WO2022082446A1 - 电极组件、电池单体、电池、用电装置、制造方法及设备 - Google Patents
电极组件、电池单体、电池、用电装置、制造方法及设备 Download PDFInfo
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- WO2022082446A1 WO2022082446A1 PCT/CN2020/122245 CN2020122245W WO2022082446A1 WO 2022082446 A1 WO2022082446 A1 WO 2022082446A1 CN 2020122245 W CN2020122245 W CN 2020122245W WO 2022082446 A1 WO2022082446 A1 WO 2022082446A1
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- Prior art keywords
- electrode assembly
- body portion
- protruding
- assembly according
- active material
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Images
Classifications
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- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/04—Construction or manufacture in general
- H01M10/0404—Machines for assembling batteries
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/0409—Machines for assembling batteries for cells with wound electrodes
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
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- H01M10/058—Construction or manufacture
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- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
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- H01M4/02—Electrodes composed of, or comprising, active material
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/166—Lids or covers characterised by the methods of assembling casings with lids
- H01M50/169—Lids or covers characterised by the methods of assembling casings with lids by welding, brazing or soldering
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- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
- H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
- H01M50/209—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for prismatic or rectangular cells
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- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/534—Electrode connections inside a battery casing characterised by the material of the leads or tabs
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/536—Electrode connections inside a battery casing characterised by the method of fixing the leads to the electrodes, e.g. by welding
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/54—Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/564—Terminals characterised by their manufacturing process
- H01M50/566—Terminals characterised by their manufacturing process by welding, soldering or brazing
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present application relates to the field of battery technology, and in particular, to an electrode assembly, a battery cell, a battery, an electrical device, a manufacturing method and equipment.
- Batteries include multiple battery cells connected in series or in parallel to achieve greater capacity or power.
- the battery cell includes a case, an electrode assembly, an adapter member, and an electrode terminal.
- the electrode assembly includes a body portion and tabs.
- the tabs of the electrode assembly are connected to the electrode terminals through the transition parts. Electric current can be conducted into or out of the body portion through electrode terminals, transition parts, and tabs. Due to higher and higher requirements for the energy density of batteries, the size of battery cells is getting larger and larger, so that the size of the electrode assembly is getting larger and larger, and the size of the main body portion is also getting larger and larger. However, as the size of the main body becomes larger, the tabs may generate serious heat, which affects the safety of the battery.
- Embodiments of the present application provide an electrode assembly, a battery cell, a battery, an electrical device, a manufacturing method, and an apparatus, which aim to solve the technical problem of serious heat generation in the tab.
- an electrode assembly including:
- the pole piece includes a main body part and at least one protruding part, the main body part includes a metal substrate and an active material layer coated on the surface of the metal substrate, the protruding part is connected to the metal substrate and protrudes along the length direction of the electrode assembly Metal base material; along the thickness direction of the electrode assembly, the size of at least a part of the protruding portion is larger than the size of the metal base material.
- the protruding portion and the metal base material are made of the same material and are integrally arranged, which can improve the connection strength between the protruding portion and the metal base material, and can also improve the connection strength between the protruding portion and the metal base material. flow performance.
- the protruding portion includes a body portion and a conductive member, and the body portion and the conductive member are stacked in a thickness direction.
- the electrode assembly can realize the lead-out or introduction of current through the body part, the conductive part and the transfer part, which can effectively improve the electrical conductivity of the electrode assembly and improve the overall overcurrent capability of the electrode assembly.
- the size of the body portion is equal to the size of the metal substrate, which facilitates reducing the processing difficulty of the body portion and the metal substrate.
- the body portion, the metal substrate, and the conductive member are made of the same material.
- the conductive member and the body portion are made of different materials, and the resistivity of the conductive member is smaller than that of the body portion.
- the conductive member with low resistivity has high current-carrying capacity, which is beneficial to further reduce the resistance of the protruding portion and improve the current-carrying capacity of the protruding portion.
- the conductive member is connected to the body portion, the end of the conductive member away from the active material layer is flush with the end of the body portion away from the active material layer, and the area where the conductive member and the body portion overlap in the thickness direction for external electrical connection.
- the protruding part is electrically connected with the transfer part, the conductive part and the body part can be electrically connected with the transfer part at the same time.
- the conductive member includes a first connecting portion and a second connecting portion, the first connecting portion is used to connect the body portion, the second connecting portion protrudes from the end of the body portion away from the active material layer, and the second connecting portion is used to connect the body portion.
- the connection portion is used for electrical connection with the outside.
- the electrode assembly of the embodiment of the present application includes a pole piece.
- the pole piece includes a main body portion and a protruding portion.
- the main body portion includes a metal base material and an active material layer.
- the protruding portion protrudes from the metal substrate along the length direction of the electrode assembly.
- the protruding part is connected with the metal substrate.
- the size of at least a part of the protruding portion is larger than the size of the metal base material, so that the protruding portion has a larger cross-sectional area, so that the protruding portion itself has a low resistance and a large thermal capacity of the protruding portion, and further This makes the protruding part have a higher flow capacity.
- the electrode assembly of the embodiments of the present application effectively solves the problem of insufficient overcurrent capability of the protruding portion of the elongated electrode assembly, and can be used during the charging or discharging process of the electrode assembly. It can alleviate the excessively rapid temperature rise of the bulge, and at the same time improve the heat dissipation performance of the bulge, thereby reducing the possibility of serious heat generation in the bulge, which can effectively improve the charging and discharging efficiency of the battery, and can reduce the battery during charging or discharging. There is a risk of overheating, increasing the safety of battery use.
- the size of the second connection portion is greater than or equal to the size of the body portion.
- the two conductive members are respectively connected to two surfaces of the body portion.
- the cross-sectional area of the protruding part is further increased, which is beneficial to further reduce the resistance of the protruding part itself, so that the protruding part itself has a higher overcurrent capability.
- the sum of the dimensions of the second connection portions of the two conductive members is greater than or equal to the dimension of the body portion.
- the cross-sectional area of the second connecting parts of the two conductive parts used for electrical connection with the adapter part can be made larger than or equal to the cross-sectional area of the main body part, effectively ensuring the overcurrent of the second connecting parts of the two conductive parts ability.
- the body portion is welded with the conductive member.
- a protective layer is provided on the body portion close to the root of the active material layer, and a welding area between the conductive member and the body portion is provided at an interval from the protective layer.
- the protective layer provided at the root of the body portion can play a protective role, reducing the possibility of the body portion being bent and pressed between two adjacent pole pieces.
- the body portion has a fuse portion.
- the fuse part set on the main body can be close to the heating area, which is beneficial to shorten the time for the temperature to transfer to the fuse part, to ensure that the fuse part can be blown in time, and to cut off the electrical connection between the protruding part and the adapter part, thus ensuring the safety of the battery.
- the electrode assembly includes two or more pole pieces, and the two or more pole pieces are stacked in a thickness direction.
- the dimension of the protruding portion along the width direction of the electrode assembly is L1
- the dimension of the pole piece along the width direction of the main body portion is L2
- L1 and L2 satisfy: 1/3L2 ⁇ L1 ⁇ 3/4L2 .
- the dimension L1 of the protruding portion in the width direction is 15 mm to 60 mm.
- the size of the pole piece along the length direction of the electrode assembly is L3
- the size of the pole piece along the width direction of the electrode assembly is L2
- L3 and L2 satisfy: the ratio of L3/L2 ranges from 4 to 20 .
- the sum of the capacities of the active material layers on the two surfaces of the metal substrate is C greater than 3 Ah and less than 10 Ah.
- Embodiments of the present application further provide a battery cell, including: the electrode assembly according to the above embodiments.
- the embodiments of the present application also provide a battery, including the battery cells of the above-mentioned embodiments.
- Embodiments of the present application also provide an electrical device, including the battery according to the above-mentioned embodiments, and the battery is used to provide electrical energy.
- Embodiments of the present application also provide a method for manufacturing an electrode assembly, including:
- coating step coating active material layer on the surface of the first part
- the material removal step is to remove part of the material on the second sheet and the second part to form a pole piece including a main body part and at least one protruding part, and the main body part includes an active material layer and a metal substrate corresponding to the active material layer, and The thickness of at least a part of the protruding part connected to the metal base material is greater than the thickness of the metal base material, the protruding part includes a main body part and a conductive part connected to the main body part, the remaining part of the second part forms the main body part, and the remaining part of the second sheet material forms conductive parts;
- the electrode assembly is formed by winding or stacking the pole piece, and the protruding portion protrudes from the metal substrate along the length direction of the electrode assembly.
- the embodiment of the present application also provides a manufacturing equipment of an electrode assembly, including:
- a first material handling device for providing a first sheet, the first sheet having a first portion and a second portion
- a coating device for coating an active material layer on the surface of the first part
- a second material handling device for providing a second sheet for connecting the second sheet to the second part
- the material removal device removes the second sheet and part of the material on the second part to form a pole piece including a main body part and at least one protruding part, the main body part includes an active material layer and a metal substrate corresponding to the active material layer, and The thickness of at least a part of the protruding part connected to the metal base material is greater than the thickness of the metal base material, the protruding part includes a main body part and a conductive part connected to the main body part, the remaining part of the second part forms the main body part, and the remaining part of the second sheet material forms conductive parts;
- the forming device is used for winding or stacking the pole piece to form the electrode assembly, and the protruding part protrudes from the metal base material along the length direction of the electrode assembly.
- FIG. 1 is a schematic structural diagram of a vehicle according to an embodiment of the present application.
- FIG. 2 is a schematic diagram of an exploded structure of a battery pack according to an embodiment of the present application.
- FIG. 3 is a schematic diagram of a partial structure of a battery module according to an embodiment of the present application.
- FIG. 4 is a schematic diagram of an exploded structure of a battery cell according to an embodiment of the present application.
- FIG. 5 is a schematic top-view structural diagram of an electrode assembly according to an embodiment of the present application.
- FIG. 6 is a schematic side view of the structure of an electrode assembly according to an embodiment of the present application.
- FIG. 7 is a partial side structural schematic diagram of an electrode assembly according to an embodiment of the present application.
- FIG. 8 is a partial side structural schematic diagram of an electrode assembly according to another embodiment of the present application.
- FIG. 9 is a partial side structural schematic diagram of an electrode assembly according to another embodiment of the present application.
- FIG. 10 is a partial side structural schematic diagram of an electrode assembly according to another embodiment of the present application.
- FIG. 11 is a partial side structural schematic diagram of an electrode assembly according to another embodiment of the present application.
- FIG. 12 is a partial side structural schematic diagram of an electrode assembly according to still another embodiment of the present application.
- FIG. 13 is a partial top-view structural schematic diagram of an electrode assembly according to an embodiment of the present application.
- FIG. 14 is a partial top-view structural schematic diagram of an electrode assembly according to another embodiment of the present application.
- 15 is a schematic diagram of a method for manufacturing an electrode assembly according to an embodiment of the present application.
- 16 is a schematic diagram of a partial structure of a pole piece according to an embodiment of the present application.
- FIG. 17 is a schematic structural diagram of an apparatus for manufacturing an electrode assembly according to an embodiment of the present application.
- the structure of the battery cell is made into a long strip-shaped flat structure, so that the The length of the electrode main body of the electrode assembly becomes large and has an elongated flat structure.
- the tabs extend from the end face of the electrode body.
- the tabs extending from the end face of the electrode body have a problem of insufficient overcurrent capability, which leads to the problem of serious heating of the tabs.
- the applicant improves the structure of the battery cell, and the embodiments of the present application are further described below.
- the embodiment of the present application provides an electrical device using the battery 10 as a power source.
- the electrical device can be, but not limited to, a vehicle, a ship, or an aircraft.
- an embodiment of the present application provides a vehicle 1 .
- the vehicle 1 may be a fuel vehicle, a gas vehicle or a new energy vehicle. New energy vehicles can be pure electric vehicles, hybrid vehicles or extended-range vehicles.
- the vehicle 1 may include a motor 1 a , a controller 1 b and a battery 10 .
- the controller 1b is used to control the battery 10 to supply power to the motor 1a.
- the motor 1a is connected to the wheels through a transmission mechanism, thereby driving the vehicle 1 to travel.
- the battery 10 can be used as a driving power source of the vehicle 1 to provide driving power for the vehicle 1 in place of or partially in place of fuel or natural gas.
- the battery 10 may be provided at the bottom, front or rear of the vehicle 1 .
- the battery 10 may be used to power the vehicle 1 .
- the battery 10 may be used as the operating power source of the vehicle 1 for the electrical system of the vehicle 1 .
- the battery 10 may be used for the operating power requirements of the vehicle 1 for starting, navigating, and operating.
- the battery 10 may include more than two battery modules 20 .
- the battery 10 further includes a case.
- the battery module 20 is disposed in the box. Two or more battery modules 20 are arranged in the box.
- the type of cabinet is not limited.
- the case can be a frame-shaped case, a disc-shaped case, a box-shaped case, or the like.
- the box body includes a first casing 11 for accommodating the battery module 20 and a second casing 12 covering with the first casing 11 .
- the first casing 11 and the second casing 12 are closed to form an accommodating portion for accommodating the battery module 20 .
- the battery module 20 may include one or more battery cells 30 .
- a plurality of battery cells 30 can be connected in series, parallel or mixed to form a battery module, and then a plurality of battery modules 20 can be connected in series, parallel or mixed to form a battery.
- Hybrid refers to a mix of series and parallel.
- the battery may include a plurality of battery cells 30, wherein the plurality of battery cells 30 may be connected in series, in parallel or in a mixed connection.
- the plurality of battery cells 30 may be directly disposed in the box. That is to say, the plurality of battery cells 30 may directly form the battery 10 , or may form the battery module 20 first, and then the battery module 20 may form the battery 10 .
- the battery cell 30 includes, but is not limited to, a lithium-ion-containing secondary battery, a lithium-ion primary battery, a lithium-sulfur battery, a sodium-lithium-ion battery, or a magnesium-ion battery.
- the width of the battery cell 30 is the same as the height of the vehicle 1 . Due to the space limitation in the height direction of the vehicle 1, the width of the battery cells 30 is also strictly limited, so when the capacity of the battery cells 30 needs to be increased, the width of the battery cells 30 cannot be increased infinitely, and the battery cells 30 can be enlarged.
- the length of the monomer 30 is also strictly limited, so when the capacity of the battery cells 30 needs to be increased, the width of the battery cells 30 cannot be increased infinitely, and the battery cells 30 can be enlarged.
- the battery cell 30 of the embodiment of the present application includes a casing 31 and an electrode assembly 32 disposed in the casing 31 .
- the housing 31 in the embodiment of the present application has a square structure or other shapes.
- the case 31 has an inner space that accommodates the electrode assembly 32 and the electrolyte, and an opening communicating with the inner space.
- the housing 31 may be made of a material such as aluminum, aluminum alloy, or plastic.
- the electrode assembly 32 is the core component of the battery cell 30 to realize the charging and discharging function.
- the battery cell 30 of the embodiment of the present application further includes an end cap 33 , an electrode terminal 34 and a transition member 35 .
- the end cap 33 is connected with the casing 31 and closes the opening of the casing 31 .
- the end cap 33 and the housing 31 may be connected by welding.
- the electrode terminal 34 is provided on the end cap 33 .
- the outer shape of the electrode terminal 34 may be circular or square, which is not limited here.
- the electrode terminal 34 is electrically connected to the electrode assembly 32 through the adapter member 35 .
- Two or more battery cells 30 can be connected in series, in parallel or in mixed connection through their respective electrode terminals 34 .
- the electrode assembly 32 of the embodiment of the present application includes an electrode body 32a.
- the electrode assembly 32 has a predetermined length, width and thickness.
- the length refers to the size of the electrode body 32a along its own length direction X
- the width refers to the size of the electrode body 32a along its own width direction Y
- the thickness refers to the size of the electrode body 32a along its own thickness direction Z.
- the longitudinal direction X, the width direction Y, and the thickness direction Z are perpendicular to each other.
- the electrode body 32 a of the embodiment of the present application may include a pole piece 321 .
- the pole piece 321 may be a positive pole piece, and the electrode body 32a may include one or more positive pole pieces.
- the pole piece 321 may also be a negative electrode piece, and the electrode body 32a may include one or more negative electrode pieces.
- the electrode body 32a includes a positive electrode sheet and a negative electrode sheet, the positive electrode sheet and the negative electrode sheet can be stacked along the thickness direction Z, so that the formed electrode assembly 32 has a laminated structure, or the positive electrode sheet and the negative electrode sheet can also be wound to form an electrode assembly 32. Since two adjacent pole pieces 321 have opposite polarities, the two adjacent pole pieces 321 can be separated by a diaphragm 322 .
- the diaphragm 322 is an insulator between two pole pieces 321 of opposite polarities.
- the pole piece 321 in the embodiment of the present application includes a main body portion 3211 and at least one protruding portion 3212 .
- the protruding portion 3212 protrudes from the main body portion 3211 in the longitudinal direction X of the electrode main body 32a.
- each of the protruding parts 3212 with the same polarity may be arranged in layers along the thickness direction Z.
- the respective main body portions 3211 are stacked in the thickness direction Z to form the electrode main body 32a.
- the adapter member 35 is electrically connected to the protruding portion 3212 .
- the adapter part 35 is welded with the protruding part 3212, such as laser welding or ultrasonic welding.
- the main body portion 3211 includes a metal base material 3211a and an active material layer 3211b. At least a part of the surface of the metal substrate 3211a is coated with the active material layer 3211b, that is, the surface of the metal substrate 3211a may be completely or partially covered by the active material layer 3211b.
- the active material layer 3211b may include a ternary material, lithium manganate or lithium iron phosphate.
- the active material layer 3211b may include graphite or silicon.
- the protruding portion 3212 is connected to the metal base material 3211a, and the protruding portion 3212 protrudes from the metal base material 3211a along the length direction X of the electrode body 32a.
- the size of at least a part of the protruding portion 3212 is larger than the size of the metal substrate 3211a, so that the cross-sectional area of the protruding portion 3212 can be increased, which is beneficial to reduce the resistance of the protruding portion 3212, and also It is beneficial to increase the overall heat capacity of the protruding portion 3212 , thereby improving the overcurrent capability of the protruding portion 3212 .
- Heat capacity refers to the amount of heat required to increase the temperature of a predetermined material by 1 degree Celsius.
- the electrode assembly 32 in the embodiment of the present application includes at least one pole piece 321 .
- the pole piece 321 includes a main body portion 3211 and a protruding portion 3212 .
- the main body portion 3211 includes a metal base material 3211a and an active material layer 3211b.
- the protruding portion 3212 protrudes from the metal substrate 3211 a along the length direction X of the electrode assembly 32 .
- the protruding portion 3212 is connected to the metal substrate 3211a.
- the size of at least a part of the protruding portion 3212 is larger than the size of the metal substrate 3211a, so that the protruding portion 3212 has a larger cross-sectional area, so that the protruding portion 3212 itself has low resistance and protrudes
- the heat capacity of the portion 3212 is large, so that the protruding portion 3212 has a higher current capacity.
- the electrode assembly 32 of the embodiment of the present application effectively solves the problem of insufficient overcurrent capability of the protrusion 3212 of the elongated electrode assembly 32, and can be During the charging or discharging process of the electrode assembly 32, the excessive temperature rise of the protruding part 3212 is relieved, and the heat dissipation performance of the protruding part 3212 is improved, thereby reducing the possibility of serious heating of the protruding part 3212, which can effectively improve the charging and discharging efficiency of the battery , and can reduce the risk of overheating of the battery during charging or discharging, and improve the safety of battery use.
- active material layers 3211b may be provided on two opposite surfaces of the metal substrate 3211a.
- the metal base material 3211a is a whole sheet, that is, the metal base material 3211a is an integrally formed structure.
- the protruding portion 3212 includes a body portion 32121 and a conductive member 32122 .
- the adapter member 35 may be electrically connected to the body portion 32121 of the protruding portion 3212 .
- the main body portion 32121 and the metal base material 3211a are made of the same material and are integrally provided.
- the material of the metal substrate 3211a and the material of the body portion 32121 are both aluminum or copper.
- the main body 32121 and the metal base 3211a are made of the same material and are integrally provided, which can improve the connection strength between the main body 32121 and the metal base 3211a, and can also improve the overcurrent performance between the body 32121 and the metal base 3211a.
- the size of at least a part of the body portion 32121 is larger than the size of the metal substrate 3211a, that is, the entire or partial size of the body portion 32121 is larger than that of the metal substrate 3211a
- the size of the body portion 32121 enables the body portion 32121 to have a larger cross-sectional area, which is beneficial to reduce its own resistance, so that the body portion 32121 itself has a higher flow capacity.
- the conductive member 32122 and the body portion 32121 are stacked and disposed.
- at least part of the conductive member 32122 may be connected to the body portion 32121 by welding, for example, laser welding or ultrasonic welding.
- the adapter part 35 may be electrically connected with the protruding part 3212 .
- the electrode assembly 32 can lead or introduce current through the body portion 32121 , the conductive member 32122 and the adapter member 35 , effectively improving the electrical conductivity of the electrode assembly 32 and improving the overall overcurrent capability of the electrode assembly 32 .
- the conductive member 32122 may be a sheet-like structure.
- the sum of the dimensions of the conductive member 32122 and the body portion 32121 is larger than that of the metal substrate 3211a, so that the protruding portion 3212 has a larger cross-sectional area, It is beneficial to further reduce the resistance of the protruding portion 3212 itself, so that the protruding portion 3212 itself has a higher overcurrent capability.
- the size of the body portion 32121 is equal to the size of the metal substrate 3211a, that is, the overall size of the body portion 32121 is equal to the size of the metal substrate 3211a.
- the surface of the body portion 32121 may be kept flush with the surface of the metal base material 3211a. In the process of integrally molding the body portion 32121 and the metal base material 3211a, since the body portion 32121 and the metal base material 3211a have the same thickness, the processing difficulty of the body portion 32121 and the metal base material 3211a can be reduced, thereby reducing the processing cost.
- the size of the conductive member 32122 is smaller than or equal to the size of the metal substrate 3211a, and the sum of the size of the conductive member 32122 and the body portion 32121 is larger than the size of the metal substrate 3211a.
- the body portion 32121 , the metal substrate 3211 a and the conductive member 32122 are made of the same material.
- the resistivity of each of the body portion 32121 , the metal base material 3211 a and the conductive member 32122 is equal.
- the material of the body portion 32121, the metal base material 3211a, and the conductive member 32122 may be aluminum material or copper material.
- the pole piece 321 is a positive pole piece
- the material of the body portion 32121 , the metal substrate 3211 a and the conductive member 32122 can be made of aluminum.
- the pole piece 321 is a negative pole piece
- the material of the body portion 32121 , the metal substrate 3211 a and the conductive member 32122 can be made of copper.
- the conductive member 32122 and the body portion 32121 are made of different materials, and the resistivity of the conductive member 32122 is smaller than that of the body portion 32121 .
- Resistivity is a physical quantity used to express the resistance characteristics of various substances. The resistance of a conductor with a length of 1 meter and a cross-sectional area of 1 square meter made of a certain material is numerically equal to the resistivity of this material.
- the conductive member 32122 with a small resistivity has a high overcurrent capability, thereby further reducing the resistance of the protruding portion 3212 and improving the overcurrent capability of the protruding portion 3212 .
- the conductive member 32122 is made of copper, and the body portion 32121 is made of aluminum.
- the conductive member 32122 is connected to the body portion 32121 .
- the end of the conductive member 32122 away from the active material layer 3211b is flush with the end of the body portion 32121 away from the active material layer 3211b.
- a region where the conductive member 32122 and the body portion 32121 overlap in the thickness direction Z is used for electrical connection with the outside.
- the area where the conductive member 32122 and the body portion 32121 overlap along the thickness direction Z is used for electrical connection with the transition member 35 .
- the protruding part 3212 is electrically connected to the transfer part 35
- the conductive member 32122 and the body part 32121 can be electrically connected to the transfer part 35 at the same time.
- the conductive member 32122 and the body portion 32121 are welded to the adapter member 35 at the same time.
- the conductive member 32122 includes a first connection portion 32122a and a second connection portion 32122b.
- the first connecting portion 32122a is used to connect the body portion 32121.
- the first connection part 32122a and the body part 32121 are connected by welding.
- the second connecting portion 32122b protrudes from the end of the main body portion 32121 away from the active material layer 3211b.
- the second connection portion 32122b is used for electrical connection with the outside. In the embodiment of the present application, the second connection portion 32122b is used for electrical connection with the adapter member 35 .
- the way in which the second connection portion 32122b is electrically connected to the adapter member 35 is beneficial to reduce the stacking thickness of the connection area between the second connection portion 32122b and the adapter member 35, so that the second connection portion 32122b and the adapter member 35 are connected by welding. It is beneficial to reduce the difficulty of welding, and reduce the possibility that the second connection portion 32122b and the adapter member 35 are soldered due to poor welding, thereby affecting the overcurrent capability between the second connection portion 32122b and the adapter member 35 .
- the size of the second connection portion 32122b is greater than or equal to the size of the body portion 32121.
- the sum of the dimensions of the second connection portion 32122b and the body portion 32121 is larger than that of the metal base material 3211a.
- the two conductive members 32122 there are two conductive members 32122 .
- the two conductive members 32122 are respectively connected to two surfaces of the body portion 32121.
- One surface of the body portion 32121 is connected to a conductive member 32122.
- the two conductive parts 32122 and the body part 32121 are provided, so that the cross-sectional area of the protruding part 3212 is further increased, which is beneficial to further reduce the resistance of the protruding part 3212 itself, so that the protruding part 3212 itself has a higher overcurrent capability. .
- the end of each conductive member 32122 away from the active material layer 3211b is flush with the end of the body portion 32121 away from the active material layer 3211b.
- a region where the two conductive members 32122 and the body portion 32121 overlap in the thickness direction Z is used for electrical connection with the outside.
- the overlapping region of the two conductive members 32122 and the body portion 32121 along the thickness direction Z is used for electrical connection with the transition member 35 .
- both conductive members 32122 include a first connection portion 32122a and a second connection portion 32122b.
- the first connection portion 32122a of each conductive member 32122 is used to connect the main body portion 32121, and the second connection portion 32122b of each conductive member 32122 protrudes from the end portion of the main body portion 32121 away from the active material layer 3211b, and the second connection portion 32122 of each conductive member 32122
- the connection portion 32122b is used for electrical connection with the outside.
- the second connection portion 32122b of each conductive member 32122 is used for electrical connection with the transition member 35 .
- the sum of the dimensions of the second connection portions 32122b of the two conductive members 32122 along the thickness direction Z is greater than or equal to the dimension of the body portion 32121 along the thickness direction Z, so that the size of the second connection portion 32122b along the thickness direction Z is greater than or equal to the dimension of the body portion 32121 along the thickness direction Z.
- the cross-sectional area of the second connection portion 32122b of the two electrically connected conductive members 32122 is greater than or equal to the cross-sectional area of the body portion 32121, which effectively ensures the overcurrent capability of the second connection portion 32122b of the two conductive members 32122 and reduces the two It is possible that the second connecting portion 32122b of the conductive member 32122 becomes a weak portion of the current-carrying capacity, thereby ensuring that the protruding portion 3212 as a whole has a good current-carrying capacity.
- the body portion 32121 is provided with a protective layer 323 near the root of the active material layer 3211b.
- the conductive member 32122 and the body portion 32121 can be connected by welding.
- the conductive member 32122 and the welding region of the main body portion 32121 are spaced apart from the protective layer 323 .
- the body portion 32121 is easily bent and deformed under force and is pressed between two adjacent pole pieces 321, thereby causing a risk of short circuit.
- the protective layer 323 provided at the root portion of the body portion 32121 can play a protective role, even if the body portion 32121 is bent and pressed into the space between the two adjacent pole pieces 321 During this time, the protective layer 323 can also effectively separate the two pole pieces 321, thereby reducing the risk of short circuit and improving the safety of the battery.
- the material of the protective layer 323 may be an insulating material, such as aluminum oxide, magnesium oxide, titanium dioxide, zirconium oxide, silicon dioxide, silicon carbide, boron carbide, calcium carbonate, aluminum silicate, calcium silicate, potassium titanate , one or more of barium sulfate.
- the protective layer 323 may be adhered to the main body portion 32121 using an adhesive.
- the binder includes one or more of polyvinylidene fluoride, polyacrylonitrile, polyacrylic acid, polyacrylate, polyacrylic acid-acrylate, polyacrylonitrile-acrylic acid, and polyacrylonitrile-acrylate.
- the protective layer 323 may be an active material layer 3211b. When the active material layer 3211b is coated on the metal substrate 3211a of the pole piece 321 , the active material layer 3211b may be coated on the root of the body portion 32121 at the same time to form the protective layer 323 .
- the body portion 32121 has a fuse portion 32121a.
- the conductive member 32122 is connected to the fuse portion 32121a of the main body portion 32121 by welding.
- the fuse part 32121a provided on the main body part 32121 can be close to the heating area, which is beneficial to shorten the time for the temperature to be transmitted to the fuse part 32121a, ensure that the fuse part 32121a can be blown in time, and cut off the protruding part 3212 and the fuse part 32121a.
- the electrical connection of the adapter part 35 is used to ensure the safety of the battery.
- the end of the body portion 32121 away from the pole piece 321 has a separation groove 32121b.
- the dividing groove 32121b divides the end portion of the main body portion 32121 so that a plurality of fuse portions 32121a are formed at the end portion.
- the size of the end of the body portion 32121 away from the pole piece 321 is reduced to form a fuse portion 32121a.
- the corners of the end of the body portion 32121 may be cut to reduce the size of the end of the body portion 32121 to form the fuse portion 32121a.
- the dimension of the protruding portion 3212 along the width direction Y of the electrode body 32a is L1
- the dimension of the pole piece 321 along the width direction Y of the electrode body 32a is L2
- L1 and L2 satisfy: 1/3L2 ⁇ L1 ⁇ 3/4L2.
- L1 may be 0.4L2, 0.5L2, 0.6L2, or 0.7L2, etc.
- the dimension L1 of the protruding portion 3212 along the width direction Y is 15 millimeters (mm) to 60 millimeters.
- the dimension of the pole piece 321 along the length direction X of the electrode body 32a is L3
- the dimension of the pole piece 321 along the width direction Y of the electrode body 32a is L2
- L3 and the width L2 satisfy: L3/L2
- the ratio ranges from 4 to 20.
- the ratio of L3/L2 is an integer from 4 to 20. Since the electrode assembly 32 of the embodiment of the present application includes the protruding portion 3212 with high current-carrying capacity, the length of the electrode piece 321 can be increased to a larger value, and a wider range of length and width ratio can be obtained, which is beneficial to improve the battery performance.
- the energy density also enables the battery to be charged quickly and is less prone to overheating, improving the safety of the battery.
- the sum of the capacities of the active material layers 3211b on the two surfaces of the metal substrate 3211a is C greater than 3Ah and less than 10Ah. Since the electrode assembly 32 of the embodiment of the present application includes the protruding portion 3212 with high overcurrent capability, the capacity of the electrode piece 321 can be increased to a larger value, which is beneficial to improve the energy density of the battery, and also enables the battery to achieve fast charging and It is less prone to overheating and improves charging efficiency.
- an embodiment of the present application further provides a method for manufacturing an electrode assembly 32, including:
- first sheet 40 having a first portion 41 and a second portion 42;
- coating step coating the active material layer 3211b on the surface of the first part 41;
- the material removal step is to remove part of the material on the second sheet 50 and the second part 42 to form a pole piece 321 including a main body part 3211 and at least one protruding part 3212, the main body part 3211 including the active material layer 3211b and the active material layer 3211b
- the thickness of at least a part of the protrusion 3212 connected to the metal base 3211a is greater than the thickness of the metal base 3211a.
- the remaining part of the second part 42 forms the body part 32121, and the remaining part of the second sheet 50 forms the conductive member 32122;
- the electrode assembly 32 is formed by winding or stacking the pole piece 321 .
- the pole piece 321 includes a protrusion 3212 .
- the pole piece 321 includes more than two protruding portions 3212 . Two or more protruding parts 3212 are arranged at intervals.
- the electrode assembly 32 manufactured by the manufacturing method of the embodiment of the present application has at least one pole piece 321 .
- the pole piece 321 includes a main body portion 3211 and at least one protruding portion 3212 .
- the protruding portion 3212 protrudes from the metal substrate 3211 a along the length direction X of the electrode assembly 32 .
- the protruding portion 3212 is connected to the metal substrate 3211a.
- the size of at least a part of the protruding portion 3212 is larger than the size of the metal substrate 3211a, so that the protruding portion 3212 has a larger cross-sectional area, so that the protruding portion 3212 has a small resistance and protrudes
- the heat capacity of the portion 3212 is large, so that the protruding portion 3212 has a higher current capacity.
- the excessive temperature rise of the protruding part 3212 is relieved, and the heat dissipation performance of the protruding part 3212 is improved, thereby reducing the possibility of serious heating of the protruding part 3212, which can effectively improve the charging and discharging efficiency of the battery , and can reduce the risk of overheating of the battery during charging or discharging, and improve the safety of battery use.
- an embodiment of the present application further provides an apparatus 100 for manufacturing an electrode assembly 32 , including:
- a first material processing device 101 for providing a first sheet 40, the first sheet 40 having a first part 41 and a second part 42;
- the coating device 102 is used for coating the active material layer 3211b on the surface of the first part 41;
- the second material processing device 103 is used for providing the second sheet material 50 and connecting the second sheet material 50 to the second part 42;
- the material removal device 104 removes part of the material on the second sheet 50 and the second part 42 to form a pole piece 321 comprising a main body 3211 and at least one protruding part 3212, the main body 3211 comprising an active material layer 3211b and a
- the metal substrate 3211a corresponding to the layer 3211b, the thickness of at least a part of the protruding portion 3212 connected to the metal substrate 3211a is greater than the thickness of the metal substrate 3211a, and the protruding portion 3212 includes a main body portion 32121 and a conductive member 32122 connected to the main body portion 32121 , the remaining part of the second part 42 forms the body part 32121, and the remaining part of the second sheet 50 forms the conductive member 32122;
- the forming device 105 is used for winding or stacking the pole piece 321 to form the electrode assembly 32 , and the protruding portion 3212 protrudes from the metal substrate 3211 a along the length direction of the electrode assembly 32 .
- the destocking device 104 includes a cutter.
- the cutter cuts the second sheet 50 and the second portion 42 along a predetermined trajectory to remove a portion of the material on the second sheet 50 and the second portion 42 .
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Abstract
Description
Claims (24)
- 一种电极组件,包括:极片,包括主体部和至少一个凸出部,所述主体部包括金属基材和涂覆于所述金属基材表面的活性物质层,所述凸出部连接于所述金属基材,并沿所述电极组件的长度方向凸出所述金属基材;沿所述电极组件的厚度方向,所述凸出部至少一部分的尺寸大于所述金属基材的尺寸。
- 根据权利要求1所述的电极组件,其中,所述凸出部与所述金属基材为相同材质且一体设置。
- 根据权利要求1或2所述的电极组件,其中,所述凸出部包括本体部和导电件,所述本体部与所述导电件沿所述厚度方向层叠设置。
- 根据权利要求3所述的电极组件,其中,沿所述厚度方向,所述本体部的尺寸与所述金属基材的尺寸相等。
- 根据权利要求3或4所述的电极组件,其中,所述本体部、所述金属基材和所述导电件为相同材质。
- 根据权利要求3或4所述的电极组件,其中,所述导电件与所述本体部为不同的材质,且所述导电件的电阻率小于所述本体部的电阻率。
- 根据权利要求3至6任一项所述的电极组件,其中,所述导电件远离所述活性物质层的端部与所述本体部远离所述活性物质层的端部齐平,所述导电件和所述本体部沿所述厚度方向重叠的区域用于与外部电连接。
- 根据权利要求3至6任一项所述的电极组件,其中,所述导电件包括第一连接部和第二连接部,所述第一连接部用于连接所述本体部,所述第二连接部凸出所述本体部远离所述活性物质层的端部,所述第二连接部用于与外部电连接。
- 根据权利要求8所述的电极组件,其中,沿所述厚度方向,所述第二连接部的尺寸大于或者等于所述本体部的尺寸。
- 根据权利要求8所述的电极组件,其中,所述导电件为两个,两个所述导电件分别连接于所述本体部的两个表面。
- 根据权利要求10所述的电极组件,其中,沿所述厚度方向,两个所述导电件的所述第二连接部的尺寸之和大于或者等于所述本体部的尺寸。
- 根据权利要求3至11任一项所述的电极组件,其中,所述本体部与所述导电件焊接。
- 根据权利要求12所述的电极组件,其中,所述本体部靠近所述活性物质层的根部设置保护层,所述导电件与所述本体部的焊接区域与所述保护层间隔设置。
- 根据权利要求3至13任一项所述的电极组件,其中,所述本体部具有熔断部。
- 根据权利要求1至14任一项所述的电极组件,其中,所述电极组件包括两个以上的所述极片,两个以上的所述极片沿所述厚度方向层叠设置。
- 根据权利要求15所述的电极组件,其中,所述凸出部沿所述电极组件的宽度方向的尺寸为L1,所述极片沿所述宽度方向的尺寸为L2,L1和L2满足:1/3L2≤L1≤3/4L2。
- 根据权利要求16所述的电极组件,其中,所述凸出部沿所述宽度方向的尺寸L1为15毫米至60毫米。
- 根据权利要求15所述的电极组件,其中,所述极片沿所述电极组件的所述长度方向的尺寸为L3,所述极片沿所述电极组件的宽度方向的尺寸为L2,L3和L2满足:L3/L2的比值范围为4至20。
- 根据权利要求15至18任一项所述的电极组件,其中,所述金属基材的两个表面的所述活性物质层的容量之和为C大于3Ah,小于10Ah。
- 一种电池单体,包括:如权利要求1至19任一项所述的电极组件。
- 一种电池,包括如权利要求20所述的电池单体。
- 一种用电装置,包括如权利要求21所述的电池,所述电池用于提供电能。
- 一种电极组件的制造方法,包括:提供第一片材,所述第一片材具有第一部分和第二部分;涂覆步骤,在所述第一部分表面上涂覆活性物质层;提供第二片材,将所述第二片材连接于所述第二部分;去料步骤,去除所述第二片材和所述第二部分上的部分材料,形成包括主体部和至少一个凸出部的极片,所述主体部包括所述活性物质层与所述活性物质层对应的金属基材,与所述金属基材连接所述凸出部至少一部分的厚度大于所述金属基材的厚度,所述凸出部包括本体部和连接于所述本体部的导电件,所述第二部分剩余部分形 成所述本体部,所述第二片材剩余部分形成所述导电件;成型步骤,将所述极片卷绕或层叠形成电极组件,所述凸出部沿所述电极组件的长度方向凸出所述金属基材。
- 一种电极组件的制造设备,包括:第一物料处理装置,用于提供第一片材,所述第一片材具有第一部分和第二部分;涂覆装置,用于在所述第一部分表面上涂覆活性物质层;第二物料处理装置,用于提供第二片材,将所述第二片材连接于所述第二部分;去料装置,去除所述第二片材和所述第二部分上的部分材料,形成包括主体部和至少一个凸出部的极片,所述主体部包括所述活性物质层与所述活性物质层对应的金属基材,与所述金属基材连接所述凸出部至少一部分的厚度大于所述金属基材的厚度,所述凸出部包括本体部和连接于所述本体部的导电件,所述第二部分剩余部分形成所述本体部,所述第二片材剩余部分形成所述导电件;成型装置,用于将所述极片卷绕或层叠形成电极组件,所述凸出部沿所述电极组件的长度方向凸出所述金属基材。
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PCT/CN2020/122245 WO2022082446A1 (zh) | 2020-10-20 | 2020-10-20 | 电极组件、电池单体、电池、用电装置、制造方法及设备 |
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EP20958029.9A EP4084207A4 (en) | 2020-10-20 | 2020-10-20 | ELECTRODE ASSEMBLY, BATTERY CELL, BATTERY, ELECTRICAL APPARATUS, AND METHOD AND DEVICE FOR MAKING |
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