ZA200603072B - Bispidon-derivated ligands and complexes for catalytically bleaching a substrate - Google Patents
Bispidon-derivated ligands and complexes for catalytically bleaching a substrate Download PDFInfo
- Publication number
- ZA200603072B ZA200603072B ZA200603072A ZA200603072A ZA200603072B ZA 200603072 B ZA200603072 B ZA 200603072B ZA 200603072 A ZA200603072 A ZA 200603072A ZA 200603072 A ZA200603072 A ZA 200603072A ZA 200603072 B ZA200603072 B ZA 200603072B
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- ZA
- South Africa
- Prior art keywords
- alkyl
- group
- composition according
- bleaching composition
- optionally substituted
- Prior art date
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- 238000005580 one pot reaction Methods 0.000 description 1
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- 229940055729 papain Drugs 0.000 description 1
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- 229940111202 pepsin Drugs 0.000 description 1
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- 235000020030 perry Nutrition 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
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- 238000010374 somatic cell nuclear transfer Methods 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/08—Bridged systems
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0325432.3A GB0325432D0 (en) | 2003-10-31 | 2003-10-31 | Ligand and complex for catalytically bleaching a substrate |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200603072B true ZA200603072B (en) | 2007-09-26 |
Family
ID=29725703
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200603072A ZA200603072B (en) | 2003-10-31 | 2004-10-18 | Bispidon-derivated ligands and complexes for catalytically bleaching a substrate |
Country Status (13)
Country | Link |
---|---|
US (1) | US7501389B2 (pt) |
EP (1) | EP1680422B1 (pt) |
JP (1) | JP2007533788A (pt) |
CN (1) | CN1894247B (pt) |
AT (1) | ATE414084T1 (pt) |
AU (1) | AU2004285647B2 (pt) |
BR (1) | BRPI0415988B1 (pt) |
CA (1) | CA2543668C (pt) |
DE (1) | DE602004017771D1 (pt) |
ES (1) | ES2314492T3 (pt) |
GB (1) | GB0325432D0 (pt) |
WO (1) | WO2005042532A1 (pt) |
ZA (1) | ZA200603072B (pt) |
Families Citing this family (156)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7557076B2 (en) | 2002-06-06 | 2009-07-07 | The Procter & Gamble Company | Organic catalyst with enhanced enzyme compatibility |
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US20070044824A1 (en) | 2005-09-01 | 2007-03-01 | Scott William Capeci | Processing system and method of processing |
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JP2009518536A (ja) * | 2005-12-14 | 2009-05-07 | ザ プロクター アンド ギャンブル カンパニー | 改善された漂白力及びしみ抜きの効果をもたらすアゾ反応開始剤化合物を含む洗剤組成物 |
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MX353911B (es) | 2012-02-03 | 2018-02-02 | Novozymes As | Variantes de lipasa y polinucleotidos que las codifican. |
WO2013116261A2 (en) | 2012-02-03 | 2013-08-08 | The Procter & Gamble Company | Compositions and methods for surface treatment with lipases |
TR201900214T4 (tr) | 2012-03-19 | 2019-02-21 | Milliken & Co | Karboksilat Boyalar |
CN104204181A (zh) | 2012-03-26 | 2014-12-10 | 宝洁公司 | 包含pH可转变的胺表面活性剂的清洁组合物 |
US9909109B2 (en) | 2012-04-02 | 2018-03-06 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
EP2875111A1 (en) | 2012-05-16 | 2015-05-27 | Novozymes A/S | Compositions comprising lipase and methods of use thereof |
EP2674475A1 (en) | 2012-06-11 | 2013-12-18 | The Procter & Gamble Company | Detergent composition |
CN104471048B (zh) | 2012-07-12 | 2018-11-16 | 诺维信公司 | 具有脂肪酶活性的多肽及编码它的多核苷酸 |
CA2879352A1 (en) | 2012-07-26 | 2014-01-30 | The Procter & Gamble Company | Low ph liquid cleaning compositions with enzymes |
EP2712915A1 (en) | 2012-10-01 | 2014-04-02 | The Procter and Gamble Company | Methods of treating a surface and compositions for use therein |
EP2904085B1 (en) | 2012-10-04 | 2018-11-07 | Ecolab USA Inc. | Pre-soak technology for laundry and other hard surface cleaning |
EP2912112B1 (en) * | 2012-10-29 | 2019-12-18 | Ashland Licensing and Intellectual Property LLC | Resin compositions |
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WO2015148361A1 (en) | 2014-03-27 | 2015-10-01 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
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US10030215B2 (en) | 2014-04-15 | 2018-07-24 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
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WO2015187757A1 (en) | 2014-06-06 | 2015-12-10 | The Procter & Gamble Company | Detergent composition comprising polyalkyleneimine polymers |
US10000602B2 (en) | 2014-10-02 | 2018-06-19 | Reichhold Llc 2 | Curable compositions |
WO2016081437A1 (en) | 2014-11-17 | 2016-05-26 | The Procter & Gamble Company | Benefit agent delivery compositions |
US10457921B2 (en) | 2014-12-05 | 2019-10-29 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
US20160230124A1 (en) | 2015-02-10 | 2016-08-11 | The Procter & Gamble Company | Liquid laundry cleaning composition |
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ES2683568T3 (es) | 2015-04-29 | 2018-09-26 | The Procter & Gamble Company | Método para tratar un tejido |
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DK3088505T3 (da) | 2015-04-29 | 2020-08-03 | Procter & Gamble | Fremgangsmåde til behandling af et tekstilstof |
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EP3720954A1 (en) | 2017-12-04 | 2020-10-14 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
WO2019113413A1 (en) | 2017-12-08 | 2019-06-13 | Novozymes A/S | Alpha-amylase variants and polynucleotides encoding same |
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WO2019154954A1 (en) | 2018-02-08 | 2019-08-15 | Novozymes A/S | Lipase variants and compositions thereof |
US12077652B2 (en) * | 2018-07-05 | 2024-09-03 | Milliken Industrials Limited | Oxidatively curable coating composition |
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US20200190433A1 (en) | 2018-12-14 | 2020-06-18 | The Procter & Gamble Company | Foaming Fibrous Structures Comprising Particles and Methods for Making Same |
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WO2023116569A1 (en) | 2021-12-21 | 2023-06-29 | Novozymes A/S | Composition comprising a lipase and a booster |
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EP4299702A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | A solid free-flowing particulate laundry detergent composition |
EP4299704A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | A method of laundering and drying fabric |
US20240026248A1 (en) | 2022-07-20 | 2024-01-25 | Ecolab Usa Inc. | Novel nonionic extended surfactants, compositions and methods of use thereof |
WO2024121058A1 (en) | 2022-12-05 | 2024-06-13 | Novozymes A/S | A composition comprising a lipase and a peptide |
Family Cites Families (12)
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AU2892897A (en) | 1996-06-19 | 1998-01-07 | Unilever Plc | Bleach activation |
CN1312811A (zh) | 1998-06-15 | 2001-09-12 | 荷兰联合利华有限公司 | 漂白催化剂和含有它们的制剂 |
PH11999002190B1 (en) | 1998-09-01 | 2007-08-06 | Unilever Nv | Composition and method for bleaching a substrate |
PH11999002188B1 (en) | 1998-09-01 | 2007-08-06 | Unilever Nv | Method of treating a textile |
EP1129164B1 (en) | 1998-11-13 | 2005-07-27 | The Procter & Gamble Company | Bleach compositions |
WO2000060045A1 (en) * | 1999-04-01 | 2000-10-12 | The Procter & Gamble Company | Transition metal bleaching agents |
GB0030673D0 (en) * | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
GB0108737D0 (en) | 2001-04-06 | 2001-05-30 | Unilever Plc | Composition and method for bleaching a substrate |
GB0212995D0 (en) * | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
RU2004139079A (ru) | 2002-06-06 | 2005-11-20 | Унилевер Н.В. (NL) | Лиганд и комплекс для каталитического обесцвечивания субстрата |
GB0212991D0 (en) * | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
GB0212984D0 (en) | 2002-06-06 | 2002-07-17 | Unilever Plc | Preserved enhancement of bleaching catalysts together |
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US7501389B2 (en) | 2009-03-10 |
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