ATE10182T1 - Katalytische wasserdampf-reformierung von kohlenwasserstoffen. - Google Patents

Katalytische wasserdampf-reformierung von kohlenwasserstoffen.

Info

Publication number
ATE10182T1
ATE10182T1 AT81100417T AT81100417T ATE10182T1 AT E10182 T1 ATE10182 T1 AT E10182T1 AT 81100417 T AT81100417 T AT 81100417T AT 81100417 T AT81100417 T AT 81100417T AT E10182 T1 ATE10182 T1 AT E10182T1
Authority
AT
Austria
Prior art keywords
reformer
exchanger
tubes
feed
passed
Prior art date
Application number
AT81100417T
Other languages
English (en)
Inventor
Andrija Fuderer
Original Assignee
Union Carbide Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corporation filed Critical Union Carbide Corporation
Application granted granted Critical
Publication of ATE10182T1 publication Critical patent/ATE10182T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0866—Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0888—Methods of cooling by evaporation of a fluid
    • C01B2203/0894—Generation of steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C01B2203/1264—Catalytic pre-treatment of the feed
    • C01B2203/127—Catalytic desulfurisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C01B2203/1294—Evaporation by heat exchange with hot process stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Catalysts (AREA)
AT81100417T 1980-01-23 1981-01-21 Katalytische wasserdampf-reformierung von kohlenwasserstoffen. ATE10182T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/114,566 US4337170A (en) 1980-01-23 1980-01-23 Catalytic steam reforming of hydrocarbons
EP81100417A EP0033128B1 (de) 1980-01-23 1981-01-21 Katalytische Wasserdampf-Reformierung von Kohlenwasserstoffen

Publications (1)

Publication Number Publication Date
ATE10182T1 true ATE10182T1 (de) 1984-11-15

Family

ID=22356049

Family Applications (1)

Application Number Title Priority Date Filing Date
AT81100417T ATE10182T1 (de) 1980-01-23 1981-01-21 Katalytische wasserdampf-reformierung von kohlenwasserstoffen.

Country Status (9)

Country Link
US (1) US4337170A (de)
EP (1) EP0033128B1 (de)
JP (1) JPS56109286A (de)
AT (1) ATE10182T1 (de)
BR (1) BR8100327A (de)
CA (1) CA1144099A (de)
DE (1) DE3167004D1 (de)
ES (1) ES8201200A1 (de)
IN (1) IN155024B (de)

Families Citing this family (50)

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US4442020A (en) * 1980-01-23 1984-04-10 Union Carbide Corporation Catalytic steam reforming of hydrocarbons
US4822521A (en) * 1983-06-09 1989-04-18 Uop Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons
US4650651A (en) * 1983-06-09 1987-03-17 Union Carbide Corporation Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons
US4545976A (en) * 1983-11-10 1985-10-08 Exxon Research & Engineering Co. Hydrocarbon steam reforming using series steam superheaters
US4578214A (en) * 1984-02-06 1986-03-25 C F Braun & Co. Process for ammonia syngas manufacture
US4755361A (en) * 1984-02-07 1988-07-05 Union Carbide Corporation Apparatus for ammonia synthesis gas production
US4592860A (en) * 1984-02-07 1986-06-03 Union Carbide Corporation Process and apparatus for ammonia synthesis gas production
US4553981A (en) * 1984-02-07 1985-11-19 Union Carbide Corporation Enhanced hydrogen recovery from effluent gas streams
US4572829A (en) * 1984-11-09 1986-02-25 Union Carbide Corporation Ammonia synthesis gas purification
GB8629497D0 (en) * 1986-12-10 1987-01-21 British Petroleum Co Plc Apparatus
US4792441A (en) * 1988-01-19 1988-12-20 Air Products And Chemicals, Inc. Ammonia synthesis
EP0334540B1 (de) * 1988-03-24 1993-10-20 Imperial Chemical Industries Plc Zweistufiges Dampfreformierungsverfahren
US5202057A (en) * 1988-09-14 1993-04-13 Air Products And Chemicals, Inc. Production of ammonia synthesis gas
US4988490A (en) * 1988-09-14 1991-01-29 Air Products And Chemicals, Inc. Adsorptive process for recovering nitrogen from flue gas
US5011625A (en) * 1989-12-11 1991-04-30 The M. W. Kellogg Company Autothermal steam reforming process
US5122299A (en) * 1989-12-11 1992-06-16 The M. W. Kellogg Company Autothermal steam reforming process
AU661877B2 (en) * 1990-04-03 1995-08-10 Standard Oil Company, The Endothermic reaction apparatus
US5567398A (en) * 1990-04-03 1996-10-22 The Standard Oil Company Endothermic reaction apparatus and method
US6096106A (en) * 1990-04-03 2000-08-01 The Standard Oil Company Endothermic reaction apparatus
US6153152A (en) * 1990-04-03 2000-11-28 The Standard Oil Company Endothermic reaction apparatus and method
GB9516125D0 (en) * 1995-08-07 1995-10-04 Ici Plc Heat exchange apparatus and process
GB2311790A (en) * 1996-04-04 1997-10-08 British Gas Plc Production of synthesis gas from hydrocarbonaceous feedstock
US7066973B1 (en) 1996-08-26 2006-06-27 Nuvera Fuel Cells Integrated reformer and shift reactor
EP0834465B1 (de) * 1996-10-04 2000-07-19 Haldor Topsoe A/S Dampfreformierungsverfahren
EP0849245A1 (de) 1996-12-20 1998-06-24 Kvaerner Process Technology Limited Verfahren und Anlage zur Herstellung von Methanol
US6168765B1 (en) 1998-09-08 2001-01-02 Uop Llc Process and apparatus for interbed injection in plate reactor arrangement
US6641625B1 (en) 1999-05-03 2003-11-04 Nuvera Fuel Cells, Inc. Integrated hydrocarbon reforming system and controls
US6986797B1 (en) 1999-05-03 2006-01-17 Nuvera Fuel Cells Inc. Auxiliary reactor for a hydrocarbon reforming system
ATE556987T1 (de) * 2000-03-22 2012-05-15 Ammonia Casale Sa Verfahren zur kohlenwasserstoffreformierung
US6508209B1 (en) 2000-04-03 2003-01-21 R. Kirk Collier, Jr. Reformed natural gas for powering an internal combustion engine
US6397790B1 (en) 2000-04-03 2002-06-04 R. Kirk Collier, Jr. Octane enhanced natural gas for internal combustion engine
US6405720B1 (en) 2000-04-03 2002-06-18 R. Kirk Collier, Jr. Natural gas powered engine
RU2216513C2 (ru) * 2001-06-28 2003-11-20 Московский государственный университет инженерной экологии Способ получения аммиака
US20030162846A1 (en) * 2002-02-25 2003-08-28 Wang Shoou-L Process and apparatus for the production of synthesis gas
JP2006502938A (ja) 2002-06-13 2006-01-26 ヌヴェラ フューエル セルズ インコーポレイテッド 優先的酸化反応装置の温度調整
US6899861B2 (en) * 2002-07-25 2005-05-31 General Motors Corporation Heat exchanger mechanization to transfer reformate energy to steam and air
US6739125B1 (en) 2002-11-13 2004-05-25 Collier Technologies, Inc. Internal combustion engine with SCR and integrated ammonia production
JP4477432B2 (ja) * 2004-06-29 2010-06-09 東洋エンジニアリング株式会社 改質器
FR2890955B1 (fr) * 2005-09-21 2008-02-01 Inst Francais Du Petrole Procede de production de gaz de synthese par vaporeformage dans un reacteur-echangeur
FR2890956B1 (fr) * 2005-09-21 2008-04-18 Inst Francais Du Petrole Procede de production de gaz de synthese par vaporeformage et oxydation partielle
FR2897052A1 (fr) * 2006-02-03 2007-08-10 Air Liquide Procede de production d'un gaz de synthese
US20110073809A1 (en) * 2009-09-25 2011-03-31 Air Liquide Process And Construction Inc. Reduction Of CO2 Emissions From A Steam Methane Reformer And/Or Autothermal Reformer Using H2 As A Fuel
EP2526044B1 (de) 2010-01-19 2018-12-05 Haldor Topsøe A/S Verfahren für das reforming von kohlenwasserstoffen
BR112012017774B1 (pt) 2010-01-19 2021-09-21 Haldor Topsoe A/S Aparelho para conduzir um processo para a produção de gás de síntese, processo para a produção de gás de síntese a partir de uma carga de alimentação de hidrocarbonetos, e, uso do aparelho
EP2676924A1 (de) 2012-06-21 2013-12-25 Haldor Topsoe A/S Verfahren für das Reforming von Kohlenwasserstoffen
US10316376B2 (en) * 2015-06-24 2019-06-11 Midrex Technologies, Inc. Methods and systems for increasing the carbon content of sponge iron in a reduction furnace
US11447389B2 (en) 2017-12-08 2022-09-20 Haldor Topsøe A/S System and process for production of synthesis gas
DE102019211133A1 (de) * 2019-07-26 2021-01-28 Thyssenkrupp Ag Reformeranordnung zur Herstellung von Synthesegas und/oder Wasserstoff
EP4105170A1 (de) * 2021-06-18 2022-12-21 Technip Energies France Verfahren und anlage zur herstellung von syngas aus kohlenwasserstoffen
US11819815B2 (en) 2021-11-19 2023-11-21 Infinium Technology, Llc Catalytic reactor for the conversion of carbon dioxide and hydrogen to syngas

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US3278452A (en) * 1959-12-24 1966-10-11 Pullman Inc Production of hydrogen-containing gases
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US3904744A (en) * 1973-10-01 1975-09-09 Exxon Research Engineering Co Process for the production of hydrogen-containing gases
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US4079017A (en) * 1976-11-19 1978-03-14 Pullman Incorporated Parallel steam reformers to provide low energy process
US4162290A (en) * 1976-11-19 1979-07-24 Pullman Incorporated Parallel steam reformers to provide low energy process
JPS5382690A (en) * 1976-12-29 1978-07-21 Chiyoda Chem Eng & Constr Co Ltd Improved preparation of synthetic gas for ammonia

Also Published As

Publication number Publication date
CA1144099A (en) 1983-04-05
ES498699A0 (es) 1981-12-01
DE3167004D1 (en) 1984-12-13
BR8100327A (pt) 1981-08-11
US4337170A (en) 1982-06-29
JPH0242761B2 (de) 1990-09-26
ES8201200A1 (es) 1981-12-01
EP0033128B1 (de) 1984-11-07
EP0033128A1 (de) 1981-08-05
JPS56109286A (en) 1981-08-29
IN155024B (de) 1984-12-22

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