AR014245A1 - Procedimiento de sintesis de polimeros en bloques por polimerizacion controlada de radicales partiendo de compuestos ditiocarbamatos - Google Patents

Procedimiento de sintesis de polimeros en bloques por polimerizacion controlada de radicales partiendo de compuestos ditiocarbamatos

Info

Publication number
AR014245A1
AR014245A1 ARP990100006A ARP990100006A AR014245A1 AR 014245 A1 AR014245 A1 AR 014245A1 AR P990100006 A ARP990100006 A AR P990100006A AR P990100006 A ARP990100006 A AR P990100006A AR 014245 A1 AR014245 A1 AR 014245A1
Authority
AR
Argentina
Prior art keywords
polymers
ditiocarbamatos
radicals
compounds
blocks
Prior art date
Application number
ARP990100006A
Other languages
English (en)
Original Assignee
Rhodia Chimie Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9716779A external-priority patent/FR2773161B1/fr
Application filed by Rhodia Chimie Sa filed Critical Rhodia Chimie Sa
Publication of AR014245A1 publication Critical patent/AR014245A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La invencion se refiere a un procedimiento de polimerizacion de polímeros en bloques de formula general (IA) o (IB), procedimiento en el cual se pone encontacto: un monomero etilénicamente insaturado de formula: CYY(=CW-CW)a=CH2, un compuesto precursor de formula general (IIA) o (IIB), y un indicador depolimerizacion de radicales.
ARP990100006A 1997-12-31 1999-01-04 Procedimiento de sintesis de polimeros en bloques por polimerizacion controlada de radicales partiendo de compuestos ditiocarbamatos AR014245A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9716779A FR2773161B1 (fr) 1997-12-31 1997-12-31 Procede de synthese de polymeres a blocs
FR9809780 1998-07-30

Publications (1)

Publication Number Publication Date
AR014245A1 true AR014245A1 (es) 2001-02-07

Family

ID=26234044

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP990100006A AR014245A1 (es) 1997-12-31 1999-01-04 Procedimiento de sintesis de polimeros en bloques por polimerizacion controlada de radicales partiendo de compuestos ditiocarbamatos

Country Status (6)

Country Link
US (1) US6812291B1 (es)
JP (1) JP2002500251A (es)
AR (1) AR014245A1 (es)
AU (1) AU1883199A (es)
CA (1) CA2315914A1 (es)
WO (1) WO1999035177A1 (es)

Families Citing this family (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001016187A1 (fr) * 1999-09-01 2001-03-08 Rhodia Chimie Composition aqueuse gelifiee comportant un copolymere a blocs comprenant au moins un bloc hydrosoluble et un bloc hydrophobe
FR2802209B1 (fr) 1999-12-10 2002-03-01 Rhodia Chimie Sa Latex a chimie de surface modifiee et poudres redispersables , leur obtention et leurs utilisations
US7335788B2 (en) 2000-02-16 2008-02-26 Lubrizol Advanced Materials, Inc. S-(α, α′-disubstituted-α″-acetic acid) substituted dithiocarbonate derivatives for controlled radical polymerizations, process and polymers made therefrom
US7495050B2 (en) 2000-02-16 2009-02-24 Lubrizol Advanced Materials, Inc. Associative thickeners for aqueous systems
US7557235B2 (en) 2000-02-16 2009-07-07 Lubrizol Advanced Materials, Inc. Hydroxyl-terminated thiocarbonate containing compounds, polymers, and copolymers, and polyurethanes and urethane acrylics made therefrom
US6596899B1 (en) 2000-02-16 2003-07-22 Noveon Ip Holdings Corp. S,S′BIS-(α, α′-DISUBSTITUTED-α″-ACETIC ACID)- TRITHIOCARBONATES AND DERIVATIVES AS INITIATOR-CHAIN TRANSFER AGENT-TERMINATOR FOR CONTROLLED RADICAL POLYMERIZATIONS AND THE PROCESS FOR MAKING THE SAME
US7205368B2 (en) 2000-02-16 2007-04-17 Noveon, Inc. S-(α, α′-disubstituted-α′ ′-acetic acid) substituted dithiocarbonate derivatives for controlled radical polymerizations, process and polymers made therefrom
KR100385724B1 (ko) * 2000-03-06 2003-05-27 주식회사 엘지화학 디티오에스테르계 화합물 및 이를 이용한 비닐계 고분자의중합방법
FR2814168B1 (fr) * 2000-09-18 2006-11-17 Rhodia Chimie Sa Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure
US6518364B2 (en) 2000-09-28 2003-02-11 Symyx Technologies, Inc. Emulsion living-type free radical polymerization, methods and products of same
US6380335B1 (en) 2000-09-28 2002-04-30 Symyx Technologies, Inc. Control agents for living-type free radical polymerization, methods of polymerizing and polymers with same
US6569969B2 (en) 2000-09-28 2003-05-27 Symyx Technologies, Inc. Control agents for living-type free radical polymerization, methods of polymerizing and polymers with same
US6395850B1 (en) 2000-09-28 2002-05-28 Symyx Technologies, Inc. Heterocycle containing control agents for living-type free radical polymerization
US6767968B1 (en) 2000-10-03 2004-07-27 Symyx Technologies, Inc. ABA-type block copolymers having a random block of hydrophobic and hydrophilic monomers and methods of making same
US6596809B2 (en) 2001-07-20 2003-07-22 Symyx Technologies, Inc. Cellulose copolymers that modify fibers and surfaces and methods of making same
US6855840B2 (en) 2002-02-11 2005-02-15 University Of Southern Mississippi Chain transfer agents for raft polymerization in aqueous media
JP4538232B2 (ja) 2002-02-11 2010-09-08 ロディア・シミ ブロックコポリマーを含む洗浄組成物
US6667376B2 (en) 2002-03-22 2003-12-23 Symyx Technologies, Inc. Control agents for living-type free radical polymerization and methods of polymerizing
FR2843314B1 (fr) 2002-08-06 2004-09-24 Rhodia Chimie Sa Synthese de microgels statistiques par polymerisation radicalaire controlee
US7737237B2 (en) * 2002-11-07 2010-06-15 Phodia Chimie Controlled structure copolymer comprising an amphoteric or zwitterionic part
FR2859209B1 (fr) * 2003-08-29 2007-11-30 Rhodia Chimie Sa Copolymere a structure controlee presentant une partie amphotere ou zwitterionique
EP1426428A1 (en) * 2002-12-06 2004-06-09 Ucb S.A. Aqueous polymer dispersions as pressure sensitive adhesives
US20040202688A1 (en) * 2002-12-13 2004-10-14 Nathalie Mougin Nail varnish composition comprising at least one film-forming gradient copolymer and cosmetic process for making up or caring for the nails
FR2848556B1 (fr) 2002-12-13 2006-06-16 Bio Merieux Procede de polymerisation radicalaire controlee
US20040185017A1 (en) * 2002-12-13 2004-09-23 Nathalie Mougin Nail varnish composition comprising at least one film-forming gradient copolymer and cosmetic process for making up and/or caring for the nails
FR2848557B1 (fr) * 2002-12-13 2006-07-07 Atofina Copolymeres a gradient solubles ou du moins dispersibles dans l'eau comme dans les solvants organiques
WO2004061525A1 (ja) 2002-12-28 2004-07-22 Jsr Corporation 感放射線性樹脂組成物
WO2004078793A1 (fr) * 2003-01-28 2004-09-16 Rhodia Chimie Procede de synthese de copolymeres ramifies par polymerisation radicalaire controlee
US6919409B2 (en) 2003-06-26 2005-07-19 Symyx Technologies, Inc. Removal of the thiocarbonylthio or thiophosphorylthio end group of polymers and further functionalization thereof
EP1464656A1 (en) * 2003-04-04 2004-10-06 Ucb S.A. Emulsifier composition
WO2005003192A1 (en) 2003-06-26 2005-01-13 Symyx Technologies, Inc. Synthesis of photoresist polymers
WO2005000924A1 (en) 2003-06-26 2005-01-06 Symyx Technologies, Inc. Photoresist polymers
ATE370975T1 (de) 2003-06-26 2007-09-15 Jsr Corp Photoresistpolymerzusammensetzungen
US7632905B2 (en) 2004-04-09 2009-12-15 L'oreal S.A. Block copolymer, composition comprising it and cosmetic treatment process
FR2871470B1 (fr) * 2004-06-11 2007-01-12 Oreal Copolymere a gradient, composition et procede cosmetique de maquillage ou de soin
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
CN100577692C (zh) 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
US7345186B2 (en) * 2005-01-18 2008-03-18 The Goodyear Tire & Rubber Company Oxathiazaphospholidine free radical control agent
US7947421B2 (en) 2005-01-24 2011-05-24 Fujifilm Corporation Positive resist composition for immersion exposure and pattern-forming method using the same
JP2008535936A (ja) 2005-02-10 2008-09-04 ザ リージェンツ オブ ザ ユニバーシティ オブ コロラド, ア ボディー コーポレイト 架橋ポリマーにおける応力緩和
US8877830B2 (en) 2005-02-10 2014-11-04 The Regents Of The University Of Colorado, A Body Corporate Stress relief for crosslinked polymers
FR2883291B1 (fr) * 2005-03-17 2010-03-05 Rhodia Chimie Sa Copolymere a blocs pouvant etre utile comme tenseur
JP5000904B2 (ja) * 2006-03-15 2012-08-15 株式会社クラレ 末端にメルカプト基を有するポリビニルアルコール系重合体の製造方法
EP1889858B1 (en) * 2006-08-17 2009-05-13 Rhodia Opérations Block copolymer, process for making the same, and use in emulsions
FI122734B (fi) * 2007-05-21 2012-06-15 Kemira Oyj Prosessikemikaali käytettäväksi paperin tai kartongin valmistuksessa
JP2009001776A (ja) * 2007-06-11 2009-01-08 Rohm & Haas Co 水性エマルジョンポリマー会合性増粘剤
CN101802027B (zh) 2007-09-12 2012-09-19 日产化学工业株式会社 超支化聚合物的制造方法
EP2160946A1 (en) 2008-09-09 2010-03-10 Polymers CRC Limited Process for the preparation of an antimicrobial article
EP2160945A1 (en) 2008-09-09 2010-03-10 Polymers CRC Limited Antimicrobial Article
WO2010101252A1 (ja) * 2009-03-06 2010-09-10 日産化学工業株式会社 ハイパーブランチポリマーの製造方法
FR2965264B1 (fr) 2010-09-27 2013-11-29 Rhodia Operations Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux
FR2965564B1 (fr) 2010-09-30 2012-10-26 Rhodia Operations Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee
EP2551338A1 (en) 2011-07-27 2013-01-30 Henkel AG & Co. KGaA Laundry detergent compositions with stain removal properties
US9758597B2 (en) 2011-08-05 2017-09-12 The Regents Of The University Of Colorado, A Body Corporate Reducing polymerization-induced shrinkage stress by reversible addition-fragmentation chain transfer
CN103732203B (zh) 2011-08-23 2017-05-03 3M创新有限公司 包含加成‑断裂剂的牙科组合物
DK2780383T3 (da) 2011-10-24 2017-02-20 Rhodia Operations Preparation of amphiphilic block polymers by controlled radical micellar polymerisation
FR2982871A1 (fr) 2011-11-22 2013-05-24 Univ Sud Toulon Var Polymeres de poly(acrylate de n-alkyle)s et leur utilisation comme abaisseurs de point d'ecoulement de petrole
CN104144957B (zh) 2012-01-31 2016-06-15 罗地亚运作公司 用于分散相聚合的活性聚(n-乙烯基内酰胺)反应性稳定剂
CN104144956B (zh) 2012-01-31 2017-04-12 罗地亚运作公司 活性反应性稳定剂存在下卤化的乙烯基单体的分散相聚合反应
CN104768519B (zh) 2012-11-12 2018-11-23 3M创新有限公司 包含加成-断裂剂的牙科组合物
FR3004458A1 (fr) 2013-04-11 2014-10-17 Rhodia Operations Fluides de fracturation a base de polymeres associatifs et de tensioactifs labiles
FR3011555A1 (fr) 2013-10-04 2015-04-10 Rhodia Operations Polymeres sequences pour le controle du filtrat
FR3027309B1 (fr) 2014-10-17 2018-08-10 Rhodia Operations Polymeres polyfonctionnels a base d'unites phosphonates et d'unites amines
FR3034776A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat
FR3034777A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat et de la rheologie
FR3034768B1 (fr) 2015-04-07 2017-05-05 Rhodia Operations Polymeres sequences pour le controle du filtrat
EP3461878A3 (fr) 2015-05-04 2019-08-07 Rhodia Operations Copolymères pour la protection des métaux et/ou la lubrification
JP6550908B2 (ja) 2015-05-08 2019-07-31 国立大学法人福井大学 アルケニルエーテル系重合体の製造方法
FR3037074B1 (fr) 2015-06-03 2017-07-14 Rhodia Operations Agents de suspension obtenus par polymerisation micellaire
FR3043083B1 (fr) 2015-10-30 2019-04-19 Rhodia Operations Polymeres sequences amphiphiles solubles en milieu fortement salin
BR112018011501B1 (pt) 2015-12-10 2022-05-31 Rhodia Operations Composição de material agrícola, seu processo de preparação e métodos para controlar e prevenir peste e para aperfeiçoar o crescimento de planta
WO2017103635A1 (en) 2015-12-16 2017-06-22 Rhodia Poliamida E Especialidades Ltda Emulsifier system for explosive emulsions
CN110023454A (zh) 2016-11-29 2019-07-16 罗地亚经营管理公司 用于颗粒分散的聚合物体系
FR3064641A1 (fr) 2017-04-03 2018-10-05 Rhodia Operations Association pour le controle du filtrat et la migration de gaz
CN110959019B (zh) * 2017-07-31 2022-10-14 电化株式会社 嵌段共聚物和嵌段共聚物的制造方法
FR3070043B1 (fr) 2017-08-09 2019-08-16 Rhodia Operations Formulation contenant un polymere associatif
KR20200053533A (ko) 2017-09-14 2020-05-18 케메탈 게엠베하 알루미늄 재료, 특히 알루미늄 휠을 예비처리하는 방법
WO2019121298A1 (fr) 2017-12-19 2019-06-27 Rhodia Operations Formulations aqueuses de tensioactifs et polymeres associatifs pour la recuperation assistee du petrole
AR114185A1 (es) 2018-01-23 2020-07-29 Adama Makhteshim Ltd Síntesis de 5-cloro-2-[(3,4,4-trifluoro-3-buten-1-il)tio]-tiazol
FR3079833B1 (fr) 2018-04-10 2020-10-09 Rhodia Operations Composition aqueuse gelifiee pour l'extraction petroliere
FR3083238A1 (fr) 2018-07-02 2020-01-03 Rhodia Operations Relargage progressif de chaines polymeres en milieu liquide
JP2022501520A (ja) 2018-07-05 2022-01-06 ケメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング 金属表面を酸性水性組成物および後リンス組成物で処理して腐食抵抗性を改善する方法
CN112424395A (zh) 2018-07-05 2021-02-26 凯密特尔有限责任公司 用酸性含水组合物处理金属表面以提高耐腐蚀性的方法
US20210355584A1 (en) 2018-09-07 2021-11-18 Rhodia Operations Method for treating surfaces of aluminum containing substrates
MX2021002643A (es) 2018-09-07 2021-05-12 Chemetall Gmbh Metodo para tratar superficies de sustratos que contienen aluminio.
BR112021005410A2 (pt) 2018-10-08 2021-06-15 Chemetall Gmbh método para tratamento de pelo menos uma superfície de um substrato, composição aquosa, mistura mestre para produzir a composição aquosa, kit de componentes, e, substrato revestido
CN112888809A (zh) 2018-10-08 2021-06-01 凯密特尔有限责任公司 金属表面的无镍磷化方法和用于这种方法的组合物
MX2021010080A (es) 2019-02-28 2021-09-21 Rhodia Operations Composiciones para una estabilizacion elevada de emulsiones.
FR3093514A1 (fr) 2019-03-05 2020-09-11 Rhodia Operations Suspension de polymères associatifs pour le traitement de formations souterraines
US11912934B2 (en) 2019-03-12 2024-02-27 Rhodia Operations Stabilized friction reducer emulsions
MX2021010694A (es) 2019-03-15 2021-10-01 Rhodia Operations Composiciones de polimero y uso de las mismas.
MX2023004398A (es) 2020-10-23 2023-07-11 Energy Solutions Us Llc Sistemas polimericos que tienen viscosidad mejorada y propiedades de transporte de apuntalantes.
FR3125296A1 (fr) 2021-07-13 2023-01-20 Rhodia Operations Préparation de polymères séquencés amphiphiles par polymérisation radicalaire micellaire inverse

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2396997A (en) * 1942-11-11 1946-03-19 Goodrich Co B F Polymerization of unsaturated organic compounds in the presence of sulphur-containing modifiers of polymerization
DE3867334D1 (de) * 1987-06-23 1992-02-13 Mitsubishi Petrochemical Co Block-copolymere vom typ ab enthaltende hydrophile gruppe.
JPH0753846B2 (ja) 1988-06-20 1995-06-07 株式会社クラレ 含イオウ接着剤
DE69009380T2 (de) 1989-09-07 1994-09-15 Tosoh Corp Chloroprenpolymerisat.
JPH04198303A (ja) 1990-11-27 1992-07-17 Sanyo Chem Ind Ltd 重合開始剤および重合方法
AUPM930394A0 (en) 1994-11-09 1994-12-01 Commonwealth Scientific And Industrial Research Organisation Block copolymer synthesis
KR100479628B1 (ko) 1996-07-10 2005-04-06 이.아이,듀우판드네모아앤드캄파니 리빙 특성을 갖는 중합 방법
FR2764892B1 (fr) 1997-06-23 2000-03-03 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
NZ505654A (en) 1997-12-18 2002-03-28 John Chiefair Living polymerisation process whereby photo-initiators of polymerisation utilises a thermal process resulting in polymers of controlled molecular weight and low polydispersity

Also Published As

Publication number Publication date
JP2002500251A (ja) 2002-01-08
WO1999035177A1 (fr) 1999-07-15
US6812291B1 (en) 2004-11-02
CA2315914A1 (fr) 1999-07-15
AU1883199A (en) 1999-07-26

Similar Documents

Publication Publication Date Title
AR014245A1 (es) Procedimiento de sintesis de polimeros en bloques por polimerizacion controlada de radicales partiendo de compuestos ditiocarbamatos
AR014244A1 (es) Procedimiento de sintesis de polimeros en bloques por polimerizacion de radicales controlada partiendo de compuestos ditioesteres y polimero en bloquesobtenido
AR016279A1 (es) Procedimiento de sintesis de polimeros en bloque, polimeros en bloque obtenidos y compuesto precursor para obtenerlos
TW200407339A (en) Manufacture method of living radical polymers and the polymers
AU2685401A (en) Synthesis method for polymers by controlled radical polymerisation with xanthates
IL146696A0 (en) Synthesis method for polymers by controlled radical polymerisation using halogenated xanthates
WO2002010223A3 (fr) Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee
ES2125676T3 (es) Polimeros a base de copolimeros en bloque.
TW200502265A (en) Method to produce UV-curable solventless acrylate-contact-adhesives
FR2814168B1 (fr) Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure
AU2555200A (en) Alkoxyamines issues de nitroxides ss-phosphores
ATE271069T1 (de) Radikalische polymerisation in gegenwart von mehreren stabilen, freien radikalen
BR0015941B1 (pt) processo para a preparação de composições de poli(met) acrilato e para a preparação de polìmeros, bem como uso de uma composição polimérica.
MXPA03005291A (es) N-alcoxi-4,4-dioxi-polialquil-piperidinas como iniciadores de polimerizacion por radicales.
IL162205A0 (en) Hail-resistant acrylic laminated glass and method for producing the same
WO2002030992A3 (en) Multi-functional initiators for atom transfer radical (co)polymerization
MX9702773A (es) Sintesis de polimeros.
HUT58673A (en) Process for producing olefine polymers containing bounded antioxidants
FR2793251B1 (fr) Procede d'obtention de polymeres oxacarbonyles, fonctionnalisation, polymeres obtenus et agents de fonctionnalisation
DE69918151D1 (de) Verfahren zur kontrollierten radikalischen Hochdruck-(Co)Polymerisation von Ethylen in Gegenwart von einem Kontrollfunktionsinitiator
ATE280186T1 (de) Verfahren zur herstellung eines katalysatorsystems für die polymerisation von olefinen
TW200516087A (en) Composition and process for the controlled synthesis of block copolymers
GB9715709D0 (en) Novel compounds
WO2003099877A3 (de) (co)polymerisate und verfahren zur radikalischen (co)polymerisation von olefinisch ungesättigten monomeren
ATE319749T1 (de) Zusammensetzung und verfahren für verbesserte kontrollierte freie radikalpolymerisation