ZA902481B - Transient spectroscopic method and apparatus for in-process analysis of molten metal - Google Patents
Transient spectroscopic method and apparatus for in-process analysis of molten metalInfo
- Publication number
- ZA902481B ZA902481B ZA902481A ZA902481A ZA902481B ZA 902481 B ZA902481 B ZA 902481B ZA 902481 A ZA902481 A ZA 902481A ZA 902481 A ZA902481 A ZA 902481A ZA 902481 B ZA902481 B ZA 902481B
- Authority
- ZA
- South Africa
- Prior art keywords
- molten metal
- plasma plume
- spectroscopic
- pulsed laser
- plasma
- Prior art date
Links
- 239000002184 metal Substances 0.000 title abstract 7
- 238000004611 spectroscopical analysis Methods 0.000 title abstract 2
- 230000001052 transient effect Effects 0.000 title abstract 2
- 238000010949 in-process test method Methods 0.000 title 1
- 239000000523 sample Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000005259 measurement Methods 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 230000003595 spectral effect Effects 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/12—Generating the spectrum; Monochromators
- G01J3/18—Generating the spectrum; Monochromators using diffraction elements, e.g. grating
- G01J3/1809—Echelle gratings
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
- G01J3/30—Measuring the intensity of spectral lines directly on the spectrum itself
- G01J3/36—Investigating two or more bands of a spectrum by separate detectors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
- G01J3/0205—Optical elements not provided otherwise, e.g. optical manifolds, diffusers, windows
- G01J3/0208—Optical elements not provided otherwise, e.g. optical manifolds, diffusers, windows using focussing or collimating elements, e.g. lenses or mirrors; performing aberration correction
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
- G01J3/0205—Optical elements not provided otherwise, e.g. optical manifolds, diffusers, windows
- G01J3/021—Optical elements not provided otherwise, e.g. optical manifolds, diffusers, windows using plane or convex mirrors, parallel phase plates, or particular reflectors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
- G01J3/0286—Constructional arrangements for compensating for fluctuations caused by temperature, humidity or pressure, or using cooling or temperature stabilization of parts of the device; Controlling the atmosphere inside a spectrometer, e.g. vacuum
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
- G01J3/0291—Housings; Spectrometer accessories; Spatial arrangement of elements, e.g. folded path arrangements
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
- G01J3/04—Slit arrangements slit adjustment
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
- G01J3/2889—Rapid scan spectrometers; Time resolved spectrometry
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/71—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light thermally excited
- G01N21/718—Laser microanalysis, i.e. with formation of sample plasma
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/12—Generating the spectrum; Monochromators
- G01J3/18—Generating the spectrum; Monochromators using diffraction elements, e.g. grating
- G01J2003/1828—Generating the spectrum; Monochromators using diffraction elements, e.g. grating with order sorter or prefilter
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/66—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light electrically excited, e.g. electroluminescence
- G01N21/69—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light electrically excited, e.g. electroluminescence specially adapted for fluids, e.g. molten metal
- G01N2021/695—Molten metals
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Optics & Photonics (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Plasma & Fusion (AREA)
- General Health & Medical Sciences (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07341748 US4986658B1 (en) | 1989-04-21 | 1989-04-21 | Transient spectroscopic method and apparatus for in-process analysis of molten metal |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA902481B true ZA902481B (en) | 1991-01-30 |
Family
ID=23338867
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA902481A ZA902481B (en) | 1989-04-21 | 1990-03-30 | Transient spectroscopic method and apparatus for in-process analysis of molten metal |
Country Status (16)
Country | Link |
---|---|
US (1) | US4986658B1 (xx) |
EP (1) | EP0469083B1 (xx) |
JP (1) | JPH04507136A (xx) |
KR (1) | KR960012784B1 (xx) |
AT (1) | ATE170627T1 (xx) |
AU (1) | AU637795B2 (xx) |
BR (1) | BR9007307A (xx) |
CA (1) | CA2051125C (xx) |
CZ (1) | CZ285316B6 (xx) |
DE (1) | DE69032620T2 (xx) |
ES (1) | ES2121752T3 (xx) |
FI (1) | FI914935A0 (xx) |
HU (1) | HUT61842A (xx) |
PL (1) | PL164530B1 (xx) |
WO (1) | WO1990013008A1 (xx) |
ZA (1) | ZA902481B (xx) |
Families Citing this family (53)
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WO1993007453A1 (en) * | 1991-10-03 | 1993-04-15 | Iowa State University Research Foundation, Inc. | Mobile inductively coupled plasma system |
NO177875C (no) * | 1993-07-26 | 1995-12-06 | Elkem As | Fremgangsmåte for direkte kjemisk analyse av smeltet metall |
DE4443407C2 (de) * | 1993-12-08 | 1999-07-22 | Fraunhofer Ges Forschung | Vorrichtung zur qualitativen und/oder quantitativen chemischen Analyse einer Substanz, insbesondere zur Analyse einer Metallschmelze |
DE4415381A1 (de) * | 1994-05-02 | 1995-11-09 | Nis Ingenieurgesellschaft Mbh | Lasergestütztes Verfahren zur Bestimmung von Edelmetallkonzentrationen in Metallen |
US5526110A (en) * | 1994-07-08 | 1996-06-11 | Iowa State University Research Foundation, Inc. | In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy |
US5585919A (en) * | 1994-10-19 | 1996-12-17 | International Business Machines Corporation | Error minimization apparatus and method for real-time spectral deconvolution of chemical mixtures |
US5586049A (en) * | 1994-10-19 | 1996-12-17 | International Business Machines Corporation | Apparatus and method for generating profiles of constituents of chemical mixtures |
US5567625A (en) * | 1994-10-19 | 1996-10-22 | International Business Machines Corporation | Apparatus and method for real-time spectral deconvolution of chemical mixtures |
US5751416A (en) * | 1996-08-29 | 1998-05-12 | Mississippi State University | Analytical method using laser-induced breakdown spectroscopy |
US6061641A (en) * | 1996-10-25 | 2000-05-09 | Hahn; David W. | Method for improving instrument response |
US5781289A (en) * | 1996-11-05 | 1998-07-14 | Sabsabi; Mohamad | Method and apparatus for rapid in situ analysis of preselected components of homogeneous solid compositions, especially pharmaceutical compositions |
ES2121702B1 (es) * | 1997-02-17 | 1999-06-16 | Univ Malaga | Sensor para monitorizacion on-line y remota de procesos automatizados de soldadura con laser. |
DE19753348A1 (de) * | 1997-12-03 | 1999-06-10 | Spectro Analytical Instr Gmbh | Vorrichtung zur Erfassung und Quantifizierung von Element-Konzentrationsverteilungen in Feststoffen |
AU2894399A (en) * | 1998-03-03 | 1999-09-20 | Baker Hughes Incorporated | Improved laser spectral analyzer with sample location detector |
US6008896A (en) * | 1998-07-01 | 1999-12-28 | National Research Council Of Canada | Method and apparatus for spectroscopic analysis of heterogeneous materials |
US5946089A (en) * | 1998-07-13 | 1999-08-31 | Jordan Valley Applied Radiation Ltd. | Plasma spectrometer with shutter assembly |
AUPP573098A0 (en) * | 1998-09-04 | 1998-10-01 | Generation Technology Research Pty Ltd | Apparatus and method for analyzing material |
US6313917B1 (en) | 1999-07-02 | 2001-11-06 | Ncr Corporation | Produce data collector and produce recognition system |
AT409553B (de) * | 2000-09-28 | 2002-09-25 | Voest Alpine Ind Anlagen | Vorrichtung zur chemischen analyse von materialproben sowie metallurgisches gefäss hierfür |
US6741345B2 (en) | 2001-02-08 | 2004-05-25 | National Research Council Of Canada | Method and apparatus for in-process liquid analysis by laser induced plasma spectroscopy |
DE10155384B4 (de) * | 2001-11-10 | 2014-12-31 | Sms Siemag Aktiengesellschaft | Online Qualitätskontrolle von Stranggieß-Produkten mittels Laseranalyse |
US6784429B2 (en) * | 2002-04-19 | 2004-08-31 | Energy Research Company | Apparatus and method for in situ, real time measurements of properties of liquids |
US6909505B2 (en) | 2002-06-24 | 2005-06-21 | National Research Council Of Canada | Method and apparatus for molten material analysis by laser induced breakdown spectroscopy |
US20070228729A1 (en) * | 2003-03-06 | 2007-10-04 | Grimmett Harold M | Tubular goods with threaded integral joint connections |
US20060006648A1 (en) * | 2003-03-06 | 2006-01-12 | Grimmett Harold M | Tubular goods with threaded integral joint connections |
US7113277B2 (en) * | 2003-05-14 | 2006-09-26 | Lockheed Martin Corporation | System and method of aerosolized agent capture and detection |
US7169239B2 (en) * | 2003-05-16 | 2007-01-30 | Lone Star Steel Company, L.P. | Solid expandable tubular members formed from very low carbon steel and method |
WO2005059527A1 (de) | 2003-12-17 | 2005-06-30 | Heraeus Electro-Nite International N.V. | Verfahren zur analyse eines schmelzstoffes, vorrichtung sowie eintauchsensor |
BE1015940A3 (fr) * | 2004-02-13 | 2005-12-06 | Heraeus Electro Nite Int | Procede d'analyse par spectrometrie d'emission optique d'une substance en fusion. |
DE10359447B4 (de) * | 2003-12-17 | 2006-03-30 | Heraeus Electro-Nite International N.V. | Eintauchsensor |
AT413244B (de) * | 2004-03-30 | 2005-12-15 | Innsitec Laser Technologies Gm | Verfahren zur ermittlung und korrektur bzw. regelung des verlaufs eines laserlichtstrahls in einem hohlkörper |
JP2006266792A (ja) * | 2005-03-23 | 2006-10-05 | Jfe Steel Kk | 溶融金属の発光分光分析装置 |
US7530265B2 (en) * | 2005-09-26 | 2009-05-12 | Baker Hughes Incorporated | Method and apparatus for elemental analysis of a fluid downhole |
DE102006047765B3 (de) * | 2006-10-06 | 2007-12-20 | Heraeus Electro-Nite International N.V. | Eintauchlanze für die Analyse von Schmelzen und Flüssigkeiten |
US7394537B1 (en) * | 2006-12-22 | 2008-07-01 | Oxford Instruments Analytical Oy | Practical laser induced breakdown spectroscopy unit |
EP2132557A2 (en) * | 2007-02-23 | 2009-12-16 | Thermo Niton Analyzers LLC | Hand-held, self-contained optical emission spectroscopy (oes) analyzer |
JP5111914B2 (ja) * | 2007-03-26 | 2013-01-09 | Nuエコ・エンジニアリング株式会社 | 粒子密度測定プローブ及び粒子密度測定装置 |
JP2009210421A (ja) * | 2008-03-04 | 2009-09-17 | Sony Corp | テラヘルツ分光装置 |
KR101107095B1 (ko) * | 2010-07-30 | 2012-01-30 | 한국수력원자력 주식회사 | 고온 용융염 중의 우라늄농도 실시간 측정장치 |
DE102011014090B4 (de) * | 2011-03-16 | 2013-04-18 | Georgsmarienhütte Gmbh | Verfahren zur Ermittlung eines Betriebs- und/oder Werkstoffparameters in einem Elektrolichtbogenofen |
US8664589B2 (en) * | 2011-12-29 | 2014-03-04 | Electro Scientific Industries, Inc | Spectroscopy data display systems and methods |
JP6095901B2 (ja) * | 2012-05-24 | 2017-03-15 | 株式会社Ihi | 物質特定装置および物質特定方法 |
BE1020753A3 (fr) * | 2012-06-14 | 2014-04-01 | Centre Rech Metallurgique | Dispositif de focalisation d'un faisceau laser par camera. |
US20140268134A1 (en) * | 2013-03-15 | 2014-09-18 | Electro Scientific Industries, Inc. | Laser sampling methods for reducing thermal effects |
CN104297218B (zh) * | 2013-07-15 | 2016-09-14 | 中国科学院沈阳自动化研究所 | 远距离冶金液态金属成分的原位、在线检测装置及方法 |
WO2015193850A1 (en) * | 2014-06-20 | 2015-12-23 | National Research Council Of Canada | Method for laser-induced breakdown spectroscopy and calibration |
US10300551B2 (en) * | 2016-11-14 | 2019-05-28 | Matthew Fagan | Metal analyzing plasma CNC cutting machine and associated methods |
RU2664485C1 (ru) * | 2017-07-05 | 2018-08-17 | Александр Николаевич Забродин | Способ спектрального анализа химического состава расплавленных металлов и устройство для его осуществления |
EP3441214B1 (en) * | 2017-08-09 | 2022-09-28 | CL Schutzrechtsverwaltungs GmbH | Apparatus for additively manufacturing of three-dimensional objects |
US11099129B2 (en) | 2017-09-14 | 2021-08-24 | Brown University | Spatially resolved standoff trace chemical sensing using backwards transient absorption spectroscopy |
US10753878B2 (en) * | 2017-09-20 | 2020-08-25 | Worcester Polytechnic Institute | Molten metal inclusion testing |
DE102018222792B4 (de) * | 2018-12-21 | 2021-12-02 | Thyssenkrupp Ag | Laserinduzierte Emissionsspektrometrie zur schnellen Gefügeuntersuchung |
CA3224593A1 (en) * | 2021-08-05 | 2023-02-09 | Andre Moreau | Refractory lance assembly and refractory lance tube |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2079561A5 (xx) * | 1970-02-05 | 1971-11-12 | Siderurgie Fse Inst Rech | |
DD127021B1 (de) * | 1976-04-29 | 1979-12-27 | Joachim Mohr | Vorrichtung fuer spektrochemische untersuchungen, insbesondere fuer die laser-mikrospektralanalyse |
US4182574A (en) * | 1976-05-27 | 1980-01-08 | Jenoptik Jena G.M.B.H. | Arrangement for carrying out laser spectral analysis |
JPS56114746A (en) * | 1980-02-14 | 1981-09-09 | Kawasaki Steel Corp | Direct analyzing method for molten metal with pulse laser light |
JPS6042644A (ja) * | 1983-08-17 | 1985-03-06 | Kawasaki Steel Corp | 精錬容器内溶湯の成分連続分析法 |
GB8403976D0 (en) * | 1984-02-15 | 1984-03-21 | British Steel Corp | Analysis of materials |
JPS6186636A (ja) * | 1984-10-05 | 1986-05-02 | Kawasaki Steel Corp | 鋼のレ−ザ発光分光分析方法 |
EP0184590B1 (en) * | 1984-12-12 | 1990-03-14 | Kawasaki Steel Corporation | Method of continuously analyzing fluidized body by laser |
JPS61181947A (ja) * | 1985-02-07 | 1986-08-14 | Osaka Oxygen Ind Ltd | 溶融金属のレ−ザ直接発光分光分析装置 |
JPS62188919A (ja) * | 1985-10-09 | 1987-08-18 | Okayama Univ | レ−ザ多段励起直接発光分析方法及び装置 |
-
1989
- 1989-04-21 US US07341748 patent/US4986658B1/en not_active Expired - Fee Related
-
1990
- 1990-03-30 ZA ZA902481A patent/ZA902481B/xx unknown
- 1990-04-20 KR KR1019910701393A patent/KR960012784B1/ko not_active IP Right Cessation
- 1990-04-20 BR BR909007307A patent/BR9007307A/pt not_active IP Right Cessation
- 1990-04-20 AU AU55322/90A patent/AU637795B2/en not_active Ceased
- 1990-04-20 CA CA002051125A patent/CA2051125C/en not_active Expired - Fee Related
- 1990-04-20 WO PCT/US1990/002078 patent/WO1990013008A1/en active IP Right Grant
- 1990-04-20 JP JP2506818A patent/JPH04507136A/ja active Pending
- 1990-04-20 HU HU903754A patent/HUT61842A/hu unknown
- 1990-04-20 ES ES90907995T patent/ES2121752T3/es not_active Expired - Lifetime
- 1990-04-20 PL PL90284866A patent/PL164530B1/pl unknown
- 1990-04-20 AT AT90907995T patent/ATE170627T1/de not_active IP Right Cessation
- 1990-04-20 EP EP90907995A patent/EP0469083B1/en not_active Expired - Lifetime
- 1990-04-20 DE DE69032620T patent/DE69032620T2/de not_active Expired - Fee Related
- 1990-04-20 CZ CS901981A patent/CZ285316B6/cs not_active IP Right Cessation
-
1991
- 1991-10-18 FI FI914935A patent/FI914935A0/fi not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
HU903754D0 (en) | 1992-02-28 |
CS198190A3 (en) | 1992-01-15 |
ES2121752T3 (es) | 1998-12-16 |
WO1990013008A1 (en) | 1990-11-01 |
CA2051125A1 (en) | 1990-10-22 |
HUT61842A (en) | 1993-03-01 |
AU637795B2 (en) | 1993-06-10 |
JPH04507136A (ja) | 1992-12-10 |
CA2051125C (en) | 1999-11-30 |
DE69032620D1 (de) | 1998-10-08 |
KR920701799A (ko) | 1992-08-12 |
US4986658B1 (en) | 1996-06-25 |
ATE170627T1 (de) | 1998-09-15 |
CZ285316B6 (cs) | 1999-07-14 |
KR960012784B1 (ko) | 1996-09-24 |
PL164530B1 (pl) | 1994-08-31 |
EP0469083A1 (en) | 1992-02-05 |
BR9007307A (pt) | 1992-03-24 |
US4986658A (en) | 1991-01-22 |
EP0469083B1 (en) | 1998-09-02 |
AU5532290A (en) | 1990-11-16 |
FI914935A0 (fi) | 1991-10-18 |
EP0469083A4 (en) | 1992-06-03 |
DE69032620T2 (de) | 1999-04-15 |
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