WO2021149803A1 - 化粧シート、化粧板及び化粧シートの製造方法 - Google Patents

化粧シート、化粧板及び化粧シートの製造方法 Download PDF

Info

Publication number
WO2021149803A1
WO2021149803A1 PCT/JP2021/002264 JP2021002264W WO2021149803A1 WO 2021149803 A1 WO2021149803 A1 WO 2021149803A1 JP 2021002264 W JP2021002264 W JP 2021002264W WO 2021149803 A1 WO2021149803 A1 WO 2021149803A1
Authority
WO
WIPO (PCT)
Prior art keywords
recess
layer
decorative sheet
pattern layer
pattern
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2021/002264
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
雄一 伊勢森
貴矢 大野
勝利 田畑
一葉 大竹
誠司 谷定
靖弘 鈴木
勇二 大原
勇樹 高木
遼 中澤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dai Nippon Printing Co Ltd
Original Assignee
Dai Nippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Nippon Printing Co Ltd filed Critical Dai Nippon Printing Co Ltd
Priority to KR1020227027523A priority Critical patent/KR20220130722A/ko
Priority to EP21744624.4A priority patent/EP4108450A4/en
Priority to US17/794,762 priority patent/US20230071952A1/en
Priority to JP2021572818A priority patent/JPWO2021149803A1/ja
Priority to CN202180009775.3A priority patent/CN114981075A/zh
Publication of WO2021149803A1 publication Critical patent/WO2021149803A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Images

Classifications

    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/02—Superimposing layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/16—Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/06—Embossing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/023—Optical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/24—Pressing or stamping ornamental designs on surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F7/00—Designs imitating three-dimensional [3D] effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/02—Designs imitating natural patterns wood grain effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/04—Designs imitating natural patterns of stone surfaces, e.g. marble
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/242—All polymers belonging to those covered by group B32B27/32
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/28—Multiple coating on one surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/10—Polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00—Decorative or ornamental articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins

Definitions

  • the present invention relates to a decorative sheet, a decorative board, and a method for manufacturing a decorative sheet.
  • a decorative board to which a decorative sheet with a design is attached is generally used.
  • the decorative sheet may be embossed to form an uneven shape to give a three-dimensional visual effect.
  • Patent Document 1 a pattern printing layer on which a pattern is printed, a transparent thermoplastic resin layer having a concavo-convex pattern synchronized with the pattern, and the surface of the transparent thermoplastic resin layer are formed on one surface side of the base sheet.
  • the surface protective layer to be protected and the gloss adjustment layer having a pattern in a gloss state synchronized with the pattern are laminated in this order, and the unevenness of the uneven pattern is characterized by the resin constituting the surface protective layer.
  • the decorative sheet is disclosed.
  • the present invention solves the above-mentioned problems, and an object of the present invention is to provide a decorative sheet having an extremely excellent design in which the pattern of the pattern layer and the recess are synchronized.
  • the transparent resin layer is the above-mentioned pattern in a decorative sheet having a pattern layer and a transparent resin layer on one of the base materials in at least this order.
  • the picture layer has a recess (D 2) located in the stacking direction of the recess (D 1), the recesses of (D 1) It was found that when the depth H is larger than the depth h of the recess (D 2 ), the pattern of the pattern layer and the recess are synchronized to each other to produce an extremely excellent design, and the present invention has been completed. rice field.
  • the decorative sheet of the present invention has at least a pattern layer and a transparent resin layer on one of the base materials in this order, and the pattern layer includes a characteristic portion and a non-characteristic portion, and the transparent resin.
  • the layer has a recess (D 1 ) synchronized with the characteristic portion of the pattern layer on the side opposite to the side having the pattern layer, and the pattern layer has the recess on the side opposite to the side having the base material.
  • (D 1) has a recess located in the stacking direction of the (D 2), the depth H of the concave portion (D 1) may be greater than the depth h of the recess (D 2).
  • the ratio (h / H) of the depth h of the recess (D 2 ) to the depth H of the recess (D 1) is preferably 0.25 or more and 0.60 or less. ..
  • the decorative sheet of the present invention preferably has a surface protective layer on the side of the transparent resin layer opposite to the side having the pattern layer.
  • the characteristic portion of the pattern layer is preferably a wood grain conduit, knots, annual rings and spots, or stripes or crack patterns of different crystal components in rocks.
  • the color difference ⁇ E between the characteristic portion and the non-characteristic portion of the pattern layer is preferably 1.3 or more.
  • the decorative board of the present invention is characterized in that the decorative sheet of the present invention is provided on the adherend.
  • the method for producing a decorative sheet of the present invention includes a laminating step of laminating a pattern layer having a characteristic portion and a non-characteristic portion and a transparent resin layer on one of the base materials in at least this order, and the above-mentioned transparency. Embossing is performed from the side of the resin layer opposite to the side having the pattern layer, and a recess (D 1 ) synchronized with the characteristic portion of the pattern layer is formed on the side of the transparent resin layer opposite to the side having the pattern layer.
  • the pattern layer has a shaping step of shaping a recess (D 2 ) located in the stacking direction of the recess (D 1 ) on the side opposite to the side having the base material, and the recess (D 1 ).
  • the depth H of is larger than the depth h of the recess (D 2).
  • the present invention can provide a decorative sheet having an extremely excellent design in which the pattern of the pattern layer and the recess are synchronized.
  • FIG. 1 It is sectional drawing which shows typically an example of the decorative sheet of this invention.
  • FIG. 1 A) and (b) are sectional views schematically showing a preferable example of the decorative sheet of the present invention.
  • FIG. 1 A) to (c) are cross-sectional views schematically showing an example of the decorative sheet of the present invention.
  • (A) is a perspective view schematically showing an example of the decorative sheet of the present invention
  • (b) is a top view schematically showing an example of the decorative sheet of the present invention
  • (c) is the present invention.
  • the decorative sheet of the present invention has at least a pattern layer, a transparent resin layer, a transparent thermoplastic resin layer, and a surface protective layer on one of the base materials in this order.
  • FIG. 1 is a cross-sectional view schematically showing an example of a decorative sheet.
  • the decorative sheet 10 has at least a pattern layer 2 and a transparent resin layer 3 on one of the base materials 1 in this order.
  • the pattern layer 2 has a feature portion 2a and a non-feature portion 2b.
  • the transparent resin layer 3 has a recess (D 1 ) synchronized with the characteristic portion of the pattern layer 2 on the side opposite to the side having the pattern layer 2, and the pattern layer 2 is on the side having the base material 1.
  • D 1 recess
  • the decorative sheet 10 of the present invention has a base material 1.
  • the base material 1 is not particularly limited, but preferably contains a non-halogen-based thermoplastic resin.
  • non-halogen thermoplastic resin examples include low-density polyethylene (including linear low-density polyethylene), medium-density polyethylene, high-density polyethylene, ethylene- ⁇ -olefin copolymer, homopolypropylene, polymethylpentene, polybutene, and ethylene-.
  • Olefin-based thermoplastic resins such as propylene copolymers, propylene-butene copolymers, ethylene-vinyl acetate copolymers, ethylene-vinyl acetate copolymer saponified products, or mixtures thereof, polyethylene terephthalates, polybutylene terephthalates, Polyethylene naphthalate, polyethylene naphthalate-isophthalate copolymer, thermoplastic ester resin such as polycarbonate and polyarylate, acrylic such as methyl polymethacrylate, ethyl polymethacrylate, ethyl polyacrylate, butyl polyacrylate and the like Examples thereof include based thermoplastic resins, polyamide-based thermoplastic resins such as nylon-6 and nylon-66, and polyimides, polyurethanes, polystyrenes, acrylonitrile-butadiene-styrene resins and the like. These non-halogen thermoplastic resins may be used alone or in combination of two or more
  • the base material 1 may be colored.
  • a colorant pigment or dye
  • the colorant for example, inorganic pigments such as titanium dioxide, carbon black and iron oxide, organic pigments such as phthalocyanine blue, and various dyes can be used. These can be selected from one or more of known or commercially available ones.
  • the amount of the colorant added may be appropriately set according to the desired color and the like.
  • the base material 1 contains various additives such as a filler, a matting agent, a foaming agent, a flame retardant, a lubricant, an antistatic agent, an antioxidant, an ultraviolet absorber, and a light stabilizer, if necessary. May be.
  • the thickness of the base material 1 is not particularly limited, but is preferably 40 ⁇ m or more and 200 ⁇ m or less.
  • the base material 1 may be composed of either a single layer or a multilayer.
  • the decorative sheet 10 has a pattern layer 2.
  • the pattern layer 2 is a layer that imparts decorativeness to the decorative sheet 10.
  • the pattern layer 2 may be, for example, a pattern layer formed by printing various patterns using ink and a printing machine, or a layer in which a concealing layer and a pattern layer are combined. good.
  • the concealing layer when the above-mentioned base material 1 is colored or has uneven color, it is possible to give an intended color and adjust the surface color.
  • stone patterns that imitate the surface of rocks such as wood grain patterns and marble patterns (for example, Travertin marble patterns), fabric patterns that imitate cloth textures and cloth-like patterns, tiled patterns, and brickwork A pattern or the like, or a pattern such as a parquet or a patchwork in which these are combined can be added to the decorative sheet.
  • These patterns are formed by multicolor printing with ordinary yellow, red, blue, and black process colors, and also by multicolor printing with special colors prepared by preparing the individual colors that make up the pattern. NS.
  • a binder resin mixed with a colorant such as a pigment or a dye, an extender pigment, a solvent, a stabilizer, a plasticizer, a catalyst, a curing agent or the like is used.
  • the binder resin is not particularly limited, and for example, urethane resin, acrylic resin, urethane-acrylic resin, urethane-acrylic copolymer resin, vinyl chloride / vinyl acetate copolymer resin, vinyl chloride / vinyl acetate / acrylic common weight. Combined resin, acrylic resin, polyester resin, nitrocellulose resin and the like are preferably mentioned. As the binder resin, any one of these can be used alone or in combination of two or more.
  • colorants examples include carbon black (black), iron black, titanium white, antimony white, yellow lead, titanium yellow, petals, cadmium red, ultramarine, cobalt blue and other inorganic pigments, quinacridone red, isoindolinone yellow, etc.
  • Organic pigments such as phthalocyanine blue, metal pigments made of scaly foil pieces such as dyes, aluminum and brass, titanium dioxide-coated mica, and pearl pigments made of scaly foil pieces such as basic lead carbonate are preferable. Can be mentioned. These can be used alone or in combination of two or more.
  • the pattern layer 2 has a feature portion 2a and a non-feature portion 2b.
  • the feature portion 2a refers to a portion having a feature capable of recognizing the pattern of the pattern layer 2.
  • the pattern layer 2 has a wood grain pattern
  • the wood grain conduits, knots, annual rings, and spots correspond to the pattern.
  • the pattern (crack pattern) expressed by stripes or cracks of different crystal components in the rock corresponds to it.
  • the non-feature portion 2b means a portion other than the feature portion 2a.
  • the color difference ⁇ E between the feature portion 2a and the non-feature portion 2b is preferably 1.3 or more. By setting such a color difference ⁇ E, the design can be made more excellent.
  • the color difference ⁇ E is more preferably 1.5 or more, further preferably 1.8 or more, and particularly preferably 2.0 or more.
  • the method for measuring and calculating the color difference ⁇ E is as follows.
  • L * a * b * color-based L * , a * and b * of the characteristic portion 2a and the non-characteristic portion 2b are used with a spectrocolorimeter (SE6000 manufactured by Nippon Denshoku Kogyo Co., Ltd.).
  • SE6000 manufactured by Nippon Denshoku Kogyo Co., Ltd.
  • the incident angle is 10 degrees (the normal direction of the surface on the transparent resin layer 3 side) to the surface of the decorative sheet 10 on the side having the transparent resin layer 3 (the side having the surface protective layer when the surface protective layer 4 is provided).
  • L * in the characterizing portion 2a, a * and b * respectively L 1 *, a 1 * and b 1 * and then, L * in the non-characteristic part 2b, a * and b L 2 * *, respectively, a Let 2 * and b 2 * .
  • the "L * a * b * color system” means the color system standardized by the CIE (Commission Internationale de l'Eclairage) and adopted in JIS Z8781-4: 2013. Further, in the L * a * b * color system, the lightness is represented by L * , and the chromaticity indicating the hue and saturation is represented by a * and b * .
  • the thickness of the pattern layer 2 is not particularly limited, and is preferably 0.1 ⁇ m or more, more preferably 0.5 ⁇ m or more and 600 ⁇ m or less, for example. When the thickness of the pattern layer 2 is within the above range, an excellent design can be imparted to the decorative sheet 10 and a concealing property can be imparted.
  • Examples of the method for forming the pattern layer 2 include a gravure printing method, an offset printing method, a screen printing method, a flexographic printing method, an electrostatic printing method, and an inkjet printing method.
  • various methods such as a roll coating method, a knife coating method, an air knife coating method, a die coating method, a lip coating method, a comma coating method, a kiss coating method, a flow coating method, and a dip coating method are used.
  • a coating method and the like can also be mentioned.
  • the decorative sheet 10 has a transparent resin layer 3.
  • the transparent resin layer 3 is preferably a layer formed of a thermoplastic resin.
  • the transparent resin layer 3 is not particularly limited as long as the pattern layer 2 can be seen, and includes any of colorless transparent, colored transparent, translucent and the like.
  • thermoplastic resin examples include olefin resins such as polyethylene, polypropylene, polybutene, polymethylpentene, and olefin-based thermoplastic elastomers, polyethylene terephthalate, polybutylene terephthalate, polyethylene narefurate, and ethylene glycol-terephthalic acid-isophthalic acid co-weight.
  • olefin resins such as polyethylene, polypropylene, polybutene, polymethylpentene, and olefin-based thermoplastic elastomers
  • polyethylene terephthalate polybutylene terephthalate
  • polyethylene narefurate examples include ethylene glycol-terephthalic acid-isophthalic acid co-weight.
  • polyester resin such as polyester thermoplastic elastomer, polymethyl (meth) acrylate, methyl (meth) acrylate-butyl (meth) acrylate copolymer
  • acrylic resins such as methyl (meth) acrylate-styrene copolymer resin
  • polycarbonate resins polyvinyl chloride, polystyrene, and ionomers.
  • polyethylene or polypropylene is more preferable because it has high tensile strength, excellent chemical resistance, and excellent production process.
  • (meth) acrylate means acrylate or methacrylate.
  • the polyethylene may be a homopolymer of ethylene, or an ⁇ -olefin such as ethylene and another comonomer copolymerizable with ethylene (for example, propylene, 1-butene, 1-hexene, 1-octene). It may be a copolymer with vinyl acetate, vinyl alcohol, etc.).
  • the polyethylene resin include high-density polyethylene (HDPE), medium-density polyethylene (MDPE), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), ultra-low-density polyethylene (VLDPE), and ultra-high-density polyethylene (Ultra-high-density polyethylene).
  • HDPE high-density polyethylene
  • MDPE medium-density polyethylene
  • LDPE low-density polyethylene
  • LLDPE linear low-density polyethylene
  • VLDPE ultra-low-density polyethylene
  • UHMWPE crosslinked polyethylene
  • the polypropylene may be a homopolymer of propylene, or ⁇ -olefin such as ethylene, 1-butene, 1-hexene, 1-octene, etc., which can be copolymerized with propylene. It may be a copolymer with vinyl acetate, vinyl alcohol, etc.). These polypropylenes may be used alone or in combination of two or more. In the present invention, a homopolymer of propylene (homopolypropylene) is particularly preferable from the viewpoint of excellent scratch resistance and bendability.
  • the transparent resin layer 3 may be composed of one layer or two or more layers.
  • the thickness of the transparent resin layer 3 is preferably 30 ⁇ m or more and 150 ⁇ m or less, and more preferably 40 ⁇ m or more and 120 ⁇ m or less, from the viewpoint of obtaining excellent scratch resistance and bending workability.
  • the total thickness of the transparent resin layer 3 is preferably 30 ⁇ m or more and 150 ⁇ m or less, and more preferably 40 ⁇ m or more and 120 ⁇ m or less.
  • the types of resins to be formed may be the same or different, and the thickness of the base material composed of the plurality of resins may be the same or different. You may.
  • the method of laminating the transparent resin layer 3 in two or more layers is not limited to a general method, and examples thereof include a dry laminating method and an extrusion heat laminating method.
  • the transparent resin layer 3 may be subjected to surface treatment such as saponification treatment, glow discharge treatment, corona discharge treatment, plasma discharge treatment, ultraviolet (UV) treatment, and flame treatment within a range not deviating from the gist of the present invention. ..
  • the decorative sheet 10 preferably has a surface protective layer on the side opposite to the side of the transparent resin layer 3 having the pattern layer 2.
  • 2 (a) and 2 (b) are cross-sectional views schematically showing a preferable example of the decorative sheet of the present invention.
  • the decorative sheet 10 has at least a pattern layer 2, a transparent resin layer 3, and a surface protective layer 4 on one of the base materials 1. And in this order.
  • the surface protective layer 4 may have a recess as shown in FIG. 2 (a), or may not have a recess as shown in FIG. 2 (b).
  • the surface protective layer 4 is a layer that imparts durability (scratch resistance, stain resistance, weather resistance, etc.) to the decorative sheet 10, and by having the surface protective layer 4, it is possible to more preferably protect the pattern layer 2. Therefore, it is possible to suitably prevent deterioration of the design due to scratches on the decorative sheet 10 itself.
  • the surface protective layer 4 may have a single layer structure, a plurality of layer structures made of the same or different materials, or the materials shown below may be appropriately mixed.
  • the surface protective layer 4 is not particularly limited, and examples thereof include those made of a two-component curable resin and a crosslinked cured product of an ionizing radiation curable resin composition.
  • the crosslinked cured product is preferably transparent, and as long as it is transparent, it may be translucent or colored as long as the pattern layer 2 is visible.
  • the binder resin of the adhesive primer layer may be used.
  • the ionizing radiation curable resin includes, for example, an oligomer having a radically polymerizable unsaturated bond or a cationically polymerizable functional group in the molecule (hereinafter, also includes so-called prepolymer, macromonomer and the like) and / or a radical in the molecule.
  • Monomers having a polymerizable unsaturated bond or a cationically polymerizable functional group are preferably used.
  • the ionizing radiation means an electromagnetic wave or a charged particle having an energy capable of polymerizing or cross-linking a molecule, and usually, an electron beam (EB) or an ultraviolet ray (UV) is generally used.
  • EB electron beam
  • UV ultraviolet ray
  • the oligomer or monomer examples include compounds having a (meth) acryloyl group, a radically polymerizable unsaturated group such as a (meth) acryloyloxy group, and a cationically polymerizable functional group such as an epoxy group in the molecule. These oligomers and monomers can be used alone or in admixture of a plurality of types.
  • the said (meth) acryloyl group means an acryloyl group or a methacryloyl group.
  • oligomers having a radically polymerizable unsaturated group in the molecule include oligomers such as urethane (meth) acrylate, polyester (meth) acrylate, epoxy (meth) acrylate, melamine (meth) acrylate, and triazine (meth) acrylate. Can be preferably used, and urethane (meth) acrylate oligomers are more preferable.
  • molecular weight a molecular weight of about 2.5 to 100,000 is usually used.
  • a polyfunctional monomer is preferable, and a polyfunctional (meth) acrylate is more preferable.
  • the polyfunctional (meth) acrylate include diethylene glycol di (meth) acrylate, propylene glycol di (meth) acrylate, bisphenol A ethylene oxide-modified di (meth) acrylate, trimethylolpropane tri (meth) acrylate, and trimethylolpropane.
  • the polyfunctional monomer means a monomer having a plurality of radically polymerizable unsaturated groups.
  • the ionizing thermosetting resin composition contains an ionizing thermosetting resin component composed of a urethane acrylate oligomer and a polyfunctional monomer, and as the ionizing thermosetting resin component, a urethane acrylate oligomer / polyfunctional monomer (mass ratio). ) Is particularly preferably 6/4 to 9/1. Within this mass ratio range, scratch resistance can be made more excellent.
  • a monofunctional monomer may be appropriately used in addition to the ionizing radiation curable resin component. Examples of the monofunctional monomer include methyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, and phenoxyethyl (meth) acrylate.
  • the ionizing radiation curable resin composition When the ionizing radiation curable resin composition is crosslinked with ultraviolet rays, it is preferable to add a photopolymerization initiator to the ionizing radiation curable resin composition.
  • a photopolymerization initiator When the ionizing radiation curable resin composition is a resin system having a radically polymerizable unsaturated group, acetophenones, benzophenones, thioxanthones, benzoins, and benzoin methyl ethers are used alone or mixed as the photopolymerization initiator. Can be used.
  • the photopolymerization initiator includes an aromatic diazonium salt, an aromatic sulfonium salt, an aromatic iodonium salt, a metatheron compound, and a benzoin.
  • a sulfonic acid ester or the like can be used alone or as a mixture.
  • the amount of these photopolymerization initiators added is about 0.1 to 10 parts by mass with respect to 100 parts by mass of the ionizing radiation curable resin component.
  • additives may be further added to the ionizing radiation curable resin composition.
  • these additives include urethane resin, polyvinyl acetal resin, polyester resin, polyolefin resin, styrene resin, polyamide resin, polycarbonate resin, acetal resin, vinyl chloride-vinyl acetate copolymer resin, vinyl acetate resin, and acrylic.
  • Thermoplastic resins such as resins and cellulose resins, lubricants such as silicone resins, waxes and fluororesins, ultraviolet absorbers such as benzotriazole, benzophenone and triazine, light stabilizers such as hindered amine radical traps, dyes and pigments. It is a colorant or the like.
  • the electron beam source of ionizing radiation for example, various electron beam accelerators such as Cockcroft-Walton type, Van de Graaff type, resonance transformer type, insulated core transformer type, linear type, dynamistron type, and high frequency type are used. It can be used to irradiate electrons with an energy of 70 to 1000 keV.
  • the irradiation dose of ionizing radiation is preferably, for example, about 1 to 10 Mrad.
  • the ultraviolet source of the ionized radiation for example, a light source such as an ultra-high pressure mercury lamp, a high pressure mercury lamp, a low pressure mercury lamp, a carbon arc lamp, a black light, or a metal halide lamp can be used, and the wavelength of the ultraviolet rays is usually 190 to 380 nm. The wavelength range is mainly used.
  • the thickness of the surface protective layer 4 is not particularly limited, but a preferable lower limit is 0.1 ⁇ m, a preferable upper limit is 50 ⁇ m, a more preferable lower limit is 1 ⁇ m, and a more preferable upper limit is 35 ⁇ m. If the thickness of the surface protective layer 4 is less than 0.1 ⁇ m, sufficient durability (scratch resistance, stain resistance, weather resistance, etc.) may not be imparted, and if it exceeds 50 ⁇ m, the transmittance decreases. The visibility of the pattern in the pattern layer may decrease.
  • the decorative sheet 10 may have a primer layer, an adhesive layer, a backer layer, and the like, if necessary.
  • the primer layer can be formed by applying a known primer agent.
  • the primer include a urethane resin-based primer made of an acrylic-modified urethane resin (acrylic urethane-based resin) and the like, and a urethane-cellulose-based resin (for example, a resin obtained by adding hexamethylene diisocyanate to a mixture of urethane and nitrified cotton. ), A resin-based primer made of a block copolymer of acrylic and urethane, and the like. Additives may be added to the primer, if necessary.
  • the additive examples include a filler such as calcium carbonate and clay, a flame retardant such as magnesium hydroxide, an antioxidant, a lubricant, a foaming agent, an ultraviolet absorber, and a light stabilizer.
  • a filler such as calcium carbonate and clay
  • a flame retardant such as magnesium hydroxide, an antioxidant, a lubricant, a foaming agent, an ultraviolet absorber, and a light stabilizer.
  • the blending amount of the additive can be appropriately set according to the product characteristics.
  • the primer layer may contain an ultraviolet absorber, if necessary.
  • an ultraviolet absorber a known ultraviolet absorber can be appropriately selected and used.
  • the thickness of the primer layer is not particularly limited, but is preferably 0.01 to 10 ⁇ m, more preferably 0.1 to 1 ⁇ m, for example.
  • the adhesive layer is not particularly limited, and a known adhesive may be used.
  • a known adhesive may be used.
  • These adhesives may be used alone or in combination of two or more.
  • the thickness of the adhesive layer after drying is preferably about 0.1 to 30 ⁇ m, more preferably about 1 to 5 ⁇ m.
  • the decorative sheet 10 may have a backer layer on the lowermost layer of the base material 1 (the side opposite to the side on which the pattern layer 2 is laminated) from the viewpoint of imparting scratch resistance and impact resistance.
  • a backer layer a known backer layer disclosed in Japanese Patent Application Laid-Open No. 2014-188941 or the like can be appropriately selected and used.
  • the transparent resin layer 3 has a recess (D 1 ) synchronized with the characteristic portion 2a of the pattern layer 2 on the side opposite to the side having the pattern layer 2, and the pattern layer 2 is the base material 1.
  • the recess (D 2 ) located in the stacking direction of the recess (D 1) is provided.
  • the concave portion (D 1 ) has a shape synchronized with the characteristic portion 2a of the pattern layer 2.
  • the recess (D 1 ) may have a shape that is a model of the outer shell of the characteristic portion 2a of the pattern of the pattern layer 2, or a shape that simplifies the outer shell of the characteristic portion 2a of the pattern of the pattern layer 2 or the characteristic portion. It may have a similar shape in which the outer shell of 2a is reduced or enlarged.
  • the recess (D 1 ) is positioned so as to be synchronized with the feature portion 2a of the pattern layer 2.
  • 3 (a) to 3 (c) are cross-sectional views schematically showing an example of the decorative sheet of the present invention.
  • the positional relationship between the recess (D 1 ) and the feature portion 2a of the pattern layer 2 may be any of FIGS. 3 (a) to 3 (c). That is, as shown in FIG. 3 (a), in the stacking direction, and the characteristic portion 2a of the pattern layer 2, the recess (D 1), but may be positioned to overlap, shown in Fig. 3 (b) as a characteristic portion 2a of the pattern layer 2, recesses (D 1) and it may be located so as to partially overlap, as shown in FIG.
  • the picture layer 2 wherein portions 2a And the recess (D 1 ) may be positioned so as not to overlap.
  • the recess (D 1 ) is located in the vicinity of the feature portion 2a of the pattern layer 2 when viewed in a plan view.
  • the term "neighborhood" means that the position of the feature portion 2a and the position of the recess (D 1 ) having a shape corresponding to the feature portion 2a are 70 mm or less when viewed in a plan view. These can be appropriately set depending on the design of the pattern layer 2.
  • the tuning relationship between the recess (D 1 ) and the feature portion 2a does not necessarily have to be established on the entire surface of the design, and if the overall design feeling is not impaired, there is a partially untuned region. You may be.
  • the width of the recess (D 1 ) will be described later.
  • the recess (D 2 ) is located in the stacking direction of the recess (D 1). As shown in FIGS. 3 (a) to 3 (c), the recess (D 2 ) is provided at a position overlapping the recess (D 1) in the stacking direction.
  • the recess (D 2) as shown in FIG. 3 (a), the characteristic portion 2a of the pattern layer 2 may be formed recess (D 2), as shown in FIG. 3 (b)
  • a recess (D 2 ) may be formed from the feature portion 2a of the pattern layer 2 to the non-feature portion 2b, and as shown in FIG. 3 (c), the recess (D) is formed in the feature portion 2a of the pattern layer 2. 2 ) may not be formed (a recess (D 2 ) is formed in the non-characteristic portion 2b).
  • the depth H of the recess (D 1 ) is larger than the depth h of the recess (D 2).
  • the pattern of the pattern layer and the recess are synchronized to achieve an extremely excellent design.
  • the relationship between the depth H of the recess (D 1 ) and the depth h of the recess (D 2 ) is such that the recess (D 1 ) and the recess (D 1) located in the stacking direction (overlapping when viewed in a plan view) and the recess. Each is established with (D 2).
  • the ratio (h / H) of the depth h of the recess (D 2 ) to the depth H of the recess (D 1 ) is 0.25 or more and 0.60 from the viewpoint of giving a three-dimensional effect. It is preferably 0.26 or more and 0.55 or less, more preferably 0.28 or more and 0.50 or less, and particularly preferably 0.30 or more and 0.48 or less. preferable.
  • the depth H of the recess (D 1 ) may be a size that can give a three-dimensional effect, and is preferably 50 ⁇ m or more and 200 ⁇ m or less, and more preferably 55 ⁇ m or more and 190 ⁇ m or less.
  • the depth h of the recess (D 2 ) is, for example, preferably 13 ⁇ m or more and 100 ⁇ m or less, and more preferably 17 ⁇ m or more and 92 ⁇ m or less.
  • the numerical ranges of the depth H and the depth h do not necessarily have to be established in all the recesses (D 1 ) and the recesses (D 2 ), and if the overall design feeling is not impaired, the numerical ranges are described.
  • recesses (D 1 ) and recesses (D 2 ) may be recesses (D 1 ) and recesses (D 2 ) that do not satisfy the above conditions.
  • some recesses (D 1 ) and recesses (D 2 ) that are synchronized may not satisfy the magnitude relationship of depth H> depth h as long as the overall design feeling is not impaired.
  • recesses (D 1 ) and recesses (D 2 ) having an arbitrary area of 10 cm ⁇ 10 cm located in the stacking direction are confirmed.
  • it is preferable that less than 30% of the total does not satisfy the magnitude relationship of depth H> depth h.
  • Such confirmation can be performed by applying an electron microscope described later and its measurement conditions.
  • the width W of the recess (D 1 ) depends on the pattern formed on the pattern layer 2, but is preferably 400 ⁇ m or more and 2000 ⁇ m or less, and more preferably 500 ⁇ m or more and 1500 ⁇ m or less.
  • the width w of the recess (D 2 ) is, for example, preferably 5 ⁇ m or more and 400 ⁇ m or less, and more preferably 10 ⁇ m or more and 100 ⁇ m or less.
  • the decorative sheet 10 is positioned in the stacking direction of the recess (D 1) and the recess (D 2), (a D 3) picture layer 2 side of the concave portion of the substrate 1, opposite to the pattern layer 2 of the substrate 1 preferably it has a recess (and D 4) of the.
  • the depth of the recess is preferably reduced in the order of the recess (D 1 ), the recess (D 2 ), the recess (D 3 ), and the recess (D 4).
  • the decorative sheet 10 has a surface protective layer 4, the recess (D 1) and the recess (D 2) opposite to the recess and the transparent resin layer 3 of the surface protective layer 4 positioned in the stacking direction of the (D 5 If there is a recess (D 5 ), the depth of the recess (D 5), the recess (D 1 ), the recess (D 2 ), the recess (D 3 ), and the recess (D 4 ) can be reduced in this order. preferable. By having such recesses (D 1 to D 5 ), it is possible to preferably achieve a design in which the pattern of the pattern layer and the recesses are synchronized.
  • Such recesses (D 1 to D 5 ) can be suitably formed by the method for producing a decorative sheet of the present invention, which will be described later.
  • the relationship of the depth of the recess (D 1 ⁇ D 5) are established respectively between the position in the stacking direction to each other (overlap when viewed from the top) the recess (D 1 ⁇ D 5).
  • FIG. 4A is a perspective view schematically showing an example of the decorative sheet of the present invention
  • FIG. 4B is a top view schematically showing an example of the decorative sheet of the present invention
  • FIG. 4C is a top view schematically showing an example of the decorative sheet of the present invention.
  • the recess formed on the surface of the decorative sheet 10 is selected.
  • FIG. 4B the major axis and the minor axis of the selected recess are determined.
  • the cut surface is observed with an electron microscope, and the widths (W and w) and depths of the recesses (D 1 ) and (D 2) are observed. (H and h) are measured.
  • the a depth H of the concave portion (D 1) means the vertical distance from the transparent resin layer 3 of the surface to the deepest recesses (D 1), the recess (D 2 )
  • Depth h means the vertical distance from the surface of the pattern layer 2 to the deepest part of the recess (D 2).
  • the long axis of the recess means a place where the length of a straight line connecting two points on the outer circumference of the recess is maximum, and the short axis of the recess means a place where the length of the long axis is maximum in the vertical direction.
  • the minor axis of the recess formed on the surface of the decorative sheet 10 coincides with the width W of the recess (D 1).
  • Width W is smaller than the minor axis of the recess formed on the surface of the decorative sheet 10. In this case, the cross section cut along the short axis of the recess can be observed and measured with an electron microscope.
  • the width W and depth H of the concave portion (D 1), and the width w and depth h of the recesses (D 2) is randomly selected ten recesses formed on the surface of the decorative sheet 10, It means an average value measured and calculated by the method described above.
  • a shape analysis laser microscope (measurement unit "VK-X1050", pedestal “VK-D1", controller "VK-X1000” (manufactured by KEYENCE)) is used at a magnification of 300 times. It can be measured by observing or the like.
  • the resin paint for example, an organic solvent-based paint having excellent quick-drying properties made of urethane resin, acrylic urethane resin, epoxy resin, polyester resin, etc., a water-based paint that is friendly to the natural environment, work environment, etc. can be used. Among them, a water-based paint mixed with a urethane-based resin is preferable. Further, as the colorant, those described in the above-mentioned pattern layer and the like can be used. Further, as a method of coloring with the resin paint, for example, the method described in Japanese Patent No. 4569720 can be applied.
  • the method for producing a decorative sheet of the present invention includes a laminating step of laminating a pattern layer having a characteristic portion and a non-characteristic portion and a transparent resin layer at least in this order on one of the base materials, and the transparent resin layer. Embossing is performed from the side opposite to the side having the pattern layer, and the recess (D 1 ) synchronized with the characteristic portion of the pattern layer is formed on the side opposite to the side having the pattern layer of the transparent resin layer, and the above.
  • the pattern layer has a shaping step of shaping a recess (D 2 ) located in the stacking direction of the recess (D 1 ) on the side opposite to the side having the base material, and the depth of the recess (D 1).
  • the value H is larger than the depth h of the recess (D 2).
  • the laminating step is a step of laminating a pattern layer and a transparent resin layer on one of the base materials in at least this order.
  • the above-mentioned base material 1, the pattern layer 2 and the transparent resin layer 3 can be used, and the pattern layer 2 and the transparent resin layer 3 are laminated on one of the base materials 1 in at least this order. Just do it. Further, it is preferable to laminate the surface protective layer 4 on the side of the transparent resin layer 3 opposite to the side having the pattern layer 2.
  • the above-mentioned adhesive layer or primer layer may be provided on one surface or between the layers of each of the above-mentioned layers.
  • the shaping step is a step of embossing from the side opposite to the side having the pattern layer of the transparent resin layer to shape a concave portion synchronized with the characteristic portion of the pattern layer.
  • Examples of the embossing include a well-known single-wafer embossing method and a method of embossing with a rotary embossing machine.
  • As the pattern used in the embossing process a design synchronized with the above-mentioned pattern layer 2 can be appropriately selected and used.
  • the temperature at the time of the above embossing is not particularly limited, but a temperature at which the so-called embossing return, in which the recesses disappear during the heat-pressing molding, is preferable.
  • the decorative sheet produced by the method for producing a decorative sheet of the present invention has a pattern layer and a transparent resin layer at least in this order on one of the base materials, and the transparent resin layer is a characteristic portion of the pattern layer.
  • has a recess (D 1) which is synchronized with the picture pattern layers has a recess (D 2) located in the stacking direction of the recess (D 1), the recess (D 1) of the depth H concave portion (D Since it is larger than the depth h of 2), it has an extremely excellent design in which the pattern of the pattern layer and the recess are synchronized.
  • the decorative board of the present invention is characterized in that the decorative sheet of the present invention is provided on the adherend.
  • adherends examples include wood boards such as single wood boards, wood plywood boards, particle boards, and MDF (medium density fiber boards); plaster boards such as plaster boards and plaster slag boards; calcium silicate boards and asbestos slate boards.
  • Cement boards such as lightweight foamed concrete boards and hollow extruded cement boards; fiber cement boards such as pulp cement boards, asbestos cement boards, and wood piece cement boards; ceramic boards such as pottery, porcelain, earthenware, glass, and amber; iron plates, zinc-plated steel plates , Metal plates such as polyvinyl chloride sol coated steel plate, aluminum plate, copper plate; thermoplastic resin plates such as polyolefin resin plate, polyvinyl chloride resin plate, acrylic resin plate, ABS plate, polycarbonate plate; phenol resin plate, urea resin plate, Thermo-curable resin plates such as unsaturated polyester resin plate, polyurethane resin plate, epoxy resin plate, melamine resin plate; phenol resin, urea resin, unsaturated polyester resin, polyurethane resin, epoxy resin, melamine resin, dially
  • thermoplastic resin plate and the thermocurable resin plate may be used as a coloring material (pigment or dye), a filler such as wood powder or calcium carbonate, a matting agent such as silica, a foaming agent, a flame retardant, or a talc.
  • a coloring material pigment or dye
  • a filler such as wood powder or calcium carbonate
  • a matting agent such as silica
  • a foaming agent such as silica
  • flame retardant such as a flame retardant
  • talc a talc
  • additives such as lubricants such as, antistatic agents, antioxidants, ultraviolet absorbers, and light stabilizers may be contained.
  • the thickness of the adherend is not particularly limited.
  • the method of laminating the decorative sheet of the present invention on the adherend is not particularly limited, and examples thereof include means of laminating via the above-mentioned primer layer and the above-mentioned adhesive layer. Be done.
  • Example 1 Prepare a base material (60 ⁇ m thick, colored polypropylene sheet) that has been subjected to corona discharge treatment on both sides, and apply ink to add 5 parts by mass of hexamethylene diisocyanate to 100 parts by mass of urethane-nitrated cotton mixed resin on one side. A 2 ⁇ m-thick primer layer is formed, and an ink to which 8 parts by mass of hexamethylene diisocyanate and 70 parts by mass of titanium oxide is added to 100 parts by mass of acrylic urethane resin is applied to the other surface to form a 2 ⁇ m-thick concealing layer. Formed.
  • an ink obtained by adding a coloring pigment to an acrylic urethane resin was applied onto the concealing layer to form a pattern layer (wood grain pattern) having a thickness of 1 ⁇ m.
  • an ink containing 11 parts by mass of hexamethylene diisocyanate was applied to 100 parts by mass of an acrylic polyol-urethane mixed resin to form an adhesive layer having a thickness of 2 ⁇ m.
  • a transparent resin layer having a thickness of 100 ⁇ m is formed on the adhesive layer by heating and melt-extruding a polypropylene resin with a T-die extruder, and hexagon is added to 100 parts by mass of an acrylic polyol-urethane mixed resin on the transparent resin layer.
  • An ink containing 6 parts by mass of methylene diisocyanate is applied to form a primer layer having a thickness of 2 ⁇ m, and then an acrylate-based electron beam curable resin is gravure-coated on the primer layer to a solid content of 30 g / m 2 .
  • an electron beam is irradiated under the conditions of an oxygen concentration of 200 ppm, an acceleration voltage of 165 KeV, and 5 mad to form a surface protective layer made of an electron beam curable resin, and further embossing is performed from the surface protective layer side.
  • a decorative sheet was prepared.
  • the color difference ⁇ E between the characteristic portion and the non-characteristic portion of the pattern layer (design layer) was 3.0.
  • Examples 2 to 10 Comparative Example 1
  • a decorative sheet was produced in the same manner as in Example 1 except that the sizes of the recesses to be shaped were changed.
  • the transparent resin layer has a recess (D 1 ) synchronized with the characteristic portion of the pattern layer and a recess (D 2 ) located in the stacking direction of the recess (D 1). It was confirmed that the depth H of D 1 ) was larger than the depth h of the recess (D 2 ), so that the pattern of the pattern layer and the recess were synchronized to produce an extremely excellent design.
  • Base material Picture layer 2a Characteristic part 2b Non-characteristic part 3 Transparent resin layer 4 Surface protection layer 10 Decorative sheet

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
PCT/JP2021/002264 2020-01-24 2021-01-22 化粧シート、化粧板及び化粧シートの製造方法 Ceased WO2021149803A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR1020227027523A KR20220130722A (ko) 2020-01-24 2021-01-22 화장 시트, 화장판 및 화장 시트의 제조 방법
EP21744624.4A EP4108450A4 (en) 2020-01-24 2021-01-22 Decorative sheet, decorative panel, and manufacturing method for decorative sheet
US17/794,762 US20230071952A1 (en) 2020-01-24 2021-01-22 Decorative sheet, decorative panel, and manufacturing method for decorative sheet
JP2021572818A JPWO2021149803A1 (https=) 2020-01-24 2021-01-22
CN202180009775.3A CN114981075A (zh) 2020-01-24 2021-01-22 装饰片、装饰板和装饰片的制造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2020-009981 2020-01-24
JP2020009981 2020-01-24
JP2020165941 2020-09-30
JP2020-165941 2020-09-30

Publications (1)

Publication Number Publication Date
WO2021149803A1 true WO2021149803A1 (ja) 2021-07-29

Family

ID=76991795

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2021/002264 Ceased WO2021149803A1 (ja) 2020-01-24 2021-01-22 化粧シート、化粧板及び化粧シートの製造方法

Country Status (6)

Country Link
US (1) US20230071952A1 (https=)
EP (1) EP4108450A4 (https=)
JP (1) JPWO2021149803A1 (https=)
KR (1) KR20220130722A (https=)
CN (1) CN114981075A (https=)
WO (1) WO2021149803A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023066746A (ja) * 2021-10-29 2023-05-16 紀伊産業株式会社 加飾シートおよびその製法、並びにそれを用いた加飾成形体
EP4497592A4 (en) * 2022-03-23 2025-10-15 Toppan Holdings Inc MANUFACTURING PROCESS FOR DECOR FILM AND DECOR FILM

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5610371A (en) * 1979-07-05 1981-02-02 Noda Plywood Mfg Co Ltd Manufacture of decorative panel board
JPH07156596A (ja) * 1993-12-08 1995-06-20 Dainippon Printing Co Ltd 転写シート及びこれを用いた凹凸模様を有する化粧材
JPH09254348A (ja) * 1996-03-19 1997-09-30 Toppan Printing Co Ltd 化粧板およびその製造方法
JP4569720B2 (ja) 2000-04-05 2010-10-27 大日本印刷株式会社 床材用化粧材
JP2012250459A (ja) * 2011-06-03 2012-12-20 Riken Technos Corp 積層フィルムおよび積層フィルムの製造方法
JP2014188941A (ja) 2013-03-28 2014-10-06 Dainippon Printing Co Ltd 化粧シート及び化粧材
JP2016182748A (ja) 2015-03-26 2016-10-20 凸版印刷株式会社 化粧シート、同調エンボス化粧材、及び化粧シートの製造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5145645B2 (ja) * 2006-03-30 2013-02-20 大日本印刷株式会社 化粧シートおよびそれを用いた化粧板
JP5287420B2 (ja) * 2009-03-27 2013-09-11 大日本印刷株式会社 化粧シート及び化粧板
JP6819102B2 (ja) * 2015-07-10 2021-01-27 大日本印刷株式会社 化粧シート、化粧板及び化粧板の製造方法
NL2016215B1 (en) * 2016-02-03 2017-08-11 Trespa Int Bv A method for manufacturing a registered embossed decorative panel
US20210283879A1 (en) * 2016-09-29 2021-09-16 Dai Nippon Printing Co., Ltd. Decorative sheet and decorative material using same
JP7039292B2 (ja) * 2017-12-28 2022-03-22 東リ株式会社 内装シート、及びその製造方法
JP2019142202A (ja) * 2018-02-23 2019-08-29 大日本印刷株式会社 発泡積層シート
DE102020007039A1 (de) * 2020-10-16 2022-04-21 Parador Gmbh Verfahren zur Herstellung einer Polyvinylchlorid-freien Deckschicht, Polyvinylchlorid-freie Deckschicht sowie Belagselement

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5610371A (en) * 1979-07-05 1981-02-02 Noda Plywood Mfg Co Ltd Manufacture of decorative panel board
JPH07156596A (ja) * 1993-12-08 1995-06-20 Dainippon Printing Co Ltd 転写シート及びこれを用いた凹凸模様を有する化粧材
JPH09254348A (ja) * 1996-03-19 1997-09-30 Toppan Printing Co Ltd 化粧板およびその製造方法
JP4569720B2 (ja) 2000-04-05 2010-10-27 大日本印刷株式会社 床材用化粧材
JP2012250459A (ja) * 2011-06-03 2012-12-20 Riken Technos Corp 積層フィルムおよび積層フィルムの製造方法
JP2014188941A (ja) 2013-03-28 2014-10-06 Dainippon Printing Co Ltd 化粧シート及び化粧材
JP2016182748A (ja) 2015-03-26 2016-10-20 凸版印刷株式会社 化粧シート、同調エンボス化粧材、及び化粧シートの製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP4108450A4

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023066746A (ja) * 2021-10-29 2023-05-16 紀伊産業株式会社 加飾シートおよびその製法、並びにそれを用いた加飾成形体
JP7821973B2 (ja) 2021-10-29 2026-03-02 紀伊産業株式会社 加飾シートおよびその製法、並びにそれを用いた加飾成形体
EP4497592A4 (en) * 2022-03-23 2025-10-15 Toppan Holdings Inc MANUFACTURING PROCESS FOR DECOR FILM AND DECOR FILM

Also Published As

Publication number Publication date
US20230071952A1 (en) 2023-03-09
JPWO2021149803A1 (https=) 2021-07-29
EP4108450A4 (en) 2024-07-03
EP4108450A1 (en) 2022-12-28
CN114981075A (zh) 2022-08-30
KR20220130722A (ko) 2022-09-27

Similar Documents

Publication Publication Date Title
JP7480542B2 (ja) 化粧シート、及び、化粧材
JP2019038195A (ja) 暗色絵柄化粧シート及びこれを用いた化粧部材
KR20220005486A (ko) 투명성 수지 필름, 투명성 수지 필름의 제조 방법, 및 화장재
JP7768309B2 (ja) 化粧材及び化粧材の製造方法
WO2021149803A1 (ja) 化粧シート、化粧板及び化粧シートの製造方法
JP6582380B2 (ja) 化粧シート
JP4858053B2 (ja) 化粧シート
JP7409371B2 (ja) 化粧材
JP2022151531A (ja) 化粧シート及び化粧材
JP7753651B2 (ja) 化粧シートの製造方法
JP7679664B2 (ja) 化粧シート、及び、化粧板
JP7679663B2 (ja) 化粧シート、及び、化粧板
JP7626061B2 (ja) 化粧材及び化粧部材
JP7666196B2 (ja) 化粧シート、及び、化粧板
JP7666197B2 (ja) 化粧シート、及び、化粧板
JP7533092B2 (ja) 化粧シートの製造方法及び化粧シートの製造装置
JP7533091B2 (ja) 化粧シートの製造方法及び化粧シートの製造装置
JP2019038194A (ja) 化粧シート及びこれを用いた化粧材
WO2023007757A1 (ja) 化粧シート、及び、化粧板
JP7225635B2 (ja) 化粧材
JP4585902B2 (ja) 化粧シート
WO2020075565A1 (ja) 透明性樹脂フィルム、化粧板及び化粧板の製造方法
JP7119825B2 (ja) 化粧シート及び化粧材
JP2024139694A (ja) 化粧シート
JP2024139695A (ja) 化粧シート

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21744624

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
ENP Entry into the national phase

Ref document number: 2021572818

Country of ref document: JP

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 20227027523

Country of ref document: KR

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2021744624

Country of ref document: EP

Effective date: 20220824