ZA200103154B - Polymers of hydrophobic nature, filled with starch complexes. - Google Patents
Polymers of hydrophobic nature, filled with starch complexes. Download PDFInfo
- Publication number
- ZA200103154B ZA200103154B ZA200103154A ZA200103154A ZA200103154B ZA 200103154 B ZA200103154 B ZA 200103154B ZA 200103154 A ZA200103154 A ZA 200103154A ZA 200103154 A ZA200103154 A ZA 200103154A ZA 200103154 B ZA200103154 B ZA 200103154B
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- ZA
- South Africa
- Prior art keywords
- starch
- complex
- polymer
- polymers
- ethylene
- Prior art date
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- 229920002472 Starch Polymers 0.000 title claims abstract description 90
- 239000008107 starch Substances 0.000 title claims abstract description 89
- 235000019698 starch Nutrition 0.000 title claims abstract description 89
- 229920000642 polymer Polymers 0.000 title claims abstract description 55
- 230000002209 hydrophobic effect Effects 0.000 title claims description 7
- 239000011159 matrix material Substances 0.000 claims abstract description 32
- 229920000728 polyester Polymers 0.000 claims abstract description 30
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims abstract description 26
- 239000007822 coupling agent Substances 0.000 claims abstract description 19
- 229920001600 hydrophobic polymer Polymers 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 18
- 239000008139 complexing agent Substances 0.000 claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 11
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 10
- 229920002988 biodegradable polymer Polymers 0.000 claims abstract description 8
- 239000004621 biodegradable polymer Substances 0.000 claims abstract description 8
- 238000010521 absorption reaction Methods 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 229920001577 copolymer Polymers 0.000 claims description 23
- 229920001971 elastomer Polymers 0.000 claims description 14
- 239000005060 rubber Substances 0.000 claims description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 13
- 239000005977 Ethylene Substances 0.000 claims description 12
- 239000004952 Polyamide Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 229920002647 polyamide Polymers 0.000 claims description 10
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- -1 alkyl titanate Chemical compound 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 5
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 5
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 5
- 239000004626 polylactic acid Substances 0.000 claims description 5
- 230000000536 complexating effect Effects 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920000954 Polyglycolide Polymers 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229920001038 ethylene copolymer Polymers 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000004633 polyglycolic acid Substances 0.000 claims description 3
- 229920001195 polyisoprene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 229920002943 EPDM rubber Polymers 0.000 claims description 2
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 2
- 229940117958 vinyl acetate Drugs 0.000 claims description 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 2
- 244000043261 Hevea brasiliensis Species 0.000 claims 1
- 230000018984 mastication Effects 0.000 claims 1
- 238000010077 mastication Methods 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 229920003052 natural elastomer Polymers 0.000 claims 1
- 229920001194 natural rubber Polymers 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 abstract description 22
- 239000004715 ethylene vinyl alcohol Substances 0.000 abstract description 22
- 229920000856 Amylose Polymers 0.000 description 15
- 238000009835 boiling Methods 0.000 description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- 229920000945 Amylopectin Polymers 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 229920002261 Corn starch Polymers 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- 235000019759 Maize starch Nutrition 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229920005839 ecoflex® Polymers 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920001610 polycaprolactone Polymers 0.000 description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N Lactic Acid Natural products CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 229920002396 Polyurea Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000004632 polycaprolactone Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007614 solvation Methods 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 238000002525 ultrasonication Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- AXKZIDYFAMKWSA-UHFFFAOYSA-N 1,6-dioxacyclododecane-7,12-dione Chemical compound O=C1CCCCC(=O)OCCCCO1 AXKZIDYFAMKWSA-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 240000003483 Leersia hexandra Species 0.000 description 1
- 241000533950 Leucojum Species 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
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- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical group C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001480 hydrophilic copolymer Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000005055 methyl trichlorosilane Substances 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229940100486 rice starch Drugs 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J5/18—Manufacture of films or sheets
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/057—Metal alcoholates
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/548—Silicon-containing compounds containing sulfur
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- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyamides (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1998TO000800A IT1305576B1 (it) | 1998-09-22 | 1998-09-22 | Polimeri a carattere idrofobico caricati con complessi dell'amido. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200103154B true ZA200103154B (en) | 2001-10-24 |
Family
ID=11417055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200103154A ZA200103154B (en) | 1998-09-22 | 2001-04-18 | Polymers of hydrophobic nature, filled with starch complexes. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6962950B1 (no) |
| EP (2) | EP1127089B1 (no) |
| JP (2) | JP5153033B2 (no) |
| KR (1) | KR100717088B1 (no) |
| CN (1) | CN1150270C (no) |
| AT (1) | ATE302818T1 (no) |
| AU (1) | AU768019B2 (no) |
| BR (1) | BR9914176B1 (no) |
| CA (1) | CA2349915C (no) |
| DE (1) | DE69926905T2 (no) |
| ES (1) | ES2247827T3 (no) |
| IL (1) | IL142109A0 (no) |
| IT (1) | IT1305576B1 (no) |
| MX (1) | MXPA01002952A (no) |
| NO (1) | NO327956B1 (no) |
| RU (1) | RU2230760C2 (no) |
| WO (1) | WO2000017270A1 (no) |
| ZA (1) | ZA200103154B (no) |
Families Citing this family (52)
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| EP0947559B1 (en) * | 1996-11-05 | 2004-10-27 | NOVAMONT S.p.A. | Biodegradable polymeric compositions comprising starch and a thermoplastic polymer |
| IT1305576B1 (it) * | 1998-09-22 | 2001-05-09 | Novamont Spa | Polimeri a carattere idrofobico caricati con complessi dell'amido. |
| US7241832B2 (en) * | 2002-03-01 | 2007-07-10 | bio-tec Biologische Naturverpackungen GmbH & Co., KG | Biodegradable polymer blends for use in making films, sheets and other articles of manufacture |
| JP3855917B2 (ja) * | 2002-11-19 | 2006-12-13 | 松下電器産業株式会社 | 空気調和機の試験装置 |
| EP2450409B1 (en) * | 2003-11-28 | 2013-06-05 | Daicel Chemical Industries, Ltd. | Dispersion and process for producing colored organic solid particle |
| US20090253324A1 (en) * | 2008-04-07 | 2009-10-08 | Biotech Products, Llc | Compostable Olefin Polymer Compositions, Composites and Landfill Biodegradation |
| US8487018B2 (en) | 2005-01-24 | 2013-07-16 | Biotech Products, Llc | Heavy metal-free and anaerobically compostable vinyl halide compositions, articles and landfill biodegradation |
| US7939582B2 (en) * | 2005-01-24 | 2011-05-10 | Biotech Products, Llc | Compostable vinyl acetate polymer compositions, composites and landfill biodegradation |
| JP2008539284A (ja) * | 2005-04-29 | 2008-11-13 | コルポラシオン ドゥ ルコール ポリテクニク ドゥ モンレアル | 熱可塑性スターチ及び合成ポリマーのブレンド並びに製造方法 |
| US7989524B2 (en) * | 2005-07-19 | 2011-08-02 | The United States Of America, As Represented By The Secretary Of Agriculture | Fiber-reinforced starch-based compositions and methods of manufacture and use |
| JP2007039585A (ja) * | 2005-08-04 | 2007-02-15 | Sumitomo Rubber Ind Ltd | ゴム組成物およびこれを用いた空気入りタイヤ |
| US7931778B2 (en) | 2005-11-04 | 2011-04-26 | Cargill, Incorporated | Lecithin-starches compositions, preparation thereof and paper products having oil and grease resistance, and/or release properties |
| US9091004B2 (en) | 2006-07-14 | 2015-07-28 | Kimberly-Clark Worldwide, Inc. | Biodegradable polylactic acid for use in nonwoven webs |
| MX2009000525A (es) | 2006-07-14 | 2009-01-27 | Kimberly Clark Co | Poliester alifatico biodegradable para usarse en telas no tejidas. |
| EP2041341B1 (en) * | 2006-07-14 | 2010-11-03 | Kimberly-Clark Worldwide, Inc. | Biodegradable aliphatic-aromatic copolyester for use in nonwoven webs |
| ITMI20061845A1 (it) * | 2006-09-27 | 2008-03-28 | Novamont Spa | Composizioni biodegradabili polifasiche a base di amido |
| US9040072B2 (en) | 2007-12-07 | 2015-05-26 | Ethicon, Inc. | Use of coupling agents to improve the interface in absorbable polymer composites |
| US9062143B2 (en) | 2008-02-08 | 2015-06-23 | Dow Global Technologies Llc | Water-redispersible polymer powder |
| US8188185B2 (en) * | 2008-06-30 | 2012-05-29 | Kimberly-Clark Worldwide, Inc. | Biodegradable packaging film |
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| US8188169B2 (en) * | 2008-08-29 | 2012-05-29 | E. I. Du Pont De Nemours And Company | Polyoxymethylene compositions and articles made from these |
| KR101000749B1 (ko) | 2008-09-30 | 2010-12-13 | 주식회사 그린케미칼 | 생분해성 수지 조성물, 그의 제조방법 및 그로부터 제조되는 생분해성 필름 |
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| US8415021B2 (en) | 2010-01-20 | 2013-04-09 | E I Du Pont De Nemours And Company | Biodegradable starch-containing composition with improved tear strength |
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| JP5379181B2 (ja) * | 2010-04-20 | 2013-12-25 | ダウ グローバル テクノロジーズ エルエルシー | 低カルボキシル化スチレンブタジエンベースのラテックスから製造された再分散可能なポリマー粉体 |
| FR2959744B1 (fr) * | 2010-05-04 | 2012-08-03 | Michelin Soc Tech | Composition de caoutchouc, utilisable pour la fabrication d'un pneumatique dont la composition comporte un amidon et un plastifiant aqueux ou hydrosoluble |
| IT1401318B1 (it) * | 2010-08-06 | 2013-07-18 | Novamont Spa | Composizioni biodegradabili polifasiche contenenti almeno un polimero di origine naturale |
| RU2445326C1 (ru) * | 2010-11-09 | 2012-03-20 | Ооо "Бор" | Способ получения биоразлагаемых композиций, включающих производные крахмала на основе простых и сложных эфиров полисахаридов |
| FR2968006B1 (fr) | 2010-11-26 | 2012-12-21 | Michelin Soc Tech | Bande de roulement de pneumatique |
| IT1403273B1 (it) | 2010-12-20 | 2013-10-17 | Novamont Spa | Derivati di oli vegetali come oli estensori per composizioni elastomeriche |
| US8366822B2 (en) | 2011-06-20 | 2013-02-05 | Dow Global Technologies Llc | Cementitious tile adhesives and method of applying the same to a tile substrate |
| ITMI20121067A1 (it) * | 2012-06-19 | 2013-12-20 | Novamont Spa | Derivati vegetali come oli estensori e biofiller in composizioni elastomeriche. |
| TWI445755B (zh) * | 2012-06-27 | 2014-07-21 | Ind Tech Res Inst | 阻燃性熱可塑性澱粉材料、生質複材及其製備方法 |
| PL2784114T3 (pl) | 2013-03-26 | 2016-04-29 | Sa Minera Catalano Aragonesa | Biodegradowalny polimer pochodzenia naturalnego |
| ITTO20130570A1 (it) | 2013-07-08 | 2015-01-09 | Fond Istituto Italiano Di Tecnologia | Procedimento per la produzione di un bioelastomero composito, idrofobico, comprendente amido |
| KR101874069B1 (ko) | 2013-11-29 | 2018-07-03 | 김노을 | 플라스틱 온수 보일러 |
| US10889655B2 (en) | 2014-12-19 | 2021-01-12 | Novamont S.P.A. | Destructured starch derivatives and elastomer compositions containing them |
| WO2016097149A1 (en) * | 2014-12-19 | 2016-06-23 | Novamont S.P.A. | Use of destructured starch derivatives as hysteresis reduction additivesfor elastomer compositions |
| US11879058B2 (en) | 2015-06-30 | 2024-01-23 | Biologiq, Inc | Yarn materials and fibers including starch-based polymeric materials |
| US11926929B2 (en) | 2015-06-30 | 2024-03-12 | Biologiq, Inc | Melt blown nonwoven materials and fibers including starch-based polymeric materials |
| US11046840B2 (en) | 2015-06-30 | 2021-06-29 | BiologiQ, Inc. | Methods for lending biodegradability to non-biodegradable plastic materials |
| US11926940B2 (en) | 2015-06-30 | 2024-03-12 | BiologiQ, Inc. | Spunbond nonwoven materials and fibers including starch-based polymeric materials |
| ITUB20160525A1 (it) * | 2016-01-19 | 2017-07-19 | Novamont Spa | Uso di composizioni comprendenti amido destrutturato in forma complessata come agenti abrasivi e/o agenti strutturanti. |
| US9908977B2 (en) * | 2016-04-13 | 2018-03-06 | Xerox Corporation | Styrenic-based polymer coated silver nanoparticle-sulfonated polyester composite powders and methods of making the same |
| US9909013B2 (en) * | 2016-04-13 | 2018-03-06 | Xerox Corporation | Silver nanoparticle-sulfonated polyester composite powders and methods of making the same |
| RU2724250C1 (ru) * | 2019-04-29 | 2020-06-22 | Ооо "Крамбиопласт" | Способ получения биоразлагаемых композиций |
| KR20220035142A (ko) * | 2019-07-10 | 2022-03-21 | 바이올로지크, 인코퍼레이티드 | 증가된 강도 및 기타 특성을 위해 소립자의 전분 및 전분계 물질을 합성 폴리머와 혼합 |
| JP7359643B2 (ja) * | 2019-10-28 | 2023-10-11 | 日本食品化工株式会社 | 複合樹脂組成物及びその製造方法 |
| CN112724524B (zh) * | 2020-12-28 | 2022-04-01 | 会通新材料股份有限公司 | 一种可生物降解阻燃聚丙烯复合材料及其制备方法 |
| DE102021101538A1 (de) * | 2021-01-25 | 2022-07-28 | Bio-Tec Biologische Naturverpackungen Gmbh & Co.Kg | Erbsenstärkehaltige Polymerzusammensetzung |
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|---|---|---|---|---|
| US598487A (en) * | 1898-02-01 | Peter quarelli | ||
| US4133784A (en) * | 1977-09-28 | 1979-01-09 | The United States Of America As Represented By The Secretary Of Agriculture | Biodegradable film compositions prepared from starch and copolymers of ethylene and acrylic acid |
| IL93620A0 (en) * | 1989-03-09 | 1990-12-23 | Butterfly Srl | Biodegradable articles based on starch and process for producing them |
| IL94588A0 (en) | 1989-06-22 | 1991-04-15 | Warner Lambert Co | Polymer base blend compositions containing destructurized starch |
| IT1232909B (it) * | 1989-08-07 | 1992-03-05 | Butterfly Srl | Composizione polimerica per la produzione di articoli di materiale plastico biodegradabile comprendente amido destrutturato e copolimero di etilene |
| IT1245408B (it) | 1991-02-20 | 1994-09-20 | Butterfly Srl | Composizioni polimeriche biodegradabili a base di amido e di polimero termoplastico |
| SK147693A3 (en) * | 1991-06-26 | 1994-09-07 | Procter & Gamble | Biodegradable, liquid impervious film |
| CA2069861A1 (en) * | 1992-05-28 | 1993-11-29 | Alphons D. Beshay | Processes for preparing polymer composites based cellulose |
| IT1256914B (it) * | 1992-08-03 | 1995-12-27 | Novamont Spa | Composizione polimerica biodegradabile. |
| US5374671A (en) | 1993-02-16 | 1994-12-20 | The Goodyear Tire & Rubber Company | Hydrophilic polymer composite and product containing same |
| US5650454A (en) * | 1995-08-23 | 1997-07-22 | Flow Polymers, Inc. | Rubber additive and rubber compounds |
| US5672639A (en) * | 1996-03-12 | 1997-09-30 | The Goodyear Tire & Rubber Company | Starch composite reinforced rubber composition and tire with at least one component thereof |
| EP0947559B1 (en) * | 1996-11-05 | 2004-10-27 | NOVAMONT S.p.A. | Biodegradable polymeric compositions comprising starch and a thermoplastic polymer |
| ITTO980524A1 (it) * | 1998-06-17 | 1999-12-17 | Novamont Spa | Composizioni contenenti amido aventi elevata resistenza all'invecchiam ento. |
| IT1305576B1 (it) * | 1998-09-22 | 2001-05-09 | Novamont Spa | Polimeri a carattere idrofobico caricati con complessi dell'amido. |
| US6211325B1 (en) * | 2000-04-14 | 2001-04-03 | Kansas State University Research Foundation | High strength plastic from reactive blending of starch and polylactic acids |
| EP1889859A1 (en) | 2006-08-18 | 2008-02-20 | Rockwool International A/S | Hydrophilic binder system for porous substrates |
-
1998
- 1998-09-22 IT IT1998TO000800A patent/IT1305576B1/it active
-
1999
- 1999-09-22 AT AT99950537T patent/ATE302818T1/de not_active IP Right Cessation
- 1999-09-22 WO PCT/EP1999/007038 patent/WO2000017270A1/en active IP Right Grant
- 1999-09-22 MX MXPA01002952A patent/MXPA01002952A/es unknown
- 1999-09-22 RU RU2001111017/04A patent/RU2230760C2/ru not_active IP Right Cessation
- 1999-09-22 CN CNB998135682A patent/CN1150270C/zh not_active Expired - Fee Related
- 1999-09-22 IL IL14210999A patent/IL142109A0/xx unknown
- 1999-09-22 DE DE69926905T patent/DE69926905T2/de not_active Expired - Lifetime
- 1999-09-22 CA CA002349915A patent/CA2349915C/en not_active Expired - Fee Related
- 1999-09-22 EP EP99950537A patent/EP1127089B1/en not_active Expired - Lifetime
- 1999-09-22 ES ES99950537T patent/ES2247827T3/es not_active Expired - Lifetime
- 1999-09-22 JP JP2000574175A patent/JP5153033B2/ja not_active Expired - Fee Related
- 1999-09-22 AU AU63284/99A patent/AU768019B2/en not_active Ceased
- 1999-09-22 US US09/787,831 patent/US6962950B1/en not_active Expired - Fee Related
- 1999-09-22 BR BRPI9914176-0A patent/BR9914176B1/pt not_active IP Right Cessation
- 1999-09-22 EP EP05107604A patent/EP1621579A1/en not_active Withdrawn
- 1999-09-22 KR KR1020017003652A patent/KR100717088B1/ko active IP Right Grant
-
2001
- 2001-03-21 NO NO20011431A patent/NO327956B1/no not_active IP Right Cessation
- 2001-04-18 ZA ZA200103154A patent/ZA200103154B/en unknown
-
2012
- 2012-10-01 JP JP2012219052A patent/JP2013018994A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA01002952A (es) | 2002-04-08 |
| ATE302818T1 (de) | 2005-09-15 |
| RU2230760C2 (ru) | 2004-06-20 |
| AU6328499A (en) | 2000-04-10 |
| EP1127089A1 (en) | 2001-08-29 |
| NO327956B1 (no) | 2009-10-26 |
| US6962950B1 (en) | 2005-11-08 |
| DE69926905T2 (de) | 2006-01-12 |
| KR100717088B1 (ko) | 2007-05-10 |
| NO20011431D0 (no) | 2001-03-21 |
| BR9914176B1 (pt) | 2009-05-05 |
| BR9914176A (pt) | 2001-06-19 |
| EP1621579A1 (en) | 2006-02-01 |
| IL142109A0 (en) | 2002-03-10 |
| IT1305576B1 (it) | 2001-05-09 |
| JP2002526586A (ja) | 2002-08-20 |
| CA2349915C (en) | 2009-10-27 |
| CN1150270C (zh) | 2004-05-19 |
| JP2013018994A (ja) | 2013-01-31 |
| EP1127089B1 (en) | 2005-08-24 |
| JP5153033B2 (ja) | 2013-02-27 |
| NO20011431L (no) | 2001-03-21 |
| WO2000017270A1 (en) | 2000-03-30 |
| KR20010079894A (ko) | 2001-08-22 |
| DE69926905D1 (de) | 2005-09-29 |
| AU768019B2 (en) | 2003-11-27 |
| CA2349915A1 (en) | 2000-03-30 |
| CN1328586A (zh) | 2001-12-26 |
| ES2247827T3 (es) | 2006-03-01 |
| ITTO980800A1 (it) | 2000-03-22 |
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