AR030339A1 - Proceso para preparar alquilarilsulfonatos - Google Patents
Proceso para preparar alquilarilsulfonatosInfo
- Publication number
- AR030339A1 AR030339A1 ARP010103834A ARP010103834A AR030339A1 AR 030339 A1 AR030339 A1 AR 030339A1 AR P010103834 A ARP010103834 A AR P010103834A AR P010103834 A ARP010103834 A AR P010103834A AR 030339 A1 AR030339 A1 AR 030339A1
- Authority
- AR
- Argentina
- Prior art keywords
- olefins
- alkylarylsulfonates
- mixture
- pentene
- hexene
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 6
- 150000001336 alkenes Chemical class 0.000 abstract 9
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 abstract 6
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 4
- ZQDPJFUHLCOCRG-UHFFFAOYSA-N 3-hexene Chemical compound CCC=CCC ZQDPJFUHLCOCRG-UHFFFAOYSA-N 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 230000029936 alkylation Effects 0.000 abstract 2
- 238000005804 alkylation reaction Methods 0.000 abstract 2
- 239000003599 detergent Substances 0.000 abstract 2
- 238000006471 dimerization reaction Methods 0.000 abstract 2
- 238000006277 sulfonation reaction Methods 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000005649 metathesis reaction Methods 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/32—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
Abstract
Se refiere a un proceso para preparar alquilarilsulfonatos por: a) reaccion de una mezcla de olefinas C4 a través de un catalizador de metátesis para preparar una mezcla de olefinas que comprende un 2-penteno y/o 3-hexeno, y la eliminacion opcional del 2-penteno y/o 3-hexeno; b) dimerizacion del 2-penteno y/o 3-hexeno obtenido en la etapa a) a través de un catalizador de dimerizacion para obtener una mezcla que contiene olefinas C10-12, y la eliminacion opcional de las olefinas C10-12; c) reaccion de las mezclas de olefinas C10-12 obtenidas en la etapa b) con un hidrocarburo aromático en presencia de un catalizador de alquilacion para formar compuestos alquilaromáticos, donde previo a la reaccion se puede agregar olefinas lineales adicionales; d) sulfonacion de compuestos alquilaromáticos obtenidos en la etapa c) y neutralizacion para obtener alquilarilsulfonatos, donde previo a la sulfonacion se pueden agregar adicionalmente alquilbencenos lineales; e)mezcla opcional de alquilarilsulfonatos obtenidas en la etapa d) con alquilarilsulfonatos lineales. Un alquilarilo de utilidad como intermediario que puede obtenerse en el proceso descripto. Un alquilarilsulfonato que puede obtenerse mediante dicho proceso y su uso como surfactante, preferentemente, en detergentes y limpiadores. Un detergente o limpiador que comprende, además de los ingredientes habituales, un alquilarilsulfonato como el descripto. Un proceso donde las olefinas obtenidas en la etapa b) tienen una proporcion de olefinas no ramificadas inferior al 25% en peso. Un proceso donde al menos el 80% de las olefinas obtenidas en la etapa b) tienen una ramificacion o dos ramificaciones en átomos de carbono adyacentes en el rango que va de 1/4 a 3/4 preferentemente de 1/3 a 2/3, de la longitud de cadena de su cadena principal. Un proceso donde, en la etapa c), se usa un catalizador de alquilacion que conduce a compuestos alquilaromáticos que en el radical alquilo tienen C1-3 con un índice H/C de 1.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10039995A DE10039995A1 (de) | 2000-08-11 | 2000-08-11 | Verfahren zur Herstellung von Alkylarylsulfonaten |
Publications (1)
Publication Number | Publication Date |
---|---|
AR030339A1 true AR030339A1 (es) | 2003-08-20 |
Family
ID=7652598
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP010103834A AR030339A1 (es) | 2000-08-11 | 2001-08-10 | Proceso para preparar alquilarilsulfonatos |
Country Status (21)
Country | Link |
---|---|
US (2) | US7060852B2 (es) |
EP (1) | EP1309545B1 (es) |
JP (1) | JP2004506036A (es) |
KR (1) | KR100809503B1 (es) |
CN (1) | CN100334073C (es) |
AR (1) | AR030339A1 (es) |
AT (1) | ATE370930T1 (es) |
AU (1) | AU2001287678A1 (es) |
BR (1) | BR0113152A (es) |
CA (1) | CA2417820C (es) |
CY (1) | CY1107798T1 (es) |
DE (2) | DE10039995A1 (es) |
DK (1) | DK1309545T3 (es) |
ES (1) | ES2290165T3 (es) |
MX (1) | MXPA03001159A (es) |
MY (1) | MY134963A (es) |
PT (1) | PT1309545E (es) |
RU (1) | RU2312099C2 (es) |
TW (1) | TWI292754B (es) |
WO (1) | WO2002014266A1 (es) |
ZA (1) | ZA200301090B (es) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10059398A1 (de) * | 2000-11-30 | 2002-06-13 | Basf Ag | Verfahren zur Herstellung von Alkylarylsulfonaten |
MY139380A (en) | 2001-10-01 | 2009-09-30 | Basf Ag | Process for the preparation of alkylaryl compounds and sulfonates thereof |
DE10248002A1 (de) * | 2002-10-15 | 2004-04-29 | Basf Ag | Verfahren zur Herstellung von Alkylarylsulfonaten |
DE10261481A1 (de) * | 2002-12-23 | 2004-07-01 | Basf Ag | Verfahren zur Herstellung von Alkylarylsulfonaten mittels modifizierter, dimerisierter Olefine |
DE10317294A1 (de) | 2003-04-15 | 2004-10-28 | Basf Ag | Verfahren zur Herstellung von alkylaromatischen Verbindungen |
DE10350333A1 (de) | 2003-10-29 | 2005-05-25 | Basf Ag | Verfahren zur Herstellung von Alkylarylverbindungen und Sulfonaten davon |
DE10360026A1 (de) * | 2003-12-19 | 2005-07-21 | Basf Ag | Verfahren zur Herstellung von Alkylaryl-Verbindungen |
US6977319B2 (en) * | 2004-03-12 | 2005-12-20 | Chevron Oronite Company Llc | Alkylated aromatic compositions, zeolite catalyst compositions and processes for making the same |
DE102004049940A1 (de) | 2004-10-13 | 2006-04-20 | Basf Ag | Verfahren zur Herstellung eines C4-Olefin-Gemisches durch Selektivhydrierung und Metatheseverfahren zur Verwendung dieses Stroms |
US20080114127A1 (en) * | 2005-04-25 | 2008-05-15 | Dieter Freitag | Method for producing branched polyphosphonates with narrow molecular weight distributions |
US20070043247A1 (en) * | 2005-08-19 | 2007-02-22 | Webber Kenneth M | Diisobutylene production |
US7449596B2 (en) * | 2005-12-21 | 2008-11-11 | Chevron Oronite Company Llc | Method of making a synthetic petroleum sulfonate |
US7598414B2 (en) * | 2006-06-01 | 2009-10-06 | Chevron Oronite Company Llc | Method of making a synthetic alkylaryl sulfonate |
US20080139840A1 (en) * | 2006-11-03 | 2008-06-12 | Matthew Thomas Anderson | Process for preparing alkyl aryl sulphonic acids and alkyl aryl sulphonates |
EP1932481B1 (en) * | 2006-12-13 | 2010-06-30 | Ethicon Endo-Surgery, Inc. | Biopsy system with vacuum control module |
US7525006B2 (en) * | 2007-05-23 | 2009-04-28 | Uop Llc | Process for producing cumene |
US7713386B2 (en) * | 2007-05-23 | 2010-05-11 | Uop Llc | Apparatus for producing ethylbenzene or cumene |
US7498472B2 (en) * | 2007-05-23 | 2009-03-03 | Uop Llc | Process for producing ethylbenzene |
US7498471B2 (en) * | 2007-05-23 | 2009-03-03 | Uop Llc | Process for producing cumene |
US7525003B2 (en) * | 2007-05-23 | 2009-04-28 | Uop Llc | Process for producing ethylbenzene |
US7525005B2 (en) * | 2007-05-23 | 2009-04-28 | Uop Llc | Process for producing cumene |
US7525004B2 (en) * | 2007-05-23 | 2009-04-28 | Uop Llc | Process for producing ethylbenzene |
FI121531B (fi) * | 2007-07-23 | 2010-12-31 | Ecocat Oy | Katalyytti poiste- tai prosessikaasuissa olevien haitallisten hiilivetyjen poistamiseksi sekä menetelmä tällaisen katalyytin valmistamiseksi ja käyttämiseksi |
US8350106B2 (en) * | 2008-06-30 | 2013-01-08 | Uop Llc | Selective hydrogenation of unsaturated aliphatic hydrocarbons in predominantly aromatic streams |
US9382350B2 (en) | 2012-09-24 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Friedel crafts alkylation of aromatics using vinyl terminated macromonomers |
US9758445B2 (en) | 2013-04-09 | 2017-09-12 | Materia, Inc. | Preparation of surfactants via cross-metathesis |
CA2908383A1 (en) | 2013-04-09 | 2014-10-16 | Materia, Inc. | Preparation of surfactants via cross-metathesis |
US9663440B2 (en) | 2013-04-09 | 2017-05-30 | Materia, Inc. | Cross metathesis of poly-branched poly-olefins |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3351654A (en) * | 1961-05-19 | 1967-11-07 | Exxon Research Engineering Co | Process of preparing biodegradable alkylbenzene sulfonates by dimerizing an olefin of 5 to 10 carbon atoms with a silica-alumina catalyst |
NL293486A (es) * | 1962-06-01 | |||
BE672383A (es) * | 1963-07-22 | |||
GB1078572A (en) * | 1964-01-17 | 1967-08-09 | British Hydrocarbon Chem Ltd | Improvements relating to the production of detergent alkylate |
US3410925A (en) * | 1964-05-14 | 1968-11-12 | Continental Oil Co | Dimerization of c3 to c18 olefins |
US4959491A (en) * | 1987-03-11 | 1990-09-25 | Chevron Research Company | Detergent grade olefins, alkylbenzenes and alkylbenzene sulfonates and processes for preparing |
US5026933A (en) * | 1987-10-07 | 1991-06-25 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
US4962249A (en) * | 1988-06-23 | 1990-10-09 | Mobil Oil Corporation | High VI lubricants from lower alkene oligomers |
US5057638A (en) * | 1990-06-22 | 1991-10-15 | Chevron Research And Technology Company | Process for making 1-hexene from 1-butene |
US5344997A (en) * | 1991-12-23 | 1994-09-06 | Uop | Alkylation of aromatics using a fluorided silica-alumina catalyst |
FR2733986B1 (fr) * | 1995-05-11 | 1997-06-13 | Inst Francais Du Petrole | Procede et installation pour la conversion de coupes c4 olefiniques en polyisobutenes et en propylene |
AU8124498A (en) * | 1997-07-21 | 1999-02-16 | Procter & Gamble Company, The | Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof |
KR100391190B1 (ko) * | 1997-07-21 | 2003-07-12 | 더 프록터 앤드 갬블 캄파니 | 개선된 알킬벤젠설포네이트 계면활성제 |
TR200000362T2 (tr) * | 1997-08-08 | 2000-07-21 | The Procter & Gamble Company | Yüzermeyle ayırma yoluyla sürfaktanların yapımı için geliştirilmiş işlemler ve bu işlemlerin ürünleri. |
DE69828989T2 (de) * | 1997-10-14 | 2006-03-30 | The Procter & Gamble Co., Cincinnati | Flüssige oder gelförmige spülmittelzusammensetzungen enthaltend in der mitte der kette verzweigte tenside |
DE10013253A1 (de) * | 2000-03-17 | 2001-09-20 | Basf Ag | Verfahren zur flexiblen Herstellung von Propen und Hexen |
-
2000
- 2000-08-11 DE DE10039995A patent/DE10039995A1/de not_active Withdrawn
-
2001
- 2001-08-10 DE DE50112916T patent/DE50112916D1/de not_active Expired - Lifetime
- 2001-08-10 ES ES01967262T patent/ES2290165T3/es not_active Expired - Lifetime
- 2001-08-10 AT AT01967262T patent/ATE370930T1/de not_active IP Right Cessation
- 2001-08-10 BR BR0113152-4A patent/BR0113152A/pt not_active Application Discontinuation
- 2001-08-10 US US10/343,835 patent/US7060852B2/en not_active Expired - Fee Related
- 2001-08-10 JP JP2002519411A patent/JP2004506036A/ja not_active Withdrawn
- 2001-08-10 PT PT01967262T patent/PT1309545E/pt unknown
- 2001-08-10 DK DK01967262T patent/DK1309545T3/da active
- 2001-08-10 AR ARP010103834A patent/AR030339A1/es unknown
- 2001-08-10 KR KR1020037001987A patent/KR100809503B1/ko not_active IP Right Cessation
- 2001-08-10 RU RU2003106706/04A patent/RU2312099C2/ru not_active IP Right Cessation
- 2001-08-10 TW TW090119633A patent/TWI292754B/zh active
- 2001-08-10 MY MYPI20013767A patent/MY134963A/en unknown
- 2001-08-10 MX MXPA03001159A patent/MXPA03001159A/es active IP Right Grant
- 2001-08-10 AU AU2001287678A patent/AU2001287678A1/en not_active Abandoned
- 2001-08-10 CA CA002417820A patent/CA2417820C/en not_active Expired - Fee Related
- 2001-08-10 WO PCT/EP2001/009297 patent/WO2002014266A1/de active IP Right Grant
- 2001-08-10 CN CNB018154263A patent/CN100334073C/zh not_active Expired - Fee Related
- 2001-08-10 EP EP01967262A patent/EP1309545B1/de not_active Expired - Lifetime
-
2003
- 2003-02-10 ZA ZA200301090A patent/ZA200301090B/en unknown
-
2006
- 2006-03-22 US US11/385,773 patent/US20060167308A1/en not_active Abandoned
-
2007
- 2007-11-12 CY CY20071101460T patent/CY1107798T1/el unknown
Also Published As
Publication number | Publication date |
---|---|
CA2417820C (en) | 2009-11-03 |
ATE370930T1 (de) | 2007-09-15 |
EP1309545B1 (de) | 2007-08-22 |
US7060852B2 (en) | 2006-06-13 |
CN100334073C (zh) | 2007-08-29 |
CY1107798T1 (el) | 2013-06-19 |
WO2002014266A1 (de) | 2002-02-21 |
US20060167308A1 (en) | 2006-07-27 |
PT1309545E (pt) | 2007-09-11 |
KR20030059098A (ko) | 2003-07-07 |
AU2001287678A1 (en) | 2002-02-25 |
BR0113152A (pt) | 2003-07-08 |
CA2417820A1 (en) | 2003-01-30 |
US20040010161A1 (en) | 2004-01-15 |
KR100809503B1 (ko) | 2008-03-04 |
MY134963A (en) | 2008-01-31 |
DK1309545T3 (da) | 2007-10-29 |
ZA200301090B (en) | 2004-03-04 |
DE50112916D1 (de) | 2007-10-04 |
TWI292754B (en) | 2008-01-21 |
EP1309545A1 (de) | 2003-05-14 |
ES2290165T3 (es) | 2008-02-16 |
RU2312099C2 (ru) | 2007-12-10 |
JP2004506036A (ja) | 2004-02-26 |
MXPA03001159A (es) | 2003-06-30 |
CN1454208A (zh) | 2003-11-05 |
DE10039995A1 (de) | 2002-02-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FB | Suspension of granting procedure |