ZA200007434B - A process for the preparation of compound fertilizer granules. - Google Patents
A process for the preparation of compound fertilizer granules. Download PDFInfo
- Publication number
- ZA200007434B ZA200007434B ZA200007434A ZA200007434A ZA200007434B ZA 200007434 B ZA200007434 B ZA 200007434B ZA 200007434 A ZA200007434 A ZA 200007434A ZA 200007434 A ZA200007434 A ZA 200007434A ZA 200007434 B ZA200007434 B ZA 200007434B
- Authority
- ZA
- South Africa
- Prior art keywords
- process according
- melter
- solid
- raw materials
- granulation
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 76
- 230000008569 process Effects 0.000 title claims abstract description 70
- 239000003337 fertilizer Substances 0.000 title claims abstract description 50
- 239000008187 granular material Substances 0.000 title claims abstract description 27
- 150000001875 compounds Chemical class 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 41
- 239000000463 material Substances 0.000 claims abstract description 39
- 239000002994 raw material Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000002844 melting Methods 0.000 claims abstract description 14
- 230000008018 melting Effects 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 238000012216 screening Methods 0.000 claims abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000015097 nutrients Nutrition 0.000 claims abstract description 6
- 238000001816 cooling Methods 0.000 claims abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012768 molten material Substances 0.000 claims abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 239000011574 phosphorus Substances 0.000 claims abstract description 4
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 4
- 239000011591 potassium Substances 0.000 claims abstract description 4
- 238000009826 distribution Methods 0.000 claims abstract description 3
- 238000005469 granulation Methods 0.000 claims description 64
- 230000003179 granulation Effects 0.000 claims description 64
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 30
- 239000004202 carbamide Substances 0.000 claims description 30
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 14
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 claims description 13
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 12
- 239000005696 Diammonium phosphate Substances 0.000 claims description 12
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 12
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 12
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 12
- 239000002426 superphosphate Substances 0.000 claims description 11
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 9
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 9
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 9
- 239000006012 monoammonium phosphate Substances 0.000 claims description 9
- 235000019270 ammonium chloride Nutrition 0.000 claims description 7
- 239000000440 bentonite Substances 0.000 claims description 7
- 229910000278 bentonite Inorganic materials 0.000 claims description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 239000001103 potassium chloride Substances 0.000 claims description 6
- 235000011164 potassium chloride Nutrition 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- 239000011785 micronutrient Substances 0.000 claims description 4
- 235000013369 micronutrients Nutrition 0.000 claims description 4
- 239000002367 phosphate rock Substances 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- 229910021532 Calcite Inorganic materials 0.000 claims description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 229940095564 anhydrous calcium sulfate Drugs 0.000 claims 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims 1
- 239000000047 product Substances 0.000 description 45
- 238000001035 drying Methods 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- 238000011021 bench scale process Methods 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 230000009102 absorption Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 239000000454 talc Substances 0.000 description 5
- 229910052623 talc Inorganic materials 0.000 description 5
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910021540 colemanite Inorganic materials 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000007580 dry-mixing Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000010006 flight Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- 235000021048 nutrient requirements Nutrition 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 210000003899 penis Anatomy 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- -1 prills Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 238000005550 wet granulation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
- Treatment Of Sludge (AREA)
- Fodder In General (AREA)
- Glanulating (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI981490A FI981490A (fi) | 1998-06-29 | 1998-06-29 | Menetelmä seoslannoitteiden valmistamiseksi |
FI982013A FI105807B (fi) | 1998-06-29 | 1998-09-18 | Menetelmä seoslannoitterakeiden valmistamiseksi |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200007434B true ZA200007434B (en) | 2001-07-13 |
Family
ID=26160610
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200007434A ZA200007434B (en) | 1998-06-29 | 2000-12-13 | A process for the preparation of compound fertilizer granules. |
Country Status (26)
Country | Link |
---|---|
US (1) | US6709685B1 (no) |
EP (1) | EP1127035B1 (no) |
JP (1) | JP2002519290A (no) |
KR (1) | KR20010053190A (no) |
CN (1) | CN1307550A (no) |
AT (1) | ATE255081T1 (no) |
AU (1) | AU754624B2 (no) |
BR (1) | BR9911721A (no) |
CA (1) | CA2336352A1 (no) |
CZ (1) | CZ294922B6 (no) |
DE (1) | DE69913193T2 (no) |
DK (1) | DK1127035T3 (no) |
EE (1) | EE04272B1 (no) |
ES (1) | ES2212585T3 (no) |
FI (2) | FI981490A (no) |
ID (1) | ID27474A (no) |
MY (1) | MY118102A (no) |
NO (1) | NO20006487D0 (no) |
PL (1) | PL189832B1 (no) |
PT (1) | PT1127035E (no) |
RU (1) | RU2227064C2 (no) |
SK (1) | SK284273B6 (no) |
TR (1) | TR200003872T2 (no) |
UA (1) | UA66862C2 (no) |
WO (1) | WO2000000452A1 (no) |
ZA (1) | ZA200007434B (no) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI108028B (fi) * | 1999-09-21 | 2001-11-15 | Kemira Agro Oy | Parannettu menetelmä ureapohjaisten seoslannoitteiden valmistamiseksi |
FI111940B (fi) * | 2000-07-14 | 2003-10-15 | Kemira Agro Oy | Menetelmä orgaanisten mineraalirakeiden valmistamiseksi |
US7128880B2 (en) * | 2002-12-19 | 2006-10-31 | Environmental Technologies Capital Partners Llc | Organic recycling with a pipe-cross or tubular reactor |
WO2007126388A1 (en) * | 2006-04-27 | 2007-11-08 | Wong Che Meng, Joseph | Fertilizer compositions for plantation crops |
CN101274870B (zh) * | 2007-03-30 | 2010-09-01 | 上海化工研究院 | 一种颗粒状复合肥料的制备方法 |
CN101993271B (zh) * | 2009-08-17 | 2013-04-24 | 深圳市芭田生态工程股份有限公司 | 复混肥生产运营系统 |
CN101993272B (zh) * | 2009-08-17 | 2013-04-24 | 深圳市芭田生态工程股份有限公司 | 即时随量复混肥生产方法 |
CN101717289B (zh) * | 2009-11-30 | 2012-05-30 | 天津芦阳化肥股份有限公司 | 氨酸管式反应器生产三元复合肥的方法 |
CN101973804B (zh) * | 2010-08-17 | 2013-03-13 | 湖北新洋丰肥业股份有限公司 | 一种含聚-γ-谷氨酸的高效高浓度硫基复合肥 |
CN101973818B (zh) * | 2010-10-25 | 2013-03-13 | 余章成 | 高塔脲甲醛缓释复合肥造粒工艺 |
WO2012170519A2 (en) * | 2011-06-10 | 2012-12-13 | Amiran Mohsen C | Process for producing fertilizer from animal manure |
CN102408261A (zh) * | 2011-07-19 | 2012-04-11 | 高英林 | 一种能分解土壤中磷钾的磷酸硫铵复合肥料 |
CN102442864A (zh) * | 2011-09-26 | 2012-05-09 | 高英林 | 一种可以分解土壤中磷钾及微量元素的酸性肥料 |
CN102503696A (zh) * | 2011-11-10 | 2012-06-20 | 上海化工研究院 | 一种颗粒复混肥料的制备方法 |
EP2780286A4 (en) | 2011-11-14 | 2015-08-12 | Intercontinental Potash Corp Usa | PROCESS FOR PROCESSING POLYHALITEZER, METHOD FOR THE PRODUCTION OF CALIUM SULFATE AND ASSOCIATED SYSTEMS |
CN102584392A (zh) * | 2012-01-18 | 2012-07-18 | 九禾股份有限公司 | 木薯复合肥料及其制备方法 |
CN102766002B (zh) * | 2012-08-13 | 2014-08-13 | 四川国光农化股份有限公司 | 一种化肥固体剂型 |
US8802048B2 (en) | 2012-09-12 | 2014-08-12 | Intercontinental Potash Corp. (Usa) | Methods of processing solutions of potassium sulfate and magnesium sulfate, methods of producing potassium sulfate, and related systems |
LT5974B (lt) | 2013-01-31 | 2013-11-25 | UAB "ARVI" ir ko | Sudėtinių trąšų gavimo būdas |
DE102013103013A1 (de) | 2013-03-25 | 2014-09-25 | Maschinenfabrik Gustav Eirich Gmbh & Co. Kg | Verfahren zur Erzeugung eines optimierten Granulats |
WO2017198735A1 (en) * | 2016-05-18 | 2017-11-23 | Kemira Oyj | Production of a phosphate containing fertilizer |
EP3336072A1 (en) * | 2016-12-13 | 2018-06-20 | YARA International ASA | Inorganic fertilizer particle |
AU2018302519B2 (en) | 2017-07-21 | 2023-10-12 | SABIC Agri-Nutrients Company | Calcium sulfate urea granules and methods for producing and using the same |
CN108452746A (zh) * | 2017-12-20 | 2018-08-28 | 湖北新洋丰肥业股份有限公司 | 一种高湿高热环境下高塔熔融造粒工艺 |
KR102580733B1 (ko) * | 2018-09-27 | 2023-09-19 | 어드밴식스 레진즈 앤드 케미컬즈 엘엘씨 | 수용성 미량영양소를 포함하는 황산암모늄 비료 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2912318A (en) * | 1957-01-16 | 1959-11-10 | Commercial Solvents Corp | Process for making mixed fertilizers containing ammonium nitrate and calcium carbonate |
FR1501758A (fr) | 1966-06-13 | 1967-11-18 | Pechiney Saint Gobain | Procédé de fabrication d'engrais granulés à sec, et produits en résultant |
ES355619A1 (es) | 1967-07-01 | 1969-11-16 | Sumitomo Chemical Co | Un procedimiento para producir un fertilizante. |
JPS4949116B1 (no) * | 1969-03-01 | 1974-12-25 | ||
SU304824A1 (ru) * | 1969-05-26 | 1974-09-05 | А. Н. Сарбаев, Куче вый, МЛ. Виноградов, Ю.Й хайлоБ,В,Б.Лебедев,Б.П.Мельников , Н.йеЛевенксБа | Б П Т В \ФШЩ SuOE?IOO j |
GB1462633A (en) | 1973-04-10 | 1977-01-26 | Fisons Ltd | Granulating urea |
NO133872C (no) | 1974-07-26 | 1976-07-14 | Norsk Hydro As | |
UST969002I4 (en) | 1977-07-25 | 1978-04-04 | Tennessee Valley Authority | Granular ammonium phosphate sulfate and urea-ammonium phosphate sulfate using a common pipe-cross reactor |
NL7807219A (nl) | 1978-07-04 | 1980-01-08 | Unie Van Kunstmestfab Bv | Werkwijze voor de bereiding van een korrelvormige npk-kunstmeststof alsmede korrelvormige npk-kunstmest- stoffen verkregen met deze werkwijze. |
JPS5515655A (en) * | 1978-07-21 | 1980-02-02 | Hitachi Metals Ltd | Globing apparatus of powder and granule |
US4410350A (en) * | 1980-03-31 | 1983-10-18 | Martin Marietta Corporation | Production of pellets and pellet-containing fertilizer composition |
NL8203723A (nl) * | 1982-09-25 | 1984-04-16 | Unie Van Kunstmestfab Bv | Werkwijze voor het bereiden van granulaire meststoffen met hoog kaliumgehalte, alsmede alsdus verkregen meststoffen. |
JPS6065785A (ja) * | 1983-09-21 | 1985-04-15 | 日本化学工業株式会社 | 粒状溶成燐肥 |
SU1353765A1 (ru) * | 1985-08-23 | 1987-11-23 | Предприятие П/Я Р-6603 | Способ получени гранулированной аммиачной селитры |
US4994100A (en) * | 1988-12-29 | 1991-02-19 | Freeport Mcmoran Resource Partners | Homogeneous granular nitrogen fertilizer |
JP2999911B2 (ja) * | 1993-12-02 | 2000-01-17 | 電気化学工業株式会社 | 粒状肥料の製造方法 |
IL113104A (en) | 1995-03-23 | 1999-01-26 | Dead Sea Works Ltd | Process for the production of granulated potassium chloride |
US5676729A (en) * | 1995-06-29 | 1997-10-14 | Western Industrial Clay Products, Ltd. | Particulate urea with mineral filler incorporated for hardness |
NO304423B1 (no) * | 1995-10-27 | 1998-12-14 | Norsk Hydro As | Homogen NK-gj°dsel og fremgangsmÕte for fremstilling derav |
-
1998
- 1998-06-29 FI FI981490A patent/FI981490A/fi unknown
- 1998-09-18 FI FI982013A patent/FI105807B/fi active
-
1999
- 1999-06-23 MY MYPI99002579A patent/MY118102A/en unknown
- 1999-06-28 UA UA2000127188A patent/UA66862C2/uk unknown
- 1999-06-28 RU RU2000131688/12A patent/RU2227064C2/ru not_active IP Right Cessation
- 1999-06-28 AT AT99932903T patent/ATE255081T1/de not_active IP Right Cessation
- 1999-06-28 DK DK99932903T patent/DK1127035T3/da active
- 1999-06-28 CN CN99808095A patent/CN1307550A/zh active Pending
- 1999-06-28 PT PT99932903T patent/PT1127035E/pt unknown
- 1999-06-28 WO PCT/FI1999/000568 patent/WO2000000452A1/en active IP Right Grant
- 1999-06-28 ID IDW20010242A patent/ID27474A/id unknown
- 1999-06-28 EP EP99932903A patent/EP1127035B1/en not_active Expired - Lifetime
- 1999-06-28 TR TR2000/03872T patent/TR200003872T2/xx unknown
- 1999-06-28 PL PL99345104A patent/PL189832B1/pl not_active IP Right Cessation
- 1999-06-28 ES ES99932903T patent/ES2212585T3/es not_active Expired - Lifetime
- 1999-06-28 KR KR1020007014780A patent/KR20010053190A/ko not_active Application Discontinuation
- 1999-06-28 DE DE69913193T patent/DE69913193T2/de not_active Expired - Fee Related
- 1999-06-28 CZ CZ20004926A patent/CZ294922B6/cs not_active IP Right Cessation
- 1999-06-28 AU AU49123/99A patent/AU754624B2/en not_active Ceased
- 1999-06-28 US US09/720,102 patent/US6709685B1/en not_active Expired - Fee Related
- 1999-06-28 CA CA002336352A patent/CA2336352A1/en not_active Abandoned
- 1999-06-28 BR BR9911721-5A patent/BR9911721A/pt not_active IP Right Cessation
- 1999-06-28 EE EEP200000771A patent/EE04272B1/xx not_active IP Right Cessation
- 1999-06-28 SK SK1977-2000A patent/SK284273B6/sk unknown
- 1999-06-28 JP JP2000557213A patent/JP2002519290A/ja active Pending
-
2000
- 2000-12-13 ZA ZA200007434A patent/ZA200007434B/en unknown
- 2000-12-19 NO NO20006487A patent/NO20006487D0/no not_active Application Discontinuation
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