0.000 description 10
- 238000004064 recycling Methods 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 230000006870 function Effects 0.000 description 7
- 238000010348 incorporation Methods 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 230000004044 response Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000005481 NMR spectroscopy Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000006057 Non-nutritive feed additive Substances 0.000 description 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- FVQMJJQUGGVLEP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)C FVQMJJQUGGVLEP-UHFFFAOYSA-N 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000001374 small-angle light scattering Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229920000034 Plastomer Polymers 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 239000012809 cooling fluid Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000003446 memory effect Effects 0.000 description 2
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920005638 polyethylene monopolymer Polymers 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- 238000010094 polymer processing Methods 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000012925 reference material Substances 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229920006300 shrink film Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- QVLAWKAXOMEXPM-DICFDUPASA-N 1,1,1,2-tetrachloro-2,2-dideuterioethane Chemical compound [2H]C([2H])(Cl)C(Cl)(Cl)Cl QVLAWKAXOMEXPM-DICFDUPASA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 238000000333 X-ray scattering Methods 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- MJSNUBOCVAKFIJ-LNTINUHCSA-N chromium;(z)-4-oxoniumylidenepent-2-en-2-olate Chemical compound [Cr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MJSNUBOCVAKFIJ-LNTINUHCSA-N 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000001595 contractor effect Effects 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229950010765 pivalate Drugs 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004460 silage Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000001370 static light scattering Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000002235 transmission spectroscopy Methods 0.000 description 1
- 238000000196 viscometry Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061424386P | 2010-12-17 | 2010-12-17 | |
| US61/424,386 | 2010-12-17 | ||
| PCT/US2011/062991 WO2012082393A1 (en) | 2010-12-17 | 2011-12-02 | Ethylene-based polymers and processess to make the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112013014809A2 BR112013014809A2 (pt) | 2016-09-27 |
| BR112013014809B1 true BR112013014809B1 (pt) | 2020-10-27 |
Family
ID=45218948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112013014809-8A BR112013014809B1 (pt) | 2010-12-17 | 2011-12-02 | polímero a base de etileno, composição e artigo |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8822601B2 (enExample) |
| EP (1) | EP2651987B1 (enExample) |
| JP (2) | JP6328933B2 (enExample) |
| KR (1) | KR101845119B1 (enExample) |
| CN (1) | CN103347907B (enExample) |
| AR (1) | AR084330A1 (enExample) |
| BR (1) | BR112013014809B1 (enExample) |
| CA (1) | CA2821248C (enExample) |
| ES (1) | ES2605991T3 (enExample) |
| SG (1) | SG191149A1 (enExample) |
| WO (1) | WO2012082393A1 (enExample) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013178242A1 (en) * | 2012-05-31 | 2013-12-05 | Borealis Ag | Low density polyethylene for extrusion coating |
| IN2015DN02921A (enExample) * | 2012-09-28 | 2015-09-18 | Dow Global Technologies Llc | |
| JP6302473B2 (ja) * | 2012-09-28 | 2018-03-28 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーおよびその製造方法 |
| KR102166723B1 (ko) * | 2013-05-22 | 2020-10-20 | 다우 글로벌 테크놀로지스 엘엘씨 | 고용융 강도를 갖는 저밀도 에틸렌-기반 폴리머를 함유하는 조성물 및 이로부터 형성된 필름 |
| BR112015027849B1 (pt) | 2013-05-22 | 2020-08-18 | Dow Global Technologies Llc | Composição, artigo e filme |
| ES2772183T3 (es) | 2014-12-30 | 2020-07-07 | Dow Global Technologies Llc | Proceso para controlar la producción y calidad del polímero a base de etileno formado mediante polimerización por radicales libres a alta presión |
| KR102488907B1 (ko) * | 2015-02-13 | 2023-01-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 쿠션 망상 구조, 및 이들의 제조 방법 |
| US10400046B2 (en) | 2015-06-25 | 2019-09-03 | Joseph J. Matsko | Portable powered paint system |
| WO2017039986A1 (en) | 2015-08-31 | 2017-03-09 | Dow Global Technologies Llc | Multilayer films and methods thereof |
| EP3168237A1 (en) | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
| CN108602997B (zh) * | 2016-02-23 | 2021-10-15 | 陶氏环球技术有限责任公司 | 基于乙烯的聚合物和其制备方法 |
| ES2848573T3 (es) * | 2016-05-18 | 2021-08-10 | Dow Global Technologies Llc | Polímeros a base de etileno y procesos para obtener los mismos |
| KR102065719B1 (ko) * | 2017-01-25 | 2020-01-13 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| WO2018139874A1 (ko) * | 2017-01-25 | 2018-08-02 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| BR112019016874B1 (pt) | 2017-02-28 | 2023-04-18 | Dow Global Technologies Llc | Composição, artigo e película de múltiplas camadas |
| US10836852B2 (en) | 2017-03-21 | 2020-11-17 | Dow Global Technologies Llc | Ethylene-based polymers with improved optics |
| US11193008B2 (en) * | 2017-04-10 | 2021-12-07 | Exxonmobil Chemical Patents Inc. | Methods for making polyolefin polymer compositions |
| WO2018218470A1 (en) | 2017-05-29 | 2018-12-06 | Dow Global Technologies Llc | Thermoplastic polyolefin compositions useful for aldehyde abatement |
| JP7171628B2 (ja) | 2017-06-28 | 2022-11-15 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーを生成するための高圧フリーラジカル重合 |
| ES2890954T3 (es) | 2017-07-28 | 2022-01-25 | Dow Global Technologies Llc | Polímeros basados en etileno de baja densidad para operaciones de revestimiento por extrusión de baja velocidad |
| KR102148084B1 (ko) * | 2018-12-11 | 2020-08-25 | 한화토탈 주식회사 | 고강도 섬유용 폴리에틸렌계 수지 조성물 |
| US20220251255A1 (en) | 2019-05-31 | 2022-08-11 | Dow Global Technologies Llc | Low density polyethylene with improved processability |
| EP3976678A1 (en) | 2019-05-31 | 2022-04-06 | Dow Global Technologies LLC | Ziegler-natta catalyzed polyethylene resins and films incorporating same |
| AR119085A1 (es) | 2019-06-06 | 2021-11-24 | Dow Global Technologies Llc | Película soplada multicapa |
| CN114555364A (zh) | 2019-10-17 | 2022-05-27 | 陶氏环球技术有限责任公司 | 多层膜和包含多层膜的制品 |
| WO2021206941A1 (en) | 2020-04-06 | 2021-10-14 | Dow Global Technologies Llc | Enhanced melt strength low-density polyethylene for use in films or blends |
| JP7516228B2 (ja) * | 2020-11-30 | 2024-07-16 | 住友化学株式会社 | 高圧法低密度ポリエチレン製造装置及び製造方法 |
| CN116490362A (zh) | 2020-12-08 | 2023-07-25 | 陶氏环球技术有限责任公司 | 涂覆制品 |
| EP4259423A1 (en) | 2020-12-08 | 2023-10-18 | Dow Global Technologies LLC | Article |
| CN116600992A (zh) | 2020-12-08 | 2023-08-15 | 陶氏环球技术有限责任公司 | 制品 |
| JP2024509738A (ja) | 2021-02-19 | 2024-03-05 | ダウ グローバル テクノロジーズ エルエルシー | 変性低密度ポリエチレン樹脂及びその製造方法 |
| WO2024163044A1 (en) | 2023-01-30 | 2024-08-08 | Dow Global Technologies Llc | Article made from recycled material containing adhesive and process |
| WO2025117421A1 (en) | 2023-11-30 | 2025-06-05 | Dow Global Technologies Llc | Recyclable polyolefin films and laminates |
| TW202523491A (zh) | 2023-11-30 | 2025-06-16 | 美商陶氏全球科技有限責任公司 | 可回收聚合物層壓體 |
| TW202523766A (zh) | 2023-11-30 | 2025-06-16 | 美商陶氏全球科技有限責任公司 | 再循環聚烯烴膜與層壓體 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4511609A (en) | 1982-09-30 | 1985-04-16 | Union Carbide Corporation | Multilayer trash bag film |
| JPH066649B2 (ja) | 1985-04-19 | 1994-01-26 | 三井石油化学工業株式会社 | ポリエチレン組成物 |
| US4705829A (en) | 1986-04-11 | 1987-11-10 | Mobil Oil Corporation | Low density polyethylene resin compositions and thermoplastic films thereof |
| US5582923A (en) * | 1991-10-15 | 1996-12-10 | The Dow Chemical Company | Extrusion compositions having high drawdown and substantially reduced neck-in |
| JP3157163B2 (ja) | 1991-12-30 | 2001-04-16 | ザ・ダウ・ケミカル・カンパニー | エチレンインターポリマーの重合 |
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| EP0600482B1 (en) | 1992-12-03 | 1998-04-08 | Mitsubishi Chemical Corporation | Resin composition for laminates |
| HU225374B1 (en) | 1993-01-29 | 2006-10-28 | Dow Global Technologies Inc | Process for producing ethylene/alfa-olefin interpolymer composition |
| US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
| US5869575A (en) | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
| JPH11171922A (ja) * | 1997-12-12 | 1999-06-29 | Nippon Unicar Co Ltd | 高融点低密度ポリエチレン樹脂 |
| US6407191B1 (en) | 1998-01-12 | 2002-06-18 | The Dow Chemical Company | Medium density ethylene polymers, a process to prepare these polymers and use of carbonyl group containing chain transfer agents in this process |
| EA005112B1 (ru) * | 1999-05-05 | 2004-10-28 | Бп Кемикэлз Лимитед | Сополимеры этилена и пленки из них |
| US20060167193A1 (en) * | 2003-03-06 | 2006-07-27 | Basell Polyolefine Gmbh | Regulation of the continuous ethylene polymerization process in a high-pressure reactor |
| JP2005232227A (ja) | 2004-02-17 | 2005-09-02 | Tosoh Corp | ポリエチレン樹脂組成物、それからなるフィルム及びその積層体 |
| US7741415B2 (en) | 2004-11-02 | 2010-06-22 | Dow Global Technologies Inc | Process for producing low density polyethylene compositions and polymers produced therefrom |
| US7538173B2 (en) * | 2005-11-21 | 2009-05-26 | Equistar Chemicals Lp | Polyolefin compositions |
| US8247065B2 (en) | 2006-05-31 | 2012-08-21 | Exxonmobil Chemical Patents Inc. | Linear polymers, polymer blends, and articles made therefrom |
| KR20110084905A (ko) * | 2008-10-07 | 2011-07-26 | 다우 글로벌 테크놀로지스 엘엘씨 | 고 활성 사슬 전달제의 사용을 통해 제조된 개선된 광학 성질을 가진 고압 저밀도 폴리에틸렌 수지 |
| US9243087B2 (en) | 2009-06-11 | 2016-01-26 | Dow Global Technologies Llc | LDPE enabling high output and good optics when blended with other polymers |
| WO2011019563A1 (en) | 2009-08-10 | 2011-02-17 | Dow Global Technologies Inc. | Ldpe for use as a blend component in shrinkage film applications |
-
2011
- 2011-12-02 BR BR112013014809-8A patent/BR112013014809B1/pt active IP Right Grant
- 2011-12-02 US US13/990,064 patent/US8822601B2/en active Active
- 2011-12-02 SG SG2013045653A patent/SG191149A1/en unknown
- 2011-12-02 KR KR1020137018568A patent/KR101845119B1/ko active Active
- 2011-12-02 EP EP11793991.8A patent/EP2651987B1/en active Active
- 2011-12-02 CN CN201180067349.1A patent/CN103347907B/zh active Active
- 2011-12-02 CA CA2821248A patent/CA2821248C/en active Active
- 2011-12-02 ES ES11793991.8T patent/ES2605991T3/es active Active
- 2011-12-02 JP JP2013544533A patent/JP6328933B2/ja active Active
- 2011-12-02 WO PCT/US2011/062991 patent/WO2012082393A1/en not_active Ceased
- 2011-12-16 AR ARP110104733A patent/AR084330A1/es active IP Right Grant
-
2017
- 2017-01-27 JP JP2017013514A patent/JP2017101251A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ES2605991T3 (es) | 2017-03-17 |
| BR112013014809A2 (pt) | 2016-09-27 |
| WO2012082393A1 (en) | 2012-06-21 |
| KR101845119B1 (ko) | 2018-04-03 |
| EP2651987A1 (en) | 2013-10-23 |
| KR20130140110A (ko) | 2013-12-23 |
| AR084330A1 (es) | 2013-05-08 |
| CN103347907A (zh) | 2013-10-09 |
| SG191149A1 (en) | 2013-07-31 |
| CA2821248C (en) | 2019-01-08 |
| EP2651987B1 (en) | 2016-09-21 |
| US8822601B2 (en) | 2014-09-02 |
| JP2017101251A (ja) | 2017-06-08 |
| CN103347907B (zh) | 2016-10-26 |
| JP2013545873A (ja) | 2013-12-26 |
| US20130261265A1 (en) | 2013-10-03 |
| JP6328933B2 (ja) | 2018-05-23 |
| CA2821248A1 (en) | 2012-06-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR112013014809B1 (pt) | polímero a base de etileno, composição e artigo | |
| BR112015006812B1 (pt) | Composição | |
| CN104781289B (zh) | 乙烯基聚合物和其制造方法 | |
| JP5989073B2 (ja) | エチレン系ポリマー組成物 | |
| BRPI0906091B1 (pt) | Polímetro etilênico e processo para preparar polímetros etilênicos. | |
| BRPI1009017B1 (pt) | polímero baseado em etileno, composição de polímero baseado em etileno e pelo menos uma camada de película | |
| BR112012003072B1 (pt) | Polímero à base de etileno, composição e camada de película | |
| BR112013013634B1 (pt) | processo para formar uma composição de polímero baseada em etileno, composição de polímero, composição, artigo | |
| BR112018016355B1 (pt) | Composição e artigo | |
| BR112019016874B1 (pt) | Composição, artigo e película de múltiplas camadas | |
| BR112019001264B1 (pt) | Espuma de polietileno não reticulada formada a partir de uma composição de polietileno |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B09X | Republication of the decision to grant [chapter 9.1.3 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 02/12/2011, OBSERVADAS AS CONDICOES LEGAIS. |