ATE62236T1 - Verfahren zur herstellung von 5hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel. - Google Patents
Verfahren zur herstellung von 5hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel.Info
- Publication number
- ATE62236T1 ATE62236T1 AT87100311T AT87100311T ATE62236T1 AT E62236 T1 ATE62236 T1 AT E62236T1 AT 87100311 T AT87100311 T AT 87100311T AT 87100311 T AT87100311 T AT 87100311T AT E62236 T1 ATE62236 T1 AT E62236T1
- Authority
- AT
- Austria
- Prior art keywords
- solvent
- water
- hydroxymethylfurfuraldehyde
- hmf
- manufacture
- Prior art date
Links
- NOEGNKMFWQHSLB-UHFFFAOYSA-N 5-hydroxymethylfurfural Chemical compound OCC1=CC=C(C=O)O1 NOEGNKMFWQHSLB-UHFFFAOYSA-N 0.000 title abstract 7
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000002904 solvent Substances 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 2
- RJGBSYZFOCAGQY-UHFFFAOYSA-N hydroxymethylfurfural Natural products COC1=CC=C(C=O)O1 RJGBSYZFOCAGQY-UHFFFAOYSA-N 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 150000001720 carbohydrates Chemical class 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 abstract 1
- 229930091371 Fructose Natural products 0.000 abstract 1
- 239000005715 Fructose Substances 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 235000014633 carbohydrates Nutrition 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Saccharide Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863601281 DE3601281A1 (de) | 1986-01-17 | 1986-01-17 | Verfahren zur herstellung von 5-hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel |
| EP87100311A EP0230250B1 (de) | 1986-01-17 | 1987-01-13 | Verfahren zur Herstellung von 5-Hydroxymethylfurfural einschliesslich eines kristallinen Produktes unter ausschliesslicher Verwendung von Wasser als Lösungsmittel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE62236T1 true ATE62236T1 (de) | 1991-04-15 |
Family
ID=6292062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT87100311T ATE62236T1 (de) | 1986-01-17 | 1987-01-13 | Verfahren zur herstellung von 5hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel. |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4740605A (en:Method) |
| EP (1) | EP0230250B1 (en:Method) |
| AT (1) | ATE62236T1 (en:Method) |
| DE (2) | DE3601281A1 (en:Method) |
Families Citing this family (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3936522A1 (de) * | 1989-11-02 | 1991-05-08 | Suedzucker Ag | 5-((alpha)-d-glucopyranosyloxymethyl)-furan-2-carboxaldehyd und dessen derivate und folgeprodukte sowie verfahren zur herstellung der verbindungen und deren verwendung |
| FR2741345B1 (fr) * | 1995-11-20 | 1998-08-07 | Agrichimie Sa | Procede et installation de condensation selective d'un derive aromatique avec un derive carbonyle dans un reacteur continu multicontact vertical |
| FR2741344B1 (fr) * | 1995-11-20 | 1998-01-23 | Agrichimie Sa | Procede et installation de fabrication selective d'hydroxymethylfurfural par hydroxymethylation du furfural |
| US6603026B2 (en) | 2001-08-07 | 2003-08-05 | Gene E. Lightner | Heterocyclic compounds produced from biomass |
| US6441202B1 (en) | 2001-08-20 | 2002-08-27 | Gene E. Lightner | Heterocyclic compounds extracted by a hydrocarbon |
| US6706900B2 (en) * | 2001-09-17 | 2004-03-16 | E. I. Du Pont De Nemours And Company | Process for preparing 2,5-diformylfuran from carbohydrates |
| US7317116B2 (en) | 2004-12-10 | 2008-01-08 | Archer-Daniels-Midland-Company | Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives |
| US7393963B2 (en) | 2004-12-10 | 2008-07-01 | Archer-Daniels-Midland Company | Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor |
| EP1834950A1 (en) | 2006-03-10 | 2007-09-19 | Avantium International B.V. | Method for the synthesis of 5-alkoxymethylfurfural ethers and their use |
| ATE473218T1 (de) | 2006-03-10 | 2010-07-15 | Furanix Technologies Bv | Verwendung organischer säureester von 5- hydroxymethylfurfural |
| JP2007261990A (ja) * | 2006-03-28 | 2007-10-11 | Canon Inc | フラン−２，５−ジカルボン酸の製造方法 |
| US7880049B2 (en) * | 2006-06-06 | 2011-02-01 | Wisconsin Alumni Research Foundation | Production of liquid alkanes in the jet fuel range (C8-C15) from biomass-derived carbohydrates |
| WO2007146636A1 (en) | 2006-06-06 | 2007-12-21 | Wisconsin Alumni Research Foundation | Catalytic process for producing furan derivatives from carbohydrates in a biphasic reactor |
| DE102007007629A1 (de) | 2007-02-16 | 2008-08-21 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 5-Hydroxymethyl-furfural über 5-Acyloxymethyl-furfural als Zwischenprodukt |
| SI2164975T1 (sl) | 2007-07-06 | 2012-06-29 | Basf Se | Postopek za proizvajanje koncentriranega vodnega glukoznega pripravka iz koruze |
| CN101456851B (zh) * | 2007-12-12 | 2012-10-24 | 中国科学院大连化学物理研究所 | 一种微波促进制备5-羟甲基糠醛的方法 |
| US20090156841A1 (en) * | 2007-12-12 | 2009-06-18 | Sanborn Alexandra J | Conversion of carbohydrates to hydroxymethylfurfural (hmf) and derivatives |
| DE102008009933A1 (de) | 2008-02-18 | 2009-08-20 | Friedrich-Schiller-Universität Jena | Verfahren zur Herstellung von 5-Hydroxymethylfurfural mit Hilfe von ionischen Flüssigkeiten |
| WO2009155297A1 (en) | 2008-06-17 | 2009-12-23 | Wisconsin Alumni Research Foundation | Chemical transformation of lignocellulosic biomass into fuels and chemicals |
| NZ596975A (en) | 2009-06-13 | 2014-04-30 | Rennovia Inc | Production of adipic acid and derivatives from carbohydrate-containing materials |
| CA2763177C (en) | 2009-06-13 | 2017-08-01 | Thomas R. Boussie | Production of glutaric acid and derivatives from carbohydrate-containing materials |
| US8669397B2 (en) | 2009-06-13 | 2014-03-11 | Rennovia, Inc. | Production of adipic acid and derivatives from carbohydrate-containing materials |
| US8314267B2 (en) * | 2009-06-26 | 2012-11-20 | Uop Llc | Carbohydrate route to para-xylene and terephthalic acid |
| BRPI1011588A2 (pt) * | 2009-07-01 | 2017-05-16 | Wisconsin Alumni Res Found | hidrólise de biomassa |
| US8669393B2 (en) * | 2010-03-05 | 2014-03-11 | Rennovia, Inc. | Adipic acid compositions |
| CN101812039B (zh) * | 2010-05-14 | 2012-09-26 | 天津大学 | 一种利用离子液体催化生成5－羟甲基糠醛的方法 |
| US9770705B2 (en) | 2010-06-11 | 2017-09-26 | Rennovia Inc. | Oxidation catalysts |
| TWI421243B (zh) * | 2010-07-15 | 2014-01-01 | Ind Tech Res Inst | 製備５-羥甲基糠醛之方法及裝置 |
| WO2012038969A1 (en) | 2010-09-03 | 2012-03-29 | Ganapati Dadasaheb Yadav | Process for converting fructose into 5-hydroxymethylfurfural using a mesoporous silica based catalyst impregnated with rare earth metals |
| FR2975396B1 (fr) * | 2011-05-16 | 2013-12-27 | Centre Nat Rech Scient | Procede de preparation de 5-hydroxymethylfurfural |
| DE102011053034A1 (de) | 2011-08-26 | 2013-02-28 | Ava-Co2 Schweiz Ag | Verfahren zur Extraktion von Furfuralen aus Biomasse |
| CN103974943A (zh) * | 2011-10-12 | 2014-08-06 | 诺维信公司 | 使用单相混合的水-有机溶剂系统从果糖生产5-羟甲基糠醛 |
| US9156802B2 (en) | 2011-12-13 | 2015-10-13 | Basf Se | Separating off 5-hydroxymethylfurfural (HMF) from reaction solutions by steam distillation |
| RU2014128457A (ru) * | 2011-12-13 | 2016-02-10 | Басф Се | Выделение 5-гидроксиметилфурфураля(гмф) из реакционных растворов при помощи перегонки с водяным паром |
| US9162998B2 (en) | 2011-12-13 | 2015-10-20 | Basf Se | Preparation of 5-hydroxymethylfurfural (HMF) from saccharide solutions in the presence of a solvent having a boiling point greater than 60° C. and less than 200° C. (at standard pressure, called low boiler for short) |
| US9169227B2 (en) | 2011-12-13 | 2015-10-27 | Basf Se | Production of 5 hydroxymethyulfurfural (HMF) from hexose solutions in the presence of steam |
| IN2014CN04393A (en:Method) | 2011-12-13 | 2015-09-04 | Basf Se | |
| CN104169263B (zh) | 2011-12-13 | 2016-06-15 | 巴斯夫欧洲公司 | 在蒸汽存在下由己糖溶液制备5-羟甲基糠醛(hmf) |
| US20140315262A1 (en) * | 2012-01-10 | 2014-10-23 | Archer Daniels Midland Company | Process for making hmf and hmf derivatives from sugars, with recovery of unreacted sugars suitable for direct fermentation to ethanol |
| WO2013109477A1 (en) | 2012-01-18 | 2013-07-25 | Rennovia, Inc. | Process for production of hexamethylenediamine from 5 - hydroxymethylfurfural |
| US9090579B2 (en) | 2012-03-12 | 2015-07-28 | Archer Daniels Midland Co. | Processes for making sugar and/or sugar alcohol dehydration products |
| EP2813494A1 (de) | 2013-06-12 | 2014-12-17 | Basf Se | Verfahren zur Herstellung von 5-Hydroxymethylfurfural (HMF) |
| DE102013223496A1 (de) | 2013-11-18 | 2015-05-21 | Tesa Se | Neuartiges Polyester geeignet zur Herstellung von Trägermaterialien für Klebebändern |
| AU2015209026A1 (en) | 2014-01-27 | 2016-07-28 | Archer-Daniels-Midland Company | Conversion of fructose-containing feedstocks to HMF-containing product |
| EP2985280A1 (en) | 2014-08-11 | 2016-02-17 | Reliance Industries Limited | A process for synthesis of furfural or derivatives thereof |
| KR101629699B1 (ko) | 2014-09-02 | 2016-06-14 | 한국화학연구원 | 5-히드록시메틸푸푸랄의 제조방법 |
| CN107001197B (zh) | 2014-12-02 | 2021-06-25 | 阿彻丹尼尔斯米德兰公司 | 由hmf生产bhmf、bhmthf、hdo和hto的方法 |
| ES2806988T3 (es) * | 2015-07-01 | 2021-02-19 | Furanix Technologies Bv | Proceso para la preparación de un derivado del furfural que consiste en neutralizar una mezcla de reacción ácida |
| ES2759451T3 (es) * | 2015-07-01 | 2020-05-11 | Furanix Technologies Bv | Proceso para la preparación de un derivado furfural |
| CN108136277B (zh) * | 2015-11-04 | 2021-11-09 | 罗门哈斯公司 | 纯化水溶液 |
| US10208006B2 (en) | 2016-01-13 | 2019-02-19 | Stora Enso Oyj | Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof |
| WO2017184545A1 (en) * | 2016-04-18 | 2017-10-26 | Rennovia, Inc. | Conversion of fructose-containing feedstocks to hmf-containing product |
| DE102016224073A1 (de) * | 2016-12-02 | 2018-06-07 | Südzucker AG | Verbessertes HMF-Herstellungsverfahren |
| EP3366712A1 (de) * | 2017-02-27 | 2018-08-29 | AVALON Industries AG | Neue hmf-oligomere |
| EP3652161A1 (en) | 2017-07-12 | 2020-05-20 | Stora Enso Oyj | Purified 2,5-furandicarboxylic acid pathway products |
| CN107805230A (zh) * | 2017-10-31 | 2018-03-16 | 安徽省利夫生物产业控股有限公司 | 一种由生物质制备5‑羟甲基糠醛的方法 |
| EP3498699A1 (en) | 2017-12-13 | 2019-06-19 | Basf Se | Chromatography method for the purification of furfural derivatives |
| DE102018208507A1 (de) | 2018-05-29 | 2019-12-05 | Südzucker AG | Anolytfraktion-katalysierte HMF-Herstellung |
| DE102018208510A1 (de) | 2018-05-29 | 2019-12-05 | Südzucker AG | Salz- und Säuregemisch-katalysierte HMF-Herstellung |
| KR102219915B1 (ko) | 2019-04-10 | 2021-02-23 | 부산대학교 산학협력단 | 가스-액체 계면 플라즈마 공정을 이용한 술폰화된 고체산 촉매의 제조방법 |
| KR102193018B1 (ko) | 2019-04-23 | 2020-12-18 | 부산대학교 산학협력단 | 셀룰로오스 가수분해를 위한 -Cl 및 -SO3H의 이중 기능성을 갖는 탄소계 고체산 촉매 및 이의 제조방법 |
| FR3097547B1 (fr) * | 2019-06-24 | 2023-04-28 | Ifp Energies Now | Procede de production de 5-hydroxymethylfurfural |
| CN116082278A (zh) * | 2021-11-05 | 2023-05-09 | 中国科学院宁波材料技术与工程研究所 | 一种提高制备5-羟甲基-2-呋喃甲醛选择性的方法 |
| CN114805254A (zh) * | 2022-04-11 | 2022-07-29 | 合肥利夫生物科技有限公司 | 一种5-羟甲基糠醛的制备方法 |
| WO2025043536A1 (zh) * | 2023-08-30 | 2025-03-06 | 乔璞科技股份有限公司 | 5-羟甲基糠醛的纯化方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2776948A (en) * | 1953-08-03 | 1957-01-08 | Dendrol Inc | Synthetic resins derived from hydroxymethylfurfural and phenols |
| US2929823A (en) * | 1956-11-26 | 1960-03-22 | Merck & Co Inc | Production of 5-hydroxymethylfurfural |
| FR2464260A1 (fr) * | 1979-09-05 | 1981-03-06 | Roquette Freres | Procede de fabrication du 5-hydroxymethylfurfural |
| DE3309564A1 (de) * | 1983-03-17 | 1984-09-20 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von 5-acetoxymethyl-furfural |
-
1986
- 1986-01-17 DE DE19863601281 patent/DE3601281A1/de active Granted
-
1987
- 1987-01-12 US US07/002,340 patent/US4740605A/en not_active Expired - Fee Related
- 1987-01-13 EP EP87100311A patent/EP0230250B1/de not_active Expired - Lifetime
- 1987-01-13 AT AT87100311T patent/ATE62236T1/de not_active IP Right Cessation
- 1987-01-13 DE DE8787100311T patent/DE3768965D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US4740605A (en) | 1988-04-26 |
| EP0230250B1 (de) | 1991-04-03 |
| DE3601281C2 (en:Method) | 1988-08-04 |
| DE3768965D1 (de) | 1991-05-08 |
| EP0230250A3 (en) | 1988-08-31 |
| EP0230250A2 (de) | 1987-07-29 |
| DE3601281A1 (de) | 1987-07-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| REN | Ceased due to non-payment of the annual fee |