WO2022113179A1 - 表示装置の製造方法 - Google Patents
表示装置の製造方法 Download PDFInfo
- Publication number
- WO2022113179A1 WO2022113179A1 PCT/JP2020/043704 JP2020043704W WO2022113179A1 WO 2022113179 A1 WO2022113179 A1 WO 2022113179A1 JP 2020043704 W JP2020043704 W JP 2020043704W WO 2022113179 A1 WO2022113179 A1 WO 2022113179A1
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- WIPO (PCT)
- Prior art keywords
- layer
- charge transport
- material layer
- photosensitive resin
- light emitting
- Prior art date
Links
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- 238000000034 method Methods 0.000 title claims abstract description 20
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Images
Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/20—Changing the shape of the active layer in the devices, e.g. patterning
- H10K71/221—Changing the shape of the active layer in the devices, e.g. patterning by lift-off techniques
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
- G09F9/30—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/10—Apparatus or processes specially adapted to the manufacture of electroluminescent light sources
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/122—Pixel-defining structures or layers, e.g. banks
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/20—Changing the shape of the active layer in the devices, e.g. patterning
- H10K71/231—Changing the shape of the active layer in the devices, e.g. patterning by etching of existing layers
- H10K71/233—Changing the shape of the active layer in the devices, e.g. patterning by etching of existing layers by photolithographic etching
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/60—Forming conductive regions or layers, e.g. electrodes
Definitions
- This disclosure relates to a manufacturing method of a display device.
- Display devices such as organic light emitting diode (OLED) display devices and quantum dot light emitting diode (QLED) display devices often include light emitting elements of a plurality of colors.
- the light emitting device of each color includes a charge transport layer and a light emitting layer.
- the suitable material, shape, etc. of the charge transport layer change depending on the color of the light emitting device provided with the charge transport layer.
- the suitable material, shape, and the like of the light emitting layer also change depending on the color of the light emitting element provided with the light emitting layer. Therefore, in the display device, it is desired to make the charge transport layer and the light emitting layer provided in the light emitting element of one color independent from the charge transport layer and the light emitting layer provided in the light emitting element of another color.
- Patent Document 1 discloses a method for manufacturing an organic EL display device.
- a light emitting layer is formed, a transport layer is formed on the light emitting layer, a peeling layer is formed on the transport layer, and the light emitting layer is photosensitive on the peeling layer.
- a sex resin layer is formed. Further, the photosensitive resin layer is exposed and developed, and the light emitting layer, the transport layer, and the peeling layer accumulated in the region not covered with the photosensitive resin layer are removed.
- a light emitting layer is formed, a transport layer is formed on the light emitting layer, a peeling layer is formed on the transport layer, and a photosensitive resin layer is formed on the peeling layer. It is formed. Further, the photosensitive resin layer is exposed and developed, and the light emitting layer, the transport layer, and the peeling layer accumulated in the region not covered with the photosensitive resin layer are removed.
- the manufacturing method of the organic EL display device disclosed in Patent Document 1 has a long manufacturing process.
- the manufacturing process can be shortened, and the charge transport layer and the light emitting layer provided in the light emitting element emitting one color of light are provided in the charge transport layer and the light emitting layer provided in the light emitting element of another color. It is an object of the present invention to provide a method of manufacturing a display device that can be made independent of.
- a method of manufacturing a display device is a step of preparing a substrate including an electrode and another electrode at a distance from the electrode in a plan view, and b) after the step a). After the step of forming the photosensitive resin material layer on the substrate and c) the step b), a charge transport material layer and a light emitting material layer are formed on the substrate, and the charge transport material layer and the electrode are used. A photomask is used after the step of forming the entire area where the light-emitting material layer and the electrode overlap with the photosensitive resin material layer, and d) the step c).
- the photosensitive resin material layer is exposed and developed to lift off the non-lift-off portions of the photosensitive resin material layer, the charge transport material layer and the light emitting material layer formed on at least a part of the electrodes.
- the photosensitive resin is formed by lifting off the lift-off portions of the photosensitive resin material layer, the charge transport material layer, and the light emitting material layer, which are formed on at least a part of the other electrodes.
- the present invention comprises a step of patterning the material layer, the charge transport material layer, and the light emitting material layer into a photosensitive resin layer, a charge transport layer, and a light emitting layer, respectively.
- FIG. 1 is a plan view schematically showing the display device 1 of the first embodiment.
- the display device 1 is an organic light emitting diode (OLED) display device, a quantum dot light emitting diode (QLED) display device, or the like. In the following, it is assumed that the display device 1 is a QLED display device.
- OLED organic light emitting diode
- QLED quantum dot light emitting diode
- the display device 1 includes a plurality of pixels P.
- the plurality of pixels P are arranged in a matrix.
- a plurality of pixels P may be arranged in a non-matrix manner.
- FIG. 2 is a cross-sectional view schematically showing each pixel P provided in the display device 1 of the first embodiment.
- each pixel P includes a first light emitting element B, a second light emitting element G, and a third light emitting element R.
- Each light emitting element of the first light emitting element B, the second light emitting element G, and the third light emitting element R constitutes a sub-pixel.
- the first light emitting element B, the second light emitting element G, and the third light emitting element R emit light of the first color, the second color, and the third color, respectively.
- the first color, the second color and the third color are different from each other.
- the first color, the second color, and the third color are blue, green, and red, respectively.
- the first color, the second color, and the third color may be colors other than blue, green, and red, respectively.
- each pixel P includes a first bank BG, a second bank GR, and a third bank RB.
- the first bank BG partitions the first light emitting element B and the second light emitting element G.
- the second bank GR partitions the second light emitting element G and the third light emitting element R.
- the third bank RB partitions the third light emitting element R and the first light emitting element B.
- each pixel P includes a substrate 11, a first pixel electrode 12B, a second pixel electrode 12G, a third pixel electrode 12R, a first photosensitive resin layer 13B, and a second photosensitive resin layer 13G.
- the substrate 11 includes a switching element (not shown), wiring, and an interlayer insulating film (not shown).
- the switching element is, for example, a thin film transistor.
- the first pixel electrode 12B, the first photosensitive resin layer 13B, the lower first charge transport layer 14B, the first light emitting layer 15B, and the upper first charge transport layer 17B are arranged in the first light emitting element B.
- the second pixel electrode 12G, the second photosensitive resin layer 13G, the lower second charge transport layer 14G, the second light emitting layer 15G, and the upper second charge transport layer 17G are arranged in the second light emitting element G.
- the third pixel electrode 12R, the third photosensitive resin layer 13R, the lower third charge transport layer 14R, the third light emitting layer 15R, and the upper third charge transport layer 17R are arranged in the third light emitting element R.
- the common electrode 19 is arranged so as to straddle the first light emitting element B, the second light emitting element G, and the third light emitting element R.
- the second charge transport layer 17G, the upper third charge transport layer 17R, and the common electrode 19 are arranged on the interlayer insulating film provided on the substrate 11.
- the switching element and wiring provided on the substrate 11 are arranged under the interlayer insulating film.
- Charge transport layer 14B, lower second charge transport layer 14G, lower third charge transport layer 14R, first light emitting layer 15B, second light emitting layer 15G, third light emitting layer 15R, upper first charge transport layer 17B, the upper second charge transport layer 17G, the upper third charge transport layer 17R, and the common electrode 19 are separated from the switching element and the wiring, and are electrically insulated from the switching element and the wiring.
- the first pixel electrode 12B, the second pixel electrode 12G, and the third pixel electrode 12R are electrically connected to the switching element via a connecting conductor arranged inside the contact hole formed in the interlayer insulating film.
- the first photosensitive resin layer 13B, the second photosensitive resin layer 13G, and the third photosensitive resin layer 13R are arranged on the first pixel electrode 12B, the second pixel electrode 12G, and the third pixel electrode 12R, respectively.
- the lower first charge transport layer 14B, the lower second charge transport layer 14G, and the lower third charge transport layer 14R are the first photosensitive resin layer 13B, the second photosensitive resin layer 13G, and the third photosensitive layer. Each is arranged on the sex resin layer 13R.
- the first light emitting layer 15B, the second light emitting layer 15G, and the third light emitting layer 15R are above the lower first charge transport layer 14B, the lower second charge transport layer 14G, and the lower third charge transport layer 14R. Are placed in each.
- the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R are arranged on the first light emitting layer 15B, the second light emitting layer 15G, and the third light emitting layer 15R, respectively. Will be done.
- the common electrode 19 is arranged so as to straddle the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R.
- the first pixel electrode 12B, the second pixel electrode 12G, and the third pixel electrode 12R are separated from each other in a plan view.
- the display device 1 may include a charge injection layer between the first pixel electrode 12B and the lower first charge transport layer 14B, and the second pixel electrode 12G and the lower second charge transport layer 14G may be provided. A charge injection layer may be provided between them, or a charge injection layer may be provided between the third pixel electrode 12R and the lower third charge transport layer 14R.
- the display device 1 may include a charge injection layer between the common electrode 19 and the upper first charge transport layer 17B, and may provide a charge injection layer between the common electrode 19 and the upper second charge transport layer 17G. It may be provided, or a charge injection layer may be provided between the common electrode 19 and the upper third charge transport layer 17R.
- the display device 1 is a painting element in which the functional layer is painted separately for each color. Therefore, the first functional layer 41B including the lower first charge transport layer 14B, the first light emitting layer 15B, and the upper first charge transport layer 17B, the lower second charge transport layer 14G, and the second light emitting layer 15G. And the second functional layer 41G including the upper second charge transport layer 17G, and the third functional layer 41R including the lower third charge transport layer 14R, the third light emitting layer 15R and the upper third charge transport layer 17R. , Independent of each other.
- the first photosensitive resin layer 13B, the second photosensitive resin layer 13G, and the third photosensitive resin layer 13R are display devices for making the first functional layer 41B, the second functional layer 41G, and the third functional layer 41R independent of each other. It is left in 1. A part of the first photosensitive resin layer 13B, the second photosensitive resin layer 13G, and the third photosensitive resin layer 13R may be omitted.
- the layers provided in the first functional layer 41B, the second functional layer 41G and the third functional layer 41R are the first photosensitive resin layer 13B, the second photosensitive resin layer 13G and the third photosensitive resin layer 13R by the lift-off process. Are formed at the same time as they are formed. Further, the first photosensitive resin layer 13B, the second photosensitive resin layer 13G, and the third photosensitive resin layer 13R are independent of each other. As a result, the layer provided in the first functional layer 41B, the layer provided in the second functional layer 41G, and the layer provided in the third functional layer 41R can be formed independently of each other.
- the light emitting element of the light emitting element, the first pixel electrode 12B, the second pixel electrode 12G, and the third pixel electrode 12R are the lower first charge transport layer 14B, the lower second charge transport layer 14G, and the lower second charge transport layer 14G.
- the first light emitting layer 15B, the second light emitting layer 15G, and the third light emitting layer 15R are contacted with each other via the three charge transport layer 14R.
- the lower first charge transport layer 14B, the lower second charge transport layer 14G, and the lower third charge transport layer 14R transport the first charge.
- the first pixel electrode 12B, the second pixel electrode 12G, and the third pixel electrode 12R are the lower first charge transport layer 14B, the lower second charge transport layer 14G, and the lower third charge transport layer 14R.
- the first charge can be injected into the first light emitting layer 15B, the second light emitting layer 15G, and the third light emitting layer 15R, respectively.
- the common electrode 19 has a first light emitting layer 15B, a second light emitting layer 15G, and a third light emitting layer via the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R. Contact each of the 15Rs.
- the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R transport the second charge.
- the first light emitting layer 15B, the second light emitting layer 15G, and the second light emitting layer 15B pass from the common electrode 19 via the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R.
- a second charge can be injected into each of the three light emitting layers 15R.
- the first charge is transmitted from the first pixel electrode 12B to the first light emitting layer 15B via the lower first charge transport layer 14B. Infused. Further, the second charge is injected from the common electrode 19 into the first light emitting layer 15B via the upper first charge transport layer 17B. As a result, the first charge and the second charge are recombined in the first light emitting layer 15B, and the first light emitting layer 15B emits light of the first color.
- the first charge is transferred from the second pixel electrode 12G to the second light emitting layer 15G via the lower second charge transport layer 14G. Infused. Further, the second charge is injected from the common electrode 19 into the second light emitting layer 15G via the upper second charge transport layer 17G. As a result, the first charge and the second charge are recombined in the second light emitting layer 15G, and the second light emitting layer 15G emits light of the second color.
- the first charge is transferred to the third light emitting layer 15R from the third pixel electrode 12R via the lower third charge transport layer 14R. Infused. Further, the second charge is injected from the common electrode 19 into the third light emitting layer 15R via the upper third charge transport layer 17R. As a result, the first charge and the second charge are recombined in the third light emitting layer 15R, and the third light emitting layer 15R emits light of the third color.
- the display device 1 has an invert structure or a conventional structure.
- the first charge is an electron.
- the second charge is a hole.
- the first pixel electrode 12B, the second pixel electrode 12G and the third pixel electrode 12R are cathodes.
- the common electrode 19 is an anode.
- the lower first charge transport layer 14B, the lower second charge transport layer 14G, and the lower third charge transport layer 14R are electron transport layers.
- the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R are hole transport layers.
- the first charge is a hole.
- the second charge is an electron.
- the first pixel electrode 12B, the second pixel electrode 12G, and the third pixel electrode 12R are anodes.
- the common electrode 19 is a cathode.
- the lower first charge transport layer 14B, the lower second charge transport layer 14G, and the lower third charge transport layer 14R are hole transport layers.
- the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R are electron transport layers.
- the first pixel electrode 12B, the second pixel electrode 12G, the third pixel electrode 12R and the common electrode 19 are made of a conductive material.
- the conductive material includes, for example, at least one selected from the group consisting of metals and transparent conductive oxides.
- the metal comprises, for example, at least one selected from the group consisting of Al, Cu, Au and Ag.
- the transparent conductive oxide is composed of, for example, indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), aluminum zinc oxide (AZO) and boron zinc oxide (BZO). Includes at least one selected.
- Each of the electrodes of the first pixel electrode 12B, the second pixel electrode 12G, the third pixel electrode 12R, and the common electrode 19 may be one layer composed of one kind of conductive material, or two kinds different from each other. It may be a laminate of two or more layers made of the above conductive materials. The two or more layers may include both a layer made of metal and a layer made of transparent conductive oxide.
- the first photosensitive resin layer 13B, the second photosensitive resin layer 13G, and the third photosensitive resin layer 13R are made of a cured product of the photosensitive resin.
- the electron transport layer is composed of an electron transport material.
- the electron transporting material includes, for example, at least one selected from the group consisting of zinc oxide, titanium oxide and strontium oxide.
- the zinc oxide is, for example, ZnO.
- the titanium oxide is, for example, TiO 2 .
- the strontium oxide titanium is, for example, SrTIO 3 .
- the electron transporting material may be an electron transporting material composed of one kind of substance, or may be an electron transporting material consisting of a mixture of two or more kinds of substances.
- the hole transport layer is composed of a hole transport material.
- the hole-transporting material includes, for example, at least one selected from the group consisting of a hole-transporting inorganic material and a hole-transporting organic material.
- the hole-transporting inorganic material comprises, for example, at least one selected from the group consisting of metal oxides, nitrides and carbides.
- the metal contains at least one selected from the group consisting of Zn, Cr, Ni, Ti, Nb, Al, Si, Mg, Ta, Hf, Zr, Y, La, Sr and Mo.
- the hole-transporting organic materials are 4,4', 4'-tris (9-carbazoyl) triphenylamine (TCTA), 4,4'-bis [N- (1-naphthyl) -N-phenyl-amino.
- NPB zinc phthalocyanine
- ZnPC zinc phthalocyanine
- CBP 4,4'-bis (carbazol-9-yl) biphenyl
- HTCN 4,4'-bis (carbazol-9-yl) biphenyl
- HTCN 3,6,7,10,11-Hexacyano-1,4,5,8,9,12-Hexaazatriphenylene
- PVK Poly (N-vinylcarbazole) (PVK)
- PVK Poly (2,7- (2,7- ( 9,9-di-n-octylfluorene)-(1,4-phenylene-((4-second butylphenyl) imino) -1,4-phenylene
- TPD TPD
- the first light emitting layer 15B is made of a blue light emitting material.
- the second light emitting layer 15G is made of a green light emitting material.
- the third light emitting layer 15R is made of a red light emitting material.
- Each light emitting material of blue light emitting material, green light emitting material and red light emitting material contains quantum dots.
- the quantum dots are, for example, semiconductor fine particles having a particle diameter of 100 nm or less.
- the semiconductor fine particles include, for example, at least one selected from the group consisting of II-VI group compounds, III-V group compounds and IV group compounds.
- the II-VI group compounds include, for example, MgS, MgSe, MgTe, CaS, CaSe, CaTe, SrS, SrSe, SrTe, BaS, BaSe, BaTe, ZnS, ZnSe, ZnTe, CdS, CdSe, CdTe, HgS, HgS and HgS. Includes at least one selected from the group consisting of.
- Group III-V compounds include, for example, at least one selected from the group consisting of GaAs, GaP, InN, InAs, InP and InSb.
- Group IV compounds include, for example, at least one selected from the group consisting of Si and Ge.
- the semiconductor fine particles may be semiconductor fine particles made of the crystal, or a semiconductor having a core / shell structure, a core made of the crystal, and a shell material having a wide bandgap, and having a shell overcoating the core. It may be fine particles.
- the first bank BG, the second bank GR and the third bank RB are made of an insulator.
- FIG. 3 is a flowchart showing a flow of manufacturing of the display device 1 of the first embodiment.
- steps S11 to S15 are executed.
- a substrate 42 including a substrate 11, a first pixel electrode 12B, a second pixel electrode 12G, a third pixel electrode 12R, a first bank BG, a second bank GR, and a third bank RB is prepared.
- the first inter-electrode layer 43B arranged between the first pixel electrode 12B and the common electrode 19 is formed.
- the first electrode-to-electrode layer 43B includes a first photosensitive resin layer 13B, a lower first charge transport layer 14B, a first light emitting layer 15B, and an upper first charge transport layer 17B.
- a second inter-electrode layer 43G arranged between the second pixel electrode 12G and the common electrode 19 is formed.
- the second electrode-to-electrode layer 43G includes a second photosensitive resin layer 13G, a lower second charge transport layer 14G, a second light emitting layer 15G, and an upper second charge transport layer 17G.
- the third electrode inter-electrode layer 43R arranged between the third pixel electrode 12R and the common electrode 19 is formed.
- the third electrode-to-electrode layer 43R includes a third photosensitive resin layer 13R, a lower third charge transport layer 14R, a third light emitting layer 15R, and an upper third charge transport layer 17R.
- step S15 after step S14 the common electrode 19 is formed.
- FIG. 4 is a flowchart showing a flow of formation of each inter-electrode layer provided in the display device 1 of the first embodiment.
- steps S101 to S105 are executed when the inter-electrode layers of the first inter-electrode layer 43B, the second inter-electrode layer 43G, and the third inter-electrode layer 43R are formed. ..
- steps S101, S102, S103 and S104 a photosensitive resin material layer, a lower charge transport material layer, a light emitting material layer and an upper charge transport material layer are formed on the substrate 42, respectively.
- step S105 the non-lift-off portion of the photosensitive resin material layer, the lower charge transport material layer, the light emitting material layer, and the upper charge transport material layer is left without being lifted off, and the photosensitive resin material layer is on the lower side. The lift-off portion of the charge transport material layer, the light emitting material layer and the upper charge transport material layer is lifted off.
- the photosensitive resin material layer, the lower charge transport material layer, the light emitting material layer, and the upper charge transport material layer become the photosensitive resin layer, the lower charge transport layer, the light emitting layer, and the upper charge transport layer. It is patterned.
- the step S102 is a step after the step S101.
- the step S103 is a step after the step S102.
- the step S104 is a step after the step S103.
- the step S105 is a step after the step S104.
- both the lower charge transport material layer and the upper charge transport material layer are charge transport material layers formed after the photosensitive resin material layer is formed in step S101.
- FIG 5 and 6 are cross-sectional views schematically showing an intermediate product obtained when the first electrode-to-electrode layer 43B provided in the display device 1 of the first embodiment is formed.
- Steps S101 to S105 are executed with the charge transport material layer 27B as the photosensitive resin material layer, the lower charge transport material layer, the light emitting material layer, and the upper charge transport material layer, respectively.
- the photosensitive resin layer, the lower charge transport layer, the light emitting layer, and the upper charge transport layer the first photosensitive resin layer 13B shown in FIG. 6, the lower first charge transport layer 14B, and the first The 1 light emitting layer 15B and the upper first charge transport layer 17B are formed, respectively.
- Each of the lower first charge transport material layer 24B, the first light emitting material layer 25B, and the upper first charge transport material layer 27B uses the first pixel electrode 12B as an electrode, and the second pixel electrode 12G and the third pixel electrode. With 12R as another electrode, the entire region where each layer and the electrode overlap is formed so as to overlap with the first photosensitive resin material layer 23B. As a result, from the lower first charge transport material layer 24B, the first light emitting material layer 25B, and the upper first charge transport material layer 27B, the lower side overlapping the first pixel electrode 12B and the first photosensitive resin layer 13B. The first charge transport layer 14B, the first light emitting layer 15B, and the upper first charge transport layer 17B can be obtained, respectively.
- Each layer of the lower first charge transport material layer 24B, the first light emitting material layer 25B, and the upper first charge transport material layer 27B has a first pixel electrode 12B, a second pixel electrode 12G, a third pixel electrode 12R, and a first layer. It is formed over one bank BG, a second bank GR, and a third bank RB. Therefore, each layer does not have to be patterned.
- the non-lift-off portion 27BP of 27B is a portion formed on at least a part of the first pixel electrode 12B.
- the portion 27BQ is a portion formed on at least a part of the second pixel electrode 12G and the third pixel electrode 12R.
- the first photosensitive resin material layer 23B is exposed and developed using a photomask.
- the lift-off portion 23BQ is exposed, the non-lift-off portion 23BP is not exposed, and the exposed lift-off portion 23BQ is removed by development.
- the first photosensitive resin material layer 23B contains a negative photosensitive resin, the non-lift-off portion 23BP is exposed, the lift-off portion 23BQ is not exposed, and the unexposed lift-off portion 23BQ is removed by development.
- FIG 7 and 8 are cross-sectional views schematically showing an intermediate product obtained when the second electrode-to-electrode layer 43G provided in the display device 1 of the first embodiment is formed.
- Steps S101 to S105 are executed with the two charge transport material layers 27G as the photosensitive resin material layer, the lower charge transport material layer, the light emitting material layer, and the upper charge transport material layer, respectively.
- the second photosensitive resin layer 13G shown in FIG. 8 the lower second charge transport layer 14G, and the second The two light emitting layers 15G and the upper second charge transport layer 17G are formed, respectively.
- Each of the lower second charge transport material layer 24G, the second light emitting material layer 25G, and the upper second charge transport material layer 27G uses the second pixel electrode 12G as an electrode, and the first pixel electrode 12B and the third pixel electrode. With 12R as another electrode, the entire region where each layer and the electrode overlap is formed so as to overlap with the second photosensitive resin material layer 23G. As a result, the lower second charge transport material layer 24G, the second light emitting material layer 25G, and the upper second charge transport material layer 27G overlap with the second pixel electrode 12G and the second photosensitive resin layer 13G. A second charge transport layer 14G, a second light emitting layer 15G, and an upper second charge transport layer 17G can be obtained, respectively.
- Each layer of the lower second charge transport material layer 24G, the second light emitting material layer 25G, and the upper second charge transport material layer 27G has a first pixel electrode 12B, a second pixel electrode 12G, a third pixel electrode 12R, and a first layer. It is formed over one bank BG, a second bank GR, and a third bank RB. Therefore, each layer does not have to be patterned.
- the non-lift-off portion 27GP of 27G is a portion formed on at least a part of the second pixel electrode 12G.
- the portion 27GQ is a portion formed on at least a part of the first pixel electrode 12B and the third pixel electrode 12R.
- the second photosensitive resin material layer 23G is exposed and developed using a photomask.
- the second photosensitive resin material layer 23G contains a positive photosensitive resin
- the lift-off portion 23GQ is exposed, the non-lift-off portion 23GP is not exposed, and the exposed lift-off portion 23GQ is removed by development.
- the second photosensitive resin material layer 23G contains a negative photosensitive resin
- the non-lift-off portion 23GP is exposed, the lift-off portion 23GQ is not exposed, and the unexposed lift-off portion 23GQ is removed by development.
- 9 and 10 are cross-sectional views schematically showing an intermediate product obtained when the third electrode layer 43R provided in the display device 1 of the first embodiment is formed.
- Steps S101 to S105 are executed with the three charge transport material layers 27R as the photosensitive resin material layer, the lower charge transport material layer, the light emitting material layer, and the upper charge transport material layer, respectively.
- the third photosensitive resin layer 13R shown in FIG. The 3 light emitting layer 15R and the upper third charge transport layer 17R are formed, respectively.
- Each of the lower third charge transport material layer 24R, the third light emitting material layer 25R, and the upper third charge transport material layer 27R uses the third pixel electrode 12R as an electrode, and the first pixel electrode 12B and the second pixel electrode. With 12G as another electrode, the entire region where each layer and the electrode overlap is formed so as to overlap with the third photosensitive resin material layer 23R. As a result, the lower third charge transport material layer 24R, the third light emitting material layer 25R, and the upper third charge transport material layer 27R overlap with the third pixel electrode 12R and the third photosensitive resin layer 13R. A third charge transport layer 14R, a third light emitting layer 15R, and an upper third charge transport layer 17R can be obtained, respectively.
- Each layer of the lower third charge transport material layer 24R, the third light emitting material layer 25R, and the upper third charge transport material layer 27R has a first pixel electrode 12B, a second pixel electrode 12G, a third pixel electrode 12R, and a third layer. It is formed over one bank BG, a second bank GR, and a third bank RB. Therefore, each layer does not have to be patterned.
- the non-lift-off portion 27RP of the 27R is a portion formed on at least a part of the third pixel electrode 12R.
- the portion 27RQ is a portion formed on at least a part of the first pixel electrode 12B and the second pixel electrode 12G.
- the third photosensitive resin material layer 23R is exposed and developed using a photomask.
- the third photosensitive resin material layer 23R contains a positive photosensitive resin
- the lift-off portion 23RQ is exposed, the non-lift-off portion 23RP is not exposed, and the exposed lift-off portion 23RQ is removed by development.
- the third photosensitive resin material layer 23R contains a negative type photosensitive resin
- the non-lift-off portion 23RP is exposed, the lift-off portion 23RQ is not exposed, and the unexposed lift-off portion 23RQ is removed by development.
- the photomasks used when the first inter-electrode layer 43B, the second inter-electrode layer 43G, and the third inter-electrode layer 43R are formed may be different photomasks from each other, or may be the same photomask. May be good. If the photomasks used when the first electrode layer 43B, the second electrode layer 43G, and the third electrode layer 43R are formed are the same photomasks, the same photomasks are used in different positions. To.
- these layers are patterned by an inkjet method when they are formed, it is difficult to achieve high resolution.
- these layers are patterned by lift-off after they are formed, it is easy to achieve high resolution.
- Lower first charge transport material layer 24B, first light emitting material layer 25B, upper first charge transport material layer 27B, lower second charge transport material layer 24G, second light emitting material layer 25G, upper second The charge transport material layer 27G, the lower third charge transport material layer 24R, the third light emitting material layer 25R, and the upper third charge transport material layer 27R are patterned by lift-off after these layers are formed. This eliminates the need for etching and ashing, and simplifies the manufacturing process of the display device 1.
- the lower first charge transport material layer 24B, the first light emitting material layer 25B, and the upper first charge transport material layer 27B are simultaneously patterned by lift-off, and the lower second charge transport material layer 24G, the second light emitting material.
- the layer 25G and the upper second charge transport material layer 27G are simultaneously patterned by lift-off, and the lower third charge transport material layer 24R, the third light emitting material layer 25R and the upper third charge transport material layer 27R are lift-off. Is patterned at the same time. This makes it possible to simplify the manufacturing process of the display device 1.
- the display device 1 is a painting element in which the functional layer is painted separately for each color.
- the first functional layer 41B, the second functional layer 41G, and the third functional layer 41R are independent of each other.
- the number of layers of the first functional layer 41B, the second functional layer 41G, the third functional layer 41R, and the like can be made different from each other, and the first functional layer 41B, the second functional layer 41G, and the third functional layer 41R can be made different from each other.
- the number of layers and the like can be set to be suitable for the first light emitting element B, the second light emitting element G, and the third light emitting element R, respectively, and the first light emitting element B, the second light emitting element G, and the third light emitting element can be set.
- the light emission characteristics of R can be improved.
- the luminous efficiency of the first light emitting element B, the second light emitting element G, and the third light emitting element R can be improved.
- the lower first charge transport layer 14B, the lower second charge transport layer 14G, and the lower third charge transport layer 14R are independent of each other. Further, the first light emitting layer 15B, the second light emitting layer 15G, and the third light emitting layer 15R are independent of each other. Further, the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R are independent of each other. As a result, the material, layer thickness, etc. of the lower first charge transport layer 14B, the first light emitting layer 15B, and the upper first charge transport layer 17B can be made suitable for the first light emitting element B. 1 The light emitting characteristics of the light emitting element B can be improved.
- the luminous efficiency of the first light emitting element B can be improved.
- the material, layer thickness, etc. of the lower second charge transport layer 14G, the second light emitting layer 15G, and the upper second charge transport layer 17G can be made suitable for the second light emitting element G, and the second light emitting element G can be used.
- the light emitting characteristics of the light emitting element G can be improved.
- the luminous efficiency of the second light emitting element G can be improved.
- the material, layer thickness, etc. of the lower third charge transport layer 14R, the third light emitting layer 15R, and the upper third charge transport layer 17R can be made suitable for the third light emitting element R, and the third light emitting element R can be used.
- the light emitting characteristics of the light emitting element R can be improved.
- the luminous efficiency of the third light emitting element R can be improved.
- FIG. 11 is a cross-sectional view schematically illustrating each pixel P provided in the display device 2 of the second embodiment.
- each pixel P has a substrate 11, a first pixel electrode 12B, a second pixel electrode 12G, a third pixel electrode 12R, and a first photosensitive resin layer 13B, as in the first embodiment.
- each pixel P further includes another first photosensitive resin layer 16B, another second photosensitive resin layer 16G, and another third photosensitive resin layer 16R.
- the other first photosensitive resin layer 16B, the other second photosensitive resin layer 16G, and the other third photosensitive resin layer 16R are attached to the first light emitting element B, the second light emitting element G, and the third light emitting element R, respectively. Be placed.
- the other first photosensitive resin layer 16B, the other second photosensitive resin layer 16G, and the other third photosensitive resin layer 16R are arranged on the substrate 11.
- the other first photosensitive resin layer 16B, the other second photosensitive resin layer 16G, and the other third photosensitive resin layer 16R are on the first light emitting layer 15B, the second light emitting layer 15G, and the third light emitting layer 15R. It is arranged under the upper first charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R, respectively.
- FIG. 12 is a flowchart showing a flow of formation of each electrode-to-electrode layer provided in the display device 2 of the second embodiment.
- the steps are the same as in the first embodiment. S101 to S105 are executed. Further, when the inter-electrode layer is formed, the step S106 is further executed.
- step S106 after the steps S101, S102 and S103 and before the steps S104 and S105, another photosensitive resin material layer is formed on the substrate 42.
- step S105 when the lift-off portion is lifted off, the lift-off portion of the other photosensitive resin material layer is lifted off, leaving the non-lift-off portion of the other photosensitive resin material layer without being lifted off. As a result, the photosensitive resin material layer is patterned into the photosensitive resin layer.
- both the lower charge transport material layer and the upper charge transport material layer are charge transport material layers formed after the photosensitive resin material layer is formed in step S101.
- FIG. 13 and 14 are cross-sectional views schematically showing an intermediate product obtained when the first electrode-to-electrode layer 43B provided in the display device 2 of the second embodiment is formed.
- steps S101 to S106 are executed with the other first photosensitive resin material layer 26B shown in FIG. 13 as another photosensitive resin material layer.
- another first photosensitive resin layer 16B shown in FIG. 14 can be obtained as another photosensitive resin layer.
- the other first photosensitive resin material layer 26B is the same as the other first photosensitive resin material layer 26B, with the first pixel electrode 12B as an electrode and the second pixel electrode 12G and the third pixel electrode 12R as other electrodes. The entire region where the electrodes overlap is formed so as to overlap the first photosensitive resin material layer 23B. As a result, another first photosensitive resin layer 16B that overlaps with the first pixel electrode 12B and the first photosensitive resin layer 13B can be obtained from the other first photosensitive resin material layer 26B.
- the other first photosensitive resin material layer 26B is formed over the first pixel electrode 12B, the second pixel electrode 12G, the third pixel electrode 12R, the first bank BG, the second bank GR, and the third bank RB. Will be done. Therefore, the other first photosensitive resin material layer 26B may not be patterned.
- the non-lift-off portion 26BP of the other first photosensitive resin material layer 26B is a portion formed on at least a part of the first pixel electrode 12B.
- the lift-off portion 26BQ of the other first photosensitive resin material layer 26B is a portion formed on at least a part of the second pixel electrode 12G and the third pixel electrode 12R.
- 15 and 16 are cross-sectional views schematically showing an intermediate product obtained when the second electrode-to-electrode layer 43G provided in the display device 2 of the second embodiment is formed.
- steps S101 to S106 are executed with the other second photosensitive resin material layer 26G shown in FIG. 15 as another photosensitive resin material layer.
- another second photosensitive resin layer 16G shown in FIG. 16 can be obtained as another photosensitive resin layer.
- the other second photosensitive resin material layer 26G has the second pixel electrode 12G as an electrode, the first pixel electrode 12B and the third pixel electrode 12R as other electrodes, and the other second photosensitive resin material layer 26G.
- the entire region where the electrodes overlap is formed so as to overlap the second photosensitive resin material layer 23G.
- another second photosensitive resin layer 16G that overlaps with the second pixel electrode 12G and the second photosensitive resin layer 13G can be obtained from the other second photosensitive resin material layer 26G.
- the other second photosensitive resin material layer 26G is formed over the first pixel electrode 12B, the second pixel electrode 12G, the third pixel electrode 12R, the first bank BG, the second bank GR, and the third bank RB. Will be done. Therefore, the other second photosensitive resin material layer 26G does not have to be patterned.
- the non-lift-off portion 26GP of the other second photosensitive resin material layer 26G is a portion formed on at least a part of the second pixel electrode 12G.
- the lift-off portion 26GQ of the other second photosensitive resin material layer 26G is a portion formed on at least a part of the first pixel electrode 12B and the third pixel electrode 12R.
- 17 and 18 are cross-sectional views schematically showing an intermediate product obtained when the third electrode layer 43R provided in the display device 2 of the second embodiment is formed.
- steps S101 to S106 are executed with the other third photosensitive resin material layer 26R shown in FIG. 17 as another photosensitive resin material layer.
- another third photosensitive resin layer 16R shown in FIG. 18 can be obtained as another photosensitive resin layer.
- the other third photosensitive resin material layer 26R has the third pixel electrode 12R as an electrode, the first pixel electrode 12B and the second pixel electrode 12G as other electrodes, and the other third photosensitive resin material layer 26R.
- the entire region where the electrodes overlap is formed so as to overlap the third photosensitive resin material layer 23R.
- another third photosensitive resin layer 16R that overlaps with the first pixel electrode 12B and the third photosensitive resin layer 13R can be obtained from the other third photosensitive resin material layer 26R.
- the other third photosensitive resin material layer 26R is formed over the first pixel electrode 12B, the second pixel electrode 12G, the third pixel electrode 12R, the first bank BG, the second bank GR, and the third bank RB. Will be done. Therefore, the other third photosensitive resin material layer 26R may not be patterned.
- the non-lift-off portion 26RP of the other third photosensitive resin material layer 26R is a portion formed on at least a part of the third pixel electrode 12R.
- the lift-off portion 26RQ of the other third photosensitive resin material layer 26R is a portion formed on at least a part of the first pixel electrode 12B and the second pixel electrode 12G.
- FIG. 19 is a cross-sectional view schematically illustrating each pixel P provided in the display device 2M of the first modification of the second embodiment.
- the first photosensitive resin layer 13B, the second photosensitive resin layer 13G, and the third photosensitive resin layer 13R are on the lower side.
- the other first photosensitive resin layer 16B, the other second photosensitive resin layer 16G, and the other third photosensitive resin layer 16R are formed on the upper first charge transport layer 17B and the upper second charge transport layer 17G. And on the upper third charge transport layer 17R, respectively, and below the common electrode 19.
- FIG. 20 is a flowchart showing a flow of formation of layers between electrodes provided in the display device 2M of the first modification of the second embodiment.
- the lower charge transport material layer is formed in the step S102 after the step S11 and before the step S101. Further, in the step S104 after the step S103 and before the step S106, the upper charge transport material layer is formed.
- the upper charge transport material layer is a charge transport material layer formed after the photosensitive resin material layer is formed in step S101. Further, the lower charge transport material layer is another charge transport material layer formed before the photosensitive resin material layer is formed in step S101.
- FIG. 21 is a cross-sectional view schematically illustrating each pixel P provided in the display device 2N of the second modification of the second embodiment.
- the display device 2N has an upper first charge transport layer 18B, an upper second charge transport layer 18G, and an upper third charge transport layer.
- a layer 18R is further provided.
- the upper first charge transport layer 18B, the upper second charge transport layer 18G, and the upper third charge transport layer 18R are the other first photosensitive resin layer 16B, the other second photosensitive resin layer 16G, and the other.
- Each is arranged on the third photosensitive resin layer 16R and is arranged under the common electrode 19.
- FIG. 22 is a flowchart showing a flow of formation of each electrode-to-electrode layer provided in the display device 2N of the second modification of the second embodiment.
- the upper charge transport material layer is further formed in the step S107 after the step S106 and before the step S105.
- step S105 when the lift-off portion is lifted off, the non-lift-off portion of the upper charge transport material layer formed in step S107 is left without being lifted off, and the lift-off portion of the upper charge transport material layer is lifted off. Will be done.
- the second embodiment, the first modification of the second embodiment, and the second modification of the second embodiment have the same effect as that of the first embodiment.
- the lower first charge transport layer 14B and the first light emitting layer 15B formed under the other first photosensitive resin layer 16B are combined with the other first photosensitive resin layer 16B. Can be protected by. Further, the lower second charge transport layer 14G and the second light emitting layer 15G formed under the other second photosensitive resin layer 16G can be protected by the other second photosensitive resin layer 16G. Further, the lower third charge transport layer 14R and the third light emitting layer 15R formed under the other third photosensitive resin layer 16R can be protected by the other third photosensitive resin layer 16R.
- the lower first charge transport layer 14B, the first light emitting layer 15B, the lower second charge transport layer 14G, and the second light emitting layer are used. It is possible to prevent the 15G, the lower third charge transport layer 14R and the third light emitting layer 15R from being damaged.
- the lower first charge transport layer 14B formed under the first photosensitive resin layer 13B is protected by the first photosensitive resin layer 13B. be able to. Further, the lower second charge transport layer 14G formed under the second photosensitive resin layer 13G can be protected by the second photosensitive resin layer 13G. Further, the lower third charge transport layer 14R formed under the third photosensitive resin layer 13R can be protected by the third photosensitive resin layer 13R. Further, the lower first charge transport layer 14B, the first light emitting layer 15B, and the upper first charge transport layer 17B formed under the other first photosensitive resin layer 16B are combined with the other first photosensitive resin layer. It can be protected by 16B.
- the lower second charge transport layer 14G, the second light emitting layer 15G, and the upper second charge transport layer 17G formed under the other second photosensitive resin layer 16G are combined with the other second photosensitive resin layer. It can be protected by 16G.
- the lower third charge transport layer 14R, the third light emitting layer 15R, and the upper third charge transport layer 17R formed under the other third photosensitive resin layer 16R are combined with the other third photosensitive resin layer. It can be protected by 16R.
- the lower first charge transport layer 14B, the first light emitting layer 15B, the upper first charge transport layer 17B, and the lower The second charge transport layer 14G, the second light emitting layer 15G, the upper second charge transport layer 17G, the lower third charge transport layer 14R, the third light transport layer 15R, and the upper third charge transport layer 17R are damaged. Can be suppressed.
- FIG. 23 is a cross-sectional view schematically illustrating each pixel P provided in the display device 3 of the third embodiment.
- the other first photosensitive resin layer 16B, the other second photosensitive resin layer 16G, and the other third photosensitive resin layer 16R are on the upper side. It is arranged on the 1 charge transport layer 17B, the upper second charge transport layer 17G, and the upper third charge transport layer 17R, respectively, and is arranged under the common electrode 19.
- FIG. 24 is a flowchart showing a flow of formation of each electrode-to-electrode layer provided in the display device 3 of the third embodiment.
- step S106 in the step S106 after the steps S101, S102, S103 and S104 and before the step S105, another photosensitive resin material layer is formed on the substrate 42.
- step S105 when the lift-off portion is lifted off, the lift-off portion of the other photosensitive resin material layer is lifted off, leaving the non-lift-off portion of the other photosensitive resin material layer without being lifted off. As a result, the other photosensitive resin material is patterned on the other photosensitive resin layer.
- the third embodiment has the same effect as that of the second embodiment.
- the lower first charge transport layer 14B, the first light emitting layer 15B, and the upper first charge transport layer 17B formed under the other first photosensitive resin layer 16B are provided. It can be protected by another first photosensitive resin layer 16B. Further, the lower second charge transport layer 14G, the second light emitting layer 15G, and the upper second charge transport layer 17G formed under the other second photosensitive resin layer 16G are combined with the other second photosensitive resin layer. It can be protected by 16G. Further, the lower third charge transport layer 14R, the third light emitting layer 15R, and the upper third charge transport layer 17R formed under the other third photosensitive resin layer 16R are combined with the other third photosensitive resin layer. It can be protected by 16R.
- the lower first charge transport layer 14B, the first light emitting layer 15B, the upper first charge transport layer 17B, and the lower second charge transport layer 17B Suppresses damage to the charge transport layer 14G, the second light emitting layer 15G, the upper second charge transport layer 17G, the lower third charge transport layer 14R, the third light emitting layer 15R, and the upper third charge transport layer 17R. can do.
- FIG. 25 is a cross-sectional view schematically illustrating each pixel P provided in the display device 4 of the fourth embodiment.
- each pixel P does not include the first bank BG, the second bank GR, and the third bank RB.
- the first photosensitive resin layer 13B, the lower first charge transport layer 14B, and the first light emitting layer are placed between the electrodes of the first pixel electrode 12B and the second pixel electrode 12G.
- the edges of the upper first charge transport layer 17B and the other first photosensitive resin layer 16B are the second photosensitive resin layer 13G, the lower second charge transport layer 14G, the second light emitting layer 15G, and the upper side. It overlaps the edges of the second charge transport layer 17G and the other second photosensitive resin layer 16G.
- the second photosensitive resin layer 13G, the lower second charge transport layer 14G, the second light emitting layer 15G, and the upper second charge are placed between the electrodes of the first pixel electrode 12B and the second pixel electrode 12G.
- the edges of the upper first charge transport layer 17B and the other first photosensitive resin layer 16B are the second photosensitive resin layer 13G, the lower second charge transport layer 14G, the second light emitting layer 15G, and the upper side. It overlaps the edges of the second charge transport layer 17G
- the edges of the transport layer 17G and the other second photosensitive resin layer 16G are the third photosensitive resin layer 13R, the lower third charge transport layer 14R, the third light emitting layer 15R, the upper third charge transport layer 17R, and the like. It overlaps with the edge of the other third photosensitive resin layer 16R. Further, above the electrodes between the third pixel electrode 12R and the first pixel electrode 12B, the third photosensitive resin layer 13R, the lower third charge transport layer 14R, the third light emitting layer 15R, and the upper third charge.
- the edges of the transport layer 17R and the other second photosensitive resin layer 16G are the first photosensitive resin layer 13B, the lower first charge transport layer 14B, the first light emitting layer 15B, the upper first charge transport layer 17B and the like. It overlaps the edge of the other first photosensitive resin layer 16B.
- step S105 the photosensitive resin material layer, the lower charge transport material layer, the light emitting material layer, and the upper side formed on the end portion of the electrode when the lift-off portion is lifted off.
- the upper end portion of the charge transport material layer and the other photosensitive resin material layer is left unlifted.
- the first electrode-to-electrode layer 43B the first photosensitive resin material layer 23B, the first charge transport material layer 24B, and the first are formed on the end portion of the first pixel electrode 12B.
- the upper end portion of the light emitting material layer 25B, the upper first charge transport material layer 27B, and the other first photosensitive resin material layer 26B is left without being lifted off.
- the second electrode-to-electrode layer 43G when the second electrode-to-electrode layer 43G is formed, the second photosensitive resin material layer 23G, the second charge transport material layer 24G, and the second are formed on the end portion of the second pixel electrode 12G. The upper end portions of the light emitting material layer 25G, the second charge transport material layer 27G and the other second photosensitive resin material layer 26G are left without being lifted off.
- the third electrode-to-electrode layer 43R is formed, the third photosensitive resin material layer 23R, the third charge transport material layer 24R, and the third are formed on the end portion of the third pixel electrode 12R. The upper end portions of the light emitting material layer 25R, the third charge transport material layer 27R, and the other third photosensitive resin material layer 26R are left without being lifted off.
- the fourth embodiment has the same effect as that of the third embodiment.
- the first bank BG, the second bank GR and the third bank RB are not provided, the first bank BG, the second bank GR and the third bank RB are provided. Edge leaks can be suppressed in the same way as in the case of.
- FIG. 26 is a cross-sectional view schematically illustrating each pixel P provided in the display device 5 of the fifth embodiment.
- the first photosensitive resin layer 13B on the first bank BG, the first photosensitive resin layer 13B, the lower first charge transport layer 14B, the first light emitting layer 15B, the upper first charge transport layer 17B, and the like.
- the edges of the first photosensitive resin layer 16B are the second photosensitive resin layer 13G, the lower second charge transport layer 14G, the second light emitting layer 15G, the upper second charge transport layer 17G, and other second photosensitive layers. It overlaps the edge of the resin layer 16G.
- the second bank GR on the second bank GR, the second photosensitive resin layer 13G, the lower second charge transport layer 14G, the second light emitting layer 15G, the upper second charge transport layer 17G, and the other second photosensitive resin.
- the edge of the layer 16G is the edge of the third photosensitive resin layer 13R, the lower third charge transport layer 14R, the third light emitting layer 15R, the upper third charge transport layer 17R, and the other third photosensitive resin layer 16R. Overlap on. Further, on the third bank RB, the third photosensitive resin layer 13R, the lower third charge transport layer 14R, the third light emitting layer 15R, the upper third charge transport layer 17R, and the other second photosensitive resin. The edges of the layer 16G are the edges of the first photosensitive resin layer 13B, the lower first charge transport layer 14B, the first light emitting layer 15B, the upper first charge transport layer 17B, and the other first photosensitive resin layer 16B. Overlap on.
- the fifth embodiment has the same effect as that of the third embodiment.
- leakage passing over the first bank BG, the second bank GR, and the third bank RB can be suppressed, and the first light emitting element B, the second light emitting element G, and the first light emitting element G can be suppressed.
- the luminous efficiency of the light emitting element R can be improved.
- FIG. 27 is a cross-sectional view schematically illustrating each pixel P provided in the display device 6 of the sixth embodiment.
- the first pixel electrode 12B, the first photosensitive resin layer 13B, the lower first charge transport layer 14B, and the first are on the first bank BG.
- the edges of the layer 15G, the upper second charge transport layer 17G, and the other second photosensitive resin layer 16G are not arranged.
- a second pixel electrode 12G, a second photosensitive resin layer 13G, a lower second charge transport layer 14G, a second light emitting layer 15G, an upper second charge transport layer 17G, and the like are not arranged.
- 2nd photosensitive resin layer 16G 3rd pixel electrode 12R, 3rd photosensitive resin layer 13R, lower 3rd charge transport layer 14R, 3rd light emitting layer 15R, upper 3rd charge transport layer 17R and others.
- the edge of the third photosensitive resin layer 16R is not arranged.
- the edge of the first photosensitive resin layer 16B is not arranged.
- FIG. 28 is a flowchart showing a flow of formation of each electrode-to-electrode layer provided in the display device 6 of the sixth embodiment.
- 29 to 32 are cross-sectional views schematically showing an intermediate product obtained when the second electrode-to-electrode layer 43G provided in the display device 6 of the sixth embodiment is formed.
- steps S101 to S106 are executed as in the third embodiment. Further, when the second electrode-to-electrode layer 43G is formed, steps S108 and S109 are further executed.
- step S105 when the lift-off portion 23GQ, the lift-off portion 24GQ, the lift-off portion 25GQ, the lift-off portion 27GQ, and the lift-off portion 26GQ are lifted off, the first pixel electrode 12B and the second pixel electrode 12G shown in FIG.
- 25GX, the upper portion 27X between the electrodes of the second charge transport material layer 27G and the upper portion 26GX between the electrodes of the other second photosensitive resin layer 26G are lifted off.
- the intermediate product shown in FIG. 30 is obtained.
- step S108 after step S105, the photosensitive bank material layer 51 is formed on the substrate 11 as shown in FIG. 31.
- the photosensitive bank material layer 51 penetrates into the portion where the upper portion between the electrodes 23GX, the upper portion between the electrodes 24GX, the upper portion between the electrodes 25GX, the upper portion 27X between the electrodes, and the upper portion 26GX between the electrodes were present.
- step S109 after step S108, as shown in FIG. 32, the photosensitive bank material layer 51 is exposed and developed onto the space between the electrodes of the first pixel electrode 12B and the second pixel electrode 12G.
- the first bank BG is formed.
- the second bank GR and the third bank RB are also formed in the same manner as the first bank BG.
- the sixth embodiment has the same effect as that of the third embodiment.
- the transport layer 14G and the lower third charge transport layer 14R are largely separated from each other and do not overlap, and are separated from each other by the first bank BG, the second bank GR, and the third bank RB. As a result, leakage between the first light emitting element B, the second light emitting element G, and the third light emitting element R can be suppressed.
- the present disclosure is not limited to the above-described embodiment, and is substantially the same as the configuration shown in the above-described embodiment, a configuration having the same action and effect, or a configuration capable of achieving the same purpose. May be replaced with.
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Abstract
Description
1.1 表示装置の平面構造
図1は、第1実施形態の表示装置1を模式的に図示する平面図である。
図2は、第1実施形態の表示装置1に備えられる各画素Pを模式的に図示する断面図である。
第1画素電極12B、第2画素電極12G及び第3画素電極12Rは、下側の第1電荷輸送層14B、下側の第2電荷輸送層14G及び下側の第3電荷輸送層14Rを介して第1発光層15B、第2発光層15G及び第3発光層15Rにそれぞれ接触する。下側の第1電荷輸送層14B、下側の第2電荷輸送層14G及び下側の第3電荷輸送層14Rは、第1電荷を輸送する。これらにより、第1画素電極12B、第2画素電極12G及び第3画素電極12Rから下側の第1電荷輸送層14B、下側の第2電荷輸送層14G及び下側の第3電荷輸送層14Rを経由して第1発光層15B、第2発光層15G及び第3発光層15Rに第1電荷をそれぞれ注入することができる。
表示装置1は、インバート構造又はコンベンショナル構造を有する。
第1画素電極12B、第2画素電極12G、第3画素電極12R及び共通電極19は、導電性材料により構成される。導電性材料は、例えば、金属及び透明導電性酸化物からなる群より選択される少なくとも1種を含む。金属は、例えば、Al、Cu、Au及びAgからなる群より選択される少なくとも1種を含む。透明導電性酸化物は、例えば、インジウムスズ酸化物(ITO)、インジウム亜鉛酸化物(IZO)、酸化亜鉛(ZnO)、アルミニウム亜鉛酸化物(AZO)及びホウ素亜鉛酸化物(BZO)からなる群より選択される少なくとも1種を含む。第1画素電極12B、第2画素電極12G、第3画素電極12R及び共通電極19の各電極は、1種の導電性材料により構成されるひとつの層であってもよいし、互いに異なる2種以上の導電性材料からなるふたつ以上の層の積層体であってもよい。ふたつ以上の層が、金属からなる層及び透明導電性酸化物からなる層の両方を含んでもよい。
図3は、第1実施形態の表示装置1の製造の流れを示すフローチャートである。
図4は、第1実施形態の表示装置1に備えられる各電極間層の形成の流れを示すフローチャートである。
第1感光性樹脂材料層23B、下側の第1電荷輸送材料層24B、第1発光材料層25B、上側の第1電荷輸送材料層27B、第2感光性樹脂材料層23G、下側の第2電荷輸送材料層24G、第2発光材料層25G、上側の第2電荷輸送材料層27G、第3感光性樹脂材料層23R、下側の第3電荷輸送材料層24R、第3発光材料層25R及び上側の第3電荷輸送材料層27Rは、これらの層が形成される際にはパターニングされておらず、これらの層が形成された後にリフトオフによりパターニングされる。このため、これらの層は、溶液プロセスにより形成することができる。
以下では、第2実施形態が第1実施形態と相違する点が説明される。説明されない点については、第1実施形態において採用される構成と同様の構成が第2実施形態においても採用される。
以下では、第3実施形態が第2実施形態と相違する点が説明される。説明されない点については、第2実施形態において採用される構成と同様の構成が第3実施形態においても採用される。
以下では、第4実施形態が第3実施形態と相違する点が説明される。説明されない点については、第3実施形態において採用される構成と同様の構成が第4実施形態においても採用される。
以下では、第5実施形態が第3実施形態と相違する点が説明される。説明されない点については、第3実施形態において採用される構成と同様の構成が第5実施形態においても採用される。
以下では、第6実施形態が第3実施形態と相違する点が説明される。説明されない点については、第3実施形態において採用される構成と同様の構成が第6実施形態においても採用される。
Claims (8)
- a)電極と、平面視において前記電極から距離を置いた他の電極と、を備える基板を準備する工程と、
b)前記工程a)の後に、前記基板の上に感光性樹脂材料層を形成する工程と、
c)前記工程b)の後に、前記基板の上に電荷輸送材料層及び発光材料層を、前記電荷輸送材料層と前記電極とが重なる領域の全域及び前記発光材料層と前記電極とが重なる領域の全域が前記感光性樹脂材料層と重なるように形成する工程と、
d)前記工程c)の後に、フォトマスクを使用して前記感光性樹脂材料層を露光及び現像して、前記電極の少なくとも一部の上に形成された、前記感光性樹脂材料層、前記電荷輸送材料層及び前記発光材料層の非リフトオフ部分をリフトオフせずに残して、前記他の電極の少なくとも一部の上に形成された、前記感光性樹脂材料層、前記電荷輸送材料層及び前記発光材料層のリフトオフ部分をリフトオフすることにより、前記感光性樹脂材料層、前記電荷輸送材料層及び前記発光材料層を感光性樹脂層、電荷輸送層及び発光層にそれぞれパターニングする工程と、
を備える表示装置の製造方法。 - 前記工程d)は、前記電極の端部の上に形成された、前記感光性樹脂材料層、前記電荷輸送材料層及び前記発光材料層の端部上部分をリフトオフせずに残す
請求項1に記載の表示装置の製造方法。 - e)第1電極を前記電極とし、第1感光性樹脂材料層を前記感光性樹脂材料層とし、第1電荷輸送材料層を前記電荷輸送材料層とし、第1発光材料層を前記発光材料層として、前記工程b)から前記工程d)までを実行して、前記感光性樹脂層、前記電荷輸送層及び前記発光層として第1感光性樹脂層、第1電荷輸送層及び第1色の光を発する第1発光層をそれぞれ得る工程と、
f)前記工程e)の後に、第2電極を前記電極とし、第2感光性樹脂材料層を前記感光性樹脂材料層とし、第2電荷輸送材料層を前記電荷輸送材料層とし、第2発光材料層を前記発光材料層として、前記工程b)から前記工程d)までを実行して、前記感光性樹脂層、前記電荷輸送層及び前記発光層として第2感光性樹脂層、第2電荷輸送層及び前記第1色と異なる第2色の光を発する第2発光層をそれぞれ得る工程と、
を備える請求項1又は2に記載の表示装置の製造方法。 - g)前記工程f)の後に、第3電極を前記電極とし、第3感光性樹脂材料層を前記感光性樹脂材料層とし、第3電荷輸送材料層を前記電荷輸送材料層とし、第3発光材料層を前記発光材料層として、前記工程b)から前記工程d)までを実行して、前記感光性樹脂層、前記電荷輸送層及び前記発光層として第3感光性樹脂層、第3電荷輸送層並びに前記第1色及び前記第2色と異なる第3色の光を発する第3発光層をそれぞれ得る工程
を備える請求項3に記載の表示装置の製造方法。 - 前記工程f)は、前記工程d)を実行する際に、前記電極と前記他の電極との電極間の上に形成された、前記感光性樹脂層、前記電荷輸送材料層及び前記発光材料層の電極間上部分をリフトオフし、
h)前記工程f)の後に、前記基板の上に感光性バンク材料層を形成する工程と、
i)前記工程h)の後に、前記感光性バンク材料層を露光及び現像して、前記電極間の上にバンクを形成する工程と、
を備える請求項3又は4に記載の表示装置の製造方法。 - j)前記工程a)の後であって前記工程b)の前に、他の電荷輸送材料層を形成する工程
を備える請求項1から5までのいずれかに記載の表示装置の製造方法。 - k)前記工程c)の後であって前記工程d)の前に、前記基板の上に他の感光性樹脂材料層を形成する工程
をさらに備える請求項1から6までのいずれかに記載の表示装置の製造方法。 - 前記工程c)は、
c-1)前記発光材料層を形成する工程と、
c-2)前記工程c-1)の後に前記電荷輸送材料層を形成する工程と、
を備える
請求項7に記載の表示装置の製造方法。
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