WO2021093650A1 - Sputtering device - Google Patents

Sputtering device Download PDF

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Publication number
WO2021093650A1
WO2021093650A1 PCT/CN2020/126456 CN2020126456W WO2021093650A1 WO 2021093650 A1 WO2021093650 A1 WO 2021093650A1 CN 2020126456 W CN2020126456 W CN 2020126456W WO 2021093650 A1 WO2021093650 A1 WO 2021093650A1
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WO
WIPO (PCT)
Prior art keywords
workpiece
sputtering
processed
base
reaction chamber
Prior art date
Application number
PCT/CN2020/126456
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French (fr)
Chinese (zh)
Inventor
李默林
Original Assignee
北京北方华创微电子装备有限公司
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Publication date
Application filed by 北京北方华创微电子装备有限公司 filed Critical 北京北方华创微电子装备有限公司
Priority to KR1020227014726A priority Critical patent/KR20220074934A/en
Priority to KR1020237040688A priority patent/KR20230164245A/en
Publication of WO2021093650A1 publication Critical patent/WO2021093650A1/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3435Applying energy to the substrate during sputtering
    • C23C14/345Applying energy to the substrate during sputtering using substrate bias
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/50Substrate holders
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/54Controlling or regulating the coating process
    • C23C14/541Heating or cooling of the substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks

Definitions

  • the invention belongs to the field of sputtering technology, and particularly relates to a sputtering device.
  • the copper interconnection process is an indispensable process for the back-end manufacturing of the chip in the prior art.
  • the copper interconnection process mainly includes the following processes, namely, first depositing a diffusion barrier layer in the etched holes, then depositing a copper seed layer, and finally The holes are filled by electroplating, and the copper interconnection lines are finally formed.
  • the aspect ratio of the via or trench
  • PVD Physical Vapor Deposition
  • the PVD equipment used in the prior art copper reflow technology usually includes a ring-shaped reaction chamber, a support pedestal arranged in the reaction chamber for carrying a wafer, and a target material arranged above the support pedestal.
  • a direct current (DC) power supply will apply DC power to the target material to make it a negative pressure with respect to the grounded reaction chamber, thereby discharging the reaction gas (such as argon) in the reaction chamber.
  • Plasma is generated and the positively charged argon ions are attracted to the negatively biased target.
  • metal atoms will escape the target surface and be deposited on the wafer.
  • a heating lamp is usually added to the reaction chamber to heat the wafer by means of thermal radiation after the film deposition process is completed.
  • the heating efficiency of this heating method is low, resulting in a slower heating rate of the wafer, resulting in a longer cycle time for the reflow process (usually more than 30 minutes). If multiple reflow process cycles are required, it will be expensive. The time is longer, which seriously affects the yield.
  • the embodiment of the present invention aims to solve at least one of the technical problems in the prior art, and proposes a sputtering device, which can increase the heating rate, so that the workpiece to be processed can quickly rise in temperature, thereby effectively shortening the reflow process cycle time and improving Productivity.
  • a sputtering device which includes a reaction chamber, in which a susceptor for carrying a workpiece to be processed is provided, and further includes:
  • a thimble mechanism arranged in the reaction chamber, the thimble mechanism can generate a relative lifting movement with the base, so as to be able to lift from the base and carry the workpiece to be processed;
  • a microwave heating mechanism is arranged in the reaction chamber, the microwave heating mechanism includes a moving unit and a microwave transmitter connected to it, wherein the moving unit is used when the workpiece to be processed is carried by the ejector mechanism , Moving the microwave transmitter below the workpiece to be processed, so that the microwave transmitter can heat the workpiece to be processed by emitting microwaves toward the workpiece.
  • the reaction chamber includes:
  • a sputtering chamber where a target material and a sputtering mechanism are arranged on the top of the sputtering chamber for performing a sputtering process on the workpiece to be processed;
  • the storage cavity is located below the sputtering cavity, the microwave heating mechanism is arranged in the storage cavity, and is used to perform a reflow process on the workpiece to be processed, and in the storage cavity and the sputtering cavity There is a through hole between the two to communicate with each other, the base is disposed in the receiving cavity and corresponds to the through hole, and the base is liftable to pass through the through hole Move between the sputtering cavity and the receiving cavity.
  • the sputtering mechanism includes:
  • the direct current power supply is connected to the target material and is used to apply a bias voltage to the target material.
  • the thimble mechanism can be raised and lowered, or the thimble mechanism is fixed relative to the base; and, the thimble mechanism includes a plurality of thimbles, and the plurality of thimbles pass through the base. In the seat or under the base.
  • the multiple thimbles are made of materials that can absorb microwaves.
  • the material that can absorb microwaves includes ceramics.
  • the mobile unit includes:
  • the rotating arm is vertically arranged in the reaction chamber and located on one side of the base, and the rotating arm can rotate around its axis;
  • the transmission arm is connected with the rotating arm, and the microwave transmitter is arranged on the transmission arm.
  • the electrical connection line of the microwave transmitter is led out of the reaction chamber through the rotating arm.
  • the transmission arm is made of metal material, and a cooling device is also provided on the transmission arm for cooling the microwave transmitter.
  • the cooling device includes a cooling water channel arranged in the transfer arm, the cooling water channel includes a water inlet pipeline, a cooling pipeline, and a water outlet pipeline, and the water inlet pipeline and the water outlet pipeline are arranged at In the transmission arm, two ends of the cooling pipeline are respectively communicated with the water inlet pipeline and the water outlet pipeline, and the cooling pipeline is spirally wound on the microwave transmitter.
  • the sputtering device provided by the embodiment of the present invention emits microwaves toward the workpiece (wafer) to be processed through a microwave transmitter, and the microwave directly acts on the polar molecules in the workpiece (wafer) to heat the workpiece to be processed,
  • the workpiece to be processed has a fast heating rate.
  • the metal film sputtered and deposited on the surface of the workpiece to be processed can effectively reflect the microwave emitted from below and return it to the workpiece to be processed, thereby further improving the microwave utilization efficiency, thereby increasing the heating efficiency, and enabling the workpiece to be processed
  • the rapid temperature rise can realize the reflow process, thereby effectively shortening the cycle time of the reflow process and improving the production efficiency.
  • FIG. 1 is a schematic structural diagram of a sputtering device provided by an embodiment of the present invention.
  • FIG. 2 is a schematic diagram of the structure of the sputtering device provided by an embodiment of the present invention when heating a workpiece to be processed.
  • FIG 3 is a schematic top view of a microwave transmitter embedded in a transmission arm and a plurality of thimbles used in an embodiment of the present invention.
  • Fig. 4 is a schematic top view of the microwave transmitter used in an embodiment of the present invention moving below the workpiece to be processed.
  • Fig. 5 is a schematic diagram of the arrangement of cooling water channels in the transfer arm used in an embodiment of the present invention.
  • FIG. 1 shows a schematic structural diagram of a sputtering device 1 provided by an embodiment of the present invention.
  • the sputtering device 1 is used to perform a sputtering process and a reflow process on the workpiece 12 to be processed.
  • particles ions or neutral atoms, molecules
  • the surface of the target material 11 is bombarded so that the atoms or molecules adjacent to the surface of the target material 11 gain enough energy to finally escape the surface of the target material 11 and deposit on the workpiece 12 to be processed to form a thin film covering the workpiece 12 to be processed.
  • the workpiece 12 to be processed is preferably a wafer, but it is not limited thereto.
  • the sputtering device 1 includes a reaction chamber 2, a base 3, a thimble mechanism 5, and a microwave heating mechanism 6.
  • the reaction chamber 2 is mainly used to provide accommodation for the sputtering process and the reflow process of the workpiece 12 to be processed. space. Please refer to FIG. 1 again.
  • the reaction chamber 2 includes a sputtering chamber 21 and a receiving chamber 22.
  • a target 11 is provided on the top of the sputtering chamber 21, and the target 11 may include copper (Cu).
  • Sputtering materials such as tantalum (Ta), titanium (Ti) or aluminum (Al), but not limited to this.
  • a sputtering mechanism 4 is also provided on the top of the sputtering chamber 21, which acts on the target material 11 and is used to perform a sputtering process on the workpiece 12 to be processed.
  • the sputtering mechanism 4 includes a magnetron 41 and a DC power supply (not shown in the figure).
  • the magnetron 41 is arranged on the back of the target 11, but it is not limited to this. In this embodiment, there may be no special requirements for the selection of the magnetron 41, and the conventional selection of those skilled in the art can be referred to. Please refer to FIG. 1 again.
  • the reaction chamber 2 is grounded, and the DC power supply is connected to the target 11 in the reaction chamber 2 (sputtering chamber 21 ).
  • the DC power supply is used to apply a bias voltage to the target 11.
  • the DC power supply applies a bias voltage to the target material 11 to make it a negative pressure with respect to the grounded reaction chamber 2 so that the reaction gas (for example, argon) in the reaction chamber 2 is discharged.
  • the reaction gas for example, argon
  • Plasma is generated and the positively charged argon ions are attracted to the negatively biased target 11.
  • the metal atoms will escape from the surface of the target, move downwards, and be deposited on the target material to be processed.
  • a metal film covering the workpiece 12 to be processed is formed to complete the magnetron sputtering process.
  • the structure of the sputtering mechanism 4 is not limited to this, and those skilled in the art can also select other suitable types of sputtering processes according to actual sputtering requirements.
  • the receiving cavity 22 is located below the sputtering cavity 21, for example, is arranged coaxially with the sputtering cavity 21, and there is a through hole 23 between the receiving cavity 22 and the sputtering cavity 21, and the through hole 23 is used to connect the receiving cavity 22 to the sputtering cavity.
  • the shooting cavity 21 is communicated so that the workpiece 12 to be processed can move between the receiving cavity 22 and the sputtering cavity 21 through the through hole 23.
  • reaction chamber 2 is not limited to this. In practical applications, those skilled in the art can also select other suitable structures of the reaction chamber 2 according to the teaching of this embodiment.
  • the sputtering cavity 21 and the receiving cavity 22 are defined by the same cavity 24.
  • the cavity 24 is usually a ring-shaped reaction cavity, but it is not limited thereto.
  • the susceptor 3 is disposed in the reaction chamber 2, specifically disposed in the receiving cavity 22 at a position corresponding to the through hole 23, and is used to carry the workpiece 12 to be processed.
  • the susceptor 3 can be raised and lowered so as to be able to rise into the sputtering chamber 21 through the through hole 23, so that the workpiece 12 to be processed is located directly under the target material 11 for sputtering.
  • the susceptor 3 is lowered into the receiving cavity 22 through the through hole 23, so that the workpiece 12 to be processed returns to the receiving cavity 22 for a reflow process.
  • the above-mentioned base 3 is preferably made of ceramic material, but it is not limited thereto.
  • the ejector mechanism 5 is arranged in the reaction chamber 2, and the ejector mechanism 5 can generate relative lifting motion with the base 3, so as to be able to lift from the base 3 and carry the workpiece 12 to be processed.
  • the workpiece to be processed 12 is located above the base 3, so that the microwave heating mechanism 6 can move below the workpiece 12 to be processed for heating.
  • the above-mentioned ejector mechanism 5 and the base 3 to generate relative lifting movements.
  • One is that both the above-mentioned ejector mechanism 5 and the base 3 can be raised and lowered, and the other is that the above-mentioned ejector mechanism 5 is fixed.
  • the base 3 can be raised and lowered. Both of these two methods can realize that the ejector mechanism 5 can lift up from the base 3 and carry the workpiece 12 to be processed, so that the workpiece 12 to be processed is located above the base 3.
  • the thimble mechanism 5 includes a plurality of thimble 51, and the plurality of thimble 51 can be inserted in the base 3, that is, the plurality of thimble can be accommodated in the base 3.
  • the arrangement of the plurality of thimble 51 is different. Not limited to this, those skilled in the art can also choose other suitable setting methods according to the teaching of this embodiment.
  • a plurality of thimble pins 51 can also be arranged under the base 3. When the workpiece 12 to be processed is subjected to the reflow process, more A thimble 51 passes through the base 3 to lift the workpiece 12 to be processed from the base 3 and carry the workpiece 12 to be processed.
  • the way for the plurality of thimbles 51 to pass through the base 3 may be that the plurality of thimbles 51 rise and pass through the base 3, or it may be that the plurality of thimbles 51 are fixed and fall through the base 3 to make A plurality of thimbles 51 pass through the base 3.
  • the multiple thimbles 51 are made of a material that can absorb microwaves, such as ceramics. Since metal materials can reflect microwaves, if the multiple ejector pins 51 are made of metal material, when they are in contact with the workpiece 12 to be processed, the contact positions of the multiple ejector pins 51 will absorb microwaves, resulting in uneven temperature rise of the workpiece 12 to be processed.
  • the multiple ejector pins 51 are made of materials that can absorb microwaves, which can avoid uneven temperature rise of the contact positions of multiple ejector pins 51 with the workpiece 12 to be processed.
  • FIG. 3 shows a schematic top view of the microwave transmitter 62 embedded in the transmission arm 611 and multiple ejector pins 51 used in an embodiment of the present invention.
  • the number of thimble 51 is three, and when the transfer arm 611 is located above the base 3, the three thimble 51 are all located around the transfer arm 611, and are distributed near the edge of the workpiece 12 to be processed.
  • the three thimbles 51 are distributed at intervals in the circumferential direction to realize the stable support of the workpiece 12 to be processed.
  • the number of thimble 51 can be set according to specific conditions, for example, four, five, or more than five, and the distribution mode of thimble 51 can be set.
  • the microwave heating mechanism 6 is arranged in the reaction chamber 2. Please refer to FIG. 1 again. In this embodiment, the microwave heating mechanism 6 is disposed in the receiving cavity 22. Please refer to FIG. 2, which shows a schematic structural diagram of the sputtering device 1 provided by an embodiment of the present invention when the workpiece 12 to be processed is heated.
  • the microwave heating mechanism 6 includes a mobile unit 61 and a microwave transmitter 62.
  • the microwave transmitter 62 is connected to the mobile unit 61.
  • the mobile unit 61 is used to transfer the microwave transmitter when the workpiece 12 to be processed has completed the sputtering process and is carried by the ejector mechanism 5.
  • the microwave transmitter 62 moves below the workpiece 12 to be processed; the microwave transmitter 62 is used to emit microwaves to the workpiece 12 to be processed to heat the workpiece 12 until the temperature required for the reflow process is reached.
  • the microwave emitted by the microwave transmitter 62 usually refers to an electromagnetic wave with a frequency between 300 MHz and 300,000 MHz and a wavelength below 1 m.
  • the microwave transmitter 62 is not limited to be applied to the reflow process after the magnetron sputtering shown in the above embodiment, and can also be applied to other reflow processes after the sputtering process. In this embodiment, there may be no special requirements for the selection of the microwave transmitter 62, and the conventional selection of those skilled in the art can be referred to.
  • the moving unit 61 includes a transmission arm 611 and a rotating arm 612, wherein the rotating arm 612 is vertically arranged in the reaction chamber 2 (specifically in the receiving cavity 22), and It is located on one side of the base 3, and the rotating arm 612 can rotate around its axis, and the rotation angle is preferably 90 degrees, but not limited to this. Those skilled in the art can also choose to set the corresponding rotation angle according to the actual situation. .
  • the rotation of the rotating arm 612 is usually driven by a stepping motor (not shown in the figure) and a corresponding drive structure (such as a variable speed gear box, etc.), but it is not limited to this, and those skilled in the art can also Choose other suitable driving means according to the common sense of the existing technicians.
  • One end of the transmission arm 611 is connected with the rotating arm 612 to be able to drive the transmission arm 611 to rotate around the axis of the rotating arm 612 when rotating.
  • the transmission arm 611 and the rotating arm 612 are connected vertically, and the connection method may be a bolt connection or a welding connection, but it is not limited to this.
  • the structure of the transmission arm 611 and the distribution of the thimble 51 cooperate with each other, so that the transmission arm 611 does not collide with the thimble mechanism 5 when the transmission arm 611 rotates along its rotation path.
  • the microwave transmitter 62 is installed on the transmission arm 611.
  • it can be fixed on the transmission arm 611 by embedding.
  • an embedded slot is provided on the transmission arm 611 to emit microwaves.
  • the device 62 is fixed therein, but it is not limited to this.
  • the electrical connection line of the microwave transmitter 62 further disclosed in this embodiment is led out of the reaction chamber 2 through the rotating arm 612 to realize the connection with the external controller, but it is not limited to this.
  • FIG. 4 shows a schematic top view of the microwave transmitter 62 moving below the workpiece 12 to be processed according to an embodiment of the present invention.
  • the rotation of the transmission arm 611 drives the microwave transmitter 62 to rotate and move to the bottom of the workpiece 12 to be processed.
  • the microwave transmitter 62 emits microwaves to the workpiece 12 to be processed, and heats the workpiece 12 to be processed, but the structure of the moving unit 61 is not limited Here, those skilled in the art can also choose other suitable structures of the mobile unit 61 according to the teaching of this embodiment.
  • the transmission arm 611 of this embodiment is made of metal material to reflect the microwaves and protect the base 3.
  • the metal transmission arm 611 has a faster temperature rise and a higher temperature, and the microwave transmitter 62 is installed on the transmission arm 611, the temperature of the microwave transmitter 62 will be too high under long-term operation, which may cause it to In order to solve this problem, please refer to FIG. 3 and FIG. 4 again.
  • a cooling device is also provided on the transmission arm 611 to cool the microwave transmitter 62.
  • the cooling device may have various structures.
  • the cooling device may include a cooling water channel 613 provided in the transmission arm 611 to cool the microwave transmitter 62 by water cooling.
  • FIG. 5 shows a schematic diagram of the arrangement of the cooling water channels 613 in the transmission arm 611 used in an embodiment of the present invention.
  • the cooling water passage 613 includes a water inlet pipe 6131, a cooling pipe 6132, and a water outlet pipe 6133.
  • the water inlet pipe 6131 and the water outlet pipe 6133 are both arranged in the transmission arm 611, and the two ends of the cooling pipe 6132 are connected to the water inlet pipe respectively.
  • 6131 and the water outlet pipe 6133 are connected to exchange the water in the cooling pipe 6132 in real time through the water inlet pipe 6131 and the water outlet pipe 6133.
  • the cooling pipe 6132 is spirally wound on the microwave transmitter 62. This winding method can increase the connection with the microwave The contact area of the emitter 62 can thereby increase the water cooling efficiency, but it is not limited to this.
  • the sputtering device 1 provided in this embodiment can be applied to PVD equipment for the sputtering process and the reflow process in the PVD manufacturing process.
  • the target 11 is installed and fixed on the top of the reaction chamber 2 (sputtering chamber 21)
  • the workpiece 12 to be processed is placed on the base 3, and the base 3 drives the waiting
  • the workpiece 12 to be processed rises into the sputtering chamber 21, and the sputtering mechanism 4 acts on the target material 11 to cause the metal atoms or molecules on the surface of the target material 11 to escape and move downward to deposit on the workpiece to be processed 12 to form a covering
  • the metal film on the workpiece 12 to be processed can be applied to PVD equipment for the sputtering process and the reflow process in the PVD manufacturing process.
  • the base 3 drives the workpiece 12 to be processed down into the receiving cavity 22 for a reflow process, and the ejector mechanism 5 lifts the workpiece 12 to be processed from the base 3 and carries the workpiece 12 to be processed.
  • the rotating arm 612 drives the transmission arm 611 to rotate around the axis of the rotating arm 612 to rotate the microwave transmitter 62 below the workpiece 12 to be processed; then, the microwave transmitter 62 is controlled to face the back of the workpiece 12 to be processed
  • the microwaves will directly act on the polar molecules in the workpiece 12 to be processed to heat the workpiece 12.
  • the metal film sputtered and deposited on the upper surface of the workpiece 12 can effectively reflect the microwave emitted from below.
  • the microwave utilization efficiency can be further improved, and the heating efficiency can be further improved, so that the workpiece 12 to be processed can quickly heat up and realize the reflow process, thereby effectively shortening the reflow process cycle time and improving production efficiency.

Abstract

The present invention relates to a sputtering device, comprising a reaction chamber, in which a base for bearing a workpiece to be processed is provided. The sputtering device further comprises: an ejection pin mechanism, which is disposed in the reaction chamber and is capable of doing a lifting motion relative to the base, so as to jack up from the base and bear the workpiece; and a microwave heating mechanism disposed in the reaction chamber and comprising a mobile unit and a microwave emitter connected to the mobile unit, wherein the mobile unit is used for moving, when the workpiece is borne by the ejection pin mechanism, the microwave emitter to a position below the workpiece so that the microwave emitter can heat the workpiece by emitting microwaves to the workpiece. According to the sputtering device provided in the embodiments of the present invention, heating rate can be improved such that the workpiece to be processed can be heated rapidly; thus, the cycle time of a reflow process is effectively shortened and production efficiency is improved.

Description

溅射装置Sputtering device 技术领域Technical field
本发明属于溅射技术领域,特别是涉及一种溅射装置。The invention belongs to the field of sputtering technology, and particularly relates to a sputtering device.
背景技术Background technique
铜互联工艺是现有技术的芯片后端制造不可或缺的工艺,铜互联工艺主要包括以下过程,即,首先在刻蚀出的孔道中沉积扩散阻挡层,然后再沉积铜籽晶层,最后通过电镀填充孔道,最终形成铜互联线路。然而,随着芯片特征尺寸的缩小(可达20纳米以下),通孔(或沟槽)的深宽比都将减小到3.8:1,部分层间的通孔(via)的深宽比甚至能达到7:1或更高,在采用物理气相沉积(Physical Vapor Deposition,以下简称PVD)法沉积铜籽晶层时,由于铜的生长速率在沟槽开口处较快,这会造成沟槽顶部悬凸,从而导致在后续电镀过程中,提前封口导致无法将沟槽完全填满,形成空洞,进而影响互联铜线的电阻,从而影响芯片的电学性能,甚至造成失效。The copper interconnection process is an indispensable process for the back-end manufacturing of the chip in the prior art. The copper interconnection process mainly includes the following processes, namely, first depositing a diffusion barrier layer in the etched holes, then depositing a copper seed layer, and finally The holes are filled by electroplating, and the copper interconnection lines are finally formed. However, as the feature size of the chip shrinks (up to 20 nanometers or less), the aspect ratio of the via (or trench) will be reduced to 3.8:1, and the aspect ratio of the vias between some layers It can even reach 7:1 or higher. When the copper seed layer is deposited by the physical vapor deposition (Physical Vapor Deposition, hereinafter referred to as PVD) method, because the copper growth rate is faster at the trench opening, this will cause the trench The top is overhanging, so that in the subsequent electroplating process, the trench cannot be completely filled by the pre-sealing, forming a cavity, which affects the resistance of the interconnected copper wire, thereby affecting the electrical performance of the chip, and even causing failure.
作为解决芯片特征尺寸在20纳米以下工艺的铜回流技术获得人们的关注,在高温(通常在300摄氏度以上)的作用下,PVD沉积的铜的表面移动性和晶粒团聚力都得到增强,在扩散作用和刻蚀出的孔道的毛细作用下,沉积铜薄膜的表面铜原子发生迁移,流入刻蚀出的深孔底部,可以避免产生空洞,且整个回流工艺可以由多个步骤循环组合而成,循环次数可视填充结构而定,以达到将深孔填充完整的目的。As a copper reflow technology that solves the process of chip feature size below 20 nanometers, it has attracted people’s attention. Under the action of high temperature (usually above 300 degrees Celsius), the surface mobility and grain agglomeration of PVD-deposited copper are enhanced. Under the effect of diffusion and the capillary action of the etched pores, the copper atoms on the surface of the deposited copper film migrate and flow into the bottom of the etched deep hole, which can avoid the generation of voids, and the entire reflow process can be combined by multiple steps. , The number of cycles depends on the filling structure to achieve the purpose of filling the deep hole completely.
现有技术的铜回流技术所采用的PVD设备通常包括圆环形的反应腔室、设置于该反应腔室内用于承载晶片的支撑基座及设置于支撑基座上方的靶材。溅射时,直流(direct current,DC)电源会施加直流功率至靶材,以使其相对于接地的反应腔室成为负压,从而使反应腔室中的反应气体(例如氩 气)放电而产生等离子体,并将带正电的氩离子吸引至负偏压的靶材。当氩离子的能量足够高时,会使金属原子逸出靶材表面并沉积在晶片上。The PVD equipment used in the prior art copper reflow technology usually includes a ring-shaped reaction chamber, a support pedestal arranged in the reaction chamber for carrying a wafer, and a target material arranged above the support pedestal. During sputtering, a direct current (DC) power supply will apply DC power to the target material to make it a negative pressure with respect to the grounded reaction chamber, thereby discharging the reaction gas (such as argon) in the reaction chamber. Plasma is generated and the positively charged argon ions are attracted to the negatively biased target. When the energy of argon ions is high enough, metal atoms will escape the target surface and be deposited on the wafer.
为了满足铜回流工艺的温度要求,通常是在反应腔室中加入加热灯管,用以在薄膜沉积工艺完成之后,采用热辐射的方式对晶片进行加热。但是,这种加热方式的加热效率较低,导致晶片升温的速率较慢,从而造成回流工艺周期时间耗时较多(通常在30分钟以上),如果需要多个回流工艺周期循环进行,则耗时更长,严重影响产率。In order to meet the temperature requirements of the copper reflow process, a heating lamp is usually added to the reaction chamber to heat the wafer by means of thermal radiation after the film deposition process is completed. However, the heating efficiency of this heating method is low, resulting in a slower heating rate of the wafer, resulting in a longer cycle time for the reflow process (usually more than 30 minutes). If multiple reflow process cycles are required, it will be expensive. The time is longer, which seriously affects the yield.
发明内容Summary of the invention
本发明实施例旨在至少解决现有技术中存在的技术问题之一,提出了一种溅射装置,其可以提高加热速率,使待加工工件能够快速升温,从而有效缩短回流工艺周期时间,提升生产效率。The embodiment of the present invention aims to solve at least one of the technical problems in the prior art, and proposes a sputtering device, which can increase the heating rate, so that the workpiece to be processed can quickly rise in temperature, thereby effectively shortening the reflow process cycle time and improving Productivity.
为实现本发明实施例的目的而提供一种溅射装置,包括反应腔室,在所述反应腔室内设置有用于承载待加工工件的基座,还包括:In order to achieve the objective of the embodiments of the present invention, a sputtering device is provided, which includes a reaction chamber, in which a susceptor for carrying a workpiece to be processed is provided, and further includes:
顶针机构,设置于所述反应腔室内,所述顶针机构能够与所述基座产生相对升降运动,以能够自所述基座顶起并承载所述待加工工件;以及A thimble mechanism, arranged in the reaction chamber, the thimble mechanism can generate a relative lifting movement with the base, so as to be able to lift from the base and carry the workpiece to be processed; and
微波加热机构,设置于所述反应腔室内,所述微波加热机构包括移动单元和与之连接的微波发射器,其中,所述移动单元用于在所述待加工工件由所述顶针机构承载时,将所述微波发射器移动至所述待加工工件的下方,以使所述微波发射器能够通过朝所述待加工工件发射微波来加热所述待加工工件。A microwave heating mechanism is arranged in the reaction chamber, the microwave heating mechanism includes a moving unit and a microwave transmitter connected to it, wherein the moving unit is used when the workpiece to be processed is carried by the ejector mechanism , Moving the microwave transmitter below the workpiece to be processed, so that the microwave transmitter can heat the workpiece to be processed by emitting microwaves toward the workpiece.
可选的,所述反应腔室包括:Optionally, the reaction chamber includes:
溅射腔,在所述溅射腔顶部设置有靶材和溅射机构,用于对所述待加工工件进行溅射工艺;以及A sputtering chamber, where a target material and a sputtering mechanism are arranged on the top of the sputtering chamber for performing a sputtering process on the workpiece to be processed; and
收纳腔,位于所述溅射腔的下方,所述微波加热机构设置于所述收纳腔 内,用于对所述待加工工件进行回流工艺,并且,在所述收纳腔与所述溅射腔之间具有使二者相互连通的通孔,所述基座设置于所述收纳腔内,且与所述通孔相对应,并且所述基座是可升降的,以能够通过所述通孔在所述溅射腔与所述收纳腔之间移动。The storage cavity is located below the sputtering cavity, the microwave heating mechanism is arranged in the storage cavity, and is used to perform a reflow process on the workpiece to be processed, and in the storage cavity and the sputtering cavity There is a through hole between the two to communicate with each other, the base is disposed in the receiving cavity and corresponds to the through hole, and the base is liftable to pass through the through hole Move between the sputtering cavity and the receiving cavity.
可选的,溅射机构包括:Optionally, the sputtering mechanism includes:
磁控管,设置于所述靶材的背面;以及A magnetron arranged on the back of the target; and
直流电源,与所述靶材连接,用于施加偏压至所述靶材。The direct current power supply is connected to the target material and is used to apply a bias voltage to the target material.
可选的,所述顶针机构是可升降的,或者所述顶针机构相对于所述基座固定不动;并且,所述顶针机构包括多个顶针,所述多个顶针穿设于所述基座内或者设置在所述基座的下方。Optionally, the thimble mechanism can be raised and lowered, or the thimble mechanism is fixed relative to the base; and, the thimble mechanism includes a plurality of thimbles, and the plurality of thimbles pass through the base. In the seat or under the base.
可选的,多个顶针由可吸收微波的材质制成。Optionally, the multiple thimbles are made of materials that can absorb microwaves.
可选的,所述可吸收微波的材质包括陶瓷。Optionally, the material that can absorb microwaves includes ceramics.
可选的,所述移动单元包括:Optionally, the mobile unit includes:
旋转臂,竖直设置于所述反应腔室内,并位于所述基座的一侧,且所述旋转臂能够围绕其轴线旋转;以及The rotating arm is vertically arranged in the reaction chamber and located on one side of the base, and the rotating arm can rotate around its axis; and
传输手臂,与所述旋转臂连接,所述微波发射器设置于所述传输手臂上。The transmission arm is connected with the rotating arm, and the microwave transmitter is arranged on the transmission arm.
可选的,所述微波发射器的电气连接线通过所述旋转臂引出所述反应腔室。Optionally, the electrical connection line of the microwave transmitter is led out of the reaction chamber through the rotating arm.
可选的,所述传输手臂采用金属材质制作,且所述传输手臂上还设置有冷却装置,用于对所述微波发射器进行冷却。Optionally, the transmission arm is made of metal material, and a cooling device is also provided on the transmission arm for cooling the microwave transmitter.
可选的,所述冷却装置包括设置在所述传输手臂中的冷却水道,所述冷却水道包括进水管路、冷却管路及出水管路,所述进水管路及所述出水管路设置于所述传输手臂内,所述冷却管路的两端分别与所述进水管路及所述出水管路连通,所述冷却管路螺旋缠绕于所述微波发射器上。Optionally, the cooling device includes a cooling water channel arranged in the transfer arm, the cooling water channel includes a water inlet pipeline, a cooling pipeline, and a water outlet pipeline, and the water inlet pipeline and the water outlet pipeline are arranged at In the transmission arm, two ends of the cooling pipeline are respectively communicated with the water inlet pipeline and the water outlet pipeline, and the cooling pipeline is spirally wound on the microwave transmitter.
本发明实施例的有益效果:The beneficial effects of the embodiments of the present invention:
本发明实施例提供的溅射装置,其通过微波发射器朝待加工工件(晶圆)发射微波,该微波直接作用于待加工工件(晶圆)内的极性分子,以加热待加工工件,待加工工件升温速率快。同时,待加工工件表面溅射沉积的金属薄膜可以有效反射从下方发射过来的微波,使其返回到待加工工件中,从而可以进一步提高微波利用效率,进而提高加热效率高,使待加工工件能够快速升温,实现回流工艺,从而有效缩短回流工艺周期时间,提升生产效率。The sputtering device provided by the embodiment of the present invention emits microwaves toward the workpiece (wafer) to be processed through a microwave transmitter, and the microwave directly acts on the polar molecules in the workpiece (wafer) to heat the workpiece to be processed, The workpiece to be processed has a fast heating rate. At the same time, the metal film sputtered and deposited on the surface of the workpiece to be processed can effectively reflect the microwave emitted from below and return it to the workpiece to be processed, thereby further improving the microwave utilization efficiency, thereby increasing the heating efficiency, and enabling the workpiece to be processed The rapid temperature rise can realize the reflow process, thereby effectively shortening the cycle time of the reflow process and improving the production efficiency.
附图说明Description of the drawings
为了更清楚地说明本发明实施例中的技术方案,下面将对实施例描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to explain the technical solutions in the embodiments of the present invention more clearly, the following will briefly introduce the drawings needed in the description of the embodiments. Obviously, the drawings in the following description are only some embodiments of the present invention. For those of ordinary skill in the art, other drawings can be obtained from these drawings without creative work.
图1是本发明一实施例提供的溅射装置的结构示意图。FIG. 1 is a schematic structural diagram of a sputtering device provided by an embodiment of the present invention.
图2是本发明一实施例提供的溅射装置加热待加工工件时的结构示意图。2 is a schematic diagram of the structure of the sputtering device provided by an embodiment of the present invention when heating a workpiece to be processed.
图3是本发明一实施例采用的微波发射器嵌装于传输手臂及多个顶针的俯视示意图。3 is a schematic top view of a microwave transmitter embedded in a transmission arm and a plurality of thimbles used in an embodiment of the present invention.
图4是本发明一实施例采用的微波发射器移动至待加工工件下方的俯视示意图。Fig. 4 is a schematic top view of the microwave transmitter used in an embodiment of the present invention moving below the workpiece to be processed.
图5是本发明一实施例采用的传输手臂内冷却水道的排布示意图。Fig. 5 is a schematic diagram of the arrangement of cooling water channels in the transfer arm used in an embodiment of the present invention.
具体实施方式Detailed ways
为使本发明的目的、技术方案和优点更加清楚,下面将结合附图对本发明实施方式作进一步地详细描述。In order to make the objectives, technical solutions and advantages of the present invention clearer, the embodiments of the present invention will be described in further detail below in conjunction with the accompanying drawings.
本发明的一实施例中,请参阅图1,其示出了本发明一实施例提供的溅射装置1的结构示意图。溅射装置1用于对待加工工件12进行溅射工艺和 回流工艺,在进行溅射工艺时,在反应腔室2中产生的等离子体中具有一定能量的粒子(离子或中性原子、分子)轰击靶材11表面,使靶材11邻近表面的原子或分子获得足够大的能量而最终逸出靶材11表面,并沉积在待加工工件12上,形成覆盖于待加工工件12上的薄膜。待加工工件12优选为晶片,但并不以此为限。In an embodiment of the present invention, please refer to FIG. 1, which shows a schematic structural diagram of a sputtering device 1 provided by an embodiment of the present invention. The sputtering device 1 is used to perform a sputtering process and a reflow process on the workpiece 12 to be processed. During the sputtering process, particles (ions or neutral atoms, molecules) with a certain energy in the plasma generated in the reaction chamber 2 The surface of the target material 11 is bombarded so that the atoms or molecules adjacent to the surface of the target material 11 gain enough energy to finally escape the surface of the target material 11 and deposit on the workpiece 12 to be processed to form a thin film covering the workpiece 12 to be processed. The workpiece 12 to be processed is preferably a wafer, but it is not limited thereto.
具体地,溅射装置1包括反应腔室2、基座3、顶针机构5和微波加热机构6,其中,反应腔室2主要用于为待加工工件12的溅射工艺及回流工艺提供容置空间。请再次参阅图1,在本实施例中,反应腔室2包括溅射腔21和收纳腔22,其中,溅射腔21内的顶部设置有靶材11,靶材11可以包括铜(Cu)、钽(Ta)、钛(Ti)或铝(Al)等溅射材料,但并不以此为限。Specifically, the sputtering device 1 includes a reaction chamber 2, a base 3, a thimble mechanism 5, and a microwave heating mechanism 6. The reaction chamber 2 is mainly used to provide accommodation for the sputtering process and the reflow process of the workpiece 12 to be processed. space. Please refer to FIG. 1 again. In this embodiment, the reaction chamber 2 includes a sputtering chamber 21 and a receiving chamber 22. A target 11 is provided on the top of the sputtering chamber 21, and the target 11 may include copper (Cu). Sputtering materials such as tantalum (Ta), titanium (Ti) or aluminum (Al), but not limited to this.
溅射腔21的顶部还设置有溅射机构4,其作用于靶材11,用于对待加工工件12进行溅射工艺。具体地,该溅射机构4包括磁控管41和直流电源(图中未示出),磁控管41设置于靶材11的背面,但并不以此为限。在本实施例中,对于磁控管41的选择可以没有特殊要求,参照本领域技术人员的常规选择即可。请再次参阅图1,反应腔室2呈接地设置,直流电源与反应腔室2(溅射腔21)内的靶材11连接,直流电源用于施加偏压至靶材11。A sputtering mechanism 4 is also provided on the top of the sputtering chamber 21, which acts on the target material 11 and is used to perform a sputtering process on the workpiece 12 to be processed. Specifically, the sputtering mechanism 4 includes a magnetron 41 and a DC power supply (not shown in the figure). The magnetron 41 is arranged on the back of the target 11, but it is not limited to this. In this embodiment, there may be no special requirements for the selection of the magnetron 41, and the conventional selection of those skilled in the art can be referred to. Please refer to FIG. 1 again. The reaction chamber 2 is grounded, and the DC power supply is connected to the target 11 in the reaction chamber 2 (sputtering chamber 21 ). The DC power supply is used to apply a bias voltage to the target 11.
在溅射机构4溅射时,直流电源施加偏压至靶材11,使其相对于接地的反应腔室2成为负压,以使反应腔室2中的反应气体(例如氩气)放电而产生等离子体,并将带正电的氩离子吸引至负偏压的靶材11,当氩离子的能量足够高时,会使金属原子逸出靶材表面,向下运动,并沉积于待加工工件12的上表面,形成覆盖于待加工工件12上的金属薄膜,完成磁控溅射工艺。当然,在实际应用中,溅射机构4的结构并不局限于此,本领域技术人员也可以根据实际溅射需求选择其他合适的类型的溅射工艺。During sputtering by the sputtering mechanism 4, the DC power supply applies a bias voltage to the target material 11 to make it a negative pressure with respect to the grounded reaction chamber 2 so that the reaction gas (for example, argon) in the reaction chamber 2 is discharged. Plasma is generated and the positively charged argon ions are attracted to the negatively biased target 11. When the energy of the argon ions is high enough, the metal atoms will escape from the surface of the target, move downwards, and be deposited on the target material to be processed. On the upper surface of the workpiece 12, a metal film covering the workpiece 12 to be processed is formed to complete the magnetron sputtering process. Of course, in practical applications, the structure of the sputtering mechanism 4 is not limited to this, and those skilled in the art can also select other suitable types of sputtering processes according to actual sputtering requirements.
收纳腔22位于溅射腔21的下方,例如与溅射腔21同轴设置,并且在收纳腔22与溅射腔21之间具有一通孔23,该通孔23用于将收纳腔22与溅 射腔21相连通,以使待加工工件12能够通过该通孔23在收纳腔22与溅射腔21之间移动。The receiving cavity 22 is located below the sputtering cavity 21, for example, is arranged coaxially with the sputtering cavity 21, and there is a through hole 23 between the receiving cavity 22 and the sputtering cavity 21, and the through hole 23 is used to connect the receiving cavity 22 to the sputtering cavity. The shooting cavity 21 is communicated so that the workpiece 12 to be processed can move between the receiving cavity 22 and the sputtering cavity 21 through the through hole 23.
需要说明的是,反应腔室2的结构并不局限于此,在实际应用中,本领域技术人员也可以根据本实施例的教导选择其他合适结构的反应腔室2。It should be noted that the structure of the reaction chamber 2 is not limited to this. In practical applications, those skilled in the art can also select other suitable structures of the reaction chamber 2 according to the teaching of this embodiment.
在本实施例中,溅射腔21与收纳腔22由同一腔体24限定而成,该腔体24通常为圆环型反应腔体,但并不以此为限。In this embodiment, the sputtering cavity 21 and the receiving cavity 22 are defined by the same cavity 24. The cavity 24 is usually a ring-shaped reaction cavity, but it is not limited thereto.
在本实施例中,基座3设置于反应腔室2内,具体设置在收纳腔22内,且与通孔23相对应的位置处,用于承载待加工工件12。并且,基座3是可升降的,以能够通过通孔23上升至溅射腔21内,使待加工工件12位于靶材11的正下方进行溅射工艺。在待加工工件12完成溅射工艺后,基座3通过通孔23下降至收纳腔22内,以使待加工工件12返回收纳腔22内进行回流工艺。上述基座3优选为陶瓷材质,但并不以此为限。In this embodiment, the susceptor 3 is disposed in the reaction chamber 2, specifically disposed in the receiving cavity 22 at a position corresponding to the through hole 23, and is used to carry the workpiece 12 to be processed. In addition, the susceptor 3 can be raised and lowered so as to be able to rise into the sputtering chamber 21 through the through hole 23, so that the workpiece 12 to be processed is located directly under the target material 11 for sputtering. After the workpiece 12 to be processed completes the sputtering process, the susceptor 3 is lowered into the receiving cavity 22 through the through hole 23, so that the workpiece 12 to be processed returns to the receiving cavity 22 for a reflow process. The above-mentioned base 3 is preferably made of ceramic material, but it is not limited thereto.
请再次参阅图1,顶针机构5设置于反应腔室2内,顶针机构5能够与基座3产生相对升降运动,以能够自基座3顶起并承载待加工工件12,此时待加工工件12位于基座3的上方,以使微波加热机构6能够移动至待加工工件12的下方进行加热。具体地,上述顶针机构5与基座3产生相对升降运动的方式有两种,一种是上述顶针机构5与基座3均能够升降,另一种是上述顶针机构5是固定不动的,而基座3能够升降,这两种方式均可以实现使顶针机构5能够自基座3顶起并承载待加工工件12,以使待加工工件12位于基座3的上方。1 again, the ejector mechanism 5 is arranged in the reaction chamber 2, and the ejector mechanism 5 can generate relative lifting motion with the base 3, so as to be able to lift from the base 3 and carry the workpiece 12 to be processed. At this time, the workpiece to be processed 12 is located above the base 3, so that the microwave heating mechanism 6 can move below the workpiece 12 to be processed for heating. Specifically, there are two ways for the above-mentioned ejector mechanism 5 and the base 3 to generate relative lifting movements. One is that both the above-mentioned ejector mechanism 5 and the base 3 can be raised and lowered, and the other is that the above-mentioned ejector mechanism 5 is fixed. The base 3 can be raised and lowered. Both of these two methods can realize that the ejector mechanism 5 can lift up from the base 3 and carry the workpiece 12 to be processed, so that the workpiece 12 to be processed is located above the base 3.
在本实施例中,顶针机构5包括多个顶针51,多个顶针51可以穿设于基座3内,也即多个顶针可容纳于基座3中但是,多个顶针51的设置方式并不局限于此,本领域技术人员也可以根据本实施例的教导选择其他合适的设置方式,例如还可以将多个顶针51设置于基座3下方,在待加工工件12进行回流工艺时,多个顶针51穿过基座3,将待加工工件12从基座3上顶 起并承载待加工工件12。此外,多个顶针51穿过基座3的方式可以是通过多个顶针51上升而穿过基座3,或者还可以是使多个顶针51固定不动,而通过基座3下降,以使多个顶针51穿过基座3。In this embodiment, the thimble mechanism 5 includes a plurality of thimble 51, and the plurality of thimble 51 can be inserted in the base 3, that is, the plurality of thimble can be accommodated in the base 3. However, the arrangement of the plurality of thimble 51 is different. Not limited to this, those skilled in the art can also choose other suitable setting methods according to the teaching of this embodiment. For example, a plurality of thimble pins 51 can also be arranged under the base 3. When the workpiece 12 to be processed is subjected to the reflow process, more A thimble 51 passes through the base 3 to lift the workpiece 12 to be processed from the base 3 and carry the workpiece 12 to be processed. In addition, the way for the plurality of thimbles 51 to pass through the base 3 may be that the plurality of thimbles 51 rise and pass through the base 3, or it may be that the plurality of thimbles 51 are fixed and fall through the base 3 to make A plurality of thimbles 51 pass through the base 3.
在本实施例中,多个顶针51采用可吸收微波的材质制成,例如为陶瓷。由于金属材质能够反射微波,若多个顶针51使用金属材质制成,其在与待加工工件12接触时,多个顶针51的接触位置会吸收微波,造成待加工工件12升温不均匀,为此,多个顶针51通过采用可吸收微波的材质制造,可以避免多个顶针51与待加工工件12的接触位置升温不均匀。In this embodiment, the multiple thimbles 51 are made of a material that can absorb microwaves, such as ceramics. Since metal materials can reflect microwaves, if the multiple ejector pins 51 are made of metal material, when they are in contact with the workpiece 12 to be processed, the contact positions of the multiple ejector pins 51 will absorb microwaves, resulting in uneven temperature rise of the workpiece 12 to be processed. The multiple ejector pins 51 are made of materials that can absorb microwaves, which can avoid uneven temperature rise of the contact positions of multiple ejector pins 51 with the workpiece 12 to be processed.
多个顶针51的分布方式可以有多种,例如,请参阅图3,其示出了本发明一实施例采用的微波发射器62嵌装于传输手臂611及多个顶针51的俯视示意图。顶针51的数量为三个,且在该传输手臂611位于基座3上方时,三个顶针51均位于传输手臂611的周围,并且分布在靠近待加工工件12的边缘的位置处。三个顶针51在圆周方向上间隔分布,以实现待加工工件12的稳定支撑。当然,在实际应用中,可以根据具体情况设定顶针51的数量,例如四个、五个及五个以上,以及设定顶针51的分布方式。There may be many ways to distribute the multiple ejector pins 51. For example, please refer to FIG. 3, which shows a schematic top view of the microwave transmitter 62 embedded in the transmission arm 611 and multiple ejector pins 51 used in an embodiment of the present invention. The number of thimble 51 is three, and when the transfer arm 611 is located above the base 3, the three thimble 51 are all located around the transfer arm 611, and are distributed near the edge of the workpiece 12 to be processed. The three thimbles 51 are distributed at intervals in the circumferential direction to realize the stable support of the workpiece 12 to be processed. Of course, in practical applications, the number of thimble 51 can be set according to specific conditions, for example, four, five, or more than five, and the distribution mode of thimble 51 can be set.
微波加热机构6设置于反应腔室2内。请再次参阅图1,在本实施例中,微波加热机构6设置于收纳腔22内。请参阅图2,其示出了本发明一实施例提供的溅射装置1加热待加工工件12时的结构示意图。微波加热机构6包括移动单元61及微波发射器62,微波发射器62与移动单元61连接,移动单元61用于在待加工工件12完成溅射工艺且由顶针机构5承载时,将微波发射器62移动至待加工工件12的下方;微波发射器62用于向待加工工件12发射微波,以加热待加工工件12,直至达到回流工艺所需温度。由微波发射器62发射出的微波通常是指频率在300MHz-300000MHz,波长在1m以下的电磁波。The microwave heating mechanism 6 is arranged in the reaction chamber 2. Please refer to FIG. 1 again. In this embodiment, the microwave heating mechanism 6 is disposed in the receiving cavity 22. Please refer to FIG. 2, which shows a schematic structural diagram of the sputtering device 1 provided by an embodiment of the present invention when the workpiece 12 to be processed is heated. The microwave heating mechanism 6 includes a mobile unit 61 and a microwave transmitter 62. The microwave transmitter 62 is connected to the mobile unit 61. The mobile unit 61 is used to transfer the microwave transmitter when the workpiece 12 to be processed has completed the sputtering process and is carried by the ejector mechanism 5. 62 moves below the workpiece 12 to be processed; the microwave transmitter 62 is used to emit microwaves to the workpiece 12 to be processed to heat the workpiece 12 until the temperature required for the reflow process is reached. The microwave emitted by the microwave transmitter 62 usually refers to an electromagnetic wave with a frequency between 300 MHz and 300,000 MHz and a wavelength below 1 m.
需要说明的是,微波发射器62不限于应用于上述实施例所示的磁控溅 射后的回流工艺制程,也可以应用于其他的溅射工艺后的回流工艺制程。在本实施例中对于微波发射器62的选择可以没有特殊要求,参照本领域技术人员的常规选择即可。It should be noted that the microwave transmitter 62 is not limited to be applied to the reflow process after the magnetron sputtering shown in the above embodiment, and can also be applied to other reflow processes after the sputtering process. In this embodiment, there may be no special requirements for the selection of the microwave transmitter 62, and the conventional selection of those skilled in the art can be referred to.
在本实施例中,请同时参阅图1和图2,移动单元61包括传输手臂611和旋转臂612,其中,旋转臂612竖直设置于反应腔室2(具体于收纳腔22)内,并位于基座3的一侧,并且,旋转臂612可围绕其轴线旋转,且旋转角度优选为90度,但并不以此为限,本领域技术人员也可以根据实际情况选择设置对应的旋转角度。另外,旋转臂612的旋转通常是通过步进电机(图中未示出)及对应的驱动结构(例如变速齿轮箱等)驱动其转动,但并不以此为限,本领域技术人员也可以根据现有技术人员的常识选择其他合适的驱动手段。In this embodiment, referring to FIGS. 1 and 2 at the same time, the moving unit 61 includes a transmission arm 611 and a rotating arm 612, wherein the rotating arm 612 is vertically arranged in the reaction chamber 2 (specifically in the receiving cavity 22), and It is located on one side of the base 3, and the rotating arm 612 can rotate around its axis, and the rotation angle is preferably 90 degrees, but not limited to this. Those skilled in the art can also choose to set the corresponding rotation angle according to the actual situation. . In addition, the rotation of the rotating arm 612 is usually driven by a stepping motor (not shown in the figure) and a corresponding drive structure (such as a variable speed gear box, etc.), but it is not limited to this, and those skilled in the art can also Choose other suitable driving means according to the common sense of the existing technicians.
传输手臂611的一端与旋转臂612连接,以能够在转动时带动传输手臂611围绕旋转臂612的轴线转动。优选的,传输手臂611与旋转臂612垂直连接,其连接方式可以是通过螺栓连接,或者也可以是通过焊接连接,但并不以此为限。此外,如图3所示,传输手臂611的结构以及顶针51的分布方式相互配合,以实现在传输手臂611沿其旋转路径转动的过程中不会碰撞到顶针机构5。One end of the transmission arm 611 is connected with the rotating arm 612 to be able to drive the transmission arm 611 to rotate around the axis of the rotating arm 612 when rotating. Preferably, the transmission arm 611 and the rotating arm 612 are connected vertically, and the connection method may be a bolt connection or a welding connection, but it is not limited to this. In addition, as shown in FIG. 3, the structure of the transmission arm 611 and the distribution of the thimble 51 cooperate with each other, so that the transmission arm 611 does not collide with the thimble mechanism 5 when the transmission arm 611 rotates along its rotation path.
请再次参阅图3,微波发射器62设置在传输手臂611上,其例如可以采用嵌装的方式固定在传输手臂611上,具体地,在传输手臂611上设置一嵌入槽,用以将微波发射器62固定在其中,但并不以此为限。本实施例进一步公开的微波发射器62的电气连接线通过旋转臂612引出反应腔室2,以实现与外部的控制器连接,但并不以此为限。Please refer to FIG. 3 again. The microwave transmitter 62 is installed on the transmission arm 611. For example, it can be fixed on the transmission arm 611 by embedding. Specifically, an embedded slot is provided on the transmission arm 611 to emit microwaves. The device 62 is fixed therein, but it is not limited to this. The electrical connection line of the microwave transmitter 62 further disclosed in this embodiment is led out of the reaction chamber 2 through the rotating arm 612 to realize the connection with the external controller, but it is not limited to this.
请参阅图4,其示出了本发明一实施例的微波发射器62移动至待加工工件12下方的俯视示意图。传输手臂611转动带动微波发射器62转动,而移动至待加工工件12的下方,通过微波发射器62向待加工工件12发射微波, 而加热待加工工件12,然移动单元61的结构并不局限于此,本领域技术人员也可以根据本实施例的教导选择其他合适的结构的移动单元61。Please refer to FIG. 4, which shows a schematic top view of the microwave transmitter 62 moving below the workpiece 12 to be processed according to an embodiment of the present invention. The rotation of the transmission arm 611 drives the microwave transmitter 62 to rotate and move to the bottom of the workpiece 12 to be processed. The microwave transmitter 62 emits microwaves to the workpiece 12 to be processed, and heats the workpiece 12 to be processed, but the structure of the moving unit 61 is not limited Here, those skilled in the art can also choose other suitable structures of the mobile unit 61 according to the teaching of this embodiment.
由于微波发射器62发射的微波会对陶瓷材质的基座3造成损伤,因此本实施例的传输手臂611为金属材质,以反射微波,保护基座3。同时,由于金属材质的传输手臂611温升较快,且温度较高,而微波发射器62设置于传输手臂611上,在长时间工作下会导致微波发射器62温度过高,从而可能导致其失效,为了解决该问题,请再次参阅图3和图4,在传输手臂611上还设置有冷却装置,用以对微波发射器62进行冷却。该冷却装置的结构可以有多种,例如,该冷却装置可以包括设置在传输手臂611中的冷却水道613,用以通过水冷的方式对微波发射器62进行冷却。Since the microwaves emitted by the microwave transmitter 62 will damage the base 3 made of ceramic material, the transmission arm 611 of this embodiment is made of metal material to reflect the microwaves and protect the base 3. At the same time, because the metal transmission arm 611 has a faster temperature rise and a higher temperature, and the microwave transmitter 62 is installed on the transmission arm 611, the temperature of the microwave transmitter 62 will be too high under long-term operation, which may cause it to In order to solve this problem, please refer to FIG. 3 and FIG. 4 again. A cooling device is also provided on the transmission arm 611 to cool the microwave transmitter 62. The cooling device may have various structures. For example, the cooling device may include a cooling water channel 613 provided in the transmission arm 611 to cool the microwave transmitter 62 by water cooling.
在本实施例中,请参阅图5,其示出了本发明一实施例采用的传输手臂611内冷却水道613的排布示意图。冷却水道613包括进水管路6131、冷却管路6132及出水管路6133,其中,进水管路6131及出水管路6133均设置于传输手臂611内,冷却管路6132的两端分别与进水管路6131及出水管路6133连通,以通过进水管路6131及出水管路6133对冷却管路6132进行实时换水,冷却管路6132螺旋缠绕于微波发射器62上,该缠绕方式可以增大与微波发射器62的接触面积,从而可以增加水冷效率,但并不以此为限。In this embodiment, please refer to FIG. 5, which shows a schematic diagram of the arrangement of the cooling water channels 613 in the transmission arm 611 used in an embodiment of the present invention. The cooling water passage 613 includes a water inlet pipe 6131, a cooling pipe 6132, and a water outlet pipe 6133. The water inlet pipe 6131 and the water outlet pipe 6133 are both arranged in the transmission arm 611, and the two ends of the cooling pipe 6132 are connected to the water inlet pipe respectively. 6131 and the water outlet pipe 6133 are connected to exchange the water in the cooling pipe 6132 in real time through the water inlet pipe 6131 and the water outlet pipe 6133. The cooling pipe 6132 is spirally wound on the microwave transmitter 62. This winding method can increase the connection with the microwave The contact area of the emitter 62 can thereby increase the water cooling efficiency, but it is not limited to this.
本实施例提供的溅射装置1可以应用于PVD设备中,用于PVD制程中溅射工艺及回流工艺的进行。请再次参阅图1,在进行溅射工艺时,将靶材11安装固定于反应腔室2(溅射腔21)的顶部,将待加工工件12放置于基座3上,基座3带动待加工工件12上升至溅射腔21内,溅射机构4作用于靶材11,使靶材11表面的金属原子或分子逸出,并向下运动,沉积于待加工工件12上,形成覆盖于待加工工件12上的金属薄膜。The sputtering device 1 provided in this embodiment can be applied to PVD equipment for the sputtering process and the reflow process in the PVD manufacturing process. 1 again, during the sputtering process, the target 11 is installed and fixed on the top of the reaction chamber 2 (sputtering chamber 21), the workpiece 12 to be processed is placed on the base 3, and the base 3 drives the waiting The workpiece 12 to be processed rises into the sputtering chamber 21, and the sputtering mechanism 4 acts on the target material 11 to cause the metal atoms or molecules on the surface of the target material 11 to escape and move downward to deposit on the workpiece to be processed 12 to form a covering The metal film on the workpiece 12 to be processed.
在上述溅射工艺完成之后,基座3带动待加工工件12下降至收纳腔22内进行回流工艺,顶针机构5将待加工工件12从基座3上顶起并承载待加 工工件12。请再次参阅图2,旋转臂612带动传输手臂611围绕旋转臂612的轴线转动,以将微波发射器62转动至待加工工件12的下方;然后,控制微波发射器62朝待加工工件12的背面发射微波,微波将直接作用于待加工工件12内的极性分子,以加热待加工工件12,同时,待加工工件12的上表面溅射沉积的金属薄膜可以有效反射从下方发射过来的微波,以使其返回到待加工工件12中,从而可以进一步提高微波利用效率,进而提高加热效率,使待加工工件12能够快速升温,实现回流工艺,从而有效缩短回流工艺周期时间,提升生产效率。After the above sputtering process is completed, the base 3 drives the workpiece 12 to be processed down into the receiving cavity 22 for a reflow process, and the ejector mechanism 5 lifts the workpiece 12 to be processed from the base 3 and carries the workpiece 12 to be processed. 2 again, the rotating arm 612 drives the transmission arm 611 to rotate around the axis of the rotating arm 612 to rotate the microwave transmitter 62 below the workpiece 12 to be processed; then, the microwave transmitter 62 is controlled to face the back of the workpiece 12 to be processed When microwaves are emitted, the microwaves will directly act on the polar molecules in the workpiece 12 to be processed to heat the workpiece 12. At the same time, the metal film sputtered and deposited on the upper surface of the workpiece 12 can effectively reflect the microwave emitted from below. In order to return it to the workpiece 12 to be processed, the microwave utilization efficiency can be further improved, and the heating efficiency can be further improved, so that the workpiece 12 to be processed can quickly heat up and realize the reflow process, thereby effectively shortening the reflow process cycle time and improving production efficiency.
上述说明示出并描述了本发明的若干优选实施方式,但如前所述,应当理解本发明并非局限于本文所披露的形式,不应看作是对其他实施方式的排除,而可用于各种其他组合、修改和环境,并能够在本文所述发明构想范围内,通过上述教导或相关领域的技术或知识进行改动。而本领域人员所进行的改动和变化不脱离本发明的精神和范围,则都应在本发明所附权利要求的保护范围内。The above description shows and describes several preferred embodiments of the present invention. However, as mentioned above, it should be understood that the present invention is not limited to the form disclosed herein, and should not be regarded as the exclusion of other embodiments, but can be used for various embodiments. Other combinations, modifications, and environments can be modified through the above teachings or technology or knowledge in related fields within the scope of the inventive concept described herein. The modifications and changes made by those skilled in the art do not depart from the spirit and scope of the present invention, and should fall within the protection scope of the appended claims of the present invention.

Claims (10)

  1. 一种溅射装置,包括反应腔室,在所述反应腔室内设置有用于承载待加工工件的基座,其特征在于,还包括:A sputtering device includes a reaction chamber in which a susceptor for carrying a workpiece to be processed is provided, and is characterized in that it further includes:
    顶针机构,设置于所述反应腔室内,所述顶针机构能够与所述基座产生相对升降运动,以能够自所述基座顶起并承载所述待加工工件;以及A thimble mechanism, arranged in the reaction chamber, the thimble mechanism can generate a relative lifting movement with the base, so as to be able to lift from the base and carry the workpiece to be processed; and
    微波加热机构,设置于所述反应腔室内,所述微波加热机构包括移动单元和与之连接的微波发射器,其中,所述移动单元用于在所述待加工工件由所述顶针机构承载时,将所述微波发射器移动至所述待加工工件的下方,以使所述微波发射器能够通过朝所述待加工工件发射微波来加热所述待加工工件。A microwave heating mechanism is arranged in the reaction chamber, the microwave heating mechanism includes a moving unit and a microwave transmitter connected to it, wherein the moving unit is used when the workpiece to be processed is carried by the ejector mechanism , Moving the microwave transmitter below the workpiece to be processed, so that the microwave transmitter can heat the workpiece to be processed by emitting microwaves toward the workpiece.
  2. 根据权利要求1所述的溅射装置,其特征在于,所述反应腔室包括:The sputtering device according to claim 1, wherein the reaction chamber comprises:
    溅射腔,在所述溅射腔顶部设置有靶材和溅射机构,用于对所述待加工工件进行溅射工艺;以及A sputtering chamber, where a target material and a sputtering mechanism are arranged on the top of the sputtering chamber for performing a sputtering process on the workpiece to be processed; and
    收纳腔,位于所述溅射腔的下方,所述微波加热机构设置于所述收纳腔内,用于对所述待加工工件进行回流工艺,并且,在所述收纳腔与所述溅射腔之间具有使二者相互连通的通孔,所述基座设置于所述收纳腔内,且与所述通孔相对应,并且所述基座是可升降的,以能够通过所述通孔在所述溅射腔与所述收纳腔之间移动。The storage cavity is located below the sputtering cavity, the microwave heating mechanism is arranged in the storage cavity, and is used to perform a reflow process on the workpiece to be processed, and in the storage cavity and the sputtering cavity There is a through hole between the two to communicate with each other, the base is disposed in the receiving cavity and corresponds to the through hole, and the base is liftable to pass through the through hole Move between the sputtering cavity and the receiving cavity.
  3. 根据权利要求2所述的溅射装置,其特征在于,所述溅射机构包括:3. The sputtering device according to claim 2, wherein the sputtering mechanism comprises:
    磁控管,设置于所述靶材的背面;以及A magnetron arranged on the back of the target; and
    直流电源,与所述靶材连接,用于施加偏压至所述靶材。The direct current power supply is connected to the target material and is used to apply a bias voltage to the target material.
  4. 根据权利要求1所述的溅射装置,其特征在于,所述顶针机构是可升降的,或者所述顶针机构相对于所述基座固定不动;并且,所述顶针机构包括多个顶针,所述多个顶针穿设于所述基座内或者设置在所述基座的下方。The sputtering device according to claim 1, wherein the thimble mechanism is liftable, or the thimble mechanism is fixed relative to the base; and the thimble mechanism includes a plurality of thimble, The plurality of thimbles are inserted in the base or arranged below the base.
  5. 根据权利要求4所述的溅射装置,其特征在于,所述多个顶针由可 吸收微波的材质制成。4. The sputtering device according to claim 4, wherein the plurality of thimble pins are made of a material that can absorb microwaves.
  6. 根据权利要求5所述的溅射装置,其特征在于,所述可吸收微波的材质包括陶瓷。The sputtering device according to claim 5, wherein the material capable of absorbing microwaves comprises ceramics.
  7. 根据权利要求1所述的溅射装置,其特征在于,所述移动单元包括:The sputtering device according to claim 1, wherein the moving unit comprises:
    旋转臂,竖直设置于所述反应腔室内,并位于所述基座的一侧,且所述旋转臂能够围绕其轴线旋转;以及The rotating arm is vertically arranged in the reaction chamber and located on one side of the base, and the rotating arm can rotate around its axis; and
    传输手臂,与所述旋转臂连接,所述微波发射器设置于所述传输手臂上。The transmission arm is connected with the rotating arm, and the microwave transmitter is arranged on the transmission arm.
  8. 根据权利要求7所述溅射装置,其特征在于,所述微波发射器的电气连接线通过所述旋转臂引出所述反应腔室。8. The sputtering device according to claim 7, wherein the electrical connection line of the microwave transmitter is led out of the reaction chamber through the rotating arm.
  9. 根据权利要求7所述的溅射装置,其特征在于,所述传输手臂采用金属材质制作,且所述传输手臂上还设置有冷却装置,用于对所述微波发射器进行冷却。8. The sputtering device according to claim 7, wherein the transmission arm is made of metal material, and a cooling device is further provided on the transmission arm for cooling the microwave transmitter.
  10. 根据权利要求9所述的溅射装置,其特征在于,所述冷却装置包括设置在所述传输手臂中的冷却水道,所述冷却水道包括进水管路、冷却管路及出水管路,所述进水管路及所述出水管路设置于所述传输手臂内,所述冷却管路的两端分别与所述进水管路及所述出水管路连通,所述冷却管路螺旋缠绕于所述微波发射器上。The sputtering device according to claim 9, wherein the cooling device comprises a cooling water channel arranged in the transfer arm, and the cooling water channel includes a water inlet pipe, a cooling pipe, and a water outlet pipe, and the cooling water channel includes a water inlet pipe, a cooling pipe, and a water outlet pipe. The water inlet pipe and the water outlet pipe are arranged in the transmission arm, the two ends of the cooling pipe are respectively communicated with the water inlet pipe and the water outlet pipe, and the cooling pipe is spirally wound around the On the microwave transmitter.
PCT/CN2020/126456 2019-11-11 2020-11-04 Sputtering device WO2021093650A1 (en)

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