ATE243165T1 - Mesoporöses zeolithisches material mit mikroporösen kristallinen mesoporenwänden - Google Patents
Mesoporöses zeolithisches material mit mikroporösen kristallinen mesoporenwändenInfo
- Publication number
- ATE243165T1 ATE243165T1 AT00979294T AT00979294T ATE243165T1 AT E243165 T1 ATE243165 T1 AT E243165T1 AT 00979294 T AT00979294 T AT 00979294T AT 00979294 T AT00979294 T AT 00979294T AT E243165 T1 ATE243165 T1 AT E243165T1
- Authority
- AT
- Austria
- Prior art keywords
- walls
- zeolite material
- mesoporous
- mesoporo
- mesoporous zeolite
- Prior art date
Links
- 239000010457 zeolite Substances 0.000 title abstract 3
- 239000002253 acid Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/005—Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/62—Synthesis on support in or on other molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/27—Beta, e.g. NU-2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/773—Nanoparticle, i.e. structure having three dimensions of 100 nm or less
- Y10S977/775—Nanosized powder or flake, e.g. nanosized catalyst
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/773—Nanoparticle, i.e. structure having three dimensions of 100 nm or less
- Y10S977/775—Nanosized powder or flake, e.g. nanosized catalyst
- Y10S977/776—Ceramic powder or flake
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16699699P | 1999-11-23 | 1999-11-23 | |
| PCT/CA2000/001375 WO2001038223A1 (en) | 1999-11-23 | 2000-11-23 | Mesoporous zeolitic material with microporous crystalline mesopore walls |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE243165T1 true ATE243165T1 (de) | 2003-07-15 |
Family
ID=22605517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT00979294T ATE243165T1 (de) | 1999-11-23 | 2000-11-23 | Mesoporöses zeolithisches material mit mikroporösen kristallinen mesoporenwänden |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6669924B1 (de) |
| EP (1) | EP1237818B1 (de) |
| AT (1) | ATE243165T1 (de) |
| AU (1) | AU1684101A (de) |
| CA (1) | CA2392296C (de) |
| DE (1) | DE60003461T2 (de) |
| WO (1) | WO2001038223A1 (de) |
Families Citing this family (69)
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|---|---|---|---|---|
| US6346140B2 (en) * | 2000-03-31 | 2002-02-12 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Porous solid for gas adsorption separation and gas adsorption separation process employing it |
| US6749628B1 (en) | 2001-05-17 | 2004-06-15 | Advanced Cardiovascular Systems, Inc. | Stent and catheter assembly and method for treating bifurcations |
| JPWO2003002458A1 (ja) * | 2001-06-29 | 2004-10-14 | 独立行政法人 科学技術振興機構 | 無機系多孔質体の製造方法 |
| US6897175B2 (en) * | 2001-10-09 | 2005-05-24 | General Electric | Catalyst and method for the alkylation of hydroxyaromatic compounds |
| CN100335567C (zh) * | 2002-03-20 | 2007-09-05 | 新加坡纳米材料科技有限公司 | CaCO3/SiO2·nH2O纳米复合颗粒和空心SiO2·nH2O纳米材料及其制备方法 |
| ES2206064B1 (es) * | 2002-10-31 | 2005-08-01 | Consejo Sup. De Investig. Cientificas. | Estructuras mesoporosas con elevada actividad catalitica en reacciones de catalisis acida y su procedimiento de preparacion. |
| US8273371B2 (en) * | 2003-06-27 | 2012-09-25 | Johan Adriaan Martens | Crystalline mesoporous oxide based materials useful for the fixation and controlled release of drugs |
| GB0315012D0 (en) * | 2003-06-27 | 2003-07-30 | Leuven K U Res & Dev | Zeotiles |
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| JP2005053728A (ja) * | 2003-08-01 | 2005-03-03 | Dsl Japan Co Ltd | 高吸油性および高い構造性を有する非晶質シリカ粒子 |
| CN100427393C (zh) * | 2003-08-07 | 2008-10-22 | 复旦大学 | 含y沸石次级结构单元的介孔分子筛及其制备方法 |
| ES2228271B1 (es) * | 2003-09-18 | 2006-06-01 | Universidad Rey Juan Carlos | Metodo para la preparacion de nanozeolita zsm-5 de elevada superficie externa por cristalizacion de nucleos sililados. |
| US8439047B2 (en) | 2003-12-22 | 2013-05-14 | Philip Morris Usa Inc. | Composite mesoporous/microporous materials and their use in smoking articles for removing certain gas phase constituents from tobacco smoke |
| US7087705B2 (en) | 2004-03-31 | 2006-08-08 | General Electric Company | Process for the monoalkylation of dihydroxy aromatic compounds |
| US20050234136A1 (en) * | 2004-04-19 | 2005-10-20 | Holland Brian T | Colloidal compositions and methods of preparing same |
| US7589041B2 (en) | 2004-04-23 | 2009-09-15 | Massachusetts Institute Of Technology | Mesostructured zeolitic materials, and methods of making and using the same |
| GB0420016D0 (en) | 2004-09-09 | 2004-10-13 | Leuven K U Res & Dev | Controlled release oral delivery system |
| CN1325375C (zh) * | 2004-10-29 | 2007-07-11 | 中国石油化工股份有限公司 | 具有多级孔道的β沸石颗粒及其制备方法 |
| US20060182681A1 (en) * | 2004-12-28 | 2006-08-17 | Fortum Oyj | Catalytic materials and method for the preparation thereof |
| FR2886636B1 (fr) * | 2005-06-02 | 2007-08-03 | Inst Francais Du Petrole | Materiau inorganique presentant des nanoparticules metalliques piegees dans une matrice mesostructuree |
| FR2886637B1 (fr) * | 2005-06-02 | 2007-08-03 | Inst Francais Du Petrole | Materiau mesostructure a forte teneur en aluminium |
| US20070104643A1 (en) * | 2005-08-05 | 2007-05-10 | Holland Brian T | Mesoporous nanocrystaline zeolite composition and preparation from amorphous colloidal metalosilicates |
| CN100439246C (zh) * | 2005-08-26 | 2008-12-03 | 吉林大学 | 硬模板或复合模板合成复合孔沸石分子筛的方法 |
| CN100453460C (zh) * | 2005-08-26 | 2009-01-21 | 吉林大学 | 高分子聚合物模板合成的复合孔沸石分子筛的制备方法 |
| KR100727288B1 (ko) | 2005-10-14 | 2007-06-13 | 한국과학기술원 | 메조다공성 골격을 갖는 미세다공성 결정성 분자체의제조방법 |
| US7288237B2 (en) * | 2005-11-17 | 2007-10-30 | Lyondell Chemical Technology, L.P. | Epoxidation catalyst |
| FR2909012B1 (fr) * | 2006-11-23 | 2009-05-08 | Inst Francais Du Petrole | Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede d'hydrocraquage/ hydroconversion et d'hydrotraitement de charges hydrocarbonees. |
| ES2319007B1 (es) | 2006-12-07 | 2010-02-16 | Rive Technology, Inc. | Metodos para fabricar materiales zeoliticos mesoestructurados. |
| US20080214882A1 (en) * | 2007-02-16 | 2008-09-04 | Board Of Trustees Of Michigan State University | Acidic mesostructured aluminosilicates assembled from surfactant-mediated zeolite hydrolysis products |
| DE102007042286A1 (de) | 2007-09-06 | 2009-03-12 | Henkel Ag & Co. Kgaa | Färbemittel mit Naturfarbstoffen und 1,3-Dihydroxyaceton |
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| US8258137B2 (en) * | 2008-01-29 | 2012-09-04 | Katholieke Universiteit Leuven | Process for release of biologically active species from mesoporous oxide systems |
| FR2929266B1 (fr) | 2008-03-31 | 2010-03-19 | Inst Francais Du Petrole | Materiau mesostructure a forte teneur en aluminium et constitue de particules spheriques de taille specifique |
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| RU2393992C1 (ru) * | 2009-03-17 | 2010-07-10 | Общество с ограниченной ответственностью "УНИСИТ" | Микромезопористый кристаллический материал и способ его получения |
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| KR101147669B1 (ko) * | 2010-07-05 | 2012-05-21 | 한국과학기술원 | 규칙적 또는 불규칙적으로 배열된 메조기공을 포함하는 제올라이트 또는 유사 제올라이트 물질 및 그의 제조 방법 |
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| CN106687410A (zh) * | 2014-07-11 | 2017-05-17 | 道达尔研究技术弗吕公司 | 涉及可回收和可再循环的中孔模板剂的制备中孔性微孔性结晶材料的方法 |
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| US10626019B2 (en) | 2014-12-30 | 2020-04-21 | W. R. Grace & Co.-Conn. | Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content |
| CN107954438B (zh) * | 2016-10-14 | 2020-09-04 | 中国石油化工股份有限公司 | 直通介孔fau分子筛及其制备方法 |
| KR101922614B1 (ko) * | 2017-05-24 | 2018-11-27 | 재단법인 탄소순환형 차세대 바이오매스 생산전환 기술연구단 | 위계다공성 베타 제올라이트 기반 수첨분해반응 촉매 및 이의 제조방법 및 상기 수첨분해반응 촉매를 활용한 트리글리세라이드를 포함하는 바이오매스로부터 바이오항공유 생산방법 |
| US10350585B1 (en) | 2018-08-14 | 2019-07-16 | Saudi Arabian Oil Company | Methods for synthesizing hierarchical zeolites for catalytic cracking |
| CN110982154A (zh) * | 2019-12-23 | 2020-04-10 | 安徽国登管业科技有限公司 | 一种抗菌pe给水管的制备方法 |
| CN111530493B (zh) * | 2020-05-27 | 2021-11-02 | 清华大学 | 一种将烷烃转化为芳烃的催化剂、制备方法及使用方法 |
| CN113307284A (zh) * | 2021-07-09 | 2021-08-27 | 山东亮剑环保新材料有限公司 | 一种纳米尺度复合分子筛的制备方法 |
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| CN1101339C (zh) * | 1998-07-01 | 2003-02-12 | 复旦大学 | 复合中微孔分子筛及其合成方法 |
| FR2802120B1 (fr) * | 1999-12-14 | 2002-02-01 | Inst Francais Du Petrole | Solide silicoaluminate micro et mesoporeux, procede de preparation, utilisation comme catalyseur et en conversion d'hydrocarbures |
-
2000
- 2000-11-23 AU AU16841/01A patent/AU1684101A/en not_active Abandoned
- 2000-11-23 WO PCT/CA2000/001375 patent/WO2001038223A1/en not_active Ceased
- 2000-11-23 DE DE60003461T patent/DE60003461T2/de not_active Expired - Fee Related
- 2000-11-23 CA CA002392296A patent/CA2392296C/en not_active Expired - Fee Related
- 2000-11-23 EP EP00979294A patent/EP1237818B1/de not_active Expired - Lifetime
- 2000-11-23 AT AT00979294T patent/ATE243165T1/de not_active IP Right Cessation
- 2000-11-24 US US09/728,494 patent/US6669924B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6669924B1 (en) | 2003-12-30 |
| AU1684101A (en) | 2001-06-04 |
| WO2001038223A1 (en) | 2001-05-31 |
| DE60003461T2 (de) | 2004-05-06 |
| CA2392296C (en) | 2008-03-11 |
| DE60003461D1 (de) | 2003-07-24 |
| EP1237818B1 (de) | 2003-06-18 |
| EP1237818A1 (de) | 2002-09-11 |
| CA2392296A1 (en) | 2001-05-31 |
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