WO2021192745A1 - 分離膜 - Google Patents

分離膜 Download PDF

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Publication number
WO2021192745A1
WO2021192745A1 PCT/JP2021/005888 JP2021005888W WO2021192745A1 WO 2021192745 A1 WO2021192745 A1 WO 2021192745A1 JP 2021005888 W JP2021005888 W JP 2021005888W WO 2021192745 A1 WO2021192745 A1 WO 2021192745A1
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WIPO (PCT)
Prior art keywords
separation
separation membrane
group
mixed liquid
water
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PCT/JP2021/005888
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English (en)
French (fr)
Japanese (ja)
Inventor
慎 片桐
真哉 西山
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Nitto Denko Corp
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Nitto Denko Corp
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Priority to EP21776506.4A priority Critical patent/EP4129456A4/en
Priority to CN202180015821.0A priority patent/CN115151335A/zh
Priority to US17/912,771 priority patent/US20230130077A1/en
Priority to JP2022509408A priority patent/JPWO2021192745A1/ja
Publication of WO2021192745A1 publication Critical patent/WO2021192745A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/10—Spiral-wound membrane modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/362—Pervaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/363—Vapour permeation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0079—Manufacture of membranes comprising organic and inorganic components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/107—Organic support material
    • B01D69/1071—Woven, non-woven or net mesh
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1216—Three or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/148—Organic/inorganic mixed matrix membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/028—Molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/38—Polyalkenylalcohols; Polyalkenylesters; Polyalkenylethers; Polyalkenylaldehydes; Polyalkenylketones; Polyalkenylacetals; Polyalkenylketals
    • B01D71/381—Polyvinylalcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/521—Aliphatic polyethers
    • B01D71/5211—Polyethylene glycol or polyethyleneoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/52—Polyethers
    • B01D71/522—Aromatic polyethers
    • B01D71/5222—Polyetherketone, polyetheretherketone, or polyaryletherketone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/54—Polyureas; Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/448—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by pervaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/04—Characteristic thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/06—Surface irregularities
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/34—Organic compounds containing oxygen

Definitions

  • the present invention relates to a separation membrane.
  • an osmotic vaporization method pervasion method
  • a vapor permeation method a method for separating water from a mixed liquid containing alcohol and water. These methods are particularly suitable for separating water from azeotropic mixtures such as mixed liquids containing ethanol and water.
  • the osmotic vaporization method is also characterized in that it is not necessary to vaporize the mixed liquid before the treatment.
  • Examples of the separation membrane used in the osmotic vaporization method include a composite membrane in which a separation functional layer is formed on a porous support.
  • an intermediate layer may be arranged between the separation function layer and the porous support in order to reduce the film thickness of the separation function layer (for example, Patent Document 1).
  • an object of the present invention is to provide a separation membrane in which defects in the separation functional layer are reduced and the decrease in the flux of the permeated fluid is suppressed.
  • the separation function layer, the intermediate layer and the porous support are provided in this order in the stacking direction.
  • the thickness of the intermediate layer is 0.1 ⁇ m to 2.5 ⁇ m.
  • a separation membrane in which the total value of the thickness of the intermediate layer and the thickness of the separation function layer is less than 4.0 ⁇ m.
  • the separation function layer, the intermediate layer and the porous support are provided in this order in the stacking direction.
  • the intermediate layer contains a polymer compound and contains Provided is a separation membrane in which the distance Ra between the Hansen solubility parameter of the polymer compound and the Hansen solubility parameter of H 2 O is less than 19 MPa 1/2.
  • the present invention it is possible to provide a separation membrane in which defects in the separation functional layer are reduced and the decrease in the flux of the permeated fluid is suppressed.
  • the intermediate layer contains a polymer compound, and the distance Ra between the Hansen solubility parameter of the polymer compound and the Hansen solubility parameter of H 2 O is less than 19 MPa 1/2.
  • the polymeric compound comprises at least one selected from the group consisting of polyether blockamides, polyvinyl alcohols, polyethers and polyurethanes.
  • the above polymeric compound comprises a polyether block amide.
  • the separation functional layer contains polyimide.
  • the polyimide contains a structural unit represented by the following formula (1).
  • A is a linking group having a solubility parameter according to the Fedors method greater than 5.0 (cal / cm 3 ) 1/2
  • B has a solubility parameter according to the Fedors method of 8.56 (cal / cm).
  • Linking groups larger than 1/2 R 1 to R 6 are independent of each other, hydrogen atom, halogen atom, hydroxy group, sulfonic acid group, alkoxy group having 1 to 30 carbon atoms, or carbon number. It is a hydrocarbon group of 1 to 30, and Ar 1 and Ar 2 are divalent aromatic groups.
  • Ar 1 and Ar 2 are phenylene groups which may have a substituent, they are represented by the following formula (2).
  • R 7 to R 10 are independent of each other, a hydrogen atom, a halogen atom, a hydroxy group, a sulfonic acid group, an alkoxy group having 1 to 30 carbon atoms, or a hydrocarbon having 1 to 30 carbon atoms. It is a group.
  • the separating functional layer contains a matrix and a filler dispersed in the matrix.
  • the thickness of the separation functional layer is 0.1 ⁇ m to 2.5 ⁇ m.
  • the separation membrane is used to separate water from a mixed liquid containing alcohol and water.
  • water that permeates the separation membrane when the space adjacent to the other surface of the separation membrane is depressurized in a state where a mixed liquid consisting of ethanol and water is in contact with one surface of the separation membrane.
  • the flux is 0.40 kg / m 2 / hr or more.
  • the concentration of ethanol in the above-mentioned mixed liquid is 50 vol% when the temperature of the mixed liquid is measured at 20 ° C., and the temperature of the mixed liquid to be brought into contact with the separation membrane is 60 ° C., and the temperature of the separation membrane is 60 ° C.
  • the space adjacent to the other surface is depressurized so that the pressure in the space is 100 kPa smaller than the atmospheric pressure in the measurement environment.
  • the water separation coefficient ⁇ with respect to ethanol is 20 or more.
  • the separation coefficient ⁇ is measured by reducing the pressure in the space adjacent to the other surface of the separation membrane in a state where the mixed liquid consisting of ethanol and water is in contact with one surface of the separation membrane, and the ethanol in the mixed liquid is measured.
  • the concentration of the mixed liquid is 50 vol% when the temperature of the mixed liquid is measured at 20 ° C., the temperature of the mixed liquid to be brought into contact with the separation membrane is 60 ° C., and the space adjacent to the other surface of the separation membrane is The pressure in the space is reduced to be 100 kPa smaller than the atmospheric pressure in the measurement environment.
  • the separation membrane 10 of the present embodiment includes the separation function layer 1, the intermediate layer 2, and the porous support 3 in this order in the stacking direction.
  • the separation function layer 1 can preferentially or selectively permeate water contained in the mixed liquid, for example.
  • the intermediate layer 2 is in direct contact with, for example, the separation function layer 1 and the porous support 3.
  • the thickness of the intermediate layer 2 is 0.1 ⁇ m to 2.5 ⁇ m.
  • the thickness of the intermediate layer 2 is preferably 2.3 ⁇ m or less, more preferably 2.0 ⁇ m or less, still more preferably 1.5 ⁇ m or less, and particularly preferably 1.0 ⁇ m or less.
  • the thickness of the intermediate layer 2 may be 0.5 ⁇ m or more.
  • the thickness of the intermediate layer 2 can be specified by, for example, the following method. First, the cross section of the separation membrane 10 is observed with a scanning electron microscope. Using the obtained electron microscope image, the distance between a pair of main surfaces of the intermediate layer 2 facing each other is measured at an arbitrary plurality of points (at least three points). The average value of the obtained values can be regarded as the thickness of the intermediate layer 2.
  • the main surface means the surface having the widest area of the intermediate layer 2.
  • the total value T of the thickness of the intermediate layer 2 and the thickness of the separation function layer 1 is less than 4.0 ⁇ m.
  • the thickness of the separation functional layer 1 is not particularly limited, and is, for example, 0.1 ⁇ m to 2.5 ⁇ m, preferably 2.3 ⁇ m or less, and more preferably 2. It is 0.0 ⁇ m or less, more preferably 1.8 ⁇ m or less, and particularly preferably 1.5 ⁇ m or less.
  • the thickness of the separation function layer 1 may be 0.5 ⁇ m or more.
  • the thickness of the separating functional layer 1 can be specified for the intermediate layer 2 by the method described above.
  • the total value T of the thickness of the intermediate layer 2 and the thickness of the separation function layer 1 is preferably 3.5 ⁇ m or less, more preferably 3.3 ⁇ m or less, still more preferably 3.0 ⁇ m or less, and particularly preferably. Is 2.8 ⁇ m or less, and particularly preferably 2.5 ⁇ m or less.
  • the lower limit of the total value T is not particularly limited, and is, for example, 0.5 ⁇ m, preferably 1.0 ⁇ m, and more preferably 1.5 ⁇ m.
  • the ratio R of the thickness of the separating functional layer 1 to the thickness of the intermediate layer 2 is not particularly limited, and is, for example, 10 or less, preferably 5.0 or less, more preferably 3.0 or less, and further. It is preferably 2.0 or less, and particularly preferably 1.0 or less.
  • the lower limit of the ratio R is not particularly limited, and may be, for example, 0.1, and in some cases, 0.3, 0.5, or 0.6.
  • the separation function layer 1 has, for example, a matrix 4 and a filler 5.
  • the filler 5 is dispersed in the matrix 4 and embedded in the matrix 4. In the form shown in FIG. 1, all the fillers 5 are separated from each other. However, the filler 5 may be partially agglomerated.
  • the separation function layer 1 does not have to contain the filler 5.
  • the matrix 4 preferably contains polyimide.
  • Examples of the polyimide contained in the matrix 4 include a polyimide (P) containing a structural unit represented by the following formula (1).
  • A is, for example, a linking group having a solubility parameter according to the Fedors method greater than 5.0 (cal / cm 3 ) 1/2.
  • the "solubility parameter by the Fedors method” may be referred to as an SP value.
  • the "solubility parameter by the Fedors method” can be calculated from the following formula.
  • ⁇ i is the SP value of the atom or atomic group of the i component.
  • ⁇ ei is the evaporation energy of the atom or atomic group of the i component.
  • ⁇ vi is the molar volume of the atom or atomic group of the i component.
  • ⁇ i [(cal / cm 3 ) 1/2 ] ( ⁇ ei / ⁇ vi) 1/2
  • the SP value of A is preferably 8.5 (cal / cm 3 ) 1/2 or more, more preferably 11.0 (cal / cm 3 ) 1/2 or more, and further preferably 12.0 (12.0 (cal / cm 3) or more. cal / cm 3 ) 1/2 or more.
  • the upper limit of the SP value of A is not particularly limited, but may be, for example, 30.0 (cal / cm 3 ) 1/2 .
  • Preferred examples of the SP value of A are 12.0 (cal / cm 3 ) 1/2 , 12.68 (cal / cm 3 ) 1/2 and the like.
  • A contains, for example, at least one selected from the group consisting of oxygen atoms, nitrogen atoms, sulfur atoms and silicon atoms, preferably at least one selected from the group consisting of oxygen atoms and nitrogen atoms, and particularly preferably.
  • A contains at least one functional group selected from the group consisting of, for example, an ether group, an ester group, a ketone group, a hydroxy group, an amide group, a thioether group and a sulfonyl group, and preferably from the group consisting of an ether group and an ester group. Includes at least one selected.
  • A may contain other groups, for example, a hydrocarbon group, in addition to the above functional groups.
  • the number of carbon atoms of the hydrocarbon group is not particularly limited, but is, for example, 1 to 15.
  • the number of carbon atoms may be 1 to 3 or 6 to 15.
  • the valence of the hydrocarbon group is also unlimited, but is preferably a divalent hydrocarbon group.
  • the divalent hydrocarbon group include a methylene group, an ethylene group, a propane-1,3-diyl group, a propane-2,2-diyl group, a butane-1,4-diyl group, and a pentane-1,5-.
  • Diyl group 2,2-dimethylpropane-1,3-diyl group, 1,4-phenylene group, 2,5-di-tert-butyl-1,4-phenylene group, 1-methyl-1,1-ethanediylbis
  • Examples include a (1,4-phenylene) group and a biphenyl-4,4'-diyl group.
  • at least one hydrogen atom contained in these hydrocarbon groups may be substituted with a halogen atom.
  • A is, for example, a linking group represented by the general formula-OR 19- O- or the general formula-COO-R 20-OOC-.
  • R 19 and R 20 are divalent hydrocarbon groups having 1 to 15 carbon atoms. Examples of the divalent hydrocarbon group include those described above.
  • A does not have to contain the above-mentioned functional group.
  • Examples of such A include an alkylene group.
  • the number of carbon atoms of the alkylene group is not particularly limited, but may be, for example, 1 to 15 or 1 to 5.
  • the alkylene group may be branched-chain, but is preferably linear.
  • the alkylene group may be partially substituted with a halogen atom, but is preferably in an unsubstituted state, that is, the alkylene group itself having a linear or branched state.
  • the number of atoms constituting the bonding chain having the smallest number of atoms is, for example, 2 or more, preferably 4 or more. Yes, more preferably 6-11.
  • the bond chain having the smallest number of atoms may be referred to as the "shortest bond chain".
  • A is an o-phenylene group
  • the number of atoms constituting the shortest bonding chain connecting the two phthalimide structures linked by A is 2.
  • A is a p-phenylene group
  • the number of atoms constituting the shortest bonding chain connecting the two phthalimide structures linked by A is four.
  • A may be one of the linking groups 1 to 26 shown in Tables 1 and 2 below. Tables 1 and 2 also show the chemical structure, SP value, and number of atoms that make up the shortest bond for linking groups 1-26.
  • A is preferably a linking group 11 or a linking group 18, and particularly preferably a linking group 18.
  • the polyimide (P) is easily dissolved in a polar organic solvent such as N-methyl-2-pyrrolidone (NMP) and 1,3-dioxolane, and is easily dissolved in a polar organic solvent such as N-methyl-2-pyrrolidone (NMP). Easy to apply the desired manufacturing method.
  • NMP N-methyl-2-pyrrolidone
  • NMP N-methyl-2-pyrrolidone
  • B is, for example, a linking group having an SP value greater than 8.56 (cal / cm 3 ) 1/2.
  • the SP value of B is preferably 9.0 (cal / cm 3 ) 1/2 or more, more preferably 11.0 (cal / cm 3 ) 1/2 or more, and further preferably 12.0 (12.0 (cal / cm 3) or more. It is cal / cm 3 ) 1/2 or more, and particularly preferably 14.0 (cal / cm 3 ) 1/2 or more.
  • the upper limit of the SP value of B is not particularly limited, but may be, for example, 30.0 (cal / cm 3 ) 1/2 .
  • Preferred examples of the SP value of B are 14.0 (cal / cm 3 ) 1/2 , 14.51 (cal / cm 3 ) 1/2 and the like.
  • B contains, for example, at least one selected from the group consisting of oxygen atoms, nitrogen atoms, sulfur atoms and silicon atoms, preferably at least one selected from the group consisting of oxygen atoms and nitrogen atoms, and particularly preferably.
  • B contains, for example, at least one functional group selected from the group consisting of an ether group, an ester group, a ketone group, a hydroxy group, an amide group, a thioether group and a sulfonyl group, and preferably contains an ether group.
  • B may contain other groups, for example, a hydrocarbon group, in addition to the above functional groups.
  • examples of the hydrocarbon group include those described above for A. B may be the same as or different from A.
  • the number of atoms constituting the bond chain having the smallest number of atoms (the shortest bond chain) among the bond chains connecting Ar 1 and Ar 2 linked by B is, for example, 1 or more. Is.
  • the upper limit of the number of atoms constituting the shortest bond chain is not particularly limited, but is, for example, 12.
  • the number of atoms constituting the shortest bond chain is preferably 1.
  • B may be one of the linking groups 5 to 26 shown in Tables 1 and 2 above.
  • B is preferably a linking group 9, a linking group 16 or a linking group 21, and particularly preferably a linking group 21.
  • R 1 to R 6 are independent of each other, a hydrogen atom, a halogen atom, a hydroxy group, a sulfonic acid group, an alkoxy group having 1 to 30 carbon atoms, or a hydrocarbon having 1 to 30 carbon atoms. It is a group.
  • R 1 to R 6 are preferably hydrogen atoms.
  • the alkoxy group or hydrocarbon group of R 1 to R 6 may be linear or branched chain.
  • the number of carbon atoms of the alkoxy group or the hydrocarbon group is preferably 1 to 20, more preferably 1 to 10, and particularly preferably 1 to 5.
  • Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group and the like.
  • the hydrocarbon group include a methyl group, an ethyl group and a propyl group. At least one hydrogen atom contained in the alkoxy group or the hydrocarbon group may be substituted with a halogen atom.
  • R 2 and R 3 , and R 5 and R 6 may be coupled to each other to form a ring structure.
  • the ring structure is, for example, a benzene ring.
  • Ar 1 and Ar 2 are divalent aromatic groups.
  • the divalent aromatic group contains an aromatic ring.
  • the nitrogen atom having a phthalimide structure is preferably directly bonded to the aromatic ring contained in Ar 1 or the aromatic ring contained in Ar 2.
  • B may be directly bonded to each of the aromatic ring contained in Ar 1 and the aromatic ring contained in Ar 2.
  • the aromatic ring is preferably composed of carbon atoms.
  • the aromatic ring may be a heteroaromatic ring containing a hetero atom such as an oxygen atom, a nitrogen atom, or a sulfur atom.
  • the aromatic ring may be a polycyclic type, but is preferably a monocyclic type.
  • the number of carbon atoms in the aromatic ring is not particularly limited, but may be, for example, 4 to 14 or 6 to 10.
  • aromatic ring examples include a benzene ring, a naphthalene ring, an anthracene ring, a phenanthrene ring, a furan ring, a pyrrole ring, a pyridine ring and a thiophene ring.
  • the aromatic ring may not have a substituent and may have a substituent.
  • substituent of the aromatic ring include a halogen atom, a hydroxy group, a sulfonic acid group, an alkoxy group having 1 to 30 carbon atoms, and a hydrocarbon group having 1 to 30 carbon atoms. Examples of the alkoxy group and the hydrocarbon group include those described above for R 1 to R 6.
  • the aromatic ring has a plurality of substituents, the plurality of substituents may be the same or different from each other.
  • Ar 1 and Ar 2 are preferably a phenylene group which may have a substituent or a naphthalenediyl group which may have a substituent.
  • Ar 1 and Ar 2 may be represented by the following formula (2) when they are phenylene groups which may have a substituent.
  • R 7 to R 10 are independent of each other, a hydrogen atom, a halogen atom, a hydroxy group, a sulfonic acid group, an alkoxy group having 1 to 30 carbon atoms, or a hydrocarbon having 1 to 30 carbon atoms. It is a group. Examples of the alkoxy group and the hydrocarbon group include those described above for R 1 to R 6. R 7 to R 10 are preferably hydrogen atoms. Equation (2) shows a p-phenylene structure.
  • the polyimide having a p-phenylene structure is not sterically bulky as compared with the polyimide having an o-phenylene structure or an m-phenylene structure, and is suitable for improving the separation performance of the separation membrane.
  • the naphthalene diyl group which may have a substituent is, for example, naphthalene-2,6-diyl structure, naphthalene-1,4-diyl structure, naphthalene-1,5-diyl structure or. It has a naphthalene-1,8-diyl structure.
  • the naphthalene diyl group which may have a substituent is, for example, a naphthalene-2,6-diyl group.
  • Ar 1 and Ar 2 may be the same or different.
  • Ar 1 may be a naphthalene-2,6-diyl group and Ar 2 may be a p-phenylene group.
  • the structural unit represented by the formula (1) is preferably the structural unit represented by the following formula (3).
  • R 11 to R 18 are independent of each other, a hydrogen atom, a halogen atom, a hydroxy group, a sulfonic acid group, an alkoxy group having 1 to 30 carbon atoms, or a hydrocarbon group having 1 to 30 carbon atoms. Examples of the alkoxy group and the hydrocarbon group include those described above for R 1 to R 6.
  • R 11 to R 18 are preferably hydrogen atoms.
  • the content of the structural unit represented by the formula (1) in the polyimide (P) is, for example, 50 mol% or more, preferably 60 mol% or more, more preferably 70 mol% or more, still more preferably 80 mol% or more. It is particularly preferably 90 mol% or more.
  • the content of the structural unit represented by the formula (1) may be 100 mol%.
  • the structural unit represented by the formula (1) is obtained by the reaction of the tetracarboxylic dianhydride (C) represented by the following formula (4) and the diamine compound (D) represented by the following formula (5). be able to.
  • C tetracarboxylic dianhydride
  • D diamine compound
  • a and R 1 to R 6 are the same as in formula (1).
  • B, Ar 1 and Ar 2 are the same as in formula (1).
  • the polyimide (P) may contain a structural unit derived from another tetracarboxylic dianhydride different from the tetracarboxylic dianhydride (C).
  • the other tetracarboxylic dianhydride is not particularly limited, and known ones can be used. Examples of other tetracarboxylic dianhydrides include pyromellitic dianhydrides and 4,4'-(hexafluoroisopropyridene) diphthalic anhydrides.
  • the ratio P1 of the structural unit derived from the tetracarboxylic dianhydride (C) to all the structural units derived from the tetracarboxylic dianhydride is, for example, 50 mol% or more, preferably 70 mol%. The above is more preferably 90 mol% or more. The ratio P1 may be 100 mol%.
  • the polyimide (P) may contain a structural unit derived from another diamine compound different from the diamine compound (D).
  • the other diamine compounds are not particularly limited, and known diamine compounds can be used. Examples of other diamine compounds include phenylenediamine, diaminobenzoic acid, diaminobiphenyl, diaminodiphenylmethane and the like.
  • polyimide (P) may contain structural units derived from diaminobenzoic acid (eg, 3,5-diaminobenzoic acid).
  • Polyimide (P) containing a structural unit derived from diaminobenzoic acid is suitable for increasing the flux of water permeating the separation membrane 10.
  • the ratio P2 of the structural unit derived from the diamine compound (D) to all the structural units derived from the diamine compound is, for example, 50 mol% or more, preferably 70 mol% or more, more preferably 90 mol. % Or more.
  • the ratio P2 may be 100 mol%.
  • Polyimide (P) can be produced, for example, by the following method.
  • the diamine compound (D) is dissolved in a solvent to obtain a solution.
  • the solvent include polar organic solvents such as N-methyl-2-pyrrolidone (NMP) and 1,3-dioxolane.
  • tetracarboxylic dianhydride (C) is gradually added to the obtained solution.
  • the tetracarboxylic dianhydride (C) and the diamine compound (D) react to form a polyamic acid.
  • the addition of the tetracarboxylic dianhydride (C) is carried out, for example, at a temperature of room temperature (25 ° C.) or lower for 3 to 20 hours under stirring conditions.
  • the polyimide (P) can be obtained by imidizing the polyamic acid.
  • the imidization method include a chemical imidization method and a thermal imidization method.
  • the chemical imidization method is a method of imidizing a polyamic acid using a dehydration condensing agent.
  • the chemical imidization method may be carried out under room temperature conditions or heating conditions.
  • Examples of the dehydration condensing agent include acetic anhydride, pyridine and triethylamine.
  • the thermal imidization method is a method of imidizing a polyamic acid by heat treatment. The temperature of the heat treatment is, for example, 180 ° C. or higher.
  • the content of polyimide (P) in the matrix 4 is, for example, 50 wt% or more, preferably 60 wt% or more, more preferably 70 wt% or more, still more preferably 80 wt% or more, and particularly preferably 90 wt%. That is all.
  • the matrix 4 is substantially made of, for example, polyimide (P).
  • the content of the matrix 4 in the separation function layer 1 is, for example, 70 wt% or more.
  • the upper limit of the content of the matrix 4 is not particularly limited, and may be 99 wt% or 95 wt%.
  • the filler 5 is, for example, hydrophilic and porous. Such a filler 5 is suitable for increasing the flux of water passing through the separation membrane 10 without significantly reducing the separation performance of the separation membrane 10.
  • the filler 5 contains, for example, at least one selected from the group consisting of zeolites and metal-organic frameworks (MOFs).
  • the filler 5 preferably contains a metal-organic framework from the viewpoint of durability against water.
  • Zeolites include, for example, molecular sieves 3A, 4A, 5A and 13X.
  • the metal-organic framework is also called a porous coordination polymer (PCP).
  • the metal-organic framework contains, for example, metal ions and organic ligands.
  • the metal ion include Co ion, Ni ion, Zn ion, Mg ion, Zr ion, Cu ion and the like.
  • the organic ligand does not have to have a polar group, but preferably has a polar group. Examples of the polar group include an aldehyde group, an amino group, an amide group, a hydroxy group, a carboxyl group and a nitro group.
  • the organic ligand contains, for example, an aromatic ring.
  • Examples of the aromatic ring contained in the organic ligand include a benzene ring and an imidazole ring.
  • Examples of the organic ligand include 2-hydroxymethylimidazole, 2-formylimidazole, terephthalic acid, 2-hydroxyterephthalic acid, 2,5-dihydroxyterephthalic acid and 2-aminoterephthalic acid.
  • metal-organic framework examples include ZIF-90, ZIF-91, UiO-66, UiO-66-NH 2 , UiO-66-OH, UiO-66-NO 2 , UiO-66-COOH, and HKUST-1.
  • MOF-74 (M Co, Ni, Zn, Mg, etc.).
  • the metal-organic framework is ZIF-90, UiO-66-NH 2 , UiO-66-OH, UiO-66-NO 2 , UiO-66- from the viewpoint of increasing the flux of water permeating the separation membrane 10. It preferably contains at least one selected from the group consisting of COOH and MOF-74 (Ni), and more preferably contains UiO-66-COOH.
  • the ratio R1 of the amount of water adsorbed on the filler 5 to the filler 5 under the water vapor of 25 ° C. and 3.2 kPa to the amount Q1 of ethanol adsorbed on the filler 5 under the ethanol atmosphere of 25 ° C. and 7.4 kPa is, for example, 2. It is 0.0 or more, preferably 3.0 or more.
  • the upper limit of the ratio R1 is not particularly limited, and is, for example, 5.0.
  • the ratio R1 may be used as an index of the hydrophilicity of the filler 5.
  • the "adsorption amount” means a value obtained by converting the volume of the gas adsorbed by 1 g of the filler 5 into the standard state (298 K, 1 atm).
  • the amount of ethanol adsorbed on the filler 5 Q1 can be specified by the following method.
  • the filler 5 is pretreated by heating it in a reduced pressure atmosphere.
  • the pretreatment may be performed in a vacuum atmosphere.
  • the temperature of the pretreatment is, for example, 100 ° C. or higher.
  • the pretreatment time is not particularly limited, and is, for example, one hour or more.
  • the filler 5 is set in a known vapor adsorption amount measuring device such as BELSORP-maxII manufactured by Microtrac Bell.
  • gaseous ethanol is introduced into the measuring device.
  • the introduced gaseous ethanol is adsorbed on the filler 5.
  • the introduction of gaseous ethanol is carried out until the pressure of ethanol in the measuring device reaches 7.4 kPa.
  • 7.4 kPa corresponds to the equilibrium vapor pressure (saturated vapor pressure) of ethanol at 25 ° C.
  • the amount of ethanol adsorbed by the filler 5 is specified.
  • the fact that the adsorption of ethanol by the filler 5 has reached an equilibrium state can be determined by the change in the pressure of ethanol in the measuring device. For example, when the change in ethanol pressure in the measuring device is 40 Pa or less in 500 seconds, it can be determined that the adsorption of ethanol by the filler 5 has reached an equilibrium state.
  • the adsorption amount of ethanol specified by the above method can be regarded as the adsorption amount Q1.
  • the amount of water adsorbed on the filler 5 Q2 can be specified by the following method. First, the filler 5 is subjected to the above-mentioned pretreatment. This filler 5 is set in the steam adsorption amount measuring device. Next, water vapor is introduced into the measuring device at a measuring temperature of 25 ° C. The water vapor is introduced until the pressure of the water vapor in the measuring device reaches 3.2 kPa. 3.2 kPa corresponds to the equilibrium vapor pressure of water at 25 ° C. After confirming that the adsorption of water by the filler 5 has reached an equilibrium state, the amount of water adsorbed by the filler 5 is specified. The specified water adsorption amount can be regarded as the adsorption amount Q2.
  • the amount of ethanol adsorbed on the filler 5 Q1 is, for example, 200 cm 3 / g or less.
  • the lower limit of the adsorption amount Q1 is not particularly limited, and may be 90 cm 3 / g or 100 cm 3 / g.
  • the amount of water adsorbed on the filler 5 Q2 is, for example, 300 cm 3 / g or more, and in some cases, 350 cm 3 / g or more, 450 cm 3 / g or more, or 500 cm 3 / g or more. It may be 550 cm 3 / g or more.
  • the upper limit of the adsorption amount Q2 is not particularly limited, and is, for example, 800 cm 3 / g.
  • the filler 5 may have a ratio R2 of BET specific surface area S2 due to water vapor adsorption to 0.005 or more with respect to BET (Brunauer-Emmett-Teller) specific surface area S1 due to nitrogen gas adsorption.
  • the ratio R2 may be used as an index of the hydrophilicity of the filler 5.
  • the ratio R2 is, for example, 0.01 or more, preferably 0.1 or more, more preferably 0.2 or more, and further preferably 0.3 or more.
  • the ratio R2 may be 25 or less, 10 or less, 1.0 or less, or 0.6 or less.
  • the BET specific surface area S1 due to the adsorption of nitrogen gas is, for example, 1500 m 2 / g or less, preferably 1000 m 2 / g or less, and may be 900 m 2 / g or less in some cases.
  • the specific surface area S1 may be 30 m 2 / g or more, or 400 m 2 / g or more.
  • BET specific surface area S2 by water vapor adsorption is, for example, 10 m 2 / g or more, preferably 100 m 2 / g or more, more preferably 150 meters 2 / g or more, in some cases 200 meters 2 / g It may be the above.
  • the specific surface area S2 may be 1000 m 2 / g or less, 600 m 2 / g or less, or 400 m 2 / g or less.
  • the shape of the filler 5 is not particularly limited, and is, for example, in the form of particles.
  • "particulate” includes spherical, ellipsoidal, scaly, fibrous and the like.
  • the average particle size of the filler 5 is not particularly limited, and is, for example, 5 nm to 10000 nm.
  • the average particle size of the filler 5 can be specified by, for example, the following method. First, the cross section of the separation function layer 1 is observed with a transmission electron microscope. In the obtained electron microscope image, the area of the specific filler 5 is calculated by image processing. The diameter of a circle having the same area as the calculated area is regarded as the particle size (particle diameter) of the specific filler 5. The particle size of any number (at least 50) of the fillers 5 is calculated, and the average value of the calculated values is regarded as the average particle size of the fillers 5.
  • the content of the filler 5 in the separation functional layer 1 may be, for example, 1 wt% or more, 5 wt% or more, 10 wt% or more, 15 wt% or more, or 20 wt% or more.
  • the content of the filler 5 in the separation functional layer 1 may be 30 wt% or less.
  • the intermediate layer 2 contains, for example, the polymer compound (E).
  • the distance Ra between the Hansen solubility parameter of the polymer compound (E) and the Hansen solubility parameter of H 2 O is preferably less than 19 MPa 1/2.
  • the intermediate layer 2 containing such a polymer compound (E) is suitable for suppressing a decrease in the flux of water permeating through the separation membrane 10. Further, this polymer compound (E) is suitable for suppressing the occurrence of defects in the intermediate layer 2 during the production of the intermediate layer 2 and adjusting the thickness of the intermediate layer 2 to 2.5 ⁇ m or less. ..
  • the intermediate layer 2 containing the polymer compound (E) also has an advantage that a separation functional layer 1 containing polyimide and having a thickness of about 2.5 ⁇ m or less can be easily formed on the surface thereof.
  • the above distance Ra may be 19 MPa 1/2 or more depending on the composition of the separation functional layer 1 and the use of the separation membrane.
  • Separation function layer 1, intermediate layer 2 and porous support 3 are provided in this order in the stacking direction.
  • the intermediate layer 2 contains the polymer compound (E) and contains the polymer compound (E).
  • a separation membrane 10 in which the distance Ra between the Hansen solubility parameter of the polymer compound (E) and the Hansen solubility parameter of H 2 O is less than 19 MPa 1/2.
  • the Hansen solubility parameter is a solubility parameter introduced by Hildebrand divided into three components, a dispersion term ⁇ D, a polarization term ⁇ P, and a hydrogen bond term ⁇ H. Details of the Hansen solubility parameter are disclosed in "Hansen Solubility Parameters; A Users Handbook (CRC Press, 2007)". The Hansen solubility parameter can be calculated using, for example, known software such as HSPiP.
  • the distance Ra between the Hansen solubility parameter of the polymer compound (E) and the Hansen solubility parameter of H 2 O can be calculated from the following formula (i). However, in the formula (i), ⁇ D 1, ⁇ P 1 and delta] H 1, respectively, dispersion term (MPa 1/2) of the polymer compound (E), the polarization term (MPa 1/2) and hydrogen bond (MPa 1/2 ). [delta] D 2, [delta] P 2 and delta] H 2 are each, H 2 O dispersion term of (18.1MPa 1/2), polarization term (17.1MPa 1/2) and hydrogen bond (16.9MPa 1/2) be.
  • Ra ⁇ 4 ⁇ ( ⁇ D 1 - ⁇ D 2) 2 + ( ⁇ P 1 - ⁇ P 2) 2 + ( ⁇ H 1 - ⁇ H 2) 2 ⁇ 1/2 (i)
  • the distance Ra between the Hansen solubility parameter of the polymer compound (E) and the Hansen solubility parameter of H 2 O is preferably 18 MPa 1/2 or less, more preferably 17 MPa 1/2 or less, and further preferably 16 MPa. It is 1/2 or less, and particularly preferably 15 MPa 1/2 or less. From the viewpoint of suppressing the swelling of the polymer compound (E) by water when water permeates the separation membrane 10, the lower limit of the distance Ra is preferably 5 MPa 1/2 , more preferably 8 MPa 1. / 2, optionally may be 10 MPa 1/2 may be 13 MPa 1/2.
  • the polymer compound (E) contains, for example, at least one selected from the group consisting of polyether blockamide, polyvinyl alcohol (PVA), polyether and polyurethane.
  • the polyether include polyethylene glycol (PEG).
  • the polymer compound (E) preferably contains a polyether block amide.
  • the polymer compound (E) may contain a silicone-based polymer such as dimethylpolysiloxane in some cases.
  • the polyether block amide is a block copolymer containing a polyether block PE and a polyamide block PA.
  • the polyether block amide is represented by, for example, the following formula (6).
  • R 21 is a divalent hydrocarbon group having 1 to 15 carbon atoms.
  • the number of carbon atoms of the divalent hydrocarbon group may be 1 to 10 or 1 to 5.
  • the divalent hydrocarbon group is preferably a linear or branched alkylene group. Specific examples of R 21 are an ethylene group and a butane-1,4-diyl group.
  • R 22 is a divalent hydrocarbon group having 1 to 20 carbon atoms. In R 22 , the number of carbon atoms of the divalent hydrocarbon group may be 3 to 18 or 3 to 15.
  • the divalent hydrocarbon group is preferably a linear or branched alkylene group. Specific examples of R 22 are pentane-1,5-diyl group and undecane-1,11-diyl group.
  • the ratio of x to y (x: y) is, for example, 1: 9 to 9: 1, preferably 5: 5 to 9: 1, and more preferably 6: 4 to 8 :. It is 2.
  • n is an integer of 1 or more.
  • polyether block amide examples include Pebax (registered trademark) 2533 and 1657 manufactured by Arkema.
  • Specific examples 1 to 5 of the polymer compound (E) are shown in Table 3 below.
  • Table 3 also shows the Hansen solubility parameter and the above distance Ra for Specific Examples 1 to 5.
  • the intermediate layer 2 may contain a polymer compound (E), particularly a polyether block amide, as a main component, and the content thereof is, for example, 50 wt% or more, preferably 60 wt% or more, more preferably. Is 70 wt% or more, more preferably 80 wt% or more, and particularly preferably 90 wt% or more.
  • the intermediate layer 2 is preferably substantially composed of the polymer compound (E).
  • the porous support 3 is not particularly limited as long as it can support the separation function layer 1 and the intermediate layer 2.
  • Examples of the porous support 3 include non-woven fabrics; porous polytetrafluoroethylene; aromatic polyamide fibers; porous metals; sintered metals; porous ceramics; porous polyesters; porous nylons; activated carbon fibers; latexs. Silicone; Silicone rubber; Permeability containing at least one selected from the group consisting of polyvinyl fluoride, vinylidene polyvinylfluoride, polyurethane, polypropylene, polyethylene, polycarbonate, polysulfone, polyether ether ketone, polyacrylonitrile, polyimide and polyphenylene oxide.
  • Porous) polymer metal foam having open cells or closed cells; polymer foam having open cells or closed cells; silica; porous glass; mesh screen and the like.
  • the porous support 3 may be a combination of two or more of these.
  • the porous support 3 has an average pore size of, for example, 0.01 to 0.4 ⁇ m.
  • the thickness of the porous support 3 is not particularly limited, and is, for example, 10 ⁇ m or more, preferably 20 ⁇ m or more, and more preferably 50 ⁇ m or more.
  • the thickness of the porous support 3 is, for example, 300 ⁇ m or less, preferably 200 ⁇ m or less, and more preferably 75 ⁇ m or less.
  • the separation membrane 10 can be produced, for example, by the following method.
  • a coating liquid containing the polymer compound (E) is prepared.
  • the solvent of the coating liquid include an organic solvent such as 2-propanol (IPA).
  • the concentration of the polymer compound (E) in the coating liquid is not particularly limited, and is, for example, 1 wt% to 10 wt%, preferably 3 wt% to 7 wt%.
  • the solvent may be preheated.
  • the heating temperature of the solvent is not particularly limited as long as it is equal to or lower than the boiling point of the solvent, and is, for example, 30 ° C to 80 ° C.
  • the coating liquid is applied onto the porous support 3 to obtain a coating film.
  • the intermediate layer 2 is formed by drying the coating film.
  • the thickness of the intermediate layer 2 can be adjusted by the concentration of the polymer compound (E) in the coating liquid and the thickness of the coating film.
  • a coating liquid containing the filler 5 and the material of the matrix 4 is prepared.
  • an organic solvent such as 1,3-dioxolane can be used.
  • the coating liquid may be subjected to ultrasonic treatment in order to improve the dispersibility of the filler 5 in the coating liquid.
  • a coating film is obtained by applying the coating liquid on the intermediate layer 2.
  • the separation functional layer 1 is formed by drying the coating film. As a result, the separation membrane 10 can be produced.
  • the material of the matrix 4 contained in the coating liquid may be a polyamic acid.
  • the separation functional layer 1 can be formed by imidizing the polyamic acid after applying the coating liquid on the intermediate layer 2.
  • the viscosity of the coating liquid for forming the separation function layer is conceivable to adjust the viscosity of the coating liquid for forming the separation function layer to a relatively low viscosity, for example, 10 mPa ⁇ s or less.
  • Coating liquids containing fillers also tend to have lower viscosities.
  • the coating liquid When a coating liquid having a low viscosity is directly applied to the porous support, the coating liquid easily penetrates into the porous support.
  • the coating liquid soaks into the porous support, it is difficult for the coating film to be uniformly formed on the surface of the porous support, and defects tend to occur in the obtained separation functional layer. Further, there is a defect in the surface of the porous support, and even when the coating liquid for forming the separation functional layer is directly applied on the surface, the defect is likely to occur in the separation functional layer.
  • the coating liquid for forming the separation functional layer 1 is applied not on the porous support 3 but on the intermediate layer 2, it is difficult for this coating liquid to permeate into the porous support 3. Therefore, even when the viscosity of the coating liquid is relatively low or when defects are present on the surface of the porous support 3, the occurrence of defects in the separation functional layer 1 can be sufficiently suppressed.
  • the number of defects in the separation function layer 1 per 1000 cm 2 of the surface of the separation function layer 1 is, for example, 10 or less, preferably 5 or less, and more preferably 2 or less. , And more preferably 0.
  • the thickness of the intermediate layer 2 and the total value T of the thickness of the intermediate layer 2 and the thickness of the separation function layer 1 are appropriately adjusted. As a result, the decrease in the flux of the permeated fluid that permeates the separation membrane 10 is suppressed.
  • the flow flux F is, for example, 0.30 kg / m 2 / hr or more, preferably 0.35 kg / m 2 / hr or more, more preferably 0.40 kg / m 2 / hr or more, and further preferably 0.40 kg / m 2 / hr or more. and a 0.45kg / m 2 / hr or more, and particularly preferably 0.50kg / m 2 / hr or more.
  • the upper limit of the water flux F is not particularly limited, and is, for example, 1.00 kg / m 2 / hr.
  • the water flux F can be measured in detail by the following method.
  • the other surface of the separation membrane 10 for example, the separation membrane 10) in a state where a mixed liquid composed of ethanol and water is in contact with one surface of the separation membrane 10 (for example, the main surface 11 on the separation function layer side of the separation membrane 10).
  • the space adjacent to the main surface 12) on the porous support side of the above is depressurized.
  • a permeated fluid that has passed through the separation membrane 10 can be obtained.
  • the concentration of ethanol in the mixed liquid is 50 vol% (44 wt%) when the temperature of the mixed liquid is measured at 20 ° C.
  • the temperature of the mixed liquid to be brought into contact with the separation membrane 10 is 60 ° C.
  • the space adjacent to the other surface of the separation membrane 10 is depressurized so that the pressure in the space becomes 100 kPa smaller than the atmospheric pressure in the measurement environment.
  • the weight of the permeated fluid and the weight ratio of water in the permeated fluid are measured. Based on the results obtained, the water flux F can be identified.
  • the water separation coefficient ⁇ of the separation membrane 10 with respect to ethanol is, for example, 20 or more, preferably 40 or more, more preferably 45 or more, and in some cases 50 or more. It may be more than 60, 60 or more, and 65 or more.
  • the upper limit of the separation coefficient ⁇ is not particularly limited, but is, for example, 500.
  • the separation membrane 10 having a separation coefficient ⁇ of 20 or more is sufficiently suitable for use in separating water from a mixed liquid containing alcohol and water.
  • the separation coefficient ⁇ can be calculated from the following formula.
  • X A and X B are the volume ratio of water and the volume ratio of alcohol in the mixed liquid, respectively.
  • Y A and Y B are the volume ratio of water and the volume ratio of alcohol in the permeated fluid that has passed through the separation membrane 10, respectively.
  • Separation factor ⁇ (Y A / Y B ) / (X A / X B)
  • Examples of the use of the separation membrane 10 of the present embodiment include the use of separating water from a mixed liquid containing alcohol and water. In this application, the flux of water that permeates the separation membrane 10 tends to be high. However, the use of the separation membrane 10 is not limited to the use of separating water from the above-mentioned mixed liquid.
  • the membrane separation device 100 of the present embodiment includes a separation membrane 10 and a tank 20.
  • the tank 20 includes a first chamber 21 and a second chamber 22.
  • the separation membrane 10 is arranged inside the tank 20. Inside the tank 20, the separation membrane 10 separates the first chamber 21 and the second chamber 22.
  • the separation membrane 10 extends from one of the pair of wall surfaces of the tank 20 to the other.
  • the first room 21 has an inlet 21a and an outlet 21b.
  • the second chamber 22 has an outlet 22a.
  • Each of the inlet 21a, the outlet 21b and the outlet 22a is, for example, an opening formed in the wall surface of the tank 20.
  • Membrane separation using the membrane separation device 100 is performed by, for example, the following method.
  • the mixed liquid 30 containing alcohol and water is supplied to the first chamber 21 through the inlet 21a.
  • the mixed liquid 30 can be brought into contact with one surface of the separation membrane 10.
  • the alcohol in the mixed liquid 30 is, for example, a lower alcohol that azeotropes with water.
  • the alcohol is preferably ethanol, but may be isopropyl alcohol (IPA).
  • the concentration of alcohol in the mixed liquid 30 is, for example, 10 wt% or more, preferably 20 wt% or more.
  • the separation membrane 10 is particularly suitable for separating water from the mixed liquid 30 having a medium alcohol concentration (20 wt% to 80 wt%, particularly 30 wt% to 70 wt%).
  • the concentration of alcohol in the mixed liquid 30 may be 80 wt% or more.
  • the mixed liquid 30 may substantially consist of alcohol and water.
  • the temperature of the mixed liquid 30 may be higher than the boiling point of the alcohol used, but is preferably lower than the boiling point of the alcohol.
  • the temperature of the mixed liquid 30 is, for example, 25 ° C. or higher, preferably 40 ° C. or higher, and more preferably 60 ° C. or higher.
  • the temperature of the mixed liquid 30 may be 75 ° C. or lower.
  • the membrane separation device 100 may further include a pump (not shown) for depressurizing the inside of the second chamber 22.
  • the second chamber 22 is depressurized so that the space inside the second chamber 22 is smaller than, for example, 10 kPa or more, preferably 50 kPa or more, more preferably 100 kPa or more, with respect to the atmospheric pressure in the measurement environment.
  • the permeated fluid 35 is supplied to the second chamber 22.
  • the permeated fluid 35 contains, for example, water as a main component. However, the permeated fluid 35 may contain a small amount of alcohol in addition to water.
  • the permeated fluid 35 may be a gas or a liquid. The permeated fluid 35 is discharged to the outside of the tank 20 through the outlet 22a.
  • the concentration of alcohol in the mixed liquid 30 gradually increases from the inlet 21a of the first chamber 21 toward the outlet 21b.
  • the mixed liquid 30 (concentrated fluid 36) treated in the first chamber 21 is discharged to the outside of the tank 20 through the outlet 21b.
  • the membrane separation device 100 of the present embodiment is preferably used in the osmotic vaporization method.
  • the membrane separation device 100 may be used for other membrane separation methods, such as a vapor permeation method. That is, in the above-mentioned membrane separation method, a mixed gas containing a gaseous alcohol and a gaseous water may be used instead of the mixed liquid 30.
  • the membrane separation device 100 of the present embodiment is suitable for a distribution type (continuous type) membrane separation method.
  • the membrane separation device 100 of the present embodiment may be used in a batch type membrane separation method.
  • the membrane separation device 110 of the present embodiment includes a central tube 41 and a laminate 42.
  • the laminate 42 contains the separation membrane 10.
  • the membrane separation device 110 is a spiral type membrane element.
  • the central canal 41 has a cylindrical shape. On the surface of the central canal 41, a plurality of holes for allowing the permeated fluid 35 to flow into the central canal 41 are formed.
  • the material of the central tube 41 include resins such as acrylonitrile / butadiene / styrene copolymer resin (ABS resin), polyphenylene ether resin (PPE resin), and polysulfon resin (PSF resin); metals such as stainless steel and titanium. Be done.
  • the inner diameter of the central canal 41 is, for example, in the range of 20 to 100 mm.
  • the laminated body 42 further includes a supply side flow path material 43 and a transmission side flow path material 44 in addition to the separation membrane 10.
  • the laminate 42 is wound around the central canal 41.
  • the membrane separation device 110 may further include an exterior material (not shown).
  • a resin net made of polyphenylene sulfide (PPS) or ethylene-chlorotrifluoroethylene copolymer (ECTFE) can be used.
  • Membrane separation using the membrane separation device 110 is performed by, for example, the following method.
  • the space inside the central canal 41 is decompressed.
  • the permeated fluid 35 that has passed through the separation membrane 10 of the laminated body 42 moves inside the central tube 41.
  • the permeated fluid 35 is discharged to the outside through the central tube 41.
  • the mixed liquid 30 (concentrated fluid 36) processed by the membrane separation device 110 is discharged to the outside from the other end of the wound laminate 42. As a result, water can be separated from the mixed liquid 30.
  • a coating liquid was prepared by dissolving a polyether block amide (Pebax (registered trademark) 2533 manufactured by Arkema Co., Ltd.) in IPA at 80 ° C. The concentration of polyether block amide in the coating liquid was 3 wt%.
  • a coating film was obtained by applying the coating liquid on the porous support.
  • a UF membrane (ultrafiltration membrane) RS-50 (a laminate of a PVDF porous layer and a PET non-woven fabric) manufactured by Nitto Denko Corporation was used.
  • the coating film was formed on the PVDF porous layer of RS-50.
  • the coating liquid was applied using an applicator with a gap of 155 ⁇ m.
  • the coating film was dried to form an intermediate layer having a thickness of 0.5 ⁇ m.
  • Polyamic acid was obtained by adding tetracarboxylic dianhydride to the obtained solution under room temperature conditions.
  • a polyimide was obtained by chemically imidizing the polyamic acid with triethylamine and acetic anhydride. Chemical imidization was performed in N-methyl-2-pyrrolidone under the condition of 60 ° C.
  • the ratio of the structural unit derived from 3,5-diaminobenzoic acid to all the structural units derived from the diamine compound was 10 mol%.
  • the polyimide was dissolved in 1,3-dioxolane to obtain a solution.
  • a polyimide solution was added to a dispersion liquid containing Molecular Sieve 4A (Zeoal 4A (particle size 300 nm) manufactured by Nakamura Choukou Co., Ltd.), and these were mixed.
  • a coating film was obtained by applying the obtained coating liquid on the intermediate layer. By drying the coating film, a separation functional layer having a thickness of 1.25 ⁇ m was formed.
  • the content of polyimide in the separation functional layer was 80 wt%, and the content of molecular sieve 4A was 20 wt%. As a result, the separation membrane of Example 1 was obtained.
  • Examples 2-5 and 8-11 Separation membranes of Examples 2 to 5 and 8 to 11 were obtained in the same manner as in Example 1 except that the thickness of the separation function layer and the thickness of the intermediate layer were changed to the values shown in Table 4.
  • the thickness of the intermediate layer was adjusted by adjusting the concentration of the polyether block amide in the coating liquid.
  • the thickness of the separation function layer was adjusted by the solid content concentration in the coating liquid.
  • Example 1 Example 1 except that Pebax® 1657 manufactured by Arkema Co., Ltd. was used as the polyether block amide, and the thickness of the separation functional layer and the thickness of the intermediate layer were changed to the values shown in Table 4. Separation membranes of Examples 6 and 12 were obtained in the same manner as in.
  • Example 7 The separation membrane of Example 7 was obtained by the same method as in Example 1 except that the intermediate layer was not prepared and the thickness of the separation functional layer was changed to the value shown in Table 4.
  • a coating liquid containing a silicone-based polymer was prepared.
  • Distance Ra of the Hansen solubility parameters of the silicone-based polymer, a Hansen solubility parameter of H 2 O was at 19 MPa 1/2 or more.
  • the content of the silicone-based polymer in the coating liquid was 2 wt%.
  • a coating film was obtained by applying the coating liquid on the porous support.
  • a UF membrane (ultrafiltration membrane) RS-50 (a laminate of a PVDF porous layer and a PET non-woven fabric) manufactured by Nitto Denko Corporation was used.
  • the coating film was formed on the PVDF porous layer of RS-50.
  • the coating liquid was applied using an applicator with a gap of 130 ⁇ m.
  • the coating film was dried to form an intermediate layer having a thickness of 1.8 ⁇ m.
  • the number of defects in the separation function layer was confirmed by the following method. First, a dyeing solution was prepared by dissolving the dyeing material in ethanol. This stain was applied on the separation function layer. At this time, the dyeing solution soaked into the separation function layer at the portion where the defect (pinhole) was present, and stained the portion of the separation function layer. Next, the surface of the separation functional layer was washed with ethanol. The number of spots (staining spots) where the dyeing solution soaked into the separation function layer was visually confirmed. Thereby, the number of defects in the separation function layer per 1000 cm 2 of the surface of the separation function layer was specified.
  • the flux F of water passing through the separation membrane and the separation coefficient ⁇ were measured by the following methods.
  • the separation membrane was set in the metal cell and sealed with an O-ring to prevent leakage.
  • 250 mL of the mixed liquid was injected into the metal cell so that the mixed liquid was in contact with the main surface of the separation membrane on the separation function layer side.
  • the mixed liquid consisted substantially of ethanol and water.
  • the concentration of ethanol in the mixed liquid was 50 vol% when the temperature of the mixed liquid was measured at 20 ° C.
  • the metal cell was heated to 60 ° C. by a hot water bath.
  • the space in the metal cell adjacent to the main surface of the separation membrane on the porous support side was depressurized. At this time, the pressure in this space was reduced so that the pressure in the space was 100 kPa smaller than the atmospheric pressure in the measurement environment. As a result, a gas permeation fluid was obtained.
  • the permeated fluid was liquefied by cooling the permeated fluid of the gas with liquid nitrogen at -196 ° C.
  • the composition of the liquid permeation fluid was analyzed using gas chromatography (GC-3200 manufactured by GL Sciences).
  • the flux F of water that permeated the separation membrane and the separation coefficient ⁇ of the separation membrane were calculated based on the composition of the permeation fluid, the weight of the permeation fluid, and the like.
  • Example 7 a plurality of samples in which a portion having a defect does not exist in the separation function layer and a sample in which a portion having a defect exists in the separation function layer are prepared, and the above measurement is performed for each sample. went.
  • the water flux F of Example 7 is the average value (0.57 kg / m 2 / hr) of the water flux identified for the plurality of samples. Further, Table 4 shows the minimum value (9.2) and the maximum value (85.5) of the separation coefficient ⁇ specified for the plurality of samples of Example 7.
  • Examples 1 to 6 in which the thickness of the intermediate layer is 0.1 ⁇ m to 2.5 ⁇ m and the total value T of the thickness of the intermediate layer and the thickness of the separation function layer is less than 4.0 ⁇ m.
  • the separation coefficient ⁇ was 20 or more, which was a practically sufficient value.
  • the separation membrane of this embodiment is suitable for separating water from a mixed liquid containing alcohol and water.
  • the separation membrane of this embodiment is useful for purifying bioethanol.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
PCT/JP2021/005888 2020-03-25 2021-02-17 分離膜 Ceased WO2021192745A1 (ja)

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CN202180015821.0A CN115151335A (zh) 2020-03-25 2021-02-17 分离膜
US17/912,771 US20230130077A1 (en) 2020-03-25 2021-02-17 Separation membrane
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WO2024202568A1 (ja) * 2023-03-28 2024-10-03 日東電工株式会社 分離膜

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EP4101521A4 (en) * 2020-02-06 2024-03-20 Nitto Denko Corporation SEPARATION MEMBRANE AND ORGANOMETALLIC STRUCTURE
WO2024202568A1 (ja) * 2023-03-28 2024-10-03 日東電工株式会社 分離膜

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EP4129456A4 (en) 2024-04-10

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