WO2022121307A1 - 彩色活性混合材料及其制备方法和应用 - Google Patents

彩色活性混合材料及其制备方法和应用 Download PDF

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WO2022121307A1
WO2022121307A1 PCT/CN2021/105727 CN2021105727W WO2022121307A1 WO 2022121307 A1 WO2022121307 A1 WO 2022121307A1 CN 2021105727 W CN2021105727 W CN 2021105727W WO 2022121307 A1 WO2022121307 A1 WO 2022121307A1
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active
color
mixed material
inorganic
inactive
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PCT/CN2021/105727
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English (en)
French (fr)
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石磊
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广东省福美材料科学技术有限公司
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Publication of WO2022121307A1 publication Critical patent/WO2022121307A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26—Silicates of the alkali metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06—Acrylates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Definitions

  • the invention belongs to the technical field of inorganic substances, and in particular, the invention relates to a color active mixed material and a preparation method and application thereof.
  • Natural soil, quartz, limestone and other inactive inorganic substances have natural colors, such as red, yellow, white and black.
  • sintered red brick blocks, cement blocks, volcanic ash, blast furnace slag, phosphate slag, fly ash and other active materials also have natural colors, such as red, yellow, white, black, but the variety of colors is not rich enough.
  • Existing decorative materials generally exhibit different colors by adding chemical pigments, and the materials obtained by this method have poor color fastness.
  • the demand for active inorganic substances is generally larger, resulting in higher cost of the entire material.
  • most of the existing building materials use cement, which is costly and has the problem of pan-alkali; plastic products are widely used in daily life, which is harmful to the environment.
  • this application is based on the existing inorganic substances, through modification, to explore more possibilities, and provide more possibilities for the fields of construction and life.
  • an object of the present invention is to provide a color active mixed material and its preparation method and application. Under the condition that the color active mixed material has strong activity, the usage amount of active inorganic substances is significantly reduced. At the same time the color is significantly enriched.
  • the present invention provides a color active mixed material.
  • the color active mixed material includes: an inactive inorganic substance, an active inorganic substance, and a surface coating agent.
  • the color active mixed material has both non-active inorganic substances and active inorganic substances, and the surface coating agent is coated on the outer surfaces of the non-active inorganic substances and the active inorganic substances, and the surface is coated
  • the interior of the agent contains both inactive inorganic substances and active inorganic substances. Under the action of the surface coating agent, the surfaces of the inactive inorganic substances and active inorganic substances are homogenized and activated, so that the obtained color active mixed material has strong activity. Under the same conditions, the amount of active inorganic substances used is significantly reduced.
  • the same color of the inactive inorganic substances can be mixed with the active inorganic substances of the same color to obtain a color active mixed material with the same color.
  • a color active mixed material that is different from the primary color of the inactive inorganic material and the active inorganic material can be obtained, which significantly enriches the color of the color active mixed material.
  • color active mixed material according to the above embodiments of the present invention may also have the following additional technical features:
  • the mass ratio of the inactive inorganic substance to the active inorganic substance is 1:(1-4).
  • the mass ratio of the inactive inorganic substance to the active inorganic substance and the mass ratio of the surface coating agent is 100:0.4-8.
  • the color active hybrid material further comprises a mineral pigment.
  • the mass ratio of the sum of the mass of the inactive inorganic substance and the active inorganic substance to the mineral pigment is 100:(0-20).
  • the mass ratio of the sum of the mass of the inactive inorganic substance, the active inorganic substance, and the mineral pigment to the surface coating agent is 100:0.2-5.
  • the inactive inorganic substance is selected from at least one of natural soil, quartz, and limestone.
  • the active inorganic substance is selected from at least one of sintered red brick discarded blocks, cement discarded blocks, pozzolans, blast furnace slag, phosphate rock slag, and fly ash.
  • the mineral pigment is selected from at least one of red iron oxide, yellow iron oxide, black iron oxide, carbon black, zinc oxide, and titanium white.
  • the surface coating agent is selected from higher ammonium salts, octadecylamine, fluorocarbon surfactants, ⁇ -aminopropyltriethoxysilane, glutathione, cysteamine Acid, gum arabic, gelatin, polypyrrolidone, 3-aminopropyltrimethoxysilane, dopamine, levodopa, dopamine hydrochloride, bovine serum albumin, polyethyleneimine, chitosan, tridecafluorooctyltrimethyl At least one of oxysilane, tridecafluorooctyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, organic amine halogen acid, and oligopeptide.
  • the present aspect proposes a method for preparing the above-mentioned color active mixed material.
  • the method includes:
  • the mixed inorganic powder and the surface coating agent are mixed and coated to obtain a color active mixed material.
  • the non-active inorganic substances of different colors and the active inorganic substances of different colors are respectively pulverized into powders of predetermined particle sizes, and then the inactive inorganic powders and the active inorganic substances are pulverized into powders of predetermined particle sizes respectively.
  • the powders are mixed, thereby obtaining a mixed inorganic powder with a predetermined particle size range that is consistent with or inconsistent with the color of the raw material inactive inorganic powder or active inorganic powder, which significantly enriches the color of the final color active mixed material.
  • the colors of the inactive inorganic powder and the active inorganic powder are both the primary colors of the material itself, the color fixation degree of the obtained color active mixed material is much stronger than that of dyeing.
  • the surface coating agent By coating the mixed inorganic powder, both the non-active inorganic powder and the active inorganic powder are covered by the surface coating agent, which can significantly improve the activity of the color active mixed material, while significantly reducing the active inorganic powder. With the dosage, the economic value of the entire color active mixed material is significantly improved.
  • color active mixed material according to the above embodiments of the present invention may also have the following additional technical features:
  • the mixed inorganic powder and the mineral pigment are mixed before subjecting the mixed inorganic powder to the coating treatment.
  • the particle size of the inactive inorganic powder is 80-12000 mesh.
  • the particle size of the active inorganic powder is 80-12000 mesh.
  • the present invention provides a cement component.
  • the cement component is prepared by using the above-mentioned color-active mixed material, or prepared by using the above-mentioned method for preparing a color-active mixed material. prepared from the color active mixed material.
  • the color active mixed material can provide color matching for the cement component, and at the same time, due to the use of the colored active mixed material, the amount of cement can be reduced by 30-100%, and the amount of inactive inorganic matter and active inorganic matter can be reduced by 30-100%.
  • the strength of the cement component can be increased by at least 20%.
  • the color active mixed material can also be directly used as the mixed material for rural and ecological scenic spots. Research has found that it has higher strength and better color than the pavement paved with pure earth and stone. effect, and better resistance to rain erosion.
  • the present invention provides a coating.
  • the coating comprises 5-20wt% of a water-based high molecular polymer with a solid content of 50wt%, 2-17wt% of a Water, 70-95 wt% color active mixed material, the color active mixed material is the above color active mixed material, or the color active mixed material prepared by the above-mentioned method for preparing a color active mixed material.
  • the coating has good dispersibility, is not easy to agglomerate, has a long and stable gel time, is resistant to wind and sun after coating, is not easy to change color, and has an aging resistance test of more than 3500 hours.
  • the present invention provides a building block.
  • the building block comprises: 8-16wt% water, 0-10wt% acrylic rubber powder, 0- 15wt% water glass, 80-92wt% color active mixed material, the color active mixed material is the above-mentioned color active mixed material, or the color active mixed material prepared by the above-mentioned method for preparing a color active mixed material .
  • the colored active mixed material in the building block can replace the clay, the sintering process is omitted, and the strength of the obtained building block exceeds that of the red brick sintered at 800 degrees Celsius, and at the same time, its The color is fully controllable, and you can choose different colors according to your needs.
  • the present invention provides a sheet or board, the sheet or board is prepared by using the above-mentioned color active mixed material, or the color prepared by using the above-mentioned preparation of the color active mixed material. Prepared from active mixed materials.
  • the sheet or board according to the embodiment of the present invention by using the above-mentioned color active mixed material to prepare the sheet or board, a new possibility is provided for the existing architectural decoration field, and the obtained sheet or board can be bendable. Up to 40 degrees, the tensile strength and elongation at break at standard temperature can reach 5MPa and 80%, respectively, and the fire rating is A1.
  • the present invention provides a profile or shell, the profile or shell is prepared by using the above-mentioned color active mixed material, or the color obtained by using the above-mentioned preparation of the color active mixed material Prepared from active mixed materials.
  • the profiles or housings of the embodiments of the present invention by using the above-mentioned color active mixed materials to prepare the profiles or housings, a new possibility is provided for the field of existing household appliances and/or digital products, and the obtained profiles or housings
  • the impact strength is 0.5-5J*m -1
  • the density is 1.1-1.3 g/cm3
  • the fire rating is A
  • the artificial aging test can reach more than 3500h.
  • FIG. 1 is a schematic flow diagram of a method for preparing a color active mixed material according to an embodiment of the present invention
  • FIG. 2 is a schematic flowchart of a method for preparing a color active mixed material according to still another embodiment of the present invention.
  • the present invention provides a color active mixed material.
  • the color active mixed material includes: an inactive inorganic substance, an active inorganic substance, and a surface coating agent.
  • the inventor found that the color active mixed material has both inactive inorganic substances and active inorganic substances, and the surface coating agent is coated on the outer surfaces of the inactive inorganic substances and the active inorganic substances, and the surface coating agent also contains inactive inorganic substances. Under the action of the surface coating agent, the surfaces of the inactive inorganic materials and the active inorganic materials are homogenized and activated, so that the obtained color active mixed material has strong activity. usage has been significantly reduced.
  • the same color of the inactive inorganic substances can be mixed with the active inorganic substances of the same color to obtain a color active mixed material with the same color.
  • a color active mixed material that is different from the primary color of the inactive inorganic material and the active inorganic material can be obtained, which significantly enriches the color of the color active mixed material.
  • the specific types of the inactive inorganic substances and the active inorganic substances are not particularly limited, for example, the inactive inorganic substances can be selected from at least one of natural soil, quartz, and limestone.
  • the active inorganic substance can be selected from at least one of sintered red brick waste, cement waste, pozzolan, blast furnace slag, phosphate rock slag, and fly ash.
  • the inventor found that the above-mentioned inactive inorganic substances can be divided into four colors according to their natural colors: red, yellow, white and black.
  • the above-mentioned active inorganic substances can also be divided into four colors: red, yellow, white and black according to their natural colors.
  • the mass ratio of inactive inorganic substances to active inorganic substances in the above-mentioned color-active mixed material may not be particularly limited, for example, it may be 1:(1-4), and specifically, for example, it may be 1:1: 1/2/3/4.
  • inactive inorganic powders of different colors can be mixed with active inorganic powders.
  • mineral pigments may be added, and the mineral pigments may or may not be consistent with the colors of the inactive inorganic substances and the active inorganic substances after mixing.
  • the specific type of the mineral pigment is not particularly limited, for example, it may be selected from at least one of red iron oxide, yellow iron oxide, black iron oxide, carbon black, zinc oxide, and titanium white.
  • the mineral pigment when the color after mixing the active inorganic substance and the inactive inorganic substance is red, can be red iron oxide, and when the color after mixing the active inorganic substance and the inactive inorganic substance is yellow, the mineral pigment can be Iron oxide yellow, when the color after mixing the active inorganic substance and the inactive inorganic substance is gray, the mineral pigment can be at least one of iron oxide black and carbon black, and the color after mixing the active inorganic substance and the inactive inorganic substance When it is white, the mineral pigment can be at least one of zinc oxide and titanium dioxide.
  • the mass ratio of the sum of the mass of the inactive inorganic substances and the active inorganic substances to the mineral pigments may be 100:(0-20), for example, it may be 100:(0.2/ 0.5/1.0/5.0/10.0/15.0/20).
  • the surface coating agent coats the surfaces of the inactive inorganic substances and the active inorganic substances, so that the surfaces of the particles are homogenized and activated, thereby enhancing the activity of the obtained color active mixed material.
  • the amount of the surface coating agent may be 0.4-8% of the sum of the inactive inorganic substances and the active inorganic substances, such as 0.4%.
  • the amount of surface coating machine can be non-active inorganic and 0.2-5% of the total mass of active inorganic matter and mineral pigment, such as 0.2%/1%/2%/3%/4%/5%.
  • the specific type of the surface coating agent is not particularly limited, such as higher ammonium salts, octadecylamine, fluorocarbon surfactants, ⁇ -aminopropyl triethoxysilane, glutathione, semi- Cystine, gum arabic, gelatin, polypyrrolidone, 3-aminopropyltrimethoxysilane, dopamine, levodopa, dopamine hydrochloride, bovine serum albumin, polyethyleneimine, chitosan, tridecafluorooctane At least one of trimethoxysilane, tridecafluorooctyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, organic amine halogen acid, and oligopeptide one.
  • the color active mixed material has both non-active inorganic substances and active inorganic substances, and the surface coating agent is coated on the outer surfaces of the non-active inorganic substances and the active inorganic substances, and the surface is coated
  • the interior of the agent contains both inactive inorganic substances and active inorganic substances. Under the action of the surface coating agent, the surfaces of the inactive inorganic substances and active inorganic substances are homogenized and activated, so that the obtained color active mixed material has strong activity. Under the same conditions, the amount of active inorganic substances used is significantly reduced.
  • the same color of the inactive inorganic substances can be mixed with the active inorganic substances of the same color to obtain a color active mixed material with the same color.
  • a color active mixed material that is different from the primary color of the inactive inorganic material and the active inorganic material can be obtained, which significantly enriches the color of the color active mixed material.
  • this aspect proposes a method for preparing the above-mentioned color active mixed material.
  • the method includes:
  • the inactive inorganic substances are pulverized to predetermined particle sizes according to color, so as to obtain inactive inorganic substance powders of different colors and predetermined particle sizes.
  • the inventors found that by first classifying the inactive inorganic substances according to color, and then pulverizing them respectively, it is beneficial to realize subsequent color matching. In practice, those skilled in the art can configure color active mixed materials of different colors according to actual needs. In addition, non-active inorganic substances can retain their own natural color, with excellent color fixation and not easy to fade.
  • the specific particle size range of the inactive inorganic powder can be selected according to the final product to be prepared.
  • the final product requires the particle size of the inactive inorganic powder to be smaller, it can be smaller.
  • the product requires that the particle size of the inactive inorganic powder can be larger, for example, it can be 80-12000 mesh, specifically, it can be 80/120/200/300/400/600/800/1000/5000/10000 /12000 mesh, when pulverizing inactive inorganic powder, inactive inorganic powder can be pulverized to 80-120 mesh and/or 200-300 mesh and/or 400-600 mesh and/or 800-1000 mesh and/or 2000-3000 and/or 4000-5000 and/or 6000-7000 and/or 8000-9000 and/or 10000-11000 and/or 11000-12000 mesh, etc.
  • the active inorganic substances are pulverized to predetermined particle sizes according to color, so as to obtain active inorganic substance powders of different colors and predetermined particle sizes.
  • the inventors found that by first classifying the active inorganic substances according to color, and then pulverizing them separately, it is beneficial to realize subsequent color matching. In practice, those skilled in the art can configure color active mixed materials of different colors according to actual needs. In addition, the active inorganic substance can retain its own natural color, with excellent color fixation, and it is not easy to fade.
  • the specific particle size range of the active inorganic powder can be selected according to the final product to be prepared.
  • the final product requires the particle size of the active inorganic powder to be smaller, it can be smaller.
  • the particle size of the active inorganic powder is larger, it can be larger, such as 80-12000 mesh, specifically, such as 80/120/200/300/400/600/800/1000/5000/10000/12000 mesh .
  • inactive inorganic powder can be pulverized to 80-120 mesh and/or 200-300 mesh and/or 400-600 mesh and/or 800-1000 mesh and/or 2000-3000 mesh And/or 4000-5000 and/or 6000-7000 and/or 8000-9000 and/or 10000-11000 and/or 11000-12000 mesh, etc.
  • the inactive inorganic powder and the active inorganic powder are mixed to obtain mixed inorganic powders of different colors.
  • inactive inorganic powders of the same color can be mixed with active inorganic powders to obtain mixed inorganic powders with the same color as the natural color of the inactive inorganic powder and/or the natural color of the active inorganic powder.
  • Inorganic powders of different colors can also be mixed with active inorganic powders to obtain mixed inorganic powders whose colors are different from the natural color of the inactive inorganic powder and/or the natural color of the active inorganic powder.
  • inactive inorganic powders within the same particle size range can also be mixed with active inorganic powders according to the needs of the final product, or inactive inorganic powders with different particle size ranges can be mixed with active inorganic powders in the same particle size range.
  • the mixed inorganic powder and the surface coating agent are mixed and coated, so as to obtain a color active mixed material.
  • the inventor found that when the mixed inorganic powder and the surface coating agent are mixed uniformly, the surface coating agent coats the surface of the mixed inorganic powder. On the one hand, the surface coating agent can make the surface of the mixed inorganic powder more uniform.
  • the surface coating machine directly coats the surface of the mixed inorganic powder, multiple coats, such as two coats, can be used.
  • the mixed inorganic powder before the mixed inorganic powder is subjected to coating treatment, it may further include:
  • the mixed inorganic powder and the mineral pigment are mixed, and the inventors found that after adding the mineral pigment, the color of the mixed inorganic powder can be more distinct. Further, the color of the mineral pigment can be consistent with the color of the mixed inorganic powder, or it can be inconsistent, and can be selected according to actual needs. When the color of the inactive inorganic particles in the mixed inorganic powder is consistent with the color of the active inorganic particles, the use of mineral pigments that are consistent with the color of the inactive inorganic particles and/or the active inorganic particles can enhance the mixed inorganic particles. The color rendering of the powder makes it more vivid.
  • the resulting mixed inorganic may exhibit a different color from the inactive inorganic particles and/or the active inorganic particles.
  • mineral pigments consistent with the color of the mixed inorganic powder can be used to make the color more vivid.
  • Mineral pigments that do not match the color of the non-reactive inorganic particles and/or the active inorganic particles and/or mixed inorganic powders may also be employed to enrich the color of the color reactive hybrid material.
  • mineral pigments are different from chemical coatings, which have more excellent dyeing durability. When mineral pigments are added to the color active mixture material, the coating of the surface coating agent can be carried out in one coating.
  • the method for preparing the above-mentioned colored active mixed material by separately pulverizing inactive inorganic substances of different colors and active inorganic substances of different colors into powders, and then mixing the inactive inorganic powders with the active inorganic powders, whereby, a mixed inorganic powder with the same or different color as the raw material non-active inorganic powder or active inorganic powder can be obtained, which significantly enriches the color of the finally obtained color active mixed material. Further, because the colors of the inactive inorganic powder and the active inorganic powder are both the primary colors of the material itself, the color fixation degree of the obtained color active mixed material is much stronger than that of dyeing.
  • both the non-active inorganic powder and the active inorganic powder are covered by the surface coating agent, which can significantly improve the activity of the color active mixed material, while significantly reducing the active inorganic powder. With the dosage, the economic value of the entire color active mixed material is significantly improved.
  • the present invention proposes a cement component.
  • the cement component is prepared by using the above-mentioned color-active mixed material, or the color-active mixed material prepared by the above-mentioned method for preparing a color-active mixed material.
  • the color active mixed material can provide color matching for the cement component, and at the same time, due to the use of the colored active mixed material, the amount of cement can be reduced by 30-100%, and the amount of inactive inorganic matter and active inorganic matter can be reduced by 30-100%.
  • the strength of the cement component can be increased by at least 20%.
  • the color active mixed material can also be directly used as the mixed material for rural and ecological scenic spots. Research has found that it has higher strength and better color than the pavement paved with pure earth and stone. effect, and better resistance to rain erosion.
  • the present invention provides a coating.
  • the coating comprises 5-20wt% (eg 5/10/15/20wt%) of a water-based high Molecular polymer, 2-17wt% water, 70-95wt% (such as 70/75/80/85/90/95wt%) color active mixed material (eg ), the color active mixed material is the above color active mixed material, Or use the above-mentioned method for preparing the color active mixed material to prepare the obtained color active mixed material.
  • the coating has good dispersibility, is not easy to agglomerate, has a long and stable gel time, is resistant to wind and sun after coating, is not easy to change color, and has an aging resistance test of more than 3500 hours.
  • the coating When used for exterior walls, it has the characteristics of long-term non-discoloration and non-pulverization, and when used for interior walls, it has good ventilation, moisture-proof and environmental protection characteristics.
  • When directly made into sheets, plates or blocks for building exterior decoration it has the characteristics of long-term non-discoloration, non-pulverization, and the same durability as cement, stone, and ceramics.
  • the present invention provides a building block.
  • the building block comprises: 8-16wt% water, 0-10wt% (such as 0/2/4/6 /8/10wt%) acrylic rubber powder, 0-15wt% (eg 0/3/6/9/12/15wt%) water glass, 80-92wt% (eg 80/82/84/86/88/ 90/92 wt%) color active mixed material, the color active mixed material is the above-mentioned color active mixed material, or the color active mixed material prepared by the above-mentioned method for preparing a color active mixed material.
  • the colored active mixed material in the building block can replace the clay, the sintering process is omitted, and the strength of the obtained building block exceeds that of the red brick sintered at 800 degrees Celsius, and at the same time, its The color is fully controllable, and you can choose different colors according to your needs.
  • the present invention provides a sheet or plate, the sheet or plate is prepared by using the above-mentioned color-active mixed material, or the color-active mixture prepared by using the above-mentioned preparation of the color-active mixed material prepared from mixed materials.
  • the sheet or board according to the embodiment of the present invention by using the above-mentioned color active mixed material to prepare the sheet or board, a new possibility is provided for the existing architectural decoration field, and the obtained sheet or board can be bendable. Up to 40 degrees, the tensile strength and elongation at break at standard temperature can reach 5MPa and 80%, respectively, and the fire rating can reach A1.
  • the formulation of the sheet or plate may be: 80-91 wt % color active mixed material, 1-16 wt % (such as 1/4/8/12/16 wt %) water-based silicone PU, 1 -4wt% (1/2/3/4wt%) short fibers, 6-12wt% water, 1-3wt% (1/2/3wt%) dispersible polymer powder.
  • the above materials are mixed and slurried, injected into a mold, dried at 120 degrees Celsius for 1 hour, and formed into sheets or plates with a thickness of 3-10mm (such as 3/4/5/6/7/8/9/10mm).
  • the bendability of the sheet or plate can reach 40 degrees, the tensile strength and elongation at break at standard temperature can reach 5MPa and 80%, respectively, and the fire rating is A1.
  • the present invention provides a profile or shell, the profile or shell is prepared by using the above-mentioned color active mixed material, or the color active obtained by using the above-mentioned preparation of the color active mixed material prepared from mixed materials.
  • the profile or shell of the embodiment of the present invention by using the above-mentioned color active mixed material to prepare a sheet or a plate, a new possibility is provided for the field of existing household appliances and/or digital products, and the obtained profile or shell
  • the impact strength is 0.5-5J*m -1
  • the density is 1.1-1.3 g/cm3
  • the fire rating is A
  • the artificial aging test can reach more than 3500h.
  • the profile or shell may be formulated as: 80-90 wt% color active hybrid material, 6-12 wt% acrylic polymer with a solid content of 50%, 3-5 wt% redispersible Latex powder, 1-3wt% polyethylene fibers with a length of 0.3mm.
  • the above materials are mixed evenly, injected into a mold, and autoclaved at 140-160 degrees Celsius for 1.5-3 hours to obtain profiles or shells.
  • shell products suitable for different household appliances and digital appliances can be obtained to replace plastics, such as computer shells, refrigerator shells, washing machine shells, microwave oven shells, TV shells, mobile phone shells, etc.
  • the resulting profile or shell has an impact strength of 0.5-5J*m -1 , a density of 1.1-1.3 g/cubic centimeter, a fire rating of Class A, and an artificial aging resistance test of more than 3500h.
  • the formula composition of the color active mixture is:
  • the formula composition of the color active mixture is:
  • the surface coating agent is equal parts of fluorocarbon surfactant, ⁇ -aminopropyl triethoxysilane, and the mass ratio of inactive inorganic to active inorganic is 1:2, and the mass ratio of the inactive inorganic matter to the active inorganic matter and the surface coating agent is 100:3.
  • the formula composition of the color active mixture is:
  • Inactive inorganic limestone, active inorganic pozzolan, the surface coating agent is equal parts of glutathione and cysteine, the mass ratio of inactive inorganic to active inorganic is 1:3, inactive inorganic to The mass ratio of active inorganic matter and surface coating agent is 100:8,
  • the formula composition of the color active mixture is:
  • the inactive inorganic substances are equal parts of natural soil and quartz, the active inorganic substances are blast furnace slag, the mineral pigment is red iron oxide, and the surface coating agent is equal parts of gum arabic and gelatin.
  • the mass ratio is 1:4, the mass ratio of the sum of the mass of inactive inorganic substances and active inorganic substances to the mineral pigments is 100:0.2, the mass ratio of the sum of the mass of inactive inorganic substances and active inorganic substances, mineral pigments and the surface coating agent The mass ratio of 100:0.2.
  • the formula composition of the color active mixture is:
  • the inactive inorganic substances are equal parts of quartz and limestone, the active inorganic substances are phosphate rock ballast, the mineral pigment is iron oxide yellow, and the surface coating agent is equal parts of polypyrrolidone and 3-aminopropyltrimethoxysilane, inactive
  • the mass ratio of inorganic matter to active inorganic matter is 1:1.5, the mass ratio of the sum of the mass of inactive inorganic matter and active inorganic matter to mineral pigment is 100:5, and the mass ratio of inactive inorganic matter to active inorganic matter and mineral pigment is 100:5.
  • the mass ratio of the sum to the surface coating agent is 100:2.
  • the formula composition of the color active mixture is:
  • Inactive inorganic substances are equal parts of natural soil, quartz and limestone, active inorganic substances are fly ash, mineral pigments are equal parts of iron oxide black and carbon black, and surface coating agents are equal parts of dopamine, levodopa, Dopamine hydrochloride, bovine serum albumin, the mass ratio of inactive inorganic substances to active inorganic substances is 1:2.5, the mass ratio of the sum of the mass of inactive inorganic substances and active inorganic substances to mineral pigments is 100:10, and the inactive inorganic substances are in a mass ratio of 100:10. The mass ratio of the sum of the mass of inorganic substances, active inorganic substances and mineral pigments to the surface coating agent is 100:3;
  • the formula composition of the color active mixture is:
  • Inactive inorganic substances are equal parts of quartz and limestone, active inorganic substances are equal parts of sintered red bricks, cement bricks, and pozzolans, mineral pigments are equal parts of zinc oxide and titanium dioxide, and surface coating agents are equal parts Tridecafluorooctyltrimethoxysilane, tridecafluorooctyltriethoxysilane, heptadecafluorodecyltriethoxysilane, heptadecafluorodecyltrimethoxysilane, inactive inorganic and active inorganic
  • the mass ratio of inactive inorganic substances and active inorganic substances is 1:3.5, the mass ratio of the sum of inactive inorganic substances and active inorganic substances to mineral pigments is 100:20, and the mass ratio of inactive inorganic substances and active inorganic substances, mineral pigments and surface coating
  • the mass ratio of the coating agent is 100:5.
  • Preparation of the color active mixed material in Example 1 pulverize the inactive inorganic matter to a predetermined particle size of 80-120 mesh to obtain an inactive inorganic powder with a predetermined particle size; pulverize the active inorganic substance to a predetermined particle size of 80-120 mesh to obtain the active inorganic powder of predetermined particle size; the non-active inorganic powder and the active inorganic powder are mixed to obtain the mixed inorganic powder; the mixed inorganic powder and the surface coating agent are mixed and coated to obtain the color active mixed material.
  • the obtained colored active mixed material is directly molded to obtain a cement component.
  • the cement component realizes percent replacement of cement, and the strength is increased by 30%, and the phenomenon of efflorescence does not occur at the same time.
  • Preparation of the color active mixed material in Example 2 pulverize the inactive inorganic matter to a predetermined particle size of 200-300 mesh to obtain an inactive inorganic powder with a predetermined particle size; pulverize the active inorganic substance to a predetermined particle size of 200-300 mesh to obtain the active inorganic powder of predetermined particle size; the non-active inorganic powder and the active inorganic powder are mixed to obtain the mixed inorganic powder; the mixed inorganic powder and the surface coating agent are mixed and coated to obtain the color active mixed material.
  • the obtained color active mixed material is directly shaped to obtain a road mixed material. When the pavement mixture is used as a pavement mixture in rural and ecological scenic spots, it has higher strength, better color effect, and better resistance to rainwater erosion than pavement paved with pure earth and stone.
  • the color active mixed material is prepared by using the formula of Example 3, specifically: pulverizing the inactive inorganic matter to a predetermined particle size of 400-600 mesh to obtain inactive inorganic powder with a predetermined particle size; Pulverize the powder to a predetermined particle size of 400-600 mesh to obtain an active inorganic powder with a predetermined particle size; mix the non-active inorganic powder and the active inorganic powder to obtain a mixed inorganic powder; mix the mixed inorganic powder and the surface coating agent Mix and coat to obtain a color active mixed material.
  • the coating is prepared by mixing the above-mentioned water-based macromolecular polymer, water and color active mixed material.
  • the coating has good dispersibility, is not easy to agglomerate, and has a long and stable gelling time. When used for exterior walls, it has the characteristics of long-term non-discoloration and non-pulverization, and when used for interior walls, it has good ventilation, moisture-proof and environmental protection characteristics.
  • the color active mixed material is prepared by using the formula of Example 4, specifically: pulverizing the inactive inorganic matter to a predetermined particle size of 800-1000 mesh to obtain an inactive inorganic powder with a predetermined particle size; Pulverize the powder to a predetermined particle size of 800-1000 mesh to obtain an active inorganic powder with a predetermined particle size; mix the inactive inorganic powder and the active inorganic powder to obtain a mixed inorganic powder; mix the mixed inorganic powder and mineral pigments, Then, it is mixed and coated with a surface coating agent to obtain a color active mixed material.
  • the coating is prepared by mixing the above-mentioned water-based macromolecular polymer, water and color active mixed material.
  • the coating has good dispersibility, is not easy to agglomerate, and has a long and stable gelling time. When used for exterior walls, it has the characteristics of long-term non-discoloration and non-pulverization, and when used for interior walls, it has good ventilation, moisture-proof and environmental protection characteristics.
  • the color active mixed material is prepared by using the formula of Example 5, specifically: pulverizing the inactive inorganic matter to a predetermined particle size of 2000-3000 mesh to obtain an inactive inorganic powder with a predetermined particle size; Pulverize the powder to a predetermined particle size of 2000-3000 mesh to obtain an active inorganic powder with a predetermined particle size; mix the inactive inorganic powder and the active inorganic powder to obtain a mixed inorganic powder; mix the mixed inorganic powder and mineral pigments, Then, it is mixed and coated with a surface coating agent to obtain a color active mixed material.
  • the coating is prepared by mixing the above-mentioned water-based macromolecular polymer, water and color active mixed material.
  • the coating has good dispersibility, is not easy to agglomerate, and has a long and stable gelling time. When used for exterior walls, it has the characteristics of long-term non-discoloration and non-powdering, and when used for interior walls, it has good ventilation, moisture-proof and environmental protection characteristics.
  • the color active mixed material is prepared by using the formula of Example 6, specifically: pulverizing the inactive inorganic matter to a predetermined particle size of 4000-5000 mesh to obtain an inactive inorganic powder with a predetermined particle size; Pulverize to a predetermined particle size of 4000-5000 mesh to obtain active inorganic powder of predetermined particle size; mix inactive inorganic powder and active inorganic powder to obtain mixed inorganic powder; mix mixed inorganic powder and mineral pigment, and then It is mixed and coated with a surface coating agent to obtain a color active mixed material.
  • the color active mixed material in the building brick can replace clay, save the sintering process, and its strength exceeds that of red brick sintered at 800 degrees Celsius. At the same time, its color is completely controllable, and different colors can be selected according to needs.
  • the color active mixed material is prepared by using the formula of Example 7, specifically: pulverizing the inactive inorganic material to a predetermined particle size of 6000-7000 mesh to obtain inactive inorganic powder with a predetermined particle size; Pulverize to a predetermined particle size of 6000-7000 mesh to obtain active inorganic powder with a predetermined particle size; mix inactive inorganic powder and active inorganic powder to obtain mixed inorganic powder; mix mixed inorganic powder and mineral pigment, and then It is mixed and coated with a surface coating agent to obtain a color active mixed material.
  • the color active mixed material in the building brick can replace clay, save the sintering process, and its strength exceeds that of red brick sintered at 800 degrees Celsius. At the same time, its color is completely controllable, and different colors can be selected according to needs.
  • the color active mixed material is prepared by using the formula of Example 1, specifically: pulverizing the inactive inorganic matter to a predetermined particle size of 80-120 meshes to obtain an inactive inorganic powder with a predetermined particle size; Pulverize to a predetermined particle size of 80-120 mesh to obtain active inorganic powder of predetermined particle size; mix inactive inorganic powder and active inorganic powder to obtain mixed inorganic powder; mix mixed inorganic powder and surface coating agent Coating to obtain a color active mixed material.
  • the color active mixed material in the building brick can replace clay, save the sintering process, and its strength exceeds that of red brick sintered at 800 degrees Celsius. At the same time, its color is completely controllable, and different colors can be selected according to needs.
  • the color active mixed material is prepared by using the formula of Example 2. Specifically: pulverize the inactive inorganic material to a predetermined particle size of 8000-9000 mesh to obtain inactive inorganic powder with a predetermined particle size; Pulverize to a predetermined particle size of 8000-9000 mesh to obtain an active inorganic powder with a predetermined particle size; mix inactive inorganic powder and active inorganic powder to obtain mixed inorganic powder; mix mixed inorganic powder and surface coating agent Coating to obtain a color active mixed material.
  • the above materials were mixed and slurried, injected into a mold, dried at 120 degrees Celsius for 1 hour, and formed into a sheet with a thickness of 3 mm.
  • the bendability of the sheet can reach 40 degrees
  • the tensile strength and elongation at break at standard temperature can reach 5MPa and 80%, respectively, and the fire rating is A1.
  • it has the characteristics of long-term non-discoloration and non-pulverization, and is as durable as cement, stone, and ceramics.
  • the color active mixed material is prepared by using the formula of Example 3. Specifically: pulverize the inactive inorganic matter to a predetermined particle size of 800-1000 mesh to obtain an inactive inorganic powder with a predetermined particle size; Pulverize to a predetermined particle size of 800-1000 mesh to obtain active inorganic powder of predetermined particle size; mix inactive inorganic powder and active inorganic powder to obtain mixed inorganic powder; mix mixed inorganic powder and surface coating agent Coating to obtain a color active mixed material.
  • the above materials were mixed and slurried, injected into a mold, dried at 120 degrees Celsius for 1 hour, and formed into a sheet with a thickness of 6 mm.
  • the bendability of the sheet can reach 40 degrees
  • the tensile strength and elongation at break at standard temperature can reach 5MPa and 80%, respectively, and the fire rating is A1.
  • it has the characteristics of long-term non-discoloration and non-pulverization, and is as durable as cement, stone, and ceramics.
  • the color active mixed material is prepared by using the formula of Example 4. Specifically: pulverize the inactive inorganic material to a predetermined particle size of 400-600 mesh to obtain inactive inorganic powder with a predetermined particle size; Pulverize to a predetermined particle size of 400-600 mesh to obtain active inorganic powder of predetermined particle size; mix inactive inorganic powder and active inorganic powder to obtain mixed inorganic powder; mix mixed inorganic powder and mineral pigment with The surface coating agent is mixed and coated to obtain a color active mixed material.
  • the above materials were mixed and made into a slurry, injected into a mold, dried at 120 degrees Celsius for 1 hour, and formed into a plate with a thickness of 10 mm.
  • the bendability of the board can reach 40 degrees, the tensile strength and elongation at break at standard temperature can reach 5MPa and 80%, respectively, and the fire rating is A1.
  • it has the characteristics of long-term non-discoloration and non-pulverization, and is as durable as cement, stone, and ceramics.
  • the color active mixed material is prepared by using the formula of Example 3, specifically: pulverizing the inactive inorganic matter to a predetermined particle size of 400-600 mesh to obtain inactive inorganic powder with a predetermined particle size; Pulverize the powder to a predetermined particle size of 400-600 mesh to obtain an active inorganic powder with a predetermined particle size; mix the non-active inorganic powder and the active inorganic powder to obtain a mixed inorganic powder; mix the mixed inorganic powder and the surface coating agent Mix and coat to obtain a color active mixed material.
  • the above materials are mixed uniformly, injected into a mold, and autoclaved at 140 degrees Celsius for 3 hours to obtain a computer casing.
  • the impact strength is 5J*m -1
  • the density is 1.1 g/cm3
  • the fire rating is A
  • the artificial aging test can reach more than 3500h.
  • the color active mixed material is prepared by using the formula of Example 6, specifically: pulverizing the inactive inorganic matter to a predetermined particle size of 10,000-11,000 mesh to obtain inactive inorganic powder with a predetermined particle size; Pulverize the powder to a predetermined particle size of 10,000-11,000 mesh to obtain an active inorganic powder with a predetermined particle size; mix the inactive inorganic powder and the active inorganic powder to obtain a mixed inorganic powder; mix the mixed inorganic powder and mineral pigments It is mixed and coated with a surface coating agent to obtain a color active mixed material.
  • the above materials were mixed uniformly, injected into a mold, and autoclaved at 150 degrees Celsius for 2 hours to obtain a refrigerator shell. Its impact strength is 4J*m -1 , the density is 1.25 g/cm3, the fire rating is A, and the artificial aging test can reach more than 3500h.
  • the color active mixed material is prepared by using the formula of Example 7, specifically: pulverizing the inactive inorganic matter to a predetermined particle size of 11,000-12,000 mesh to obtain inactive inorganic powder with a predetermined particle size; Pulverize the powder to a predetermined particle size of 11000-12000 mesh to obtain an active inorganic powder with a predetermined particle size; mix the inactive inorganic powder and the active inorganic powder to obtain a mixed inorganic powder; mix the mixed inorganic powder and mineral pigments It is mixed and coated with a surface coating agent to obtain a color active mixed material.
  • the above materials are mixed uniformly, injected into a mold, and autoclaved at 160 degrees Celsius for 1.5 hours to obtain a mobile phone case. Its impact strength is 3.5J*m -1 , the density is 1.1 g/cm3, the fire rating is A, and the artificial aging test can reach more than 3500h.

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Abstract

本发明公开了一种彩色活性混合材料及其制备方法和应用，包括：非活性无机物、活性无机物、表面包覆剂。该彩色活性混合材料同时具有非活性无机物和活性无机物，表面包覆剂包覆于非活性无机物和活性无机物的外表面，在表面包覆剂的作用下，非活性无机物和活性无机物的表面得到均化和活化，使得彩色活性混合材料在具有较强活性的条件下，活性无机物的使用量显著降低。同时由于非活性无机物和活性无机物本身自带颜色，采用同样颜色的非活性无机物与活性无机物混合可得到与其颜色一致的彩色活性混合材料，而采用不同颜色的非活性无机物和活性无机物混合，可得区别于非活性无机物和活性无机物原色的彩色活性混合材料，丰富了彩色活性混合材料的颜色。

Description

彩色活性混合材料及其制备方法和应用 技术领域
本发明属于无机物技术领域，具体而言，本发明涉及彩色活性混合材料及其制备方法和应用。
背景技术
天然土、石英、石灰石等非活性无机物具有天然的颜色，如红色、黄色、白色、黑色，同样的，烧结红砖弃块、水泥弃块、火山灰、高炉矿渣、磷矿渣、粉煤灰等活性材料也具有天然的颜色，如红色、黄色、白色、黑色，但颜色的种类不够丰富。现有装饰材料，一般通过添加化学颜料来呈现出不同的颜色，采用这种方法所得材料的固色性差。同时为了得到活性较高的材料，一般对于活性无机物的需求量较大，导致整个材料的成本较高。同时，现有建筑材料多用水泥，成本较高，且存在泛碱的问题；生活中塑料用品广泛，对环境有害。
因此，本申请基于现有无机物，通过改性，探寻更多可能，为建筑、生活等领域提供更多的可能。
发明内容
本发明旨在至少在一定程度上解决相关技术中的技术问题之一。为此，本发明的一个目的在于提出一种彩色活性混合材料及其制备方法和应用。该彩色活性混合材料在具有较强活性的条件下，活性无机物的使用量显著降低。同时颜色得到显著丰富。
在本发明的一个方面，本发明提出了一种彩色活性混合材料，根据本发明的实施例，所述彩色活性混合材料包括：非活性无机物、活性无机物、表面包覆剂。
根据本发明实施例的彩色活性混合材料，该彩色活性混合材料同时具有非活性无机物和活性无机物，且表面包覆剂包覆于非活性无机物和活性无机物的外表面，表面包覆剂内部同时含有非活性无机物和活性无机物，在表面包覆剂的作用下，非活性无机物和活性无机物的表面得到均化和活化，使得所得的彩色活性混合材料在具有较强活性的条件下，活性无机物的使用量显著降低。同时由于非活性无机物和活性无机物本身自带颜色，采用同样颜色的非活性无机物与同样颜色的活性无机物混合可得到与其颜色一致的彩色活性混合材料，而采用不同颜色的非活性无机物和活性无机物混合后，可得到区别于非活性无机物和活性无机物原色的彩色活性混合材料，显著丰富了彩色活性混合材料的颜色。
另外，根据本发明上述实施例的彩色活性混合材料还可以具有如下附加的技术特征：
在本发明的一些实施例中，所述非活性无机物与所述活性无机物的质量比为1∶(1-4)。
在本发明的一些实施例中，所述非活性无机物与所述活性无机物的质量和与所述表面包覆剂的质量比为100∶0.4-8。
在本发明的一些实施例中，所述彩色活性混合材料进一步包括矿物颜料。
在本发明的一些实施例中，所述非活性无机物和所述活性无机物的质量之和与所 述矿物颜料的质量比为100∶(0-20)。
在本发明的一些实施例中，所述非活性无机物和所述活性无机物、所述矿物颜料的质量之和与所述表面包覆剂的质量比为100∶0.2-5。
在本发明的一些实施例中，所述非活性无机物选自天然土、石英、石灰石中的至少之一。
在本发明的一些实施例中，所述活性无机物选自烧结红砖弃块、水泥弃块、火山灰、高炉矿碴、磷矿碴、粉煤灰中的至少之一。
在本发明的一些实施例中，所述矿物颜料选自氧化铁红、氧化铁黄、氧化铁黑、炭黑、氧化锌、钛白中的至少之一。
在本发明的一些实施例中，所述表面包覆剂选自高级铵盐、十八胺、氟碳表面活性剂、γ-氨丙基三乙氧基硅烷、谷胱甘肽、半胱氨酸、阿拉伯胶、明胶、聚吡咯烷酮、3-氨基丙基三甲氧基硅烷、多巴胺、左旋多巴、多巴胺盐酸盐、牛血清蛋白、聚乙烯亚胺、壳聚糖、十三氟辛基三甲氧基硅烷、十三氟辛基三乙氧基硅烷、十七氟癸基三乙氧基硅烷、十七氟癸基三甲氧基硅烷、有机胺卤酸、寡肽中的至少之一。
在本方面的再一个方面，本方面提出了一种制备上述彩色活性混合材料的方法，根据本发明的实施例，所述方法包括：
将非活性无机物按照颜色分别粉碎至预定粒径，以便得到不同颜色预定粒径的非活性无机物粉末；
将活性无机物按照颜色分别粉碎至预定粒径，以便得到不同颜色预定粒径的活性无机物粉末；
将所述非活性无机物粉末和所述活性无机物粉末混合，以便得到不同颜色的混合无机物粉末；
将所述混合无机物粉末和表面包覆剂混合包覆，以便得到彩色活性混合材料。
根据本发明实施例的制备上述彩色活性混合材料的方法，通过将不同颜色非活性无机物和不同颜色的活性无机物分别粉碎成预定粒径粉末，然后再将非活性无机物粉末与活性无机物粉末混合，由此可得到与原料非活性无机物粉末或活性无机物粉末颜色一致或不一致的预定粒径范围的混合无机物粉末，显著丰富了最终所得彩色活性混合材料的颜色。进一步的，因非活性无机物粉末和活性无机物粉末的颜色都是材料本身的原色，使得所得的彩色活性混合材料的颜色固色度相比于染色要强得多。通过将混合无机物粉末进行包覆，使得非活性无机物粉末和活性无机物粉末都被表面包覆剂包覆于内部，可显著提高彩色活性混合材料的活性，同时显著降低了活性无机物的用量，使得整个彩色活性混合材料的经济价值显著提高。
另外，根据本发明上述实施例的彩色活性混合材料还可以具有如下附加的技术特征：
在本发明的一些实施例中，在将所述混合无机物粉末进行所述包覆处理之前，将所述混合无机物粉末和矿物颜料混合。
在本发明的一些实施例中，所述非活性无机物粉末的粒径为80-12000目。
在本发明的一些实施例中，所述活性无机物粉末的粒径为80-12000目。
在本发明的又一个方面，本发明提出了一种水泥构件，根据本发明的实施例，所述 水泥构件采用上述彩色活性混合材料制备而成，或采用上述制备彩色活性混合材料的方法制备所得的所述彩色活性混合材料制备而成。根据本发明实施例的水泥构件，彩色活性混合材料可以为水泥构件提供颜色调配，同时因采用了彩色活性混合材料，水泥的用量可减少30-100％，且非活性无机物与活性无机物的配合，可使水泥构件的强度增加至少20％。进一步的，在节省和/或替代水泥这方面，也可以直接将彩色活性混合材料作为乡村、生态景区路面混合材料，研究发现，其比纯土石铺设的路面具有更高的强度，更优异的彩色效果，以及更优的耐雨水冲刷的特点。
在本发明的又一个方面，本发明提出了一种涂料，根据本发明的实施例，所述涂料包括5-20wt％的固含量为50wt％的水基高分子聚合物、2-17wt％的水、70-95wt％的彩色活性混合材料，所述彩色活性混合材料为上述彩色活性混合材料，或采用上述制备彩色活性混合材料的方法制备所得的所述彩色活性混合材料。根据本发明实施例的涂料，该涂料分散性好，不易结团，胶凝时间长且稳定，涂覆后耐风吹日晒，不易变色，耐老化实验可达3500h以上。用于外墙时，具有长期不变色、不粉化的特性，用于内墙时具有很好的透气、防潮、环保特性。直接制成片材、板材或块材用于建筑外装饰时，具有长期不变色、不粉化、如同水泥、石材、陶瓷一样耐久的特性。
在本发明的又一个方面，本发明提出了一种建筑砖块，根据本发明的实施例，所述建筑砖块包括：8-16wt％的水、0-10wt％的丙烯酸胶粉、0-15wt％的水玻璃、80-92wt％的彩色活性混合材料，所述彩色活性混合材料是上述的彩色活性混合材料，或是采用上述制备彩色活性混合材料的方法制备所得的所述彩色活性混合材料。根据本发明实施例的建筑砖块，该建筑砖块中的彩色活性混合材料可替代黏土，省去烧结工艺，且所得的建筑砖块强度超过800摄氏度下烧结的红砖的强度，同时，其颜色完全可控，可以根据需要选择不同的颜色。
在本发明的又一个方面，本发明提出了一种片材或板材，所述片材或板材是采用上述彩色活性混合材料制备而成，或采用上述制备彩色活性混合材料制备所得的所述彩色活性混合材料制备而成。根据本发明实施例的片材或板材，通过采用上述彩色活性混合材料制备片材或板材，为现有建筑装饰领域提供了一种新的可能，且所得的片材或板材的可弯曲度可达40度，标准温度下拉伸强度和断裂伸长率分别可达5MPa和80％，防火等级为A1级。
在本发明的又一个方面，本发明提出了一种型材或壳体，所述型材或壳体是采用上述彩色活性混合材料制备而成，或采用上述制备彩色活性混合材料制备所得的所述彩色活性混合材料制备而成。根据本发明实施例的型材或壳体，通过采用上述彩色活性混合材料制备型材或壳体，为现有生活电器和/或数码产品领域提供了一种新的可能，且所得的型材或壳体的抗冲击强度为0.5-5J*m -1，密度为1.1-1.3克/立方厘米，防火等级为A级，人工耐老化实验可达3500h以上。
本发明的附加方面和优点将在下面的描述中部分给出，部分将从下面的描述中变得明显，或通过本发明的实践了解到。
附图说明
本发明的上述和/或附加的方面和优点从结合下面附图对实施例的描述中将变得 明显和容易理解，其中：
图1是根据本发明一个实施例的制备彩色活性混合材料的方法流程示意图；
图2是根据本发明再一个实施例的制备彩色活性混合材料的方法流程示意图。
具体实施方式
下面详细描述本发明的实施例，所述实施例的示例在附图中示出，其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的，旨在用于解释本发明，而不能理解为对本发明的限制。
在本发明的一个方面，本发明提出了一种彩色活性混合材料，根据本发明的实施例，所述彩色活性混合材料包括：非活性无机物、活性无机物、表面包覆剂。发明人发现，该彩色活性混合材料同时具有非活性无机物和活性无机物，且表面包覆剂包覆于非活性无机物和活性无机物的外表面，表面包覆剂内部同时含有非活性无机物和活性无机物，在表面包覆剂的作用下，非活性无机物和活性无机物的表面得到均化和活化，使得所得的彩色活性混合材料在具有较强活性的条件下，活性无机物的使用量显著降低。同时由于非活性无机物和活性无机物本身自带颜色，采用同样颜色的非活性无机物与同样颜色的活性无机物混合可得到与其颜色一致的彩色活性混合材料，而采用不同颜色的非活性无机物和活性无机物混合后，可得到区别于非活性无机物和活性无机物原色的彩色活性混合材料，显著丰富了彩色活性混合材料的颜色。
根据本发明的一些实施例，非活性无机物和活性无机物的具体类型并不受特别限制，如非活性无机物可以选自天然土、石英、石灰石中的至少之一。活性无机物可以选自烧结红砖弃块、水泥弃块、火山灰、高炉矿碴、磷矿碴、粉煤灰中的至少之一。发明人发现，上述非活性无机物可以按照其天然色分为红、黄、白、黑四色，同样，上述活性无机物也可以按照其天然色分为红、黄、白、黑四色。
根据本发明的一些实施例，上述彩色活性混合材料中非活性无机物与活性无机物的质量比可以不受特别限制，如可以为1∶(1-4)，具体的，如可以为1∶1/2/3/4。
为了使彩色活性混合材料的颜色更加丰富，可以采用不同颜色的非活性无机物粉末与活性无机物粉末混合。进一步的，为了使彩色活性混合材料的颜色更加鲜明，可以添加矿物颜料，该矿物颜料可以与非活性无机物和活性无机物混合后的颜色一致，也可以不一致。根据本发明的一些实施例，矿物颜料的具体类型并不受特别限制，如可以选自氧化铁红、氧化铁黄、氧化铁黑、炭黑、氧化锌、钛白中的至少之一。具体的，如当活性无机物与非活性无机物混合之后的颜色为红色时，矿物颜料可以为氧化铁红，当活性无机物与非活性无机物混合之后的颜色为黄色时，矿物颜料可以为氧化铁黄，当活性无机物与非活性无机物混合之后的颜色为灰色时，矿物颜料可以为氧化铁黑、炭黑中的至少之一，当活性无机物与非活性无机物混合之后的颜色为白色时，矿物颜料可以为氧化锌、钛白中的至少之一。
根据本发明的一些实施例，当添加矿物颜料时，非活性无机物和活性无机物的质量之和与矿物颜料的质量比可以为100∶(0-20)，如可以为100∶(0.2/0.5/1.0/5.0/10.0/15.0/20)。发明人发现，通过添加上述比例的矿物颜料，可使得非活性无机物和活性无机物的混合物的色彩更加鲜明，或者染上区别于非活性无机物、活性无机物、两者混合物的颜色。
表面包覆剂包覆于非活性无机物与活性无机物的表面，使得粒子表面得到均化和活化，进而提升所得彩色活性混合材料的活性。根据本发明的一些实施例，当彩色活性混合材料中不包含有矿物颜料时，表面包覆剂的用量可以为非活性无机物和活性无机物质量之和的0.4-8％，如可以为0.4％/1％/2％/3％/4％/5％/6％/7％/8％；当彩色活性混合材料中含有矿物颜料时，表面包覆机的用量可以为非活性无机物和活性无机物、矿物颜料的质量之和的0.2-5％，如可以为0.2％/1％/2％/3％/4％/5％。进一步的，表面包覆剂的具体类型并不受特别限制，如可以为高级铵盐、十八胺、氟碳表面活性剂、γ-氨丙基三乙氧基硅烷、谷胱甘肽、半胱氨酸、阿拉伯胶、明胶、聚吡咯烷酮、3-氨基丙基三甲氧基硅烷、多巴胺、左旋多巴、多巴胺盐酸盐、牛血清蛋白、聚乙烯亚胺、壳聚糖、十三氟辛基三甲氧基硅烧、十三氟辛基三乙氧基硅烷、十七氟癸基三乙氧基硅烷、十七氟癸基三甲氧基硅烷、有机胺卤酸、寡肽中的至少之一。
根据本发明实施例的彩色活性混合材料，该彩色活性混合材料同时具有非活性无机物和活性无机物，且表面包覆剂包覆于非活性无机物和活性无机物的外表面，表面包覆剂内部同时含有非活性无机物和活性无机物，在表面包覆剂的作用下，非活性无机物和活性无机物的表面得到均化和活化，使得所得的彩色活性混合材料在具有较强活性的条件下，活性无机物的使用量显著降低。同时由于非活性无机物和活性无机物本身自带颜色，采用同样颜色的非活性无机物与同样颜色的活性无机物混合可得到与其颜色一致的彩色活性混合材料，而采用不同颜色的非活性无机物和活性无机物混合后，可得到区别于非活性无机物和活性无机物原色的彩色活性混合材料，显著丰富了彩色活性混合材料的颜色。
在本方面的再一个方面，本方面提出了一种制备上述彩色活性混合材料的方法，根据本发明的实施例，参考图1，该方法包括：
S100：将非活性无机物按照颜色分别粉碎至预定粒径
该步骤中，将非活性无机物按照颜色分别粉碎至预定粒径，以便得到不同颜色预定粒径的非活性无机物粉末。发明人发现，通过按照颜色先将非活性无机物分类，再分别进行粉碎，有利于实现后续的配色，在实践过程中，本领域技术人员可以根据实际需要配置出不同颜色的彩色活性混合材料。且非活性无机物可以保留自身的天然色，固色度优异，不容易掉色。
根据本发明的一些实施例，非活性无机物粉末的具体粒径范围可以根据最终需要制得的产品进行选择，当最终产品要求非活性无机物粉末的粒径小些时可以小些，当最终产品要求非活性无机物粉末的粒径大些时可以大些，如可以为80-12000目，具体的，如可以为80/120/200/300/400/600/800/1000/5000/10000/12000目，在粉碎非活性无机物粉末时，可以将非活性无机物粉末粉碎至80-120目和/或200-300目和/或400-600目和/或800-1000目和/或2000-3000和/或4000-5000和/或6000-7000和/或8000-9000和/或10000-11000和/或11000-12000目等。
S200：将活性无机物按照颜色分别粉碎至预定粒径
该步骤中，将活性无机物按照颜色分别粉碎至预定粒径，以便得到不同颜色预定粒径的活性无机物粉末。发明人发现，通过按照颜色先将活性无机物分类，再分别进行粉碎，有利于实现后续的配色，在实践过程中，本领域技术人员可以根据实际需要配置出不同颜色的彩色活性混合材料。且活性无机物可以保留自身的天然色，固色度优异，不容易掉 色。
根据本发明的一些实施例，活性无机物粉末的具体粒径范围可以根据最终需要制得的产品进行选择，当最终产品要求活性无机物粉末的粒径小些时可以小些，当最终产品要求活性无机物粉末的粒径大些时可以大些，如可以为80-12000目，具体的，如可以为80/120/200/300/400/600/800/1000/5000/10000/12000目，在粉碎非活性无机物粉末时，可以将非活性无机物粉末粉碎至80-120目和/或200-300目和/或400-600目和/或800-1000目和/或2000-3000和/或4000-5000和/或6000-7000和/或8000-9000和/或10000-11000和/或11000-12000目等。
S300：将非活性无机物粉末和活性无机物粉末混合
该步骤中，将非活性无机物粉末和活性无机物粉末混合，以便得到不同颜色的混合无机物粉末。发明人发现，在该步骤中，可以将相同颜色的非活性无机物粉末与活性无机物粉末混合，以得到颜色与非活性无机物粉末天然色和/或活性无机物粉末天然色相同的混合无机物粉末；也可以将不同颜色的非活性无机物粉末与活性无机物粉末混合，以得到颜色与非活性无机物粉末天然色和/或活性无机物粉末天然色不相同的混合无机物粉末。由此，避免了非活性无机物粉末和活性无机物粉末天然色的局限性，显著丰富了彩色活性混合材料的颜色。且因非活性无机物和活性无机物本身自带天然色，使得所得的彩色活性混合材料的颜色表观更自然和固色度更高。同样，也可以根据最终产品的需要将相同粒径范围内的非活性无机物粉末与活性无机物粉末混合，或者将不同粒径范围的非活性无机物粉末与同一粒径范围内的活性无机物粉末混合，或者将相同粒径范围内的非活性无机物粉末与不同粒径范围内的活性无机物粉末混合，或者将不同粒径范围内的非活性无机物粉末与不同粒径范围内的活性无机物粉末混合，以满足不同产品的需求。
S400：将混合无机物粉末和表面包覆剂混合包覆
该步骤中，将混合无机物粉末和表面包覆剂混合包覆，以便得到彩色活性混合材料。发明人发现，在将混合均匀的混合无机物粉末与表面包覆剂混合时，表面包覆剂包覆于混合无机物粉末表面，一方面，表面包覆剂可以使得混合无机物粉末表面更加均匀化，一方面可以提高颗粒表面的活性，使得所得的彩色活性混合材料具有较优的活性，进一步的，因混合无机物粉末中同时包含有非活性无机物粉末颗粒和活性无机物粉末颗粒，在包覆剂的作用下，使得两者之间的作用加强，得到性能优于单独的非活性无机物和活性无机物，效果显著。表面包覆机直接包覆于混合无机物粉末表面时，可以采用多次包覆，如两次包覆。
根据本发明的实施例，参考图2，在将混合无机物粉末进行包覆处理之前，可进一步包括：
S500：将混合无机物粉末和矿物颜料混合
该步骤中，将混合无机物粉末和矿物颜料混合，发明人发现，加入矿物颜料后，可使混合无机物粉末的颜色更加分明。进一步的，矿物颜料的颜色可以与混合无机物粉末的颜色一致，也可以不一致，可以根据实际需要进行选择。当混合无机物粉末中的非活性无机物颗粒的颜色与活性无机物颗粒的颜色一致时，采用与非活性无机物颗粒和/或活性无机物颗粒的颜色一致的矿物颜料，可以加强混合无机物粉末的显色度，使其色彩更加鲜明。当混合无机物粉末中的非活性无机物颗粒的颜色与活性无机物颗粒的颜色不一致时，当颗粒度较小时，所得的混合无机物可以呈现出不同于非活性无机物颗粒和/或活性无机物颗粒 的颜色，此时可以采用与混合无机物粉末颜色一致的矿物颜料，使其色彩更加鲜明。也可以采用与非活性无机物颗粒和/或活性无机物颗粒和/或混合无机物粉末颜色不一致的矿物颜料，以丰富彩色活性混合材料的颜色。同时矿物颜料不同于化学涂料，其具有更优异的染色持久度。当彩色活性混合材料中添加了矿物颜料时，表面包覆剂的包覆可以采用一次包覆。
根据本发明实施例的制备上述彩色活性混合材料的方法，通过将不同颜色非活性无机物和不同颜色的活性无机物分别粉碎成粉末，然后再将非活性无机物粉末与活性无机物粉末混合，由此可得到与原料非活性无机物粉末或活性无机物粉末颜色一致或不一致的混合无机物粉末，显著丰富了最终所得彩色活性混合材料的颜色。进一步的，因非活性无机物粉末和活性无机物粉末的颜色都是材料本身的原色，使得所得的彩色活性混合材料的颜色固色度相比于染色要强得多。通过将混合无机物粉末进行包覆，使得非活性无机物粉末和活性无机物粉末都被表面包覆剂包覆于内部，可显著提高彩色活性混合材料的活性，同时显著降低了活性无机物的用量，使得整个彩色活性混合材料的经济价值显著提高。
需要说明的是，彩色活性混合材料中的优势和特征同样适用于制备彩色活性混合材料的方法，在此不再赘述。
在本发明的又一个方面，本发明提出了一种水泥构件，根据本发明的实施例，水泥构件采用上述彩色活性混合材料制备而成，或采用上述制备彩色活性混合材料的方法制备所得的彩色活性混合材料制备而成。根据本发明实施例的水泥构件，彩色活性混合材料可以为水泥构件提供颜色调配，同时因采用了彩色活性混合材料，水泥的用量可减少30-100％，且非活性无机物与活性无机物的配合，可使水泥构件的强度增加至少20％。进一步的，在节省和/或替代水泥这方面，也可以直接将彩色活性混合材料作为乡村、生态景区路面混合材料，研究发现，其比纯土石铺设的路面具有更高的强度，更优异的彩色效果，以及更优的耐雨水冲刷的特点。
在本发明的又一个方面，本发明提出了一种涂料，根据本发明的实施例，涂料包括5-20wt％(如5/10/15/20wt％)的固含量为50wt％的水基高分子聚合物、2-17wt％的水、70-95wt％(如70/75/80/85/90/95wt％)的彩色活性混合材料(如)，彩色活性混合材料为上述彩色活性混合材料，或采用上述制备彩色活性混合材料的方法制备所得的所述彩色活性混合材料。根据本发明实施例的涂料，该涂料分散性好，不易结团，胶凝时间长且稳定，涂覆后耐风吹日晒，不易变色，耐老化实验可达3500h以上。用于外墙时，具有长期不变色、不粉化的特性，用于内墙时具有很好的透气、防潮、环保特性。直接制成片材、板材或块材用于建筑外装饰时，具有长期不变色、不粉化、如同水泥、石材、陶瓷一样耐久的特性。
在本发明的又一个方面，本发明提出了一种建筑砖块，根据本发明的实施例，建筑砖块包括：8-16wt％的水、0-10wt％(如0/2/4/6/8/10wt％)的丙烯酸胶粉、0-15wt％(如0/3/6/9/12/15wt％)的水玻璃、80-92wt％(如80/82/84/86/88/90/92wt％)的彩色活性混合材料，所述彩色活性混合材料是上述的彩色活性混合材料，或是采用上述制备彩色活性混合材料的方法制备所得的所述彩色活性混合材料。根据本发明实施例的建筑砖块，该建筑砖块中的彩色活性混合材料可替代黏土，省去烧结工艺，且所得的建筑砖块强度超过800摄氏度下烧结的红砖的强度，同时，其颜色完全可控，可以根据需要选择不同的颜色。
在本发明的又一个方面，本发明提出了一种片材或板材，该片材或板材是采用上 述彩色活性混合材料制备而成，或采用上述制备彩色活性混合材料制备所得的所述彩色活性混合材料制备而成。根据本发明实施例的片材或板材，通过采用上述彩色活性混合材料制备片材或板材，为现有建筑装饰领域提供了一种新的可能，且所得的片材或板材的可弯曲度可达40度，标准温度下拉伸强度和断裂伸长率分别可达5MPa和80％，防火等级可达A1级。
根据本发明的一些实施例，片材或板材的配方可以为：80-91wt％的彩色活性混合材料，1-16wt％(如1/4/8/12/16wt％)的水性硅PU，1-4wt％(1/2/3/4wt％)的短纤维，6-12wt％的水，1-3wt％(1/2/3wt％)的可再分散乳胶粉。将上述材料混合制浆，注入模具，在120摄氏度下干燥1h，成型得厚度为3-10mm(如3/4/5/6/7/8/9/10mm)的片材或板材。该片材或板材的可弯曲度可达40度，标准温度下拉伸强度和断裂伸长率分别可达5MPa和80％，防火等级为A1级。
在本发明的又一个方面，本发明提出了一种型材或壳体，该型材或壳体是采用上述彩色活性混合材料制备而成，或采用上述制备彩色活性混合材料制备所得的所述彩色活性混合材料制备而成。根据本发明实施例的型材或壳体，通过采用上述彩色活性混合材料制备片材或板材，为现有生活电器和/或数码产品领域提供了一种新的可能，且所得的型材或壳体的抗冲击强度为0.5-5J*m -1，密度为1.1-1.3克/立方厘米，防火等级为A级，人工耐老化实验可达3500h以上。
根据本发明的一些实施例，型材或壳体的配方可以为：80-90wt％的彩色活性混合材料，6-12wt％的固含量为50％的丙烯酸聚合物，3-5wt％的可再分散乳胶粉，1-3wt％的长度为0.3mm的聚乙烯纤维。将上述材料混合均匀，注入模具，在140-160摄氏度下蒸压1.5-3h，得到型材或壳体。通过选择不同的模具，可以得到适用于不同生活电器和数码电器的外壳产品，以替代塑料，如电脑外壳、冰箱外壳、洗衣机外壳、微波炉外壳、电视外壳、手机外壳等。所得的型材或壳体的抗冲击强度为0.5-5J*m -1，密度为1.1-1.3克/立方厘米，防火等级为A级，人工耐老化实验可达3500h以上。
下面参考具体实施例，对本发明进行描述，需要说明的是，这些实施例仅仅是描述性的，而不以任何方式限制本发明。
实施例1
彩色活性混合材料的配方组成为：
非活性无机物天然土，活性无机物烧结红砖弃块，表面包覆剂十八胺，非活性无机物与活性无机物的质量比为1∶1，非活性无机物与活性无机物的质量和与表面包覆剂的质量比为100∶0.4。
实施例2
彩色活性混合材料的配方组成为：
非活性无机物石英，活性无机物水泥弃块，表面包覆剂为均等份的氟碳表面活性剂、γ-氨丙基三乙氧基硅烷，非活性无机物与活性无机物的质量比为1∶2，非活性无机物与活性无机物的质量和与表面包覆剂的质量比为100∶3。
实施例3
彩色活性混合材料的配方组成为：
非活性无机物石灰石，活性无机物火山灰，表面包覆剂为均等份的谷胱甘肽、半胱 氨酸，非活性无机物与活性无机物的质量比为1∶3，非活性无机物与活性无机物的质量和与表面包覆剂的质量比为100∶8，
实施例4
彩色活性混合材料的配方组成为：
非活性无机物为均等份的天然土、石英，活性无机物为高炉矿碴，矿物颜料为氧化铁红，表面包覆剂为均等份的阿拉伯胶、明胶，非活性无机物与活性无机物的质量比为1∶4，非活性无机物和活性无机物的质量之和与矿物颜料的质量比为100∶0.2，非活性无机物和活性无机物、矿物颜料的质量之和与表面包覆剂的质量比为100∶0.2。
实施例5
彩色活性混合材料的配方组成为：
非活性无机物为均等份的石英、石灰石，活性无机物为磷矿碴，矿物颜料为氧化铁黄，表面包覆剂为均等份的聚吡咯烷酮、3-氨基丙基三甲氧基硅烷，非活性无机物与活性无机物的质量比为1∶1.5，非活性无机物和活性无机物的质量之和与矿物颜料的质量比为100∶5，非活性无机物和活性无机物、矿物颜料的质量之和与表面包覆剂的质量比为100∶2。
实施例6
彩色活性混合材料的配方组成为：
非活性无机物为均等份的天然土、石英、石灰石，活性无机物为粉煤灰，矿物颜料为均等份的氧化铁黑、炭黑，表面包覆剂为均等份的多巴胺、左旋多巴、多巴胺盐酸盐、牛血清蛋白，非活性无机物与活性无机物的质量比为1∶2.5，非活性无机物和活性无机物的质量之和与矿物颜料的质量比为100∶10，非活性无机物和活性无机物、矿物颜料的质量之和与表面包覆剂的质量比为100∶3；
实施例7
彩色活性混合材料的配方组成为：
非活性无机物为均等份的石英、石灰石，活性无机物为均等份的烧结红砖弃块、水泥弃块、火山灰，矿物颜料为均等份的氧化锌、钛白，表面包覆剂为均等份的十三氟辛基三甲氧基硅烷、十三氟辛基三乙氧基硅烷、十七氟癸基三乙氧基硅烷、十七氟癸基三甲氧基硅烷，非活性无机物与活性无机物的质量比为1∶3.5，非活性无机物和活性无机物的质量之和与矿物颜料的质量比为100∶20，非活性无机物和活性无机物、矿物颜料的质量之和与表面包覆剂的质量比为100∶5。
实施例8
一种水泥构件
制备实施例1中的彩色活性混合材料：将非活性无机物粉碎至预定粒径80-120目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径80-120目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和表面包覆剂混合包覆，得到彩色活性混合材料。将所得的彩色活性混合材料直接成型，得到水泥构件。该水泥构件实现了百分比替代水泥，且强度增加30％，同时不会出现泛碱现象。
实施例9
一种路面混合材料
制备实施例2中的彩色活性混合材料：将非活性无机物粉碎至预定粒径200-300目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径200-300目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和表面包覆剂混合包覆，得到彩色活性混合材料。将所得的彩色活性混合材料直接成型，得到路面混合材料。该路面混合材料作为乡村、生态景区路面混合材料时，比纯土石铺设的路面具有更高的强度，更优异的彩色效果，以及更优的耐雨水冲刷的特点。
实施例10
一种涂料
包括：5wt％的固含量为50wt％的水基高分子聚合物、2wt％的水、93wt％的彩色活性混合材料。其中，彩色活性混合材料是采用实施例3的配方制备而成的，具体为：将非活性无机物粉碎至预定粒径400-600目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径400-600目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和表面包覆剂混合包覆，得到彩色活性混合材料。将上述水基高分子聚合物、水、彩色活性混合材料混合制备得到涂料。该涂料分散性好，不易结团，胶凝时间长且稳定，涂覆后耐风吹日晒，不易变色，耐老化实验可达3500h以上。用于外墙时，具有长期不变色、不粉化的特性，用于内墙时具有很好的透气、防潮、环保特性。
实施例11
一种涂料
包括：10wt％的固含量为50wt％的水基高分子聚合物、10wt％的水、80wt％的彩色活性混合材料。其中，彩色活性混合材料是采用实施例4的配方制备而成的，具体为：将非活性无机物粉碎至预定粒径800-1000目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径800-1000目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和矿物颜料混合，之后和表面包覆剂混合包覆，得到彩色活性混合材料。将上述水基高分子聚合物、水、彩色活性混合材料混合制备得到涂料。该涂料分散性好，不易结团，胶凝时间长且稳定，涂覆后耐风吹日晒，不易变色，耐老化实验可达3500h以上。用于外墙时，具有长期不变色、不粉化的特性，用于内墙时具有很好的透气、防潮、环保特性。
实施例12
一种涂料
包括：20wt％的固含量为50wt％的水基高分子聚合物、7wt％的水、73wt％的彩色活性混合材料。其中，彩色活性混合材料是采用实施例5的配方制备而成的，具体为：将非活性无机物粉碎至预定粒径2000-3000目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径2000-3000目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和矿物颜料混合，之后和表面包覆剂混合包覆，得到彩色活性混合材料。将上述水基高分子聚合物、水、彩色活性混合材料混合制备得到涂料。该涂料分散性好，不易结团，胶凝时间长且稳定，涂覆后耐风吹日晒，不易变色，耐老化实验可达3500h以上。用于外墙时，具有长期不变色、不粉化的特性，用于 内墙时具有很好的透气、防潮、环保特性。
实施例13
一种建筑砖块
包括：8wt％的水、12wt％的水玻璃、80wt％的彩色活性混合材料。其中，彩色活性混合材料是采用实施例6的配方制备得到的，具体为：将非活性无机物粉碎至预定粒径4000-5000目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径4000-5000目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和矿物颜料混合，之后和表面包覆剂混合包覆，得到彩色活性混合材料。该建筑砖块中的彩色活性混合材料可替代黏土，省去烧结工艺，且强度超过800摄氏度下烧结的红砖的强度，同时，其颜色完全可控，可以根据需要选择不同的颜色。
实施例14
一种建筑砖块
包括：12wt％的水、3wt％的丙烯酸胶粉、85wt％的彩色活性混合材料。其中，彩色活性混合材料是采用实施例7的配方制备得到的，具体为：将非活性无机物粉碎至预定粒径6000-7000目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径6000-7000目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和矿物颜料混合，之后和表面包覆剂混合包覆，得到彩色活性混合材料。该建筑砖块中的彩色活性混合材料可替代黏土，省去烧结工艺，且强度超过800摄氏度下烧结的红砖的强度，同时，其颜色完全可控，可以根据需要选择不同的颜色。
实施例15
一种建筑砖块
包括：8wt％的水、92wt％的彩色活性混合材料。其中，彩色活性混合材料是采用实施例1的配方制备得到的，具体为：将非活性无机物粉碎至预定粒径80-120目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径80-120目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和表面包覆剂混合包覆，得到彩色活性混合材料。该建筑砖块中的彩色活性混合材料可替代黏土，省去烧结工艺，且强度超过800摄氏度下烧结的红砖的强度，同时，其颜色完全可控，可以根据需要选择不同的颜色。
实施例16
一种片材
包括：80wt％的彩色活性混合材料，1wt％的水性硅PU，4wt％的短纤维，12wt％的水，3wt％的可再分散乳胶粉。其中彩色活性混合材料是采用实施例2的配方制备而成的，具体的：将非活性无机物粉碎至预定粒径8000-9000目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径8000-9000目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和表面包覆剂混合包覆，得到彩色活性混合材料。将上述材料混合制浆，注入模具，在120摄氏度下干燥1h，成型得厚度为3mm的片材。该片材的可弯曲度可达40度，标准温度下拉伸强度和断裂伸 长率分别可达5MPa和80％，防火等级为A1级。同时具有长期不变色、不粉化、如同水泥、石材、陶瓷一样耐久的特性。
实施例17
一种片材
包括：85wt％的彩色活性混合材料，5wt％的水性硅PU，2wt％的短纤维，6wt％的水，2wt％的可再分散乳胶粉。其中彩色活性混合材料是采用实施例3的配方制备而成的，具体的：将非活性无机物粉碎至预定粒径800-1000目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径800-1000目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和表面包覆剂混合包覆，得到彩色活性混合材料。将上述材料混合制浆，注入模具，在120摄氏度下干燥1h，成型得厚度为6mm的片材。该片材的可弯曲度可达40度，标准温度下拉伸强度和断裂伸长率分别可达5MPa和80％，防火等级为A1级。同时具有长期不变色、不粉化、如同水泥、石材、陶瓷一样耐久的特性。
实施例18
一种板材
包括：91wt％的彩色活性混合材料，1wt％的水性硅PU，1wt％的短纤维，6wt％的水，1wt％的可再分散乳胶粉。其中彩色活性混合材料是采用实施例4的配方制备而成的，具体的：将非活性无机物粉碎至预定粒径400-600目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径400-600目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和矿物颜料混合后与表面包覆剂混合包覆，得到彩色活性混合材料。将上述材料混合制浆，注入模具，在120摄氏度下干燥1h，成型得厚度为10mm的板材。该板材的可弯曲度可达40度，标准温度下拉伸强度和断裂伸长率分别可达5MPa和80％，防火等级为A1级。同时具有长期不变色、不粉化、如同水泥、石材、陶瓷一样耐久的特性。
实施例19
一种电脑外壳
包括：80wt％的彩色活性混合材料，12wt％的固含量为50％的丙烯酸聚合物，5wt％的可再分散乳胶粉，3wt％的长度为0.3mm的聚乙烯纤维。其中，彩色活性混合材料是采用实施例3的配方制备而成的，具体为：将非活性无机物粉碎至预定粒径400-600目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径400-600目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和表面包覆剂混合包覆，得到彩色活性混合材料。将上述材料混合均匀，注入模具，在140摄氏度下蒸压3h，得到电脑外壳。其抗冲击强度为5J*m -1，密度为1.1克/立方厘米，防火等级为A级，人工耐老化实验可达3500h以上。
实施例20
一种冰箱外壳
包括：85wt％的彩色活性混合材料，9wt％的固含量为50％的丙烯酸聚合物，4wt％的可再分散乳胶粉，2wt％的长度为0.3mm的聚乙烯纤维。其中，彩色活性混合材料是采用实施例6的配方制备而成的，具体为：将非活性无机物粉碎至预定粒径10000-11000目，得到预 定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径10000-11000目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和矿物颜料混合后与表面包覆剂混合包覆，得到彩色活性混合材料。将上述材料混合均匀，注入模具，在150摄氏度下蒸压2h，得到冰箱外壳。其抗冲击强度为4J*m -1，密度为1.25克/立方厘米，防火等级为A级，人工耐老化实验可达3500h以上。
实施例21
一种手机外壳
包括：90wt％的彩色活性混合材料，6wt％的固含量为50％的丙烯酸聚合物，3wt％的可再分散乳胶粉，1wt％的长度为0.3mm的聚乙烯纤维。其中，彩色活性混合材料是采用实施例7的配方制备而成的，具体为：将非活性无机物粉碎至预定粒径11000-12000目，得到预定粒径的非活性无机物粉末；将活性无机物粉碎至预定粒径11000-12000目，得到预定粒径的活性无机物粉末；将非活性无机物粉末和活性无机物粉末混合，得到混合无机物粉末；将混合无机物粉末和矿物颜料混合后与表面包覆剂混合包覆，得到彩色活性混合材料。将上述材料混合均匀，注入模具，在160摄氏度下蒸压1.5h，得到手机外壳。其抗冲击强度为3.5J*m -1，密度为1.1克/立方厘米，防火等级为A级，人工耐老化实验可达3500h以上。
在本说明书的描述中，参考术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中，对上述术语的示意性表述不必须针对的是相同的实施例或示例。而且，描述的具体特征、结构、材料或者特点可以在任一个或多个实施例或示例中以合适的方式结合。此外，在不相互矛盾的情况下，本领域的技术人员可以将本说明书中描述的不同实施例或示例以及不同实施例或示例的特征进行结合和组合。
尽管上面已经示出和描述了本发明的实施例，可以理解的是，上述实施例是示例性的，不能理解为对本发明的限制，本领域的普通技术人员在本发明的范围内可以对上述实施例进行变化、修改、替换和变型。

Claims (10)

  1. 一种彩色活性混合材料，其特征在于，包括：非活性无机物、活性无机物、表面包覆剂。
  2. 根据权利要求1所述的彩色活性混合材料，其特征在于，所述非活性无机物与所述活性无机物的质量比为1:(1-4)；
    任选的，所述非活性无机物与所述活性无机物的质量和与所述表面包覆剂的质量比为100:0.4-8。
  3. 根据权利要求1所述的彩色活性混合材料，其特征在于，进一步包括矿物颜料；
    任选的，所述非活性无机物和所述活性无机物的质量之和与所述矿物颜料的质量比为100:(0-20)；
    任选的，所述非活性无机物和所述活性无机物、所述矿物颜料的质量之和与所述表面包覆剂的质量比为100:0.2-5；
    任选的，所述非活性无机物选自天然土、石英、石灰石中的至少之一；
    任选的，所述活性无机物选自烧结红砖弃块、水泥弃块、火山灰、高炉矿硝、磷矿硝、粉煤灰中的至少之一；
    任选的，所述矿物颜料选自氧化铁红、氧化铁黄、氧化铁黑、炭黑、氧化锌、钦臼中的至少之一；
    任选的，所述表面包覆剂选自高级饺盐、十八胺、氪碳表面活性剂、y-氨丙咭三乙氧咭硅炕、谷胱甘肤、半胱氨酸、阿拉伯胶、明胶、聚阰咯炕酮、3-氨咭丙咭三甲氧咭硅炕、多巳胺、左旋多巳、多巳胺盐酸盐、牛血清蛋臼、聚乙烯亚胺、壳聚糖、十三氪辛咭三甲氧咭硅炕、十三氪辛咭三乙氧咭硅炕、十七氪癸咭三乙氧咭硅炕、十七氪癸咭三甲氧咭硅炕、有机胺卤酸、寡肤中的至少之一。
  4. 一种制备权利要求1-3中任一项所述的彩色活性混合材料的方法，其特征在于，包括：
    将非活性无机物按照颜色分别粉碎至预定粒径，以便得到不同颜色预定粒径的非活性无机物粉末；
    将活性无机物按照颜色分别粉碎至预定粒径，以便得到不同颜色预定粒径的活性无机物粉末；
    将所述非活性无机物粉末和所述活性无机物粉末混合，以便得到不同颜色的混合无机物粉末；
    将所述混合无机物粉末和表面包覆剂混合包覆，以便得到彩色活性混合材料。
  5. 根据权利要求4所述的方法，其特征在于，在将所述混合无机物粉末进行所述包覆处理之前，将所述混合无机物粉末和矿物颜料混合；
    任选的，所述非活性无机物粉末的粒径为80-12000目；
    所述活性无机物粉末的粒径为80-12000目。
  6. 一种水泥构件，其特征在于，所述水泥构件采用权利要求1-3中的任一项所述的彩色活性混合材料制备而成，或采用权利要求4-5中任一项所述的方法制备所得的所述彩色活性混合材料制备而成。
  7. 一种涂料，其特征在于，包括：5-20wt％的固含量为50wt％的水咭高分子聚合物、2-17wt％的水、70-95wt％的彩色活性混合材料，所述彩色活性混合材料是权利要求1-3中的 任一项所述的彩色活性混合材料，或是采用权利要求4-5中任一项所述的方法制备所得的所述彩色活性混合材料。
  8. 一种建筑砖块，其特征在于，包括：8-16wt％的水、0-lOwt％的丙烯酸胶粉、0-15wt％的水玻璃、80-92wt％的彩色活性混合材料，所述彩色活性混合材料是权利要求1-3中的任一项所述的彩色活性混合材料，或是采用权利要求4-5中任一项所述的方法制备所得的所述彩色活性混合材料。
  9. 一种片材或板材，其特征在于，所述片材或板材是采用权利要求1-3中的任一项所述的彩色活性混合材料制备而成，或采用权利要求4-5中任一项所述的方法制备所得的所述彩色活性混合材料制备而成。
  10. 一种型材或壳体，其特征在于，所述型材或壳体是采用权利要求1-3中的任一项所述的彩色活性混合材料制备而成，或采用权利要求4-5中任一项所述的方法制备所得的所述彩色活性混合材料制备而成。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117511539A (zh) * 2023-11-17 2024-02-06 中国科学院兰州化学物理研究所 一种手性绿色荧光硅纳米颗粒的制备及在识别检测谷氨酸对映体中的应用

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112608080B (zh) * 2020-12-08 2023-02-03 广东省福美材料科学技术有限公司 彩色活性混合材料及其制备方法和应用
CN113416014B (zh) * 2021-06-28 2022-09-23 东南大学 一种可调控颜色的修复剂及制法和含有该修复剂的混凝土
CN116675515A (zh) * 2023-04-25 2023-09-01 安徽千鑫通讯科技有限公司 一种陶瓷手机盖及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002038684A1 (en) * 2000-11-08 2002-05-16 Saitron Limited Powder compositions and methodology for manufacturing same
CN1644553A (zh) * 2004-12-23 2005-07-27 江阴采麟彩砂制品有限公司 彩砂及制备方法
CN102875112A (zh) * 2012-09-15 2013-01-16 汉寿县永兴砖厂 一种淤泥浇注的彩色建筑板材
CN105753408A (zh) * 2016-03-04 2016-07-13 山西大学 一种人造彩砂及其制备方法
CN106830979A (zh) * 2017-02-24 2017-06-13 天津市建筑工程质量检测中心 一种仿火山岩多孔材料
CN112608080A (zh) * 2020-12-08 2021-04-06 广东省福美材料科学技术有限公司 彩色活性混合材料及其制备方法和应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1132225A (zh) * 1995-03-28 1996-10-02 赵金良 一种无机颜料及填料的表面处理剂及其制备方法
CN103013183A (zh) * 2012-11-28 2013-04-03 福建师范大学 粉煤灰空心微珠基复合钛白及其制备方法
CN103304172A (zh) * 2013-06-14 2013-09-18 合肥工业大学 一种彩砂的制备方法
CN103709833B (zh) * 2013-12-20 2015-04-01 苏州世名科技股份有限公司 生产线调色用聚合物包覆无机颜料色浆的制备方法
CN104403401B (zh) * 2014-10-23 2016-06-01 陕西理工学院 一种表面包覆SiO2的改性粉煤灰及其制备方法和用途
CA2967456C (en) * 2014-12-08 2024-02-06 Valspar Sourcing, Inc. Polymer-encapsulated pigment particle
CN106318354B (zh) * 2015-06-18 2018-09-18 中国石油化工股份有限公司 一种降脆增韧材料及其制备方法和由其制备的水泥浆
CN105293991A (zh) * 2015-10-16 2016-02-03 卓达新材料科技集团威海股份有限公司 填料用改性剂及其填料的制备方法
CN105601171A (zh) * 2016-02-02 2016-05-25 赵建林 一种免烧陶瓷透水砖及其制造方法
CN106674602B (zh) * 2016-12-20 2019-09-20 广东生益科技股份有限公司 一种包覆型填料浆料组合物的制备方法、包含该浆料组合物的预浸料、层压板和印刷电路板
CN109503922B (zh) * 2018-11-19 2021-11-19 深圳免喷材料科技有限公司 一种颜料功能母粒的制备方法及其产品和应用

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002038684A1 (en) * 2000-11-08 2002-05-16 Saitron Limited Powder compositions and methodology for manufacturing same
CN1644553A (zh) * 2004-12-23 2005-07-27 江阴采麟彩砂制品有限公司 彩砂及制备方法
CN102875112A (zh) * 2012-09-15 2013-01-16 汉寿县永兴砖厂 一种淤泥浇注的彩色建筑板材
CN105753408A (zh) * 2016-03-04 2016-07-13 山西大学 一种人造彩砂及其制备方法
CN106830979A (zh) * 2017-02-24 2017-06-13 天津市建筑工程质量检测中心 一种仿火山岩多孔材料
CN112608080A (zh) * 2020-12-08 2021-04-06 广东省福美材料科学技术有限公司 彩色活性混合材料及其制备方法和应用

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117511539A (zh) * 2023-11-17 2024-02-06 中国科学院兰州化学物理研究所 一种手性绿色荧光硅纳米颗粒的制备及在识别检测谷氨酸对映体中的应用

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