WO2021241255A1 - 多官能ビニル樹脂及びその製造方法 - Google Patents

多官能ビニル樹脂及びその製造方法 Download PDF

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WO2021241255A1
WO2021241255A1 PCT/JP2021/018295 JP2021018295W WO2021241255A1 WO 2021241255 A1 WO2021241255 A1 WO 2021241255A1 JP 2021018295 W JP2021018295 W JP 2021018295W WO 2021241255 A1 WO2021241255 A1 WO 2021241255A1
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group
resin
polyfunctional vinyl
vinyl resin
parts
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English (en)
French (fr)
Japanese (ja)
Inventor
正浩 宗
一男 石原
在滿 韓
海璃 尹
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Nippon Steel Chemical and Materials Co Ltd
Kukdo Chemical Co Ltd
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Nippon Steel Chemical and Materials Co Ltd
Kukdo Chemical Co Ltd
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Application filed by Nippon Steel Chemical and Materials Co Ltd, Kukdo Chemical Co Ltd filed Critical Nippon Steel Chemical and Materials Co Ltd
Priority to US17/926,131 priority Critical patent/US12378345B2/en
Priority to CN202180036207.2A priority patent/CN115667355B/zh
Priority to JP2022526878A priority patent/JPWO2021241255A1/ja
Priority to KR1020227039089A priority patent/KR102803525B1/ko
Publication of WO2021241255A1 publication Critical patent/WO2021241255A1/ja
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Definitions

  • the present invention relates to a polyfunctional vinyl resin and a polyfunctional vinyl resin composition having both low dielectric loss tangent and high thermal conductivity, which are useful for printed circuit boards, encapsulants, casting materials, etc. of electronic devices, and cured products thereof.
  • a cured resin for example, a cured resin such as a bisphenol divinylbenzyl ether resin or a phenol novolac type polyvinylbenzyl ether resin has been proposed (Patent Documents 1 and 2).
  • Patent Documents 1 and 2 a cured resin such as a bisphenol divinylbenzyl ether resin or a phenol novolac type polyvinylbenzyl ether resin
  • these vinylbenzyl ether resins not only did not have sufficient properties in the initial dielectric properties, but also could not give a cured resin with a small change in the dielectric properties with respect to a severe thermal history, and in terms of heat resistance. , It was not high enough.
  • a polyfunctional vinyl resin obtained by converting at least one hydroxyl group selected from the group consisting of a phenol aralkyl resin, a naphthol aralkyl resin, a biphenyl type phenol novolac resin, and a biphenyl type naphthol novolak resin into a vinyl benzyl ether.
  • a polyfunctional vinyl resin composition (Patent Document 6) is disclosed.
  • the vinylbenzyl etherified polyfunctional vinyl resin synthesized according to the manufacturing method disclosed therein has a large total halogen content and a large amount of residual vinyl aromatic halomethyl compound, so that it has undergone a severe thermal history.
  • the dielectric loss tangent and heat resistance are not satisfactory as an insulating material corresponding to a high frequency, and the moldability is also liable to cause molding defects, which is not desirable.
  • polyhydric phenol and monovalent phenol having 3 or more and less than 9 phenolic hydroxyl groups in the molecule and having an alkyl group or an alkylene group at the 2nd and 6th positions of at least one phenolic hydroxyl group.
  • the phenolic hydroxyl group of the polyfunctional phenylene ether oligomer obtained by reacting a compound is vinylbenzylated (Patent Document 7).
  • the vinylbenzyl ether resin obtained by this technique has a drawback that the molding processing temperature is high due to its high viscosity and the dielectric loss tangent is significantly deteriorated when exposed to a high temperature in an air atmosphere. rice field.
  • the conventional vinyl benzyl ether resin has heat resistance that satisfies the low dielectric loss tangent after a severe thermal history that can withstand lead-free soldering, which is required for electrical insulating material applications, especially high frequency compatible electrical insulating materials. It does not give a cured product with, and is also inadequate in terms of reliability and processability.
  • Japanese Unexamined Patent Publication No. 63-68537 Japanese Unexamined Patent Publication No. 64-65110 Special Table 1-503238 Gazette Japanese Unexamined Patent Publication No. 9-31006 Japanese Unexamined Patent Publication No. 2004-323730 Japanese Unexamined Patent Publication No. 2003-306591 JP-A-2007-308685
  • the subject of the present invention is a vinyl having a low relative permittivity and a low dielectric loss tangent, but with a small change in dielectric properties after receiving a severe thermal history, showing high thermal conductivity, and giving a cured product having a high glass transition temperature.
  • resins and resin compositions resin compositions, cured products or materials containing them that can be used as dielectric materials, insulating materials, heat-resistant materials in the fields of electrical / electronic industry, space / aircraft industry, etc. The purpose is to provide.
  • the present inventor is a phenol of a polyvalent hydroxy resin having a dicyclopentenyl group obtained from a reaction between a 2,6-disubstituted phenol and a dicyclopentadiene as a substituent.
  • a polyfunctional vinyl resin in which the sex hydroxyl group is aromatic vinyl was used, and completed the present invention.
  • the present invention is a polyfunctional vinyl resin represented by the following general formula (1).
  • R 1 independently represents a hydrocarbon group having 1 to 8 carbon atoms.
  • R 2 independently represents a hydrogen atom or a dicyclopentenyl group, and at least one is a dicyclopentenyl group.
  • X independently represents a hydrogen atom or a vinyl group-containing aromatic group represented by the above formula (1a), and at least one is a vinyl group-containing aromatic group.
  • n indicates the number of repetitions, and the average value thereof is a number of 1 to 5.
  • Ar of the formula (1a) represents an aromatic ring, and an aromatic ring selected from the group of a benzene ring, a naphthalene ring and a biphenyl ring is preferable, and the aromatic ring Ar may be unsubstituted or has one or more substituents. good.
  • the present invention is a method for producing the above-mentioned polyfunctional vinyl resin, in which 0.28 to 2 times mol of dicyclopentadiene is added to 1 mol of 2,6-di-substituted phenol represented by the following general formula (2). After the polyvalent hydroxy resin represented by the following general formula (3) was obtained by reacting at the ratio of It is a method for producing a polyfunctional vinyl resin, which comprises reacting. here, R 1 , R 2 , X, and n are synonymous with the definitions in the above general formula (1), respectively. R 3 indicates halogen.
  • the present invention is a polyfunctional vinyl resin composition containing a polyfunctional vinyl resin and a radical polymerization initiator as essential components, and a cured polyfunctional vinyl resin obtained by curing the polyfunctional vinyl resin. Further, it is a resin sheet including a semi-cured product of a polyfunctional vinyl resin composition, a prepreg made of a fibrous base material, and a support film, and a laminated board formed by laminating the prepreg and / or the resin sheet.
  • the polyfunctional vinyl resin and composition of the present invention and further the cured product obtained by curing the composition, have a high thermal conductivity while having a low relative permittivity and dielectric loss tangent, and are used as electronic materials for high-speed communication equipment such as electronic parts. It is useful as a material that easily releases heat from wiring and has little signal loss. In particular, it can maintain excellent dielectric properties even when it receives a high-temperature thermal history under an air atmosphere, and has high reliability in electrical properties even under harsh usage conditions.
  • the GPC chart of the polyvalent hydroxy resin obtained in the synthesis example 1 is shown.
  • the IR chart of the polyvalent hydroxy resin obtained in Synthesis Example 1 is shown.
  • the GPC chart of the polyfunctional vinyl resin obtained in Example 1 is shown.
  • R ⁇ SUP> 1 ⁇ / SUP> represents a hydrocarbon group having 1 to 8 carbon atoms, an alkyl group having 1 to 8 carbon atoms, an aryl group having 6 to 8 carbon atoms, and 7 carbon atoms.
  • An aralkyl group of -8 or an allyl group is preferable.
  • the alkyl group having 1 to 8 carbon atoms may be linear, branched or cyclic, and may be, for example, a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group or a sec-butyl group.
  • Examples of the aryl group having 6 to 8 carbon atoms include, but are not limited to, a phenyl group, a tolyl group, a xylyl group, an ethylphenyl group and the like.
  • Examples of the aralkyl group having 7 to 8 carbon atoms include, but are not limited to, a benzyl group and an ⁇ -methylbenzyl group.
  • substituents a methyl group or a phenyl group is preferable, and a methyl group is particularly preferable, from the viewpoint of easy availability and reactivity when prepared as a cured product.
  • R 2 independently represents a hydrogen atom or a dicyclopentenyl group, and at least one is a dicyclopentenyl group.
  • the dicyclopentenyl group is a group derived from dicyclopentadiene and is represented by the following formula (1b) or formula (1c).
  • X independently represents a hydrogen atom or a vinyl group-containing aromatic group represented by the above formula (1a), and at least one is a vinyl group-containing aromatic group, which is a group derived from a raw material aromatic vinylizing agent.
  • Ar of the formula (1a) is an aromatic ring selected from the group of benzene ring, naphthalene ring and biphenyl ring.
  • the aromatic ring Ar may be unsubstituted or may have one or more substituents. When it has a substituent, it is preferably 1 to 4, and the substituent is preferably an alkyl group or an aryl group having 1 to 10 carbon atoms, and more preferably an alkyl group or a phenyl group having 1 to 3 carbon atoms.
  • n is the number of repetitions, which indicates a number of 1 or more, and the average value thereof indicates a number of 1 to 5, preferably 1.1 to 4.0, more preferably 1.2 to 3.0, and 1. 3 to 2.0 is more preferable.
  • the average value is a number average.
  • the number average molecular weight (Mn) of the polyfunctional vinyl resin of the present invention is preferably 400 to 3000, more preferably 500 to 1500.
  • the vinyl equivalent (g / eq,) is preferably 200 to 600, more preferably 220 to 550, even more preferably 300 to 550, and particularly preferably 400 to 500.
  • the total amount of chlorine is preferably 1500 ppm or less, more preferably 1300 ppm or less.
  • the polyfunctional vinyl resin of the present invention can be suitably obtained by reacting the polyvalent hydroxy resin represented by the general formula (3) with the aromatic vinyl agent represented by the general formula (4). Can be done.
  • the polyvalent hydroxy resin represented by the general formula (3) is, for example, by a method of reacting dicyclopentadiene with the 2,6-di-substituted phenol represented by the general formula (2) at a predetermined ratio.
  • dicyclopentadiene may be added continuously, or it may be added in several steps (two or more divided sequential additions), and the reaction may be intermittent.
  • the ratio is 0.28 to 2-fold mol of dicyclopentadiene to 1 mol of 2,6-di-substituted phenol.
  • the ratio of dicyclopentadiene to 1 mol of 2,6-disubstituted phenol is 0.25 to 1-fold mol and 0.28 to 1-fold mol. It is preferably 0.3 to 0.5 times the mole, more preferably.
  • dicyclopentadiene is sequentially added in portions and reacted, 0.8 to 2 times mol is preferable as a whole, and 0.9 to 1.7 times mol is more preferable.
  • the ratio of dicyclopentadiene used at each stage is preferably 0.28 to 1-fold molar.
  • the 2,6-di-substituted phenol is 2,6-dimethylphenol, 2,6-diethylphenol, 2,6-dipropylphenol, 2,6-diisopropylphenol, 2,6-di (n-butyl) phenol. , 2,6-di (t-butyl) phenol, 2,6-dihexylphenol, 2,6-dicyclohexylphenol, 2,6-diphenylphenol, etc., which are easily available and can be used as a cured product. From the viewpoint of reactivity, 2,6-diphenylphenol and 2,6-dimethylphenol are preferable, and 2,6-dimethylphenol is particularly preferable.
  • the catalyst used for reacting phenols with dicyclopentadiene is Lewis acid, specifically, boron trifluoride, boron trifluoride / phenol complex, boron trifluoride / ether complex and the like.
  • Boron trifluoride compounds, metal chlorides such as aluminum chloride, tin chloride, zinc chloride, titanium tetrachloride, iron chloride, and organic sulfonic acids such as methanesulfonic acid, ethanesulfonic acid, and propanesulfonic acid are handled.
  • Boron trifluoride / ether complex is preferable because of its ease of use.
  • the amount of the catalyst used is 0.001 to 20 parts by mass, preferably 0.5 to 10 parts by mass with respect to 100 parts by mass of dicyclopentadiene.
  • reaction method a method in which 2,6-di-substituted phenol and a catalyst are charged in a reactor and dicyclopentadiene is added dropwise over 1 to 10 hours is preferable.
  • the reaction temperature is preferably 50 to 200 ° C, more preferably 100 to 180 ° C, and even more preferably 120 to 160 ° C.
  • the reaction time is preferably 1 to 10 hours, more preferably 3 to 10 hours, still more preferably 4 to 8 hours.
  • alkali such as sodium hydroxide, potassium hydroxide, calcium hydroxide, etc.
  • a solvent such as aromatic hydrocarbons such as toluene and xylene and ketones such as methyl ethyl ketone and methyl isobutyl ketone is added and dissolved, washed with water, and then the solvent is recovered under reduced pressure to obtain the desired poly.
  • a valent hydroxy resin can be obtained. It is preferable that the entire amount of dicyclopentadiene is reacted as much as possible, a part of the 2,6-di-substituted phenol is unreacted, preferably 10% or less is unreacted, and the reaction is carried out under reduced pressure.
  • aromatic hydrocarbons such as benzene, toluene and xylene, halogenated hydrocarbons such as chlorobenzene and dichlorobenzene, ethylene glycol dimethyl ether, diethylene glucol dimethyl ether and the like may be used as necessary for adjusting the viscosity.
  • a solvent such as ethers of the above and ketones such as methylisobutylketone, cyclopentanone, and cyclohexanone may be used.
  • Mass spectrometry (MS) and Fourier transform infrared spectrophotometer (FT-IR) measurement method can be used as a method for confirming that the dicyclopentenyl group has been introduced into the polyvalent hydroxy resin. can.
  • an electrospray mass spectrometry method ESI-MS
  • FD-MS field decomposition method
  • the dicyclopentenyl group has been introduced by subjecting a sample obtained by separating components having different numbers of nuclei by mass spectrometry to GPC or the like.
  • a sample dissolved in an organic solvent such as THF is applied onto the KRS-5 cell, and the cell with a sample thin film obtained by drying the organic solvent is measured by FT-IR.
  • the peak derived from the C—O stretching vibration in the phenol nucleus appears near 1210 cm -1
  • the peak derived from the CH stretching vibration of the olefin moiety of the dicyclopentadiene skeleton is 3040 cm only when the dicyclopentadiene group is introduced. Appears near -1.
  • the amount of dicyclopentenyl group introduced can be quantified by the ratio (A 3040 / A 1210 ) of the peak (A 1210) in the vicinity. It has been confirmed that the larger the ratio, the better the physical property value, and the preferable ratio (A 3040 / A 1210 ) for satisfying the desired physical property is 0.05 or more, more preferably 0.10 or more, and particularly 0. .10 to 0.30.
  • the hydroxyl group equivalent of the polyfunctional hydroxy resin is preferably 150 to 500, more preferably 200 to 350.
  • the weight average molecular weight (Mw) is preferably 500 to 2000, more preferably 600 to 900, and the number average molecular weight (Mn) is preferably 350 to 1200, more preferably 400 to 600.
  • the softening point is preferably 70 to 120 ° C, more preferably 70 to 110 ° C.
  • the polyfunctional vinyl resin of the present invention is preferably obtained by reacting the polyvalent hydroxy resin represented by the general formula (3) thus obtained with an aromatic vinylizing agent represented by the general formula (4). Obtainable.
  • halomethylstyrene As the aromatic vinyl agent represented by the general formula (4), halomethylstyrene is preferable. Specific examples of halomethylstyrene include chloromethylstyrene, bromomethylstyrene and isomers thereof, and those having a substituent. Regarding the substitution position of the halomethyl form, for example, in the case of halomethylstyrene, the 4-position is preferable, and the 4-position is preferably 60% by mass or more of the whole.
  • the reaction between the polyvalent hydroxy resin and halomethylstyrene as an aromatic vinyl agent can be carried out in the absence of a solvent or in the presence of a solvent.
  • the reaction is possible by adding halomethylstyrene to the polyvalent hydroxy resin, adding a metal hydroxide to carry out the reaction, and removing the produced metal salt by a method such as filtration or washing with water.
  • the ratio of the polyvalent hydroxy resin to the aromatic vinylizing agent is preferably 0.5 to 1.5 equivalents, more preferably 0.5 to 1.5 equivalents, with respect to 1 equivalent of the hydroxyl group equivalent of the polyvalent hydroxy resin. It is advisable to react so that the amount is 0.8 to 1.2 equivalents.
  • solvent examples include, but are not limited to, benzene, toluene, xylene, methyl isobutyl ketone, diethylene glycol dimethyl ether, cyclopentanone, cyclohexanone and the like.
  • metal hydroxide examples include, but are not limited to, sodium hydroxide, potassium hydroxide and the like.
  • the reaction should be at a temperature of 100 ° C. or lower, preferably 80 ° C. or lower, and if there is a concern about self-polymerization of halomethylstyrene as an aromatic vinylizing agent, quinones, nitro compounds, nitrophenols, nitroso compounds, nitron compounds. , Oxygen and other polymerization inhibitors may be used.
  • the reaction end point can be determined by tracking the residual amount of halomethylstyrene as an aromatic vinylizing agent with various chromatograms, and as a method for adjusting the reaction rate, the type and amount of metal hydroxide and the addition rate can be adjusted. It can be adjusted by adjusting and using an appropriate catalyst.
  • polyfunctional vinyl resin of the present invention can be cured by itself, it is also suitable to use it as a polyfunctional resin composition containing various additives.
  • a radical polymerization initiator can be blended and cured to promote curing.
  • the radical polymerization initiator also referred to as a radical polymerization catalyst
  • the resin composition of the present invention undergoes a crosslinking reaction by means such as heating as described later and is cured, but the reaction temperature at that time is lowered.
  • it may be used by containing a radical polymerization initiator for the purpose of accelerating the cross-linking reaction of unsaturated groups.
  • the amount of the radical polymerization initiator used for this purpose is preferably 0.01 to 12 parts by mass, more preferably 0.1 to 8 parts by mass with respect to 100 parts by mass of the polyfunctional vinyl resin.
  • radical polymerization initiators are benzoyl peroxide, cumene hydroperoxide, 2,5-dimethylhexane-2,5-dihydroperoxide, 2,5-dimethyl-2,5-di ().
  • t-butylperoxy) Hexin-3 di-t-butyl peroxide, t-butylcumyl peroxide, ⁇ , ⁇ '-bis (t-butylperoxy-m-isopropyl) benzene, 2,5-dimethyl- 2,5-Di (t-butylperoxy) hexane, dicumyl peroxide, di-t-butylperoxyisophthalate, t-butylperoxybenzoate, 2,2-bis (t-butylperoxy) butane, Peroxides such as 2,2-bis (t-butylperoxy) octane, 2,5-dimethyl-2,5-di (benzoylperoxy) he
  • 2,3-dimethyl-2,3-diphenylbutane can also be used as a radical polymerization initiator (or polymerization catalyst).
  • the catalyst and radical polymerization initiator used for curing the present resin composition are not limited to these examples.
  • the polyfunctional vinyl resin composition of the present invention can be blended with other vinyl resins or other thermal polyfunctional vinyl resins.
  • vinyl ester resin polyvinyl benzyl resin, epoxy resin, oxetane resin, maleimide resin, acrylate resin, polyester resin, polyurethane resin, polycyanate resin, phenol resin, benzoxazine resin and the like.
  • thermoplastic resins such as polystyrene resin, polyphenylene ether resin, polyetherimide resin, polyether sulfone resin, PPS resin, polycyclopentadiene resin, and polycycloolefin resin, styrene-ethylene-propylene copolymer, and styrene- Thermoplastic elastomers such as ethylene-butylene copolymer, styrene-butadiene copolymer, styrene-isoprene copolymer, hydrogenated styrene-butadiene copolymer, hydrogenated styrene-isoprene copolymer, polybutagen, polyisoprene, etc. It is also possible to mix rubbers and the like.
  • various known flame retardants can be used for the purpose of improving the flame retardancy of the obtained cured product as long as the reliability is not deteriorated.
  • the flame retardants that can be used include halogen-based flame retardants, phosphorus-based flame retardants, nitrogen-based flame retardants, silicone-based flame retardants, inorganic flame retardants, organic metal salt-based flame retardants, and the like. From the viewpoint of the environment, halogen-free flame retardants are preferable, and phosphorus-based flame retardants are particularly preferable.
  • These flame retardants may be used alone, two or more kinds of flame retardants of the same system may be used in combination, or flame retardants of different systems may be used in combination.
  • the polyfunctional vinyl resin composition of the present invention may contain components other than those listed above for the purpose of further improving its functionality.
  • Such other components include fillers, UV inhibitors, antioxidants, coupling agents, plasticizers, fluxes, rocking modifiers, smoothing agents, colorants, pigments, dispersants, emulsifiers, and low elasticity. Examples thereof include agents, mold release agents, antifoaming agents, ion trapping agents and the like.
  • Examples of the filler include molten silica, crystalline silica, alumina, silicon nitride, boron nitride, aluminum nitride, aluminum hydroxide, calcium hydroxide, magnesium hydroxide, boehmite, talc, mica, clay, calcium carbonate, magnesium carbonate, and the like.
  • Inorganic fillers such as barium carbonate, zinc oxide, titanium oxide, magnesium oxide, magnesium silicate, calcium silicate, zirconium silicate, barium sulfate, carbon, carbon fiber, glass fiber, alumina fiber, silica alumina fiber, silicon carbide
  • fibrous fillers such as fibers, polyester fibers, polyamide fibers, cellulose fibers, aramid fibers, and ceramic fibers, and fine particle rubber.
  • Other components include organic pigments such as quinacridone, azo, and phthalocyanine, inorganic pigments such as titanium oxide, metal foil pigments, and rust preventive pigments, and ultraviolet absorption such as hindered amines, benzotriazoles, and benzophenones.
  • Agents antioxidants such as hindered phenol-based, phosphorus-based, sulfur-based, and hydrazide-based, mold release agents such as stearic acid, palmitic acid, zinc stearate, calcium stearate, leveling agents, leology control agents, pigment dispersion.
  • Additives such as agents, anti-repellent agents, antifoaming agents and the like can be mentioned.
  • the blending amount of these other components is preferably in the range of 0.01 to 20% by mass with respect to the total solid content in the resin composition.
  • the polyfunctional vinyl resin composition of the present invention can be made into a resin varnish by dissolving it in a solvent.
  • the solvent include methyl ethyl ketone, acetone, toluene, xylene, tetrahydrofuran, dioxolane, dimethylformamide, methyl isobutyl ketone, methoxypropanol, cyclohexanone, methyl cellosolve, ethyl diglycol acetate, propylene glycol monomethyl ether acetate, ⁇ -butyrolactone and the like.
  • the selection and the appropriate amount of use can be appropriately selected depending on the application.
  • the solvent has a boiling point of 160 ° C. or lower, such as methyl ethyl ketone, acetone, toluene, xylene, and 1-methoxy-2-propanol, and the non-volatile content is 20 to 80% by mass. It is preferable to use in.
  • ketones such as acetone, methyl ethyl ketone and cyclohexanone
  • ester compounds such as ethyl acetate, butyl acetate, cellosolve acetate, propylene glycol monomethyl ether acetate, carbitol acetate and ⁇ -butyrolactone.
  • carbitols such as cellosolve and butyl carbitol
  • aromatic hydrocarbons such as toluene and xylene, dimethylformamide, dimethylacetamide, N-methylpyrrolidone and the like
  • the non-volatile content is 20 to 80% by mass. It is preferable to use it in proportion.
  • the laminated board of the present invention is obtained by curing a resin varnish. Specific examples thereof include a printed wiring board, a printed circuit board, a flexible printed wiring board, and a build-up wiring board.
  • the cured product obtained by curing the polyfunctional vinyl resin composition of the present invention can be used as a molded product, a laminate, a cast product, an adhesive, a coating film, or a film.
  • the cured product of the semiconductor encapsulation material is a cast product or a molded product, and as a method for obtaining a cured product for this purpose, the compound is cast or molded using a transfer molding machine, an injection molding machine, or the like. Further, the cured product can be obtained by further heating at 80 to 230 ° C. for 0.5 to 10 hours.
  • the cured product of the resin varnish is a laminate, and as a method for obtaining this cured product, the resin varnish is impregnated into a base material such as the fibrous filler or paper and dried by heating to obtain a prepreg, which is then used. It can be obtained by hot press molding alone or by laminating with a metal foil such as a copper foil.
  • an inorganic high-dielectric powder such as barium titanate or an inorganic magnetic material such as ferrite.
  • a substrate is added to the prepreg of the present invention to increase mechanical strength and dimensional stability.
  • Such substrates include various glass cloths such as roving cloths, cloths, chopped mats, surfacer mats, asbestos cloths, metal fiber cloths, and other synthetic or natural inorganic fiber cloths, all aromatic polyamide fibers, and all fragrances.
  • Woven fabrics or non-woven fabrics obtained from liquid crystal fibers such as group polyester fibers and polybenzozar fibers, woven fabrics or non-woven fabrics obtained from synthetic fibers such as polyvinyl alcohol fibers, polyester fibers and acrylic fibers, cotton cloths, linen cloths, natural fibers such as felts.
  • Cloths such as cloth, carbon fiber cloth, kraft paper, cotton paper, natural cellulose-based cloth such as paper-glass mixed fiber paper, and papers are used individually or in combination of two or more.
  • the proportion of the base material in the prepreg is preferably 5 to 90% by mass, preferably 10 to 80% by mass, and more preferably 20 to 70% by mass.
  • the amount of the base material is less than 5% by mass, the dimensional stability and strength of the cured product tend to decrease. Further, when the amount of the base material exceeds 90% by mass, the dielectric property of the cured product tends to deteriorate.
  • a coupling agent can be used in the prepreg of the present invention for the purpose of improving the adhesiveness at the interface between the resin and the base material.
  • the coupling agent general agents such as a silane coupling agent, a titanate coupling agent, an aluminum-based coupling agent, and a zircoaluminate coupling agent can be used.
  • the polyfunctional vinyl resin composition of the present invention and other components, if necessary, are uniformly mixed in the above aromatic, ketone or the like solvent, or a mixed solvent thereof.
  • a method of dissolving or dispersing in a substrate, impregnating the substrate with the substrate, and then drying the substrate can be mentioned.
  • Impregnation is performed by dipping, coating, or the like. The impregnation can be repeated multiple times as needed, and at this time, the impregnation can be repeated using a plurality of solutions having different compositions and concentrations to finally adjust to the desired resin composition and amount. It is possible.
  • a cured product can be obtained by curing the prepreg of the present invention by a method such as heating.
  • the manufacturing method is not particularly limited, and for example, a plurality of prepregs are laminated, and each layer is bonded under heat and pressure, and at the same time, thermosetting is performed to obtain a cured product (laminated plate) having a desired thickness. Can be done. It is also possible to obtain a multi-layered laminate having a new layer structure by combining a cured product once adhesively cured and a prepreg. Laminate molding and curing are usually performed simultaneously using a hot press or the like, but both may be performed independently. That is, the uncured or semi-cured prepreg obtained by laminating and molding in advance can be cured by heat treatment or another method.
  • Molding and curing are carried out, for example, in temperature: 80-300 ° C., pressure: 0.1-1000 kgf / cm 2 , time: 1 minute to 10 hours, more preferably temperature: 150-250 ° C., pressure: 1-. 500 kgf / cm 2 , time: 1 minute to 5 hours.
  • the laminate of the present invention is composed of a layer of the prepreg of the present invention and a layer of a metal foil.
  • the metal foil used here include copper foil and aluminum foil.
  • the thickness is not particularly limited, but is in the range of 3 to 200 ⁇ m, more preferably 5 to 105 ⁇ m.
  • the polyfunctional vinyl resin composition of the present invention described above the prepreg obtained from the substrate, and the metal leaf are laminated in a layer structure according to the purpose and heated. Examples thereof include a method of adhering each layer under pressure and at the same time thermally curing the layers.
  • the cured product and the metal foil are laminated in an arbitrary layer structure.
  • the metal leaf can be used as both a surface layer and an intermediate layer. In addition to the above, it is also possible to repeat laminating and curing a plurality of times to form a multi-layered structure.
  • Adhesive can also be used for adhesion to metal foil.
  • the adhesive include, but are not limited to, epoxy-based, acrylic-based, phenol-based, cyanoacrylate-based, and the like.
  • the above-mentioned laminate molding and curing can be performed under the same conditions as the production of the cured product of the prepreg of the present invention.
  • the polyfunctional vinyl resin composition of the present invention can also be molded into a film.
  • the thickness is not particularly limited, but is in the range of 3 to 200 ⁇ m, more preferably 5 to 105 ⁇ m.
  • the method for producing the film of the present invention is not particularly limited, and for example, the polyfunctional vinyl resin composition and other components, if necessary, are contained in an aromatic, ketone or other solvent, or a mixed solvent thereof. Examples thereof include a method in which the solvent is uniformly dissolved or dispersed in a resin film, applied to a resin film such as a PET film, and then dried. The coating can be repeated multiple times as needed, and at this time, the coating can be repeated using a plurality of solutions having different compositions and concentrations to finally adjust the desired resin composition and amount. Is.
  • a metal foil with a resin can be obtained from the polyfunctional vinyl resin composition of the present invention and the metal foil.
  • the metal foil used here include copper foil and aluminum foil.
  • the thickness is not particularly limited, but is in the range of 3 to 200 ⁇ m, more preferably 5 to 105 ⁇ m.
  • the method for producing the metal leaf with resin is not particularly limited, and for example, the polyfunctional vinyl resin composition and other components, if necessary, are contained in a solvent such as aromatic or ketone, or a mixed solvent thereof. Examples thereof include a method in which the solvent is uniformly dissolved or dispersed in a metal leaf, applied to a metal foil, and then dried. The coating can be repeated multiple times as needed, and at this time, the coating can be repeated using a plurality of solutions having different compositions and concentrations to finally adjust to the desired resin composition and amount. It is possible.
  • the substrate for electronic materials is made by using the laminate of the present invention.
  • the electronic material substrate is a mobile phone, PHS, notebook computer, PDA (personal digital assistant), or portable television that is required to have reliability in an environment where heat resistance and water resistance are required and transmission reliability of high-frequency signals.
  • circuit board for the above-mentioned electric / electronic equipment because of the heat resistance stability of the excellent dielectric property of the cured product of the present invention, the dimensional stability corresponding to the formation of a circuit having a fine pattern, and the moldability.
  • Specific examples thereof include single-sided, double-sided, multi-layer printed circuit boards, flexible boards, and build-up boards.
  • a multilayer circuit board using metal plating as the conductor layer is also included as a preferable example.
  • Hydroxy group equivalent Measured according to JIS K 0070 standard. Specifically, using a potentiometric titrator, 1,4-dioxane is used as a solvent, acetylation is performed with 1.5 mol / L acetyl chloride, and excess acetyl chloride is decomposed with water to 0.5 mol / L-. Titration was performed using potassium hydroxide. Unless otherwise specified, the hydroxyl group equivalent of the polyvalent hydroxy resin means the phenolic hydroxyl group equivalent.
  • 0.1 g of the sample was dissolved in 10 mL of THF, and 50 ⁇ L of the sample filtered through a microfilter was used.
  • GPC-8020 Model II version 6.00 manufactured by Tosoh Corporation was used.
  • Relative permittivity and dielectric loss tangent Measured according to JIS C 2565 standard. Specifically, the sample is dried in an oven set at 105 ° C. for 2 hours, allowed to cool in a desiccator, and then measured using a cavity resonator method permittivity measuring device manufactured by AET Co., Ltd. It is shown by the value of 1 GHz.
  • Glass transition temperature (Tg) Measured according to JIS C 6481 standard. Specifically, it was represented by the tan ⁇ peak top when the measurement was performed with a dynamic viscoelasticity measuring device (EXSTAR DMS6100, manufactured by Hitachi High-Tech Science Corporation) under a temperature rising condition of 5 ° C./min.
  • HV3 Vinyl compound (manufactured by Mitsubishi Gas Chemical Company, Ope-2ST, Mn1187, vinyl group equivalent 590)
  • Synthesis example 1 140 parts of 2,6-xylenol, 9.3 parts of 47% BF 3 ether complex (first) in a reactor consisting of a glass separable flask equipped with a stirrer, thermometer, nitrogen blowing ring, dropping funnel, and condenser. (0.1 times mol) with respect to the dicyclopentadiene added to the mixture was charged and heated to 110 ° C. with stirring. While maintaining the same temperature, 86.6 parts of dicyclopentadiene (0.57 times mol with respect to 2,6-xylenol) was added dropwise over 1 hour. After further reacting at a temperature of 110 ° C.
  • the MIBK was evaporated and removed by heating to 160 ° C. under a reduced pressure of 5 mmHg to obtain 274 parts of a reddish brown polyvalent hydroxy resin (P1).
  • the hydroxyl group equivalent was 299
  • the resin had a softening point of 97 ° C.
  • the absorption ratio (A 3040 / A 1210 ) was 0.17.
  • M- 253, 375, 507, 629 was confirmed.
  • the GPC of the obtained multivalent hydroxy resin (P1) is shown in FIG. 1, and the FT-IR is shown in FIG. 2, respectively.
  • Mw in GPC was 690 and Mn was 510.
  • c shows the peak derived from the CH expansion and contraction vibration of the olefin moiety of the dicyclopentadiene skeleton
  • d shows the absorption by the CH expansion and contraction vibration in the phenol nucleus.
  • Synthesis example 2 In the same reaction apparatus as in Synthesis Example 1, 140 parts of 2,6-xylenol and 9.3 parts of 47% BF 3 ether complex (0.1 times by mole with respect to the dicyclopentadiene added first) were charged and stirred. While warming to 110 ° C. While maintaining the same temperature, 86.6 parts of dicyclopentadiene (0.57 times mol with respect to 2,6-xylenol) was added dropwise over 1 hour. After further reacting at a temperature of 110 ° C. for 3 hours, 90.6 parts of dicyclopentadiene (0.60 times mol with respect to 2,6-xylenol) was added dropwise in 1 hour while maintaining the same temperature. The reaction was further carried out at 120 ° C.
  • the hydroxyl group equivalent was 341, the resin had a softening point of 104 ° C., and the absorption ratio (A 3040 / A 1210 ) was 0.27.
  • M- 253, 375, 507, 629 was confirmed.
  • Mw in GPC was 830 and Mn was 530.
  • Synthesis example 3 To the same reactor as in Synthesis Example 1, 970 parts of 2,6-xylenol were charged 14.5 parts of 47% BF 3 etherate, it was heated with stirring to 70 ° C.. While maintaining the same temperature, 300 parts of dicyclopentadiene (0.29 times mol with respect to 2,6-xylenol) was added dropwise over 2 hours. Further, the reaction was carried out at a temperature of 125 to 135 ° C. for 6 hours, and 2.3 parts of calcium hydroxide was added. Further, 4.6 parts of a 10% oxalic acid aqueous solution was added. Then, it was heated to 160 ° C. and dehydrated, and then heated to 200 ° C.
  • Example 1 100 parts of the polyvalent hydroxy resin (P1), 230 parts of diethylene glycol dimethyl ether, and 51.1 parts of chloromethylstyrene were charged in the same apparatus as in Synthesis Example 1 and dissolved by raising the temperature to 70 ° C. 39.5 parts of a 48% potassium hydroxide aqueous solution was added dropwise over 1 hour, and the reaction was further carried out at 75 ° C. for 4 hours. It was confirmed by gas chromatography that there was no residual chloromethylstyrene, and the solvent was recovered under reduced pressure. The obtained resin was dissolved in 300 parts of toluene and washed with 100 parts of water until the pH of the aqueous layer reached 7. Then, the solvent was distilled off under reduced pressure to obtain 203 parts of vinyl resin (V1) which is a toluene solution having a non-volatile content of 65%. The vinyl equivalent was 417 and the total chlorine was 1150 ppm.
  • V1 vinyl resin
  • Example 2 100.0 parts of a polyvalent hydroxy resin (P2), 230 parts of diethylene glycol dimethyl ether, and 44.7 parts of chloromethylstyrene were charged in the same apparatus as in Synthesis Example 1 and dissolved by raising the temperature to 70 ° C. 34.6 parts of a 48% potassium hydroxide aqueous solution was added dropwise over 1 hour, and the reaction was further carried out at 75 ° C. for 4 hours. It was confirmed by gas chromatography that there was no residual chloromethylstyrene, and the solvent was recovered under reduced pressure. The obtained resin was dissolved in 320 parts of toluene and washed with 100 parts of water until the pH of the aqueous layer reached 7. Then, the solvent was distilled off under reduced pressure to obtain 196 parts of vinyl resin (V2) which is a toluene solution having a non-volatile content of 65%. The vinyl equivalent was 462 and the total chlorine was 1030 ppm.
  • V2 vinyl resin
  • Example 3 100 parts of the polyvalent hydroxy resin (P3), 230 parts of diethylene glycol dimethyl ether, and 71.7 parts of chloromethylstyrene were charged in the same apparatus as in Synthesis Example 1 and dissolved by raising the temperature to 70 ° C. 55.4 parts of a 48% potassium hydroxide aqueous solution was added dropwise over 1 hour, and the reaction was further carried out at 75 ° C. for 4 hours. It was confirmed by gas chromatography that there was no residual chloromethylstyrene, and the solvent was recovered under reduced pressure. The obtained resin was dissolved in 370 parts of toluene and washed with 100 parts of water until the pH of the aqueous layer reached 7. Then, the solvent was distilled off under reduced pressure to obtain 234 parts of vinyl resin (V3) which is a toluene solution having a non-volatile content of 65%. The vinyl equivalent was 334 and the total chlorine was 1230 ppm.
  • V3 vinyl resin
  • Comparative Example 1 118.6 parts of a polyvalent hydroxy resin (P4), 277.1 parts of diethylene glycol dimethyl ether, and 81.2 parts of chloromethylstyrene were charged in the same apparatus as in Synthesis Example 1, and the temperature was raised to 70 ° C. to dissolve them. 62.8 parts of a 48% potassium hydroxide aqueous solution was added dropwise over 1 hour, and the reaction was further carried out at 75 ° C. for 4 hours. It was confirmed by gas chromatography that there was no residual chloromethylstyrene, and the solvent was recovered under reduced pressure. The obtained resin was dissolved in 410 parts of toluene and washed with 100 parts of water until the pH of the aqueous layer reached 7.
  • HV1 vinyl resin
  • the vinyl equivalent was 331 and the total chlorine was 1680 ppm.
  • Comparative Example 2 95.0 parts of a polyvalent hydroxy resin (P5), 222 parts of diethylene glycol dimethyl ether, and 138.1 parts of chloromethylstyrene were charged in the same apparatus as in Synthesis Example 1 and dissolved by raising the temperature to 70 ° C. 106.8 parts of a 48% potassium hydroxide aqueous solution was added dropwise over 1 hour, and the reaction was further carried out at 75 ° C. for 4 hours. It was confirmed by gas chromatography that there was no residual chloromethylstyrene, and the solvent was recovered under reduced pressure. The obtained resin was dissolved in 500 parts of toluene and washed with 100 parts of water until the pH of the aqueous layer reached 7.
  • HV2 vinyl resin
  • the vinyl equivalent was 235 and the total chlorine was 1830 ppm.
  • Examples 4 to 7, Comparative Examples 3 to 5 The mixture was mixed at the blending ratios shown in Table 1 and dissolved in a solvent to obtain a uniform varnish.
  • the varnish was applied to a PET film, dried at 130 ° C. for 5 minutes, and peeled off from the PET film to obtain a resin composition.
  • the resin composition was sandwiched between mirror plates and cured under reduced pressure at 130 ° C. for 15 minutes and 210 ° C. for 80 minutes while applying a pressure of 2 MPa to obtain a cured product.
  • Table 1 shows the measurement results of the relative permittivity, dielectric loss tangent, thermal conductivity, and Tg of the obtained cured product.
  • the polyfunctional vinyl resin of the example showed excellent physical properties such as high glass transition temperature and thermal conductivity, low relative permittivity, and low dielectric loss tangent as compared with the comparative example.
  • the polyfunctional vinyl resin and composition of the present invention are excellent in dielectric and thermal conductivity, can be used for various applications such as lamination, molding, and adhesion, and are particularly useful as electronic materials for high-speed communication equipment.

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