WO2021193503A1 - Cosmetic composition - Google Patents

Cosmetic composition Download PDF

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Publication number
WO2021193503A1
WO2021193503A1 PCT/JP2021/011648 JP2021011648W WO2021193503A1 WO 2021193503 A1 WO2021193503 A1 WO 2021193503A1 JP 2021011648 W JP2021011648 W JP 2021011648W WO 2021193503 A1 WO2021193503 A1 WO 2021193503A1
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WO
WIPO (PCT)
Prior art keywords
component
cosmetic composition
mass
oil
hair
Prior art date
Application number
PCT/JP2021/011648
Other languages
French (fr)
Japanese (ja)
Inventor
範子 藤田
佳那子 小林
イクバル ムハンマド
Original Assignee
株式会社マンダム
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Publication date
Application filed by 株式会社マンダム filed Critical 株式会社マンダム
Priority to CN202180013001.8A priority Critical patent/CN115052577A/en
Priority to KR1020227027378A priority patent/KR20220125319A/en
Publication of WO2021193503A1 publication Critical patent/WO2021193503A1/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a cosmetic composition.
  • Cosmetic compositions such as hair treatments, body creams and face creams are used.
  • a composition containing a cationic surfactant and / or a higher alcohol is known as a hair cosmetic composition used by being applied to hair.
  • Japanese Unexamined Patent Publication No. 2004-509860 Japanese Unexamined Patent Publication No. 2010-013405 Japanese Unexamined Patent Publication No. 2007-001953
  • Cosmetic compositions as described in Patent Documents 1 to 3 form a cationic gel, which can enhance the adhesion of the composition to the application target.
  • a treatment hair cosmetic composition
  • the adhesion to the hair is increased, and the treatment effect is effectively exhibited.
  • a feeling of adhesion use in which the composition is felt to be sufficiently attached to the application target. It is desirable that the feeling) and the richness (feeling of use in which a high-concentration composition is applied) are high.
  • the conventional cosmetic composition In order to enhance the richness, it is effective to increase the blending amount of the cationic surfactant and / or the higher alcohol, but in the conventional cosmetic composition, when the blending amount of these components is increased to some extent or more, the compounding amount is said to be high.
  • the composition becomes too hard and tends to give a solid feel.
  • the conventional cosmetic composition when the composition becomes hard, the feeling of adhesion to the application target such as hair is reduced, and the actual feeling of the effect such as the treatment effect is lowered. Further, in this case, the coatability is also lowered.
  • An object of the present invention is to provide a cosmetic composition capable of enhancing the feeling of adhesion to an application target and the applicability while enhancing the richness.
  • the present invention provides a cosmetic composition containing the following component (A), the following component (B), the following component (C), the following component (D), and the following component (E).
  • Component (A) a compound represented by the following formula (1) R 1 -N + ( CH 3) 3 X - (1) (In the above formula (1), R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms, and X ⁇ represents Cl ⁇ or Br ⁇ .)
  • Component (B): Compound R 2 -C represented by the following formula (2) ( O) -NH -C 3 H 6 -N + (CH 3) 3 Z - (2) (In the above formula (2), R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms, and Z ⁇ represents Cl ⁇ or Br ⁇ .)
  • the cosmetic composition of the present invention preferably contains the following component (F).
  • Ingredient (F) An oily ingredient selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
  • the component (F) contains the silicone oil.
  • the silicone oil contains the following component (F1).
  • Component (F1) Silicone oil selected from the group consisting of silicone oil having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more and amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa ⁇ s.
  • the component (F) contains the ester oil and the ester oil contains the following component (F2).
  • the cosmetic composition of the present invention preferably contains the following component (G).
  • Component (G) Cationized cellulose having an alkyl group having 10 or more carbon atoms
  • the cosmetic composition of the present invention preferably contains the following component (H).
  • the content of the component (A) is preferably 0.5% by mass or more and 5.0% by mass or less.
  • the content of the component (D) is preferably 3.0% by mass or more and 20.0% by mass or less.
  • the cosmetic composition of the present invention is preferably a hair cosmetic composition.
  • the cosmetic composition of the present invention is applied to an object to be applied and then washed away before use.
  • the cosmetic composition of the present invention contains a specific component (A), a specific component (B), a specific component (C), a specific component (D), and a specific component (E). Therefore, it is possible to enhance the feeling of adhesion to the object to be coated and the applicability while enhancing the richness.
  • the cosmetic composition of the present invention has a compound represented by the following formula (1), a compound represented by the following formula (2), and polyglycerin having 2 to 6 fatty acids ester-bonded to each other. It contains a polyglycerin fatty acid ester having an average added molar number of glycerin of 4 to 12, an aliphatic alcohol having 12 to 24 carbon atoms, and water.
  • R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms
  • X ⁇ represents Cl ⁇ or Br ⁇ .
  • R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms, and Z ⁇ represents Cl ⁇ or Br ⁇ .
  • component (A) the above-mentioned “compound represented by the above formula (1)” may be referred to as “component (A)".
  • component (B) the above-mentioned “compound represented by the above formula (2)” may be referred to as “component (B)".
  • component (C) polyglycerin fatty acid ester in which 2 to 6 fatty acids are ester-bonded to polyglycerin and the average number of moles of glycerin added is 4 to 12
  • component (D) aliphatic alcohol having 12 to 24 carbon atoms
  • the cosmetic composition of the present invention has the above-mentioned structure, it is possible to enhance the feeling of adhesion to the application target and the applicability while enhancing the richness.
  • the reason why the cosmetic composition of the present invention can enhance the richness and adhesion at the time of application is that the component (A), the component (D) and the component (E) may be referred to as a cationic gel ( ⁇ gel). It is thought that this is due to the formation of).
  • the component (B) and the component (C) are blended in addition to the component (A), the component (D) and the component (E), the component (A) and the component (C) Even if the amount of the component (D) is increased to harden the cosmetic composition, it is possible to suppress a decrease in adhesion and coatability. Further, by blending the component (B) and the component (C), the viscoelasticity of the cosmetic composition changes, and although the cosmetic composition has a certain degree of hardness when left to stand, the cosmetic composition tends to stretch when applied. .. Therefore, it is possible to improve the applicability to the application target such as hair and the feeling of adhesion to the application target at the time of application. In the cosmetic composition of the present invention, the feeling of adhesion and the applicability can be enhanced while enhancing the richness, so that the feeling of use and the actual feeling of effect can be enhanced.
  • the cosmetic composition of the present invention may contain an oily component selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
  • oil-based component selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil may be referred to as “component (F)".
  • the cosmetic composition of the present invention may contain cationized cellulose having an alkyl group having 10 or more carbon atoms.
  • component (G) cationized cellulose having an alkyl group having 10 or more carbon atoms
  • the cosmetic composition of the present invention may contain polypropylene glycol alkyl ether.
  • polypropylene glycol alkyl ether may be referred to as “component (H)".
  • the cosmetic composition of the present invention contains at least the component (A), the component (B), the component (C), the component (D), and the component (E).
  • the cosmetic composition of the present invention may contain the component (F), may contain the component (G), or may contain the component (H).
  • the cosmetic composition of the present invention may contain ingredients other than the ingredients (A) to (H).
  • component (A), component (B), component (C), component (D), component (E), component (F), component (G), component (H) and other components Only one type may be used, or two or more types may be used.
  • the component (A) is a compound represented by the following formula (1).
  • Component (A) is a monoalkyl quaternary ammonium cationic surfactant.
  • the component (A) is a component for forming a cation gel.
  • a gel network is formed by the component (A), the component (D), and the component (E).
  • the cosmetic composition of the present invention contains the component (F)
  • droplets of the component (F) can stably exist due to the gel network, and the emulsion stability can be enhanced.
  • the component (A) only one kind may be used, or two or more kinds may be used in combination.
  • R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms.
  • the aliphatic hydrocarbon group preferably has 16 to 22 carbon atoms.
  • Examples of the aliphatic hydrocarbon group include an alkyl group, an alkenyl group, and an alkynyl group.
  • the R 1 is preferably a linear or branched alkyl group, and more preferably a linear alkyl group.
  • X ⁇ is a counter anion of a quaternary ammonium cation and represents Cl ⁇ or Br ⁇ .
  • Examples of the component (A) include stearyltrimethylammonium chloride (stealtrimonium chloride, INCI name: Steartrimonium Chloride), stearyltrimethylammonium bromide (stealtrimonium bromide), alkyltrimethylammonium chloride (behentrimonium chloride, INCI name). : Behentrimonium Chloride), cetyltrimethylammonium chloride (cetrimonium chloride), cetyltrimethylammonium bromide (cetrimonium bromide) and the like.
  • the content of the component (A) in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, still more preferably 2.0% by mass or more. It is preferably 5.0% by mass or less, more preferably 4.5% by mass or less, and further preferably 4.0% by mass or less.
  • the content of the component (A) is at least the above lower limit, the richness and adhesion at the time of application can be further enhanced.
  • the content of the component (A) is not more than the above upper limit, the cosmetic composition does not become too hard, and the coatability and the adhesive feeling can be further improved.
  • the content of the component (A) is the total content of all the components (A) in the cosmetic composition of the present invention.
  • the component (B) is a compound represented by the following formula (2).
  • the viscoelastic behavior of the cosmetic composition is changed by the component (B), and the stretchability at the time of application is improved.
  • the emulsifying power of the oily component for example, the component (F)
  • the component (B) can be enhanced by the component (B)
  • the emulsifying stability can be improved when the cosmetic composition of the present invention is an emulsified cosmetic composition. Can be enhanced.
  • the component (B) only one kind may be used, or two or more kinds may be used in combination.
  • R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms.
  • the aliphatic hydrocarbon group preferably has 13 to 21 carbon atoms.
  • Examples of the aliphatic hydrocarbon group include an alkyl group, an alkenyl group and an alkynyl group. From the viewpoint of further improving the coatability, the R 2 is preferably a linear or branched alkyl group, and more preferably a linear alkyl group.
  • Z ⁇ is a counter anion of a quaternary ammonium cation and represents Cl ⁇ or Br ⁇ .
  • component (B) examples include palmitamide propyltrimonium chloride (INCI name: Palmitamideplopyltrimonium Chloride) and the like.
  • component (B) examples include the trade name "VARISOFT PATC” (manufactured by Evonik Japan).
  • the content of the component (B) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.3% by mass or more. It is preferably 3.0% by mass or less, more preferably 2.5% by mass or less, and further preferably 2.0% by mass or less.
  • the stretchability at the time of application is further improved.
  • the amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to effectively suppress the deterioration of the adhesive feeling and the coatability.
  • the cosmetic composition of the present invention is an emulsified cosmetic composition
  • the emulsification stability can be further enhanced.
  • the content of the component (B) is not more than the above upper limit, the richness can be further enhanced.
  • the content of the above component (B) is the total content of all the components (B) in the cosmetic composition of the present invention.
  • the component (C) is a polyglycerin fatty acid ester in which 2 to 6 fatty acids are ester-bonded to polyglycerin and the average number of moles of glycerin added is 4 to 12.
  • the viscoelastic behavior of the cosmetic composition is changed by the component (C), and the stretchability at the time of application is improved.
  • the component (C) even if the blending amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to suppress a decrease in adhesion and coatability. Further, since the stability of the cation gel can be enhanced by the component (C), the stability (stability with time) of the cosmetic composition of the present invention can be enhanced.
  • the component (C) only one kind may be used, or two or more kinds may be used in combination.
  • the component (A) and the component (D) form a structure such as micelles and emulsion particles in the cosmetic composition. It is presumed that the effect of the component (B) and the component (C) is due to the loosening of the packing state of the molecular chains in the structure by incorporating the component (B) and the component (C) into the structure. However, it is not limited to this.
  • component (C) examples include polyglycerin di fatty acid ester, polyglycerin tri fatty acid ester, polyglycerin tetra fatty acid ester, polyglycerin penta fatty acid ester, and polyglycerin hexa fatty acid ester.
  • the component (C) is preferably a polyglycerin fatty acid ester (at least one polyglycerin fatty acid ester) selected from the group consisting of a polyglycerin difatty acid ester and a polyglycerin trifatty acid ester.
  • the average number of moles of glycerin added to the polyglycerin portion of the component (C) is preferably 5 to 10.
  • Examples of the fatty acid in the component (C) include linear or branched saturated or unsaturated fatty acids having 10 to 22 carbon atoms. The number of carbon atoms is preferably 12 to 18.
  • Examples of the fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, and oleic acid. The fatty acid is preferably stearic acid.
  • the component (C) includes polyglyceryl-10 diisostearate, polyglyceryl diisostearate-10, polyglyceryl dioleate-5, polyglyceryl dioleate-10, polyglyceryl dimyristate-10, polyglyceryl trilaurate-10, and the like.
  • examples thereof include polyglyceryl-5 trimyristate, polyglyceryl trioleate-5, polyglyceryl pentastearate-10, polyglyceryl pentaoleate-10, and polyglyceryl hexastearate-5.
  • the component (C) is polyglyceryl distearate-10, polyglyceryl diisostearate-10, polyglyceryl pentastearate-10, polyglyceryl trioleate-5, polyglyceryl trilaurate-10.
  • polyglycerin fatty acid ester selected from the group consisting of polyglyceryl dioleate-10 (at least one polyglycerin fatty acid ester), and more preferably polyglyceryl dystearate-10.
  • the content of the component (C) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.3% by mass or more. It is preferably 3.0% by mass or less, more preferably 2.5% by mass or less, and further preferably 2.0% by mass or less.
  • the content of the component (C) is at least the above lower limit, the stretchability at the time of coating is further improved.
  • the amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to effectively suppress the deterioration of the adhesive feeling and the coatability.
  • the stability of the cosmetic composition of the present invention can be enhanced.
  • the content of the component (C) is not more than the above upper limit, the richness can be further enhanced.
  • the content of the component (C) is the total content of all the components (C) in the cosmetic composition of the present invention.
  • the component (D) is an aliphatic alcohol having 12 to 24 carbon atoms.
  • the component (D) is a so-called higher alcohol.
  • the component (D) is a component for forming a cation gel.
  • a gel network is formed by the component (A), the component (D), and the component (E).
  • the cosmetic composition of the present invention contains the component (F)
  • the emulsion stability can be enhanced.
  • the component (D) only one kind may be used, or two or more kinds may be used in combination.
  • component (D) examples include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, isostearyl alcohol, hexyldecanol, 2-octyldodecanol, oleyl alcohol, decyltetradecanol, and behenyl alcohol.
  • the component (D) is preferably an aliphatic alcohol (at least one aliphatic alcohol) selected from the group consisting of stearyl alcohol, cetyl alcohol, and behenyl alcohol, and is preferably stearyl alcohol. More preferably.
  • the content of the component (D) in 100% by mass of the cosmetic composition of the present invention is preferably 3.0% by mass or more, more preferably 5.0% by mass or more, still more preferably 6.5% by mass or more. It is preferably 20.0% by mass or less, more preferably 15.0% by mass or less, still more preferably 13.0% by mass or less.
  • the content of the component (D) is at least the above lower limit, the richness and adhesion at the time of application can be further enhanced.
  • the content of the component (D) is not more than the above upper limit, the cosmetic composition does not become too hard, and the coatability and the adhesive feeling can be further improved.
  • the content of the above component (D) is the total content of all the components (D) in the cosmetic composition of the present invention.
  • the content of the component (A) is 2.0% by mass or more and the content of the component (D) is 6.5% by mass or more, the richness is particularly felt. Can be enhanced. Further, in this case, the effect of further enhancing the adhesive feeling and the coatability by using the component (B) and the component (C) in combination is particularly likely to be exhibited.
  • the component (E) is water.
  • the component (E) is preferably purified water.
  • the content of the component (E) in the cosmetic composition of the present invention can be appropriately adjusted according to the content of other components.
  • the content of the component (E) in 100% by mass of the cosmetic composition of the present invention is preferably 40.0% by mass or more, more preferably 45.0% by mass or more, preferably 85.0% by mass or less, and more. It is preferably 80.0% by mass or less.
  • the component (F) is an oily component (at least one oily component) selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
  • the cosmetic composition of the present invention preferably contains the component (F). By blending the component (F), an emulsified cosmetic composition can be obtained. Therefore, the cosmetic composition of the present invention is preferably an emulsified cosmetic composition.
  • the component (F) can satisfactorily impart a soft feeling (soft feeling), a silky feeling, and a cohesive feeling to the dried hair when the emulsified cosmetic composition is applied to the hair.
  • the component (F) only one kind may be used, or two or more kinds may be used in combination.
  • silicone oil examples include methylpolysiloxane (dimethicone) and dimethylsilicone oil such as highly polymerized methylpolysiloxane; methylphenylsilicone oil such as methylphenylpolysiloxane; methylcyclopolysiloxane, octamethylcyclotetrasiloxane, and decamethylcyclo.
  • Cyclic silicone oils such as pentasiloxane and dodecamethylcyclohexasiloxane; aminopropylmethylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, and aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer weight
  • Amino-modified silicones such as coalesces, carboxy-modified silicones, fatty acid-modified silicones, alcohol-modified silicones, aliphatic alcohol-modified silicones, epoxy-modified silicones, fluorine-modified silicones, alkyl-modified silicones, and other modified silicones; methylhydrogenpolysiloxane, dimethiconol, etc. Can be mentioned.
  • the silicone oil is a silicone oil selected from the group consisting of a silicone oil having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more and an amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa ⁇ s (at least one). Silicone oil) is preferably contained.
  • silicone oil selected from the group consisting of a silicone oil having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more and an amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa ⁇ s. May be described as "component (F1)".
  • component (F11) silicone oil having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more
  • component (F11) is a highly polymerized silicone.
  • component (F12) amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa ⁇ s
  • the silicone oil preferably contains the component (F1).
  • the silicone oil preferably contains a silicone oil selected from the group consisting of the component (F11) and the component (F12).
  • the component (F11) contains an amino-modified silicone having a viscosity at 25 ° C. of 10,000 mPa ⁇ s or more.
  • the cosmetic composition of the present invention contains the component (F11), it is possible to give the hair after drying a smooth feeling.
  • the cosmetic composition of the present invention contains the component (F12), it is possible to enhance the softness of the hair at the time of application and after drying.
  • the viscosity of the component (F11) at 25 ° C. is 10,000 mPa ⁇ s or more, preferably 60,000 mPa ⁇ s or more, more preferably 80,000 mPa ⁇ s or more, preferably 30 million mPa ⁇ s or less, more preferably. Is 1.5 million mPa ⁇ s or less, more preferably 1 million mPa ⁇ s or less.
  • the viscosity is at least the above lower limit and at least the above upper limit, it is possible to impart a smoother feeling to the dried hair even more satisfactorily.
  • ester oil examples include cetyl octanate, ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, 2-ethylhexyl palmitate, octyldodecyl myristate, isopropyl isostearate, and propylene glycol isostearate.
  • ester oil examples include dimer dilinoleic acid di (isostearyl / phytosteryl), dimer dilinoleic acid dimer dilinoleic acid, dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), and dimer dilinoleic acid. Hydrogenated castor oil and dimer acid esters such as diglycerin isostearate with dimer dilinoleic acid can also be mentioned. Further, examples of the ester oil include a hydrogenated rosin condensate of dimer linoleic acid and a dimer diol ester such as diima linoleyl diisostearic acid.
  • the ester oil preferably contains a dimer acid ester.
  • component (F2) dimeric acid ester
  • the ester oil preferably contains the component (F2).
  • the cosmetic composition of the present invention contains the component (F2), it is possible to impart a good cohesive feeling to the hair.
  • Examples of the vegetable oils include macadamia nut oil, eucalyptus oil, palm oil, avocado oil, saflower oil, olive oil, palm oil, palm kernel oil, kukui nut oil, shea butter, cacao butter, almond oil, and sunflower oil. , Rosehip oil, olive squalane, camellia oil, kiwi fruit seed oil, camellia oil, apricot oil, sesame oil, soybean oil, jojoba oil, castor oil, hazelnut oil, meadowfoam oil, peppermint oil, argan oil, carrot oil, lavender Examples include oil, sugar squalane, and cranbear bicinica seed oil.
  • hydrocarbon oil examples include ⁇ -olefin oligomers, light isoparaffin, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, liquid isoparaffin, and liquid paraffin.
  • the component (F) preferably contains the above-mentioned silicone oil, preferably contains the above-mentioned ester oil, and more preferably contains the above-mentioned silicone oil and the above-mentioned ester oil.
  • the component (F) preferably contains the component (F1), preferably contains the component (F2), and more preferably contains the component (F1) and the component (F2).
  • the content of the silicone oil in 100% by mass of the cosmetic composition of the present invention is preferably 1.0% by mass or more, more preferably 3. It is 0% by mass or more, preferably 30.0% by mass or less, and more preferably 20.0% by mass or less.
  • the content of the silicone oil is the sum of the contents of all the silicone oils in the cosmetic composition of the present invention.
  • the content of the component (F1) in 100% by mass of the cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.1% by mass or more. It is 0.5% by mass or more, preferably 10.0% by mass or less, and more preferably 5.0% by mass or less.
  • the content of the component (F1) is the total content of all the components (F1) in the cosmetic composition of the present invention.
  • the content of the above ester oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1. It is 0% by mass or more, preferably 20.0% by mass or less, and more preferably 10.0% by mass or less.
  • the content of the ester oil is the sum of the contents of all the ester oils in the cosmetic composition of the present invention.
  • the content of the component (F2) in 100% by mass of the cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.1% by mass or more. It is 0.2% by mass or more, preferably 10.0% by mass or less, and more preferably 5.0% by mass or less.
  • the content of the component (F2) is the total content of all the components (F2) in the cosmetic composition of the present invention.
  • the content of the vegetable oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.2% by mass. % Or more, preferably 10.0% by mass or less, more preferably 5.0% by mass or less.
  • the content of the vegetable oil is the sum of the contents of all the vegetable oils in the cosmetic composition of the present invention.
  • the content of the above-mentioned hydrocarbon oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 0.5% by mass or more. It is 1.0% by mass or more, preferably 10.0% by mass or less, and more preferably 7.0% by mass or less.
  • the content of the above hydrocarbon oil is the sum of the contents of all the hydrocarbon oils in the cosmetic composition of the present invention.
  • the content of the component (F) in 100% by mass of the cosmetic composition of the present invention is preferably 1.0% by mass or more, more preferably 5.0% by mass or more, preferably 35.0% by mass or less, and more. It is preferably 20.0% by mass or less.
  • the content of the above component (F) is the total content of all the components (F) in the cosmetic composition of the present invention.
  • the component (G) is a cationized cellulose having an alkyl group having 10 or more carbon atoms.
  • the component (G) can improve the cohesiveness of the hair at the time of application and after drying, and can enhance the softness of the hair at the time of rinsing and after drying. Further, by using the component (G) and the component (F) in combination, the blending effect of the component (F) can be further enhanced.
  • the component (G) only one kind may be used, or two or more kinds may be used in combination.
  • Examples of the component (G) include polyquaternium-67 and the like.
  • the number of carbon atoms of the alkyl group of the component (G) is preferably 24 or less, more preferably 22 or less.
  • the component (G) is preferably polyquaternium-67.
  • the polyquaternium-67 is a polymer of a quaternary ammonium salt obtained by adding a trimethylammonium-substituted epoxide and a lauryldimethylammonium-substituted epoxide to hydroxyethyl cellulose, and is a cationized hydroxyethyl cellulose derivative.
  • the content of the component (G) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, preferably 1.0% by mass or less, and more. It is preferably 0.7% by mass or less.
  • the content of the component (G) is at least the above lower limit and at least the above upper limit, the cohesiveness of the hair at the time of application and after drying can be further improved, and the finger passage during rinsing can be improved. , The softness of the hair after drying can be further enhanced.
  • the component (H) is polypropylene glycol alkyl ether (polyoxypropylene alkyl ether).
  • the component (H) is used in combination with the component (F), the above-mentioned effect exhibited by the component (F) is more effectively exhibited.
  • the component (H) only one kind may be used, or two or more kinds may be used in combination.
  • Examples of the component (H) include PPG-3 caprylyl ether and PPG-5 caprylyl ether.
  • the component (H) is preferably PPG-3 caprylyl ether. In this case, the above-mentioned effect exerted by the component (F) is more effectively exerted.
  • the content of the component (H) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, preferably 5.0% by mass or less, and more. It is preferably 3.0% by mass or less.
  • the content of the component (H) is at least the above lower limit and at least the above upper limit, the above-mentioned effect exerted by the component (F) is more effectively exerted.
  • the cosmetic composition of the present invention may contain components other than the above-mentioned components (A) to (H).
  • Other components include lower alcohols such as ethanol; polyhydric alcohols; oily components other than component (F); anionic surfactants, and cationic surfactants different from both components (A) and (B).
  • moisturizers bactericides
  • pearlizing agents anti-inflammatory agents such as glycyrrhizinic acid and its salts
  • refreshing agents such as menthol
  • phosphoric acid and its salts, citric acid and its salts, PH adjuster such as lactic acid and its salts, sodium hydroxide, triethanolamine
  • fragrance ultraviolet absorber
  • antioxidant metal ion sequestering agent (chelating agent)
  • film-forming polymer compound such as pyrivinylpyrrolidone; kaolin , Silica, talc and other powders; pigments; pigments; vitamins; amino acids; astringents; whitening agents; animal and plant extracts; acids; alkalis and the like.
  • the cosmetic composition of the present invention is preferably an emulsified cosmetic composition.
  • an oily component such as the component (F)
  • the cosmetic composition can be made into an emulsified cosmetic composition.
  • the emulsified cosmetic composition is preferably an oil-in-water (O / W) type emulsified cosmetic composition.
  • the cosmetic composition of the present invention may be a hair cosmetic composition or a skin cosmetic composition.
  • hair cosmetic composition include hair treatments and hair styling products.
  • skin cosmetic composition include body cream and face cream.
  • the cosmetic composition of the present invention is preferably a hair cosmetic composition, and is an emulsified hair cosmetic composition. Is more preferable.
  • the cosmetic composition of the present invention is applied to an object to be applied and then washed away before use.
  • the cosmetic composition of the present invention is more preferably a hair cosmetic composition that is applied to the hair and then washed away.
  • the cosmetic composition of the present invention is preferably a hair treatment.
  • a method for producing a cosmetic composition of the present invention a known method for producing a cosmetic composition can be adopted.
  • the method for producing the cosmetic composition of the present invention include a method of stirring and homogenizing each component with a paddle mixer or the like.
  • the main components used in the examples and comparative examples are as follows.
  • Behentrimonium chloride trade name "GENAMIN KDMP", manufactured by Clariant, dimethyltrimethylammonium behenated Stealtrimonium chloride: trade name "Cotamin 86W”, manufactured by Kao, dimethyltrimethylammonium stearate
  • Polyquaternium-10 Product name "Kachinal HC-200", manufactured by Toho Chemical Industry Co., Ltd.
  • a cosmetic composition (hair cosmetic composition) was prepared by blending the compounding ingredients shown in Tables 1 to 5 below (the compounding unit is mass%).
  • the blending amount in the table (blending amount in 100% by mass of the hair cosmetic composition) is shown as a net content (unit: mass%).
  • the obtained hair cosmetic composition was evaluated as follows. The evaluation results are shown in the table. The evaluation was carried out by five professional evaluators.
  • Hair bundles human hair, length 30 cm, weight 10 g
  • Hair bundles were immersed in lukewarm water at about 40 ° C. After lightly squeezing the hair bundle after immersion to remove water to some extent, 2 g of the obtained hair cosmetic composition was picked up and applied uniformly to the entire hair bundle. At that time, the coatability, adhesion, and richness were evaluated according to the following criteria.
  • Test Example 2 Softness of hair at the time of application
  • the central portion of the hair bundle was lightly grasped so as to fold in the longitudinal direction, and the softness of the hair bundle at that time was evaluated according to the following criteria.
  • the softness of the hair at the time of application is that the hair bundle is soaked in lukewarm water at about 40 ° C., and then the hair bundle is lightly squeezed to remove water to some extent. It was evaluated in comparison with (referred to as "hair bundle").
  • Test Example 3 A feeling of cohesiveness of hair after drying
  • the hair bundle evaluated in Test Example 2 was rinsed with running water (warm water at about 40 ° C.) for about 1 minute, and then dried with a dryer.
  • the hair bundle immediately after drying was visually observed and evaluated according to the following criteria.
  • Test Example 4 Smooth feeling of hair after drying After the evaluation in Test Example 3, the feel was confirmed by passing a finger from the upper part to the lower part of the hair bundle, and the evaluation was made according to the following criteria.
  • Test Example 5 Softness of hair after drying
  • the central portion of the hair bundle was lightly grasped so as to fold in the longitudinal direction, and the softness of the hair bundle at that time was evaluated according to the following criteria.
  • the softness of the dried hair was evaluated by comparing the unapplied hair bundle prepared in Test Example 2 with the hair bundle dried by a dryer (referred to as "uncoated dried hair bundle").
  • Body care mask (wash-out type body treatment) Behentrimonium chloride 1.5% by mass Palmitamid propyltrimonium chloride 0.3% by mass Polyglyceryl distearate-10 1.0% by mass Stearyl alcohol 10.0% by mass Shea butter 3.0% by mass Dimer dilinoleic acid Dimer dilinoleil 1.0% by mass Tri (caprylic acid / capric acid) glyceryl 5.0% by mass PPG-3 Caprylyl Ether 1.0% by mass Isononyl isononanoate 2.0% by mass Polyquaternium-67 0.3% by mass Glycerin 2.0% by mass Propylene glycol 0.5% by mass Citric acid (pH adjuster) Appropriate amount Purified water Total remaining amount 100% by mass

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Abstract

Provided is a cosmetic composition which can be improved in the feeling of adhesion and applicability to a subject while also improving the richness thereof.　The cosmetic composition according to the present invention comprises a compound represented by formula (1) (a component A), a compound represented by formula (2) (a component B), a polyglycerin fatty acid ester in which 2 to 6 fatty acids are bonded via ester bonds to polyglycerin and the average number of moles of glycerin added is 4 to 12 (a component C), an aliphatic alcohol having 12 to 24 carbon atoms (a component D) and water (a component E).　R1-N+(CH3)3X- (1) (In formula (1), R1 represents a linear or branched aliphatic hydrocarbon group having 12 to 22 carbon atoms, and X- represents Cl- or Br-).　R2-C(=O)-NH-C3H6-N+(CH3)3Z- (2) (In formula (2), R2 represents a linear or branched aliphatic hydrocarbon group having 11 to 21 carbon atoms, and Z- represents Cl- or Br-.)

Description

化粧料組成物Cosmetic composition
　本発明は、化粧料組成物に関する。 The present invention relates to a cosmetic composition.
　ヘアトリートメント、ボディクリーム及びフェイスクリーム等の化粧料組成物が用いられている。例えば、下記の特許文献１～３に示されているように、毛髪に塗布して用いられる毛髪化粧料組成物として、カチオン界面活性剤及び／又は高級アルコールを含む組成物が知られている。 Cosmetic compositions such as hair treatments, body creams and face creams are used. For example, as shown in Patent Documents 1 to 3 below, a composition containing a cationic surfactant and / or a higher alcohol is known as a hair cosmetic composition used by being applied to hair.
特開２００４－５０９８６０号公報Japanese Unexamined Patent Publication No. 2004-509860 特開２０１０－０１３４０５号公報Japanese Unexamined Patent Publication No. 2010-013405 特開２００７－００１９５３号公報Japanese Unexamined Patent Publication No. 2007-001953
　特許文献１～３に記載のような化粧料組成物はカチオンゲルを形成しており、これにより、塗布対象への該組成物の付着性を高めることができる。例えば、トリートメント（毛髪化粧料組成物）では、毛髪への付着性が高くなり、トリートメント効果が効果的に発揮される。また、トリートメント効果が感じられるなどの効果実感を高めるためには、組成物を毛髪などの塗布対象に塗布する際に、付着感（組成物が塗布対象に十分に付着していると感じられる使用感）やコク感（濃度の高い組成物を塗布していると感じられる使用感）が高いことが望ましい。 Cosmetic compositions as described in Patent Documents 1 to 3 form a cationic gel, which can enhance the adhesion of the composition to the application target. For example, in a treatment (hair cosmetic composition), the adhesion to the hair is increased, and the treatment effect is effectively exhibited. In addition, in order to enhance the actual feeling of the effect such as the treatment effect, when the composition is applied to an application target such as hair, a feeling of adhesion (use in which the composition is felt to be sufficiently attached to the application target). It is desirable that the feeling) and the richness (feeling of use in which a high-concentration composition is applied) are high.
　しかしながら、従来の化粧料組成物では、コク感を十分に高めることは困難である。 However, it is difficult to sufficiently enhance the richness with the conventional cosmetic composition.
　コク感を高めるためには、カチオン界面活性剤及び／又は高級アルコールの配合量を増やすことが効果的であるものの、従来の化粧料組成物では、これらの成分の配合量がある程度以上多くなると該組成物が固くなり過ぎて固形の感触が生じやすい。従来の化粧料組成物では、該組成物が固くなった場合に、毛髪などの塗布対象への付着感が低下して、トリートメント効果が感じられるなどの効果実感が低下する。さらに、この場合には、塗布性も低下する。 In order to enhance the richness, it is effective to increase the blending amount of the cationic surfactant and / or the higher alcohol, but in the conventional cosmetic composition, when the blending amount of these components is increased to some extent or more, the compounding amount is said to be high. The composition becomes too hard and tends to give a solid feel. In the conventional cosmetic composition, when the composition becomes hard, the feeling of adhesion to the application target such as hair is reduced, and the actual feeling of the effect such as the treatment effect is lowered. Further, in this case, the coatability is also lowered.
　本発明の目的は、コク感を高めながら、塗布対象への付着感及び塗布性を高めることができる化粧料組成物を提供することである。 An object of the present invention is to provide a cosmetic composition capable of enhancing the feeling of adhesion to an application target and the applicability while enhancing the richness.
　本発明は、下記成分（Ａ）と、下記成分（Ｂ）と、下記成分（Ｃ）と、下記成分（Ｄ）と、下記成分（Ｅ）とを含む、化粧料組成物を提供する。 The present invention provides a cosmetic composition containing the following component (A), the following component (B), the following component (C), the following component (D), and the following component (E).
　成分（Ａ）：下記式（１）で表される化合物
　　Ｒ１－Ｎ＋（ＣＨ３）３Ｘ－　　　（１）
　（前記式（１）中、Ｒ１は、直鎖状又は分岐鎖状の炭素数１２～２２の脂肪族炭化水素基を表し、Ｘ－は、Ｃｌ－又はＢｒ－を表す。） Component (A): a compound represented by the following formula (1) R 1 -N + ( CH 3) 3 X - (1)
(In the above formula (1), R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms, and X − represents Cl − or Br − .)
　成分（Ｂ）：下記式（２）で表される化合物
　　Ｒ２－Ｃ（＝Ｏ）－ＮＨ－Ｃ３Ｈ６－Ｎ＋（ＣＨ３）３Ｚ－　　　（２）
　（前記式（２）中、Ｒ２は、直鎖状又は分岐鎖状の炭素数１１～２１の脂肪族炭化水素基を表し、Ｚ－は、Ｃｌ－又はＢｒ－を表す。） Component (B): Compound R 2 -C represented by the following formula (2) (= O) -NH -C 3 H 6 -N + (CH 3) 3 Z - (2)
(In the above formula (2), R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms, and Z − represents Cl − or Br − .)
　成分（Ｃ）：ポリグリセリンに２～６個の脂肪酸がエステル結合しており、かつグリセリンの平均付加モル数が４～１２であるポリグリセリン脂肪酸エステル Component (C): Polyglycerin fatty acid ester in which 2 to 6 fatty acids are ester-bonded to polyglycerin and the average number of moles of glycerin added is 4 to 12.
　成分（Ｄ）：炭素数１２～２４の脂肪族アルコール Ingredient (D): Aliphatic alcohol with 12 to 24 carbon atoms
　成分（Ｅ）：水 Ingredient (E): water
　本発明の化粧料組成物は、下記成分（Ｆ）を含むことが好ましい。 The cosmetic composition of the present invention preferably contains the following component (F).
　成分（Ｆ）：シリコーン油、エステル油、植物油、及び炭化水素油からなる群より選ばれる油性成分 Ingredient (F): An oily ingredient selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
　本発明の化粧料組成物では、前記成分（Ｆ）が、前記シリコーン油を含むことが好ましい。 In the cosmetic composition of the present invention, it is preferable that the component (F) contains the silicone oil.
　本発明の化粧料組成物では、前記シリコーン油が、下記成分（Ｆ１）を含むことが好ましい。 In the cosmetic composition of the present invention, it is preferable that the silicone oil contains the following component (F1).
　成分（Ｆ１）：２５℃における粘度が１万ｍＰａ・ｓ以上であるシリコーン油、及び２５℃における粘度が１万ｍＰａ・ｓ未満であるアミノ変性シリコーンからなる群より選ばれるシリコーン油 Component (F1): Silicone oil selected from the group consisting of silicone oil having a viscosity at 25 ° C. of 10,000 mPa · s or more and amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa · s.
　本発明の化粧料組成物では、前記成分（Ｆ）が、前記エステル油を含み、前記エステル油が、下記成分（Ｆ２）を含むことが好ましい。 In the cosmetic composition of the present invention, it is preferable that the component (F) contains the ester oil and the ester oil contains the following component (F2).
　成分（Ｆ２）：ダイマー酸エステル Ingredient (F2): Dimer acid ester
　本発明の化粧料組成物は、下記成分（Ｇ）を含むことが好ましい。 The cosmetic composition of the present invention preferably contains the following component (G).
　成分（Ｇ）：炭素数１０以上のアルキル基を有するカチオン化セルロース Component (G): Cationized cellulose having an alkyl group having 10 or more carbon atoms
　本発明の化粧料組成物は、下記成分（Ｈ）を含むことが好ましい。 The cosmetic composition of the present invention preferably contains the following component (H).
　成分（Ｈ）：ポリプロピレングリコールアルキルエーテル Component (H): Polypropylene glycol alkyl ether
　本発明の化粧料組成物では、前記成分（Ａ）の含有量が、０．５質量％以上、５．０質量％以下であることが好ましい。 In the cosmetic composition of the present invention, the content of the component (A) is preferably 0.5% by mass or more and 5.0% by mass or less.
　本発明の化粧料組成物では、前記成分（Ｄ）の含有量が、３．０質量％以上、２０．０質量％以下であることが好ましい。 In the cosmetic composition of the present invention, the content of the component (D) is preferably 3.0% by mass or more and 20.0% by mass or less.
　本発明の化粧料組成物は、毛髪化粧料組成物であることが好ましい。 The cosmetic composition of the present invention is preferably a hair cosmetic composition.
　本発明の化粧料組成物は、塗布対象に塗布された後、洗い流して用いられることが好ましい。 It is preferable that the cosmetic composition of the present invention is applied to an object to be applied and then washed away before use.
　本発明の化粧料組成物は、特定の成分（Ａ）と、特定の成分（Ｂ）と、特定の成分（Ｃ）と、特定の成分（Ｄ）と、特定の成分（Ｅ）とを含むので、コク感を高めながら、塗布対象への付着感及び塗布性を高めることができる。 The cosmetic composition of the present invention contains a specific component (A), a specific component (B), a specific component (C), a specific component (D), and a specific component (E). Therefore, it is possible to enhance the feeling of adhesion to the object to be coated and the applicability while enhancing the richness.
　以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
　本発明の化粧料組成物は、下記式（１）で表される化合物と、下記式（２）で表される化合物と、ポリグリセリンに２～６個の脂肪酸がエステル結合しており、かつグリセリンの平均付加モル数が４～１２であるポリグリセリン脂肪酸エステルと、炭素数１２～２４の脂肪族アルコールと、水とを含む。 The cosmetic composition of the present invention has a compound represented by the following formula (1), a compound represented by the following formula (2), and polyglycerin having 2 to 6 fatty acids ester-bonded to each other. It contains a polyglycerin fatty acid ester having an average added molar number of glycerin of 4 to 12, an aliphatic alcohol having 12 to 24 carbon atoms, and water.
　　Ｒ１－Ｎ＋（ＣＨ３）３Ｘ－　　　（１）
　（上記式（１）中、Ｒ１は、直鎖状又は分岐鎖状の炭素数１２～２２の脂肪族炭化水素基を表し、Ｘ－は、Ｃｌ－又はＢｒ－を表す。） R 1 -N + (CH 3) 3 X - (1)
(In the above formula (1), R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms, and X − represents Cl − or Br − .)
　　Ｒ２－Ｃ（＝Ｏ）－ＮＨ－Ｃ３Ｈ６－Ｎ＋（ＣＨ３）３Ｚ－　　　（２）
　（上記式（２）中、Ｒ２は、直鎖状又は分岐鎖状の炭素数１１～２１の脂肪族炭化水素基を表し、Ｚ－は、Ｃｌ－又はＢｒ－を表す。） R 2 -C (= O) -NH -C 3 H 6 -N + (CH 3) 3 Z - (2)
(In the above formula (2), R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms, and Z − represents Cl − or Br − .)
　本明細書においては、上記「上記式（１）で表される化合物」を「成分（Ａ）」と記載することがある。 In the present specification, the above-mentioned "compound represented by the above formula (1)" may be referred to as "component (A)".
　本明細書においては、上記「上記式（２）で表される化合物」を「成分（Ｂ）」と記載することがある。 In the present specification, the above-mentioned "compound represented by the above formula (2)" may be referred to as "component (B)".
　本明細書においては、上記「ポリグリセリンに２～６個の脂肪酸がエステル結合しており、かつグリセリンの平均付加モル数が４～１２であるポリグリセリン脂肪酸エステル」を「成分（Ｃ）」と記載することがある。 In the present specification, the above-mentioned "polyglycerin fatty acid ester in which 2 to 6 fatty acids are ester-bonded to polyglycerin and the average number of moles of glycerin added is 4 to 12" is referred to as "component (C)". May be described.
　本明細書においては、上記「炭素数１２～２４の脂肪族アルコール」を「成分（Ｄ）」と記載することがある。 In the present specification, the above-mentioned "aliphatic alcohol having 12 to 24 carbon atoms" may be referred to as "component (D)".
　本明細書においては、上記「水」を「成分（Ｅ）」と記載することがある。 In this specification, the above "water" may be referred to as "ingredient (E)".
　本発明の化粧料組成物では、上記の構成が備えられているので、コク感を高めながら、塗布対象への付着感及び塗布性を高めることができる。本発明の化粧料組成物が塗布時のコク感及び付着感を高めることができる理由は、成分（Ａ）、成分（Ｄ）及び成分（Ｅ）により、カチオンゲル（αゲルと称されることもある）が形成されることによるものと考えられる。また、本発明の化粧料組成物では、成分（Ａ）、成分（Ｄ）及び成分（Ｅ）に加えて、成分（Ｂ）及び成分（Ｃ）が配合されているので、成分（Ａ）や成分（Ｄ）の配合量を多くして化粧料組成物が固くなったとしても、付着感及び塗布性の低下を抑制できる。また、成分（Ｂ）及び成分（Ｃ）を配合することにより、化粧料組成物の粘弾性が変化し、静置時にはある程度の固さを有するものの、塗布時には該化粧料組成物が伸びやすくなる。そのため、毛髪などの塗布対象への塗布性及び塗布時の塗布対象への付着感を高めることができる。本発明の化粧料組成物では、コク感を高めながら、付着感及び塗布性を高めることができるので、使用感及び効果実感を高めることができる。 Since the cosmetic composition of the present invention has the above-mentioned structure, it is possible to enhance the feeling of adhesion to the application target and the applicability while enhancing the richness. The reason why the cosmetic composition of the present invention can enhance the richness and adhesion at the time of application is that the component (A), the component (D) and the component (E) may be referred to as a cationic gel (α gel). It is thought that this is due to the formation of). Further, in the cosmetic composition of the present invention, since the component (B) and the component (C) are blended in addition to the component (A), the component (D) and the component (E), the component (A) and the component (C) Even if the amount of the component (D) is increased to harden the cosmetic composition, it is possible to suppress a decrease in adhesion and coatability. Further, by blending the component (B) and the component (C), the viscoelasticity of the cosmetic composition changes, and although the cosmetic composition has a certain degree of hardness when left to stand, the cosmetic composition tends to stretch when applied. .. Therefore, it is possible to improve the applicability to the application target such as hair and the feeling of adhesion to the application target at the time of application. In the cosmetic composition of the present invention, the feeling of adhesion and the applicability can be enhanced while enhancing the richness, so that the feeling of use and the actual feeling of effect can be enhanced.
　本発明の化粧料組成物は、シリコーン油、エステル油、植物油、及び炭化水素油からなる群より選ばれる油性成分を含んでいてもよい。 The cosmetic composition of the present invention may contain an oily component selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
　本明細書においては、上記「シリコーン油、エステル油、植物油、及び炭化水素油からなる群より選ばれる油性成分」を「成分（Ｆ）」と称する場合がある。 In the present specification, the above-mentioned "oil-based component selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil" may be referred to as "component (F)".
　本発明の化粧料組成物は、炭素数１０以上のアルキル基を有するカチオン化セルロースを含んでいてもよい。 The cosmetic composition of the present invention may contain cationized cellulose having an alkyl group having 10 or more carbon atoms.
　本明細書においては、上記「炭素数１０以上のアルキル基を有するカチオン化セルロース」を「成分（Ｇ）」と称する場合がある。 In the present specification, the above-mentioned "cationized cellulose having an alkyl group having 10 or more carbon atoms" may be referred to as "component (G)".
　本発明の化粧料組成物は、ポリプロピレングリコールアルキルエーテルを含んでいてもよい。 The cosmetic composition of the present invention may contain polypropylene glycol alkyl ether.
　本明細書においては、上記「ポリプロピレングリコールアルキルエーテル」を「成分（Ｈ）」と称する場合がある。 In the present specification, the above "polypropylene glycol alkyl ether" may be referred to as "component (H)".
　上記のように、本発明の化粧料組成物は、成分（Ａ）と成分（Ｂ）と成分（Ｃ）と成分（Ｄ）と成分（Ｅ）とを少なくとも含む。本発明の化粧料組成物は、成分（Ｆ）を含んでいてもよく、成分（Ｇ）を含んでいてもよく、成分（Ｈ）を含んでいてもよい。また、本発明の化粧料組成物は、成分（Ａ）～（Ｈ）以外の他の成分を含んでいてもよい。 As described above, the cosmetic composition of the present invention contains at least the component (A), the component (B), the component (C), the component (D), and the component (E). The cosmetic composition of the present invention may contain the component (F), may contain the component (G), or may contain the component (H). In addition, the cosmetic composition of the present invention may contain ingredients other than the ingredients (A) to (H).
　上記の成分、例えば、成分（Ａ）、成分（Ｂ）、成分（Ｃ）、成分（Ｄ）、成分（Ｅ）、成分（Ｆ）、成分（Ｇ）、成分（Ｈ）や他の成分は、それぞれ、１種のみが用いられてもよく、２種以上が用いられてもよい。 The above components, for example, component (A), component (B), component (C), component (D), component (E), component (F), component (G), component (H) and other components , Only one type may be used, or two or more types may be used.
　以下、本発明の化粧料組成物に用いられる各成分の詳細を説明する。 Hereinafter, details of each component used in the cosmetic composition of the present invention will be described.
　（成分（Ａ））
　成分（Ａ）は、下記式（１）で表される化合物である。成分（Ａ）は、モノアルキル４級アンモニウムカチオン界面活性剤である。成分（Ａ）は、カチオンゲルを形成するための成分である。成分（Ａ）と成分（Ｄ）と成分（Ｅ）とにより、ゲルネットワークが形成される。また、本発明の化粧料組成物が成分（Ｆ）を含む場合には、ゲルネットワークにより成分（Ｆ）の液滴が安定的に存在でき、乳化安定性を高めることができる。成分（Ａ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。 (Ingredient (A))
The component (A) is a compound represented by the following formula (1). Component (A) is a monoalkyl quaternary ammonium cationic surfactant. The component (A) is a component for forming a cation gel. A gel network is formed by the component (A), the component (D), and the component (E). Further, when the cosmetic composition of the present invention contains the component (F), droplets of the component (F) can stably exist due to the gel network, and the emulsion stability can be enhanced. As the component (A), only one kind may be used, or two or more kinds may be used in combination.
　Ｒ１－Ｎ＋（ＣＨ３）３Ｘ－　　　（１） R 1 -N + (CH 3) 3 X - (1)
　上記式（１）中、Ｒ１は、直鎖状又は分岐鎖状の炭素数１２～２２の脂肪族炭化水素基を表す。上記脂肪族炭化水素基の炭素数は、１６～２２であることが好ましい。上記脂肪族炭化水素基としては、アルキル基、アルケニル基、及びアルキニル基が挙げられる。塗布性をより一層高める観点からは、上記Ｒ１は、直鎖状又は分岐鎖状のアルキル基であることが好ましく、直鎖状のアルキル基であることがより好ましい。 In the above formula (1), R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms. The aliphatic hydrocarbon group preferably has 16 to 22 carbon atoms. Examples of the aliphatic hydrocarbon group include an alkyl group, an alkenyl group, and an alkynyl group. From the viewpoint of further improving the coatability, the R 1 is preferably a linear or branched alkyl group, and more preferably a linear alkyl group.
　上記式（１）中、Ｘ－は、第四級アンモニウムカチオンのカウンターアニオンであり、Ｃｌ－又はＢｒ－を表す。 In the above formula (1), X − is a counter anion of a quaternary ammonium cation and represents Cl − or Br −.
　成分（Ａ）としては、例えば、塩化ステアリルトリメチルアンモニウム（ステアルトリモニウムクロリド、ＩＮＣＩ名：Ｓｔｅａｒｔｒｉｍｏｎｉｕｍ　Ｃｈｌｏｒｉｄｅ）、臭化ステアリルトリメチルアンモニウム（ステアルトリモニウムブロミド）、塩化アルキルトリメチルアンモニウム（ベヘントリモニウムクロリド、ＩＮＣＩ名：Ｂｅｈｅｎｔｒｉｍｏｎｉｕｍ　Ｃｈｌｏｒｉｄｅ）、塩化セチルトリメチルアンモニウム（セトリモニウムクロリド）、及び臭化セチルトリメチルアンモニウム（セトリモニウムブロミド）等が挙げられる。 Examples of the component (A) include stearyltrimethylammonium chloride (stealtrimonium chloride, INCI name: Steartrimonium Chloride), stearyltrimethylammonium bromide (stealtrimonium bromide), alkyltrimethylammonium chloride (behentrimonium chloride, INCI name). : Behentrimonium Chloride), cetyltrimethylammonium chloride (cetrimonium chloride), cetyltrimethylammonium bromide (cetrimonium bromide) and the like.
　成分（Ａ）を含む市販品としては、商品名「ＶＡＲＩＳＯＦＴ　３００」、商品名「ＶＡＲＩＳＯＦＴ　８５　Ｐｅｌｌｅｔｓ」（以上、エボニックジャパン社製）、商品名「ＡＲＱＵＡＤ　１８－５０」（ＡｋｚｏＮｏｂｅｌ社製）、商品名「ＣＴＡＣ　３０ＫＣ」（ＫＣＩ社製）、商品名「ＮＩＫＫＯＬ　ＣＡ－２２５０Ｅ」（日光ケミカルズ社製）、商品名「ＧＥＮＡＭＩＮ　ＫＤＭＰ」（クラリアント社製）、商品名「コータミン８６Ｗ」（花王社製）などが挙げられる。 Commercially available products containing the ingredient (A) include the product name "VARISOFT 300", the product name "VARISOFT 85 Pellets" (above, manufactured by Ebonic Japan), the product name "ARQUAD 18-50" (manufactured by AkzoNobel), and the product name. "CTAC 30KC" (manufactured by KCI), product name "NIKKOL CA-2250E" (manufactured by Nikko Chemicals), product name "GENAMIN KDMP" (manufactured by Clariant), product name "Kotamin 86W" (manufactured by Kao), etc. Can be mentioned.
　本発明の化粧料組成物１００質量％中、成分（Ａ）の含有量は、好ましくは０．５質量％以上、より好ましくは１．０質量％以上、さらに好ましくは２．０質量％以上、好ましくは５．０質量％以下、より好ましくは４．５質量％以下、さらに好ましくは４．０質量％以下である。成分（Ａ）の含有量が上記下限以上であると、塗布時のコク感及び付着感をより一層高めることができる。成分（Ａ）の含有量が上記上限以下であると、化粧料組成物が固くなり過ぎず、塗布性及び付着感をより一層高めることができる。上記成分（Ａ）の含有量は、本発明の化粧料組成物中の全ての成分（Ａ）の含有量の合計である。 The content of the component (A) in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, still more preferably 2.0% by mass or more. It is preferably 5.0% by mass or less, more preferably 4.5% by mass or less, and further preferably 4.0% by mass or less. When the content of the component (A) is at least the above lower limit, the richness and adhesion at the time of application can be further enhanced. When the content of the component (A) is not more than the above upper limit, the cosmetic composition does not become too hard, and the coatability and the adhesive feeling can be further improved. The content of the component (A) is the total content of all the components (A) in the cosmetic composition of the present invention.
　（成分（Ｂ））
　成分（Ｂ）は、下記式（２）で表される化合物である。下記式（２）において、－Ｃ（＝Ｏ）－基は、カルボニル基である。成分（Ｂ）により、化粧料組成物の粘弾性挙動が変化し、塗布時の伸びやすさが向上する。特に、成分（Ｂ）により、成分（Ａ）や成分（Ｄ）の配合量を多くして化粧料組成物が固くなったとしても、付着感及び塗布性の低下を抑制できる。また、成分（Ｂ）により、油性成分（例えば、成分（Ｆ））の乳化力を高めることができるので、本発明の化粧料組成物が乳化化粧料組成物である場合に、乳化安定性を高めることができる。成分（Ｂ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。 (Component (B))
The component (B) is a compound represented by the following formula (2). In the following formula (2), the -C (= O) -group is a carbonyl group. The viscoelastic behavior of the cosmetic composition is changed by the component (B), and the stretchability at the time of application is improved. In particular, even if the amount of the component (A) and the component (D) is increased by the component (B) to harden the cosmetic composition, it is possible to suppress a decrease in adhesion and coatability. Further, since the emulsifying power of the oily component (for example, the component (F)) can be enhanced by the component (B), the emulsifying stability can be improved when the cosmetic composition of the present invention is an emulsified cosmetic composition. Can be enhanced. As the component (B), only one kind may be used, or two or more kinds may be used in combination.
　Ｒ２－Ｃ（＝Ｏ）－ＮＨ－Ｃ３Ｈ６－Ｎ＋（ＣＨ３）３Ｚ－　　　（２） R 2 -C (= O) -NH -C 3 H 6 -N + (CH 3) 3 Z - (2)
　上記式（２）中、Ｒ２は、直鎖状又は分岐鎖状の炭素数１１～２１の脂肪族炭化水素基を表す。上記脂肪族炭化水素基の炭素数は、１３～２１であることが好ましい。上記脂肪族炭化水素基としては、アルキル基、アルケニル基及びアルキニル基が挙げられる。塗布性をより一層高める観点からは、上記Ｒ２は、直鎖状又は分岐鎖状のアルキル基であることが好ましく、直鎖状のアルキル基であることがより好ましい。 In the above formula (2), R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms. The aliphatic hydrocarbon group preferably has 13 to 21 carbon atoms. Examples of the aliphatic hydrocarbon group include an alkyl group, an alkenyl group and an alkynyl group. From the viewpoint of further improving the coatability, the R 2 is preferably a linear or branched alkyl group, and more preferably a linear alkyl group.
　上記式（２）中、Ｚ－は、第四級アンモニウムカチオンのカウンターアニオンであり、Ｃｌ－又はＢｒ－を表す。 In the above formula (2), Z − is a counter anion of a quaternary ammonium cation and represents Cl − or Br −.
　成分（Ｂ）としては、例えば、パルミタミドプロピルトリモニウムクロリド（ＩＮＣＩ名：Ｐａｌｍｉｔａｍｉｄｏｐｒｏｐｙｌｔｒｉｍｏｎｉｕｍ　Ｃｈｌｏｒｉｄｅ）等が挙げられる。 Examples of the component (B) include palmitamide propyltrimonium chloride (INCI name: Palmitamideplopyltrimonium Chloride) and the like.
　成分（Ｂ）を含む市販品としては、商品名「ＶＡＲＩＳＯＦＴ　ＰＡＴＣ」（エボニックジャパン社製）等が挙げられる。 Examples of commercially available products containing the component (B) include the trade name "VARISOFT PATC" (manufactured by Evonik Japan).
　本発明の化粧料組成物１００質量％中、成分（Ｂ）の含有量は、好ましくは０．０５質量％以上、より好ましくは０．１質量％以上、さらに好ましくは０．３質量％以上、好ましくは３．０質量％以下、より好ましくは２．５質量％以下、さらに好ましくは２．０質量％以下である。成分（Ｂ）の含有量が上記下限以上であると、塗布時の伸びやすさがより一層向上する。また、成分（Ａ）や成分（Ｄ）の配合量を多くして化粧料組成物が固くなったとしても、付着感及び塗布性の低下を効果的に抑制できる。さらに、本発明の化粧料組成物が乳化化粧料組成物である場合に、乳化安定性をより一層高めることができる。成分（Ｂ）の含有量が上記上限以下であると、コク感をより一層高めることができる。上記成分（Ｂ）の含有量は、本発明の化粧料組成物中の全ての成分（Ｂ）の含有量の合計である。 The content of the component (B) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.3% by mass or more. It is preferably 3.0% by mass or less, more preferably 2.5% by mass or less, and further preferably 2.0% by mass or less. When the content of the component (B) is at least the above lower limit, the stretchability at the time of application is further improved. Further, even if the amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to effectively suppress the deterioration of the adhesive feeling and the coatability. Furthermore, when the cosmetic composition of the present invention is an emulsified cosmetic composition, the emulsification stability can be further enhanced. When the content of the component (B) is not more than the above upper limit, the richness can be further enhanced. The content of the above component (B) is the total content of all the components (B) in the cosmetic composition of the present invention.
　（成分（Ｃ））
　成分（Ｃ）は、ポリグリセリンに２～６個の脂肪酸がエステル結合しており、かつグリセリンの平均付加モル数が４～１２であるポリグリセリン脂肪酸エステルである。成分（Ｃ）により、化粧料組成物の粘弾性挙動が変化し、塗布時の伸びやすさが向上する。成分（Ｃ）により、成分（Ａ）や成分（Ｄ）の配合量を多くして化粧料組成物が固くなったとしても、付着感及び塗布性の低下を抑制できる。また、成分（Ｃ）により、カチオンゲルの安定性を高めることができるので、本発明の化粧料組成物の安定性（経時安定性）を高めることができる。成分（Ｃ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。 (Component (C))
The component (C) is a polyglycerin fatty acid ester in which 2 to 6 fatty acids are ester-bonded to polyglycerin and the average number of moles of glycerin added is 4 to 12. The viscoelastic behavior of the cosmetic composition is changed by the component (C), and the stretchability at the time of application is improved. With the component (C), even if the blending amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to suppress a decrease in adhesion and coatability. Further, since the stability of the cation gel can be enhanced by the component (C), the stability (stability with time) of the cosmetic composition of the present invention can be enhanced. As the component (C), only one kind may be used, or two or more kinds may be used in combination.
　成分（Ａ）及び成分（Ｄ）は、化粧料組成物中において、ミセルやエマルション粒子などの構造体を形成する。成分（Ｂ）及び成分（Ｃ）による効果は、成分（Ｂ）及び成分（Ｃ）が上記構造体中に取り込まれることにより、上記構造体中の分子鎖のパッキング状態を緩めることによるものと推定されるが、これに限定されるものではない。 The component (A) and the component (D) form a structure such as micelles and emulsion particles in the cosmetic composition. It is presumed that the effect of the component (B) and the component (C) is due to the loosening of the packing state of the molecular chains in the structure by incorporating the component (B) and the component (C) into the structure. However, it is not limited to this.
　成分（Ｃ）としては、ポリグリセリンジ脂肪酸エステル、ポリグリセリントリ脂肪酸エステル、ポリグリセリンテトラ脂肪酸エステル、ポリグリセリンペンタ脂肪酸エステル、及びポリグリセリンヘキサ脂肪酸エステル等が挙げられる。 Examples of the component (C) include polyglycerin di fatty acid ester, polyglycerin tri fatty acid ester, polyglycerin tetra fatty acid ester, polyglycerin penta fatty acid ester, and polyglycerin hexa fatty acid ester.
　成分（Ｃ）は、ポリグリセリンジ脂肪酸エステル、及びポリグリセリントリ脂肪酸エステルからなる群より選ばれるポリグリセリン脂肪酸エステル（少なくとも１のポリグリセリン脂肪酸エステル）であることが好ましい。 The component (C) is preferably a polyglycerin fatty acid ester (at least one polyglycerin fatty acid ester) selected from the group consisting of a polyglycerin difatty acid ester and a polyglycerin trifatty acid ester.
　成分（Ｃ）のポリグリセリン部分のグリセリンの平均付加モル数は、５～１０が好ましい。 The average number of moles of glycerin added to the polyglycerin portion of the component (C) is preferably 5 to 10.
　成分（Ｃ）における上記脂肪酸としては、炭素数１０～２２の直鎖状又は分岐鎖状の飽和又は不飽和の脂肪酸が挙げられる。上記炭素数は１２～１８が好ましい。上記脂肪酸としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、及びオレイン酸等が挙げられる。上記脂肪酸は、ステアリン酸であることが好ましい。 Examples of the fatty acid in the component (C) include linear or branched saturated or unsaturated fatty acids having 10 to 22 carbon atoms. The number of carbon atoms is preferably 12 to 18. Examples of the fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, and oleic acid. The fatty acid is preferably stearic acid.
　成分（Ｃ）としては、より具体的には、ジステアリン酸ポリグリセリル－１０、ジイソステアリン酸ポリグリセリル－１０、ジオレイン酸ポリグリセリル－５、ジオレイン酸ポリグリセリル－１０、ジミリスチン酸ポリグリセリル－１０、トリラウリン酸ポリグリセリル－１０、トリミリスチン酸ポリグリセリル－５、トリオレイン酸ポリグリセリル－５、ペンタステアリン酸ポリグリセリル－１０、ペンタオレイン酸ポリグリセリル－１０、及びヘキサステアリン酸ポリグリセリル－５等が挙げられる。 More specifically, the component (C) includes polyglyceryl-10 diisostearate, polyglyceryl diisostearate-10, polyglyceryl dioleate-5, polyglyceryl dioleate-10, polyglyceryl dimyristate-10, polyglyceryl trilaurate-10, and the like. Examples thereof include polyglyceryl-5 trimyristate, polyglyceryl trioleate-5, polyglyceryl pentastearate-10, polyglyceryl pentaoleate-10, and polyglyceryl hexastearate-5.
　付感着及び塗布性をより一層高める観点から、成分（Ｃ）は、ジステアリン酸ポリグリセリル－１０、ジイソステアリン酸ポリグリセリル－１０、ペンタステアリン酸ポリグリセリル－１０、トリオレイン酸ポリグリセリル－５、トリラウリン酸ポリグリセリル－１０、及びジオレイン酸ポリグリセリル－１０からなる群より選ばれるポリグリセリン脂肪酸エステル（少なくとも１のポリグリセリン脂肪酸エステル）であることが好ましく、ジステアリン酸ポリグリセリル－１０であることがより好ましい。 From the viewpoint of further enhancing the attachment and applicability, the component (C) is polyglyceryl distearate-10, polyglyceryl diisostearate-10, polyglyceryl pentastearate-10, polyglyceryl trioleate-5, polyglyceryl trilaurate-10. , And polyglycerin fatty acid ester selected from the group consisting of polyglyceryl dioleate-10 (at least one polyglycerin fatty acid ester), and more preferably polyglyceryl dystearate-10.
　本発明の化粧料組成物１００質量％中、成分（Ｃ）の含有量は、好ましくは０．０５質量％以上、より好ましくは０．１質量％以上、さらに好ましくは０．３質量％以上、好ましくは３．０質量％以下、より好ましくは２．５質量％以下、さらに好ましくは２．０質量％以下である。成分（Ｃ）の含有量が上記下限以上であると、塗布時の伸びやすさがより一層向上する。また、成分（Ａ）や成分（Ｄ）の配合量を多くして化粧料組成物が固くなったとしても、付着感及び塗布性の低下を効果的に抑制できる。さらに、本発明の化粧料組成物の安定性を高めることができる。成分（Ｃ）の含有量が上記上限以下であると、コク感をより一層高めることができる。上記成分（Ｃ）の含有量は、本発明の化粧料組成物中の全ての成分（Ｃ）の含有量の合計である。 The content of the component (C) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.3% by mass or more. It is preferably 3.0% by mass or less, more preferably 2.5% by mass or less, and further preferably 2.0% by mass or less. When the content of the component (C) is at least the above lower limit, the stretchability at the time of coating is further improved. Further, even if the amount of the component (A) and the component (D) is increased to harden the cosmetic composition, it is possible to effectively suppress the deterioration of the adhesive feeling and the coatability. Furthermore, the stability of the cosmetic composition of the present invention can be enhanced. When the content of the component (C) is not more than the above upper limit, the richness can be further enhanced. The content of the component (C) is the total content of all the components (C) in the cosmetic composition of the present invention.
　（成分（Ｄ））
　成分（Ｄ）は、炭素数１２～２４の脂肪族アルコールである。成分（Ｄ）は、所謂、高級アルコールである。成分（Ｄ）は、カチオンゲルを形成するための成分である。成分（Ａ）と成分（Ｄ）と成分（Ｅ）とにより、ゲルネットワークが形成される。また、本発明の化粧料組成物が成分（Ｆ）を含む場合には、乳化安定性を高めることができる。成分（Ｄ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。 (Component (D))
The component (D) is an aliphatic alcohol having 12 to 24 carbon atoms. The component (D) is a so-called higher alcohol. The component (D) is a component for forming a cation gel. A gel network is formed by the component (A), the component (D), and the component (E). Further, when the cosmetic composition of the present invention contains the component (F), the emulsion stability can be enhanced. As the component (D), only one kind may be used, or two or more kinds may be used in combination.
　成分（Ｄ）としては、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、セテアリルアルコール、イソステアリルアルコール、ヘキシルデカノール、２－オクチルドデカノール、オレイルアルコール、デシルテトラデカノール、及びベヘニルアルコール等が挙げられる。 Examples of the component (D) include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, isostearyl alcohol, hexyldecanol, 2-octyldodecanol, oleyl alcohol, decyltetradecanol, and behenyl alcohol.
　コク感をより一層高める観点からは、成分（Ｄ）は、ステアリルアルコール、セチルアルコール、及びベヘニルアルコールからなる群より選ばれる脂肪族アルコール（少なくとも１の脂肪族アルコール）であることが好ましく、ステアリルアルコールであることがより好ましい。 From the viewpoint of further enhancing the richness, the component (D) is preferably an aliphatic alcohol (at least one aliphatic alcohol) selected from the group consisting of stearyl alcohol, cetyl alcohol, and behenyl alcohol, and is preferably stearyl alcohol. More preferably.
　本発明の化粧料組成物１００質量％中、成分（Ｄ）の含有量は、好ましくは３．０質量％以上、より好ましくは５．０質量％以上、さらに好ましくは６．５質量％以上、好ましくは２０．０質量％以下、より好ましくは１５．０質量％以下、さらに好ましくは１３．０質量％以下である。成分（Ｄ）の含有量が上記下限以上であると、塗布時のコク感及び付着感をより一層高めることができる。成分（Ｄ）の含有量が上記上限以下であると、化粧料組成物が固くなり過ぎず、塗布性及び付着感をより一層高めることができる。上記成分（Ｄ）の含有量は、本発明の化粧料組成物中の全ての成分（Ｄ）の含有量の合計である。 The content of the component (D) in 100% by mass of the cosmetic composition of the present invention is preferably 3.0% by mass or more, more preferably 5.0% by mass or more, still more preferably 6.5% by mass or more. It is preferably 20.0% by mass or less, more preferably 15.0% by mass or less, still more preferably 13.0% by mass or less. When the content of the component (D) is at least the above lower limit, the richness and adhesion at the time of application can be further enhanced. When the content of the component (D) is not more than the above upper limit, the cosmetic composition does not become too hard, and the coatability and the adhesive feeling can be further improved. The content of the above component (D) is the total content of all the components (D) in the cosmetic composition of the present invention.
　本発明の化粧料組成物では、成分（Ａ）の含有量が２．０質量％以上であり、かつ成分（Ｄ）の含有量が６．５質量％以上である場合に、コク感を特に高めることができる。さらに、この場合に、成分（Ｂ）及び成分（Ｃ）を併用することによる付着感及び塗布性をより一層高める効果が特に発揮されやすくなる。 In the cosmetic composition of the present invention, when the content of the component (A) is 2.0% by mass or more and the content of the component (D) is 6.5% by mass or more, the richness is particularly felt. Can be enhanced. Further, in this case, the effect of further enhancing the adhesive feeling and the coatability by using the component (B) and the component (C) in combination is particularly likely to be exhibited.
　（成分（Ｅ））
　成分（Ｅ）は、水である。成分（Ｅ）は精製水であることが好ましい。 (Component (E))
The component (E) is water. The component (E) is preferably purified water.
　本発明の化粧料組成物中の成分（Ｅ）の含有量は、他の成分の含有量によって適宜調整することができる。本発明の化粧料組成物１００質量％中、成分（Ｅ）の含有量は、好ましくは４０．０質量％以上、より好ましくは４５．０質量％以上、好ましくは８５．０質量％以下、より好ましくは８０．０質量％以下である。 The content of the component (E) in the cosmetic composition of the present invention can be appropriately adjusted according to the content of other components. The content of the component (E) in 100% by mass of the cosmetic composition of the present invention is preferably 40.0% by mass or more, more preferably 45.0% by mass or more, preferably 85.0% by mass or less, and more. It is preferably 80.0% by mass or less.
　（成分（Ｆ））
　成分（Ｆ）は、シリコーン油、エステル油、植物油、及び炭化水素油からなる群より選ばれる油性成分（少なくとも１の油性成分）である。本発明の化粧料組成物は、成分（Ｆ）を含むことが好ましい。成分（Ｆ）を配合することにより、乳化化粧料組成物とすることができる。したがって、本発明の化粧料組成物は、乳化化粧料組成物であることが好ましい。また、成分（Ｆ）により、乳化化粧料組成物を毛髪に塗布したときに、乾燥後の毛髪に柔軟感（やわらかな感触）、さらさら感及びまとまり感を良好に付与することができる。成分（Ｆ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。 (Component (F))
The component (F) is an oily component (at least one oily component) selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil. The cosmetic composition of the present invention preferably contains the component (F). By blending the component (F), an emulsified cosmetic composition can be obtained. Therefore, the cosmetic composition of the present invention is preferably an emulsified cosmetic composition. In addition, the component (F) can satisfactorily impart a soft feeling (soft feeling), a silky feeling, and a cohesive feeling to the dried hair when the emulsified cosmetic composition is applied to the hair. As the component (F), only one kind may be used, or two or more kinds may be used in combination.
　上記シリコーン油としては、メチルポリシロキサン（ジメチコン）、及び高重合メチルポリシロキサン等のジメチルシリコーン油；メチルフェニルポリシロキサン等のメチルフェニルシリコーン油；メチルシクロポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、及びドデカメチルシクロヘキサシロキサン等の環状シリコーン油；アミノプロピルメチルシロキサン・ジメチルシロキサン共重合体、アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体、及びアミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体等のアミノ変性シリコーン、カルボキシ変性シリコーン、脂肪酸変性シリコーン、アルコール変性シリコーン、脂肪族アルコール変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、アルキル変性シリコーンなどの変性シリコーン；メチルハイドロジェンポリシロキサン、ジメチコノール等が挙げられる。 Examples of the silicone oil include methylpolysiloxane (dimethicone) and dimethylsilicone oil such as highly polymerized methylpolysiloxane; methylphenylsilicone oil such as methylphenylpolysiloxane; methylcyclopolysiloxane, octamethylcyclotetrasiloxane, and decamethylcyclo. Cyclic silicone oils such as pentasiloxane and dodecamethylcyclohexasiloxane; aminopropylmethylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, and aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer weight Amino-modified silicones such as coalesces, carboxy-modified silicones, fatty acid-modified silicones, alcohol-modified silicones, aliphatic alcohol-modified silicones, epoxy-modified silicones, fluorine-modified silicones, alkyl-modified silicones, and other modified silicones; methylhydrogenpolysiloxane, dimethiconol, etc. Can be mentioned.
　上記シリコーン油は、２５℃における粘度が１万ｍＰａ・ｓ以上であるシリコーン油、及び２５℃における粘度が１万ｍＰａ・ｓ未満であるアミノ変性シリコーンからなる群より選ばれるシリコーン油（少なくとも１のシリコーン油）を含むことが好ましい。 The silicone oil is a silicone oil selected from the group consisting of a silicone oil having a viscosity at 25 ° C. of 10,000 mPa · s or more and an amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa · s (at least one). Silicone oil) is preferably contained.
　本明細書においては、上記「２５℃における粘度が１万ｍＰａ・ｓ以上であるシリコーン油、及び２５℃における粘度が１万ｍＰａ・ｓ未満であるアミノ変性シリコーンからなる群より選ばれるシリコーン油」を「成分（Ｆ１）」と記載することがある。 In the present specification, the above-mentioned "silicone oil selected from the group consisting of a silicone oil having a viscosity at 25 ° C. of 10,000 mPa · s or more and an amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa · s". May be described as "component (F1)".
　本明細書においては、上記「２５℃における粘度が１万ｍＰａ・ｓ以上であるシリコーン油」を「成分（Ｆ１１）」と記載することがある。成分（Ｆ１１）は、高重合シリコーンである。 In the present specification, the above-mentioned "silicone oil having a viscosity at 25 ° C. of 10,000 mPa · s or more" may be referred to as "component (F11)". The component (F11) is a highly polymerized silicone.
　本明細書においては、上記「２５℃における粘度が１万ｍＰａ・ｓ未満であるアミノ変性シリコーン」を「成分（Ｆ１２）」と記載することがある。 In the present specification, the above-mentioned "amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa · s" may be referred to as "component (F12)".
　したがって、上記シリコーン油は、成分（Ｆ１）を含むことが好ましい。上記シリコーン油は、成分（Ｆ１１）及び成分（Ｆ１２）からなる群より選ばれるシリコーン油を含むことが好ましい。なお、成分（Ｆ１１）には、２５℃における粘度が１万ｍＰａ・ｓ以上であるアミノ変性シリコーンが含まれる。 Therefore, the silicone oil preferably contains the component (F1). The silicone oil preferably contains a silicone oil selected from the group consisting of the component (F11) and the component (F12). The component (F11) contains an amino-modified silicone having a viscosity at 25 ° C. of 10,000 mPa · s or more.
　本発明の化粧料組成物が成分（Ｆ１１）を含む場合には、乾燥後の毛髪にさらさら感を良好に付与することができる。本発明の化粧料組成物が成分（Ｆ１２）を含む場合には、塗布時及び乾燥後の毛髪の柔軟感を高めることができる。 When the cosmetic composition of the present invention contains the component (F11), it is possible to give the hair after drying a smooth feeling. When the cosmetic composition of the present invention contains the component (F12), it is possible to enhance the softness of the hair at the time of application and after drying.
　成分（Ｆ１１）の２５℃における粘度は、１万ｍＰａ・ｓ以上であり、好ましくは６万ｍＰａ・ｓ以上、より好ましくは８万ｍＰａ・ｓ以上、好ましくは３０００万ｍＰａ・ｓ以下、より好ましくは１５０万ｍＰａ・ｓ以下、さらに好ましくは１００万ｍＰａ・ｓ以下である。上記粘度が上記下限以上及び上記上限以下であると、乾燥後の毛髪にさらさら感をより一層良好に付与することができる。 The viscosity of the component (F11) at 25 ° C. is 10,000 mPa · s or more, preferably 60,000 mPa · s or more, more preferably 80,000 mPa · s or more, preferably 30 million mPa · s or less, more preferably. Is 1.5 million mPa · s or less, more preferably 1 million mPa · s or less. When the viscosity is at least the above lower limit and at least the above upper limit, it is possible to impart a smoother feeling to the dried hair even more satisfactorily.
　上記エステル油としては、オクタン酸セチル、オレイン酸エチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸ミリスチル、パルミチン酸セチル、パルミチン酸２－エチルヘキシル、ミリスチン酸オクチルドデシル、イソステアリン酸イソプロピル、イソステアリン酸プロピレングリコール、２－エチルヘキサン酸セチル、トリ２－エチルヘキサン酸グリセリル、トリ（カプリル酸／カプリン酸）グリセリル、イソノナン酸イソノニル、アジピン酸ジイソプロピル、テトラオクタン酸ペンタエリスリチル、テトライソステアリン酸ペンタエリトリット、リンゴ酸ジイソステアリル、トリエチルヘキサン酸エリスリチル、ヒドロキシステアリン酸２－エチルヘキシル、ヘキサ（ヒドロキシステアリン酸／ステアリン酸／ロジン酸）ジペンタエリスリチル、テトラ（ヒドロキシステアリン酸／イソステアリン酸）ジペンタエリスリチル、ヘキサヒドロキシステアリン酸ジペンタエリスリチル、（エチルヘキサン酸／ステアリン酸／アジピン酸）グリセリル、トリ（カプリル酸／カプリン酸／ミリスチン酸／ステアリン酸）グリセリル、ヘキサ（ベヘン酸／安息香酸／エチルヘキサン酸）ジペンタエリスリチル、及び安息香酸アルキル（Ｃ１２－１５）等が挙げられる。 Examples of the ester oil include cetyl octanate, ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, 2-ethylhexyl palmitate, octyldodecyl myristate, isopropyl isostearate, and propylene glycol isostearate. Cetyl 2-ethylhexanoate, glyceryl tri2-ethylhexanoate, glyceryl tri (caprylic acid / capric acid), isononyl isononanoate, diisopropyl adipate, pentaerythrityl tetraoctanoate, pentaerythrit tetraisostearate, diiolate Isostearyl, erythricyl triethylhexarate, 2-ethylhexyl hydroxystearate, hexa (hydroxystearic acid / stearic acid / logonic acid) dipentaerythrityl, tetra (hydroxystearic acid / isostearic acid) dipentaerythrityl, dipentaerythrityl hexahydroxystearate, (ethylhexanoic acid) / Stearic acid / adipic acid) glyceryl, tri (caprylic acid / capric acid / myristic acid / stearic acid) glyceryl, hexa (bechenic acid / benzoic acid / ethylhexanoic acid) dipentaerythrityl, alkyl benzoate (C12-15), etc. Can be mentioned.
　また、上記エステル油としては、ダイマージリノール酸ジ（イソステアリル／フィトステリル）、ダイマージリノール酸ダイマージリノレイル、ダイマージリノール酸（フィトステリル／イソステアリル／セチル／ステアリル／ベヘニル）、ダイマージリノール酸水添ヒマシ油、及びダイマージリノール酸ジグリセリンイソステアレート等のダイマー酸エステルも挙げられる。さらに、上記エステル油としては、ダイマージリノール酸水添ロジン縮合物、及びジイソステアリン酸ダイマージリノレイル等のダイマージオールエステルも挙げられる。 Examples of the ester oil include dimer dilinoleic acid di (isostearyl / phytosteryl), dimer dilinoleic acid dimer dilinoleic acid, dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), and dimer dilinoleic acid. Hydrogenated castor oil and dimer acid esters such as diglycerin isostearate with dimer dilinoleic acid can also be mentioned. Further, examples of the ester oil include a hydrogenated rosin condensate of dimer linoleic acid and a dimer diol ester such as diima linoleyl diisostearic acid.
　上記エステル油は、ダイマー酸エステルを含むことが好ましい。 The ester oil preferably contains a dimer acid ester.
　本明細書においては、上記「ダイマー酸エステル」を「成分（Ｆ２）」と記載することがある。 In the present specification, the above-mentioned "dimeric acid ester" may be referred to as "component (F2)".
　したがって、上記エステル油は、成分（Ｆ２）を含むことが好ましい。本発明の化粧料組成物が成分（Ｆ２）を含む場合には、毛髪にまとまり感を良好に付与することができる。 Therefore, the ester oil preferably contains the component (F2). When the cosmetic composition of the present invention contains the component (F2), it is possible to impart a good cohesive feeling to the hair.
　上記植物油としては、例えば、マカデミアナッツ油、ユーカリ油、ヤシ油、アボカド油、サフラワー油、オリーブ油、パーム油、パーム核油、ククイナッツ油、シア脂（シアバター）、カカオバター、アーモンド油、ヒマワリ油、ローズヒップ油、オリーブスクワラン、カメリアオイル、キウイフルーツシード油、ツバキ油、杏仁油、ゴマ油、大豆油、ホホバ油、ヒマシ油、ヘーゼルナッツ油、メドウフォーム油、ハッカ油、アルガンオイル、カロットオイル、ラベンダー油、シュガースクワラン、及びクランベアビシニカ種子油等が挙げられる。 Examples of the vegetable oils include macadamia nut oil, eucalyptus oil, palm oil, avocado oil, saflower oil, olive oil, palm oil, palm kernel oil, kukui nut oil, shea butter, cacao butter, almond oil, and sunflower oil. , Rosehip oil, olive squalane, camellia oil, kiwi fruit seed oil, camellia oil, apricot oil, sesame oil, soybean oil, jojoba oil, castor oil, hazelnut oil, meadowfoam oil, peppermint oil, argan oil, carrot oil, lavender Examples include oil, sugar squalane, and cranbear bicinica seed oil.
　上記炭化水素油としては、α－オレフィンオリゴマー、軽質イソパラフィン、軽質流動イソパラフィン、スクワラン、合成スクワラン、植物性スクワラン、流動イソパラフィン、及び流動パラフィン等が挙げられる。 Examples of the hydrocarbon oil include α-olefin oligomers, light isoparaffin, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, liquid isoparaffin, and liquid paraffin.
　成分（Ｆ）は、上記シリコーン油を含むことが好ましく、上記エステル油を含むことが好ましく、上記シリコーン油と上記エステル油とを含むことがより好ましい。成分（Ｆ）は、成分（Ｆ１）を含むことが好ましく、成分（Ｆ２）を含むことが好ましく、成分（Ｆ１）と成分（Ｆ２）とを含むことがより好ましい。 The component (F) preferably contains the above-mentioned silicone oil, preferably contains the above-mentioned ester oil, and more preferably contains the above-mentioned silicone oil and the above-mentioned ester oil. The component (F) preferably contains the component (F1), preferably contains the component (F2), and more preferably contains the component (F1) and the component (F2).
　本発明の化粧料組成物が上記シリコーン油を含む場合に、本発明の化粧料組成物１００質量％中、上記シリコーン油の含有量は、好ましくは１．０質量％以上、より好ましくは３．０質量％以上、好ましくは３０．０質量％以下、より好ましくは２０．０質量％以下である。上記シリコーン油の含有量は、本発明の化粧料組成物中の全てのシリコーン油の含有量の合計である。 When the cosmetic composition of the present invention contains the silicone oil, the content of the silicone oil in 100% by mass of the cosmetic composition of the present invention is preferably 1.0% by mass or more, more preferably 3. It is 0% by mass or more, preferably 30.0% by mass or less, and more preferably 20.0% by mass or less. The content of the silicone oil is the sum of the contents of all the silicone oils in the cosmetic composition of the present invention.
　本発明の化粧料組成物が成分（Ｆ１）を含む場合に、本発明の化粧料組成物１００質量％中、成分（Ｆ１）の含有量は、好ましくは０．１質量％以上、より好ましくは０．５質量％以上、好ましくは１０．０質量％以下、より好ましくは５．０質量％以下である。成分（Ｆ１）の含有量は、本発明の化粧料組成物中の全ての成分（Ｆ１）の含有量の合計である。 When the cosmetic composition of the present invention contains the component (F1), the content of the component (F1) in 100% by mass of the cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.1% by mass or more. It is 0.5% by mass or more, preferably 10.0% by mass or less, and more preferably 5.0% by mass or less. The content of the component (F1) is the total content of all the components (F1) in the cosmetic composition of the present invention.
　本発明の化粧料組成物が上記エステル油を含む場合に、本発明の化粧料組成物１００質量％中、上記エステル油の含有量は、好ましくは０．５質量％以上、より好ましくは１．０質量％以上、好ましくは２０．０質量％以下、より好ましくは１０．０質量％以下である。上記エステル油の含有量は、本発明の化粧料組成物中の全てのエステル油の含有量の合計である。 When the cosmetic composition of the present invention contains the above ester oil, the content of the above ester oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1. It is 0% by mass or more, preferably 20.0% by mass or less, and more preferably 10.0% by mass or less. The content of the ester oil is the sum of the contents of all the ester oils in the cosmetic composition of the present invention.
　本発明の化粧料組成物が成分（Ｆ２）を含む場合に、本発明の化粧料組成物１００質量％中、成分（Ｆ２）の含有量は、好ましくは０．１質量％以上、より好ましくは０．２質量％以上、好ましくは１０．０質量％以下、より好ましくは５．０質量％以下である。成分（Ｆ２）の含有量は、本発明の化粧料組成物中の全ての成分（Ｆ２）の含有量の合計である。 When the cosmetic composition of the present invention contains the component (F2), the content of the component (F2) in 100% by mass of the cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.1% by mass or more. It is 0.2% by mass or more, preferably 10.0% by mass or less, and more preferably 5.0% by mass or less. The content of the component (F2) is the total content of all the components (F2) in the cosmetic composition of the present invention.
　本発明の化粧料組成物が上記植物油を含む場合に、本発明の化粧料組成物１００質量％中、上記植物油の含有量は、好ましくは０．０５質量％以上、より好ましくは０．２質量％以上、好ましくは１０．０質量％以下、より好ましくは５．０質量％以下である。上記植物油の含有量は、本発明の化粧料組成物中の全ての植物油の含有量の合計である。 When the cosmetic composition of the present invention contains the vegetable oil, the content of the vegetable oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.2% by mass. % Or more, preferably 10.0% by mass or less, more preferably 5.0% by mass or less. The content of the vegetable oil is the sum of the contents of all the vegetable oils in the cosmetic composition of the present invention.
　本発明の化粧料組成物が上記炭化水素油を含む場合に、本発明の化粧料組成物１００質量％中、上記炭化水素油の含有量は、好ましくは０．５質量％以上、より好ましくは１．０質量％以上、好ましくは１０．０質量％以下、より好ましくは７．０質量％以下である。上記炭化水素油の含有量は、本発明の化粧料組成物中の全ての炭化水素油の含有量の合計である。 When the cosmetic composition of the present invention contains the above-mentioned hydrocarbon oil, the content of the above-mentioned hydrocarbon oil in 100% by mass of the cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 0.5% by mass or more. It is 1.0% by mass or more, preferably 10.0% by mass or less, and more preferably 7.0% by mass or less. The content of the above hydrocarbon oil is the sum of the contents of all the hydrocarbon oils in the cosmetic composition of the present invention.
　本発明の化粧料組成物１００質量％中、成分（Ｆ）の含有量は、好ましくは１．０質量％以上、より好ましくは５．０質量％以上、好ましくは３５．０質量％以下、より好ましくは２０．０質量％以下である。成分（Ｆ）の含有量が上記下限以上及び上記上限以下であると、化粧料組成物を毛髪に塗布したときに、乾燥後の毛髪にさらさら感及びまとまり感をより一層良好に付与することができる。上記成分（Ｆ）の含有量は、本発明の化粧料組成物中の全ての成分（Ｆ）の含有量の合計である。 The content of the component (F) in 100% by mass of the cosmetic composition of the present invention is preferably 1.0% by mass or more, more preferably 5.0% by mass or more, preferably 35.0% by mass or less, and more. It is preferably 20.0% by mass or less. When the content of the component (F) is at least the above lower limit and at least the above upper limit, when the cosmetic composition is applied to the hair, it is possible to give the hair after drying a smooth and cohesive feeling even better. can. The content of the above component (F) is the total content of all the components (F) in the cosmetic composition of the present invention.
　（成分（Ｇ））
　成分（Ｇ）は、炭素数１０以上のアルキル基を有するカチオン化セルロースである。成分（Ｇ）により、塗布時及び乾燥後の毛髪のまとまり感を良好にすることができ、また、洗い流し時及び乾燥後の毛髪の柔軟感を高めることができる。さらに、成分（Ｇ）と成分（Ｆ）とを併用することにより、成分（Ｆ）の配合効果をより高めることができる。成分（Ｇ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。 (Ingredient (G))
The component (G) is a cationized cellulose having an alkyl group having 10 or more carbon atoms. The component (G) can improve the cohesiveness of the hair at the time of application and after drying, and can enhance the softness of the hair at the time of rinsing and after drying. Further, by using the component (G) and the component (F) in combination, the blending effect of the component (F) can be further enhanced. As the component (G), only one kind may be used, or two or more kinds may be used in combination.
　成分（Ｇ）としては、ポリクオタニウム－６７等が挙げられる。 Examples of the component (G) include polyquaternium-67 and the like.
　成分（Ｇ）のアルキル基の炭素数は、好ましくは２４以下、より好ましくは２２以下である。 The number of carbon atoms of the alkyl group of the component (G) is preferably 24 or less, more preferably 22 or less.
　成分（Ｇ）は、ポリクオタニウム－６７であることが好ましい。この場合には、塗布時及び乾燥後の毛髪のまとまり感をより一層良好にすることができ、また、洗い流し時の指通り性を良好にし、乾燥後の毛髪の柔軟感をより一層高めることができる。上記ポリクオタニウム－６７は、ヒドロキシエチルセルロースにトリメチルアンモニウム置換エポキシド及びラウリルジメチルアンモニウム置換エポキシドを付加反応させて得られる４級アンモニウム塩の重合体であり、カチオン化ヒドロキシエチルセルロース誘導体である。 The component (G) is preferably polyquaternium-67. In this case, the cohesiveness of the hair at the time of application and after drying can be further improved, the finger passage during rinsing can be improved, and the softness of the hair after drying can be further enhanced. can. The polyquaternium-67 is a polymer of a quaternary ammonium salt obtained by adding a trimethylammonium-substituted epoxide and a lauryldimethylammonium-substituted epoxide to hydroxyethyl cellulose, and is a cationized hydroxyethyl cellulose derivative.
　本発明の化粧料組成物１００質量％中、成分（Ｇ）の含有量は、好ましくは０．０５質量％以上、より好ましくは０．１質量％以上、好ましくは１．０質量％以下、より好ましくは０．７質量％以下である。成分（Ｇ）の含有量が上記下限以上及び上記上限以下であると、塗布時及び乾燥後の毛髪のまとまり感をより一層良好にすることができ、また、洗い流し時の指通り性を良好にし、乾燥後の毛髪の柔軟感をより一層高めることができる。 The content of the component (G) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, preferably 1.0% by mass or less, and more. It is preferably 0.7% by mass or less. When the content of the component (G) is at least the above lower limit and at least the above upper limit, the cohesiveness of the hair at the time of application and after drying can be further improved, and the finger passage during rinsing can be improved. , The softness of the hair after drying can be further enhanced.
　（成分（Ｈ））
　成分（Ｈ）は、ポリプロピレングリコールアルキルエーテル（ポリオキシプロピレンアルキルエーテル）である。特に、成分（Ｈ）が成分（Ｆ）と併用されることにより、成分（Ｆ）が発揮する上記の効果がより一層効果的に発揮される。成分（Ｈ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。 (Ingredient (H))
The component (H) is polypropylene glycol alkyl ether (polyoxypropylene alkyl ether). In particular, when the component (H) is used in combination with the component (F), the above-mentioned effect exhibited by the component (F) is more effectively exhibited. As the component (H), only one kind may be used, or two or more kinds may be used in combination.
　成分（Ｈ）としては、ＰＰＧ－３カプリリルエーテル、及びＰＰＧ－５カプリリルエーテル等が挙げられる。 Examples of the component (H) include PPG-3 caprylyl ether and PPG-5 caprylyl ether.
　成分（Ｈ）は、ＰＰＧ－３カプリリルエーテルであることが好ましい。この場合には、成分（Ｆ）が発揮する上記の効果がより一層効果的に発揮される。 The component (H) is preferably PPG-3 caprylyl ether. In this case, the above-mentioned effect exerted by the component (F) is more effectively exerted.
　本発明の化粧料組成物１００質量％中、成分（Ｈ）の含有量は、好ましくは０．０５質量％以上、より好ましくは０．１質量％以上、好ましくは５．０質量％以下、より好ましくは３．０質量％以下である。成分（Ｈ）の含有量が上記下限以上及び上記上限以下であると、成分（Ｆ）が発揮する上記の効果がより一層効果的に発揮される。 The content of the component (H) in 100% by mass of the cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, preferably 5.0% by mass or less, and more. It is preferably 3.0% by mass or less. When the content of the component (H) is at least the above lower limit and at least the above upper limit, the above-mentioned effect exerted by the component (F) is more effectively exerted.
　（他の成分）
　本発明の化粧料組成物は、上述した成分（Ａ）～（Ｈ）以外の他の成分を含んでいてもよい。上記他の成分としては、エタノール等の低級アルコール；多価アルコール；成分（Ｆ）以外の油性成分；アニオン性界面活性剤、成分（Ａ）及び（Ｂ）の双方とは異なるカチオン性界面活性剤、及び両性界面活性剤の界面活性剤；保湿剤；殺菌剤；パール化剤；グリチルリチン酸及びその塩等の抗炎症剤；メントール等の清涼剤；リン酸及びその塩類、クエン酸及びその塩類、乳酸及びその塩類、水酸化ナトリウム、トリエタノールアミン等のｐＨ調整剤；香料；紫外線吸収剤；酸化防止剤；金属イオン封鎖剤（キレート剤）；ピリビニルピロリドン等の皮膜形成性高分子化合物；カオリン、シリカ、タルク等の粉体；色素；顔料；ビタミン類；アミノ酸類；収斂剤；美白剤；動植物抽出物；酸；アルカリ等が挙げられる。 (Other ingredients)
The cosmetic composition of the present invention may contain components other than the above-mentioned components (A) to (H). Other components include lower alcohols such as ethanol; polyhydric alcohols; oily components other than component (F); anionic surfactants, and cationic surfactants different from both components (A) and (B). , And amphoteric surfactants; moisturizers; bactericides; pearlizing agents; anti-inflammatory agents such as glycyrrhizinic acid and its salts; refreshing agents such as menthol; phosphoric acid and its salts, citric acid and its salts, PH adjuster such as lactic acid and its salts, sodium hydroxide, triethanolamine; fragrance; ultraviolet absorber; antioxidant; metal ion sequestering agent (chelating agent); film-forming polymer compound such as pyrivinylpyrrolidone; kaolin , Silica, talc and other powders; pigments; pigments; vitamins; amino acids; astringents; whitening agents; animal and plant extracts; acids; alkalis and the like.
　（化粧料組成物の他の詳細）
　本発明の化粧料組成物は、乳化化粧料組成物であることが好ましい。成分（Ｆ）等の油性成分を配合することにより、化粧料組成物を乳化化粧料組成物とすることができる。上記乳化化粧料組成物は、水中油（Ｏ／Ｗ）型の乳化化粧料組成物であることが好ましい。 (Other details of cosmetic composition)
The cosmetic composition of the present invention is preferably an emulsified cosmetic composition. By blending an oily component such as the component (F), the cosmetic composition can be made into an emulsified cosmetic composition. The emulsified cosmetic composition is preferably an oil-in-water (O / W) type emulsified cosmetic composition.
　本発明の化粧料組成物は、毛髪化粧料組成物であってもよく、皮膚化粧料組成物であってもよい。上記毛髪化粧料組成物としては、ヘアトリートメント及び整髪剤等が挙げられる。上記皮膚化粧料組成物としては、ボディクリーム及びフェイスクリーム等が挙げられる。 The cosmetic composition of the present invention may be a hair cosmetic composition or a skin cosmetic composition. Examples of the hair cosmetic composition include hair treatments and hair styling products. Examples of the skin cosmetic composition include body cream and face cream.
　毛髪に塗布することによって本発明の効果がより一層効果的に発揮されることから、本発明の化粧料組成物は、毛髪化粧料組成物であることが好ましく、乳化毛髪化粧料組成物であることがより好ましい。 Since the effect of the present invention is more effectively exhibited by applying it to hair, the cosmetic composition of the present invention is preferably a hair cosmetic composition, and is an emulsified hair cosmetic composition. Is more preferable.
　本発明の化粧料組成物は、塗布対象に塗布された後、洗い流して用いられることが好ましい。本発明の化粧料組成物は、毛髪に塗布された後、洗い流して用いられる毛髪化粧料組成物であることがより好ましい。本発明の化粧料組成物は、ヘアトリートメントであることが好ましい。 It is preferable that the cosmetic composition of the present invention is applied to an object to be applied and then washed away before use. The cosmetic composition of the present invention is more preferably a hair cosmetic composition that is applied to the hair and then washed away. The cosmetic composition of the present invention is preferably a hair treatment.
　本発明の化粧料組成物の製造方法として、公知の化粧料組成物の製造方法を採用することができる。本発明の化粧料組成物の製造方法としては、各成分をパドルミキサー等で撹拌して均一化する方法等が挙げられる。 As a method for producing a cosmetic composition of the present invention, a known method for producing a cosmetic composition can be adopted. Examples of the method for producing the cosmetic composition of the present invention include a method of stirring and homogenizing each component with a paddle mixer or the like.
　以下、本発明について、実施例及び比較例を挙げて具体的に説明する。本発明は、以下の実施例のみに限定されない。 Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited to the following examples.
　実施例及び比較例で用いた主な成分は下記のとおりである。 The main components used in the examples and comparative examples are as follows.
　（成分（Ａ））
　ベヘントリモニウムクロリド：商品名「ＧＥＮＡＭＩＮ　ＫＤＭＰ」、クラリアント社製、ベヘニン酸塩化ジメチルトリメチルアンモニウム
　ステアルトリモニウムクロリド：商品名「コータミン８６Ｗ」、花王社製、ステアリン酸塩化ジメチルトリメチルアンモニウム (Ingredient (A))
Behentrimonium chloride: trade name "GENAMIN KDMP", manufactured by Clariant, dimethyltrimethylammonium behenated Stealtrimonium chloride: trade name "Cotamin 86W", manufactured by Kao, dimethyltrimethylammonium stearate
　（成分（Ｂ））
　パルミタミドプロピルトリモニウムクロリド：商品名「ＶＡＲＩＳＯＦＴ　ＰＡＴＣ」、エボニックジャパン社製 (Component (B))
Palmitamid Propyl Trimonium Chloride: Product Name "VARISOFT PATC", manufactured by Evonik Japan
　（成分（Ｃ））
　ジステアリン酸ポリグリセリル－１０（１）：商品名「サンソフトＱ１８２Ｓ－Ｃ」、太陽化学社製、ＨＬＢ値：１１
　ジステアリン酸ポリグリセリル－１０（２）：商品名「サンソフトＱ１８２Ｙ－Ｃ」、太陽化学社製、ＨＬＢ値：１１．１
　トリオレイン酸ポリグリセリル－５：商品名「サンソフトＡ－１７３Ｅ－Ｃ」、太陽化学社製、ＨＬＢ値：７．１
　ジオレイン酸ポリグリセリル－１０：商品名「サンソフトＱ１７２Ｙ－Ｃ」、太陽化学社製、ＨＬＢ値：１２．３
　トリラウリン酸ポリグリセリル－１０：商品名「サンソフトＱ１２３Ｙ－Ｃ」、太陽化学社製、ＨＬＢ値：８．３
　ペンタステアリン酸ポリグリセリル－１０：商品名「サンソフトＱ１８５－Ｓ－Ｃ」、太陽化学社製、ＨＬＢ値：７ (Component (C))
Polyglyceryl distearate-10 (1): Product name "Sunsoft Q182SC", manufactured by Taiyo Kagaku Co., Ltd., HLB value: 11
Polyglyceryl distearate-10 (2): Trade name "Sunsoft Q182Y-C", manufactured by Taiyo Kagaku Co., Ltd., HLB value: 11.1
Polyglyceryl trioleate-5: Product name "Sunsoft A-173E-C", manufactured by Taiyo Kagaku Co., Ltd., HLB value: 7.1
Polyglyceryl dioleate-10: Product name "Sunsoft Q172Y-C", manufactured by Taiyo Kagaku Co., Ltd., HLB value: 12.3
Polyglyceryl trilaurate-10: Product name "Sunsoft Q123Y-C", manufactured by Taiyo Kagaku Co., Ltd., HLB value: 8.3
Polyglyceryl pentastearate-10: Product name "Sunsoft Q185-SC", manufactured by Taiyo Kagaku Co., Ltd., HLB value: 7
　（成分（Ｆ））
　高重合ジメチルポリシロキサン（１０万ｍＰａ・ｓ）：商品名「ＤＯＷＳＩＬ　ＢＹ１１－０２６」、ダウ・東レ社製、２５℃における粘度：約１０万ｍＰａ・ｓ
　高重合ジメチルポリシロキサン（１００万ｍＰａ・ｓ）：商品名「ＴＳＦ４５１－１００ＭＡ」、モメンティブ・パフォーマンス・マテリアルズ社製、２５℃における粘度：約１００万ｍＰａ・ｓ
　高重合ジメチルポリシロキサン（１８００万ｍＰａ・ｓ）：商品名「ＸＦ４９-８１１」、モメンティブ・パフォーマンス・マテリアルズ社製、２５℃における粘度：約１８００万ｍＰａ・ｓ
　アミノ変性シリコーン：商品名「ＢＥＬＳＩＬ　ＡＤＭ　１６５０」、旭化成ワッカー社製
　ジメチルポリシロキサン：商品名「ＤＯＷ　ＣＯＲＮＩＮＧ　ＴＯＲＡＹ　ＳＨ　２００　Ｃ　ＦＬＵＩＤ　２０　ＣＳ」、ダウ・東レ社製、２５℃における粘度：２０ｍＰａ・ｓ (Component (F))
Highly polymerized dimethylpolysiloxane (100,000 mPa · s): Trade name "DOWNSIL BY11-026", manufactured by Dow Toray Co., Ltd., viscosity at 25 ° C: about 100,000 mPa · s
Highly polymerized dimethylpolysiloxane (1 million mPa · s): Trade name "TSF451-100MA", manufactured by Momentive Performance Materials, Inc., viscosity at 25 ° C: approx. 1 million mPa · s
Highly polymerized dimethylpolysiloxane (18 million mPa · s): Trade name "XF49-811", manufactured by Momentive Performance Materials, Inc., viscosity at 25 ° C: approx. 18 million mPa · s
Amino-modified silicone: trade name "BELSIL ADM 1650", manufactured by Asahi Kasei Wacker dimethylpolysiloxane: trade name "DOWN CORNING TORAY SH 200 C FLUID 20 CS", manufactured by Dow Toray, viscosity at 25 ° C: 20 mPa · s
　（成分（Ｇ））
　ポリクオタニウム－６７：商品名「ＳｏｆｔＣＡＴ　Ｐｏｌｙｍｅｒ　ＳＬ－３０」、ダウ・ケミカル社製 (Ingredient (G))
Polyquaternium-67: Product name "SoftCAT Polymer SL-30", manufactured by Dow Chemical Co., Ltd.
　（その他）
　ポリクオタニウム－１０：商品名「カチナール　ＨＣ－２００」、東邦化学工業社製 (others)
Polyquaternium-10: Product name "Kachinal HC-200", manufactured by Toho Chemical Industry Co., Ltd.
　（実施例１～２７及び比較例１～７）
　下記の表１～５に示す配合成分を配合（配合単位は質量％）し、化粧料組成物（毛髪化粧料組成物）を調製した。表中の配合量（毛髪化粧料組成物１００質量％中の配合量）は、純分量（単位：質量％）で示した。 (Examples 1 to 27 and Comparative Examples 1 to 7)
A cosmetic composition (hair cosmetic composition) was prepared by blending the compounding ingredients shown in Tables 1 to 5 below (the compounding unit is mass%). The blending amount in the table (blending amount in 100% by mass of the hair cosmetic composition) is shown as a net content (unit: mass%).
　（評価）
　得られた毛髪化粧料組成物について、以下の評価を行った。評価結果は表中に示した。評価は５名の専門評価員が行った。 (evaluation)
The obtained hair cosmetic composition was evaluated as follows. The evaluation results are shown in the table. The evaluation was carried out by five professional evaluators.
　（試験例１：塗布時の毛髪への塗布性、付着感、コク感）
　毛束（人毛、長さ３０ｃｍ、重さ１０ｇ）を約４０℃のぬるま湯に浸漬した。浸漬後の毛束を軽く絞って水分をある程度除去した後、得られた毛髪化粧料組成物２ｇを手に取り、毛束全体に均一に塗布した。その際の、塗布性、付着感、コク感を下記の基準で評価した。 (Test Example 1: Applyability to hair at the time of application, feeling of adhesion, feeling of richness)
Hair bundles (human hair, length 30 cm, weight 10 g) were immersed in lukewarm water at about 40 ° C. After lightly squeezing the hair bundle after immersion to remove water to some extent, 2 g of the obtained hair cosmetic composition was picked up and applied uniformly to the entire hair bundle. At that time, the coatability, adhesion, and richness were evaluated according to the following criteria.
　＜毛髪への塗布性の評価基準＞
　○（良好）：毛髪化粧料組成物ののびが良く、毛髪上に均一に塗布できる。
　×（不良）：毛髪化粧料組成物ののびが悪く、毛髪上に均一に塗布しにくい。 <Evaluation criteria for applicability to hair>
◯ (Good): The hair cosmetic composition spreads well and can be applied evenly on the hair.
× (Poor): The hair cosmetic composition does not spread well, and it is difficult to apply it evenly on the hair.
　＜塗布時の毛髪への付着感の評価基準＞
　○（良好）：塗布に従って、毛髪化粧料組成物が毛髪に付着して、手の中から無くなっていく感触がある。
　×（不良）：塗布する際に、毛髪化粧料組成物が手の中でのびるものの、毛髪に十分付着せず、手の中に残り続ける感触がある。 <Evaluation criteria for adhesion to hair during application>
◯ (Good): There is a feeling that the hair cosmetic composition adheres to the hair and disappears from the hands as it is applied.
X (defective): When applied, the hair cosmetic composition spreads in the hands, but does not sufficiently adhere to the hair, and there is a feeling that it remains in the hands.
　＜塗布時のコク感の評価基準＞
　○（良好）：塗布時にある程度の抵抗感が感じられ、濃度の高い組成物を塗布している実感がある。
　×（不良）：塗布時に抵抗感がほとんど感じられず、濃度の高い組成物を塗布している実感がない。 <Evaluation criteria for richness during application>
◯ (Good): A certain degree of resistance is felt at the time of application, and there is a feeling that a high-concentration composition is applied.
X (defective): Almost no resistance is felt at the time of application, and there is no actual feeling that a high-concentration composition is applied.
　（試験例２：塗布時の毛髪の柔軟感）
　試験例１で毛束に毛髪化粧料組成物を塗布した直後に、毛束中央部を長手方向に折るように軽く握り、その際の、毛束の柔軟感を下記の基準で評価した。塗布時の毛髪の柔軟感は、毛束を約４０℃のぬるま湯に浸漬した後、毛束を軽く絞って水分をある程度除去した、毛髪化粧料組成物を塗布していない毛束（「未塗布の毛束」と称する）と比較して評価した。 (Test Example 2: Softness of hair at the time of application)
Immediately after applying the hair cosmetic composition to the hair bundle in Test Example 1, the central portion of the hair bundle was lightly grasped so as to fold in the longitudinal direction, and the softness of the hair bundle at that time was evaluated according to the following criteria. The softness of the hair at the time of application is that the hair bundle is soaked in lukewarm water at about 40 ° C., and then the hair bundle is lightly squeezed to remove water to some extent. It was evaluated in comparison with (referred to as "hair bundle").
　＜塗布時の毛髪の柔軟感の評価基準＞
　○（良好）：未塗布の毛束と比べて、非常に柔らかくなっている。
　△（やや良好）：未塗布の毛束と比べて、明らかに柔らかくなっている。
　×（不良）：未塗布の毛束と比べて、柔らかさが同等程度又は少し柔らかい程度である。 <Evaluation criteria for hair softness when applied>
○ (Good): Very soft compared to unapplied hair bundles.
Δ (Slightly good): Clearly softer than the unapplied hair bundle.
X (defective): The softness is about the same as or slightly softer than that of the unapplied hair bundle.
　（試験例３：乾燥後の毛髪のまとまり感）
　試験例２で評価した後の毛束を、流水（約４０℃のぬるま湯）で約１分間すすいだ後、ドライヤーで乾燥した。乾燥直後の毛束を目視観察し、下記の基準で評価した。 (Test Example 3: A feeling of cohesiveness of hair after drying)
The hair bundle evaluated in Test Example 2 was rinsed with running water (warm water at about 40 ° C.) for about 1 minute, and then dried with a dryer. The hair bundle immediately after drying was visually observed and evaluated according to the following criteria.
　＜乾燥後の毛髪のまとまり感の評価基準＞
　○（良好）：毛束の毛先が広がっておらず、かつ、毛束全体としても広がっていない。
　△（やや良好）：毛束の毛先は広がっているものの、毛束全体としては広がっていない。
　×（不良）：毛束が全体的に明らかに広がっている。 <Evaluation criteria for the feeling of cohesiveness of hair after drying>
○ (Good): The tips of the hair bundles have not spread, and the hair bundles as a whole have not spread.
Δ (Slightly good): Although the tips of the hair bundles are widened, the hair bundles as a whole are not spread.
× (defective): The hair bundle is clearly spread as a whole.
　（試験例４：乾燥後の毛髪のさらさら感）
　試験例３で評価した後の毛束の上部から下部方向に指を通して感触を確認して、下記の基準で評価した。 (Test Example 4: Smooth feeling of hair after drying)
After the evaluation in Test Example 3, the feel was confirmed by passing a finger from the upper part to the lower part of the hair bundle, and the evaluation was made according to the following criteria.
　＜乾燥後の毛髪のさらさら感の評価基準＞
　○（良好）：指が引っ掛かるような感触がなく、指どおりが良好である。
　×（不良）：指が引っ掛かるような感触があり、指どおりが不良である。 <Evaluation criteria for the silky feel of hair after drying>
○ (Good): There is no feeling that the finger is caught, and the finger passage is good.
× (Defective): There is a feeling that the finger is caught, and the finger passage is poor.
　（試験例５：乾燥後の毛髪の柔軟感）
　試験例４で評価した後の毛束の毛束中央部を長手方向に折るように軽く握り、その際の、毛束の柔軟感を下記の基準で評価した。乾燥後の毛髪の柔軟感は、試験例２で作製した未塗布の毛束をドライヤーで乾燥した毛束（「未塗布の乾燥毛束」と称する）と比較して評価した。 (Test Example 5: Softness of hair after drying)
After the evaluation in Test Example 4, the central portion of the hair bundle was lightly grasped so as to fold in the longitudinal direction, and the softness of the hair bundle at that time was evaluated according to the following criteria. The softness of the dried hair was evaluated by comparing the unapplied hair bundle prepared in Test Example 2 with the hair bundle dried by a dryer (referred to as "uncoated dried hair bundle").
　＜乾燥後の毛髪の柔軟感の評価基準＞
　○（良好）：未塗布の乾燥毛束と比べて、非常に柔らかくなっている。
　△（やや良好）：未塗布の乾燥毛束と比べて、明らかに柔らかくなっている。
　×（不良）：未塗布の乾燥毛束と比べて、柔らかさが同等程度又は少し柔らかい程度である。 <Evaluation criteria for the softness of hair after drying>
○ (Good): Very soft compared to unapplied dry hair bundles.
Δ (Slightly good): Clearly softer than the unapplied dry hair bundle.
X (defective): The softness is about the same as or slightly softer than that of the unapplied dry hair bundle.
　組成及び結果を下記の表１～５に示す。 The composition and results are shown in Tables 1 to 5 below.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
　また、実施例１～２７で得られた化粧料組成物約５ｇを手に取り、腕全体に均一に塗布したところ、化粧料組成物の肌への付着感が良好であり、また、化粧料組成物の伸びが良く、塗布性が良好であった。 Further, when about 5 g of the cosmetic composition obtained in Examples 1 to 27 was picked up and applied evenly to the entire arm, the cosmetic composition adhered well to the skin, and the cosmetic was applied. The composition had good spreadability and good coatability.
　以下に、本発明の化粧料組成物の処方例を示す。 An example of prescribing the cosmetic composition of the present invention is shown below.
　（処方例１）ヘアマスク（ヘアトリートメント）
ベヘントリモニウムクロリド　　　　　　　　　　　　　　　３．０質量％
パルミタミドプロピルトリモニウムクロリド　　　　　　　　１．０質量％
ジステアリン酸ポリグリセリル－１０　　　　　　　　　　　０．５質量％
ステアリルアルコール　　　　　　　　　　　　　　　　　　８．０質量％
高重合ジメチルポリシロキサン（１０万ｍＰａ・ｓ）　　　　１．５質量％
アミノ変性シリコーン　　　　　　　　　　　　　　　　　　１．０質量％
ジメチルポリシロキサン（２０ｍＰａ・ｓ）　　　　　　　　３．０質量％
アルガンオイル　　　　　　　　　　　　　　　　　　　　　１．０質量％
イソノナン酸イソノニル　　　　　　　　　　　　　　　　　２．０質量％
ポリクオタニウム－１０　　　　　　　　　　　　　　　　　０．３質量％
グリセリン　　　　　　　　　　　　　　　　　　　　　　　３．０質量％
プロピレングリコール　　　　　　　　　　　　　　　　　　１．０質量％
加水分解コンキオリン液　　　　　　　　　　　　　　　　　０．５質量％
クエン酸（ｐＨ調整剤）　　　　　　　　　　　　　　　　　　　　　適量
精製水　　　　　　　　　　　　　　　　　　　　　　　　　　　　　残量
合計　　　　　　　　　　　　　　　　　　　　　　　　　　１００質量％ (Prescription example 1) Hair mask (hair treatment)
Behentrimonium chloride 3.0% by mass
Palmitamid propyltrimonium chloride 1.0% by mass
Polyglyceryl distearate-10 0.5% by mass
Stearyl alcohol 8.0% by mass
Highly polymerized dimethylpolysiloxane (100,000 mPa · s) 1.5% by mass
Amino modified silicone 1.0% by mass
Dimethylpolysiloxane (20 mPa · s) 3.0% by mass
Argan oil 1.0% by mass
Isononyl isononanoate 2.0% by mass
Polyquaternium-10 0.3% by mass
Glycerin 3.0% by mass
Propylene glycol 1.0% by mass
Hydrolyzed conchiolin solution 0.5% by mass
Citric acid (pH adjuster) Appropriate amount Purified water Total remaining amount 100% by mass
　（処方例２）ヘアマスク（ヘアトリートメント）
ベヘントリモニウムクロリド　　　　　　　　　　　　　　　２．５質量％
パルミタミドプロピルトリモニウムクロリド　　　　　　　　０．５質量％
ジステアリン酸ポリグリセリル－１０　　　　　　　　　　　０．５質量％
ステアリルアルコール　　　　　　　　　　　　　　　　　１０．０質量％
高重合ジメチルポリシロキサン（１０万ｍＰａ・ｓ）　　　　１．５質量％
アミノ変性シリコーン　　　　　　　　　　　　　　　　　　１．０質量％
ジメチルポリシロキサン（２０ｍＰａ・ｓ）　　　　　　　　３．０質量％
ダイマージリノール酸ダイマージリノレイル　　　　　　　　１．０質量％
ＰＰＧ－３カプリリルエーテル　　　　　　　　　　　　　　１．０質量％
イソノナン酸イソノニル　　　　　　　　　　　　　　　　　２．０質量％
ポリクオタニウム－６７　　　　　　　　　　　　　　　　　０．３質量％
グリセリン　　　　　　　　　　　　　　　　　　　　　　　２．０質量％
プロピレングリコール　　　　　　　　　　　　　　　　　　０．５質量％
メドウフォーム－δ－ラクトン　　　　　　　　　　　　　　０．３質量％
シクロヘキサンジカルボン酸ビスエトキシジグリコール　　　１．０質量％
クエン酸（ｐＨ調整剤）　　　　　　　　　　　　　　　　　　　　　適量
精製水　　　　　　　　　　　　　　　　　　　　　　　　　　　　　残量
合計　　　　　　　　　　　　　　　　　　　　　　　　　　１００質量％ (Prescription example 2) Hair mask (hair treatment)
Behentrimonium chloride 2.5% by mass
Palmitamid propyltrimonium chloride 0.5% by mass
Polyglyceryl distearate-10 0.5% by mass
Stearyl alcohol 10.0% by mass
Highly polymerized dimethylpolysiloxane (100,000 mPa · s) 1.5% by mass
Amino modified silicone 1.0% by mass
Dimethylpolysiloxane (20 mPa · s) 3.0% by mass
Dimer dilinoleic acid Dimer dilinoleil 1.0% by mass
PPG-3 Caprylyl Ether 1.0% by mass
Isononyl isononanoate 2.0% by mass
Polyquaternium-67 0.3% by mass
Glycerin 2.0% by mass
Propylene glycol 0.5% by mass
Meadowfoam-δ-lactone 0.3% by mass
Cyclohexanedicarboxylic acid bisethoxydiglycol 1.0% by mass
Citric acid (pH adjuster) Appropriate amount Purified water Total remaining amount 100% by mass
　（処方例３）ヘアコンディショナー（ヘアトリートメント）
ベヘントリモニウムクロリド　　　　　　　　　　　　　　　１．５質量％
パルミタミドプロピルトリモニウムクロリド　　　　　　　　０．３質量％
ジステアリン酸ポリグリセリル－１０　　　　　　　　　　　０．５質量％
ステアリルアルコール　　　　　　　　　　　　　　　　　　５．０質量％
高重合ジメチルポリシロキサン（１０万ｍＰａ・ｓ）　　　　１．０質量％
ジメチルポリシロキサン（２０ｍＰａ・ｓ）　　　　　　　　２．０質量％
クランベアビシニカ種子油　　　　　　　　　　　　　　　　１．０質量％
トリ（カプリル酸／カプリン酸）グリセリル　　　　　　　　１．０質量％
ＰＰＧ－３カプリリルエーテル　　　　　　　　　　　　　　１．０質量％
イソノナン酸イソノニル　　　　　　　　　　　　　　　　　２．０質量％
ポリクオタニウム－６７　　　　　　　　　　　　　　　　　０．３質量％
グリセリン　　　　　　　　　　　　　　　　　　　　　　　２．０質量％
プロピレングリコール　　　　　　　　　　　　　　　　　　０．５質量％
シクロヘキサンジカルボン酸ビスエトキシジグリコール　　　１．０質量％
クエン酸（ｐＨ調整剤）　　　　　　　　　　　　　　　　　　　　　適量
精製水　　　　　　　　　　　　　　　　　　　　　　　　　　　　　残量
合計　　　　　　　　　　　　　　　　　　　　　　　　　　１００質量％ (Prescription example 3) Hair conditioner (hair treatment)
Behentrimonium chloride 1.5% by mass
Palmitamid propyltrimonium chloride 0.3% by mass
Polyglyceryl distearate-10 0.5% by mass
Stearyl alcohol 5.0% by mass
Highly polymerized dimethylpolysiloxane (100,000 mPa · s) 1.0% by mass
Dimethylpolysiloxane (20 mPa · s) 2.0% by mass
Clan Bear Bicinica Seed Oil 1.0% by Mass
Tri (caprylic acid / capric acid) glyceryl 1.0% by mass
PPG-3 Caprylyl Ether 1.0% by mass
Isononyl isononanoate 2.0% by mass
Polyquaternium-67 0.3% by mass
Glycerin 2.0% by mass
Propylene glycol 0.5% by mass
Cyclohexanedicarboxylic acid bisethoxydiglycol 1.0% by mass
Citric acid (pH adjuster) Appropriate amount Purified water Total remaining amount 100% by mass
　（処方例４）ボディケアマスク（洗い流すタイプのボディ用トリートメント）
ベヘントリモニウムクロリド　　　　　　　　　　　　　　　１．５質量％
パルミタミドプロピルトリモニウムクロリド　　　　　　　　０．３質量％
ジステアリン酸ポリグリセリル－１０　　　　　　　　　　　１．０質量％
ステアリルアルコール　　　　　　　　　　　　　　　　　１０．０質量％
シア脂　　　　　　　　　　　　　　　　　　　　　　　　　３．０質量％
ダイマージリノール酸ダイマージリノレイル　　　　　　　　１．０質量％
トリ（カプリル酸／カプリン酸）グリセリル　　　　　　　　５．０質量％
ＰＰＧ－３カプリリルエーテル　　　　　　　　　　　　　　１．０質量％
イソノナン酸イソノニル　　　　　　　　　　　　　　　　　２．０質量％
ポリクオタニウム－６７　　　　　　　　　　　　　　　　　０．３質量％
グリセリン　　　　　　　　　　　　　　　　　　　　　　　２．０質量％
プロピレングリコール　　　　　　　　　　　　　　　　　　０．５質量％
クエン酸（ｐＨ調整剤）　　　　　　　　　　　　　　　　　　　　　適量
精製水　　　　　　　　　　　　　　　　　　　　　　　　　　　　　残量
合計　　　　　　　　　　　　　　　　　　　　　　　　　　１００質量％ (Prescription example 4) Body care mask (wash-out type body treatment)
Behentrimonium chloride 1.5% by mass
Palmitamid propyltrimonium chloride 0.3% by mass
Polyglyceryl distearate-10 1.0% by mass
Stearyl alcohol 10.0% by mass
Shea butter 3.0% by mass
Dimer dilinoleic acid Dimer dilinoleil 1.0% by mass
Tri (caprylic acid / capric acid) glyceryl 5.0% by mass
PPG-3 Caprylyl Ether 1.0% by mass
Isononyl isononanoate 2.0% by mass
Polyquaternium-67 0.3% by mass
Glycerin 2.0% by mass
Propylene glycol 0.5% by mass
Citric acid (pH adjuster) Appropriate amount Purified water Total remaining amount 100% by mass

Claims (11)

  1. 　下記成分Ａと、下記成分Ｂと、下記成分Ｃと、下記成分Ｄと、下記成分Ｅとを含む、化粧料組成物。
    　成分Ａ：下記式（１）で表される化合物
    　　Ｒ１－Ｎ＋（ＣＨ３）３Ｘ－　　　（１）
    　（前記式（１）中、Ｒ１は、直鎖状又は分岐鎖状の炭素数１２～２２の脂肪族炭化水素基を表し、Ｘ－は、Ｃｌ－又はＢｒ－を表す。）
    　成分Ｂ：下記式（２）で表される化合物
    　　Ｒ２－Ｃ（＝Ｏ）－ＮＨ－Ｃ３Ｈ６－Ｎ＋（ＣＨ３）３Ｚ－　　　（２）
    　（前記式（２）中、Ｒ２は、直鎖状又は分岐鎖状の炭素数１１～２１の脂肪族炭化水素基を表し、Ｚ－は、Ｃｌ－又はＢｒ－を表す。）
    　成分Ｃ：ポリグリセリンに２～６個の脂肪酸がエステル結合しており、かつグリセリンの平均付加モル数が４～１２であるポリグリセリン脂肪酸エステル
    　成分Ｄ：炭素数１２～２４の脂肪族アルコール
    　成分Ｅ：水     A cosmetic composition containing the following component A, the following component B, the following component C, the following component D, and the following component E.
    Component A: a compound represented by the following formula (1) R 1 -N + ( CH 3) 3 X - (1)
    (In the above formula (1), R 1 represents a linear or branched-chain aliphatic hydrocarbon group having 12 to 22 carbon atoms, and X − represents Cl − or Br − .)
    Component B: a compound represented by the following formula (2) R 2 -C (= O) -NH-C 3 H 6 -N + (CH 3) 3 Z - (2)
    (In the above formula (2), R 2 represents a linear or branched-chain aliphatic hydrocarbon group having 11 to 21 carbon atoms, and Z − represents Cl − or Br − .)
    Component C: Polyglycerin fatty acid ester in which 2 to 6 fatty acids are ester-bonded to polyglycerin and the average number of moles of glycerin added is 4 to 12. Polyglycerin fatty acid ester Component D: Fatty alcohol component E having 12 to 24 carbon atoms :water
  2. 　下記成分Ｆを含む、請求項１に記載の化粧料組成物。
    　成分Ｆ：シリコーン油、エステル油、植物油、及び炭化水素油からなる群より選ばれる油性成分     The cosmetic composition according to claim 1, which comprises the following component F.
    Component F: An oily component selected from the group consisting of silicone oil, ester oil, vegetable oil, and hydrocarbon oil.
  3. 　前記成分Ｆが、前記シリコーン油を含む、請求項２に記載の化粧料組成物。 The cosmetic composition according to claim 2, wherein the component F contains the silicone oil.
  4. 　前記シリコーン油が、下記成分Ｆ１を含む、請求項３に記載の化粧料組成物。
    　成分Ｆ１：２５℃における粘度が１万ｍＰａ・ｓ以上であるシリコーン油、及び２５℃における粘度が１万ｍＰａ・ｓ未満であるアミノ変性シリコーンからなる群より選ばれるシリコーン油     The cosmetic composition according to claim 3, wherein the silicone oil contains the following component F1.
    Component F1: Silicone oil selected from the group consisting of a silicone oil having a viscosity at 25 ° C. of 10,000 mPa · s or more and an amino-modified silicone having a viscosity at 25 ° C. of less than 10,000 mPa · s.
  5. 　前記成分Ｆが、前記エステル油を含み、
    　前記エステル油が、下記成分Ｆ２を含む、請求項２～４のいずれか１項に記載の化粧料組成物。
    　成分Ｆ２：ダイマー酸エステル     The component F contains the ester oil and contains
    The cosmetic composition according to any one of claims 2 to 4, wherein the ester oil contains the following component F2.
    Ingredient F2: Dimer acid ester
  6. 　下記成分Ｇを含む、請求項１～５のいずれか１項に記載の化粧料組成物。
    　成分Ｇ：炭素数１０以上のアルキル基を有するカチオン化セルロース     The cosmetic composition according to any one of claims 1 to 5, which comprises the following component G.
    Component G: Cationized cellulose having an alkyl group having 10 or more carbon atoms
  7. 　下記成分Ｈを含む、請求項１～６のいずれか１項に記載の化粧料組成物。
    　成分Ｈ：ポリプロピレングリコールアルキルエーテル     The cosmetic composition according to any one of claims 1 to 6, which comprises the following component H.
    Component H: Polypropylene glycol alkyl ether
  8. 　前記成分Ａの含有量が、０．５質量％以上、５．０質量％以下である、請求項１～７のいずれか１項に記載の化粧料組成物。 The cosmetic composition according to any one of claims 1 to 7, wherein the content of the component A is 0.5% by mass or more and 5.0% by mass or less.
  9. 　前記成分Ｄの含有量が、３．０質量％以上、２０．０質量％以下である、請求項１～８のいずれか１項に記載の化粧料組成物。 The cosmetic composition according to any one of claims 1 to 8, wherein the content of the component D is 3.0% by mass or more and 20.0% by mass or less.
  10. 　毛髪化粧料組成物である、請求項１～９のいずれか１項に記載の化粧料組成物。 The cosmetic composition according to any one of claims 1 to 9, which is a hair cosmetic composition.
  11. 　塗布対象に塗布された後、洗い流して用いられる、請求項１～１０のいずれか１項に記載の化粧料組成物。 The cosmetic composition according to any one of claims 1 to 10, which is used after being applied to an application target and then washed away.
PCT/JP2021/011648 2020-03-24 2021-03-22 Cosmetic composition WO2021193503A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002234824A (en) * 2001-02-09 2002-08-23 Sakamoto Yakuhin Kogyo Co Ltd Transparent hair-treatment agent
JP2012056926A (en) * 2010-09-13 2012-03-22 Toho Chem Ind Co Ltd Composition for hair
JP2016013984A (en) * 2014-07-02 2016-01-28 日本精化株式会社 Hair cosmetics

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2000274799A1 (en) * 2000-09-13 2002-03-26 The Procter And Gamble Company Concentrated conditioning composition
JP4883261B2 (en) * 2005-06-27 2012-02-22 ライオン株式会社 Hair cosmetics
JP2010013405A (en) * 2008-07-04 2010-01-21 Kracie Home Products Ltd Hair cosmetic
EP2710997A4 (en) * 2011-05-18 2015-01-21 Daicel Corp Oil composition for cosmetics material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002234824A (en) * 2001-02-09 2002-08-23 Sakamoto Yakuhin Kogyo Co Ltd Transparent hair-treatment agent
JP2012056926A (en) * 2010-09-13 2012-03-22 Toho Chem Ind Co Ltd Composition for hair
JP2016013984A (en) * 2014-07-02 2016-01-28 日本精化株式会社 Hair cosmetics

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