BR112013005428A2 - processo para animação direta de álcoois secundários com amônia para formar aminas primárias - Google Patents

processo para animação direta de álcoois secundários com amônia para formar aminas primárias

Info

Publication number
BR112013005428A2
BR112013005428A2 BR112013005428A BR112013005428A BR112013005428A2 BR 112013005428 A2 BR112013005428 A2 BR 112013005428A2 BR 112013005428 A BR112013005428 A BR 112013005428A BR 112013005428 A BR112013005428 A BR 112013005428A BR 112013005428 A2 BR112013005428 A2 BR 112013005428A2
Authority
BR
Brazil
Prior art keywords
ammonia
primary amines
secondary alcohols
form primary
phase
Prior art date
Application number
BR112013005428A
Other languages
English (en)
Inventor
Andreas Martin
Angela Kockritz
Florian Klasovsky
Jan Christoph Pfeffer
Jens Deutsch
Thomas Haas
Thomas Tacke
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of BR112013005428A2 publication Critical patent/BR112013005428A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

processo para animação direta de álcoois secundários com amônia para formar aminas primárias. a presente invenção refere-se a um processo para preparação de aminas primárias compreendendo as etapas de processo a) preparação de uma solução de um álcool secundário em uma fase fluida, não gasosa, b) contatação da fase com amônia livre e/ou com pelo menos um composto que libera amônia e um catalisador homogênio e, se apropriado, c) isolamento da amina primária formada na etapa de processo b), caraccterizado pelo fato de que a proporção em volume da fase líquida para o volume da fase gasosa na etapa de processo b é maior ou igual a 0,25 e/ou qua a amônia na etapa de processo b) relativo aos grupos hidroxila no álcool secundário é empregada em uma proporção molar de pelo menos 5 para 1.
BR112013005428A 2010-09-10 2011-08-23 processo para animação direta de álcoois secundários com amônia para formar aminas primárias BR112013005428A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102010040560 2010-09-10
DE201110004465 DE102011004465A1 (de) 2010-09-10 2011-02-21 Verfahren zur direkten Aminierung sekundärer Alkohole mit Ammoniak zu primären Aminen
PCT/EP2011/064435 WO2012031884A1 (de) 2010-09-10 2011-08-23 Verfahren zur direkten aminierung sekundärer alkohole mit ammoniak zu primären aminen

Publications (1)

Publication Number Publication Date
BR112013005428A2 true BR112013005428A2 (pt) 2016-06-07

Family

ID=44645668

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013005428A BR112013005428A2 (pt) 2010-09-10 2011-08-23 processo para animação direta de álcoois secundários com amônia para formar aminas primárias

Country Status (9)

Country Link
US (1) US8927773B2 (pt)
EP (1) EP2614042A1 (pt)
JP (1) JP5946455B2 (pt)
CN (1) CN103097324A (pt)
BR (1) BR112013005428A2 (pt)
CA (1) CA2807605A1 (pt)
DE (1) DE102011004465A1 (pt)
RU (1) RU2593994C2 (pt)
WO (1) WO2012031884A1 (pt)

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EP2647696A1 (de) 2012-04-02 2013-10-09 Evonik Degussa GmbH Verfahren zur aeroben Herstellung von Alanin oder einer unter Verbrauch von Alanin entstehenden Verbindung
CN104487444B (zh) * 2012-07-23 2017-03-29 巴斯夫欧洲公司 在不含阴离子配体的配合物催化剂存在下用氨均相催化胺化醇的方法
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EP2746397A1 (de) 2012-12-21 2014-06-25 Evonik Industries AG Herstellung von Omega-Aminofettsäuren
EP2746400A1 (de) 2012-12-21 2014-06-25 Evonik Industries AG Herstellung von Aminen und Diaminen aus einer Carbonsäure oder Dicarbonsäure oder eines Monoesters davon
EP2759598A1 (de) 2013-01-24 2014-07-30 Evonik Industries AG Verfahren zur Herstellung von alpha, omega-Alkandiol
WO2016008547A1 (de) * 2014-07-18 2016-01-21 Rheinisch-Westfälische Technische Hochschlule (Rwth) Aachen Verfahren zur herstellung primärer isohexid-amine
KR20170083085A (ko) 2014-11-10 2017-07-17 로디아 오퍼레이션스 직접 아민화 반응에 의한 아민을 형성하는 방법
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Also Published As

Publication number Publication date
US8927773B2 (en) 2015-01-06
RU2013115801A (ru) 2014-10-20
JP5946455B2 (ja) 2016-07-06
DE102011004465A1 (de) 2012-03-15
RU2593994C2 (ru) 2016-08-10
EP2614042A1 (de) 2013-07-17
CN103097324A (zh) 2013-05-08
CA2807605A1 (en) 2012-03-15
WO2012031884A1 (de) 2012-03-15
JP2013538816A (ja) 2013-10-17
US20130165672A1 (en) 2013-06-27

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

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