AR038190A1 - Activacion de catalizador con soporte - Google Patents

Activacion de catalizador con soporte

Info

Publication number
AR038190A1
AR038190A1 ARP030100157A ARP030100157A AR038190A1 AR 038190 A1 AR038190 A1 AR 038190A1 AR P030100157 A ARP030100157 A AR P030100157A AR P030100157 A ARP030100157 A AR P030100157A AR 038190 A1 AR038190 A1 AR 038190A1
Authority
AR
Argentina
Prior art keywords
catalyst
impregnation
solution
optionally
oxidizing
Prior art date
Application number
ARP030100157A
Other languages
English (en)
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of AR038190A1 publication Critical patent/AR038190A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • B01J37/14—Oxidising with gases containing free oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso para activación de un catalizador o precursor de catalizador de metal con soporte ventajoso para la hidrogenación del monóxido de carbono para formar una mezcla de hidrocarburos, que comprende la reducción con un gas con contenido de H a temperatura elevada de manera que por lo menos una porción esté en estado metálico, la impregnación bajo atmósfera no oxidante con una solución de por lo menos un miembro seleccionado entre el grupo que consiste en sales de amonio, sales de alquilamonio y ácidos orgánicos débiles, optativamente también con contenido de amoníaco, a tal punto que haya absorbido un volúmen de solución igual a por lo menos 10 % de su volúmen de poro calculado, oxidando con un oxidante gaseoso en presencia de la solución de impregnación y reduciendo con un gas con contenido de H a temperaturas elevadas para formar un catalizador activo. Los pasos que comienzan con la impregnación se pueden repetir. Optativamente, el catalizador puede ser calcinado tras el paso de oxidación y/o pasivizado después de la activación.
ARP030100157A 2002-01-29 2003-01-20 Activacion de catalizador con soporte AR038190A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/059,918 US6753351B2 (en) 2002-01-29 2002-01-29 Supported catalyst activation

Publications (1)

Publication Number Publication Date
AR038190A1 true AR038190A1 (es) 2005-01-05

Family

ID=27609918

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP030100157A AR038190A1 (es) 2002-01-29 2003-01-20 Activacion de catalizador con soporte

Country Status (14)

Country Link
US (1) US6753351B2 (es)
EP (1) EP1480743B1 (es)
JP (1) JP4456873B2 (es)
CN (1) CN100490977C (es)
AR (1) AR038190A1 (es)
AT (1) ATE339252T1 (es)
AU (1) AU2003217168B2 (es)
CA (1) CA2472245C (es)
DE (1) DE60308329T2 (es)
DK (1) DK1480743T3 (es)
ES (1) ES2272958T3 (es)
TW (1) TWI248834B (es)
WO (1) WO2003068396A1 (es)
ZA (1) ZA200404976B (es)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2005111977A (ru) * 2002-09-20 2005-10-10 КонокоФиллипс Кампэни (US) Способ подавления гидрогенолиза суспензии катализатора и способ активации катализатора в синтезе фишера-тропша и способ получения углеводородов из синтез-газа
US6949488B2 (en) * 2002-09-20 2005-09-27 Conocophillips Company Fischer-Tropsch catalyst regeneration
US7973086B1 (en) 2010-10-28 2011-07-05 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst and hydrocracking catalyst
JP5001543B2 (ja) * 2004-11-17 2012-08-15 三菱レイヨン株式会社 パラジウム含有担持触媒の製造方法
TWI294413B (en) * 2004-11-19 2008-03-11 Ind Tech Res Inst Method for converting co and hydrogen into methane and water
US7358211B2 (en) * 2004-11-24 2008-04-15 E.I. Du Pont De Nemours And Company Catalyst for the production of 1,3-propanediol by catalytic hydrogenation of 3-hydroxypropanal
US7524787B2 (en) * 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
JP4857565B2 (ja) * 2005-01-27 2012-01-18 株式会社Ｉｈｉ フィッシャー・トロプシュ合成触媒とその製造方法
JP4765382B2 (ja) * 2005-04-18 2011-09-07 トヨタ自動車株式会社 耐熱性を備えた複合酸化物の製法
JP4835027B2 (ja) * 2005-04-18 2011-12-14 トヨタ自動車株式会社 複合体の製法
JP4765381B2 (ja) * 2005-04-18 2011-09-07 トヨタ自動車株式会社 耐熱性を備えた複合酸化物の製法
CN101134164B (zh) * 2006-08-31 2010-12-22 中国石油化工股份有限公司 一种钴基费托合成催化剂及其制备方法
CN101688124B (zh) * 2007-05-04 2013-01-23 沙索技术有限公司 催化剂
US20090023822A1 (en) * 2007-07-19 2009-01-22 Tijm Peter J Method for activating and regenerating catalyst for a fischer-tropsch synthesis reaction
US8614158B2 (en) * 2008-02-29 2013-12-24 Schlumberger Technology Corporation Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process
US8431507B2 (en) 2008-03-28 2013-04-30 Shell Oil Company Process for regenerating a catalyst
EP2276563B1 (en) * 2008-04-15 2018-05-23 Sasol Technology (Proprietary) Limited Process for the preparation of a COBALT BASED FISCHER-TROPSCH CATALYST and Fischer Tropsch process
JP5478097B2 (ja) * 2008-04-15 2014-04-23 花王株式会社 ２−アルキル−２−シクロアルケン−１−オンの製造方法
US7939953B2 (en) * 2008-04-16 2011-05-10 Schlumberger Technology Corporation Micro scale fischer-tropsch and oxygenate synthesis process startup unit
US8293805B2 (en) * 2008-05-29 2012-10-23 Schlumberger Technology Corporation Tracking feedstock production with micro scale gas-to-liquid units
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
WO2010078371A2 (en) * 2008-12-29 2010-07-08 Chevron U.S.A. Inc. Preparation of cobalt-containing acidic support-based fischer-tropsch catalysts
US8216963B2 (en) * 2008-12-29 2012-07-10 Chevron U.S.A. Inc. Preparation of cobalt-ruthenium fischer-tropsch catalysts
EP2409764A4 (en) * 2009-03-18 2012-10-10 Toyota Motor Co Ltd METHOD FOR CHARGING NANOPARTICLES
US7943674B1 (en) 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst
BR112012014717B1 (pt) 2009-12-16 2019-11-12 Shell Int Research processo para regenerar uma ou mais partículas de catalisador de fischer-tropsch que compreendem cobalto
US20110160315A1 (en) * 2009-12-30 2011-06-30 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using synthesis gas conversion catalyst and hydroisomerization catalyst
GB2482171B (en) * 2010-07-22 2018-04-11 Gtl F1 Ag Catalyst treatment
US8519011B2 (en) 2010-10-28 2013-08-27 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst, hydrocracking and hydroisomerization catalyst
FR2984346B1 (fr) * 2011-12-14 2013-12-27 IFP Energies Nouvelles Procede de fabrication d'hydrocarbures avec chargement en continu du catalyseur
WO2014137293A1 (en) * 2013-03-06 2014-09-12 National University Of Singapore A method for preparing a highly dispersed supported metal catalyst
CN104549559B (zh) * 2013-10-28 2017-03-15 中国石油化工股份有限公司 流化床合成气直接制备低碳烯烃铁基催化剂的活化方法
CN105080570B (zh) * 2014-05-14 2017-10-27 中国石油化工股份有限公司 流化床合成气直接制备低碳烯烃铁基催化剂的再生方法
FR3064498B1 (fr) * 2017-03-30 2021-10-29 Ifp Energies Now Procede de preparation de catalyseurs a base de cobalt
CN110961100B (zh) * 2018-09-30 2022-12-20 中国石油化工股份有限公司 环己烷脱氢制环己烯催化剂及制备方法
US10434506B1 (en) 2018-12-18 2019-10-08 Emerging Fuels Technology, Inc. Method for activation or regeneration of a catalyst
CN113117761B (zh) * 2019-12-31 2023-05-05 中国石油化工股份有限公司 一种钝化处理硫化态加氢催化剂的方法
CN114425439A (zh) * 2020-09-18 2022-05-03 中国石油化工股份有限公司 一种废催化裂化催化剂复活方法
CN114736714A (zh) * 2021-01-07 2022-07-12 国家能源投资集团有限责任公司 费托合成系统及其开工方法和费托合成催化剂的在线置换方法
CN113333011B (zh) * 2021-06-01 2023-11-17 中国科学院过程工程研究所 一种复合催化剂及其制备方法和应用
CN115518647B (zh) * 2021-06-24 2023-08-08 中国石油化工股份有限公司 一种固定床合成气生产低碳烯烃的催化剂及其制备方法和应用

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2369956A (en) 1936-10-06 1945-02-20 Feisst Walter Synthesis of multilink hydrocarbons from hydrogen and carbon monoxide
US2542558A (en) 1949-01-29 1951-02-20 Texas Co Regeneration of a cobalt oxo synthesis catalyst
US3839191A (en) 1969-03-25 1974-10-01 Total Energy Corp Hydrocracking of coal liquids
FR2036937B1 (es) 1969-04-18 1976-04-16 Inst Francais Du Petrole
US4191664A (en) 1975-06-16 1980-03-04 Union Oil Company Of California Thermally stable nickel-alumina catalysts useful for methanation and other reactions
US4088671A (en) 1976-03-19 1978-05-09 Gulf Research & Development Company Conversion of synthesis gas using a cobalt-ruthenium catalyst
US4413064A (en) 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
US4670414A (en) 1981-10-13 1987-06-02 Kobylinski Thaddeus P Activated cobalt catalyst and synthesis gas conversion using same
US4605679A (en) 1981-10-13 1986-08-12 Chevron Research Company Activated cobalt catalyst and synthesis gas conversion using same
EP0091238B1 (en) 1982-04-06 1986-11-12 LUCAS INDUSTRIES public limited company Secondary zinc electrode for a secondary electro-chemical cell and a method of manufacturing such an electrode
JPS5916884A (ja) 1982-07-19 1984-01-28 Fujisawa Pharmaceut Co Ltd 新規フラン化合物
GB8610442D0 (en) 1986-04-29 1986-06-04 Shell Int Research Regeneration of spent alumina-based catalysts
US4814066A (en) 1988-05-19 1989-03-21 Phillips Petroleum Company Reactivation of spent catalytic cracking catalyst
US4978689A (en) 1989-03-17 1990-12-18 Mobil Oil Corp. Conversion of synthesis gas to liquid hydrocarbons
US4954244A (en) 1989-06-22 1990-09-04 Phillips Petroleum Company Treatment of spent cracking catalysts
US4929336A (en) 1989-10-12 1990-05-29 Phillips Petroleum Company Treatment of spent cracking catalysts
GB9114314D0 (en) 1991-07-02 1991-08-21 British Petroleum Co Plc Catalyst treatment for fisher-tropsch process
MY109378A (en) 1992-08-18 1997-01-31 Shell Int Research Process for the preparation of a catalyst for a catalyst precursor
US5292705A (en) 1992-09-24 1994-03-08 Exxon Research & Engineering Co. Activation of hydrocarbon synthesis catalyst
US5495055A (en) 1994-08-12 1996-02-27 Arco Chemical Technology, L.P. Acetone hydrogenation using a supported ruthenium catalyst
EP1042067B1 (en) * 1997-12-30 2004-04-28 Shell Internationale Research Maatschappij B.V. Cobalt based fischer-tropsch catalyst
FR2782280B1 (fr) 1998-08-12 2000-09-22 Inst Francais Du Petrole Catalyseurs supportes utilisables dans des reactions de transformation de composes organiques
US6103184A (en) * 1999-09-13 2000-08-15 Heck; Philip Hand-held torch circle cutter
US6331574B1 (en) * 1999-10-08 2001-12-18 Exxonmobil Research And Engineering Company Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst compositions, use of the catalysts for conducting such reactions, and the products of such reactions
US6313062B1 (en) 1999-10-29 2001-11-06 Exxon Reserach And Engineering Company Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst composition, use of the catalysts for conducting such reactions, and the products of such reactions

Also Published As

Publication number Publication date
US20030144130A1 (en) 2003-07-31
JP4456873B2 (ja) 2010-04-28
DK1480743T3 (da) 2007-01-29
TW200302135A (en) 2003-08-01
ZA200404976B (en) 2006-02-22
EP1480743B1 (en) 2006-09-13
ATE339252T1 (de) 2006-10-15
JP2005516769A (ja) 2005-06-09
CN1625441A (zh) 2005-06-08
CA2472245C (en) 2010-09-28
US6753351B2 (en) 2004-06-22
AU2003217168A1 (en) 2003-09-04
ES2272958T3 (es) 2007-05-01
AU2003217168B2 (en) 2007-11-15
EP1480743A1 (en) 2004-12-01
TWI248834B (en) 2006-02-11
CN100490977C (zh) 2009-05-27
CA2472245A1 (en) 2003-08-21
DE60308329D1 (de) 2006-10-26
DE60308329T2 (de) 2007-09-06
WO2003068396A1 (en) 2003-08-21

Similar Documents

Publication Publication Date Title
AR038190A1 (es) Activacion de catalizador con soporte
Burch et al. The role of copper and zinc oxide in methanol synthesis catalysts
Figueiredo et al. The role of surface chemistry in catalysis with carbons
ES2192985B1 (es) Nuevo catalizador para la reduccion de no a n2 con hidrogeno en condiciones de nox oxidantes.
CO5650173A2 (es) Proceso catalitico para el tratamiento de compuestos organi- cos
DE69816450D1 (de) Reduktion von nitraten
EA200500981A1 (ru) Способ каталитического селективного окисления сернистых соединений
BR0309140A (pt) Processo para a remoção de óxidos de nitrogênio
ATE246535T1 (de) Verfahren und vorrichtung zur selektiven katalytischen reduktion von stickoxiden in einem sauerstoffhaltigen gasförmigen medium
CO4410234A1 (es) Proceso para la preparacion de monoxido de carbono y/o hidrogeno
DE60315424D1 (de) Verfahren zur verbesserung eines katalysators
AR038134A1 (es) Regeneracion de catalizador soportado
MY117932A (en) Process for increasing cobalt catalyst hydrogenation activity via aqueous low temperature oxidation
Boyano et al. Carbon-based catalytic briquettes for the reduction of NO: Effect of H2SO4 and HNO3 carbon support treatment
DE60213476D1 (de) Trägerkatalysatorbehandlung
Bansal et al. Studies on ultra-clean carbon surfaces—IV. Decomposition of carbon-oxygen surface complexes
KR102032387B1 (ko) 개질된 활성탄을 포함하는 이산화탄소 흡수제 재생용 촉매, 이의 제조방법 및 이를 이용하여 이산화탄소를 포집하는 방법
CN107413350A (zh) 混合稀土脱硝催化剂及其制备方法
GB979381A (en) Catalytic oxidation
GB1381370A (en) Process for removing nitrogen oxides from exhaust gases
RU2005130340A (ru) Способ хранения водорода путем осущестления каталитических реакций гидрирования-дегидрирования ароматических субстратов под воздействием свч (вч) излучения
GB944207A (en) Catalyst for removing oxygen from gaseous mixtures
JPWO2019181681A1 (ja) 構造体触媒の製造方法、および構造体触媒を用いた水素製造方法
AR029961A1 (es) Un reactor que comprende una capa consolidada de catalizador soportado o precursor de catalizador soportado, un uso del reactor y una capa consolidada de catalizador soportado o precursor de catalizador soportado
Tetelman Recent developments in classical/internal/ hydrogen embrittlement

Legal Events

Date Code Title Description
FB Suspension of granting procedure