AR047575A1 - Metodo para controlar la acumulacion de placas en reactores de fase gaseosa - Google Patents

Metodo para controlar la acumulacion de placas en reactores de fase gaseosa

Info

Publication number
AR047575A1
AR047575A1 ARP050100004A ARP050100004A AR047575A1 AR 047575 A1 AR047575 A1 AR 047575A1 AR P050100004 A ARP050100004 A AR P050100004A AR P050100004 A ARP050100004 A AR P050100004A AR 047575 A1 AR047575 A1 AR 047575A1
Authority
AR
Argentina
Prior art keywords
static
control
accumulation
plates
reactor
Prior art date
Application number
ARP050100004A
Other languages
English (en)
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of AR047575A1 publication Critical patent/AR047575A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1809—Controlling processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H50/00—Details of electromagnetic relays
    • H01H50/54—Contact arrangements
    • H01H50/548—Contact arrangements for miniaturised relays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00734—Controlling static charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00254—Formation of unwanted polymer, such as "pop-corn"
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00—Contacts
    • H01H1/12—Contacts characterised by the manner in which co-operating contacts engage
    • H01H1/14—Contacts characterised by the manner in which co-operating contacts engage by abutting
    • H01H1/20—Bridging contacts
    • H01H1/2075—T-shaped bridge; bridging contact has lateral arm for mounting resiliently or on a pivot
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00—Contacts
    • H01H1/12—Contacts characterised by the manner in which co-operating contacts engage
    • H01H1/14—Contacts characterised by the manner in which co-operating contacts engage by abutting
    • H01H1/20—Bridging contacts
    • H01H1/2083—Bridging contact surfaces directed at an oblique angle with respect to the movement of the bridge
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H9/00—Details of switching devices, not covered by groups H01H1/00 - H01H7/00
    • H01H9/30—Means for extinguishing or preventing arc between current-carrying parts
    • H01H9/38—Auxiliary contacts on to which the arc is transferred from the main contacts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Electromagnetism (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Las realizaciones se refieren a la medicion y el control de la estática en un reactor de polimerizacion de fase gaseosa. En particular, las realizaciones se refieren a monitorear la estática del remanente en una zona de entrada durante la polimerizacion de la fase gaseosa para determinar el inicio de los eventos de discontinuidad del reactor tales como los atascamientos y la acumulacion de placa. Las realizaciones también se refieren al monitoreo de la estática remanente para determinar la necesidad de adiciones efectivas de aditivos de continuidad que minimicen la actividad de estática del reactor y por lo tanto impidan los eventos de discontinuidad.
ARP050100004A 2004-01-02 2005-01-03 Metodo para controlar la acumulacion de placas en reactores de fase gaseosa AR047575A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53402604P 2004-01-02 2004-01-02
US11/011,421 US20050148742A1 (en) 2004-01-02 2004-12-14 Method for controlling sheeting in gas phase reactors

Publications (1)

Publication Number Publication Date
AR047575A1 true AR047575A1 (es) 2006-01-25

Family

ID=34713153

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP050100004A AR047575A1 (es) 2004-01-02 2005-01-03 Metodo para controlar la acumulacion de placas en reactores de fase gaseosa

Country Status (15)

Country Link
US (1) US20050148742A1 (es)
EP (1) EP1699830B1 (es)
JP (1) JP5295501B2 (es)
KR (1) KR101139201B1 (es)
AR (1) AR047575A1 (es)
AT (1) ATE471951T1 (es)
AU (1) AU2004313933B2 (es)
BR (1) BRPI0417918B1 (es)
CA (1) CA2547342A1 (es)
DE (1) DE602004027834D1 (es)
ES (1) ES2347965T3 (es)
MY (1) MY143204A (es)
RU (1) RU2348650C2 (es)
TW (1) TW200530275A (es)
WO (1) WO2005068507A1 (es)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7846736B2 (en) * 2001-12-17 2010-12-07 Univation Technologies, Llc Method for polymerization reaction monitoring with determination of entropy of monitored data
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7078467B1 (en) * 2005-06-14 2006-07-18 Univation Technologies, Llc Single catalyst low, medium and high density polyethylenes
US7808227B2 (en) * 2006-07-07 2010-10-05 Univation Technologies, Llc Systems and methods for detecting impurities in reactor systems
AU2007279379A1 (en) * 2006-07-31 2008-02-07 Univation Technologies, Llc Method and apparatus for controlling static charge in polyolefin reactors
TWI404730B (zh) * 2007-02-05 2013-08-11 Univation Tech Llc 控制聚合物性質之方法
TW200902558A (en) * 2007-02-16 2009-01-16 Univation Tech Llc Method for on-line monitoring and control of polymerization processes and reactors to prevent discontinuity events
CN101802019B (zh) * 2007-08-16 2014-01-08 尤尼威蒂恩技术有限责任公司 连续性添加剂及其在聚合工艺中的用途
CN101965371B (zh) * 2007-12-31 2015-09-23 陶氏环球技术有限责任公司 用于聚合基于烯烃的聚合物的方法
WO2009096937A1 (en) * 2008-01-31 2009-08-06 Univation Technologies, Inc. Systems and methods for detecting liquid pooling in reactor systems
WO2009131663A2 (en) † 2008-04-22 2009-10-29 Univation Technologies, Llc Reactor systems and processes for using the same
BRPI0922454A2 (pt) * 2008-12-18 2018-05-22 Univation Tech Llc método para tratamento de leito de semente para uma reação de polimerização
RU2527945C2 (ru) * 2009-01-08 2014-09-10 Юнивейшн Текнолоджиз, Ллк Добавка для процессов полимеризации полиолефинов
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
RU2549541C2 (ru) 2009-07-28 2015-04-27 Юнивейшн Текнолоджиз, Ллк Способ полимеризации с использованием нанесенного катализатора с затрудненной геометрией
BR112012005542B1 (pt) * 2009-09-11 2019-08-20 Basell Poliolefine Italia S.R.L Processo para polimerização em fase gasosa de olefinas
IN2012DN02132A (es) 2009-12-18 2015-08-21 Univation Tech Llc
RU2542240C2 (ru) * 2010-05-28 2015-02-20 Юнивейшн Текнолоджиз, Ллк Способ и устройство для отслеживания и восстановления электрических свойств пленки на стенках реактора полимеризации
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
US8742041B2 (en) * 2010-11-30 2014-06-03 Univation Technologies, Llc Processes for the polymerization of olefins with extracted metal carboxylate salts
CN103347905B (zh) 2010-12-22 2015-12-16 尤尼威蒂恩技术有限责任公司 用于聚烯烃聚合方法的添加剂
CA2739969C (en) 2011-05-11 2018-08-21 Nova Chemicals Corporation Improving reactor operability in a gas phase polymerization process
US9321859B2 (en) 2011-06-09 2016-04-26 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
CA2742461C (en) 2011-06-09 2018-06-12 Nova Chemicals Corporation Modified phosphinimine catalysts for olefin polymerization
US9127094B2 (en) 2011-06-09 2015-09-08 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US9243092B2 (en) 2011-06-09 2016-01-26 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US9127106B2 (en) 2011-06-09 2015-09-08 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US9315591B2 (en) 2011-06-09 2016-04-19 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US9221935B2 (en) 2011-06-09 2015-12-29 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
WO2013101541A1 (en) * 2011-12-31 2013-07-04 Univation Technologies, Llc Continuity additive for polyolefin polymerization processes
CN103257090B (zh) * 2012-02-17 2015-10-07 中国石油化工股份有限公司 一种检测搅拌床反应器内结块的方法
EP2711379A1 (en) * 2012-09-21 2014-03-26 Basell Poliolefine Italia S.r.l. Process for the gas-phase polymerization of olefins
CN103769009B (zh) * 2012-10-19 2016-01-20 中国石油化工股份有限公司 一种沸腾床反应器
US9433914B2 (en) * 2013-12-20 2016-09-06 Chevron Phillips Chemical Company, Lp Polyolefin reactor system having a gas phase reactor
RU2687495C2 (ru) 2013-12-23 2019-05-14 Инеос Юроуп Аг Введение улавливателя
EP3087108B2 (en) 2013-12-23 2022-04-20 Ineos Europe AG Process
RU2701741C1 (ru) * 2014-04-02 2019-10-01 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Каталитическая композиция, способы получения и применение в способе полимеризации
CN104159385B (zh) * 2014-07-04 2016-07-27 中国石油化工股份有限公司 一种聚乙烯反应器的静电消除方法
KR102495590B1 (ko) * 2019-05-10 2023-02-06 웰이앤씨 주식회사 공정반응기의 정전기 제거장치
WO2020231109A1 (ko) * 2019-05-10 2020-11-19 웰이앤씨 주식회사 공정반응기의 정전기 제거장치
WO2021011768A1 (en) * 2019-07-18 2021-01-21 Exxonmobil Research And Engineering Company Multi-sensory probes and systems for monitoring fluidization

Family Cites Families (108)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5066737A (en) * 1990-10-22 1991-11-19 Shell Oil Company Olefin polymerization catalyst
US3221002A (en) * 1963-09-26 1965-11-30 Cabot Corp Process for polymerization utilizing a surface treated inorganic solid catalyst
US3487112A (en) * 1967-04-27 1969-12-30 Monsanto Co Vapor phase hydroformylation process
US3687920A (en) * 1971-01-25 1972-08-29 Union Carbide Corp Polymerization of olefins with silane modified catalyst system
US4115639A (en) * 1971-06-24 1978-09-19 Union Carbide Corporation Ethylene polymerization with ether modified catalyst
US4086408A (en) * 1973-12-20 1978-04-25 Union Carbide Corporation Ethylene polymerization with silane modified catalyst
GB1443074A (en) * 1974-01-14 1976-07-21 Ici Ltd Olefin polymerisation process
IT1037112B (it) * 1975-03-28 1979-11-10 Montedison Spa Catalizzatori per la polimerizzazione delle olfine
US4077904A (en) * 1976-06-29 1978-03-07 Union Carbide Corporation Olefin polymerization process and catalyst therefor
US4101445A (en) * 1976-09-22 1978-07-18 Union Carbide Corporation Preparation of modified and activated chromocene catalysts for ethylene polymerization
DE2731067C3 (de) * 1977-07-09 1981-11-26 Bunawerke Hüls GmbH, 4370 Marl Verfahren zur Herstellung von Polybutadien mit einem hohen Gehalt an Monomereneinheiten in cis-1,4- Struktur
DE2966150D1 (en) * 1978-03-23 1983-10-20 Ici Plc Gas-phase olefin polymerisation system and process for operating it
US4302566A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
US4302565A (en) * 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4182810A (en) * 1978-04-21 1980-01-08 Phillips Petroleum Company Prevention of fouling in polymerization reactors
US4482687A (en) * 1979-10-26 1984-11-13 Union Carbide Corporation Preparation of low-density ethylene copolymers in fluid bed reactor
US4376062A (en) * 1979-11-28 1983-03-08 Union Carbide Corporation Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization
US4379758A (en) * 1980-12-24 1983-04-12 Union Carbide Corporation Catalyst composition for polymerizing ethylene
US5019633A (en) * 1980-12-24 1991-05-28 Technology Corporation Catalyst composition for polymerizing ethylene
US4532311A (en) * 1981-03-26 1985-07-30 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
US4376191A (en) * 1981-10-01 1983-03-08 Union Carbide Corporation Use of dialkylzinc compounds to initiate polymerization of ethylene with chromium oxide catalysts
CA1219994A (en) * 1981-12-24 1987-03-31 Nobunori Maehara Process for producing polybutadiene rubber with enhanced mechanical strength
DE3366573D1 (en) * 1982-06-24 1986-11-06 Bp Chimie Sa Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed
US4560671A (en) * 1983-07-01 1985-12-24 Union Carbide Corporation Olefin polymerization catalysts adapted for gas phase processes
FR2555182B1 (fr) * 1983-11-23 1986-11-07 Bp Chimie Sa Procede de preparation de catalyseur supporte pour la copolymerisation de l'ethylene avec des alpha-olefines superieures
US4755495A (en) * 1986-02-27 1988-07-05 Union Carbide Corporation Process for activation of titanium and vanadium catalysts useful in ethylene polymerization
US4689437A (en) * 1986-07-21 1987-08-25 Union Carbide Corporation Oligomerization to alpha-olefins
US4719193A (en) * 1986-09-30 1988-01-12 Union Carbide Corporation Processes for preparing polyethylene catalysts by heating catalyst precursors
US4855370A (en) * 1986-10-01 1989-08-08 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
FR2609036B1 (fr) * 1986-12-29 1989-04-14 Bp Chimie Sa Polymerisation ou copolymerisation d'ethylene en phase gazeuse en presence d'un prepolymere comprenant un catalyseur d'oxyde de chrome
US5264405A (en) * 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5026795A (en) * 1987-02-24 1991-06-25 Phillips Petroleum Co Process for preventing fouling in a gas phase polymerization reactor
DE3881728T3 (de) * 1987-03-14 1998-01-15 Mitsubishi Chem Ind Verfahren zur Herstellung eines Propylen-alpha-Olefin-Blockkopolymers.
US5093415A (en) * 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
FR2628110B1 (fr) * 1988-03-03 1994-03-25 Bp Chimie Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation
US5149819A (en) * 1988-04-28 1992-09-22 Ricoh Company, Ltd. Squarylium compounds and optical information recording medium using the same
FR2646426B2 (fr) * 1988-09-13 1991-08-16 Bp Chemicals Sa Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite
DE3833445A1 (de) * 1988-10-01 1990-04-05 Basf Ag Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems
DE3833444A1 (de) * 1988-10-01 1990-04-05 Basf Ag Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems
US5376612A (en) * 1989-08-10 1994-12-27 Phillips Petroleum Company Chromium catalysts and process for making chromium catalysts
US5227440A (en) * 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2660926B1 (fr) * 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
PL166690B1 (pl) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
US5070055A (en) * 1990-06-29 1991-12-03 Union Carbide Chemicals And Plastics Technology Corporation Novel coimpregnated vanadium-zirconium catalyst for making polyethylene with broad or bimodal MW distribution
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
US5239022A (en) * 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
US5243001A (en) * 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
US5176953A (en) * 1990-12-21 1993-01-05 Amoco Corporation Oriented polymeric microporous films
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5852148A (en) * 1991-07-10 1998-12-22 Minnesota Mining & Manufacturing Company Perfluoroalkyl halides and derivatives
US5126414A (en) * 1991-10-11 1992-06-30 Mobil Oil Corporation Control of oligomer level in low pressure polyethylene reactor systems
DE59210001D1 (de) * 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5233049A (en) * 1991-10-29 1993-08-03 Occidental Chemical Corporation Highly fluorinated bis-imides
US5331071A (en) * 1991-11-12 1994-07-19 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
EP0614468B1 (en) * 1991-11-25 1997-09-17 Exxon Chemical Patents Inc. Polyonic transition metal catalyst composition
DE69224463T2 (de) * 1991-11-28 1998-07-09 Showa Denko Kk Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
IT1262933B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Processo per la polimerizzazione in fase gas di alfa-olefine
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
DE4334045A1 (de) * 1993-10-06 1995-04-13 Bayer Ag Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen
US5670438A (en) * 1993-10-27 1997-09-23 Phillips Petroleum Company Catalyst compositions and catalytic processes
CA2139064A1 (en) * 1993-12-27 1995-06-28 Mitsui Chemicals, Inc. Olefin polymerization catalyst and process for olefin polymerization
FI96867C (fi) * 1993-12-27 1996-09-10 Borealis Polymers Oy Leijupetireaktori
IT1274016B (it) * 1994-02-21 1997-07-14 Spherilene Srl Processo per la polimerizzazione in fase gas delle a-olefine
US5473020A (en) * 1994-06-30 1995-12-05 Phillips Petroleum Company Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use
US5461123A (en) * 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US5539124A (en) * 1994-12-19 1996-07-23 Occidental Chemical Corporation Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring
US5554775A (en) * 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
US5880241A (en) * 1995-01-24 1999-03-09 E. I. Du Pont De Nemours And Company Olefin polymers
GB9502870D0 (en) * 1995-02-14 1995-04-05 Zeneca Ltd Chiral compounds
US5527752A (en) * 1995-03-29 1996-06-18 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the production of polyolefins
FI104827B (fi) * 1995-04-12 2000-04-14 Borealis Polymers Oy Menetelmä likaantumisen ja kerrostumisen estämiseksi kaasufaasireaktoreissa
US5637660A (en) * 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
ATE223929T1 (de) * 1995-05-16 2002-09-15 Univation Tech Llc Herstellung von polyethylen unter verwendung eines stereoisomeren metallocens
US5661095A (en) * 1995-06-06 1997-08-26 Quantum Chemical Corporation Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane
IT1275777B1 (it) * 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
DE69602329T2 (de) * 1995-09-14 1999-09-23 Showa Denko K.K., Tokio/Tokyo Katalysator für ethylenische Polymerisation
EP0768322A1 (en) * 1995-10-16 1997-04-16 Sumitomo Chemical Company, Limited Method for preparing catalyst component for olefin polymerization, catalyst for olefin polymerization and process for producing olefin polymer with the catalyst
US5869585A (en) * 1995-10-30 1999-02-09 Mobil Oil Corporation Multi-component catalyst systems for olefin polymerization
US5744417A (en) * 1996-05-02 1998-04-28 Lyondell Petrochemical Company Supported catalyst
CZ170897A3 (en) * 1996-06-06 1997-12-17 Union Carbide Chem Plastic Control of static charge in the course of polymerization process during which metallocene catalyst is used
DE69730838T2 (de) * 1996-07-23 2006-02-16 E.I. Du Pont De Nemours And Co., Wilmington Polymerisationsverfahren für olefinen
US5731392A (en) * 1996-09-20 1998-03-24 Mobil Oil Company Static control with TEOS
US5856258A (en) * 1996-10-15 1999-01-05 Northwestern University Phenolate constrained geometry polymerization catalyst and method for preparing
US5849655A (en) * 1996-12-20 1998-12-15 Fina Technology, Inc. Polyolefin catalyst for polymerization of propylene and a method of making and using thereof
KR19980060611A (ko) * 1996-12-31 1998-10-07 김영환 티타늄 실리사이드 제조방법
US5856547A (en) * 1997-01-08 1999-01-05 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane compounds
US5854363A (en) * 1997-01-08 1998-12-29 Phillips Petroleum Company (Omega-alkenyl) (cyclopentacarbyl) metallocene compounds
US5747406A (en) * 1997-01-10 1998-05-05 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the production of olefin polymers
US5851945A (en) * 1997-02-07 1998-12-22 Exxon Chemical Patents Inc. Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state
US5756611A (en) * 1997-02-21 1998-05-26 Lyondell Petrochemical Company α-olefin polymerization catalysts
SE518145C2 (sv) * 1997-04-18 2002-09-03 Sandvik Ab Multiskiktbelagt skärverktyg
US6008667A (en) * 1997-11-19 1999-12-28 Texas Instruments Incorporated Emitter-coupled logic to CMOS logic converter and method of operation
US6245868B1 (en) * 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
US7354880B2 (en) * 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
DE19835467A1 (de) * 1998-08-06 2000-02-17 Elenac Gmbh Feststoffreaktor mit antistatischer Beschichtung zur Durchführung von Reaktionen in der Gasphase
US6111034A (en) * 1998-12-31 2000-08-29 Union Carbide Chemicals & Plastics Technology Corporation Static control in olefin polymerization
CA2394533A1 (en) * 1999-12-15 2001-06-21 Univation Technologies, Llc Polymerization process
GB0027990D0 (en) * 2000-11-16 2001-01-03 Bp Chemicals Snc Polymerisation process
WO2002046246A2 (en) * 2000-12-04 2002-06-13 Univaton Technologies, Llc Polimerization process
EP1308464A1 (en) * 2001-10-19 2003-05-07 BP Chemicals S.N.C. Process for the gas-phase (co-)polymerisation of olefins in a fluidised bed reactor
US6831140B2 (en) * 2002-12-26 2004-12-14 Univation Technologies, Llc Static measurement and detection in a gas phase polyethylene reactor

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MY143204A (en) 2011-03-31
ATE471951T1 (de) 2010-07-15
KR20060117980A (ko) 2006-11-17
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KR101139201B1 (ko) 2012-07-05
CA2547342A1 (en) 2005-07-28
US20050148742A1 (en) 2005-07-07
WO2005068507A1 (en) 2005-07-28
RU2348650C2 (ru) 2009-03-10
BRPI0417918A (pt) 2007-04-17
ES2347965T3 (es) 2010-11-26
TW200530275A (en) 2005-09-16
JP2007517936A (ja) 2007-07-05
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EP1699830B1 (en) 2010-06-23
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DE602004027834D1 (de) 2010-08-05

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