ATE293493T1 - Saure aktivierung von ruthenium-metathese- katalysatoren und lebende romp in wasser - Google Patents
Saure aktivierung von ruthenium-metathese- katalysatoren und lebende romp in wasserInfo
- Publication number
- ATE293493T1 ATE293493T1 AT98956491T AT98956491T ATE293493T1 AT E293493 T1 ATE293493 T1 AT E293493T1 AT 98956491 T AT98956491 T AT 98956491T AT 98956491 T AT98956491 T AT 98956491T AT E293493 T1 ATE293493 T1 AT E293493T1
- Authority
- AT
- Austria
- Prior art keywords
- water
- romp
- acid
- reactions
- ruthenium
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/96—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
- B01J2540/40—Non-coordinating groups comprising nitrogen
- B01J2540/42—Quaternary ammonium groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/929—Special chemical considerations
- Y10S585/94—Opening of hydrocarbon ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US6440597P | 1997-10-30 | 1997-10-30 | |
US09/183,025 US6284852B1 (en) | 1997-10-30 | 1998-10-29 | Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water |
PCT/US1998/023343 WO1999022865A1 (en) | 1997-10-30 | 1998-10-30 | Acid activation of ruthenium metathesis catalysts and living romp metathesis polymerization in water |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE293493T1 true ATE293493T1 (de) | 2005-05-15 |
Family
ID=26744483
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT98956491T ATE293493T1 (de) | 1997-10-30 | 1998-10-30 | Saure aktivierung von ruthenium-metathese- katalysatoren und lebende romp in wasser |
Country Status (7)
Country | Link |
---|---|
US (2) | US6284852B1 (de) |
EP (1) | EP1056538B1 (de) |
JP (2) | JP4554072B2 (de) |
AT (1) | ATE293493T1 (de) |
AU (1) | AU1300699A (de) |
DE (1) | DE69829882T2 (de) |
WO (1) | WO1999022865A1 (de) |
Families Citing this family (80)
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US6284852B1 (en) * | 1997-10-30 | 2001-09-04 | California Institute Of Technology | Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water |
JP2002509960A (ja) * | 1998-03-31 | 2002-04-02 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | ルテニウムおよびオスミウムカルベンカルボニル触媒 |
TW495517B (en) * | 1998-04-23 | 2002-07-21 | Hitachi Chemical Co Ltd | Curable molding material and method for producing molded article |
WO1999058592A1 (fr) * | 1998-05-14 | 1999-11-18 | Hitachi Chemical Company, Ltd. | Composition de resine et procede utilisant cette composition pour produire un article durci |
EP2000803A1 (de) | 1998-11-30 | 2008-12-10 | Nanosphere, Inc. | Nanoteilchen mit Polymerschalen |
US8133421B2 (en) * | 1999-02-23 | 2012-03-13 | Warsaw Orthopedic, Inc. | Methods of making shaped load-bearing osteoimplant |
US20030135080A1 (en) * | 1999-12-21 | 2003-07-17 | Botha Jan Mattheus | Metathesis process for converting short chain olefins to longer chain olefins |
JP4295096B2 (ja) * | 2001-08-29 | 2009-07-15 | カリフォルニア インスティチュート オブ テクノロジー | 2個以上のヘテロ原子を含有する架橋された二環式および多環式のオレフィンの開環メタセシス重合 |
EP1468004B1 (de) * | 2002-01-22 | 2006-12-20 | Universiteit Gent | Metallkomplexe für die metathese |
EP1603857A4 (de) * | 2003-01-13 | 2006-05-17 | Cargill Inc | Verfahren zur herstellung von industriechemikalien |
WO2005048283A2 (en) * | 2003-07-18 | 2005-05-26 | Northwestern University | Surface and site-specific polymerization by direct-write lithography |
US7250523B2 (en) * | 2003-10-22 | 2007-07-31 | Board Of Trustees Of Michigan State University | Imido-tethered carbenes of molybdenum for ring-opening metathesis polymerization and ring-closing metathesis |
US7132565B2 (en) * | 2004-02-13 | 2006-11-07 | National Taiwan University Of Science & Technology | Norbornene compounds with cross-linkable groups and their derivatives |
CA2554006A1 (en) * | 2004-02-26 | 2005-09-09 | Universiteit Gent | Metal complexes for use in olefin metathesis and atom group transfer reactions |
US20070185343A1 (en) * | 2004-02-26 | 2007-08-09 | Universiteit Gent | Metal complexes for use in olefin metathesis and atom group transfer reactions |
US8461223B2 (en) * | 2005-04-07 | 2013-06-11 | Aspen Aerogels, Inc. | Microporous polycyclopentadiene-based aerogels |
ATE496057T1 (de) * | 2005-08-22 | 2011-02-15 | Telene Sas | Vielfachkoordinierte metal-komplexe zur verwendung in metathese-reaktionen |
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ES2288370B1 (es) * | 2005-09-21 | 2009-04-01 | Universidad De Almeria | Nuevos catalizadores para la metatesis de olefinas en medio acuoso. |
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US8067610B2 (en) * | 2006-07-13 | 2011-11-29 | Yann Schrodi | Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis |
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TWI777027B (zh) * | 2018-01-26 | 2022-09-11 | 日商住友電木股份有限公司 | 聚環烯烴單體及由能夠產生光酸作為光學材料的化合物活化之催化劑 |
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TW202313841A (zh) | 2021-06-30 | 2023-04-01 | 美商普羅梅勒斯有限公司 | 作為乙烯基加成觸媒之穩定型uv活性有機鈀化合物 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5312940A (en) * | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
EP1251135A3 (de) * | 1992-04-03 | 2004-01-02 | California Institute Of Technology | Hochwirksame Ruthenium- und Osmium- Metall-Carbenkomplexe für die Olefinmetathesereaktionen, und deren Herstellung |
US5710298A (en) | 1992-04-03 | 1998-01-20 | California Institute Of Technology | Method of preparing ruthenium and osmium carbene complexes |
EP0792307A1 (de) * | 1994-11-17 | 1997-09-03 | Ciba SC Holding AG | Polymerisierbare zusammensetzung und verfahren zur polymerisation von cyclischen olefinen |
US6235856B1 (en) * | 1994-12-23 | 2001-05-22 | Ciba Specialty Chemicals Corporation | Polymerization of dicyclopentadiene |
US5831108A (en) | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
JPH09183832A (ja) * | 1995-12-28 | 1997-07-15 | Nippon Zeon Co Ltd | 成形材料 |
US6020443A (en) * | 1996-02-08 | 2000-02-01 | Advanced Polymer Technologies, Inc. | Polymerization of low grade DCPD monomers using an olefin metathesis catalyst |
US6284852B1 (en) * | 1997-10-30 | 2001-09-04 | California Institute Of Technology | Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water |
-
1998
- 1998-10-29 US US09/183,025 patent/US6284852B1/en not_active Expired - Lifetime
- 1998-10-30 JP JP2000518785A patent/JP4554072B2/ja not_active Expired - Fee Related
- 1998-10-30 DE DE69829882T patent/DE69829882T2/de not_active Expired - Lifetime
- 1998-10-30 AT AT98956491T patent/ATE293493T1/de not_active IP Right Cessation
- 1998-10-30 EP EP98956491A patent/EP1056538B1/de not_active Expired - Lifetime
- 1998-10-30 AU AU13006/99A patent/AU1300699A/en not_active Abandoned
- 1998-10-30 WO PCT/US1998/023343 patent/WO1999022865A1/en active IP Right Grant
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2001
- 2001-06-14 US US09/882,776 patent/US6486279B2/en not_active Expired - Lifetime
-
2010
- 2010-03-17 JP JP2010061372A patent/JP2010138413A/ja active Pending
Also Published As
Publication number | Publication date |
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US6486279B2 (en) | 2002-11-26 |
JP2010138413A (ja) | 2010-06-24 |
DE69829882T2 (de) | 2006-03-09 |
AU1300699A (en) | 1999-05-24 |
EP1056538A4 (de) | 2002-12-04 |
WO1999022865A1 (en) | 1999-05-14 |
US6284852B1 (en) | 2001-09-04 |
EP1056538A1 (de) | 2000-12-06 |
JP4554072B2 (ja) | 2010-09-29 |
JP2002516911A (ja) | 2002-06-11 |
EP1056538B1 (de) | 2005-04-20 |
US20020055598A1 (en) | 2002-05-09 |
DE69829882D1 (de) | 2005-05-25 |
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