AR042666A1 - Procedimiento para preparar alquilarilsulfonatos e intermediarios de los mismos por medio de olefinas dimerizadas modificadas - Google Patents
Procedimiento para preparar alquilarilsulfonatos e intermediarios de los mismos por medio de olefinas dimerizadas modificadasInfo
- Publication number
- AR042666A1 AR042666A1 ARP030104817A ARP030104817A AR042666A1 AR 042666 A1 AR042666 A1 AR 042666A1 AR P030104817 A ARP030104817 A AR P030104817A AR P030104817 A ARP030104817 A AR P030104817A AR 042666 A1 AR042666 A1 AR 042666A1
- Authority
- AR
- Argentina
- Prior art keywords
- olefins
- alkylarylsulfonates
- weight
- prepare
- pentene
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 title 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 abstract 6
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- ZQDPJFUHLCOCRG-UHFFFAOYSA-N 3-hexene Chemical compound CCC=CCC ZQDPJFUHLCOCRG-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 238000006471 dimerization reaction Methods 0.000 abstract 2
- 238000006277 sulfonation reaction Methods 0.000 abstract 2
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 1
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000005649 metathesis reaction Methods 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/32—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of salts of sulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Detergent Compositions (AREA)
Abstract
Obtención de alquilarilsulfonatos y su uso como tensioactivos y un detergente o agente de limpieza que los comprende. Reivindicación 1: Un procedimiento para preparar alquilarilsulfonatos por: a) reacción de una mezcla de olefinas C4 sobre un catalizador de metátesis para preparar una mezcla olefínica que comprende 2-penteno y/o 3-hexeno, y eliminación opcional del 2-penteno y/o 3-hexeno; b) dimerización del 2-penteno y/o 3-hexeno obtenidos en la etapa a) en presencia de un catalizador de dimerización para obtener una mezcla que comprende olefinas C10-12, eliminación de las olefinas C10-12 y eliminación del 5 al 30% en peso, en base a las olefinas C10-12 eliminada, de constituyentes de bajo punto de ebullición de las olefinas C10-12; c) reacción de las mezclas de olefinas C10-12 obtenidas en la etapa b) con un hidrocarburo aromático en presencia de un catalizador de alquilación para formar compuestos alquilaromáticos, donde, antes de la reacción, puede agregarse en forma adicional 0 al 60% en peso, en base a las mezclas de olefinas C10-12 obtenidas en la etapa b), de olefinas lineales; d) sulfonación de los compuestos alquilaromáticos obtenidos en la etapa c) y neutralización para obtener alquilarilsulfonatos, donde, de la sulfonación, puede agregarse en forma adicional 0 al 60% en peso, en base a los compuestos alquilaromáticos obtenidos en la etapa c), de alquilbencenos lineales, si no tuvo lugar ninguna adición en la etapa c); e) mezcla opcional de los alquilarilsulfonatos obtenidos en la etapa d) con 0 al 60% en peso, en base a los alquilarilsulfonatos obtenidos en la etapa d), de alquilarilsulfonatos lineales, si no tuvo lugar ninguna adición en las etapas c) y d).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10261481A DE10261481A1 (de) | 2002-12-23 | 2002-12-23 | Verfahren zur Herstellung von Alkylarylsulfonaten mittels modifizierter, dimerisierter Olefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR042666A1 true AR042666A1 (es) | 2005-06-29 |
Family
ID=32404344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP030104817A AR042666A1 (es) | 2002-12-23 | 2003-12-23 | Procedimiento para preparar alquilarilsulfonatos e intermediarios de los mismos por medio de olefinas dimerizadas modificadas |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US20060052630A1 (es) |
| EP (1) | EP1581485B1 (es) |
| JP (1) | JP4307389B2 (es) |
| KR (1) | KR20050088137A (es) |
| CN (1) | CN1296352C (es) |
| AR (1) | AR042666A1 (es) |
| AT (1) | ATE357430T1 (es) |
| AU (1) | AU2003300221A1 (es) |
| BR (1) | BR0317634A (es) |
| CA (1) | CA2511184A1 (es) |
| DE (2) | DE10261481A1 (es) |
| ES (1) | ES2283873T3 (es) |
| MX (1) | MXPA05005936A (es) |
| MY (1) | MY135566A (es) |
| RU (1) | RU2005123322A (es) |
| WO (1) | WO2004058692A1 (es) |
| ZA (1) | ZA200505050B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7598414B2 (en) * | 2006-06-01 | 2009-10-06 | Chevron Oronite Company Llc | Method of making a synthetic alkylaryl sulfonate |
| US7713386B2 (en) * | 2007-05-23 | 2010-05-11 | Uop Llc | Apparatus for producing ethylbenzene or cumene |
| US7525004B2 (en) * | 2007-05-23 | 2009-04-28 | Uop Llc | Process for producing ethylbenzene |
| US7525005B2 (en) * | 2007-05-23 | 2009-04-28 | Uop Llc | Process for producing cumene |
| US7525006B2 (en) * | 2007-05-23 | 2009-04-28 | Uop Llc | Process for producing cumene |
| US7498471B2 (en) * | 2007-05-23 | 2009-03-03 | Uop Llc | Process for producing cumene |
| US7498472B2 (en) * | 2007-05-23 | 2009-03-03 | Uop Llc | Process for producing ethylbenzene |
| US7525003B2 (en) * | 2007-05-23 | 2009-04-28 | Uop Llc | Process for producing ethylbenzene |
| EP2459784B1 (en) * | 2009-07-27 | 2013-05-01 | DSM IP Assets B.V. | Polyolefin member and method of manufacturing by using an antifoaming agent |
| CN102703050A (zh) * | 2012-05-28 | 2012-10-03 | 西南石油大学 | 一种四聚磺酸盐型表面活性剂及其制备方法 |
| EP3986847A1 (en) | 2019-06-20 | 2022-04-27 | ExxonMobil Chemical Patents Inc. | Amphiphilic reaction products from vinylidene olefins and methods for production thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10039995A1 (de) * | 2000-08-11 | 2002-02-21 | Basf Ag | Verfahren zur Herstellung von Alkylarylsulfonaten |
-
2002
- 2002-12-23 DE DE10261481A patent/DE10261481A1/de not_active Withdrawn
-
2003
- 2003-12-22 AU AU2003300221A patent/AU2003300221A1/en not_active Abandoned
- 2003-12-22 MY MYPI20034950A patent/MY135566A/en unknown
- 2003-12-22 DE DE50306876T patent/DE50306876D1/de not_active Expired - Fee Related
- 2003-12-22 AT AT03799498T patent/ATE357430T1/de not_active IP Right Cessation
- 2003-12-22 RU RU2005123322/04A patent/RU2005123322A/ru not_active Application Discontinuation
- 2003-12-22 KR KR1020057011772A patent/KR20050088137A/ko not_active Application Discontinuation
- 2003-12-22 CN CNB2003801073601A patent/CN1296352C/zh not_active Expired - Fee Related
- 2003-12-22 MX MXPA05005936A patent/MXPA05005936A/es active IP Right Grant
- 2003-12-22 CA CA002511184A patent/CA2511184A1/en not_active Abandoned
- 2003-12-22 EP EP03799498A patent/EP1581485B1/de not_active Expired - Lifetime
- 2003-12-22 US US10/538,473 patent/US20060052630A1/en not_active Abandoned
- 2003-12-22 ES ES03799498T patent/ES2283873T3/es not_active Expired - Lifetime
- 2003-12-22 BR BR0317634-7A patent/BR0317634A/pt not_active IP Right Cessation
- 2003-12-22 JP JP2004562814A patent/JP4307389B2/ja not_active Expired - Fee Related
- 2003-12-22 WO PCT/EP2003/014712 patent/WO2004058692A1/de active IP Right Grant
- 2003-12-23 AR ARP030104817A patent/AR042666A1/es unknown
-
2005
- 2005-06-22 ZA ZA200505050A patent/ZA200505050B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20060052630A1 (en) | 2006-03-09 |
| JP4307389B2 (ja) | 2009-08-05 |
| JP2006511578A (ja) | 2006-04-06 |
| DE50306876D1 (de) | 2007-05-03 |
| CN1732150A (zh) | 2006-02-08 |
| ZA200505050B (en) | 2006-09-27 |
| ATE357430T1 (de) | 2007-04-15 |
| MY135566A (en) | 2008-05-30 |
| WO2004058692A1 (de) | 2004-07-15 |
| MXPA05005936A (es) | 2005-08-18 |
| AU2003300221A1 (en) | 2004-07-22 |
| CN1296352C (zh) | 2007-01-24 |
| EP1581485B1 (de) | 2007-03-21 |
| BR0317634A (pt) | 2005-11-29 |
| RU2005123322A (ru) | 2006-01-27 |
| EP1581485A1 (de) | 2005-10-05 |
| DE10261481A1 (de) | 2004-07-01 |
| KR20050088137A (ko) | 2005-09-01 |
| ES2283873T3 (es) | 2007-11-01 |
| CA2511184A1 (en) | 2004-07-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |