DE69918151D1 - Verfahren zur kontrollierten radikalischen Hochdruck-(Co)Polymerisation von Ethylen in Gegenwart von einem Kontrollfunktionsinitiator - Google Patents

Verfahren zur kontrollierten radikalischen Hochdruck-(Co)Polymerisation von Ethylen in Gegenwart von einem Kontrollfunktionsinitiator

Info

Publication number
DE69918151D1
DE69918151D1 DE69918151T DE69918151T DE69918151D1 DE 69918151 D1 DE69918151 D1 DE 69918151D1 DE 69918151 T DE69918151 T DE 69918151T DE 69918151 T DE69918151 T DE 69918151T DE 69918151 D1 DE69918151 D1 DE 69918151D1
Authority
DE
Germany
Prior art keywords
polymerization
initiating
ethylene
stable
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69918151T
Other languages
English (en)
Other versions
DE69918151T2 (de
Inventor
Michael Buback
Eric Minaux
Thierry Senninger
Blevec Jean-Marc Le
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Atofina SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9812477A external-priority patent/FR2784111B1/fr
Priority claimed from FR9910198A external-priority patent/FR2797878B1/fr
Application filed by Atofina SA filed Critical Atofina SA
Application granted granted Critical
Publication of DE69918151D1 publication Critical patent/DE69918151D1/de
Publication of DE69918151T2 publication Critical patent/DE69918151T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • C08F4/32Organic compounds
    • C08F4/38Mixtures of peroxy-compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
DE69918151T 1998-10-06 1999-10-06 Verfahren zur kontrollierten radikalischen Hochdruck-(Co)Polymerisation von Ethylen in Gegenwart von einem Kontrollfunktionsinitiator Expired - Lifetime DE69918151T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
FR9812477A FR2784111B1 (fr) 1998-10-06 1998-10-06 Polymerisatin radicalaire en presence de plusieurs radicaux libres stables
FR9812477 1998-10-06
FR9910198 1999-08-05
FR9910198A FR2797878B1 (fr) 1999-08-05 1999-08-05 Procede de polymerisation ou copolymerisation radicalaire controlee de l'ethylene sous haute pression en presence d'un amorceur-controleur
PCT/FR1999/002318 WO2000020469A1 (fr) 1998-10-06 1999-10-06 Procede de polymerisation ou copolymerisation radicalaire controlee de l'ethylene sous haute pression en presence d'un amorceur-controleur

Publications (2)

Publication Number Publication Date
DE69918151D1 true DE69918151D1 (de) 2004-07-22
DE69918151T2 DE69918151T2 (de) 2005-06-30

Family

ID=26234579

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69918151T Expired - Lifetime DE69918151T2 (de) 1998-10-06 1999-10-06 Verfahren zur kontrollierten radikalischen Hochdruck-(Co)Polymerisation von Ethylen in Gegenwart von einem Kontrollfunktionsinitiator

Country Status (7)

Country Link
US (1) US6734269B1 (de)
EP (1) EP1119585B1 (de)
JP (1) JP5000038B2 (de)
AT (1) ATE269362T1 (de)
AU (1) AU5987899A (de)
DE (1) DE69918151T2 (de)
WO (1) WO2000020469A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2804118B1 (fr) * 2000-01-26 2003-08-22 Atofina Procede de polymerisation ou copolymerisation radicalaire controlee de l'ethylene sous haute pression en presence de radicaux libres amorceurs et de radicaux nitroxydes indoliniques controleurs
FR2807439B1 (fr) 2000-04-07 2003-06-13 Atofina Polymeres multimodaux par polymerisation radicalaire controlee en presence d'alcoxyamines
CA2406255C (en) * 2000-05-19 2010-12-21 Ciba-Specialty Chemicals Holding Inc. Hydroxylamine esters as polymerization initiators
CN1732408B (zh) 2002-12-28 2010-04-21 Jsr株式会社 辐射敏感性树脂组合物
FR2870251B1 (fr) * 2004-05-11 2010-09-17 Arkema Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention
JP5068765B2 (ja) * 2005-12-14 2012-11-07 ノバルティス アーゲー シリコーンヒドロゲルの製造方法
US7498398B2 (en) * 2006-03-21 2009-03-03 Sabic Innovative Plastics Ip B.V. Thermoplastic composition, method of making, and articles formed therefrom
EP2151457A1 (de) 2008-07-28 2010-02-10 Total Petrochemicals France Verfahren zur Herstellung eines Diblock-Copolymers mit einem Monovinylaroma-Polymerblock
BRPI1009981B1 (pt) 2009-05-01 2019-12-31 Bimini Tech Llc sistemas, métodos e composições para otimizar os enxertos enriquecidos de tecido e célula

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5247091A (en) * 1975-10-13 1977-04-14 Sumitomo Chem Co Ltd Process for preparing block copolymers
US4492787A (en) * 1981-09-18 1985-01-08 Mitsubishi Chemical Industries Limited Process for continuously producing propylene-ethylene block copolymer
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン 遊離基重合開始用化合物
AU571240B2 (en) * 1983-07-11 1988-04-14 Commonwealth Scientific And Industrial Research Organisation Alkoxy-amines, useful as initiators
US5449724A (en) * 1994-12-14 1995-09-12 Xerox Corporation Stable free radical polymerization process and thermoplastic materials produced therefrom
FR2730240A1 (fr) * 1995-02-07 1996-08-09 Atochem Elf Sa Stabilisation d'un polymere par un radical libre stable
FR2748484B1 (fr) * 1996-05-13 1998-07-24 Atochem Elf Sa Polymerisation en presence d'un radical libre stable et d'un initiateur de radicaux libres
DE19622441A1 (de) 1996-06-05 1997-12-11 Basf Ag Verfahren zum Verdichten ethylenisch ungesättigter Monomerer
FR2755969B1 (fr) * 1996-11-20 1998-12-24 Atochem Elf Sa Polymerisation en presence d'un radical libre stable et d'un iniferter
EP0996643B1 (de) 1997-07-15 2003-03-26 Ciba SC Holding AG Von nitrone- oder nitroso-verbindungen abgeleitete alkoxyaminverbindungen-enthaltende polymerisierbare zusammensetzungen
US5891971A (en) * 1997-08-15 1999-04-06 Xerox Corporation Polymerization processes
FR2773158B1 (fr) * 1997-12-30 2000-02-04 Atochem Elf Sa Procede de polymerisation radicalaire controlee faisant intervenir une faible quantite de radical libre stable
SG82601A1 (en) 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators

Also Published As

Publication number Publication date
DE69918151T2 (de) 2005-06-30
JP2002526610A (ja) 2002-08-20
EP1119585B1 (de) 2004-06-16
US6734269B1 (en) 2004-05-11
EP1119585A1 (de) 2001-08-01
AU5987899A (en) 2000-04-26
WO2000020469A1 (fr) 2000-04-13
ATE269362T1 (de) 2004-07-15
JP5000038B2 (ja) 2012-08-15

Similar Documents

Publication Publication Date Title
AU2685401A (en) Synthesis method for polymers by controlled radical polymerisation with xanthates
ES2073838T3 (es) Dispersiones polimeras acuosas.
ID24188A (id) Metode produksi polimerizat sintetis dengan kandungan monomer residu yang sangat rendah, produk dan penggunannya
DE60233961D1 (de) Verfahren zur Polymerisation von Buten-1
WO2002010223A3 (fr) Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee
ATE299847T1 (de) Verfahren zum verdichten ethylenisch ungesättigter monomerer
AU9000901A (en) Method for block polymer synthesis by controlled radical polymerisation in the presence of a disulphide compound
MXPA03005291A (es) N-alcoxi-4,4-dioxi-polialquil-piperidinas como iniciadores de polimerizacion por radicales.
DE69918151D1 (de) Verfahren zur kontrollierten radikalischen Hochdruck-(Co)Polymerisation von Ethylen in Gegenwart von einem Kontrollfunktionsinitiator
DE60336359D1 (de) Verfahren zur radikalären Polymerisation von Blockpolymeren und Blockpolymere
IL107147A (en) Polymers formed by combining linear polymer chains, their production and compositions containing them
DE69918629D1 (de) Radikalische Polymerisation in Gegenwart von mehreren stabilen, freien Radikalen
DE50202289D1 (de) Verfahren zur hochdruckpolymerisation von ethylen
DE59806830D1 (de) Verfahren zur copolymerisation von ethylen mit vinylcarboxylaten
WO1998024821A3 (de) Verfahren zur Herstellung von Polymerisaten durch Emulsionspolymerisation
ES2067496T3 (es) Derivados de urea etilenicamente insaturados y procedimiento para su preparacion.
EP0372599A3 (de) Verfahren zur Polymerisation von strukturell verschiedenen Monomeren
DE59911566D1 (de) Verfahren zur lebenden freien radikalischen polymerisation
DE602004003585D1 (de) Verfahren zur polymerisation und copolymerisation von ethylen in der gasphase
ATE256154T1 (de) Verfahren zur hochdruckpolymerisation von ethylen in gegenwart von überkritischem wasser
WO2003099877A3 (de) (co)polymerisate und verfahren zur radikalischen (co)polymerisation von olefinisch ungesättigten monomeren
ES8307878A1 (es) Un metodo para unis sustratos impermeables al aire, constituido por metales activos, metales relativamente inactivos, nometales o combinaciones de ellos.
SE7713562L (sv) Sett att i vattensuspension polymerisera vinylhalogenidmonomerer
DE602004003707D1 (de) Verfahren zur polymerisation und copolymerisation von ethylen in der gasphase
KR900000395A (ko) 에틸렌, 비닐 아세테이트 및 반응성 할로겐-함유 단량체의 인터폴리머를 제조하는 방법

Legal Events

Date Code Title Description
8364 No opposition during term of opposition