WO2020203546A1 - Feuille de transfert - Google Patents

Feuille de transfert Download PDF

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Publication number
WO2020203546A1
WO2020203546A1 PCT/JP2020/013315 JP2020013315W WO2020203546A1 WO 2020203546 A1 WO2020203546 A1 WO 2020203546A1 JP 2020013315 W JP2020013315 W JP 2020013315W WO 2020203546 A1 WO2020203546 A1 WO 2020203546A1
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WO
WIPO (PCT)
Prior art keywords
layer
transfer sheet
transfer
acrylic resin
acetate copolymer
Prior art date
Application number
PCT/JP2020/013315
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English (en)
Japanese (ja)
Inventor
慧理 司馬
Original Assignee
大日本印刷株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 大日本印刷株式会社 filed Critical 大日本印刷株式会社
Publication of WO2020203546A1 publication Critical patent/WO2020203546A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer

Definitions

  • the present invention relates to a transfer sheet that is transferred to a transfer body made of an inorganic material.
  • a transfer sheet on which various patterns are printed has been transferred to a transfer body such as stone, wood, concrete, or metal.
  • a decorative material having the same design as natural wood is produced by transferring a transfer sheet printed with a wood grain pattern similar to that of natural wood to a transfer body of a calcium silicate board. (See Patent Document 1).
  • the decorative material provided with the above transfer sheet may be used in applications where heat resistance is required.
  • the plasticizer for example, phthalate ester
  • the heat-welding adhesive layer tends to soften at a high temperature. Therefore, when a heat resistance test (for example, JAS specially processed decorative plywood type 2 immersion peeling test) is performed on a decorative material on which a transfer sheet is transferred to a calcium silicate board, the air that has thermally expanded inside the transferred body, or The generated gas cannot be suppressed by the heat-sealing adhesive layer, swelling occurs on the surface of the decorative material, and the adhesion with the calcium silicate board cannot be maintained.
  • a heat resistance test for example, JAS specially processed decorative plywood type 2 immersion peeling test
  • the air bubbles are generated by heat even inside the heat-sealing adhesive layer, the air bubbles also cause swelling on the surface of the decorative material. Further, even when the surface of the decorative material does not swell, abnormalities such as deformation may occur in the decorative material, and the appearance design may be deteriorated.
  • An object of the present invention is to provide a transfer sheet having excellent adhesion to a transfer object, heat resistance, and appearance design.
  • the first invention is a transfer sheet (1) to be transferred to a transfer material made of an inorganic material, which comprises a releasable support (10) and a transfer layer (2) including an adhesive layer (40).
  • the adhesive layer contains a vinyl chloride-vinyl acetate copolymer and an acrylic resin
  • the vinyl chloride-vinyl acetate copolymer has a blending ratio of 50 or more and 100% with respect to the acrylic resin. It is less than, and the glass transition temperature of the acrylic resin is 60 ° C. or higher.
  • the second invention is the transfer sheet according to the first invention, and the glass transition temperature of the acrylic resin is 110 ° C. or lower.
  • the third invention is a transfer sheet according to the first or second invention, and the glass transition temperature of the vinyl chloride-vinyl acetate copolymer is 70 ° C. or higher.
  • the fourth invention is a transfer sheet according to any one of the first to third inventions, and the inorganic material is a calcium silicate plate.
  • the fifth invention is a transfer sheet according to any one of the first to fourth inventions, and the transfer layer includes at least one layer of a release layer and a decorative layer in addition to the adhesive layer.
  • FIG. 1 is a diagram schematically shown, and the size and shape of each part are exaggerated as appropriate for easy understanding. are doing. Numerical values such as dimensions of each member and material names described in the present specification are examples of embodiments, and are not limited thereto, and may be appropriately selected and used.
  • FIG. 1 is a cross-sectional view of the transfer sheet 1 in the present embodiment.
  • the transfer sheet 1 can be stored or transported in the form shown in FIG.
  • the transfer sheet 1 of the present embodiment includes a release support 10, a release layer 20, a decorative layer 30, a heat-welding adhesive layer 40, and a release base sheet 50.
  • the release layer 20, the decorative layer 30, and the heat-weld adhesive layer 40 constitute the transfer layer 2.
  • the configuration of the transfer layer 2 is not limited to the combination of the present embodiment, and other functional layers may be included. Further, the transfer layer 2 may be configured not to include a part of the functional layers from the combination of the present embodiment.
  • the transfer sheet 1 of the present embodiment a thin film sheet having flexibility is adopted as the releasable support 10 having releasability with respect to the release layer 20 (transfer layer 2).
  • the release layer 20, the decorative layer 30, and the heat-weld adhesive layer 40 constituting the transfer layer 2 are laminated in this order.
  • laminated in this order means not only direct lamination but also indirect lamination. For example, between the releasable support 10 and the release layer 20, another It means that even if there is a layer of, it is acceptable.
  • the releasable support 10 is a sheet that supports the transfer layer 2 including the heat-sealing adhesive layer 40.
  • the releasable support 10 has releasability (removability) with respect to the transfer layer 2, and after the transfer sheet 1 is adhered to the transferred body 60 (described later), the releasable layer 20 (transfer layer 2). It is peeled off from the interface with.
  • the releasable support 10 is a sheet made of, for example, a polyester resin such as polyethylene terephthalate, polyethylene naphthalate, or polybutylene terephthalate, a polyolefin resin such as polypropylene, polyethylene, or polymethylpentene, or a thermoplastic resin such as a polyamide resin.
  • a polyester resin such as polyethylene terephthalate, polyethylene naphthalate, or polybutylene terephthalate
  • a polyolefin resin such as polypropylene, polyethylene, or polymethylpentene
  • a thermoplastic resin such as a polyamide resin.
  • the releasable support 10 a form in which the transfer layer 2 and a resin layer having releasability are laminated on the surface on the side where the transfer layer 2 of paper is formed can be mentioned.
  • the paper high-quality paper, linter paper, glassine paper, parchment paper, kraft paper and the like can be used.
  • Examples of the resin layer having releasability with respect to the transfer layer 2 include the above-mentioned various thermoplastic resins, melamine resin, epoxy resin, silicon resin and the like.
  • these releasable supports a biaxially stretched polyethylene terephthalate (PET) sheet is preferable in terms of excellent strength and flexibility.
  • PET polyethylene terephthalate
  • a conventionally known release layer may be formed on the surface of the release support 10 on the release layer 20 side, or a release process may be applied.
  • the film thickness of the releasable support 10 is about 10 to 100 ⁇ m, preferably 20 to 60 ⁇ m.
  • the release layer 20 is a layer laminated to facilitate the release of the releasable support 10 from the transfer layer 2.
  • the release layer 20 remains as the outermost layer of the transfer layer 2 after the transfer layer 2 on the transfer sheet 1 is adhered onto the transfer target 60 and the releasable support 10 is peeled off.
  • the release layer 20 can be used as a protective layer on the outermost surface of the decorative material 100, but usually, the durability such as abrasion resistance, stain resistance, water resistance, and weather resistance of the surface of the decorative material 100 is further enhanced.
  • a top coat layer 70 (described later) is further formed on the surface of the release layer 20.
  • Examples of the resin constituting the release layer 20 include methyl poly (meth) acrylate, ethyl poly (meth) acrylate, butyl poly (meth) acrylate, and methyl (meth) methyl acrylate-butyl acrylate.
  • Acrylic resin such as coalescence, one of (meth) acrylic acid alkyl ester monomers such as (meth) methyl acrylate, (meth) ethyl acrylate, (meth) propyl acrylate, (meth) butyl acrylate, etc.
  • (meth) acrylic acid is a notation meaning acrylic acid or methacrylic acid.
  • compositions include, for example, an ultraviolet absorber (UVA) composed of organic compounds such as benzotriazole, benzophenone, and triazine, or fine particles such as titanium oxide, zirconium oxide, and cerium oxide, and a hindered amine radical scavenger.
  • UVA ultraviolet absorber
  • a radical scavenger such as (HALS) may be added.
  • the layer thickness (dry) of the release layer 20 is, for example, about 1 to 2 ⁇ m.
  • the decorative layer 30 is a layer on which the pattern (design) of the transfer sheet 1 is formed, and is formed by printing or the like.
  • the resin constituting the decorative layer 30 include an acrylic resin, a vinyl chloride-vinyl acetate copolymer (vinyl acetate) resin, a cellulose resin, a urethane resin, and a composition obtained by mixing an acrylic resin and a vinyl acetate resin. And so on. Further, various known coloring pigments, coloring dyes and the like are added to the decorative layer 30.
  • the layer thickness (dry) of the decorative layer 30 is, for example, about 5 ⁇ m.
  • the heat-welding adhesive layer 40 is a layer that adheres the transfer sheet 1 and the transfer body 60 when the transfer sheet 1 is transferred to the transfer body 60.
  • the heat-sealing adhesive layer 40 is provided on the transfer layer 2 on the opposite side of the releasable support 10.
  • the heat-weld adhesive layer 40 contains a vinyl chloride-vinyl acetate copolymer and an acrylic resin (or an acrylic resin composition).
  • the vinyl chloride-vinyl acetate copolymer is a material that easily adheres to the sealer layer 62 (described later) formed on the surface of the transferred body 60.
  • the transferability and adhesion of the transfer sheet 1 to the transferred body 60 by the vinyl chloride-vinyl acetate copolymer contained in the heat-welding adhesive layer 40 You can get sex.
  • the vinyl chloride-vinyl acetate copolymer is a material for imparting heat resistance to the decorative material 100 (described later) to which the transfer sheet 1 has been transferred.
  • the glass transition temperature (Tg) of the vinyl chloride-vinyl acetate copolymer is preferably 70 ° C. or higher.
  • the blending ratio of the vinyl chloride-vinyl acetate copolymer to the total of the vinyl chloride-vinyl acetate copolymer and the acrylic resin composition is set to 50% or 80%. There is.
  • the blending ratio of the vinyl chloride-vinyl acetate copolymer to the total of the vinyl chloride-vinyl acetate copolymer and the acrylic resin composition is preferably 50% or more and less than 100%, and 70% or more and less than 100%. It is more desirable to set it to 70% or more and 90% or less.
  • the acrylic resin is a material for imparting heat resistance to the decorative material 100 (described later) to which the transfer sheet 1 has been transferred.
  • the glass transition temperature (Tg) of the acrylic resin is preferably 60 ° C. or higher.
  • the layer thickness (dry) of the heat-sealing adhesive layer 40 is preferably 1 or more and 10 ⁇ m or less, and more preferably 1 or more and 2 ⁇ m or less.
  • the release base sheet 50 is a sheet that is temporarily laminated on the heat-sealing adhesive layer 40.
  • the release base sheet 50 is peeled from the transfer sheet 1 in order to expose the heat-weldable adhesive layer 40 when the transfer sheet 1 is transferred to the transfer target 60.
  • Examples of the material constituting the release base sheet 50 include silicon release type polyethylene terephthalate (PET), untreated polyethylene terephthalate, polypropylene and the like.
  • PET polyethylene terephthalate
  • the thickness of the release base sheet 50 is preferably 10 ⁇ m or more and 100 ⁇ m or less, and more preferably 20 ⁇ m or more and 60 ⁇ m or less.
  • the release base sheet 50 is provided as needed.
  • FIG. 3 and FIG. 4 are cross-sectional views showing a method of manufacturing the decorative material 100.
  • the release base sheet 50 is peeled from the transfer sheet 1.
  • the surface (joint surface) of the heat-welding adhesive layer 40 opposite to the decorative layer 30 is exposed.
  • the transfer sheet 1 from which the release base sheet 50 has been peeled off is laminated on the transferred body 60.
  • the transfer sheet 1 can be continuously laminated on the transferred body 60, for example, in the form of a roll-to-roll, a roll-to-sheet, or the like.
  • Roll to roll means that a band-shaped transfer sheet 1 is pulled out from a roll (winding) and supplied to a flat plate-shaped transfer target (transfer target body 61), and a transfer layer 2 is placed on the transfer target.
  • This is a processing mode in which a strip-shaped releasable support (removable support 10) from which the transfer layer 2 has been released is wound again on a roll after being laminated.
  • the "roll to sheet” means that the strip-shaped transfer sheet 1 is pulled out from the roll (winding) and supplied to the flat plate-shaped transfer body, and before and after the transfer layer 2 is laminated on the transfer target body,
  • the transfer sheet 1 is cut to a size roughly equivalent to one sheet to be transferred and made into single leaves, and the single-leaf releasable support from which the transfer layer 2 is released is removed (discarded) one by one.
  • the transfer sheet 1 may be manually laminated on the transferred body 60 and then pressed with a spatula or the like to uniformly adhere to the surface of the transferred body 60.
  • the transferred body 60 of the present embodiment includes a transferred body main body 61 and a sealer layer 62.
  • the transfer body body 61 is the transfer body itself to which the transfer sheet 1 is transferred.
  • the body to be transferred 61 is made of an inorganic material. Examples of the inorganic material constituting the transfer body body 61 include a porous material such as calcium silicate and a porous stone material.
  • the sealer layer 62 is an undercoat layer for sealing or filling the surface of the transfer body body 61 to improve the adhesion between the transfer body body 61 and the transfer sheet 1.
  • Examples of the material constituting the sealer layer 62 include urethane resin.
  • the releasable support 10 is peeled off from the transfer sheet 1 adhered onto the transfer body 60.
  • the transfer step is completed by peeling the releasable support 10 from the transfer sheet 1, and the surface of the peeling layer 20 opposite to the decorative layer 30 is exposed.
  • the heat-weld adhesive layer 40 of the transfer sheet 1 and the transferred body 60 are bonded with a strong adhesive force, so that when the releasable support 10 is peeled off from the transfer sheet 1. , The transfer sheet 1 does not peel off from the transferred body 60.
  • the top coat layer 70 is formed on the exposed surface of the release layer 20.
  • the laminate of the transfer layer 2 including the top coat layer 70 and the transferred body 60 is also referred to as “decorative material 100”.
  • the top coat layer 70 is a layer for imparting color, gloss, etc. to the surface of the decorative material 100 and protecting the decorative layer 30 as a finishing agent. Further, by forming the top coat layer 70, it is possible to impart durability such as weather resistance, stain resistance, and abrasion resistance to the decorative material 100.
  • the top coat layer 70 examples include an acrylic resin, a silicon-based resin, a fluororesin, and a urethane resin that are cured by ionizing radiation such as ultraviolet rays (UV resin) and electron beams (EB), or by heat.
  • the thickness of the top coat layer 70 is not particularly limited, but is preferably 5 ⁇ m or more and 1000 ⁇ m or less, and more preferably 10 ⁇ m or more and 300 ⁇ m or less.
  • the decorative material 100 is heated and pressurized for a predetermined time (hereinafter, also referred to as “thermal transfer”).
  • the heating and pressurization of the decorative material 100 are schematically represented by arrows.
  • pressure may be applied to the decorative material 100 while blowing hot air, or the decorative material 100 may be installed in a heating furnace set to a predetermined temperature. Further, a roller provided with a heat source inside may be moved over a predetermined time while being pressed against the surface of the decorative material 100. The method of heating the decorative material 100 and the method of applying pressure can be appropriately selected.
  • top coat layer 70 When the top coat layer 70 is an ionizing radiation curable resin, it is cured by irradiating it with ionizing radiation such as ultraviolet rays.
  • ionizing radiation such as ultraviolet rays.
  • FIG. 4 (F) a state in which the inside of the heat-sealing adhesive layer 40 is cured by heating is represented by a fine dot pattern.
  • a 25 ⁇ m-thick biaxially stretched PET sheet (“E5001” manufactured by Toyobo Co., Ltd.) was prepared as the releasable support 10, and an acrylic resin composition (“A50-1” Tg at about 50 ° C. Showa Inc.) was prepared on one surface thereof. (Manufactured by Kogyo Co., Ltd.) was applied to form a release layer 20 having a film thickness (dry) of 1 ⁇ m.
  • a composition of a vinyl chloride-vinyl acetate copolymer (“Chemical X (NT)” Tg about 75 ° C. manufactured by Showa Ink Industry Co., Ltd.) and an acrylic resin composition (“A50-1” Tg about 50 ° C., " Inks prepared by blending "SSCON” Tg about 70 ° C. and “Chemical X (NT) Tg about 100 ° C., both manufactured by Showa Ink Industry Co., Ltd.) at a ratio of 5 levels from 0: 100 to 100: 0.
  • a calcium silicate plate (transfer body body 61 and sealer layer 62) is prepared, and after preheating this at 100 ° C., the transfer sheets of Comparative Examples and Examples are 160 on the surface thereof.
  • the decorative materials of Comparative Examples and Examples were prepared by thermal transfer at ⁇ 180 ° C.
  • the releasable support 10 is peeled from this decorative material, a solvent-free acrylic resin-based ultraviolet curable resin paint is applied onto the exposed release layer 20, and the top coat layer is cured by ultraviolet irradiation from a mercury lamp. 70 was formed.
  • the decorative materials of Comparative Examples 1 to 7 (11 types) and the decorative materials of Examples 1 to 4 (4 types) were prepared as test samples, respectively.
  • a JAS specially processed decorative plywood type 2 immersion peeling test was carried out. Specifically, the state of the surface of the decorative material after immersing the decorative material as a test sample in warm water at 70 ° C. for 2 hours and then drying at 60 ° C. for 3 hours was observed.
  • FIGS. 5 to 7 The evaluation results of each of the above test items for each of the decorative materials of Comparative Examples 1 to 7 and Examples 1 to 4 are shown in FIGS. 5 to 7.
  • FIG. 5 is a diagram showing the evaluation results of the decorative material in which the glass transition temperature Tg of the acrylic resin composition is about 50 ° C.
  • FIG. 6 is a diagram showing the evaluation results of the decorative material in which the glass transition temperature Tg of the acrylic resin composition is about 70 ° C.
  • FIG. 7 is a diagram showing the evaluation results of the decorative material in which the glass transition temperature Tg of the acrylic resin composition is about 100 ° C.
  • Comparative Example 1 The cosmetic material in which the heat-weldable adhesive layer 40 was formed only with the acrylic resin composition had NG adhesion.
  • Comparative Example 2 In the heat-welding adhesive layer 40, the decorative materials in which the compounding ratio of the vinyl chloride-vinyl acetate copolymer to the acrylic resin was 20:80 to 80:20 (3 patterns) had good adhesion. It was OK, but the heat resistance was NG.
  • Comparative Example 5 A decorative material in which the heat-weld adhesive layer 40 was formed only with the composition of a vinyl chloride-vinyl acetate copolymer was OK in adhesion and heat resistance, but was NG in the evaluation of appearance design. It became.
  • Comparative Example 3 The decorative materials in which the compounding ratios of the vinyl chloride-vinyl acetate copolymer to the acrylic resin were 0: 100 and 20:80 (2 patterns) were all OK in adhesion, but heat resistance was high. It became NG.
  • Comparative Example 6 A decorative material in which the heat-weldable adhesive layer 40 was formed only with the composition of a vinyl chloride-vinyl acetate copolymer was OK in adhesion and heat resistance, but was NG in the evaluation of appearance design. It became.
  • Example 1 The decorative material in which the compounding ratio of the vinyl chloride-vinyl acetate copolymer to the acrylic resin was 50:50 was OK in all of the evaluations of adhesion, heat resistance and appearance design.
  • Example 2 The decorative material in which the compounding ratio of the vinyl chloride-vinyl acetate copolymer to the acrylic resin was 80:20 was OK in all of the evaluations of adhesion, heat resistance and appearance design.
  • Comparative Example 4 The adhesiveness of the decorative material in which the compounding ratio of the vinyl chloride-vinyl acetate copolymer to the acrylic resin was 0: 100 and 20:80 (2 patterns) was NG.
  • Comparative Example 7 A decorative material in which the heat-weld adhesive layer 40 was formed only with the composition of a vinyl chloride-vinyl acetate copolymer was OK in adhesion and heat resistance, but was NG in the evaluation of appearance design. It became.
  • Example 3 The decorative material in which the compounding ratio of the vinyl chloride-vinyl acetate copolymer to the acrylic resin was 50:50 was OK in all of the evaluations of adhesion, heat resistance and appearance design.
  • Example 4 A decorative material having a blending ratio of vinyl chloride-vinyl acetate copolymer acrylic resin of 80:20 was OK in all evaluations of adhesion, heat resistance and appearance design.
  • the transfer sheet according to the present invention can impart excellent adhesion, heat resistance and appearance design to the transferred object.
  • the decorative material provided with the transfer layer of the transfer sheet is a building wall material (exterior material, interior material), partition, door, window frame and other fittings, building materials, desk, dining table, cupboard, counter table, sink.
  • a building wall material exterior material
  • partition, door, window frame and other fittings building materials
  • desk, dining table, cupboard, counter table, sink In addition to furniture such as cupboards and upholstery, it can also be applied to indoor or outdoor (exterior) cover materials for vehicles such as automobiles, railroad vehicles, ships, and aircraft, various signs, and panel materials for outdoor advertisements. ..
  • Transfer sheet 2 Transfer layer 10 Releasable support 20 Release layer 30 Decorative layer 40 Heat-weld adhesive layer 50 Release base sheet 60 Transfer material 70 Top coat layer 100 Decorative material

Abstract

La présente invention concerne une feuille de transfert présentant une excellente adhérence à un corps à transférer, une excellente résistance à la chaleur et une excellente conception d'apparence.　La feuille de transfert (1), qui est transférée à un corps à transférer formé d'un matériau inorganique, comporte un corps de support libérable (10) et une couche de transfert (2) comprenant une couche adhésive stratifiée (40), la couche adhésive contenant un copolymère de chlorure de vinyle-acétate de vinyle et une résine acrylique, le rapport de composition entre le copolymère de chlorure de vinyle-acétate de vinyle par rapport à la résine acrylique est compris entre 50 et 100 % (à l'exclusion de 100 %) et la température de transition vitreuse de la résine acrylique est égale ou supérieure à 60 °C.
PCT/JP2020/013315 2019-03-29 2020-03-25 Feuille de transfert WO2020203546A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019066591A JP2020163706A (ja) 2019-03-29 2019-03-29 転写シート
JP2019-066591 2019-03-29

Publications (1)

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WO2020203546A1 true WO2020203546A1 (fr) 2020-10-08

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WO (1) WO2020203546A1 (fr)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06179283A (ja) * 1992-12-14 1994-06-28 Dainippon Printing Co Ltd 転写層の膜切れ性を改良した転写フイルム
JPH06198824A (ja) * 1992-12-28 1994-07-19 Dainippon Printing Co Ltd 塩化ビニル樹脂成形体からなる外装材用の転写シート
JPH07242074A (ja) * 1994-03-04 1995-09-19 Dainippon Printing Co Ltd 転写シート
JP2010143039A (ja) * 2008-12-18 2010-07-01 Dainippon Printing Co Ltd パッチ転写媒体
JP2010173203A (ja) * 2009-01-30 2010-08-12 Dainippon Printing Co Ltd パッチ転写媒体
JP2016198746A (ja) * 2015-04-14 2016-12-01 凸版印刷株式会社 化粧鋼板の製造方法および化粧鋼板
JP2017052124A (ja) * 2015-09-07 2017-03-16 大日本印刷株式会社 転写箔及び印画物の製造方法
JP2019048426A (ja) * 2017-09-11 2019-03-28 大日本印刷株式会社 転写シート及び化粧板の製造方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011104832A (ja) * 2009-11-16 2011-06-02 Toppan Cosmo Inc 化粧シート
JP6733465B2 (ja) * 2016-09-28 2020-07-29 大日本印刷株式会社 転写用ハードコートフィルム及びハードコート積層体

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06179283A (ja) * 1992-12-14 1994-06-28 Dainippon Printing Co Ltd 転写層の膜切れ性を改良した転写フイルム
JPH06198824A (ja) * 1992-12-28 1994-07-19 Dainippon Printing Co Ltd 塩化ビニル樹脂成形体からなる外装材用の転写シート
JPH07242074A (ja) * 1994-03-04 1995-09-19 Dainippon Printing Co Ltd 転写シート
JP2010143039A (ja) * 2008-12-18 2010-07-01 Dainippon Printing Co Ltd パッチ転写媒体
JP2010173203A (ja) * 2009-01-30 2010-08-12 Dainippon Printing Co Ltd パッチ転写媒体
JP2016198746A (ja) * 2015-04-14 2016-12-01 凸版印刷株式会社 化粧鋼板の製造方法および化粧鋼板
JP2017052124A (ja) * 2015-09-07 2017-03-16 大日本印刷株式会社 転写箔及び印画物の製造方法
JP2019048426A (ja) * 2017-09-11 2019-03-28 大日本印刷株式会社 転写シート及び化粧板の製造方法

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