BG63311B1 - Нови съполимерни сулфидни минерални депресанти и метод за използването им - Google Patents
Нови съполимерни сулфидни минерални депресанти и метод за използването им Download PDFInfo
- Publication number
- BG63311B1 BG63311B1 BG102747A BG10274798A BG63311B1 BG 63311 B1 BG63311 B1 BG 63311B1 BG 102747 A BG102747 A BG 102747A BG 10274798 A BG10274798 A BG 10274798A BG 63311 B1 BG63311 B1 BG 63311B1
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- Prior art keywords
- hydrogen
- units
- valuable
- range
- rock
- Prior art date
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- 229920001577 copolymer Polymers 0.000 title claims abstract description 45
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 35
- 239000011707 mineral Substances 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 14
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title abstract description 19
- 239000011435 rock Substances 0.000 claims abstract description 29
- 238000005188 flotation Methods 0.000 claims abstract description 22
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 17
- 239000012535 impurity Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004088 foaming agent Substances 0.000 claims abstract description 4
- 239000006260 foam Substances 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims abstract description 3
- 239000001257 hydrogen Substances 0.000 claims description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 17
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 229960001748 allylthiourea Drugs 0.000 claims description 10
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical group CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 9
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical group NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 5
- RMCLKZFGXBSDIO-UHFFFAOYSA-N 3,3-dihydroxypropyl 2-methylprop-2-enoate Chemical group CC(=C)C(=O)OCCC(O)O RMCLKZFGXBSDIO-UHFFFAOYSA-N 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 5
- 239000010802 sludge Substances 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 3
- 150000002431 hydrogen Chemical group 0.000 claims 4
- 230000005494 condensation Effects 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 5
- 230000001143 conditioned effect Effects 0.000 abstract description 3
- 239000013055 pulp slurry Substances 0.000 abstract 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 19
- 229910052725 zinc Inorganic materials 0.000 description 19
- 239000011701 zinc Substances 0.000 description 19
- 229910052569 sulfide mineral Inorganic materials 0.000 description 9
- 150000004763 sulfides Chemical class 0.000 description 9
- -1 alkyl acrylamides Chemical class 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 8
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 7
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 6
- 230000000881 depressing effect Effects 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 229910052683 pyrite Inorganic materials 0.000 description 5
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 5
- 239000011028 pyrite Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 229910001656 zinc mineral Inorganic materials 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical class [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052952 pyrrhotite Inorganic materials 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052950 sphalerite Inorganic materials 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- WOCGAOBSWOEOTH-UHFFFAOYSA-N 2,2-dihydroxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(O)O WOCGAOBSWOEOTH-UHFFFAOYSA-N 0.000 description 1
- UCQSDHBYLHDTQP-UHFFFAOYSA-N 4,4-dihydroxybutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCC(O)O UCQSDHBYLHDTQP-UHFFFAOYSA-N 0.000 description 1
- UFRVDAKKTKKSFN-UHFFFAOYSA-N 4,4-dihydroxybutyl prop-2-enoate Chemical compound OC(O)CCCOC(=O)C=C UFRVDAKKTKKSFN-UHFFFAOYSA-N 0.000 description 1
- BDUXUMCSFCPKFQ-UHFFFAOYSA-N 5,5-dihydroxypentyl prop-2-enoate Chemical compound OC(O)CCCCOC(=O)C=C BDUXUMCSFCPKFQ-UHFFFAOYSA-N 0.000 description 1
- ZZQCHOZVNQOHQE-UHFFFAOYSA-N 6,6-dihydroxyhexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCC(O)O ZZQCHOZVNQOHQE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004160 Ammonium persulphate Substances 0.000 description 1
- NABGKRWTAWMXRC-UHFFFAOYSA-N C(C=C)(=O)OC1CCC(CC1)(O)O Chemical compound C(C=C)(=O)OC1CCC(CC1)(O)O NABGKRWTAWMXRC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- WIKSRXFQIZQFEH-UHFFFAOYSA-N [Cu].[Pb] Chemical compound [Cu].[Pb] WIKSRXFQIZQFEH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 235000019395 ammonium persulphate Nutrition 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- WUUZKBJEUBFVMV-UHFFFAOYSA-N copper molybdenum Chemical compound [Cu].[Mo] WUUZKBJEUBFVMV-UHFFFAOYSA-N 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- URMNHHAUVFEMIG-UHFFFAOYSA-N ethyl 6-methyl-2-oxo-4-phenyl-3,4-dihydro-1h-pyrimidine-5-carboxylate Chemical compound CCOC(=O)C1=C(C)NC(=O)NC1C1=CC=CC=C1 URMNHHAUVFEMIG-UHFFFAOYSA-N 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011005 laboratory method Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- QWENMOXLTHDKDL-UHFFFAOYSA-N pentoxymethanedithioic acid Chemical compound CCCCCOC(S)=S QWENMOXLTHDKDL-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 239000004296 sodium metabisulphite Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229940035024 thioglycerol Drugs 0.000 description 1
- ZEMGGZBWXRYJHK-UHFFFAOYSA-N thiouracil Chemical compound O=C1C=CNC(=S)N1 ZEMGGZBWXRYJHK-UHFFFAOYSA-N 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 229910001662 tin mineral Inorganic materials 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000012989 trithiocarbonate Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/06—Depressants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/625,263 US5756622A (en) | 1996-03-28 | 1996-03-28 | Polymeric sulfide mineral depressants |
| PCT/US1997/005825 WO1997035897A1 (en) | 1996-03-28 | 1997-03-26 | Novel polymeric sulfide mineral depressants |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BG102747A BG102747A (en) | 1999-05-31 |
| BG63311B1 true BG63311B1 (bg) | 2001-09-28 |
Family
ID=24505274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG102747A BG63311B1 (bg) | 1996-03-28 | 1998-09-02 | Нови съполимерни сулфидни минерални депресанти и метод за използването им |
Country Status (20)
| Country | Link |
|---|---|
| US (2) | US5756622A (ru) |
| EP (1) | EP0889917B1 (ru) |
| CN (1) | CN1103343C (ru) |
| AR (1) | AR006426A1 (ru) |
| AU (1) | AU705721B2 (ru) |
| BG (1) | BG63311B1 (ru) |
| BR (1) | BR9708350A (ru) |
| CA (1) | CA2250055C (ru) |
| ES (1) | ES2152667T3 (ru) |
| GR (1) | GR3034826T3 (ru) |
| ID (1) | ID19553A (ru) |
| IN (1) | IN191595B (ru) |
| MY (1) | MY118127A (ru) |
| OA (1) | OA10887A (ru) |
| PE (1) | PE6498A1 (ru) |
| PL (1) | PL186880B1 (ru) |
| PT (1) | PT889917E (ru) |
| RU (1) | RU2175331C2 (ru) |
| WO (1) | WO1997035897A1 (ru) |
| ZA (1) | ZA972720B (ru) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6799682B1 (en) * | 2000-05-16 | 2004-10-05 | Roe-Hoan Yoon | Method of increasing flotation rate |
| JP4022595B2 (ja) * | 2004-10-26 | 2007-12-19 | コニカミノルタオプト株式会社 | 撮影装置 |
| AU2006210497A1 (en) * | 2005-02-04 | 2006-08-10 | Mineral And Coal Technologies, Inc. | Improving the separation of diamond from gangue minerals |
| CN101244404A (zh) * | 2008-03-21 | 2008-08-20 | 北京矿冶研究总院 | 钼铋矿物的分离方法 |
| AP2013007317A0 (en) | 2008-07-25 | 2013-12-31 | Cytec Tech Corp | Flotation reagents and flotation processes utilizing same |
| CN101337206B (zh) * | 2008-08-13 | 2011-02-02 | 中南大学 | 硫化矿浮选捕收剂及二酰基双硫脲应用方法和制备方法 |
| CA2782436C (en) * | 2009-12-04 | 2018-05-22 | Barrick Gold Corporation | Separation of copper minerals from pyrite using air-metabisulfite treatment |
| GB201115823D0 (en) | 2011-09-13 | 2011-10-26 | Novel Polymer Solutions Ltd | Mineral processing |
| CN103788294B (zh) * | 2012-10-30 | 2016-03-30 | 中国石油化工股份有限公司 | 一种丙烯酰胺共聚物及其制备方法和应用 |
| CA2972260A1 (en) * | 2014-12-23 | 2016-06-30 | Kemira Oyj | Selective flocculants for mineral ore beneficiation |
| WO2016109254A1 (en) * | 2014-12-30 | 2016-07-07 | Lucas Moore | Depressants for mineral ore flotation |
| CN106478877B (zh) * | 2015-08-31 | 2018-08-17 | 中国石油化工股份有限公司 | 一种共聚物及其制备方法与应用 |
| CN105834008A (zh) * | 2016-06-08 | 2016-08-10 | 江西元再生资源有限公司 | 一种铜尾矿中含砷硫化矿物抑制剂的制备方法 |
| US10369577B2 (en) * | 2016-10-07 | 2019-08-06 | Cytec Industries Inc. | Compositions and methods for selective separation of minerals from sulfide ores |
| US10654048B2 (en) | 2017-03-09 | 2020-05-19 | Chevron Phillips Chemical Company Lp | Recovery of molybdenum using sodium metabisulfite and a thiocarbonate depressant |
| CN110653072A (zh) * | 2019-09-28 | 2020-01-07 | 北京矿冶科技集团有限公司 | 一种钼多金属硫化矿浮选分离抑制剂及其浮选分离方法 |
| CN110681495B (zh) * | 2019-09-28 | 2021-08-06 | 北京矿冶科技集团有限公司 | 一种硫脲类化合物浮选分离抑制剂及其浮选分离方法 |
| CN111649237B (zh) * | 2020-01-16 | 2021-11-26 | 中石化中原石油工程设计有限公司 | 一种枯竭气藏储气库用地面集输系统 |
| CN115921119A (zh) * | 2022-11-29 | 2023-04-07 | 昆明理工大学 | 一种铜钼矿浮选分离抑制剂及应用 |
| CN117861861B (zh) * | 2024-03-12 | 2024-05-31 | 中国矿业大学(北京) | 一种锌矿物抑制剂及铅锌混浮精矿的浮选分离方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4902764A (en) * | 1985-08-28 | 1990-02-20 | American Cyanamid Company | Polymeric sulfide mineral depressants |
| US4744893A (en) * | 1985-08-28 | 1988-05-17 | American Cyanamid Company | Polymeric sulfide mineral depressants |
| US4866150A (en) * | 1988-04-18 | 1989-09-12 | American Cyanamid Company | Polymeric sulfide mineral depressants |
| US4888106A (en) * | 1988-04-18 | 1989-12-19 | American Cyanamid Company | Method of using polymeric sulfide mineral depressants |
-
1996
- 1996-03-28 US US08/625,263 patent/US5756622A/en not_active Expired - Lifetime
-
1997
- 1997-02-12 PE PE1997000088A patent/PE6498A1/es not_active IP Right Cessation
- 1997-02-24 MY MYPI97000697A patent/MY118127A/en unknown
- 1997-03-20 IN IN504CA1997 patent/IN191595B/en unknown
- 1997-03-26 CA CA002250055A patent/CA2250055C/en not_active Expired - Fee Related
- 1997-03-26 AR ARP970101242A patent/AR006426A1/es unknown
- 1997-03-26 PL PL97328965A patent/PL186880B1/pl not_active IP Right Cessation
- 1997-03-26 AU AU27249/97A patent/AU705721B2/en not_active Ceased
- 1997-03-26 ES ES97921123T patent/ES2152667T3/es not_active Expired - Lifetime
- 1997-03-26 PT PT97921123T patent/PT889917E/pt unknown
- 1997-03-26 WO PCT/US1997/005825 patent/WO1997035897A1/en active IP Right Grant
- 1997-03-26 EP EP97921123A patent/EP0889917B1/en not_active Expired - Lifetime
- 1997-03-26 BR BR9708350A patent/BR9708350A/pt not_active IP Right Cessation
- 1997-03-26 RU RU98119541/04A patent/RU2175331C2/ru not_active IP Right Cessation
- 1997-03-26 CN CN97193365A patent/CN1103343C/zh not_active Expired - Fee Related
- 1997-03-27 ZA ZA9702720A patent/ZA972720B/xx unknown
- 1997-03-27 ID IDP971043A patent/ID19553A/id unknown
- 1997-12-11 US US08/989,062 patent/US5959054A/en not_active Expired - Lifetime
-
1998
- 1998-09-02 BG BG102747A patent/BG63311B1/bg unknown
- 1998-09-28 OA OA9800181A patent/OA10887A/en unknown
-
2000
- 2000-11-10 GR GR20000402513T patent/GR3034826T3/el not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| OA10887A (en) | 2003-02-18 |
| EP0889917A1 (en) | 1999-01-13 |
| AU705721B2 (en) | 1999-05-27 |
| PT889917E (pt) | 2001-04-30 |
| GR3034826T3 (en) | 2001-02-28 |
| CA2250055A1 (en) | 1997-10-02 |
| AU2724997A (en) | 1997-10-17 |
| US5756622A (en) | 1998-05-26 |
| IN191595B (ru) | 2003-12-06 |
| US5959054A (en) | 1999-09-28 |
| AR006426A1 (es) | 1999-08-25 |
| ES2152667T3 (es) | 2001-02-01 |
| CN1103343C (zh) | 2003-03-19 |
| PL328965A1 (en) | 1999-03-01 |
| ZA972720B (en) | 1997-10-23 |
| BG102747A (en) | 1999-05-31 |
| WO1997035897A1 (en) | 1997-10-02 |
| CA2250055C (en) | 2006-01-31 |
| BR9708350A (pt) | 1999-08-03 |
| PE6498A1 (es) | 1998-03-04 |
| RU2175331C2 (ru) | 2001-10-27 |
| PL186880B1 (pl) | 2004-03-31 |
| EP0889917B1 (en) | 2000-11-02 |
| ID19553A (id) | 1998-07-23 |
| CN1214704A (zh) | 1999-04-21 |
| MY118127A (en) | 2004-09-30 |
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