AU2010320062B2 - Method for producing detergent granules - Google Patents
Method for producing detergent granules Download PDFInfo
- Publication number
- AU2010320062B2 AU2010320062B2 AU2010320062A AU2010320062A AU2010320062B2 AU 2010320062 B2 AU2010320062 B2 AU 2010320062B2 AU 2010320062 A AU2010320062 A AU 2010320062A AU 2010320062 A AU2010320062 A AU 2010320062A AU 2010320062 B2 AU2010320062 B2 AU 2010320062B2
- Authority
- AU
- Australia
- Prior art keywords
- acid precursor
- particle size
- weight
- amount
- average particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 115
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000008187 granular material Substances 0.000 title abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 216
- 239000002253 acid Substances 0.000 claims abstract description 70
- 239000002243 precursor Substances 0.000 claims abstract description 65
- 239000000843 powder Substances 0.000 claims abstract description 47
- 239000007788 liquid Substances 0.000 claims description 63
- 238000005507 spraying Methods 0.000 claims description 52
- 239000012530 fluid Substances 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 39
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 36
- 238000006386 neutralization reaction Methods 0.000 claims description 35
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical group CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 claims description 31
- 239000002994 raw material Substances 0.000 claims description 31
- 239000003945 anionic surfactant Substances 0.000 claims description 24
- 239000000344 soap Substances 0.000 claims description 23
- -1 alkali metal aluminosilicate Chemical class 0.000 claims description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims 1
- 238000009826 distribution Methods 0.000 abstract description 19
- 230000000694 effects Effects 0.000 abstract description 5
- 230000001747 exhibiting effect Effects 0.000 abstract description 3
- 230000003472 neutralizing effect Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 47
- 238000003756 stirring Methods 0.000 description 33
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 21
- 229910021536 Zeolite Inorganic materials 0.000 description 20
- 239000010457 zeolite Substances 0.000 description 20
- 238000002156 mixing Methods 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 13
- 239000007921 spray Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 238000004090 dissolution Methods 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 7
- 235000017550 sodium carbonate Nutrition 0.000 description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 description 7
- 235000011152 sodium sulphate Nutrition 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000004220 aggregation Methods 0.000 description 6
- 230000002776 aggregation Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000005469 granulation Methods 0.000 description 6
- 230000003179 granulation Effects 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 238000013019 agitation Methods 0.000 description 5
- 150000005215 alkyl ethers Chemical class 0.000 description 5
- 239000011362 coarse particle Substances 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 5
- 150000007522 mineralic acids Chemical class 0.000 description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 235000019832 sodium triphosphate Nutrition 0.000 description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 230000003113 alkalizing effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 1
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001955 cumulated effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004482 other powder Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009-263325 | 2009-11-18 | ||
| JP2009263325 | 2009-11-18 | ||
| PCT/JP2010/070593 WO2011062234A1 (ja) | 2009-11-18 | 2010-11-18 | 洗剤粒子群の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2010320062A1 AU2010320062A1 (en) | 2012-05-31 |
| AU2010320062B2 true AU2010320062B2 (en) | 2014-09-18 |
Family
ID=44059707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2010320062A Expired - Fee Related AU2010320062B2 (en) | 2009-11-18 | 2010-11-18 | Method for producing detergent granules |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP2011127104A (ja) |
| CN (1) | CN102712885B (ja) |
| AU (1) | AU2010320062B2 (ja) |
| BR (1) | BR112012011994A2 (ja) |
| WO (1) | WO2011062234A1 (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5971753B2 (ja) * | 2012-07-09 | 2016-08-17 | 花王株式会社 | 洗剤粒子の製造方法 |
| CN110819474A (zh) * | 2019-08-05 | 2020-02-21 | 广州索汰清洁技术有限公司 | 商用厨房油污厨具清洗剂、清洗装置以及清洗方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06502212A (ja) * | 1990-10-03 | 1994-03-10 | ザ、プロクター、エンド、ギャンブル、カンパニー | 粒状感ｐＨ界面活性剤を含有する高密度洗剤組成物の製法 |
| JP2005239786A (ja) * | 2004-02-24 | 2005-09-08 | Lion Corp | ノニオン界面活性剤含有粒子及びその製造方法並びに洗剤組成物 |
| JP2006509855A (ja) * | 2002-12-12 | 2006-03-23 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | 乾式中和法ｉｉ |
-
2010
- 2010-11-18 JP JP2010257792A patent/JP2011127104A/ja active Pending
- 2010-11-18 WO PCT/JP2010/070593 patent/WO2011062234A1/ja active Application Filing
- 2010-11-18 CN CN201080061448.4A patent/CN102712885B/zh active Active
- 2010-11-18 AU AU2010320062A patent/AU2010320062B2/en not_active Expired - Fee Related
- 2010-11-18 BR BR112012011994A patent/BR112012011994A2/pt not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06502212A (ja) * | 1990-10-03 | 1994-03-10 | ザ、プロクター、エンド、ギャンブル、カンパニー | 粒状感ｐＨ界面活性剤を含有する高密度洗剤組成物の製法 |
| JP2006509855A (ja) * | 2002-12-12 | 2006-03-23 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | 乾式中和法ｉｉ |
| JP2005239786A (ja) * | 2004-02-24 | 2005-09-08 | Lion Corp | ノニオン界面活性剤含有粒子及びその製造方法並びに洗剤組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2010320062A1 (en) | 2012-05-31 |
| WO2011062234A1 (ja) | 2011-05-26 |
| CN102712885A (zh) | 2012-10-03 |
| CN102712885B (zh) | 2014-10-15 |
| JP2011127104A (ja) | 2011-06-30 |
| BR112012011994A2 (pt) | 2016-05-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5525755B2 (ja) | 界面活性剤担持用顆粒群 | |
| EP2841553B1 (en) | Process for the production of a detergent granule, detergent granule and detergent composition comprising said granule | |
| JPH07503750A (ja) | スルホン酸の中和による洗剤粒状物の製法 | |
| JPH09502760A (ja) | 非イオン界面活性剤を含む粒状洗剤組成物およびこのような組成物の製法 | |
| JPH08170100A (ja) | 低ｐＨ粒状洗剤組成物 | |
| AU2010320062B2 (en) | Method for producing detergent granules | |
| EP2123744B1 (en) | Manufacture of dertergent granules by dry neutralisation | |
| AU2010320064B2 (en) | Method for producing detergent granules | |
| CN103221527B (zh) | 洗涤剂颗粒群的制造方法 | |
| JP5624811B2 (ja) | 高嵩密度洗剤粒子群の製造方法 | |
| WO2012067227A1 (ja) | 洗剤粒子群の製造方法 | |
| EP3030641B1 (en) | Process for the production of a detergent granule, detergent granule and detergent composition comprising said granule | |
| WO2012157681A1 (ja) | 洗剤粒子群の製造方法 | |
| JP2003521548A (ja) | 流動床乾燥器内のノズルの高さの調整による低密度洗浄剤組成物の製造法 | |
| AU2010320063B2 (en) | Method for producing surfactant-supporting granule cluster | |
| JP2012255146A (ja) | 洗剤粒子群の製造方法 | |
| JP4143853B2 (ja) | 水溶性無機物質含有粒子 | |
| KR101840074B1 (ko) | 입상 세제 조성물 및 그 제조 방법 | |
| JP6097003B2 (ja) | 粒状洗剤組成物 | |
| AU2006334038B2 (en) | Method for producing detergent particles | |
| JP4393862B2 (ja) | 洗剤粒子群の製法 | |
| JP2013147578A (ja) | 洗剤添加用粒子群の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK25 | Application lapsed reg. 22.2i(2) - failure to pay acceptance fee |