AR043048A1 - Derivados de 4-(3,3-dihalo- aliloxi) fenol con propiedades pesticidas - Google Patents
Derivados de 4-(3,3-dihalo- aliloxi) fenol con propiedades pesticidasInfo
- Publication number
- AR043048A1 AR043048A1 ARP030103119A ARP030103119A AR043048A1 AR 043048 A1 AR043048 A1 AR 043048A1 AR P030103119 A ARP030103119 A AR P030103119A AR P030103119 A ARP030103119 A AR P030103119A AR 043048 A1 AR043048 A1 AR 043048A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- cycloalkyl
- haloalkyl
- alkoxy
- haloalkoxy
- Prior art date
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- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
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- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
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- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
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- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D277/38—Nitrogen atoms
- C07D277/44—Acylated amino or imino radicals
- C07D277/48—Acylated amino or imino radicals by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof, e.g. carbonylguanidines
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- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
- C07D285/08—1,2,4-Thiadiazoles; Hydrogenated 1,2,4-thiadiazoles
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- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
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- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
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- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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Abstract
Composiciones pesticidas, en las que el principio activo se seleccionó de esos compuestos o una sal aceptable desde el punto de vista agroquímico de los mismos, un procedimiento para la preparación de tales composiciones y su uso, el material de reproducción vegetal tratado con tales composiciones y un método para controlar plagas. Reivindicación 1: Un compuesto de la fórmula (1) en donde A0, A1 y A2 son, cada uno independientemente del otro, una unión o un puente alquileno C1-6 que no está sustituido o está sustituid con de uno a seis sustituyentes iguales o diferentes seleccionados entre cicloalquilo C3-8, cicloalquilo-C3-8-alquilo- C1-6 y haloalquilo C1-3; A3 es un puente alquileno C1-6, que no está sustituido o está sustituido con de uno a seis sustituyentes iguales o diferentes seleccionados entre cicloalquilo C3-8, cicloalquilo-C3-8-alquilo-C1-6 y haloalquilo C1-3; D es CH ó N; X1 y X2 son, cada uno independientemente del otro, flúor, cloro o bromo; R1, R2 y R3 son, cada uno independientemente de los otros, H, halógeno, OH, SH, CN, nitro, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, -S(=O)-alquilo C1-6, -S(O)2-alquilo C1-6, alcoxicarbonilo C1-6 ó haloalquiniloxi C3-6; en donde cuando m es 2, los sustituyentes R3 son independientes entre sí; R4 es H, halógeno, OH, SH; CN, nitro, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, -S(=O)-alquilo C1-6, -S(=O)2-alquilo C1-6, ó alcoxicarbonilo C1-6; en donde los sustituyentes R4 son independientes entre sí, cuando k es mayor a 1; ó N(R5)2 en donde los dos sustituyentes R5 son independientes entre sí; R5 es H, CN, OH, alquilo C1-6, cicloalquilo C3-8, cicloalquilo C3-8-alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, -C(=O)R8, -C(=S)R8, fenilo, bencilo; o fenilo o bencilo, cada uno de los cuales está sustituido en el anillo aromático con uno a cinco sustituyentes iguales o diferentes seleccionados entre el grupo que consiste en halógeno, alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, hidroxi, ciano y nitro; o los dos sustituyentes R5 juntos forman un puente alquileno con 4 a 8 miembros, de cadena recta o ramificada, en donde un grupo CH2 puede haberse reemplazado por O, S ó NR9, y el puente alquileno no está sustituido o está sustituido con de uno a cuatro sustituyentes iguales o diferentes seleccionados entre cicloalquilo C3-8, cicloalquilo C3-8-alquilo C1-6, y haloalquilo C1-3; W es O, NR6, S, SO, SO2, -C(=O)-O-, -O-C(=O)-, -C(=O)-NR7-, ó -NR7-C(=O)-; T es una unión, O, NH, NR6, S, SO, SO2, -C(=O)-O-, -O-C(=O)-, -C(=O)-NR7- ó -NR7-C(=O)-; Q es O, NR6, S, SO ó SO2; Y es O, NR6, S, SO ó SO2; R6 y R7 son, independientemente entre sí, H, alquilo C1-6, haloalquilo C1-3, alquilcarbonilo C1-6, haloalquilcarbonilo C1-3, alcoxialquilo C1-6, cicloalquilo C3-8 ó bencilo; R8 es alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, cicloalquilo C3-6, fenilo, bencilo; o fenilo o bencilo donde cada uno de ellos no está sustituido o está sustituido con de uno a tres sustituyentes iguales o diferentes seleccionados entre halógeno, CN, nitro, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alcoxicarbonilo C1-6, haloalcoxicarbonilo C1-3 y haloalqueniloxi C2-6; R9 es H, alquilo C1-6, haloalquilo C1-3, alquilcarbonilo C1-6, haloalquilcarbonilo C1-6, alcoxialquilo C1-6, cicloalquilo C3-8 ó bencilo; k es 1, 2 ó 3 cuando D es nitrógeno; o es 1, 2, 3 ó 4 cuando D es CH; m es 1 ó 2; E es un heteroarilo que está sustituido o no, dependiendo de las sustituciones posibles en el anillo, con de uno a cuatro sustituyentes iguales o diferentes seleccionados entre R10; R10 es halógeno, CN, NO2, OH, SH, alquilo C1-6, haloalquilo C1-6, hidroxialquilo C1-6, cicloalquilo c3-8, cicloalquilo C3-8-alquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C3-6, haloalquinilo C3-6, alcoxi C1-6, alcoxi C1-6-alquilo C1-6, haloalcoxi C1-6, haloalcoxi C1-6-alquilo C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alqueniloxi C2-6-alquilo C1-6, haloalqueniloxi C2-6-alquilo C1-6, alquiniloxi C3-6, haloalquiniloxi C3-6, alquiniloxi C3-6-alquilo C1-6, cicloalcoxi C3-8, cicloalquilo C3-8-alcoxi C1-6, cicloalcoxi C3-8-alquilo C1-6, cicloalcoxi C3-8-alcoxi C1-6, cicloalquilo C3-8-alcoxi C1-6-alquilo C1-6, alquilcarbonilo C1-6-alquilo C1-6, alcoxicarbonilo C1-6-alquilo C1-6, alquiltio C1-6, alqueniltio C2-6, alquiniltio C3-6, cicloalquiltio C3-6, cicloalquilo C3-6-alquiltio C1-6, haloalqueniltio C2-6, haloalquiltio C1-6, NH2, NH(alquilo C1-6), N(alquilo C1-6)2, alquilcarbonilamino C1-6, haloalquilcarbonilamino C1-6, alcoxicarbonilamino C1-6, alquilaminocarbonilamino C1-6, -SO-alquilo C1-6, -SO-haloalquilo C1-6, -SO2-alquilo C1-6, -SO2-haloalquilo C1-6, -C(=O)R11, fenilo o bencilo; en donde los radicales fenilo y bencilo pueden estar sustituidos con uno a tres sustituyentes seleccionados entre halógeno, OH, SH, CN, nitro, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, -S(=O)-alquilo C1-6, -S(=O)2-alquilo C1-6, alcoxicarbonilo C1-6 y haloalqueniloxi C2-6, y R11 es H, OH, alquilo C1-6, cicloalquilo C3-8, cicloalquilo C3-8-alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, cicloalcoxi C3-8, cicloalquilo C3-8-alcoxi C1-6, haloalcoxi C1-6, alquenilo C2-6, haloalquenilo C2-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquinilo C2-6, haloalquinilo C2-6, alquiniloxi C2-6, haloalquiniloxi C2-6, NH2, NH-alquilo C1-6, -N(alquilo C1-6)2, NH-fenilo, NH-bencilo, fenoxi o benciloxi; y en donde sea procedente, a sus posibles isómeros E/Z, mezclas isoméricas E/Z y/o tautómeros, en cada caso en forma libre o en forma de sal.
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US (2) | US7608631B2 (es) |
EP (1) | EP1537077A2 (es) |
JP (1) | JP2006507245A (es) |
AR (1) | AR043048A1 (es) |
AU (1) | AU2003266333A1 (es) |
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TW200406370A (en) * | 2002-06-28 | 2004-05-01 | Syngenta Participations Ag | 4-(3,3-Dihalo-allyloxy)phenoxy alkyl derivatives |
TW200406152A (en) * | 2002-08-30 | 2004-05-01 | Syngenta Participations Ag | 4-(3,3-Dihalo-allyloxy) phenol derivatives having pesticidal properties |
JP2006525335A (ja) | 2003-04-30 | 2006-11-09 | エフ エム シー コーポレーション | 殺虫性(ジハロプロペニル)フェニルアルキル置換ジヒドロベンゾフラン及びジヒドロベンゾピラン誘導体 |
TW200507752A (en) | 2003-06-23 | 2005-03-01 | Syngenta Participations Ag | Pesticidally active ketone and oxime derivatives |
TW200612961A (en) * | 2004-05-18 | 2006-05-01 | Fmc Corp | Substituted cyclic urea derivatives |
CA2974477C (en) * | 2007-08-27 | 2019-12-31 | Dart Neuroscience (Cayman) Ltd. | Therapeutic isoxazole compounds |
PE20142449A1 (es) | 2008-12-18 | 2015-01-11 | Bayer Cropscience Ag | Amidas del acido antranilico sustituidas con tetrazol como plaguicidas |
RS54277B1 (en) | 2010-06-15 | 2016-02-29 | Bayer Intellectual Property Gmbh | PROCEDURE FOR THE PRODUCTION OF TETRAZOLOM SUBSTITUTED ANTHRANILIC ACID DIAMID DERIVATIVES AND THE NEW CRYSTAL MODIFICATION OF THESE DERIVATIVES |
CN102718701B (zh) * | 2011-03-30 | 2014-05-07 | 中国中化股份有限公司 | 芳氧基二卤丙烯醚类化合物与应用 |
ES2653205T3 (es) | 2011-07-08 | 2018-02-06 | Bayer Intellectual Property Gmbh | Procedimiento de preparación de derivados de diamida del ácido antranílico sustituidos con tetrazol mediante la reacción de ácidos de pirazol con ésteres del ácido antranílico |
CN103764649B (zh) | 2011-08-26 | 2016-10-19 | 拜耳知识产权有限责任公司 | 通过苯并噁嗪酮与胺反应制备四唑取代的邻氨基苯甲酸二酰胺衍生物的方法 |
CN103102348B (zh) * | 2011-11-14 | 2016-06-08 | 上海交通大学 | 噁二唑类化合物及其制备方法、药物组合物及其用途 |
CN103145637A (zh) * | 2013-03-17 | 2013-06-12 | 石家庄学院 | 3-苯基-5-溴-1,2,4-噁二唑衍生物的合成新工艺 |
CA3002299A1 (en) | 2015-11-05 | 2017-05-11 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
CR20180332A (es) * | 2015-11-19 | 2018-10-18 | Basf Se | Oxadiazoles sustituidos para combatir hongos fitopatógenos |
JP2018537457A (ja) | 2015-11-19 | 2018-12-20 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 植物病原菌を駆除するための置換オキサジアゾール |
EP3439477B1 (en) | 2016-04-08 | 2020-05-06 | Syngenta Participations AG | Microbiocidal oxadiazole derivatives |
CA3020532A1 (en) | 2016-04-11 | 2017-10-19 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
WO2017211649A1 (en) | 2016-06-09 | 2017-12-14 | Basf Se | Substituted oxadiazoles for combating phytopathogenic fungi |
JP7051829B2 (ja) | 2016-06-13 | 2022-04-11 | グラクソスミスクライン、インテレクチュアル、プロパティー、ディベロップメント、リミテッド | Dnmt1の阻害剤としての置換ピリジン |
US20220056007A1 (en) | 2018-12-03 | 2022-02-24 | Fmc Corporation | Method for preparing n-phenylpyrazole-1-carboxamides |
CN113636987B (zh) * | 2021-08-12 | 2022-09-20 | 南通慧源塑胶有限公司 | 含噻二唑单元的氯代丙烯衍生物的制备和用途 |
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WO1997027173A2 (en) * | 1996-01-24 | 1997-07-31 | Sumitomo Chemical Company, Limited | Dihalopropene compounds, their use as insecticides/acaricides and intermediates for their production |
JPH09263572A (ja) * | 1996-01-24 | 1997-10-07 | Sumitomo Chem Co Ltd | ジハロプロペン化合物、その用途およびその製造中間体 |
US6140274A (en) | 1996-01-30 | 2000-10-31 | Sumitomo Chemical Company, Limited | Dihalopropene compounds, their use as insecticides/acaricides and intermediates for their production |
CN1167104A (zh) | 1996-01-31 | 1997-12-10 | 住友化学工业株式会社 | 氟丙烯化合物,含有该化合物的杀虫剂以及制备过程中的中间体 |
US6437184B1 (en) | 1997-04-08 | 2002-08-20 | Sumitomo Chemical Company, Limited | Oxime compounds, their use, and intermediates for their production |
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TW200406370A (en) * | 2002-06-28 | 2004-05-01 | Syngenta Participations Ag | 4-(3,3-Dihalo-allyloxy)phenoxy alkyl derivatives |
TW200406152A (en) * | 2002-08-30 | 2004-05-01 | Syngenta Participations Ag | 4-(3,3-Dihalo-allyloxy) phenol derivatives having pesticidal properties |
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AU2003266333A8 (en) | 2004-03-19 |
JP2006507245A (ja) | 2006-03-02 |
TW200406152A (en) | 2004-05-01 |
US20050288186A1 (en) | 2005-12-29 |
EP1537077A2 (en) | 2005-06-08 |
WO2004020445A3 (en) | 2004-04-15 |
AU2003266333A1 (en) | 2004-03-19 |
US20100016383A1 (en) | 2010-01-21 |
WO2004020445A2 (en) | 2004-03-11 |
US7608631B2 (en) | 2009-10-27 |
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