ZA986369B - Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles. - Google Patents

Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.

Info

Publication number
ZA986369B
ZA986369B ZA9806369A ZA986369A ZA986369B ZA 986369 B ZA986369 B ZA 986369B ZA 9806369 A ZA9806369 A ZA 9806369A ZA 986369 A ZA986369 A ZA 986369A ZA 986369 B ZA986369 B ZA 986369B
Authority
ZA
South Africa
Prior art keywords
monoalkenenitriles
hydrocyanation
nonconjugated
diolefins
isomerization
Prior art date
Application number
ZA9806369A
Other languages
English (en)
Inventor
Wilson Tam
Thomas Foo
James Michael Garner
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of ZA986369B publication Critical patent/ZA986369B/xx

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
ZA9806369A 1997-07-29 1998-07-17 Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles. ZA986369B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US5402397P 1997-07-29 1997-07-29

Publications (1)

Publication Number Publication Date
ZA986369B true ZA986369B (en) 2000-01-17

Family

ID=21988284

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA9806369A ZA986369B (en) 1997-07-29 1998-07-17 Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.

Country Status (14)

Country Link
US (2) US5981772A (ko)
EP (1) EP1000021B1 (ko)
JP (1) JP2002509550A (ko)
KR (1) KR100545279B1 (ko)
CN (2) CN1255415C (ko)
BR (1) BR9810820B1 (ko)
CA (1) CA2291443A1 (ko)
DE (1) DE69808481T2 (ko)
HK (1) HK1029983A1 (ko)
ID (1) ID23785A (ko)
MY (1) MY125853A (ko)
TW (1) TW527339B (ko)
WO (1) WO1999006357A1 (ko)
ZA (1) ZA986369B (ko)

Families Citing this family (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001021580A1 (en) * 1999-09-20 2001-03-29 E.I. Du Pont De Nemours And Company Multidentate phosphite ligands, catalytic compositions containing such ligands and catalytic processes utilizing such catalytic compositions
US6515161B1 (en) 1999-09-20 2003-02-04 E. I. Du Pont De Nemours And Company Hydroformylation process utilizing multidentate phosphite ligands
KR100714324B1 (ko) * 1999-09-20 2007-05-04 이 아이 듀폰 디 네모아 앤드 캄파니 다좌 포스파이트 리간드, 및 이를 함유하는 촉매 조성물
US6380421B1 (en) 1999-09-20 2002-04-30 E. I. Du Pont De Nemours And Company Multidentate phosphite ligands, catalytic compositions containing such ligands and catalytic processes utilizing such catalytic compositions
US6307107B1 (en) * 1999-09-20 2001-10-23 E.I. Du Pont De Nemours And Company Hydroformylation of acyclic monoethylenically unsaturated compounds to corresponding terminal aldehydes
DE10038037A1 (de) * 2000-08-02 2002-04-18 Basf Ag Zur Herstellung von Nitrilen geeigneter Katalysator und Verfahren zur Herstellung von Nitrilen
CA2427579C (en) * 2000-11-17 2009-11-03 The Penn State Research Foundation Ortho substituted chiral phosphines and phosphinites and their use in asymmetric catalytic reactions
FR2819250B1 (fr) * 2001-01-05 2004-12-03 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
DE10136488A1 (de) * 2001-07-27 2003-02-06 Basf Ag Ni(O) enthaltendes Katalysatorsystem
DE10150285A1 (de) * 2001-10-12 2003-04-17 Basf Ag Phosphonite
AR036636A1 (es) * 2001-10-12 2004-09-22 Basf Ag Fosfonita i, su uso como ligando en complejos de metal de transicion, dichos complejos, procedimiento para la obtencion de estos ultimos, uso de complejos de metal transitorio como catalizador y procedimientos para la adicion de acido cianhidrico a un doble enlace olefinico y para la isomerizacion d
DE10150286A1 (de) * 2001-10-12 2003-04-17 Basf Ag Phosphinite
US6660876B2 (en) * 2001-11-26 2003-12-09 E. I. Du Pont De Nemours And Company Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions
AR038161A1 (es) * 2002-01-24 2004-12-29 Basf Ag Procedimiento para separar acidos de mezclas de reaccion quimicas con la ayuda de liquidos ionicos
EP1344770A1 (en) * 2002-03-12 2003-09-17 E.I. du Pont de Nemours and Company Process for the hydrocyanation of butadiene
FR2842195B1 (fr) * 2002-07-15 2005-12-02 Rhodia Polyamide Intermediates Procede de fabrication de composes nitrile a partir de composes a insaturation ethylenique
FR2842196B1 (fr) * 2002-07-15 2006-01-13 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US6906218B2 (en) 2002-12-18 2005-06-14 Invista North America S.A.R.L. Cyclohexane derivatives and methods for their preparation
US6936171B2 (en) * 2003-01-08 2005-08-30 Invista North America S.A.R.L. Process for catalyst recovery from hydrocyanation product mixtures
US6897329B2 (en) * 2003-01-14 2005-05-24 Invista North America S.A.R.L. Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
US7015360B2 (en) * 2003-03-28 2006-03-21 Dow Global Technologies, Inc. Asymmetric catalysts prepared from optically active bisphosphites bridged by achiral diols
US6844289B2 (en) * 2003-04-08 2005-01-18 Invista North America S.A.R.L. Process for the preparation of a nickel/phosphorous ligand catalyst
FR2854891B1 (fr) * 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
DE602004022429D1 (de) 2003-09-11 2009-09-17 Invista Tech Sarl Verfahren zur hydrocyanierung von ungesättigten carbonsäure-derivaten
DE10351000A1 (de) * 2003-10-30 2005-06-09 Basf Ag Verfahren zur Herstellung von Nickel(O)-Phosphorligand-Komplexen
DE10350999A1 (de) * 2003-10-30 2005-06-02 Basf Ag Katalysator, umfassend wenigstens einen Nickel(O)Komplex stabilisiert durch einen sterisch anspruchsvollen Chelatphosphinitphosphitliganden, sowie ein Verfahren zur Herstellung von Nitrilen
DE10352757A1 (de) * 2003-11-12 2005-06-16 Studiengesellschaft Kohle Mbh Chirale Di- und Triphosphite
DE102004004696A1 (de) 2004-01-29 2005-08-18 Basf Ag Kontinuierliches Verfahren zur Herstellung von linearen Pentennitrilen
DE102004004720A1 (de) * 2004-01-29 2005-08-18 Basf Ag Verfahren zur Herstellung von 3-Pentennitril
US8119829B2 (en) * 2004-09-08 2012-02-21 Invista North America S.A.R.L. Process of hydrocyanation of unsaturated carboxylic acid derivatives
DE102005015893A1 (de) * 2005-04-06 2006-10-12 Basf Ag Verbessertes Verfahren zur Herstellung von Biphenolen aus Monophenolen
US7880028B2 (en) * 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7709673B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7709674B2 (en) 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7659422B2 (en) * 2006-07-14 2010-02-09 Invista North America S.A.R.L. Hydrocyanation process with reduced yield losses
CN101910119B (zh) 2008-01-15 2013-05-29 因温斯特技术公司 用于制备和精制3-戊烯腈，和用于精制2-甲基-3-丁烯腈的方法
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
FR2926816B1 (fr) 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2937321B1 (fr) 2008-10-21 2010-10-22 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2941455B1 (fr) 2009-01-29 2011-02-11 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
WO2012005917A1 (en) 2010-07-07 2012-01-12 Invista Technologies S.A.R.L. Process for making nitriles
WO2012033556A1 (en) 2010-09-07 2012-03-15 Invista Technologies S.A R.L. Preparing a nickel phosphorus ligand complex
WO2013052610A1 (en) 2011-10-07 2013-04-11 Invista Technologies S.A R.L. Process for making nitriles
JP2015512862A (ja) 2011-12-21 2015-04-30 インヴィスタ テクノロジーズ エスアエルエル 安定なエマルジョンを減じるための抽出溶媒制御
KR20140127220A (ko) 2011-12-21 2014-11-03 인비스타 테크놀러지스 에스.에이 알.엘. 안정한 에멀젼을 감소시키기 위한 추출 용매 제어
KR20140108683A (ko) 2011-12-21 2014-09-12 인비스타 테크놀러지스 에스.에이 알.엘. 안정한 에멀젼을 감소시키기 위한 추출 용매 제어
JP2015503510A (ja) 2011-12-21 2015-02-02 インヴィスタ テクノロジーズ エスアエルエル 安定なエマルジョンを減じるための抽出溶媒制御
US9458185B2 (en) 2012-02-10 2016-10-04 The Regents Of The University Of California First row metal-based catalysts for hydosilylation
KR20150045410A (ko) * 2012-06-01 2015-04-28 인비스타 테크놀러지스 에스.에이 알.엘. 안정화된 히드로시안화 리간드 조성물
WO2013181096A1 (en) 2012-06-01 2013-12-05 Invista Technologies S.A.R.L. Process for stabilizing hydrocyanation catalyst
CN109369706A (zh) * 2012-06-01 2019-02-22 英威达纺织（英国）有限公司 稳定的配体混合物及用于制备其的方法
ES2603929T3 (es) * 2012-10-12 2017-03-02 Evonik Degussa Gmbh Bisfosfito asimétrico
EP3022172B1 (en) 2013-07-17 2018-10-17 INVISTA Textiles (U.K.) Limited Separating a solvent from a nickel catalyst by distillation
ITMI20131612A1 (it) * 2013-09-30 2015-03-31 Maurizio Benaglia Dioli bieteroaromatici e loro derivati.
EP3160933B1 (en) 2014-06-27 2018-08-15 INVISTA Textiles (U.K.) Limited Integrated process for nitrile manufacture with enhanced liquid-liquid extraction
EP3160907B1 (en) 2014-06-27 2019-11-20 INVISTA Textiles (U.K.) Limited Enhanced extraction of impurities from mixture comprising nitriles
CN108640854A (zh) * 2018-04-28 2018-10-12 山东豪迈化工技术有限公司 一种己二腈的合成方法
CN113912516B (zh) * 2021-10-15 2023-06-27 浙江新和成股份有限公司 一种多齿亚磷酸酯配体在催化合成己二腈中的应用
WO2023228077A1 (en) 2022-05-23 2023-11-30 Inv Nylon Chemicals Americas, Llc Multidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2023228075A1 (en) 2022-05-23 2023-11-30 Inv Nylon Chemicals Americas, Llc Multidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028720A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028715A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Processes for producing nitriles and phosphorus-containing catalysts for use in such processes
WO2024028718A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Bidfntate phosphite ligands. catalytic compositions containing such ligands. and catalytic processes utilizing such catalytic compositions
WO2024028719A2 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028722A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028717A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Arsenic-containing ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028716A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Processes for producing nitriles and phosphorus-containing catalysts for use in such processes

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496215A (en) * 1965-11-23 1970-02-17 Du Pont Hydrocyanation of olefins using selected nickel phosphite catalysts
US3536748A (en) * 1965-11-23 1970-10-27 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles
US3496217A (en) * 1967-05-23 1970-02-17 Du Pont Hydrocyanation of olefins
US3676481A (en) * 1970-06-29 1972-07-11 Du Pont Catalytic isomerization of 2-methyl-3-butenenitrile to linear pentenenitriles in the presence of certain metal salt and/or tri(hydrocarbyl)boron promoters
JP3416956B2 (ja) * 1991-06-11 2003-06-16 三菱化学株式会社 ヒドロホルミル化法およびビスホスファイト化合物
CN1145531C (zh) * 1993-11-23 2004-04-14 纳幕尔杜邦公司 催化剂前身组合物
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
TW315370B (ko) * 1994-10-07 1997-09-11 Du Pont
US5449807A (en) * 1994-11-18 1995-09-12 E. I. Du Pont De Nemours And Company Catalyzed vapor phase hydrocyanation of diolefinic compounds
IN187044B (ko) * 1995-01-27 2002-01-05 Du Pont
US5821378A (en) * 1995-01-27 1998-10-13 E. I. Du Pont De Nemours And Company Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
US5710306A (en) * 1996-03-15 1998-01-20 Dsm N.V. Process to prepare a multidentate phosphite compound
JPH1045775A (ja) * 1996-04-30 1998-02-17 Mitsubishi Chem Corp ビスホスファイト化合物の製造方法
JP3812046B2 (ja) * 1996-04-30 2006-08-23 三菱化学株式会社 ビスホスファイト化合物及びそれを用いるヒドロホルミル化方法
DE19717359B4 (de) * 1996-04-30 2014-10-30 Mitsubishi Chemical Corp. Bisphosphitverbindungen und Verfahren zu deren Herstellung
EP0839794A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the continuous preparation of an alkyl 5-formylvalerate compound

Also Published As

Publication number Publication date
CN1265093A (zh) 2000-08-30
CN1255415C (zh) 2006-05-10
MY125853A (en) 2006-08-30
US6120700A (en) 2000-09-19
WO1999006357A1 (en) 1999-02-11
EP1000021B1 (en) 2002-10-02
HK1029983A1 (en) 2001-04-20
DE69808481T2 (de) 2003-07-10
CN1515576A (zh) 2004-07-28
BR9810820B1 (pt) 2010-06-01
ID23785A (id) 2000-05-11
EP1000021A1 (en) 2000-05-17
CN1117728C (zh) 2003-08-13
CA2291443A1 (en) 1999-02-11
TW527339B (en) 2003-04-11
JP2002509550A (ja) 2002-03-26
BR9810820A (pt) 2000-07-25
US5981772A (en) 1999-11-09
KR20010022366A (ko) 2001-03-15
DE69808481D1 (de) 2002-11-07
KR100545279B1 (ko) 2006-01-24

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