AR014244A1 - Procedimiento de sintesis de polimeros en bloques por polimerizacion de radicales controlada partiendo de compuestos ditioesteres y polimero en bloquesobtenido - Google Patents
Procedimiento de sintesis de polimeros en bloques por polimerizacion de radicales controlada partiendo de compuestos ditioesteres y polimero en bloquesobtenidoInfo
- Publication number
- AR014244A1 AR014244A1 ARP990100005A ARP990100005A AR014244A1 AR 014244 A1 AR014244 A1 AR 014244A1 AR P990100005 A ARP990100005 A AR P990100005A AR P990100005 A ARP990100005 A AR P990100005A AR 014244 A1 AR014244 A1 AR 014244A1
- Authority
- AR
- Argentina
- Prior art keywords
- blocks
- radical polymerization
- polymers
- ditioester
- synthesis
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polymerization Catalysts (AREA)
Abstract
La invencion se refiere a un procedimiento de preparacion, por polimerizacion de radicales, de polimeros en bloques de formula general (I),procedimiento en el cual se pone en contacto: un monomero etilénicamente insaturado de formula: CYY(=CW-CW)a=CH2, un compuesto precursor de formulageneral (II), y un indicador de polimerizacion de radicales.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9716779A FR2773161B1 (fr) | 1997-12-31 | 1997-12-31 | Procede de synthese de polymeres a blocs |
Publications (1)
Publication Number | Publication Date |
---|---|
AR014244A1 true AR014244A1 (es) | 2001-02-07 |
Family
ID=9515362
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP990100005A AR014244A1 (es) | 1997-12-31 | 1999-01-04 | Procedimiento de sintesis de polimeros en bloques por polimerizacion de radicales controlada partiendo de compuestos ditioesteres y polimero en bloquesobtenido |
Country Status (8)
Country | Link |
---|---|
US (1) | US6545098B1 (es) |
EP (1) | EP1044231B1 (es) |
AR (1) | AR014244A1 (es) |
AU (1) | AU1971499A (es) |
DE (1) | DE69818865T2 (es) |
FR (1) | FR2773161B1 (es) |
WO (1) | WO1999035178A1 (es) |
ZA (2) | ZA9811908B (es) |
Families Citing this family (64)
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FR2794463B1 (fr) * | 1999-06-04 | 2005-02-25 | Rhodia Chimie Sa | Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes |
US6437040B2 (en) | 1999-09-01 | 2002-08-20 | Rhodia Chimie | Water-soluble block copolymers comprising a hydrophilic block and a hydrophobic block |
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US6258275B1 (en) * | 1999-10-01 | 2001-07-10 | Ecole Polytechnique Federale De Lausanne | Affinity macroligands |
FR2802209B1 (fr) | 1999-12-10 | 2002-03-01 | Rhodia Chimie Sa | Latex a chimie de surface modifiee et poudres redispersables , leur obtention et leurs utilisations |
US7495050B2 (en) * | 2000-02-16 | 2009-02-24 | Lubrizol Advanced Materials, Inc. | Associative thickeners for aqueous systems |
US7557235B2 (en) * | 2000-02-16 | 2009-07-07 | Lubrizol Advanced Materials, Inc. | Hydroxyl-terminated thiocarbonate containing compounds, polymers, and copolymers, and polyurethanes and urethane acrylics made therefrom |
FR2814168B1 (fr) * | 2000-09-18 | 2006-11-17 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure |
JP4889867B2 (ja) * | 2001-03-13 | 2012-03-07 | 株式会社カネカ | 末端にアルケニル基を有するビニル系重合体の製造方法、ビニル系重合体および硬化性組成物 |
FR2829137B1 (fr) | 2001-08-28 | 2003-12-19 | Rhodia Chimie Sa | Procede de polymerisation radicalaire realise en presence de composes disulfures |
JP4538232B2 (ja) | 2002-02-11 | 2010-09-08 | ロディア・シミ | ブロックコポリマーを含む洗浄組成物 |
FR2843314B1 (fr) * | 2002-08-06 | 2004-09-24 | Rhodia Chimie Sa | Synthese de microgels statistiques par polymerisation radicalaire controlee |
DE10243666A1 (de) * | 2002-09-20 | 2004-04-01 | Bayer Ag | Dithiocarbaminsäureester |
US20040185017A1 (en) * | 2002-12-13 | 2004-09-23 | Nathalie Mougin | Nail varnish composition comprising at least one film-forming gradient copolymer and cosmetic process for making up and/or caring for the nails |
WO2004078793A1 (fr) * | 2003-01-28 | 2004-09-16 | Rhodia Chimie | Procede de synthese de copolymeres ramifies par polymerisation radicalaire controlee |
NL1025250C2 (nl) * | 2004-01-15 | 2005-07-18 | Univ Eindhoven Tech | Multi- en bi-functionele dithiocarboxylaatverbindingen, monofunctionele alkoxycarbonyldithiocarbamaatverbinding, een werkwijze voor de bereiding van alkoxycarbonyldithiocarbamaatverbindingen evenals een werkwijze voor het door middel van radicaalpolymerisatie bereiden van multiblok-copolymeren. |
US7632905B2 (en) * | 2004-04-09 | 2009-12-15 | L'oreal S.A. | Block copolymer, composition comprising it and cosmetic treatment process |
FR2871470B1 (fr) * | 2004-06-11 | 2007-01-12 | Oreal | Copolymere a gradient, composition et procede cosmetique de maquillage ou de soin |
US7279446B2 (en) | 2004-11-15 | 2007-10-09 | Rhodia Inc. | Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance |
FR2883291B1 (fr) * | 2005-03-17 | 2010-03-05 | Rhodia Chimie Sa | Copolymere a blocs pouvant etre utile comme tenseur |
EP1889858B1 (en) * | 2006-08-17 | 2009-05-13 | Rhodia Opérations | Block copolymer, process for making the same, and use in emulsions |
JP2009001776A (ja) * | 2007-06-11 | 2009-01-08 | Rohm & Haas Co | 水性エマルジョンポリマー会合性増粘剤 |
FR2965264B1 (fr) | 2010-09-27 | 2013-11-29 | Rhodia Operations | Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux |
FR2965564B1 (fr) | 2010-09-30 | 2012-10-26 | Rhodia Operations | Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee |
EP2551338A1 (en) | 2011-07-27 | 2013-01-30 | Henkel AG & Co. KGaA | Laundry detergent compositions with stain removal properties |
EP2780383B1 (fr) | 2011-10-24 | 2016-03-16 | Rhodia Operations | Preparation de polymeres sequences amphiphiles par polymerisation radicalaire micellaire a caractere controle |
US9487598B2 (en) | 2012-01-31 | 2016-11-08 | Rhodia Operations | Live poly(n-vinyl lactam) reactive stabilizers for dispersed phase polymerization |
EP2809698B1 (fr) | 2012-01-31 | 2016-01-27 | Rhodia Operations | Polymérisation en phase dispersée de monomères vinyliques halogénés en présence de stabilisants réactifs vivants |
FR3004458A1 (fr) | 2013-04-11 | 2014-10-17 | Rhodia Operations | Fluides de fracturation a base de polymeres associatifs et de tensioactifs labiles |
FR3011555A1 (fr) | 2013-10-04 | 2015-04-10 | Rhodia Operations | Polymeres sequences pour le controle du filtrat |
FR3027309B1 (fr) | 2014-10-17 | 2018-08-10 | Rhodia Operations | Polymeres polyfonctionnels a base d'unites phosphonates et d'unites amines |
FR3034768B1 (fr) | 2015-04-07 | 2017-05-05 | Rhodia Operations | Polymeres sequences pour le controle du filtrat |
FR3034777A1 (fr) | 2015-04-07 | 2016-10-14 | Rhodia Operations | Polymeres sequences pour le controle du filtrat et de la rheologie |
FR3034776A1 (fr) | 2015-04-07 | 2016-10-14 | Rhodia Operations | Polymeres sequences pour le controle du filtrat |
EP3461878A3 (fr) | 2015-05-04 | 2019-08-07 | Rhodia Operations | Copolymères pour la protection des métaux et/ou la lubrification |
JP6550908B2 (ja) | 2015-05-08 | 2019-07-31 | 国立大学法人福井大学 | アルケニルエーテル系重合体の製造方法 |
FR3037074B1 (fr) | 2015-06-03 | 2017-07-14 | Rhodia Operations | Agents de suspension obtenus par polymerisation micellaire |
FR3043083B1 (fr) | 2015-10-30 | 2019-04-19 | Rhodia Operations | Polymeres sequences amphiphiles solubles en milieu fortement salin |
JP7139246B2 (ja) | 2015-12-10 | 2022-09-20 | アダマ・マクテシム・リミテッド | 高分子電解質層形成ブロックコポリマーならびにその組成物および使用 |
WO2017103635A1 (en) | 2015-12-16 | 2017-06-22 | Rhodia Poliamida E Especialidades Ltda | Emulsifier system for explosive emulsions |
CA3043623A1 (en) | 2016-11-29 | 2018-06-07 | Lingjuan SHEN | Polymeric systems for particle dispersion |
FR3064641A1 (fr) | 2017-04-03 | 2018-10-05 | Rhodia Operations | Association pour le controle du filtrat et la migration de gaz |
FR3070043B1 (fr) | 2017-08-09 | 2019-08-16 | Rhodia Operations | Formulation contenant un polymere associatif |
CN111601912B (zh) | 2017-09-14 | 2022-07-22 | 凯密特尔有限责任公司 | 预处理铝材料,特别是铝轮毂的方法 |
US11421147B2 (en) | 2017-12-19 | 2022-08-23 | Rhodia Operations | Aqueous formulations of surfactants and associative polymers for the assisted recovery of petroleum |
MX2020006375A (es) | 2017-12-20 | 2020-09-03 | Rhodia Operations | Sistemas polimericos para dispersion de particulas. |
AR114185A1 (es) | 2018-01-23 | 2020-07-29 | Adama Makhteshim Ltd | Síntesis de 5-cloro-2-[(3,4,4-trifluoro-3-buten-1-il)tio]-tiazol |
FR3079833B1 (fr) | 2018-04-10 | 2020-10-09 | Rhodia Operations | Composition aqueuse gelifiee pour l'extraction petroliere |
FR3083238A1 (fr) | 2018-07-02 | 2020-01-03 | Rhodia Operations | Relargage progressif de chaines polymeres en milieu liquide |
MX2021000135A (es) | 2018-07-05 | 2021-03-25 | Chemetall Gmbh | Metodo para el tratamiento de superficies metalicas con una composicion acuosa acida y una composicion post-enjuague para mejorar la resistencia a la corrosion. |
US20210269654A1 (en) | 2018-07-05 | 2021-09-02 | Chemetall Gmbh | Method for treating metallic surfaces with an acidic aqueous composition to improve corrosion resistance |
EP3783040A4 (en) * | 2018-08-31 | 2021-07-07 | Denka Company Limited | COPOLYMER OF CHLOROPRENE MONOMER AND UNSATURATED NITRILE COMPOUND, COMPOSITION WITH COPOLYMER, VULCANIZATION MOLDED BODY AND USE OF THE VULCANIZED MOLDED BODY |
MX2021002641A (es) | 2018-09-07 | 2021-05-12 | Chemetall Gmbh | Metodo para tratar superficies de sustratos que contienen aluminio. |
US11958989B2 (en) | 2018-09-07 | 2024-04-16 | Rhodia Operations | Method for treating surfaces of aluminum containing substrates |
WO2020074527A1 (en) | 2018-10-08 | 2020-04-16 | Chemetall Gmbh | Method for ni-free phosphatizing of metal surfaces and composition for use in such a method |
KR20210070351A (ko) | 2018-10-08 | 2021-06-14 | 케메탈 게엠베하 | 금속 표면의 ni-무함유 인산염처리 방법 및 이러한 방법에 사용하기 위한 조성물 |
US11649400B2 (en) | 2018-10-11 | 2023-05-16 | Energy Solutions (US) LLC | Polymer dispersion by controlled radical polymerization |
JP2022522446A (ja) | 2019-02-28 | 2022-04-19 | ローディア オペレーションズ | エマルジョンの高安定化のための組成物 |
FR3093514A1 (fr) | 2019-03-05 | 2020-09-11 | Rhodia Operations | Suspension de polymères associatifs pour le traitement de formations souterraines |
US11912934B2 (en) | 2019-03-12 | 2024-02-27 | Rhodia Operations | Stabilized friction reducer emulsions |
WO2020190622A1 (en) | 2019-03-15 | 2020-09-24 | Rhodia Operations | Polymer compositions and use of the same |
US11441066B2 (en) | 2019-12-02 | 2022-09-13 | Solvay Usa Inc. | Polymer dispersions for oilfield friction reduction |
MX2023004398A (es) | 2020-10-23 | 2023-07-11 | Energy Solutions Us Llc | Sistemas polimericos que tienen viscosidad mejorada y propiedades de transporte de apuntalantes. |
FR3125296A1 (fr) | 2021-07-13 | 2023-01-20 | Rhodia Operations | Préparation de polymères séquencés amphiphiles par polymérisation radicalaire micellaire inverse |
Family Cites Families (18)
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---|---|---|---|---|
US2396997A (en) | 1942-11-11 | 1946-03-19 | Goodrich Co B F | Polymerization of unsaturated organic compounds in the presence of sulphur-containing modifiers of polymerization |
US3580830A (en) | 1968-09-05 | 1971-05-25 | Goodrich Co B F | Preparation of xanthate terminated polymers |
US5314962A (en) | 1987-04-07 | 1994-05-24 | Mitsubishi Petrochemical Company Limited | ABA type block copolymers |
EP0296850B1 (en) | 1987-06-23 | 1992-01-02 | Mitsubishi Petrochemical Co., Ltd. | Hydrophilic group-containing ab-type block copolymer |
JPH0753846B2 (ja) * | 1988-06-20 | 1995-06-07 | 株式会社クラレ | 含イオウ接着剤 |
MX173261B (es) | 1988-06-28 | 1994-02-14 | Minnesota Mining & Mfg | Copolimeros acrilicos y metodo para su fabricacion |
DE69009380T2 (de) | 1989-09-07 | 1994-09-15 | Tosoh Corp | Chloroprenpolymerisat. |
CA2038117A1 (en) | 1990-03-29 | 1991-09-30 | Mahfuza B. Ali | Controllable radiation curable photoiniferter prepared adhesives for attachment of microelectronic devices and a method of attaching microelectronic devices therewith |
JPH04198303A (ja) * | 1990-11-27 | 1992-07-17 | Sanyo Chem Ind Ltd | 重合開始剤および重合方法 |
DE69225591T2 (de) | 1991-02-06 | 1999-01-07 | Commw Scient Ind Res Org | Polymerisationsregelung |
IL111484A (en) * | 1993-11-03 | 2001-06-14 | Commw Scient Ind Res Org | Polymerization process using pendant chain transfer means to regulate the molecular weight, the polymers thus obtained and a number of new pesticide compounds |
FR2720751B1 (fr) * | 1994-06-03 | 1996-07-19 | Rhone Poulenc Chimie | Copolymère polyoléfinique greffe. |
AUPM930394A0 (en) * | 1994-11-09 | 1994-12-01 | Commonwealth Scientific And Industrial Research Organisation | Block copolymer synthesis |
FR2738573B1 (fr) * | 1995-09-08 | 1997-10-17 | Rhone Poulenc Chimie | Utilisation en tant qu'agents thermoepaississants de copolymeres multiblocs |
US5627248A (en) * | 1995-09-26 | 1997-05-06 | The Dow Chemical Company | Difunctional living free radical polymerization initiators |
EP0910587B1 (en) * | 1996-07-10 | 2001-12-12 | E.I. Du Pont De Nemours And Company | Polymerization with living characteristics |
FR2764892B1 (fr) | 1997-06-23 | 2000-03-03 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs |
ES2277678T3 (es) | 1997-12-18 | 2007-07-16 | E.I. Du Pont De Nemours And Company | Proceso de polimerizacion con caracteristicas vivientes y polimeros obtenidos mediante este proceso. |
-
1997
- 1997-12-31 FR FR9716779A patent/FR2773161B1/fr not_active Expired - Fee Related
-
1998
- 1998-12-28 WO PCT/FR1998/002891 patent/WO1999035178A1/fr active IP Right Grant
- 1998-12-28 DE DE69818865T patent/DE69818865T2/de not_active Expired - Fee Related
- 1998-12-28 EP EP98964531A patent/EP1044231B1/fr not_active Expired - Lifetime
- 1998-12-28 AU AU19714/99A patent/AU1971499A/en not_active Abandoned
- 1998-12-28 US US09/582,401 patent/US6545098B1/en not_active Expired - Lifetime
- 1998-12-29 ZA ZA9811908A patent/ZA9811908B/xx unknown
- 1998-12-29 ZA ZA9811909A patent/ZA9811909B/xx unknown
-
1999
- 1999-01-04 AR ARP990100005A patent/AR014244A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
AU1971499A (en) | 1999-07-26 |
WO1999035178A1 (fr) | 1999-07-15 |
DE69818865D1 (de) | 2003-11-13 |
DE69818865T2 (de) | 2004-08-19 |
EP1044231B1 (fr) | 2003-10-08 |
ZA9811908B (en) | 1999-06-30 |
EP1044231A1 (fr) | 2000-10-18 |
US6545098B1 (en) | 2003-04-08 |
FR2773161A1 (fr) | 1999-07-02 |
ZA9811909B (en) | 1999-06-29 |
FR2773161B1 (fr) | 2000-01-21 |
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