BR112013007779B1 - processo para produzir um poliuretano flexível e resiliente - Google Patents
processo para produzir um poliuretano flexível e resiliente Download PDFInfo
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- BR112013007779B1 BR112013007779B1 BR112013007779A BR112013007779A BR112013007779B1 BR 112013007779 B1 BR112013007779 B1 BR 112013007779B1 BR 112013007779 A BR112013007779 A BR 112013007779A BR 112013007779 A BR112013007779 A BR 112013007779A BR 112013007779 B1 BR112013007779 B1 BR 112013007779B1
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- Prior art keywords
- polyol
- weight
- mixture
- less
- flexible
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- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- QVQGTNFYPJQJNM-UHFFFAOYSA-N dicyclohexylmethanamine Chemical compound C1CCCCC1C(N)C1CCCCC1 QVQGTNFYPJQJNM-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 230000011987 methylation Effects 0.000 description 1
- 238000007069 methylation reaction Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- KFIGICHILYTCJF-UHFFFAOYSA-N n'-methylethane-1,2-diamine Chemical compound CNCCN KFIGICHILYTCJF-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004616 structural foam Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- NQRYJNQNLNOLGT-UHFFFAOYSA-N tetrahydropyridine hydrochloride Natural products C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000003190 viscoelastic substance Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/125—Water, e.g. hydrated salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/02—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/06—Flexible foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38868410P | 2010-10-01 | 2010-10-01 | |
| PCT/US2010/059169 WO2012044338A1 (en) | 2010-10-01 | 2010-12-07 | Process for making low density high resiliency flexible polyurethane foam |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112013007779A2 BR112013007779A2 (pt) | 2016-06-07 |
| BR112013007779B1 true BR112013007779B1 (pt) | 2019-09-03 |
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| US (1) | US8957123B2 (https=) |
| EP (1) | EP2621987B1 (https=) |
| JP (1) | JP5905892B2 (https=) |
| KR (1) | KR101795111B1 (https=) |
| CN (1) | CN103221445B (https=) |
| BR (1) | BR112013007779B1 (https=) |
| WO (1) | WO2012044338A1 (https=) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103709367B (zh) * | 2012-09-29 | 2018-09-04 | 科思创聚合物（中国）有限公司 | 聚氨酯组合物以及聚氨酯道碴道床的维修方法 |
| TR201905777T4 (tr) * | 2014-04-01 | 2019-05-21 | Dow Global Technologies Llc | Poliüretan ürünler yapmak için iyi üfleme-jelleşme dengesi sağlayan polieter poliol. |
| JP6215285B2 (ja) * | 2015-03-31 | 2017-10-18 | 三洋化成工業株式会社 | 軟質ポリウレタンモールドフォームの製造方法 |
| US11041041B2 (en) * | 2015-10-08 | 2021-06-22 | Dow Global Technologies Llc | High resiliency polyurethane foams made with high functionality, high equivalent weight polyols with mainly secondary hydroxyl groups |
| KR102320607B1 (ko) * | 2016-03-29 | 2021-11-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 반 경질 폴리우레탄 발포체 및 제조 방법 |
| CN110167986B (zh) * | 2017-01-23 | 2022-01-18 | 陶氏环球技术有限责任公司 | 柔性聚氨酯泡沫和制得方法 |
| WO2018169833A1 (en) * | 2017-03-15 | 2018-09-20 | Covestro Llc | Viscoelastic polyurethane foams with reduced temperature sensitivity |
| CN107189028B (zh) * | 2017-06-23 | 2020-02-28 | 黎明化工研究设计院有限责任公司 | 一种环保高性能快速脱模聚氨酯反应注射成型组合物及其自催化扩链剂的制备方法 |
| BR112020008298A2 (pt) | 2017-11-10 | 2020-10-20 | Dow Global Technologies Llc | sistema de espuma de poliuretano |
| CN111263781B (zh) * | 2017-11-10 | 2022-10-18 | 陶氏环球技术有限责任公司 | 聚氨酯泡沫系统 |
| CN107857865B (zh) * | 2017-11-20 | 2021-07-16 | 郑州精益达汽车零部件有限公司 | 一种汽车座椅用全水环保阻燃型胀气记忆聚氨酯泡沫及其制备方法 |
| CN109836551B (zh) * | 2019-01-28 | 2021-12-10 | 上海鸿得聚氨酯有限公司 | 一种聚氨酯运动防护泡沫衬垫组合物及其制备方法 |
| JP7678764B2 (ja) * | 2019-05-13 | 2025-05-16 | ダウ グローバル テクノロジーズ エルエルシー | 低密度、低圧縮永久歪み、長回復時間のポリウレタンフォーム |
| CN110144036A (zh) * | 2019-06-12 | 2019-08-20 | 烟台市顺达聚氨酯有限责任公司 | 一种全水低密度聚氨酯包装材料及其制备方法 |
| KR102843007B1 (ko) * | 2019-09-30 | 2025-08-11 | 현대자동차주식회사 | 외관 성형성, 냄새저감 및 흡음성능이 향상된 흡음재용 저밀도 폴리우레탄 폼 조성물, 폴리우레탄 폼 제조방법 및 이를 통해 제조된 폴리우레탄 폼 |
| EP3892663A1 (en) | 2020-04-09 | 2021-10-13 | Covestro Deutschland AG | Rigid polyurethane foam |
| CN112175163B (zh) * | 2020-09-30 | 2022-03-29 | 合肥安利聚氨酯新材料有限公司 | 一种具有自催化性能的电子包装革用无溶剂中间层聚氨酯树脂的制备方法和应用 |
| US20220112326A1 (en) * | 2020-10-12 | 2022-04-14 | Ford Global Technologies, Llc | Renewable-based flexible polyurethane foams |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03239716A (ja) * | 1990-02-19 | 1991-10-25 | Sanyo Chem Ind Ltd | 軟質ポリウレタンフォーム形成組成物および製法 |
| DE4135588A1 (de) | 1991-10-29 | 1993-05-06 | Basf Ag, 6700 Ludwigshafen, De | Hochreaktive, tertiaere aminogruppen gebunden enthaltende polyoxyalkylenpolyole, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyisocyanat-polyadditionsprodukten |
| AU2001234776B2 (en) | 2000-02-10 | 2006-02-23 | Dow Global Technologies Inc. | Low emission polyurethane polymers made with autocatalytic polyols |
| TW592813B (en) * | 2001-08-15 | 2004-06-21 | Dow Global Technologies Inc | Process to manufacture polyurethane products |
| PL368988A1 (en) | 2001-10-01 | 2005-04-04 | Dow Global Technologies Inc. | Autocatalytic polyols with gelling characteristics and polyurethane products made therefrom |
| AU2002357617A1 (en) * | 2001-12-21 | 2003-07-09 | Asahi Glass Company, Limited | Low-resilience flexible polyurethane foam and process for producing the same |
| TW200516093A (en) * | 2003-09-19 | 2005-05-16 | Asahi Glass Co Ltd | Flexible polyurethane foam and process for producing the same |
| JP4771367B2 (ja) * | 2003-10-28 | 2011-09-14 | 三井化学株式会社 | 軟質ポリウレタンフォームおよびその用途 |
| JP4791375B2 (ja) * | 2003-12-23 | 2011-10-12 | ダウ グローバル テクノロジーズ エルエルシー | イミン結合および第３級アミンを含有する堅牢触媒（ｎｏｎ−ｆｕｇｉｔｉｖｅｃａｔａｌｙｓｔｓ）、ならびにそれから作製したポリウレタン製品 |
| JP4412116B2 (ja) | 2004-08-30 | 2010-02-10 | 旭硝子株式会社 | 低反発性軟質ポリウレタンフォームおよびその製造方法 |
| JP4910702B2 (ja) * | 2004-11-18 | 2012-04-04 | 旭硝子株式会社 | 軟質ポリウレタンフォームの製造方法 |
| US20070142607A1 (en) * | 2005-12-15 | 2007-06-21 | Bayer Materialscience Llc | Weather resistant polyurethane elastomer |
| RU2435793C2 (ru) | 2006-03-23 | 2011-12-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Полиолы на основе природных масел с собственными поверхностно-активными свойствами для вспенивания полиуретанов |
| EP2403887A1 (en) * | 2009-03-05 | 2012-01-11 | Dow Global Technologies LLC (formerly Known As Dow Global Technologies Inc.) | Polyols from hppo and polyurethane products made therefrom |
| EP2519558B1 (en) * | 2009-12-29 | 2015-01-21 | Dow Global Technologies LLC | Method for making low density polyurethane foam for sound and vibration absorption |
-
2010
- 2010-12-07 BR BR112013007779A patent/BR112013007779B1/pt active IP Right Grant
- 2010-12-07 EP EP10788483.5A patent/EP2621987B1/en active Active
- 2010-12-07 US US13/876,620 patent/US8957123B2/en active Active
- 2010-12-07 JP JP2013531561A patent/JP5905892B2/ja active Active
- 2010-12-07 CN CN201080070201.9A patent/CN103221445B/zh active Active
- 2010-12-07 KR KR1020137011446A patent/KR101795111B1/ko active Active
- 2010-12-07 WO PCT/US2010/059169 patent/WO2012044338A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JP5905892B2 (ja) | 2016-04-20 |
| EP2621987A1 (en) | 2013-08-07 |
| CN103221445A (zh) | 2013-07-24 |
| EP2621987B1 (en) | 2015-07-29 |
| WO2012044338A1 (en) | 2012-04-05 |
| JP2013540179A (ja) | 2013-10-31 |
| US8957123B2 (en) | 2015-02-17 |
| BR112013007779A2 (pt) | 2016-06-07 |
| CN103221445B (zh) | 2015-02-04 |
| KR101795111B1 (ko) | 2017-11-07 |
| KR20130115271A (ko) | 2013-10-21 |
| US20130184368A1 (en) | 2013-07-18 |
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