WO2021193503A1 - Composition cosmétique - Google Patents

Composition cosmétique Download PDF

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Publication number
WO2021193503A1
WO2021193503A1 PCT/JP2021/011648 JP2021011648W WO2021193503A1 WO 2021193503 A1 WO2021193503 A1 WO 2021193503A1 JP 2021011648 W JP2021011648 W JP 2021011648W WO 2021193503 A1 WO2021193503 A1 WO 2021193503A1
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Prior art keywords
component
cosmetic composition
mass
oil
hair
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PCT/JP2021/011648
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English (en)
Japanese (ja)
Inventor
範子 藤田
佳那子 小林
イクバル ムハンマド
Original Assignee
株式会社マンダム
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Application filed by 株式会社マンダム filed Critical 株式会社マンダム
Priority to KR1020227027378A priority Critical patent/KR20220125319A/ko
Priority to CN202180013001.8A priority patent/CN115052577A/zh
Publication of WO2021193503A1 publication Critical patent/WO2021193503A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a cosmetic composition.
  • Cosmetic compositions such as hair treatments, body creams and face creams are used.
  • a composition containing a cationic surfactant and / or a higher alcohol is known as a hair cosmetic composition used by being applied to hair.
  • Japanese Unexamined Patent Publication No. 2004-509860 Japanese Unexamined Patent Publication No. 2010-013405 Japanese Unexamined Patent Publication No. 2007-001953
  • Cosmetic compositions as described in Patent Documents 1 to 3 form a cationic gel, which can enhance the adhesion of the composition to the application target.
  • a treatment hair cosmetic composition
  • the adhesion to the hair is increased, and the treatment effect is effectively exhibited.
  • a feeling of adhesion use in which the composition is felt to be sufficiently attached to the application target. It is desirable that the feeling) and the richness (feeling of use in which a high-concentration composition is applied) are high.
  • the conventional cosmetic composition In order to enhance the richness, it is effective to increase the blending amount of the cationic surfactant and / or the higher alcohol, but in the conventional cosmetic composition, when the blending amount of these components is increased to some extent or more, the compounding amount is said to be high.
  • the composition becomes too hard and tends to give a solid feel.
  • the conventional cosmetic composition when the composition becomes hard, the feeling of adhesion to the application target such as hair is reduced, and the actual feeling of the effect such as the treatment effect is lowered. Further, in this case, the coatability is also lowered.
  • An object of the present invention is to provide a cosmetic composition capable of enhancing the feeling of adhesion to an application target and the applicability while enhancing the richness.
  • the present invention provides a cosmetic composition containing the following component (A), the following component (B), the following component (C), the following component (D), and the following component (E).
  • Component (A) a compound represented by the following formula (1) R 1 -N + ( CH 3) 3 X - (1) (In the above formula (1), R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms, and X ⁇ represents Cl ⁇ or Br ⁇ .)
  • Component (B): Compound R 2 -C represented by the following formula (2) ( O) -NH -C 3 H 6 -N + (CH 3) 3 Z - (2) (In the above formula (2), R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms, and Z ⁇ represents Cl ⁇ or Br ⁇ .)
  • the cosmetic composition of the present invention preferably contains the following component (F).
  • Ingredient (F) An oily ingredient selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
  • the component (F) contains the silicone oil.
  • the silicone oil contains the following component (F1).
  • Component (F1) Silicone oil selected from the group consisting of silicone oil having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more and amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa ⁇ s.
  • the component (F) contains the ester oil and the ester oil contains the following component (F2).
  • the cosmetic composition of the present invention preferably contains the following component (G).
  • Component (G) Cationized cellulose having an alkyl group having 10 or more carbon atoms
  • the cosmetic composition of the present invention preferably contains the following component (H).
  • the content of the component (A) is preferably 0.5% by mass or more and 5.0% by mass or less.
  • the content of the component (D) is preferably 3.0% by mass or more and 20.0% by mass or less.
  • the cosmetic composition of the present invention is preferably a hair cosmetic composition.
  • the cosmetic composition of the present invention is applied to an object to be applied and then washed away before use.
  • the cosmetic composition of the present invention contains a specific component (A), a specific component (B), a specific component (C), a specific component (D), and a specific component (E). Therefore, it is possible to enhance the feeling of adhesion to the object to be coated and the applicability while enhancing the richness.
  • the cosmetic composition of the present invention has a compound represented by the following formula (1), a compound represented by the following formula (2), and polyglycerin having 2 to 6 fatty acids ester-bonded to each other. It contains a polyglycerin fatty acid ester having an average added molar number of glycerin of 4 to 12, an aliphatic alcohol having 12 to 24 carbon atoms, and water.
  • R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms
  • X ⁇ represents Cl ⁇ or Br ⁇ .
  • R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms, and Z ⁇ represents Cl ⁇ or Br ⁇ .
  • component (A) the above-mentioned “compound represented by the above formula (1)” may be referred to as “component (A)".
  • component (B) the above-mentioned “compound represented by the above formula (2)” may be referred to as “component (B)".
  • component (C) polyglycerin fatty acid ester in which 2 to 6 fatty acids are ester-bonded to polyglycerin and the average number of moles of glycerin added is 4 to 12
  • component (D) aliphatic alcohol having 12 to 24 carbon atoms
  • the cosmetic composition of the present invention has the above-mentioned structure, it is possible to enhance the feeling of adhesion to the application target and the applicability while enhancing the richness.
  • the reason why the cosmetic composition of the present invention can enhance the richness and adhesion at the time of application is that the component (A), the component (D) and the component (E) may be referred to as a cationic gel ( ⁇ gel). It is thought that this is due to the formation of).
  • the component (B) and the component (C) are blended in addition to the component (A), the component (D) and the component (E), the component (A) and the component (C) Even if the amount of the component (D) is increased to harden the cosmetic composition, it is possible to suppress a decrease in adhesion and coatability. Further, by blending the component (B) and the component (C), the viscoelasticity of the cosmetic composition changes, and although the cosmetic composition has a certain degree of hardness when left to stand, the cosmetic composition tends to stretch when applied. .. Therefore, it is possible to improve the applicability to the application target such as hair and the feeling of adhesion to the application target at the time of application. In the cosmetic composition of the present invention, the feeling of adhesion and the applicability can be enhanced while enhancing the richness, so that the feeling of use and the actual feeling of effect can be enhanced.
  • the cosmetic composition of the present invention may contain an oily component selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
  • oil-based component selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil may be referred to as “component (F)".
  • the cosmetic composition of the present invention may contain cationized cellulose having an alkyl group having 10 or more carbon atoms.
  • component (G) cationized cellulose having an alkyl group having 10 or more carbon atoms
  • the cosmetic composition of the present invention may contain polypropylene glycol alkyl ether.
  • polypropylene glycol alkyl ether may be referred to as “component (H)".
  • the cosmetic composition of the present invention contains at least the component (A), the component (B), the component (C), the component (D), and the component (E).
  • the cosmetic composition of the present invention may contain the component (F), may contain the component (G), or may contain the component (H).
  • the cosmetic composition of the present invention may contain ingredients other than the ingredients (A) to (H).
  • component (A), component (B), component (C), component (D), component (E), component (F), component (G), component (H) and other components Only one type may be used, or two or more types may be used.
  • the component (A) is a compound represented by the following formula (1).
  • Component (A) is a monoalkyl quaternary ammonium cationic surfactant.
  • the component (A) is a component for forming a cation gel.
  • a gel network is formed by the component (A), the component (D), and the component (E).
  • the cosmetic composition of the present invention contains the component (F)
  • droplets of the component (F) can stably exist due to the gel network, and the emulsion stability can be enhanced.
  • the component (A) only one kind may be used, or two or more kinds may be used in combination.
  • R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms.
  • the aliphatic hydrocarbon group preferably has 16 to 22 carbon atoms.
  • Examples of the aliphatic hydrocarbon group include an alkyl group, an alkenyl group, and an alkynyl group.
  • the R 1 is preferably a linear or branched alkyl group, and more preferably a linear alkyl group.
  • X ⁇ is a counter anion of a quaternary ammonium cation and represents Cl ⁇ or Br ⁇ .
  • Examples of the component (A) include stearyltrimethylammonium chloride (stealtrimonium chloride, INCI name: Steartrimonium Chloride), stearyltrimethylammonium bromide (stealtrimonium bromide), alkyltrimethylammonium chloride (behentrimonium chloride, INCI name). : Behentrimonium Chloride), cetyltrimethylammonium chloride (cetrimonium chloride), cetyltrimethylammonium bromide (cetrimonium bromide) and the like.
  • the content of the component (A) in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, still more preferably 2.0% by mass or more. It is preferably 5.0% by mass or less, more preferably 4.5% by mass or less, and further preferably 4.0% by mass or less.
  • the content of the component (A) is at least the above lower limit, the richness and adhesion at the time of application can be further enhanced.
  • the content of the component (A) is not more than the above upper limit, the cosmetic composition does not become too hard, and the coatability and the adhesive feeling can be further improved.
  • the content of the component (A) is the total content of all the components (A) in the cosmetic composition of the present invention.
  • the component (B) is a compound represented by the following formula (2).
  • the viscoelastic behavior of the cosmetic composition is changed by the component (B), and the stretchability at the time of application is improved.
  • the emulsifying power of the oily component for example, the component (F)
  • the component (B) can be enhanced by the component (B)
  • the emulsifying stability can be improved when the cosmetic composition of the present invention is an emulsified cosmetic composition. Can be enhanced.
  • the component (B) only one kind may be used, or two or more kinds may be used in combination.
  • R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms.
  • the aliphatic hydrocarbon group preferably has 13 to 21 carbon atoms.
  • Examples of the aliphatic hydrocarbon group include an alkyl group, an alkenyl group and an alkynyl group. From the viewpoint of further improving the coatability, the R 2 is preferably a linear or branched alkyl group, and more preferably a linear alkyl group.
  • Z ⁇ is a counter anion of a quaternary ammonium cation and represents Cl ⁇ or Br ⁇ .
  • component (B) examples include palmitamide propyltrimonium chloride (INCI name: Palmitamideplopyltrimonium Chloride) and the like.
  • component (B) examples include the trade name "VARISOFT PATC” (manufactured by Evonik Japan).
  • the content of the component (B) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.3% by mass or more. It is preferably 3.0% by mass or less, more preferably 2.5% by mass or less, and further preferably 2.0% by mass or less.
  • the stretchability at the time of application is further improved.
  • the amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to effectively suppress the deterioration of the adhesive feeling and the coatability.
  • the cosmetic composition of the present invention is an emulsified cosmetic composition
  • the emulsification stability can be further enhanced.
  • the content of the component (B) is not more than the above upper limit, the richness can be further enhanced.
  • the content of the above component (B) is the total content of all the components (B) in the cosmetic composition of the present invention.
  • the component (C) is a polyglycerin fatty acid ester in which 2 to 6 fatty acids are ester-bonded to polyglycerin and the average number of moles of glycerin added is 4 to 12.
  • the viscoelastic behavior of the cosmetic composition is changed by the component (C), and the stretchability at the time of application is improved.
  • the component (C) even if the blending amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to suppress a decrease in adhesion and coatability. Further, since the stability of the cation gel can be enhanced by the component (C), the stability (stability with time) of the cosmetic composition of the present invention can be enhanced.
  • the component (C) only one kind may be used, or two or more kinds may be used in combination.
  • the component (A) and the component (D) form a structure such as micelles and emulsion particles in the cosmetic composition. It is presumed that the effect of the component (B) and the component (C) is due to the loosening of the packing state of the molecular chains in the structure by incorporating the component (B) and the component (C) into the structure. However, it is not limited to this.
  • component (C) examples include polyglycerin di fatty acid ester, polyglycerin tri fatty acid ester, polyglycerin tetra fatty acid ester, polyglycerin penta fatty acid ester, and polyglycerin hexa fatty acid ester.
  • the component (C) is preferably a polyglycerin fatty acid ester (at least one polyglycerin fatty acid ester) selected from the group consisting of a polyglycerin difatty acid ester and a polyglycerin trifatty acid ester.
  • the average number of moles of glycerin added to the polyglycerin portion of the component (C) is preferably 5 to 10.
  • Examples of the fatty acid in the component (C) include linear or branched saturated or unsaturated fatty acids having 10 to 22 carbon atoms. The number of carbon atoms is preferably 12 to 18.
  • Examples of the fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, and oleic acid. The fatty acid is preferably stearic acid.
  • the component (C) includes polyglyceryl-10 diisostearate, polyglyceryl diisostearate-10, polyglyceryl dioleate-5, polyglyceryl dioleate-10, polyglyceryl dimyristate-10, polyglyceryl trilaurate-10, and the like.
  • examples thereof include polyglyceryl-5 trimyristate, polyglyceryl trioleate-5, polyglyceryl pentastearate-10, polyglyceryl pentaoleate-10, and polyglyceryl hexastearate-5.
  • the component (C) is polyglyceryl distearate-10, polyglyceryl diisostearate-10, polyglyceryl pentastearate-10, polyglyceryl trioleate-5, polyglyceryl trilaurate-10.
  • polyglycerin fatty acid ester selected from the group consisting of polyglyceryl dioleate-10 (at least one polyglycerin fatty acid ester), and more preferably polyglyceryl dystearate-10.
  • the content of the component (C) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.3% by mass or more. It is preferably 3.0% by mass or less, more preferably 2.5% by mass or less, and further preferably 2.0% by mass or less.
  • the content of the component (C) is at least the above lower limit, the stretchability at the time of coating is further improved.
  • the amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to effectively suppress the deterioration of the adhesive feeling and the coatability.
  • the stability of the cosmetic composition of the present invention can be enhanced.
  • the content of the component (C) is not more than the above upper limit, the richness can be further enhanced.
  • the content of the component (C) is the total content of all the components (C) in the cosmetic composition of the present invention.
  • the component (D) is an aliphatic alcohol having 12 to 24 carbon atoms.
  • the component (D) is a so-called higher alcohol.
  • the component (D) is a component for forming a cation gel.
  • a gel network is formed by the component (A), the component (D), and the component (E).
  • the cosmetic composition of the present invention contains the component (F)
  • the emulsion stability can be enhanced.
  • the component (D) only one kind may be used, or two or more kinds may be used in combination.
  • component (D) examples include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, isostearyl alcohol, hexyldecanol, 2-octyldodecanol, oleyl alcohol, decyltetradecanol, and behenyl alcohol.
  • the component (D) is preferably an aliphatic alcohol (at least one aliphatic alcohol) selected from the group consisting of stearyl alcohol, cetyl alcohol, and behenyl alcohol, and is preferably stearyl alcohol. More preferably.
  • the content of the component (D) in 100% by mass of the cosmetic composition of the present invention is preferably 3.0% by mass or more, more preferably 5.0% by mass or more, still more preferably 6.5% by mass or more. It is preferably 20.0% by mass or less, more preferably 15.0% by mass or less, still more preferably 13.0% by mass or less.
  • the content of the component (D) is at least the above lower limit, the richness and adhesion at the time of application can be further enhanced.
  • the content of the component (D) is not more than the above upper limit, the cosmetic composition does not become too hard, and the coatability and the adhesive feeling can be further improved.
  • the content of the above component (D) is the total content of all the components (D) in the cosmetic composition of the present invention.
  • the content of the component (A) is 2.0% by mass or more and the content of the component (D) is 6.5% by mass or more, the richness is particularly felt. Can be enhanced. Further, in this case, the effect of further enhancing the adhesive feeling and the coatability by using the component (B) and the component (C) in combination is particularly likely to be exhibited.
  • the component (E) is water.
  • the component (E) is preferably purified water.
  • the content of the component (E) in the cosmetic composition of the present invention can be appropriately adjusted according to the content of other components.
  • the content of the component (E) in 100% by mass of the cosmetic composition of the present invention is preferably 40.0% by mass or more, more preferably 45.0% by mass or more, preferably 85.0% by mass or less, and more. It is preferably 80.0% by mass or less.
  • the component (F) is an oily component (at least one oily component) selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
  • the cosmetic composition of the present invention preferably contains the component (F). By blending the component (F), an emulsified cosmetic composition can be obtained. Therefore, the cosmetic composition of the present invention is preferably an emulsified cosmetic composition.
  • the component (F) can satisfactorily impart a soft feeling (soft feeling), a silky feeling, and a cohesive feeling to the dried hair when the emulsified cosmetic composition is applied to the hair.
  • the component (F) only one kind may be used, or two or more kinds may be used in combination.
  • silicone oil examples include methylpolysiloxane (dimethicone) and dimethylsilicone oil such as highly polymerized methylpolysiloxane; methylphenylsilicone oil such as methylphenylpolysiloxane; methylcyclopolysiloxane, octamethylcyclotetrasiloxane, and decamethylcyclo.
  • Cyclic silicone oils such as pentasiloxane and dodecamethylcyclohexasiloxane; aminopropylmethylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, and aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer weight
  • Amino-modified silicones such as coalesces, carboxy-modified silicones, fatty acid-modified silicones, alcohol-modified silicones, aliphatic alcohol-modified silicones, epoxy-modified silicones, fluorine-modified silicones, alkyl-modified silicones, and other modified silicones; methylhydrogenpolysiloxane, dimethiconol, etc. Can be mentioned.
  • the silicone oil is a silicone oil selected from the group consisting of a silicone oil having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more and an amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa ⁇ s (at least one). Silicone oil) is preferably contained.
  • silicone oil selected from the group consisting of a silicone oil having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more and an amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa ⁇ s. May be described as "component (F1)".
  • component (F11) silicone oil having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more
  • component (F11) is a highly polymerized silicone.
  • component (F12) amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa ⁇ s
  • the silicone oil preferably contains the component (F1).
  • the silicone oil preferably contains a silicone oil selected from the group consisting of the component (F11) and the component (F12).
  • the component (F11) contains an amino-modified silicone having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more.
  • the cosmetic composition of the present invention contains the component (F11), it is possible to give the hair after drying a smooth feeling.
  • the cosmetic composition of the present invention contains the component (F12), it is possible to enhance the softness of the hair at the time of application and after drying.
  • the viscosity of the component (F11) at 25 ° C. is 10,000 mPa ⁇ s or more, preferably 60,000 mPa ⁇ s or more, more preferably 80,000 mPa ⁇ s or more, preferably 30 million mPa ⁇ s or less, more preferably. Is 1.5 million mPa ⁇ s or less, more preferably 1 million mPa ⁇ s or less.
  • the viscosity is at least the above lower limit and at least the above upper limit, it is possible to impart a smoother feeling to the dried hair even more satisfactorily.
  • ester oil examples include cetyl octanate, ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, 2-ethylhexyl palmitate, octyldodecyl myristate, isopropyl isostearate, and propylene glycol isostearate.
  • ester oil examples include dimer dilinoleic acid di (isostearyl / phytosteryl), dimer dilinoleic acid dimer dilinoleic acid, dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), and dimer dilinoleic acid. Hydrogenated castor oil and dimer acid esters such as diglycerin isostearate with dimer dilinoleic acid can also be mentioned. Further, examples of the ester oil include a hydrogenated rosin condensate of dimer linoleic acid and a dimer diol ester such as diima linoleyl diisostearic acid.
  • the ester oil preferably contains a dimer acid ester.
  • component (F2) dimeric acid ester
  • the ester oil preferably contains the component (F2).
  • the cosmetic composition of the present invention contains the component (F2), it is possible to impart a good cohesive feeling to the hair.
  • Examples of the vegetable oils include macadamia nut oil, eucalyptus oil, palm oil, avocado oil, saflower oil, olive oil, palm oil, palm kernel oil, kukui nut oil, shea butter, cacao butter, almond oil, and sunflower oil. , Rosehip oil, olive squalane, camellia oil, kiwi fruit seed oil, camellia oil, apricot oil, sesame oil, soybean oil, jojoba oil, castor oil, hazelnut oil, meadowfoam oil, peppermint oil, argan oil, carrot oil, lavender Examples include oil, sugar squalane, and cranbear bicinica seed oil.
  • hydrocarbon oil examples include ⁇ -olefin oligomers, light isoparaffin, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, liquid isoparaffin, and liquid paraffin.
  • the component (F) preferably contains the above-mentioned silicone oil, preferably contains the above-mentioned ester oil, and more preferably contains the above-mentioned silicone oil and the above-mentioned ester oil.
  • the component (F) preferably contains the component (F1), preferably contains the component (F2), and more preferably contains the component (F1) and the component (F2).
  • the content of the silicone oil in 100% by mass of the cosmetic composition of the present invention is preferably 1.0% by mass or more, more preferably 3. It is 0% by mass or more, preferably 30.0% by mass or less, and more preferably 20.0% by mass or less.
  • the content of the silicone oil is the sum of the contents of all the silicone oils in the cosmetic composition of the present invention.
  • the content of the component (F1) in 100% by mass of the cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.1% by mass or more. It is 0.5% by mass or more, preferably 10.0% by mass or less, and more preferably 5.0% by mass or less.
  • the content of the component (F1) is the total content of all the components (F1) in the cosmetic composition of the present invention.
  • the content of the above ester oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1. It is 0% by mass or more, preferably 20.0% by mass or less, and more preferably 10.0% by mass or less.
  • the content of the ester oil is the sum of the contents of all the ester oils in the cosmetic composition of the present invention.
  • the content of the component (F2) in 100% by mass of the cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.1% by mass or more. It is 0.2% by mass or more, preferably 10.0% by mass or less, and more preferably 5.0% by mass or less.
  • the content of the component (F2) is the total content of all the components (F2) in the cosmetic composition of the present invention.
  • the content of the vegetable oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.2% by mass. % Or more, preferably 10.0% by mass or less, more preferably 5.0% by mass or less.
  • the content of the vegetable oil is the sum of the contents of all the vegetable oils in the cosmetic composition of the present invention.
  • the content of the above-mentioned hydrocarbon oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 0.5% by mass or more. It is 1.0% by mass or more, preferably 10.0% by mass or less, and more preferably 7.0% by mass or less.
  • the content of the above hydrocarbon oil is the sum of the contents of all the hydrocarbon oils in the cosmetic composition of the present invention.
  • the content of the component (F) in 100% by mass of the cosmetic composition of the present invention is preferably 1.0% by mass or more, more preferably 5.0% by mass or more, preferably 35.0% by mass or less, and more. It is preferably 20.0% by mass or less.
  • the content of the above component (F) is the total content of all the components (F) in the cosmetic composition of the present invention.
  • the component (G) is a cationized cellulose having an alkyl group having 10 or more carbon atoms.
  • the component (G) can improve the cohesiveness of the hair at the time of application and after drying, and can enhance the softness of the hair at the time of rinsing and after drying. Further, by using the component (G) and the component (F) in combination, the blending effect of the component (F) can be further enhanced.
  • the component (G) only one kind may be used, or two or more kinds may be used in combination.
  • Examples of the component (G) include polyquaternium-67 and the like.
  • the number of carbon atoms of the alkyl group of the component (G) is preferably 24 or less, more preferably 22 or less.
  • the component (G) is preferably polyquaternium-67.
  • the polyquaternium-67 is a polymer of a quaternary ammonium salt obtained by adding a trimethylammonium-substituted epoxide and a lauryldimethylammonium-substituted epoxide to hydroxyethyl cellulose, and is a cationized hydroxyethyl cellulose derivative.
  • the content of the component (G) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, preferably 1.0% by mass or less, and more. It is preferably 0.7% by mass or less.
  • the content of the component (G) is at least the above lower limit and at least the above upper limit, the cohesiveness of the hair at the time of application and after drying can be further improved, and the finger passage during rinsing can be improved. , The softness of the hair after drying can be further enhanced.
  • the component (H) is polypropylene glycol alkyl ether (polyoxypropylene alkyl ether).
  • the component (H) is used in combination with the component (F), the above-mentioned effect exhibited by the component (F) is more effectively exhibited.
  • the component (H) only one kind may be used, or two or more kinds may be used in combination.
  • Examples of the component (H) include PPG-3 caprylyl ether and PPG-5 caprylyl ether.
  • the component (H) is preferably PPG-3 caprylyl ether. In this case, the above-mentioned effect exerted by the component (F) is more effectively exerted.
  • the content of the component (H) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, preferably 5.0% by mass or less, and more. It is preferably 3.0% by mass or less.
  • the content of the component (H) is at least the above lower limit and at least the above upper limit, the above-mentioned effect exerted by the component (F) is more effectively exerted.
  • the cosmetic composition of the present invention may contain components other than the above-mentioned components (A) to (H).
  • Other components include lower alcohols such as ethanol; polyhydric alcohols; oily components other than component (F); anionic surfactants, and cationic surfactants different from both components (A) and (B).
  • moisturizers bactericides
  • pearlizing agents anti-inflammatory agents such as glycyrrhizinic acid and its salts
  • refreshing agents such as menthol
  • phosphoric acid and its salts, citric acid and its salts, PH adjuster such as lactic acid and its salts, sodium hydroxide, triethanolamine
  • fragrance ultraviolet absorber
  • antioxidant metal ion sequestering agent (chelating agent)
  • film-forming polymer compound such as pyrivinylpyrrolidone; kaolin , Silica, talc and other powders; pigments; pigments; vitamins; amino acids; astringents; whitening agents; animal and plant extracts; acids; alkalis and the like.
  • the cosmetic composition of the present invention is preferably an emulsified cosmetic composition.
  • an oily component such as the component (F)
  • the cosmetic composition can be made into an emulsified cosmetic composition.
  • the emulsified cosmetic composition is preferably an oil-in-water (O / W) type emulsified cosmetic composition.
  • the cosmetic composition of the present invention may be a hair cosmetic composition or a skin cosmetic composition.
  • hair cosmetic composition include hair treatments and hair styling products.
  • skin cosmetic composition include body cream and face cream.
  • the cosmetic composition of the present invention is preferably a hair cosmetic composition, and is an emulsified hair cosmetic composition. Is more preferable.
  • the cosmetic composition of the present invention is applied to an object to be applied and then washed away before use.
  • the cosmetic composition of the present invention is more preferably a hair cosmetic composition that is applied to the hair and then washed away.
  • the cosmetic composition of the present invention is preferably a hair treatment.
  • a method for producing a cosmetic composition of the present invention a known method for producing a cosmetic composition can be adopted.
  • the method for producing the cosmetic composition of the present invention include a method of stirring and homogenizing each component with a paddle mixer or the like.
  • the main components used in the examples and comparative examples are as follows.
  • Behentrimonium chloride trade name "GENAMIN KDMP", manufactured by Clariant, dimethyltrimethylammonium behenated Stealtrimonium chloride: trade name "Cotamin 86W”, manufactured by Kao, dimethyltrimethylammonium stearate
  • Polyquaternium-10 Product name "Kachinal HC-200", manufactured by Toho Chemical Industry Co., Ltd.
  • a cosmetic composition (hair cosmetic composition) was prepared by blending the compounding ingredients shown in Tables 1 to 5 below (the compounding unit is mass%).
  • the blending amount in the table (blending amount in 100% by mass of the hair cosmetic composition) is shown as a net content (unit: mass%).
  • the obtained hair cosmetic composition was evaluated as follows. The evaluation results are shown in the table. The evaluation was carried out by five professional evaluators.
  • Hair bundles human hair, length 30 cm, weight 10 g
  • Hair bundles were immersed in lukewarm water at about 40 ° C. After lightly squeezing the hair bundle after immersion to remove water to some extent, 2 g of the obtained hair cosmetic composition was picked up and applied uniformly to the entire hair bundle. At that time, the coatability, adhesion, and richness were evaluated according to the following criteria.
  • Test Example 2 Softness of hair at the time of application
  • the central portion of the hair bundle was lightly grasped so as to fold in the longitudinal direction, and the softness of the hair bundle at that time was evaluated according to the following criteria.
  • the softness of the hair at the time of application is that the hair bundle is soaked in lukewarm water at about 40 ° C., and then the hair bundle is lightly squeezed to remove water to some extent. It was evaluated in comparison with (referred to as "hair bundle").
  • Test Example 3 A feeling of cohesiveness of hair after drying
  • the hair bundle evaluated in Test Example 2 was rinsed with running water (warm water at about 40 ° C.) for about 1 minute, and then dried with a dryer.
  • the hair bundle immediately after drying was visually observed and evaluated according to the following criteria.
  • Test Example 4 Smooth feeling of hair after drying After the evaluation in Test Example 3, the feel was confirmed by passing a finger from the upper part to the lower part of the hair bundle, and the evaluation was made according to the following criteria.
  • Test Example 5 Softness of hair after drying
  • the central portion of the hair bundle was lightly grasped so as to fold in the longitudinal direction, and the softness of the hair bundle at that time was evaluated according to the following criteria.
  • the softness of the dried hair was evaluated by comparing the unapplied hair bundle prepared in Test Example 2 with the hair bundle dried by a dryer (referred to as "uncoated dried hair bundle").
  • Body care mask (wash-out type body treatment) Behentrimonium chloride 1.5% by mass Palmitamid propyltrimonium chloride 0.3% by mass Polyglyceryl distearate-10 1.0% by mass Stearyl alcohol 10.0% by mass Shea butter 3.0% by mass Dimer dilinoleic acid Dimer dilinoleil 1.0% by mass Tri (caprylic acid / capric acid) glyceryl 5.0% by mass PPG-3 Caprylyl Ether 1.0% by mass Isononyl isononanoate 2.0% by mass Polyquaternium-67 0.3% by mass Glycerin 2.0% by mass Propylene glycol 0.5% by mass Citric acid (pH adjuster) Appropriate amount Purified water Total remaining amount 100% by mass

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Abstract

L'invention concerne une composition cosmétique qui peut être améliorée en termes de sensation d'adhérence et d'application chez un sujet, ainsi qu'en termes d'onctuosité.　La composition cosmétique selon la présente invention comprend un composé représenté par la formule (1) (composant A), un composé représenté par la formule (2) (composant B), un ester d'acide gras de polyglycérine dans lequel 2 à 6 acides gras sont liés par l'intermédiaire de liaisons ester à de la polyglycérine et le nombre moyen de moles de glycérine ajoutée varie de 4 à 12 (composant C), un alcool aliphatique comportant 12 à 24 atomes de carbone (composant D) et de l'eau (composant E).　R1-N+(CH3)3X- (1) (Dans la formule (1), R1 représente un groupe hydrocarboné aliphatique linéaire ou ramifié comportant 12 à 22 atomes de carbone et X- représente Cl- ou Br-.)　R2-C(=O)-NH-C3H6-N+(CH3)3Z- (2) (Dans la formule (2), R2 représente un groupe hydrocarboné aliphatique linéaire ou ramifié comportant 11 à 21 atomes de carbone et Z- représente Cl- ou Br-.)
PCT/JP2021/011648 2020-03-24 2021-03-22 Composition cosmétique WO2021193503A1 (fr)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002234824A (ja) * 2001-02-09 2002-08-23 Sakamoto Yakuhin Kogyo Co Ltd 透明ヘアトリートメント剤
JP2012056926A (ja) * 2010-09-13 2012-03-22 Toho Chem Ind Co Ltd 毛髪用組成物
JP2016013984A (ja) * 2014-07-02 2016-01-28 日本精化株式会社 毛髪化粧料

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2000274799A1 (en) * 2000-09-13 2002-03-26 The Procter And Gamble Company Concentrated conditioning composition
JP4883261B2 (ja) * 2005-06-27 2012-02-22 ライオン株式会社 毛髪化粧料
JP2010013405A (ja) * 2008-07-04 2010-01-21 Kracie Home Products Ltd 毛髪化粧料
EP2710997A4 (fr) * 2011-05-18 2015-01-21 Daicel Corp Composition d'huile pour produit cosmétique

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002234824A (ja) * 2001-02-09 2002-08-23 Sakamoto Yakuhin Kogyo Co Ltd 透明ヘアトリートメント剤
JP2012056926A (ja) * 2010-09-13 2012-03-22 Toho Chem Ind Co Ltd 毛髪用組成物
JP2016013984A (ja) * 2014-07-02 2016-01-28 日本精化株式会社 毛髪化粧料

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