AR029294A1 - Produccion de alquilaromaticos - Google Patents
Produccion de alquilaromaticosInfo
- Publication number
- AR029294A1 AR029294A1 ARP010103087A ARP010103087A AR029294A1 AR 029294 A1 AR029294 A1 AR 029294A1 AR P010103087 A ARP010103087 A AR P010103087A AR P010103087 A ARP010103087 A AR P010103087A AR 029294 A1 AR029294 A1 AR 029294A1
- Authority
- AR
- Argentina
- Prior art keywords
- aromatic compound
- molecular sieves
- transalkylation catalyst
- zeolite
- alquilaromaticos
- Prior art date
Links
- 150000001491 aromatic compounds Chemical class 0.000 abstract 4
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000002808 molecular sieve Substances 0.000 abstract 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 2
- 238000010555 transalkylation reaction Methods 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- -1 cumene Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052680 mordenite Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/02—Monocyclic hydrocarbons
- C07C15/085—Isopropylbenzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/80—Mixtures of different zeolites
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un proceso para producir un compuesto aromático monoalquilado, particularmente cumeno, que comprende la etapa de poner en contacto un compuesto aromático polialquilado con un compuesto aromático alquilable bajo condiciones de fase por lo menos parcialmente líquida y en la presencia de un catalizador de transalquilacion para producir el compuesto aromático monoalquilado, donde el catalizador de transalquilacion comprende una mezcla de por lo menos dos tamices moleculares cristalinos diferentes, donde cada uno de dichos tamices moleculares es seleccionado entre zeolita beta, zeolita Y, mordenita y un material que tiene un patron de difraccion de rayos û X que incluye máximos de espaciamientos d a 12, 4 + o - 0,25, 6,9 + o - , 0,15, 3,57 + o û 0,07 y 3,42 + o û 0,07 Angstrom.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/619,560 US6936744B1 (en) | 2000-07-19 | 2000-07-19 | Alkylaromatics production |
Publications (1)
Publication Number | Publication Date |
---|---|
AR029294A1 true AR029294A1 (es) | 2003-06-18 |
Family
ID=24482401
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP010103087A AR029294A1 (es) | 2000-07-19 | 2001-06-28 | Produccion de alquilaromaticos |
Country Status (17)
Country | Link |
---|---|
US (1) | US6936744B1 (es) |
EP (1) | EP1218324B1 (es) |
JP (1) | JP4726387B2 (es) |
KR (1) | KR100734689B1 (es) |
CN (1) | CN1211324C (es) |
AR (1) | AR029294A1 (es) |
AT (1) | ATE264284T1 (es) |
AU (1) | AU7159101A (es) |
BR (1) | BR0106981A (es) |
CA (1) | CA2385243A1 (es) |
CZ (1) | CZ2002958A3 (es) |
DE (1) | DE60102784T2 (es) |
ES (1) | ES2217166T3 (es) |
FI (1) | FI20020503A (es) |
MX (1) | MXPA02002766A (es) |
TW (1) | TWI243815B (es) |
WO (1) | WO2002008159A1 (es) |
Families Citing this family (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7148391B1 (en) | 2002-11-14 | 2006-12-12 | Exxonmobil Chemical Patents Inc. | Heavy aromatics processing |
US7553791B2 (en) | 2002-11-14 | 2009-06-30 | Exxonmobil Chemical Patents Inc. | Heavy aromatics conversion catalyst composition and processes therefor and therewith |
CA2603674C (en) | 2005-03-31 | 2011-07-26 | Exxonmobil Chemical Patents Inc. | Process and catalyst for the transalkylation of aromatics |
US20070161837A1 (en) * | 2006-01-07 | 2007-07-12 | Fina Technology, Inc. | Zeolitic transalkylation with aluminum chloride alkylation |
EP1996323B1 (en) * | 2006-02-14 | 2016-07-13 | ExxonMobil Chemical Patents Inc. | Process for manufacturing molecular sieve of mfs framework type and its use |
JP5537813B2 (ja) * | 2006-02-14 | 2014-07-02 | エクソンモービル・ケミカル・パテンツ・インク | Mcm−22型モレキュラーシーブの製造方法 |
US8859836B2 (en) | 2006-02-14 | 2014-10-14 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process using molecular sieve of MFS framework type |
EP1996327A1 (en) * | 2006-02-14 | 2008-12-03 | ExxonMobil Chemical Patents Inc. | A molecular sieve composition |
EP1996328B1 (en) * | 2006-02-14 | 2016-07-13 | ExxonMobil Chemical Patents Inc. | Method of preparing a molecular sieve composition |
US7846418B2 (en) * | 2006-02-14 | 2010-12-07 | Exxonmobil Chemical Patents Inc. | MCM-22 family molecular sieve composition |
JP4934684B2 (ja) | 2006-02-14 | 2012-05-16 | エクソンモービル・ケミカル・パテンツ・インク | 高生産性のモレキュラーシーブの製造方法 |
US7732651B2 (en) * | 2006-06-01 | 2010-06-08 | Chevron Oronite Company, Llc | Method of making an alkylated aromoatic using acidic ionic liquid catalyst |
WO2008013639A1 (en) | 2006-07-28 | 2008-01-31 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (emm-10-p), its method of making, and use for hydrocarbon conversions |
US7959899B2 (en) * | 2006-07-28 | 2011-06-14 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions |
JP5571950B2 (ja) | 2006-07-28 | 2014-08-13 | エクソンモービル・ケミカル・パテンツ・インク | モレキュラーシーブ組成物(emm−10)とその製造方法、およびこの組成物を用いた炭化水素の転換方法 |
US7883686B2 (en) * | 2006-07-28 | 2011-02-08 | Exxonmobil Chemical Patents Inc. | MCM-22 family molecular sieve composition, its method of making, and use for hydrocarbon conversions |
US7420098B2 (en) * | 2007-01-12 | 2008-09-02 | Uop Llc | Dual zone aromatic alkylation process |
WO2008097737A1 (en) | 2007-02-09 | 2008-08-14 | Exxonmobil Chemical Patents Inc. A Corporation Of The State Of Delaware | Improved alkylaromatic production process |
US7737314B2 (en) | 2007-02-12 | 2010-06-15 | Exxonmobil Chemical Patents Inc. | Production of high purity ethylbenzene from non-extracted feed and non-extracted reformate useful therein |
US8816145B2 (en) | 2007-06-21 | 2014-08-26 | Exxonmobil Chemical Patents Inc. | Liquid phase alkylation process |
US7790940B2 (en) | 2007-06-21 | 2010-09-07 | Exxonmobil Chemical Patents Inc. | Liquid phase alkylation process |
EP2176200B1 (en) * | 2007-08-25 | 2011-09-07 | ExxonMobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
US7906685B2 (en) * | 2007-09-21 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
WO2009038900A1 (en) * | 2007-09-21 | 2009-03-26 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
WO2009055216A2 (en) | 2007-10-26 | 2009-04-30 | Exxonmobil Chemical Patents Inc. | Method of preparing a molecular sieve composition |
PL2217374T3 (pl) * | 2007-11-02 | 2022-08-08 | Badger Licensing, Llc | Proces odmładzania kompozycji katalizatora |
JP5348803B2 (ja) * | 2007-11-16 | 2013-11-20 | エクソンモービル・ケミカル・パテンツ・インク | 触媒再生方法 |
KR101123499B1 (ko) * | 2008-02-12 | 2012-06-12 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 사이클로헥실벤젠의 제조방법 |
WO2009128984A1 (en) | 2008-04-14 | 2009-10-22 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
WO2009134516A1 (en) * | 2008-05-01 | 2009-11-05 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
US8586496B2 (en) * | 2008-07-22 | 2013-11-19 | Exxonmobil Chemical Patents Inc. | Preparation of molecular sieve catalysts and their use in the production of alkylaromatic hydrocarbons |
US8704023B2 (en) * | 2008-07-28 | 2014-04-22 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition EMM-13, a method of making and a process of using the same |
JP5476379B2 (ja) * | 2008-07-28 | 2014-04-23 | エクソンモービル・ケミカル・パテンツ・インク | 新規なモレキュラーシーブ組成物emm−12、その製造方法およびその使用プロセス |
CA2729174C (en) | 2008-07-28 | 2013-07-02 | Exxonmobil Chemical Patents Inc. | Process of making alkylaromatics using emm-12 |
US8217213B2 (en) * | 2008-07-28 | 2012-07-10 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using EMM-12 |
US8212096B2 (en) | 2008-07-28 | 2012-07-03 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using EMM-13 |
EP2331465B1 (en) * | 2008-07-28 | 2018-08-29 | ExxonMobil Chemical Patents Inc. | Process of making alkylaromatics using emm-13 |
EP2411351A4 (en) | 2009-02-26 | 2012-09-12 | Exxonmobil Chem Patents Inc | PROCESS FOR PREPARING CYCLOHEXYLBENZENE |
US9150469B2 (en) * | 2009-05-18 | 2015-10-06 | Uop Llc | Aromatic alkylation process with reduced byproduct formation |
US8163966B2 (en) * | 2009-11-30 | 2012-04-24 | Exxonmobil Chemical Patents Inc. | Aromatics processing catalyst system |
US9545622B2 (en) | 2010-10-11 | 2017-01-17 | Exxonmobil Chemical Patents Inc. | Activation and use of hydroalkylation catalysts |
CN103827033B (zh) * | 2011-09-16 | 2016-05-11 | 埃克森美孚化学专利公司 | 改进的mcm-56制造方法 |
KR101701578B1 (ko) * | 2011-09-16 | 2017-02-01 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 개선된 액체상 알킬화 방법 |
US9108893B2 (en) | 2011-10-17 | 2015-08-18 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
EP2812297A1 (en) | 2012-02-08 | 2014-12-17 | ExxonMobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
KR102527695B1 (ko) * | 2015-02-04 | 2023-04-28 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 분자체의 제조 방법 |
US10118165B2 (en) | 2015-02-04 | 2018-11-06 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and use in heavy aromatics conversion processes |
US10053403B2 (en) | 2015-02-04 | 2018-08-21 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes |
CN108779046A (zh) * | 2016-03-28 | 2018-11-09 | 埃克森美孚化学专利公司 | 芳族流体的烷基转移方法 |
KR102252012B1 (ko) | 2016-10-04 | 2021-05-17 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 중질 방향족 탄화수소의 불균화 및 알킬교환 |
US20200385322A1 (en) * | 2017-01-25 | 2020-12-10 | Exxonmobil Chemical Patents Inc. | Transalkylation Process and Catalyst Composition Used Therein |
WO2021076260A1 (en) * | 2019-10-17 | 2021-04-22 | Exxonmobil Chemical Patents Inc. | Production of alkylaromatic compounds |
US11820723B2 (en) * | 2019-10-17 | 2023-11-21 | Exxonmobil Chemicals Patents Inc. | Production of alkylaromatic compounds |
US11975981B2 (en) | 2022-03-02 | 2024-05-07 | Sogang University Research & Business Development Foundation | MWW-type zeolite with macroscale hollow structure |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL6503410A (es) | 1963-02-21 | 1965-09-20 | ||
US3308069A (en) | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
US3385906A (en) * | 1965-05-25 | 1968-05-28 | Union Carbide Corp | Production of cumene |
US3766093A (en) | 1972-01-07 | 1973-10-16 | Mobil Oil Corp | Treatment of organic cationcontaining zeolites |
US3751504A (en) | 1972-05-12 | 1973-08-07 | Mobil Oil Corp | Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation |
US3894104A (en) | 1973-08-09 | 1975-07-08 | Mobil Oil Corp | Aromatization of hetero-atom substituted hydrocarbons |
US4016218A (en) | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
US4459426A (en) * | 1980-04-25 | 1984-07-10 | Union Oil Company Of California | Liquid-phase alkylation and transalkylation process |
DE3117135A1 (de) | 1981-04-30 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe |
US4415438A (en) | 1981-11-24 | 1983-11-15 | Dean Robert R | Method for catalytically converting residual oils |
US4547605A (en) | 1983-09-28 | 1985-10-15 | Mobil Oil Corporation | Catalyst for alkylation of aromatic hydrocarbons |
US4826667A (en) | 1986-01-29 | 1989-05-02 | Chevron Research Company | Zeolite SSZ-25 |
US4954325A (en) | 1986-07-29 | 1990-09-04 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis and use |
US4774377A (en) * | 1987-09-11 | 1988-09-27 | Uop Inc. | Alkylation/transalkylation process |
US4891458A (en) | 1987-12-17 | 1990-01-02 | Innes Robert A | Liquid phase alkylation or transalkylation process using zeolite beta |
US4992606A (en) | 1988-10-06 | 1991-02-12 | Mobil Oil Corp. | Process for preparing short chain alkyl aromatic compounds |
US5334795A (en) | 1990-06-28 | 1994-08-02 | Mobil Oil Corp. | Production of ethylbenzene |
US5250277A (en) | 1991-01-11 | 1993-10-05 | Mobil Oil Corp. | Crystalline oxide material |
US5236575A (en) | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
US5362697A (en) | 1993-04-26 | 1994-11-08 | Mobil Oil Corp. | Synthetic layered MCM-56, its synthesis and use |
FR2744718B1 (fr) | 1996-02-09 | 1998-04-03 | Inst Francais Du Petrole | Procede de dismutation et/ou de transalkylation d'hydrocarbures alkylaromatiques en presence de deux catalyseurs zeolithiques |
US6984764B1 (en) | 1999-05-04 | 2006-01-10 | Exxonmobil Oil Corporation | Alkylaromatics production |
-
2000
- 2000-07-19 US US09/619,560 patent/US6936744B1/en not_active Expired - Lifetime
-
2001
- 2001-06-26 AT AT01950620T patent/ATE264284T1/de not_active IP Right Cessation
- 2001-06-26 CN CNB018020984A patent/CN1211324C/zh not_active Expired - Lifetime
- 2001-06-26 ES ES01950620T patent/ES2217166T3/es not_active Expired - Lifetime
- 2001-06-26 JP JP2002514069A patent/JP4726387B2/ja not_active Expired - Lifetime
- 2001-06-26 MX MXPA02002766A patent/MXPA02002766A/es unknown
- 2001-06-26 KR KR1020027003598A patent/KR100734689B1/ko active IP Right Grant
- 2001-06-26 AU AU71591/01A patent/AU7159101A/en not_active Abandoned
- 2001-06-26 WO PCT/US2001/020643 patent/WO2002008159A1/en not_active Application Discontinuation
- 2001-06-26 BR BR0106981-0A patent/BR0106981A/pt not_active Application Discontinuation
- 2001-06-26 EP EP01950620A patent/EP1218324B1/en not_active Expired - Lifetime
- 2001-06-26 CZ CZ2002958A patent/CZ2002958A3/cs unknown
- 2001-06-26 DE DE60102784T patent/DE60102784T2/de not_active Expired - Fee Related
- 2001-06-26 CA CA002385243A patent/CA2385243A1/en not_active Abandoned
- 2001-06-28 AR ARP010103087A patent/AR029294A1/es not_active Application Discontinuation
- 2001-07-19 TW TW090117673A patent/TWI243815B/zh not_active IP Right Cessation
-
2002
- 2002-03-18 FI FI20020503A patent/FI20020503A/fi unknown
Also Published As
Publication number | Publication date |
---|---|
MXPA02002766A (es) | 2002-08-30 |
DE60102784D1 (de) | 2004-05-19 |
ES2217166T3 (es) | 2004-11-01 |
KR20020039347A (ko) | 2002-05-25 |
EP1218324B1 (en) | 2004-04-14 |
TWI243815B (en) | 2005-11-21 |
BR0106981A (pt) | 2002-05-14 |
AU7159101A (en) | 2002-02-05 |
US6936744B1 (en) | 2005-08-30 |
KR100734689B1 (ko) | 2007-07-02 |
CZ2002958A3 (cs) | 2003-12-17 |
ATE264284T1 (de) | 2004-04-15 |
CN1386113A (zh) | 2002-12-18 |
JP4726387B2 (ja) | 2011-07-20 |
DE60102784T2 (de) | 2005-03-31 |
WO2002008159A1 (en) | 2002-01-31 |
EP1218324A1 (en) | 2002-07-03 |
CA2385243A1 (en) | 2002-01-31 |
JP2004504368A (ja) | 2004-02-12 |
FI20020503A (fi) | 2002-05-17 |
CN1211324C (zh) | 2005-07-20 |
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