AU2015226940B2 - High power electrode materials - Google Patents
High power electrode materials Download PDFInfo
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- AU2015226940B2 AU2015226940B2 AU2015226940A AU2015226940A AU2015226940B2 AU 2015226940 B2 AU2015226940 B2 AU 2015226940B2 AU 2015226940 A AU2015226940 A AU 2015226940A AU 2015226940 A AU2015226940 A AU 2015226940A AU 2015226940 B2 AU2015226940 B2 AU 2015226940B2
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- lithium
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- 239000007772 electrode material Substances 0.000 title abstract description 10
- 230000014759 maintenance of location Effects 0.000 claims abstract description 8
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- PTZOLXYHGCJRHA-UHFFFAOYSA-L azanium;iron(2+);phosphate Chemical compound [NH4+].[Fe+2].[O-]P([O-])([O-])=O PTZOLXYHGCJRHA-UHFFFAOYSA-L 0.000 claims description 16
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- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 41
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- 239000002994 raw material Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
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- 239000002153 silicon-carbon composite material Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010421 standard material Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
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- 238000007669 thermal treatment Methods 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
- C01B25/451—Phosphates containing plural metal, or metal and ammonium containing metal and ammonium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/009—Compounds containing iron, with or without oxygen or hydrogen, and containing two or more other elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
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| AU2019204949A AU2019204949B2 (en) | 2014-03-07 | 2019-07-10 | High power electrode materials |
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| CN108201895B (zh) * | 2017-10-18 | 2020-08-28 | 扬州明晟新能源科技有限公司 | 一种具有可见光响应的新型SPH–Ag光催化剂及其制备方法 |
| CN107910552B (zh) * | 2017-11-14 | 2020-06-09 | 山东黄蓝伟业新能源科技有限公司 | 一种羟基磷酸铁铵的制备方法 |
| KR102727941B1 (ko) * | 2019-06-17 | 2024-11-08 | 주식회사 엘지에너지솔루션 | 양극재 불순물 및 수용성 코팅물질 분석 방법 |
| CN113666350B (zh) * | 2021-08-19 | 2022-10-25 | 湖北虹润高科新材料有限公司 | 一种可灵活调节晶体结构的二水磷酸铁及其制备方法 |
| JP2023136225A (ja) * | 2022-03-16 | 2023-09-29 | 国立大学法人山口大学 | リン酸アンモニウム鉄の製造方法、及びリン酸鉄リチウムの製造方法 |
| DE102024123358A1 (de) | 2023-08-17 | 2025-02-20 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Fahrzeug, Batterie für das Fahrzeug und Batteriezelle für die Batterie, Verfahren zur Herstellung der Batteriezelle |
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| US6379843B1 (en) * | 1996-06-14 | 2002-04-30 | Hitachi Maxwell, Ltd. | Nonaqueous secondary battery with lithium titanium cathode |
| US6235427B1 (en) | 1998-05-13 | 2001-05-22 | Fuji Photo Film Co., Ltd. | Nonaqueous secondary battery containing silicic material |
| JP4151210B2 (ja) * | 2000-08-30 | 2008-09-17 | ソニー株式会社 | 正極活物質及びその製造方法、並びに非水電解質電池及びその製造方法 |
| KR100490549B1 (ko) * | 2003-02-07 | 2005-05-17 | 삼성에스디아이 주식회사 | 카본 화합물이 흡착된 정극 활물질 및 이를 채용한 리튬전지 |
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| CN101244813B (zh) * | 2007-02-15 | 2010-09-29 | 比亚迪股份有限公司 | 碱式磷酸铁铵及制备方法、磷酸铁的制备方法及磷酸亚铁锂的制备方法 |
| DE102007049757A1 (de) * | 2007-10-16 | 2009-04-23 | Chemische Fabrik Budenheim Kg | Eisen(III)orthophosphat für Li-Ionen-Akkumulatoren |
| TWI466370B (zh) | 2008-01-17 | 2014-12-21 | A123 Systems Inc | 鋰離子電池的混合式金屬橄欖石電極材料 |
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| US9178215B2 (en) * | 2009-08-25 | 2015-11-03 | A123 Systems Llc | Mixed metal olivine electrode materials for lithium ion batteries having improved specific capacity and energy density |
| WO2013138541A1 (en) * | 2012-03-15 | 2013-09-19 | Imra America, Inc. | Iron phosphates: negative electrode materials for aqueous rechargeable sodium ion energy storage devices |
| CN103268938A (zh) * | 2013-01-22 | 2013-08-28 | 合肥国轩高科动力能源股份公司 | 一种锂离子正极材料磷酸铁锰锂固溶体的制备方法 |
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Non-Patent Citations (5)
| Title |
|---|
| CAVELLEC M ET AL: "Synthetic spheniscidite", ACTA CRYSTALLOGRAPHICA SECTION C. CRYSTAL STRUCTURE COMMUNICATIONS, MUNKSGAARD, COPENHAGEN, DK, vol. C50, no. 9, 15 September 1994 (1994-09-15), DK, pages 1379 - 1381, XP002771787, ISSN: 0108-2701, DOI: 10.1107/S0108270194003896 * |
| Choudhury et al(A synthetic iron phosphate mineral, spheniscidite, [NH4]+[Fe2(OH)(H2O)(PO4)2]-H2O, exhibiting reversible dehydration, Proc, Indian Acad. Sci., vol. 111, No. 5, (1999), pp. 627-637). * |
| GRENECHE, J.M. CAVELLEC, M. FEREY, G.: "Magnetic properties of synthetic spheniscidite", JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, ELSEVIER, AMSTERDAM, NL, vol. 167, no. 1-2, 1 March 1997 (1997-03-01), AMSTERDAM, NL, pages 57 - 64, XP004115641, ISSN: 0304-8853, DOI: 10.1016/S0304-8853(96)00627-0 * |
| REALE, PRISCILLA et al., "Synthesis and thermal behavior of crystalline hydrated iron (III) phosphates of interest as positive electrodes in Li batteries", Chemistry of Materials., (2003), vol. 15, no. 26, ISSN 0897-4756, pages 5051 - 5058 * |
| TROBAJO, CAMINO et al., "Hydrothermal synthesis of iron (III) phosphates in the presence of urea", Journal of the Chemical Society, Dalton Transactions, (2000), no. 5, ISSN 1470-479x, pages 787 - 790 * |
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| AU2019204949A1 (en) | 2019-07-25 |
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| JP7293167B2 (ja) | 2023-06-19 |
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| EP3412631B1 (en) | 2023-05-03 |
| CN106061892B (zh) | 2019-11-08 |
| AU2019204947B2 (en) | 2020-07-16 |
| KR102423392B1 (ko) | 2022-07-21 |
| AU2018204689B2 (en) | 2019-08-08 |
| AU2015226940A1 (en) | 2016-09-01 |
| JP2020161487A (ja) | 2020-10-01 |
| CN106061892A (zh) | 2016-10-26 |
| EP3114081A4 (en) | 2017-12-13 |
| JP6767266B2 (ja) | 2020-10-14 |
| EP3114081A1 (en) | 2017-01-11 |
| TW201603367A (zh) | 2016-01-16 |
| AU2018204689A1 (en) | 2018-07-19 |
| WO2015134948A1 (en) | 2015-09-11 |
| KR20160131021A (ko) | 2016-11-15 |
| EP3412631A1 (en) | 2018-12-12 |
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