WO2020253781A1 - 一种用于汽油车辆减排节油的太赫兹材料及其制备方法和应用 - Google Patents

一种用于汽油车辆减排节油的太赫兹材料及其制备方法和应用 Download PDF

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WO2020253781A1
WO2020253781A1 PCT/CN2020/096829 CN2020096829W WO2020253781A1 WO 2020253781 A1 WO2020253781 A1 WO 2020253781A1 CN 2020096829 W CN2020096829 W CN 2020096829W WO 2020253781 A1 WO2020253781 A1 WO 2020253781A1
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terahertz
emission reduction
gasoline
fuel saving
wave
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PCT/CN2020/096829
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English (en)
French (fr)
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侯文豪
佟延
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天津中安信业集团有限公司
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Priority to US17/620,682 priority Critical patent/US20220098502A1/en
Publication of WO2020253781A1 publication Critical patent/WO2020253781A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/181—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by a dry process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/081—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing particle radiation or gamma-radiation
    • B01J19/085—Electron beams only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1216—Inorganic compounds metal compounds, e.g. hydrides, carbides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F02M27/06—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by rays, e.g. infrared and ultraviolet
    • F02M27/065—Radioactive radiation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08—Materials not undergoing a change of physical state when used
    • C09K5/10—Liquid materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204—Metals or alloys
    • C10L2200/0213—Group II metals: Be, Mg, Ca, Sr, Ba, Ra, Zn, Cd, Hg
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204—Metals or alloys
    • C10L2200/0218—Group III metals: Sc, Y, Al, Ga, In, Tl
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204—Metals or alloys
    • C10L2200/0231—Group VI metals: Cr, Mo, W, Po
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204—Metals or alloys
    • C10L2200/024—Group VIII metals: Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0272—Silicon containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0415—Light distillates, e.g. LPG, naphtha
    • C10L2200/0423—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/023—Specifically adapted fuels for internal combustion engines for gasoline engines

Definitions

  • the invention belongs to the technical field of terahertz, and specifically relates to a terahertz material used for emission reduction and fuel saving of gasoline vehicles, and a preparation method and application thereof.
  • the main components in automobile exhaust are hydrocarbons, nitrogen oxides, carbon monoxide, carbon dioxide, water, nitrogen and a small amount of oxygen.
  • hydrocarbons, nitrogen oxides, and carbon monoxide that cause environmental pollution. Since the production conditions of hydrocarbons are opposite to those of nitrogen oxides, increasing the combustion efficiency of fuels will increase the combustion temperature, and high temperatures are likely to produce nitrogen oxides. Therefore, there is no reliable method to simultaneously reduce the hydrocarbons and nitrogen oxides in the exhaust gas.
  • the invention is a material based on terahertz technology, and products manufactured using the material can greatly reduce hydrocarbons and nitrogen oxides at the same time.
  • the invention can increase the gasoline energy conversion rate up to 47-50%.
  • the present invention provides a terahertz material used for emission reduction and fuel saving of gasoline vehicles, and a preparation method and application thereof.
  • the present invention adopts the following technical solutions:
  • a terahertz material used for emission reduction and fuel saving of gasoline vehicles including the following parts by weight of raw materials: SiOx: 20 to 35, Al 2 O 3 : 3-15, SiO 2 : 25 to 45, Fe 2 O 3 : 15-25, Ochre: 20-40, Barium Tungstate: 0.5-2, CaCO 3 : 15-25, Binchotan: 5-10.
  • the preparation method of the terahertz material for emission reduction and fuel saving of gasoline vehicles is as follows:
  • the terahertz radiation line includes a terahertz radiation component, a transmission belt and a tunnel frame; the terahertz radiation component is installed on the tunnel frame, the conveyor belt is set through the tunnel frame, and the terahertz radiation component is matched with the conveyor belt;
  • the irradiation component includes a terahertz wave electronic generator and a cable.
  • the terahertz wave electronic generator includes a logic unit, a fundamental wave unit, an equalization circuit, an amplifier, and a radiator.
  • the terahertz wave electronic generator is connected to the radiator through the cable , The radiator is attached to the inner wall of the tunnel frame.
  • the fundamental wave unit includes several fundamental wave modules arranged in parallel.
  • the fundamental wave module includes a driver, a BAW filter, a charge pump, an electrophotonic transition module and a resonant cavity; the logic unit controls the opening and closing of the charge pump through the driver, The external power supply supplies power to the electrophotonic transition module through the BAW filter and charge pump, and the electron beam generated in the electrophotonic transition module is transmitted to the resonant cavity to form a stable terahertz fundamental wave; the logic unit controls each fundamental wave module to emit the terahertz fundamental The terahertz fundamental wave is transmitted to the equalization circuit.
  • the equalization circuit adjusts the received terahertz fundamental wave to obtain a composite terahertz wave.
  • the composite terahertz wave is transmitted to the amplifier, and the amplifier amplifies the received composite terahertz wave.
  • Terahertz waves, amplified terahertz waves are transmitted to the radiator.
  • the electrophotonic transition module includes an electron gun, a pulse deflection coil, an electron beam, an anode, and a transition cavity; the transition cavity is connected to the resonant cavity, and the electron gun and the pulse deflection coil are installed in the transition cavity, and the pulse deflection coils form a frequency selection Electric field; the anode is installed on the inner wall of the resonant cavity; the electron gun is connected to an external power supply via a BAW via a charge pump and filter.
  • the electron gun emits electron beams into the frequency-selective electric field formed by the pulse deflection coil 36, and the frequency-selected electron beam enters the resonant cavity after resonance Received by the anode to form a terahertz fundamental wave.
  • the terahertz irradiation line has a power of 10 mW to 100 W and a time of 5 seconds to 1 hour for the enhancement treatment.
  • terahertz material for gasoline vehicle emission reduction and fuel saving produced by the preparation method directly added to the coolant for use and/or made into an activation sheet for use in gasoline vehicles, for example, terahertz materials can be used
  • the activation sheet is attached to the housing of the air cleaner.
  • the terahertz material is directly added to the coolant.
  • 2.5-6g terahertz material is required per liter of gasoline; for quantitative products with different displacement ranges, for example, 10g per bottle, suitable for less than 2.0L
  • the weight of each film is about 25-40g, and the amount of terahertz material is about 30-55% of the weight of the finished product.
  • the engine below 2.0L uses 2 pieces
  • the engine below 3.5L uses 3 or 4 pieces
  • the engine below 5.0L uses 4-6 pieces. If there is not enough place to attach the air filter shell, wrap the film on the outside of the air pipe and fix it with a cable tie.
  • terahertz materials used as raw materials for the production of auto parts, such as main water tanks, air filter housings, engine intake pipes, fuel pipes, fuel tank bottoms, ceramic pistons, spark plugs, cylinder liners, etc.
  • the terahertz material for gasoline vehicles of the present invention has the following beneficial effects: 1)
  • the terahertz material of the present invention includes SiOx.
  • SiOx has a special lattice structure. The existence of SiOx makes the The infrared emissivity of the Hertz material can reach 92-96%, while the infrared emissivity of the terahertz material without adding SiOx is only about 80%; 2)
  • the present invention improves the molecular activity of gasoline and air that participate in combustion work. Reducing molecular clusters to improve combustion efficiency is to solve the problem from the source; 3) At the same time, it has the effects of reducing emissions, energy saving, and improving power.
  • the products on the market are single-project products, and they often achieve a function At the same time, side effects that affect other functions occur; the principle of the present invention is completely different from these products.
  • the present invention has the lowest cost in terms of any single effect; 6)
  • the present invention can simultaneously reduce all the harmful substances in the exhaust gas: hydrocarbons, nitrogen oxides, and carbon monoxide, but because the fuel burns more fully, it produces There will be more carbon dioxide and water; 7)
  • Derivative products with the present invention as the core raw material can meet the needs of all gasoline engines and automobile inventory transformations and mass production of the whole machine factory; 8) The most optimistic estimation, all gasoline vehicles are used This product can reduce urban PM2.5 by about 15-20%.
  • the invention can increase the energy conversion rate of gasoline up to 47-50%.
  • Figure 1 The best solution for using terahertz materials for gasoline vehicles to reduce emissions and save fuel according to the present invention
  • Figure 2 The best modification plan and principle of the terahertz material used for emission reduction and fuel saving of gasoline vehicles of the present invention for internal combustion engine emission reduction;
  • Fig. 3 The whole scheme of the transformation of the vehicle with the terahertz material used for the emission reduction and fuel saving of gasoline vehicles of the present invention
  • Figure 4 The application of the terahertz material for gasoline vehicle emission reduction and fuel saving of the present invention in a complete machine plant
  • Figure 5 is a schematic diagram of the structure of a terahertz irradiation line
  • Figure 6 is a schematic diagram of the terahertz wave electron generator in Figure 5;
  • Fig. 7 is a schematic diagram of the fundamental wave module in Fig. 5;
  • FIG. 8 is a schematic diagram of the electrophotonic transition module in FIG. 7;
  • Figure 9 is a comparison diagram of the energy-saving effects of terahertz materials used for emission reduction and fuel saving of gasoline vehicles;
  • Figure 10 is a comparison diagram of the carbon monoxide emission reduction effect of terahertz materials used for emission reduction and fuel saving of gasoline vehicles;
  • Figure 11 is a comparison diagram of the emission reduction effect of terahertz materials used for gasoline vehicles to reduce emissions and fuel consumption on hydrocarbons;
  • Figure 12 is a comparison diagram of the effect of terahertz materials used for gasoline vehicle emission reduction and fuel saving on nitrogen oxide emission reduction; 1- internal combustion engine, 2- main water tank, 3- coolant/cooling cycle with terahertz material added, 4- Main water tank port, 5-secondary water tank, 6-small water tank—cab heating radiator, 7—coolant with terahertz material added, 8-fuel (gasoline, diesel, liquefied gas, etc.), 9-fuel tank, 10- fuel pump, 11- activated sheet containing terahertz material, 12-air inlet, 13-air (microscopically neatly arranged), 14-terahertz wave, 15-activated air (microscopic disorder and disorder), 16-air Filter housing, 17-air filter element, 18-filtered air (disordered), 19-injector, 20-internal combustion engine-combustion chamber, 21-activated air and fuel more fully contact, 22-piston/compression Stroke start, 23-Exhaust port, 24-Coolant/main tank
  • a kind of terahertz material for gasoline vehicle emission reduction and fuel saving including the following parts by weight of raw materials: SiOx: 25, Al 2 O 3 : 8, SiO 2 : 30, Fe 2 O 3 : 20, ochre: 30, Barium tungstate: 1, CaCO 3 : 20.
  • the preparation method of the terahertz material used for emission reduction and fuel saving of gasoline vehicles includes the following steps:
  • the terahertz irradiation line includes a terahertz irradiation assembly, a transmission belt 011, and a tunnel frame 012; the terahertz irradiation assembly is installed on the tunnel frame 012, and the conveyor belt 011 is set through the tunnel frame 012, and the terahertz irradiation
  • the photo component is matched with the conveyor belt 011;
  • the terahertz radiation component includes a terahertz wave electronic generator and a cable, and the terahertz wave electronic generator includes a logic unit 01, a fundamental wave unit 02, an equalization circuit 03, an amplifier 04 and Radiator 05:
  • the terahertz wave electronic generator is connected to the radiator 05 through a cable, and the radiator 05 is attached to the inner wall of the tunnel frame 012.
  • the fundamental wave unit 02 includes several fundamental wave modules arranged in parallel.
  • the fundamental wave modules include a driver 06, a BAW filter 07, a charge pump 08, an electrophotonic transition module 09 and a resonance Cavity 010;
  • the logic unit 01 controls the opening and closing of the charge pump 08 through the driver 06, the external power supply supplies power to the electrophotonic transition module 09 through the BAW filter 07 and the charge pump 08, and the electron beam generated in the electrophotonic transition module 09 is transmitted to the resonant cavity
  • a stable terahertz fundamental wave is formed in 010;
  • the logic unit 01 controls each fundamental wave module to emit a terahertz fundamental wave, and the terahertz fundamental wave is transmitted to the equalization circuit 03, and the equalization circuit 03 adjusts the received terahertz fundamental wave to obtain a composite
  • the terahertz wave, the composite terahertz wave is transmitted to the amplifier 04, the amplifier 04 amplifies the received composite terahertz wave to obtain the amplified tera
  • the electrophotonic transition module 09 includes an electron gun 035, a pulse deflection coil 036, an electron beam 037, an anode 038, and a transition cavity 039; the transition cavity 039 is in communication with the resonant cavity 010, and the electron gun 035 and the pulse deflection coil 036 is installed in the transition cavity 039, and a frequency selective electric field is formed between the pulse deflection coils 036; the anode 038 is installed on the inner wall of the resonant cavity 010; the electron gun 035 is connected to the external power supply via the charge pump 08 and the filter 07 via BAW, and the electron gun 035 emits electrons The beam 037 enters the frequency-selective electric field formed by the pulse deflection coil 036, and the frequency-selected electron beam enters the resonant cavity 010 and is received by the anode 038 to form a terahertz fundamental wave.
  • a kind of terahertz material for gasoline vehicle emission reduction and fuel saving including the following parts by weight of raw materials: SiOx: 20, Al 2 O 3 : 15, SiO 2 : 25, Fe 2 O 3 : 25, ochre: 20, Barium tungstate: 2, CaCO 3 : 15.
  • the preparation method of the terahertz material used for emission reduction and fuel saving of gasoline vehicles includes the following steps:
  • the crude silicon Si, SiO 2 and Binchotan charcoal were mixed in a weight ratio of 1:3:5, heated to 700°C in an oxygen-free environment, and maintained for 8 hours to generate black crystalline SiOx.
  • the resulting SiOx and The other raw materials are mixed according to the stated ratio and crushed to a fineness of 200-500 mesh. After adding an appropriate amount of water, stir, turn into small balls through a circular turntable, and heat to 1000°C in an oxygen-free environment for 4 hours.
  • Carry out secondary pulverization detect infrared emissivity ⁇ 0.92, then go through pulverization and powder processing again, the fineness reaches more than 10000 meshes, through the terahertz irradiation line for enhanced treatment (power 50W, time 1min), get the reduction Terahertz material for draining oil.
  • the structure of the terahertz irradiation line is the same as in Example 1.
  • a kind of terahertz material for gasoline vehicle emission reduction and fuel saving including the following parts by weight of raw materials: SiOx: 35, Al 2 O 3 : 3, SiO 2 : 45, Fe 2 O 3 : 5, ochre: 40, Barium tungstate: 0.5, CaCO 3 : 25.
  • the preparation method of the terahertz material used for emission reduction and fuel saving of gasoline vehicles includes the following steps:
  • the structure of the terahertz irradiation line is the same as in Example 1.
  • a kind of terahertz material for gasoline vehicle emission reduction and fuel saving including the following parts by weight of raw materials: SiOx: 25, Al 2 O 3 : 10, SiO 2 : 40, Fe 2 O 3 : 18, Ochre: 35, Barium tungstate: 1.5, CaCO 3 : 22.
  • the preparation method of the terahertz material used for emission reduction and fuel saving of gasoline vehicles includes the following steps:
  • the structure of the terahertz irradiation line is the same as in Example 1.
  • Figure 1 is an engine 1 which is also the most basic application form of the present invention.
  • the terahertz material for emission reduction and fuel saving of the present invention is used to add terahertz coolant 3 and terahertz air filter housing 16 and use them in combination.
  • the terahertz material of the present invention is made of engine coolant 3 with emission reduction, energy saving and power enhancement, and is injected into the cooling system through the main water tank port 4.
  • Some engine systems do not have a main water tank port, and the engine system can be injected from the auxiliary water tank 5.
  • the application of the terahertz material of the present invention in gasoline engines includes the following features:
  • the terahertz coolant is safe for people without nuclear radiation (particle radiation).
  • the terahertz material is mixed with the plastic master batch for injection molding. Do not mix into the metal casing.
  • the filter of the metal shell can only use the terahertz activation sheet 11@ Figure 2 to achieve the invented emission reduction, energy saving and power improvement effect.
  • the air filter housing with terahertz material added, as the air filter housing, has the same strength and temperature resistance as the ordinary air filter housing. Terahertz materials have no effect on the durability of plastics, reducing emissions and energy saving and improving power performance for more than 20 years.
  • This scheme is very suitable for automobile and engine manufacturers to directly adopt during vehicle production.
  • the use of the terahertz material for emission reduction and fuel saving of the present invention can produce a variety of emission reduction and energy saving products based on the terahertz principle, including antifreeze essence 24, air activation tablets 25-26, and fuel activation tablets 27- 28 and so on.
  • the most classic application method of this solution is the same as that of Example 1.
  • the antifreeze essence 24+air activation sheet 25 has the same effect as that of Example 1.
  • the scheme is more suitable for retrofitting existing vehicles.
  • the antifreeze essence 24 is injected into the cooling system through the main water tank port.
  • Some engine systems do not have a main water tank port, you can inject the engine system from the auxiliary water tank. It is extremely easy to stick the air activation sheet on the outside 25 of the air filter housing. However, in some vehicles, there is no flat surface on the air filter housing for sticking the air activating sheet to the outside of the engine intake pipe 26 to achieve almost the same effect.
  • the difficulty of implementing the fuel activation film is much greater than that of the air activation film, and the efficiency improvement is not obvious, so it is not necessary to use it.
  • the service life of the air activated sheet is 10 years, and its temperature resistance range is -40 ⁇ 200°C, which is fully adapted to the harsh environment in the engine compartment.
  • This scheme is very suitable for the emission reduction and energy saving modification of existing vehicles, and will surely bring considerable benefits to the society and car owners.
  • the use of the terahertz material for emission reduction and fuel saving of the present invention can produce a variety of emission reduction and energy saving original vehicle parts based on the terahertz principle.
  • a scheme needs to be further verified and optimized by the whole machine factory and engine factory. It includes special coolant 29 containing terahertz material, main water tank 30, air filter element 31, air filter housing 32, engine intake pipe 33, fuel pipe 34, fuel tank bottom 35, ceramic piston, spark plug, cylinder liner 36.
  • the terahertz material for emission reduction and fuel saving of the present invention can only be added to materials that are formed at medium and low temperature ( ⁇ 500°C) such as ceramics, plastics, silica gel, and rubber.
  • materials that are formed at medium and low temperature such as ceramics, plastics, silica gel, and rubber.
  • composite materials can be used, a layer of organic material is attached to the metal, and the organic material is added with the method of reducing emission and fuel saving terahertz material of the present invention.
  • Quanchai gasoline engine model A15G; fuel: 92 gasoline (including alcohol); cylinders arranged in-line four-cylinder; test time: 2019/1/16; power: 84kW; torque: 143Nm; displacement 1.499L; test location: Henan Luoyang; New Energy Engine Laboratory, Henan University of Science and Technology.
  • the test results are shown in Table 1-4 and Figure 8-12.

Abstract

一种用于汽油车辆减排节油的太赫兹材料，包括以下重量份数的原料：SiOx：20～35、Al 2O 3：3-15、SiO 2：25～45、Fe 2O 3：15～25、赭石：20～40、钨酸钡：0.5～2、CaCO 3：15～25。还公开了该太赫兹材料的制备方法，将各组分原料按照上述比例混合，经过粉碎，进入无氧环境下加热到600～1200℃，维持3～8小时，进行二次粉碎，经过太赫兹辐照线在10mW～100W、时间5秒～1小时条件下进行增强处理，得到用于汽油车辆减排节油的太赫兹材料。还公开了该太赫兹材料的应用。该太赫兹材料是通过提升参加燃烧做功的汽油和空气的分子活性、减小分子团，进而提高燃烧效率，同时具有减排、节能、提升动力的效果。

Description

一种用于汽油车辆减排节油的太赫兹材料及其制备方法和应用 技术领域
本发明属于太赫兹技术领域，具体涉及一种用于汽油车辆减排节油的太赫兹材料及其制备方法和应用。
背景技术
汽车尾气中的主要成分是碳氢化合物、氮氧化物、一氧化碳、二氧化碳、水、氮气和少量的氧气。其中造成环境污染的是碳氢化合物、氮氧化物、一氧化碳。由于碳氢化合物的产生条件与氮氧化物是相反的，提高燃料的燃烧效率，燃烧温度就会升高，高温则容易是产生氮氧化物。因此目前还没有一个可靠的方法能够同时降低尾气中的碳氢化合物、氮氧化物。本发明是一种基于太赫兹技术的材料，使用该材料制造的产品可以同时大幅降低碳氢化合物、氮氧化物。
不仅如此，由于目前发动机的能量转化率最高为42％，各科研机构穷尽各种手段，也很难使燃油的热效率继续提升，本发明可以提高汽油的能量转化率最高达到47～50％。
发明内容
针对现有技术中存在的问题，本发明提供一种用于汽油车辆减排节油的太赫兹材料及其制备方法和应用。
为解决上述技术问题，本发明采用以下技术方案：
一种用于汽油车辆减排节油的太赫兹材料，包括以下重量份数的原料：SiOx：20～35、Al 2O 3：3-15、SiO 2：25～45、Fe 2O 3：15～25、赭石：20～40、钨酸钡：0.5～2，CaCO 3：15～25、备长炭：5～10。
所述用于汽油车辆减排节油的太赫兹材料的制备方法如下：
(1)将粗硅Si、SiO 2和备长炭按照重量比1:(3～5):(5～10)的比例混合，在无氧的环境下加温到700～1500℃，维持1～8小时，生成黑色结晶体SiOx；
(2)将制成的SiOx与其他各组分原料按照所述比例混合，经过粉碎，细度达到200～500目，适量加水后搅拌(以原料粉末成球为标准)，经过圆形转盘变成小球，进入无氧环境下加热到600～1200℃，维持3～8小时，进行二次粉碎；
(3)检测红外发射率≥0.92，然后再次经过粉碎和粉末加工，细度达到10000目以上，经过太赫兹辐照线进行增强处理，得到用于汽油车辆减排节油的太赫兹材料。
所述太赫兹辐照线包括太赫兹辐照组件、传动带和隧道框架；太赫兹辐照组件安装在隧道框架上，传送带贯穿隧道框架设置，太赫兹辐照组件与传送带相配合；所述太赫兹辐照组件包括太赫兹波电子发生器和电缆，所述太赫兹波电子发生器，包括逻辑单元、基波单元、均衡电路、放大器和辐射器，太赫兹波电子发生器通过电缆与辐射器连接，辐射器贴附在隧道框架内壁。
所述基波单元包括若干个并联设置的基波模块，所述基波模块，包括驱动器、BAW滤波器、电荷泵、电光子跃迁模块和谐振腔；逻辑单元通过驱动器控制电荷泵的启闭，外部电源经BAW滤波器和电荷泵给电光子跃迁模块供电，电光子跃迁模块内产生的电子束传输到谐振腔内形成稳定的太赫兹基波；逻辑单元控制各基波模块发射出太赫兹基波，太赫兹基波传输 到均衡电路，均衡电路对接收到的太赫兹基波进行调理得到复合太赫兹波，复合太赫兹波传输给放大器，放大器对接收到的复合太赫兹波进行放大得到放大太赫兹波，放大太赫兹波传输到辐射器。
所述电光子跃迁模块，包括电子枪、脉冲偏转线圈、电子束、阳极、跃迁腔；跃迁腔与谐振腔连通，且电子枪和脉冲偏转线圈安装在跃迁腔内，且脉冲偏转线圈之间构成选频电场；阳极安装在谐振腔内壁；电子枪经电荷泵和滤波器与外部电源经BAW连接，电子枪发射电子束到脉冲偏转线圈36构成的选频电场内，选频后的电子束进入谐振腔谐振后被阳极接收形成太赫兹基波。
进一步，太赫兹辐照线进行增强处理的功率10mW～100W、时间5秒～1小时。
所述的制备方法制得的用于汽油车辆减排节油太赫兹材料的应用：直接加入冷却液中使用和/或制成激活片应用于汽油车辆，例如可以将采用太赫兹材料制成的激活片贴附在空气滤清器的外壳上。
将所述太赫兹材料直接加入冷却液中，根据发动机排量计算，每升汽油需用太赫兹材料2.5～6g；针对不同排量范围的定量产品，例如，每瓶10g，适用于2.0L以下的发动机；两瓶用于3.5L以下的发动机；三瓶用于5.0L以下的发动机。每个胶片成品重量，大约25～40g，太赫兹材料用量约为成品重量的30～55％。对应发动机，2.0L以下的发动机，用2片，3.5L以下的发动机用3或4片，5.0L以下的发动机用4～6片。空气滤清器的外壳，上面如果没有足够地方贴附的话，就把胶片裹在空气管的外面用扎带固定。
所述太赫兹材料的应用：作为汽车零部件生产的原材料使用，如主水 箱、空气滤清器外壳、发动机进气管、燃料管道、燃料箱底部、陶瓷活塞、火花塞、缸套等。
本发明的用于汽油车辆减排节油的太赫兹材料对比现有技术具备下述有益效果：1)本发明的太赫兹材料包括SiOx，SiOx具有特殊的晶格结构，SiOx的存在，使得太赫兹材料的红外发射率可以达到92-96％，而不加SiOx制得的太赫兹材料红外发射率仅仅为80％左右；2)本发明是通过提升参加燃烧做功的汽油和空气的分子活性、减小分子团，进而提高燃烧效率，这是从源头上解决问题；3)同时具有减排、节能、提升动力的效果，目前市场上都是单一项目的产品，而且经常会在实现一个功能的同时，出现影响其他功能的副作用；本发明的原理与这些产品也完全不一样。5)本发明就任何一个单一效果来讲成本都是最低的；6)本发明可以同时降低尾气中的全部有害物质：碳氢化合物、氮氧化物、一氧化碳，但由于燃料的燃烧更加充分，产生的二氧化碳和水会更多一些；7)以本发明为核心原料的衍生产品可以满足全部汽油发动机和汽车的存量改造和整机厂量产的需求；8)最乐观的测算，汽油车辆全部采用本产品可以降低城市PM2.5约15～20％。9)本发明可以提高汽油的能量转化率最高达到47～50％。
附图说明
图1本发明的用于汽油车辆减排节油的太赫兹材料使用最佳方案；
图2本发明的用于汽油车辆减排节油的太赫兹材料进行内燃机减排最佳改造方案及原理；
图3本发明的用于汽油车辆减排节油的太赫兹材料进行汽车改造的全部方案；
图4本发明的用于汽油车辆减排节油的太赫兹材料在整机厂的应用；
图5为太赫兹辐照线的结构示意图；
图6为图5中太赫兹波电子发生器的原理图；
图7为图5中基波模块的原理图；
图8为图7中电光子跃迁模块的示意图；
图9为用于汽油车辆减排节油的太赫兹材料的节能作用对比图；
图10为用于汽油车辆减排节油的太赫兹材料对一氧化碳的减排作用对比图；
图11为用于汽油车辆减排节油的太赫兹材料对碳氢化合物的减排作用对比图；
图12为用于汽油车辆减排节油的太赫兹材料对氮氧化物减排作用对比图；1-内燃机、2-主水箱、3-加入了太赫兹材料的冷却液/冷却循环、4-主水箱口、5-副水箱、6-小水箱——驾驶室暖风散热器、7-加入了太赫兹材料的冷却液8-燃料(汽油、柴油、液化气等)、9-燃料箱、10-燃料泵、11-含有太赫兹材料的激活片、12-空气入口、13-空气(微观整齐排列)、14-太赫兹波、15-激活的空气(微观混乱无序)、16-空气滤清器外壳、17-空气滤芯、18-过滤后的空气(无序)、19-喷油嘴、20-内燃机-燃烧室、21-激活的空气与燃料更充分接触、22-活塞/压缩冲程开始、23-排气口、24-加入了太赫兹材料的冷却液/主水箱、25-含有太赫兹材料的激活片/空气滤清器外壳、26-含有太赫兹材料的激活片/发动机进气管、27-含有太赫兹材料的激活片/燃料管道、28-含有太赫兹材料的激活片/燃料箱底部、29-含有太赫兹材料的特制冷却液、30-含有太赫兹材料的主水箱、31-含有太赫兹材料的空气滤芯、32-含有太 赫兹材料的空气滤清器外壳、33-含有太赫兹材料的发动机进气管、34-含有太赫兹材料的燃料管道、35-含有太赫兹材料的燃料箱底壳、36-含有太赫兹材料的陶瓷活塞、火花塞、缸套、017太赫兹波电子发生器、018、焙烧后的太赫兹材料半成品、015电缆、012隧道框架、011传送带、01逻辑单元、02基波单元、03均衡电路、04放大器、05辐射器、06驱动器、07BAW滤波器、08电荷泵、09电光子跃迁模块、010电子束传输到谐振腔、035电子枪、036脉冲偏转线圈、037电子束、038阳极、039跃迁腔。
具体实施方式
下面结合具体实施例，对本发明做进一步说明。应理解，以下实施例仅用于说明本发明而非用于限制本发明的范围，该领域的技术熟练人员可以根据上述发明的内容作出一些非本质的改进和调整。
实施例1
一种用于汽油车辆减排节油的太赫兹材料，包括以下重量份数的原料：SiOx：25、Al 2O 3：8、SiO 2：30、Fe 2O 3：20、赭石：30、钨酸钡：1，CaCO 3：20。
所述的用于汽油车辆减排节油的太赫兹材料的制备方法，包括以下步骤：
(1)将粗硅Si、SiO 2和备长炭按照重量比1:4:8的比例混合，在无氧的环境下加温到1200℃，维持5小时，生成黑色结晶体SiOx；
(2)将制成的SiOx与其他各组分原料按照所述比例混合，经过粉碎，细度达到200～500目，适量加水后搅拌，经过圆形转盘变成小球，进入无氧环境下加热到800℃，维持5小时，进行二次粉碎；
(3)检测红外发射率≥0.92，然后再次经过粉碎和粉末加工，细度达到10000目以上，经过太赫兹辐照线进行增强处理(功率20W、时间10min)，得到用于汽油车辆减排节油的太赫兹材料。
如图5所示，所述太赫兹辐照线包括太赫兹辐照组件、传动带011和隧道框架012；太赫兹辐照组件安装在隧道框架012上，传送带011贯穿隧道框架012设置，太赫兹辐照组件与传送带011相配合；所述太赫兹辐照组件包括太赫兹波电子发生器和电缆，所述太赫兹波电子发生器包括逻辑单元01、基波单元02、均衡电路03、放大器04和辐射器05；太赫兹波电子发生器通过电缆与辐射器05连接，辐射器05贴附在隧道框架012内壁。
如图6-7所示，所述基波单元02包括若干个并联设置的基波模块，所述基波模块，包括驱动器06、BAW滤波器07、电荷泵08、电光子跃迁模块09和谐振腔010；逻辑单元01通过驱动器06控制电荷泵08的启闭，外部电源经BAW滤波器07和电荷泵08给电光子跃迁模块09供电，电光子跃迁模块09内产生的电子束传输到谐振腔010内形成稳定的太赫兹基波；逻辑单元01控制各基波模块发射出太赫兹基波，太赫兹基波传输到均衡电路03，均衡电路03对接收到的太赫兹基波进行调理得到复合太赫兹波，复合太赫兹波传输给放大器04，放大器04对接收到的复合太赫兹波进行放大得到放大太赫兹波，放大太赫兹波传输到辐射器05。
如图8所示，所述电光子跃迁模块09，包括电子枪035、脉冲偏转线圈036、电子束037、阳极038、跃迁腔039；跃迁腔039与谐振腔010连通，且电子枪035和脉冲偏转线圈036安装在跃迁腔039内，且脉冲偏转线圈036之间构成选频电场；阳极038安装在谐振腔010内壁；电子枪035 经电荷泵08和滤波器07与外部电源经BAW连接，电子枪035发射电子束037到脉冲偏转线圈036构成的选频电场内，选频后的电子束进入谐振腔010谐振后被阳极038接收形成太赫兹基波。
实施例2
一种用于汽油车辆减排节油的太赫兹材料，包括以下重量份数的原料：SiOx：20、Al 2O 3：15、SiO 2：25、Fe 2O 3：25、赭石：20、钨酸钡：2，CaCO 3：15。
所述的用于汽油车辆减排节油的太赫兹材料的制备方法，包括以下步骤：
将粗硅Si、SiO 2和备长炭按照重量比1:3:5的比例混合，在无氧的环境下加温到700℃，维持8小时，生成黑色结晶体SiOx，将制成的SiOx与其他各组分原料按照所述比例混合，经过粉碎，细度达到200～500目，适量加水后搅拌，经过圆形转盘变成小球，进入无氧环境下加热到1000℃，维持4小时，进行二次粉碎；检测红外发射率≥0.92，然后再次经过粉碎和粉末加工，细度达到10000目以上，经过太赫兹辐照线进行增强处理(功率50W、时间1min)，得到用于汽油车辆减排节油的太赫兹材料。
太赫兹辐照线的结构同实施例1。
实施例3
一种用于汽油车辆减排节油的太赫兹材料，包括以下重量份数的原料：SiOx：35、Al 2O 3：3、SiO 2：45、Fe 2O 3：5、赭石：40、钨酸钡：0.5，CaCO 3：25。
所述的用于汽油车辆减排节油的太赫兹材料的制备方法，包括以下步 骤：
(1)将粗硅Si、SiO 2和备长炭按照重量比1:5:10的比例混合，在无氧的环境下加温到1500℃，维持1小时，生成黑色结晶体SiOx；
(2)将制成的SiOx与其他各组分原料按照所述比例混合，经过粉碎，细度达到200～500目，适量加水后搅拌，经过圆形转盘变成小球，进入无氧环境下加热到600℃，维持8小时，进行二次粉碎；
(3)检测红外发射率≥0.92，然后再次经过粉碎和粉末加工，细度达到10000目以上，经过太赫兹辐照线进行增强处理(功率100W、时间5秒)，得到用于汽油车辆减排节油的太赫兹材料。
太赫兹辐照线的结构同实施例1。
实施例4
一种用于汽油车辆减排节油的太赫兹材料，包括以下重量份数的原料：SiOx：25、Al 2O 3：10、SiO 2：40、Fe 2O 3：18、赭石：35、钨酸钡：1.5，CaCO 3：22。
所述的用于汽油车辆减排节油的太赫兹材料的制备方法，包括以下步骤：
(1)将粗硅Si、SiO 2和备长炭按照重量比1:4:7的比例混合，在无氧的环境下加温到1000℃，维持5小时，生成黑色结晶体SiOx；
(2)将制成的SiOx与其他各组分原料按照所述比例混合，经过粉碎，细度达到200～500目，适量加水后搅拌，经过圆形转盘变成小球，进入无氧环境下加热到1200℃，维持3小时，进行二次粉碎；
(3)检测红外发射率≥0.92，然后再次经过粉碎和粉末加工，细度达 到10000目以上，经过太赫兹辐照线进行增强处理(功率10mW、时间1小时)，得到用于汽油车辆减排节油的太赫兹材料。
太赫兹辐照线的结构同实施例1。
应用例1
图1，是一台发动机1，也是本发明最基本的应用形式，使用本发明的减排节油的太赫兹材料加入太赫兹冷却液3和太赫兹空滤外壳16，并将它们联合使用。主要性能：碳氢化合物HC降低35～99％，氮氧化物NOx降低40～90％，一氧化碳CO降低30～-5％，市区节能6～-10％，高速节能9～-20％(极限40％)，0～100km/h行驶距离缩短10％，0～100km/h加速时间减少3％，动力曲线明显改善，降低一档燃油标号且更省油。
本发明的太赫兹材料制成具有减排节能提升动力功效的发动机冷却液3，经主水箱口4注入冷却系统。有的发动机系统没有主水箱口，则可以从副水箱5注入发动机系统。
本发明的太赫兹材料在汽油发动机的应用包括以下特征：
1)太赫兹冷却液的防冻液方面的性能与普通防冻液相同，规格也与普通防冻液相同。
2)太赫兹冷却液使用寿命与普通防冻液相同，期间作为冷却液的效能没有衰减。只要系统没有泄露，或车辆事故造成冷却液损失，其减排节能性能不会变化。
3)太赫兹冷却液无核辐射(粒子辐射)对人安全。
4)在空气滤清器外壳制作的时候，将太赫兹材料混入塑料母料进行注塑。不能混入金属外壳。金属外壳的滤清器只能采用太赫兹激活片11@ 图2方式达成本发明的减排节能提升动力的效果。
5)添加了太赫兹材料的空气滤清器外壳，作为空滤外壳的强度、耐温等性能与普通空滤外壳相同。太赫兹材料对塑料的耐久性没有影响，减排节能提升动力的性能长达20年以上。
本方案很适合汽车和发动机生产厂在车辆生产时直接采用。
应用例2
如图2所示，使用本发明的减排节油的太赫兹材料可以制造多种太赫兹原理的减排、节能产品，包括防冻精华液24、空气激活片25-26、燃料激活片27-28等。这个方案最经典的应用方式与实施例1一样，防冻精华液24+空气激活片25，效能与实施例1完全一样。方案更适合既有车辆进行改造用。
防冻精华液24经主水箱口注入冷却系统。有的发动机系统没有主水箱口，则可以从副水箱注入发动机系统。将空气激活片粘在空滤外壳的外面25是极其容易的事情。但有些车辆的空滤外壳上没有平面用于粘贴空气激活片捆在发动机进气管26外面也会取得几乎一样的效果。燃料激活片实施难度相比空气激活片难度大得多，而且效能提升并不明显，因此能不用就不用了吧。
1)防冻精华液加入冷却系统后，其冷却和防冻性能与普通防冻液一样，其减排节能效能与太赫兹冷却液一样。
2)防冻精华液加入冷却系统后，其使用寿命与普通防冻液相同，期间作为冷却液的效能没有衰减。只要系统没有泄露，或车辆事故造成冷却液损失，其减排节能性能不会变化。
3)防冻精华液和空气激活片无核辐射(粒子辐射)对人安全。
4)空气激活片的使用寿命10年，其耐温范围-40～200℃，完全适应发动机舱内的严酷环境。
本方案很适合既有车辆减排节能改装，必将给社会和车主带来可观的利益。
应用例3
如图3所示，列举了使用本发明的减排节油的太赫兹材料可以制造多种太赫兹原理的减排、节能的原厂车辆零件。这样的方案有待于整机厂和发动机厂的进一步验证和优化。包括含有太赫兹材料的特制冷却液29、主水箱30、空气滤芯31、空气滤清器外壳32、发动机进气管33、燃料管道34、燃料箱底壳35、陶瓷活塞、火花塞、缸套36。
本发明的减排节油的太赫兹材料只能加入陶瓷、塑料、硅胶、橡胶等中低温(<500℃)成型的材料。对于金属制造的零件可以用复合材料，在金属上附着一层有机材料，并在有机材料里添加本发明的减排节油的太赫兹材料的方法解决。
本方案里所有的零部件的寿命和强度与原来的零部件相比完全一样，规格尺寸也完全一样。只是维修替换的时候必须注意不能用原来的零件，否则减排节能效果会大打折扣。
发动机台架测试(尾气净：冷却液添加剂+空气激活贴)
全柴汽油发动机型号：A15G；燃料：92号汽油(含酒精)；汽缸排列直列四缸；测试时间：2019/1/16；功率：84kW；扭矩：143Nm；排量1.499L；测试地点：河南洛阳；河南科技大学新能源发动机实验室。 测试结果如表1-4所示和图8-12所示。
表1尾气净的节能作用
Figure PCTCN2020096829-appb-000001
工况/千瓦油耗 原机 尾气净 节油率
城市工况 338.8 299.1 11.73％
高速工况 410.5 363.4 11.46％
表2尾气净的减排作用-一氧化碳
Figure PCTCN2020096829-appb-000002
表3尾气净的减排作用-碳氢化合物
Figure PCTCN2020096829-appb-000003
表4尾气净的减排作用-氮氧化物
Figure PCTCN2020096829-appb-000004
以上显示和描述了本发明的基本原理和主要特征以及本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (9)

  1. 一种用于汽油车辆减排节油的太赫兹材料，其特征在于包括以下重量份数的原料：SiOx：20～35、Al 2O 3：3-15、SiO 2：25～45、Fe 2O 3：15～25、赭石：20～40、钨酸钡：0.5～2，CaCO 3：15～25。
  2. 根据权利要求1所述的用于汽油车辆减排节油的太赫兹材料的制备方法，其特征在于包括以下步骤：
    (1)将粗硅Si、SiO 2和备长炭按照重量比1:(3～5):(5～10)的比例混合，在无氧的环境下加温到700～1500℃，维持1～8小时，生成黑色结晶体SiOx；
    (2)将制成的SiOx与其他各组分原料按照所述比例混合，经过粉碎，细度达到200～500目，适量加水后搅拌，经过圆形转盘变成小球，进入无氧环境下加热到600～1200℃，维持3～8小时，进行二次粉碎；
    (3)检测红外发射率≥0.92，然后再次经过粉碎和粉末加工，细度达到10000目以上，经过太赫兹辐照线进行增强处理，得到用于汽油车辆减排节油的太赫兹材料。
  3. 根据权利要求2所述的用于汽油车辆减排节油的太赫兹材料的制备方法，其特征在于：所述太赫兹辐照线包括太赫兹辐照组件、传动带(011)和隧道框架(012)；太赫兹辐照组件安装在隧道框架(012)上，传送带(011)贯穿隧道框架(012)设置，太赫兹辐照组件与传送带(011)相配合；所述太赫兹辐照组件包括太赫兹波电子发生器和电缆，所述太赫兹波电子发生器包括逻辑单元(01)、基波单元(02)、均衡电路(03)、放大器(04)和辐射器(05)；太赫兹波电子发生器通过电缆与辐射器连接，辐射器贴附在隧道框架内壁。
  4. 根据权利要求3所述的用于汽油车辆减排节油的太赫兹材料的制备方法，其特征在于：所述基波单元(02)包括若干个并联设置的基波模块，所述基波模块，包括驱动器(06)、BAW滤波器(07)、电荷泵(08)、电光子跃迁模块(09)和谐振腔(010)；逻辑单元(01)通过驱动器(06)控制电荷泵(08)的启闭，外部电源经BAW滤波器(07)和电荷泵(08)给电光子跃迁模块(09)供电，电光子跃迁模块(09)内产生的电子束传输到谐振腔(010)内形成稳定的太赫兹基波；逻辑单元(01)控制各基波模块发射出太赫兹基波，太赫兹基波传输到均衡电路(03)，均衡电路(03)对接收到的太赫兹基波进行调理得到复合太赫兹波，复合太赫兹波传输给放大器(04)，放大器(04)对接收到的复合太赫兹波进行放大得到放大太赫兹波，放大太赫兹波传输到辐射器(05)。
  5. 根据权利要求4所述的用于汽油车辆减排节油的太赫兹材料的制备方法，其特征在于：所述电光子跃迁模块(09)，包括电子枪(035)、脉冲偏转线圈(036)、电子束(037)、阳极(038)、跃迁腔(039)；跃迁腔(039)与谐振腔(010)连通，且电子枪(035)和脉冲偏转线圈(036)安装在跃迁腔(039)内，且脉冲偏转线圈(036)之间构成选频电场；阳极(038)安装在谐振腔(010)内壁；电子枪(035)经电荷泵(08)和滤波器(07)与外部电源经BAW连接，电子枪(035)发射电子束(037)到脉冲偏转线圈(036)构成的选频电场内，选频后的电子束进入谐振腔(010)谐振后被阳极(038)接收形成太赫兹基波。
  6. 根据权利要求2所述的用于汽油车辆减排节油的太赫兹材料的制备方法，其特征在于：太赫兹辐照线进行增强处理的功率10mW～100W、时间5秒 ～1小时。
  7. 根据权利要求1-6任一所述的制备方法制得的用于汽油车辆减排节油太赫兹材料的应用，其特征在于：直接加入冷却液中使用和/或制成激活片应用于汽油车辆。
  8. 根据权利要求7所述的应用，其特征在于：将所述太赫兹材料直接加入冷却液中，根据发动机排量计算，每升汽油需用太赫兹材料2.5～6g；以每个激活片成品重量为25～40g计算，太赫兹材料用量约为成品重量的30～55％，激活片的制备工艺同普通硅胶片的制备。
  9. 根据权利要求1-6任一所述的制备方法制得的用于汽油车辆减排节油太赫兹材料的应用，其特征在于：作为汽车零部件生产的原材料使用，汽车零部件包括但不限于主水箱、空气滤清器外壳、发动机进气管、燃料管道、燃料箱底部、陶瓷活塞、火花塞、缸套。
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