AR043048A1 - Derivados de 4-(3,3-dihalo- aliloxi) fenol con propiedades pesticidas - Google Patents

Derivados de 4-(3,3-dihalo- aliloxi) fenol con propiedades pesticidas

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Publication number
AR043048A1
AR043048A1 ARP030103119A ARP030103119A AR043048A1 AR 043048 A1 AR043048 A1 AR 043048A1 AR P030103119 A ARP030103119 A AR P030103119A AR P030103119 A ARP030103119 A AR P030103119A AR 043048 A1 AR043048 A1 AR 043048A1
Authority
AR
Argentina
Prior art keywords
alkyl
cycloalkyl
haloalkyl
alkoxy
haloalkoxy
Prior art date
Application number
ARP030103119A
Other languages
English (en)
Original Assignee
Syngenta Participations Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Participations Ag filed Critical Syngenta Participations Ag
Publication of AR043048A1 publication Critical patent/AR043048A1/es

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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/325—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
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    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Indole Compounds (AREA)
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Abstract

Composiciones pesticidas, en las que el principio activo se seleccionó de esos compuestos o una sal aceptable desde el punto de vista agroquímico de los mismos, un procedimiento para la preparación de tales composiciones y su uso, el material de reproducción vegetal tratado con tales composiciones y un método para controlar plagas. Reivindicación 1: Un compuesto de la fórmula (1) en donde A0, A1 y A2 son, cada uno independientemente del otro, una unión o un puente alquileno C1-6 que no está sustituido o está sustituid con de uno a seis sustituyentes iguales o diferentes seleccionados entre cicloalquilo C3-8, cicloalquilo-C3-8-alquilo- C1-6 y haloalquilo C1-3; A3 es un puente alquileno C1-6, que no está sustituido o está sustituido con de uno a seis sustituyentes iguales o diferentes seleccionados entre cicloalquilo C3-8, cicloalquilo-C3-8-alquilo-C1-6 y haloalquilo C1-3; D es CH ó N; X1 y X2 son, cada uno independientemente del otro, flúor, cloro o bromo; R1, R2 y R3 son, cada uno independientemente de los otros, H, halógeno, OH, SH, CN, nitro, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, -S(=O)-alquilo C1-6, -S(O)2-alquilo C1-6, alcoxicarbonilo C1-6 ó haloalquiniloxi C3-6; en donde cuando m es 2, los sustituyentes R3 son independientes entre sí; R4 es H, halógeno, OH, SH; CN, nitro, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, -S(=O)-alquilo C1-6, -S(=O)2-alquilo C1-6, ó alcoxicarbonilo C1-6; en donde los sustituyentes R4 son independientes entre sí, cuando k es mayor a 1; ó N(R5)2 en donde los dos sustituyentes R5 son independientes entre sí; R5 es H, CN, OH, alquilo C1-6, cicloalquilo C3-8, cicloalquilo C3-8-alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, -C(=O)R8, -C(=S)R8, fenilo, bencilo; o fenilo o bencilo, cada uno de los cuales está sustituido en el anillo aromático con uno a cinco sustituyentes iguales o diferentes seleccionados entre el grupo que consiste en halógeno, alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, hidroxi, ciano y nitro; o los dos sustituyentes R5 juntos forman un puente alquileno con 4 a 8 miembros, de cadena recta o ramificada, en donde un grupo CH2 puede haberse reemplazado por O, S ó NR9, y el puente alquileno no está sustituido o está sustituido con de uno a cuatro sustituyentes iguales o diferentes seleccionados entre cicloalquilo C3-8, cicloalquilo C3-8-alquilo C1-6, y haloalquilo C1-3; W es O, NR6, S, SO, SO2, -C(=O)-O-, -O-C(=O)-, -C(=O)-NR7-, ó -NR7-C(=O)-; T es una unión, O, NH, NR6, S, SO, SO2, -C(=O)-O-, -O-C(=O)-, -C(=O)-NR7- ó -NR7-C(=O)-; Q es O, NR6, S, SO ó SO2; Y es O, NR6, S, SO ó SO2; R6 y R7 son, independientemente entre sí, H, alquilo C1-6, haloalquilo C1-3, alquilcarbonilo C1-6, haloalquilcarbonilo C1-3, alcoxialquilo C1-6, cicloalquilo C3-8 ó bencilo; R8 es alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, cicloalquilo C3-6, fenilo, bencilo; o fenilo o bencilo donde cada uno de ellos no está sustituido o está sustituido con de uno a tres sustituyentes iguales o diferentes seleccionados entre halógeno, CN, nitro, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alcoxicarbonilo C1-6, haloalcoxicarbonilo C1-3 y haloalqueniloxi C2-6; R9 es H, alquilo C1-6, haloalquilo C1-3, alquilcarbonilo C1-6, haloalquilcarbonilo C1-6, alcoxialquilo C1-6, cicloalquilo C3-8 ó bencilo; k es 1, 2 ó 3 cuando D es nitrógeno; o es 1, 2, 3 ó 4 cuando D es CH; m es 1 ó 2; E es un heteroarilo que está sustituido o no, dependiendo de las sustituciones posibles en el anillo, con de uno a cuatro sustituyentes iguales o diferentes seleccionados entre R10; R10 es halógeno, CN, NO2, OH, SH, alquilo C1-6, haloalquilo C1-6, hidroxialquilo C1-6, cicloalquilo c3-8, cicloalquilo C3-8-alquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C3-6, haloalquinilo C3-6, alcoxi C1-6, alcoxi C1-6-alquilo C1-6, haloalcoxi C1-6, haloalcoxi C1-6-alquilo C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alqueniloxi C2-6-alquilo C1-6, haloalqueniloxi C2-6-alquilo C1-6, alquiniloxi C3-6, haloalquiniloxi C3-6, alquiniloxi C3-6-alquilo C1-6, cicloalcoxi C3-8, cicloalquilo C3-8-alcoxi C1-6, cicloalcoxi C3-8-alquilo C1-6, cicloalcoxi C3-8-alcoxi C1-6, cicloalquilo C3-8-alcoxi C1-6-alquilo C1-6, alquilcarbonilo C1-6-alquilo C1-6, alcoxicarbonilo C1-6-alquilo C1-6, alquiltio C1-6, alqueniltio C2-6, alquiniltio C3-6, cicloalquiltio C3-6, cicloalquilo C3-6-alquiltio C1-6, haloalqueniltio C2-6, haloalquiltio C1-6, NH2, NH(alquilo C1-6), N(alquilo C1-6)2, alquilcarbonilamino C1-6, haloalquilcarbonilamino C1-6, alcoxicarbonilamino C1-6, alquilaminocarbonilamino C1-6, -SO-alquilo C1-6, -SO-haloalquilo C1-6, -SO2-alquilo C1-6, -SO2-haloalquilo C1-6, -C(=O)R11, fenilo o bencilo; en donde los radicales fenilo y bencilo pueden estar sustituidos con uno a tres sustituyentes seleccionados entre halógeno, OH, SH, CN, nitro, alquilo C1-6, haloalquilo C1-6, alquilcarbonilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, -S(=O)-alquilo C1-6, -S(=O)2-alquilo C1-6, alcoxicarbonilo C1-6 y haloalqueniloxi C2-6, y R11 es H, OH, alquilo C1-6, cicloalquilo C3-8, cicloalquilo C3-8-alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, cicloalcoxi C3-8, cicloalquilo C3-8-alcoxi C1-6, haloalcoxi C1-6, alquenilo C2-6, haloalquenilo C2-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquinilo C2-6, haloalquinilo C2-6, alquiniloxi C2-6, haloalquiniloxi C2-6, NH2, NH-alquilo C1-6, -N(alquilo C1-6)2, NH-fenilo, NH-bencilo, fenoxi o benciloxi; y en donde sea procedente, a sus posibles isómeros E/Z, mezclas isoméricas E/Z y/o tautómeros, en cada caso en forma libre o en forma de sal.
ARP030103119A 2002-08-30 2003-08-28 Derivados de 4-(3,3-dihalo- aliloxi) fenol con propiedades pesticidas AR043048A1 (es)

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