ATE309259T1 - Überbrückte bisindenylmetallocenverbindungen - Google Patents

Überbrückte bisindenylmetallocenverbindungen

Info

Publication number
ATE309259T1
ATE309259T1 AT03027480T AT03027480T ATE309259T1 AT E309259 T1 ATE309259 T1 AT E309259T1 AT 03027480 T AT03027480 T AT 03027480T AT 03027480 T AT03027480 T AT 03027480T AT E309259 T1 ATE309259 T1 AT E309259T1
Authority
AT
Austria
Prior art keywords
alkenyl
aryl
alkyl
metallocene compound
arylalkenyl
Prior art date
Application number
AT03027480T
Other languages
German (de)
English (en)
Inventor
Matthew C Kuchta
Udo M Stehling
Robert T Li
William T Haygood
Terry J Burkhardt
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/620,198 external-priority patent/US6380330B1/en
Priority claimed from US09/620,341 external-priority patent/US6380123B1/en
Priority claimed from US09/620,303 external-priority patent/US6414095B1/en
Priority claimed from US09/619,750 external-priority patent/US6380120B1/en
Priority claimed from US09/619,757 external-priority patent/US6380334B1/en
Priority claimed from US09/619,764 external-priority patent/US6376409B1/en
Priority claimed from US09/620,613 external-priority patent/US6380331B1/en
Priority claimed from US09/619,751 external-priority patent/US6380121B1/en
Priority claimed from US09/620,046 external-priority patent/US6380122B1/en
Priority claimed from US09/620,359 external-priority patent/US6376413B1/en
Priority claimed from US09/619,749 external-priority patent/US6376407B1/en
Priority claimed from US09/620,302 external-priority patent/US6376411B1/en
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE309259T1 publication Critical patent/ATE309259T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
AT03027480T 2000-06-30 2001-05-21 Überbrückte bisindenylmetallocenverbindungen ATE309259T1 (de)

Applications Claiming Priority (14)

Application Number Priority Date Filing Date Title
US21545900P 2000-06-30 2000-06-30
US21559700P 2000-06-30 2000-06-30
US09/619,750 US6380120B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,757 US6380334B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,764 US6376409B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,198 US6380330B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,749 US6376407B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/619,751 US6380121B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,359 US6376413B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,341 US6380123B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,302 US6376411B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,046 US6380122B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,613 US6380331B1 (en) 2000-06-30 2000-07-19 Metallocene compositions
US09/620,303 US6414095B1 (en) 2000-06-30 2000-07-19 Metallocene compositions

Publications (1)

Publication Number Publication Date
ATE309259T1 true ATE309259T1 (de) 2005-11-15

Family

ID=27585093

Family Applications (2)

Application Number Title Priority Date Filing Date
AT03027480T ATE309259T1 (de) 2000-06-30 2001-05-21 Überbrückte bisindenylmetallocenverbindungen
AT01937633T ATE260289T1 (de) 2000-06-30 2001-05-21 Verbrückte bisindenyl substituierte metallocen- verbindungen

Family Applications After (1)

Application Number Title Priority Date Filing Date
AT01937633T ATE260289T1 (de) 2000-06-30 2001-05-21 Verbrückte bisindenyl substituierte metallocen- verbindungen

Country Status (6)

Country Link
EP (2) EP1294733B1 (enExample)
JP (1) JP2004502698A (enExample)
AT (2) ATE309259T1 (enExample)
DE (2) DE60102156T8 (enExample)
ES (2) ES2211808T3 (enExample)
WO (1) WO2002002575A1 (enExample)

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EP2532687A3 (en) 2011-06-10 2013-04-10 Borealis AG Bridged Metallocene Catalysts
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EP3022234B1 (en) 2013-07-17 2018-12-26 ExxonMobil Chemical Patents Inc. Substituted metallocene catalysts
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
EP3301119B1 (en) 2013-07-17 2021-03-17 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
US9944665B2 (en) 2013-12-19 2018-04-17 Exxonmobil Chemical Patents Inc. Bridged bis(indenyl) transitional metal complexes, production, and use thereof
CN105829326B (zh) * 2013-12-19 2019-11-08 埃克森美孚化学专利公司 桥连双(茚基)过渡金属络合物、其制备与应用
US9963522B2 (en) 2014-03-20 2018-05-08 Japan Polypropylene Corporation Metallocene complex and method for producing olefin polymer
JP6201853B2 (ja) * 2014-03-25 2017-09-27 日本ポリプロ株式会社 メタロセン錯体及びオレフィン重合体の製造方法
ES2635519T3 (es) 2014-11-21 2017-10-04 Borealis Ag Procedimiento para producir gránulos de copolímeros blandos
BR112017005285B1 (pt) 2014-12-08 2021-09-28 Borealis Ag Processo para extrudar e peletizar um copolímero de propileno
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
CN107690441A (zh) 2015-06-05 2018-02-13 埃克森美孚化学专利公司 聚合物在气相或淤浆相中的单反应器制备
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
WO2016196339A2 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
EP3124567A1 (en) 2015-07-30 2017-02-01 Borealis AG Polypropylene based hot-melt adhesive composition
EP3178853B1 (en) 2015-12-07 2018-07-25 Borealis AG Process for polymerising alpha-olefin monomers
JP6613987B2 (ja) * 2016-03-28 2019-12-04 日本ポリプロ株式会社 メタロセン錯体、オレフィン重合用触媒、およびオレフィン重合体の製造方法
EP3243622B1 (en) 2016-05-13 2020-09-09 Borealis AG Process for hydraulic conveying of polyolefin pellets
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
EP3608364A1 (en) 2018-08-06 2020-02-12 Borealis AG Multimodal propylene random copolymer based composition suitable as hot melt adhesive composition
US20210277290A1 (en) 2018-08-06 2021-09-09 Borealis Ag Propylene random copolymer based hot melt adhesive composition
US12146019B2 (en) 2018-11-30 2024-11-19 Borealis Ag Washing process
EP4017887A4 (en) 2019-08-22 2023-01-18 ExxonMobil Chemical Patents Inc. ISOTACTIC PROPYLENE HOMOPOLYMERS AND COPOLYMERS MADE WITH C1-SYMMETRIC METALLOCENE CATALYSTS
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
EP4247825A1 (en) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. Metallocene polypropylene prepared using aromatic solvent-free supports
EP4144435A1 (en) 2021-09-01 2023-03-08 Borealis AG Gas phase polymerization process with improved gas recycling
US20250002617A1 (en) 2021-09-02 2025-01-02 ExxonMobil Technology and Engineering Company C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers
KR20250049337A (ko) 2022-08-09 2025-04-11 엑손모빌 케미칼 패턴츠 인코포레이티드 디페닐실란 가교 c1 대칭 촉매의 제조 방법 및 이로부터 제조된 중합체
EP4389783A1 (en) 2022-12-20 2024-06-26 Borealis AG Catalyst transition process
EP4389776A1 (en) 2022-12-20 2024-06-26 Borealis AG Process
CN120380039A (zh) 2022-12-23 2025-07-25 北欧化工股份公司 聚丙烯共聚物的生产方法
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WO2024133045A1 (en) 2022-12-23 2024-06-27 Borealis Ag Process for producing a high-flow polypropylene homopolymer
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TW294669B (enExample) * 1992-06-27 1997-01-01 Hoechst Ag

Also Published As

Publication number Publication date
EP1294733B1 (en) 2004-02-25
DE60114896D1 (de) 2005-12-15
ATE260289T1 (de) 2004-03-15
DE60114896T2 (de) 2006-07-27
DE60102156T8 (de) 2005-06-23
EP1411058B1 (en) 2005-11-09
ES2211808T3 (es) 2004-07-16
DE60102156D1 (de) 2004-04-01
JP2004502698A (ja) 2004-01-29
WO2002002575A1 (en) 2002-01-10
ES2247473T3 (es) 2006-03-01
DE60114896T8 (de) 2007-04-26
EP1294733A1 (en) 2003-03-26
DE60102156T2 (de) 2004-12-09
EP1411058A1 (en) 2004-04-21

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