WO2020199499A1 - 金手指及其制作方法、电路板及其制作方法 - Google Patents
金手指及其制作方法、电路板及其制作方法 Download PDFInfo
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- WO2020199499A1 WO2020199499A1 PCT/CN2019/104446 CN2019104446W WO2020199499A1 WO 2020199499 A1 WO2020199499 A1 WO 2020199499A1 CN 2019104446 W CN2019104446 W CN 2019104446W WO 2020199499 A1 WO2020199499 A1 WO 2020199499A1
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- WIPO (PCT)
- Prior art keywords
- layer
- nickel
- conductive layer
- palladium
- gold finger
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/11—Printed elements for providing electric connections to or between printed circuits
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/24—Reinforcing the conductive pattern
- H05K3/241—Reinforcing the conductive pattern characterised by the electroplating method; means therefor, e.g. baths or apparatus
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/28—Applying non-metallic protective coatings
- H05K3/282—Applying non-metallic protective coatings for inhibiting the corrosion of the circuit, e.g. for preserving the solderability
Definitions
- the invention relates to the technical field of corrosion resistance, in particular to a gold finger and a manufacturing method thereof, a circuit board and a manufacturing method thereof.
- the circuit board includes a substrate, a circuit and a gold finger.
- the circuit and the gold finger are both arranged on the substrate, and the circuit is electrically connected with the gold finger. After the customer purchases the circuit board from the manufacturer, the corresponding components can be welded on the circuit board to realize the corresponding function.
- the corrosion resistance of gold fingers is one of the indicators for customers to judge gold fingers and circuit boards including gold fingers. Customers usually use mixed gas corrosion tests to test the corrosion resistance of gold fingers. In traditional technology, it is difficult for gold fingers to pass the mixed gas corrosion test.
- a method for making gold fingers including:
- a sealing film is formed on the side of the palladium layer facing away from the nickel layer.
- a conductive layer is formed to electrically connect with the circuit.
- a nickel layer is formed on the conductive layer to prevent corrosion of the conductive layer.
- the nickel layer can also serve as a welding base for components.
- a palladium layer is formed on the side of the nickel layer facing away from the conductive layer to prevent corrosion of the nickel layer and improve the corrosion resistance of the gold finger.
- a sealing film is formed on the side of the palladium layer facing away from the nickel layer to further improve the corrosion resistance of the gold finger, so that the gold finger can pass the mixed gas corrosion test.
- the method further includes the step of performing microetching, brushing and/or sandblasting on the conductive layer.
- the conductive layer is a copper layer
- the nickel layer is formed by an autocatalytic redox reaction using hypophosphite as a reducing agent, and the reaction formula is as follows:
- the palladium layer is formed by the redox reaction of sodium hypophosphite and hydrochloric acid, and the reaction formula is as follows:
- a method for manufacturing a circuit board includes:
- a conductive pattern is formed on a substrate, the conductive pattern includes electrically connected lines and a conductive layer, the conductive pattern is divided into a soldering area and a non-welding area, wherein the conductive layer and part of the wiring are located in the soldering area, Another part of the circuit is located in the non-welded area;
- a sealing film is formed, the sealing film covers the conductive pattern after nickel-palladium plating, wherein the conductive layer covered with the sealing film forms a gold finger.
- a conductive pattern is formed on the substrate, and the conductive pattern includes electrically connected lines and conductive layers so as to satisfy the electrical connection relationship of the components to be soldered.
- the conductive pattern is divided into a welding area and a non-welding area. Among them, the conductive layer and part of the circuit are located in the welding area, and another part of the circuit is located in the non-welding area, forming a solder resist layer covering the conductive pattern of the non-welding area to protect the conductive non-welding area
- the conductive pattern is not oxidized, and the part of the conductive pattern located in the non-welded area is prevented from being connected to the portion located in the welding area to cause short circuit.
- Micro-etching, brushing and/or sandblasting of the conductive patterns in the welding area to ensure that the conductive patterns in the welding area are clean and pollution-free.
- Nickel-palladium is plated on the conductive pattern after microetching, brushing and/or sandblasting to improve the corrosion resistance of the conductive pattern located in the welding area.
- a sealing film covering the conductive pattern after plating nickel and palladium is formed to further improve the corrosion resistance of the conductive pattern in the welding area, so that the gold finger can pass the mixed gas corrosion test.
- a gold finger including:
- a nickel layer arranged on the conductive layer
- the palladium layer is disposed on the side of the nickel layer facing away from the conductive layer;
- the sealing film is arranged on the side of the palladium layer facing away from the nickel layer.
- the conductive layer is used for electrical connection with the circuit.
- the nickel layer provided on the conductive layer can prevent the conductive layer from corroding, and on the other hand, it can provide a welding base for the components to be welded.
- the palladium layer arranged on the side of the nickel layer facing away from the conductive layer can prevent the nickel layer from corroding and improve the corrosion resistance of the gold finger.
- the sealing film provided on the side of the palladium layer facing away from the nickel layer can further improve the corrosion resistance of the gold finger, so that the gold finger can pass the mixed gas corrosion test.
- the conductive layer is a copper layer, and the thickness of the nickel layer ranges from 3 ⁇ m to 8 ⁇ m.
- the thickness of the palladium layer ranges from 0.1 ⁇ m to 0.3 ⁇ m.
- the thickness of the sealing film ranges from 0.02 ⁇ m to 0.03 ⁇ m.
- a circuit board including:
- the gold finger as described above is arranged on the substrate;
- a circuit is arranged on the substrate, and the circuit is electrically connected with the golden finger.
- the circuit board includes the gold finger and has the technical effect of the gold finger, the gold finger can pass the mixed gas corrosion test.
- Fig. 1 is a schematic flow chart of a method for manufacturing a gold finger in an embodiment
- FIG. 2 is a schematic flowchart of a method for manufacturing a gold finger in another embodiment
- FIG. 3 is a schematic flowchart of a manufacturing method of a circuit board in an embodiment
- FIG. 4 is a schematic flowchart of a manufacturing method of a circuit board in another embodiment
- Figure 5 is a cross-sectional view of a gold finger in an embodiment.
- a method for manufacturing a gold finger in an embodiment is used to make a corrosion-resistant gold finger, so that the gold finger can pass the mixed gas corrosion test.
- the method for making gold fingers includes the following steps:
- Step S110 forming a conductive layer.
- the conductive layer is electrically connected to the circuit.
- the conductive layer is formed by etching, the conductive layer is a copper layer, and the process is mature, wherein the thickness of the copper layer can be flexibly set according to customer needs.
- the conductive layer can be formed by other methods, such as laser.
- the conductive layer can also be a layered structure of other materials, such as an aluminum layer.
- a nickel layer is formed on the conductive layer.
- the existence of the nickel layer can prevent corrosion of the conductive layer on the one hand, and on the other hand can play the role of providing a welding base for the components.
- the nickel layer can be formed by electroplating or electroless plating.
- the nickel layer is formed by an autocatalytic redox reaction using hypophosphite as a reducing agent, and the reaction formula is as follows:
- the method of using hypophosphite as a reducing agent to form an autocatalytic redox reaction has the characteristics of low cost. Understandably, the nickel layer in this embodiment is formed by electroless plating, and since hydrogen is generated during the reaction, pores will appear on the nickel layer. Of course, in other embodiments, electroplating or other electroless plating methods can also be used to form the nickel layer.
- the thickness of the nickel layer ranges from 3 ⁇ m to 8 ⁇ m. If the thickness of the nickel layer is less than 3 ⁇ m, the conductive layer will easily diffuse to the surface of the nickel layer facing away from the conductive layer. On the one hand, the corrosion resistance of the gold finger will decrease, and on the other hand, the gold finger will have poor soldering. If the thickness of the nickel layer is greater than 8 ⁇ m, the nickel layer is prone to nickel corrosion defects, resulting in poor welding of the gold fingers. In this embodiment, the thickness of the nickel layer is 5 ⁇ m. Of course, in other embodiments, the thickness of the nickel layer may be 4 ⁇ m, 6 ⁇ m, or the like.
- a palladium layer is formed on the side of the nickel layer opposite to the conductive layer.
- the presence of the palladium layer can prevent the nickel layer from corroding and improve the corrosion resistance of the gold finger.
- the palladium layer can be formed by electroplating or electroless plating.
- the palladium layer is formed by the redox reaction of sodium hypophosphite and hydrochloric acid, and the reaction formula is as follows:
- the method of using sodium hypophosphite and hydrochloric acid system to perform oxidation-reduction reaction to form a palladium layer has the characteristics of low cost, difficult to black plate and high welding reliability. It is understandable that the formation method of the palladium layer in this embodiment belongs to electroless plating. Since hydrogen is generated during the reaction, pores will appear on the palladium layer. Of course, in other embodiments, the palladium layer can also be formed by electroplating or other electroless plating methods.
- the thickness of the palladium layer ranges from 0.1 ⁇ m to 0.3 ⁇ m. If the thickness of the palladium layer is less than 0.1 ⁇ m, the diameter of the pores generated in the palladium layer will be too large, which exceeds the sealing ability of the sealing film, and the corrosion resistance of the gold finger is reduced. If the thickness of the palladium layer is greater than 0.3 ⁇ m, it is more difficult to form the palladium layer, resulting in increased cost. In this embodiment, the thickness of the nickel layer is 0.2 ⁇ m. Of course, in other embodiments, the thickness of the nickel layer may be 0.15 ⁇ m, 0.25 ⁇ m, or the like.
- Step S140 forming a sealing film on the side of the palladium layer facing away from the nickel layer.
- the presence of the sealing film can further improve the corrosion resistance of the gold finger, so that the gold finger can pass the mixed gas corrosion test.
- the sealing film can be formed with a sealing agent.
- the sealing agent is NF1208 sealing agent produced by Guangzhou Tianzhi Environmental Protection Technology Co., Ltd.
- the temperature range of the sealing solution prepared by the sealing agent can be 50-60°C, and the reaction time can be 3 minutes ⁇ 5min. For example, react at 55°C for 4 min.
- the sealing film can also be formed with other types of sealing agents.
- the traditional anti-oxidant layer is usually formed by using anti-oxidant solution, which is difficult to form a film.
- the sealing film in this embodiment has strong biological surface activity and can quickly penetrate into the pores of the plating layer to play a role.
- the sealing film can form a bidentate or multidentate chelate structure with the metal at the pores of the plating layer, passivate the plating layer by layer, and eliminate the hidden corrosion risk of the plating layer.
- the sealing film also has a certain degree of hydrophobicity to strengthen the protection of the sealing and cut off the channel of external corrosive gas.
- the thickness of the sealing film ranges from 0.02 ⁇ m to 0.03 ⁇ m. If the thickness of the sealing film is less than 0.02 ⁇ m, it will lead to poor sealing, such as missing sealing. If the thickness of the sealing film is less than 0.03 ⁇ m, it will result in poor welding. In this embodiment, the thickness of the sealing film is 0.025 ⁇ m. Of course, in other embodiments, the thickness of the sealing film may be 0.02 ⁇ m or 0.03 ⁇ m, etc. It should be noted that when the nickel layer and/or the palladium layer are formed by other methods that do not generate pores, the presence of the sealing film can still improve the corrosion resistance of the gold finger.
- the manufacturing method of gold fingers in another embodiment is used to manufacture corrosion-resistant gold fingers, which has the feature of lower cost.
- the manufacturing method of gold fingers in another embodiment and the manufacturing method of gold fingers in one embodiment mainly include the following differences:
- the method further includes step S111 of performing micro-etching, brushing and/or sandblasting on the conductive layer.
- the combination of microetching, brushing and/or sandblasting can effectively remove oxides and impurities on the surface of the conductive layer, roughen the conductive layer, and clean the conductive layer, so that the conductive layer is clean. No pollution.
- sulfuric acid and sodium persulfate can be used to roughen the conductive layer to enhance the bonding ability of the conductive layer and the nickel layer.
- a sandblasting machine can be used to spray blasting materials such as alumina onto the conductive layer, so that the conductive layer has a certain degree of cleanliness and roughness.
- spray blasting materials such as alumina
- the conductive layer has a certain degree of cleanliness and roughness.
- only micro-etching, brushing or sandblasting can be used to clean the board surface.
- the method further includes step S141 of detecting the sealing condition.
- the inspection of the sealing condition it can focus on detecting whether there is a phenomenon of missing sealing, so as to make high-quality golden fingers.
- the second inspection can be done with inspection tools such as a tenfold mirror.
- the sealing quality of the pores can also be tested during the testing of the sealing condition.
- the normal production time of a single cycle of the gold immersion tank is 25 minutes.
- the chemical sealing agent sealing time is 5 minutes, by contrast, the efficiency can be increased by 80%.
- a method of manufacturing a circuit board in an embodiment is used to manufacture a circuit board including gold fingers, and the gold fingers included in the circuit board can pass the mixed gas corrosion test.
- the manufacturing method of the circuit board includes the following steps:
- a conductive pattern is formed on the substrate.
- the conductive pattern includes electrically connected lines and a conductive layer.
- the conductive pattern is divided into a soldering area and a non-welding area.
- the conductive layer and some of the lines are located in the soldering area, and the other part of the wiring is located in the non-welding area. .
- the circuit and the conductive layer are electrically connected to meet the electrical connection relationship of the components to be welded.
- the conductive pattern can be formed by etching.
- the material of the circuit and the conductive layer is copper, which is relatively uniform and the process is mature. Of course, in other embodiments, the material of the circuit and/or the conductive layer can be changed.
- a pad is formed in step S210, the pad belongs to a conductive pattern, and both the circuit and the conductive layer include pads.
- step S220 a solder resist layer is formed, and the solder resist layer covers the conductive pattern in the non-welded area.
- the presence of the solder resist layer can protect the non-welded parts on the conductive pattern from oxidation, and prevent the conductive pattern in the non-welded area from being connected to the conductive pattern in the soldered area and cause a short circuit.
- the pad is located in the bonding area.
- step S230 the conductive pattern of the welding area is micro-etched, brushed and/or sandblasted.
- Micro-etching, brushing and/or sand blasting can be performed only on the conductive pattern in the soldering area, or on the entire surface of the substrate plate where the conductive pattern is formed.
- the three methods of micro-etching, brushing, and sandblasting are combined, and the entire surface of the substrate plate on which the conductive pattern is formed is performed, which is convenient for operation. Of course, in other embodiments, one or two of them can be selected.
- Step S240 plating nickel and palladium on the conductive pattern after microetching, brushing and/or sandblasting.
- the nickel-palladium plating is performed by electroless plating.
- the conductive pattern is first plated with nickel, and then the nickel-plated conductive pattern is plated with palladium.
- nickel-palladium plating is performed by electroplating.
- a sealing film is formed.
- the sealing film covers the conductive pattern plated with nickel and palladium, wherein the conductive layer covered with the sealing film forms a gold finger.
- the presence of the sealing film can further improve the corrosion resistance of the conductive pattern.
- a sealing film is formed on the conductive patterns located in the welding area. It should be noted that the sealing film can be formed in the welding area and the non-welding area, the sealing film in the welding area can disappear during the welding process, and the sealing film in the non-welding area can still be retained after welding.
- a method for manufacturing a circuit board in another embodiment is used for manufacturing a circuit board with good corrosion resistance.
- the manufacturing method of the circuit board in another embodiment and the manufacturing method of the circuit board in one embodiment mainly include the following differences:
- the method further includes step S221 to form characters on the solder resist layer.
- the presence of characters can play a role in marking, so that components can be placed on the circuit board later.
- the specific content of the required characters can be determined according to the needs of customers.
- step S241 is further included, forming: cutting the substrate into at least two sub-boards. Partially process the larger substrate first, and then cut the processed substrate into at least two sub-boards to improve production efficiency.
- an isolation layer can be arranged between the daughter board and the daughter board to prevent the daughter board from being scratched.
- the isolation layer may be a paper layer or the like.
- the method further includes step S242 to perform an electrical test on the conductive pattern.
- the electrical test can be used to determine whether there is a short circuit in the conductive pattern, so as to improve the pass rate of the circuit board. If the flying probe tester is used for electrical testing, it is necessary to ensure that the circuit board has no needle marks on the side of the pad to further improve the pass rate of the circuit board.
- step S242 and before step S250 it further includes step S253, the first quality inspection.
- the first quality inspection you can focus on the appearance inspection (such as the width and length of the circuit board, etc.) in order to produce high-quality circuit boards.
- the first quality inspection can be completed with inspection tools such as visual inspection machines.
- the first quality inspection can be performed between step S241 and step S242.
- step S253 can be omitted.
- step S250 it further includes step S251, a second quality inspection.
- the focus can be on whether there is any leakage of sealing holes in order to produce high-quality circuit boards.
- the second quality inspection can be completed with inspection tools such as a tenfold mirror.
- the sealing quality of the pores can also be inspected.
- the second quality inspection can be omitted.
- step S252 is further included to package the substrate after the sealing film is formed.
- the existence of step S272 can prevent the circuit board from being damaged and facilitate the handling of the circuit board.
- step S252 may be omitted.
- the circuit board in one embodiment has the characteristics of good corrosion resistance and low cost, and includes a substrate, gold fingers and circuits.
- the gold fingers and circuits are all arranged on the substrate, and the circuits are electrically connected to the gold fingers.
- the gold finger can be integrally formed with the circuit.
- Corresponding components can be welded on the circuit board to achieve corresponding functions.
- the golden finger 10 in an embodiment has the characteristics of good corrosion resistance.
- the gold finger 10 includes a conductive layer 100, a nickel layer 200, a palladium layer 300, and a sealing film 400. It should be noted that the gold finger 10 in this embodiment can be manufactured by the gold finger manufacturing method described in any of the foregoing embodiments.
- the nickel layer 200 is disposed on the conductive layer 100, the palladium layer 300 is disposed on the side of the nickel layer 200 facing away from the conductive layer 100, and the sealing film 400 is disposed on the side of the palladium layer 300 facing away from the nickel layer 200.
- the presence of the conductive layer 100 facilitates the electrical connection between the gold finger 10 and the circuit.
- the nickel layer 200 disposed on the conductive layer 100 can prevent corrosion of the conductive layer 100 on the one hand, and can provide a welding base for the components to be welded on the other hand.
- the palladium layer 300 disposed on the side of the nickel layer 200 facing away from the conductive layer 100 can prevent the nickel layer 200 from corroding and improve the corrosion resistance of the gold finger 10.
- the sealing film 400 disposed on the side of the palladium layer 300 facing away from the nickel layer 200 can further improve the corrosion resistance of the gold finger 10 so that the gold finger 10 can pass the mixed gas corrosion test.
- the conductive layer 100 is a copper layer.
- the conductive layer 100 is another layered structure capable of conducting electricity.
- the thickness of the nickel layer 200 ranges from 3 ⁇ m to 8 ⁇ m. If the thickness of the nickel layer 200 is less than 3 ⁇ m, the conductive layer 100 will easily diffuse to the surface of the nickel layer 200 facing away from the conductive layer 100. On the one hand, the corrosion resistance of the gold finger 10 will decrease, and on the other hand, the gold finger 10 will be reduced. Poor welding appears. If the thickness of the nickel layer 200 is greater than 8 ⁇ m, the nickel layer 200 is prone to nickel corrosion defects, resulting in poor soldering of the gold finger 10. In this embodiment, the thickness of the nickel layer 200 is 5 ⁇ m. Of course, in other embodiments, the thickness of the nickel layer 200 may be 4 ⁇ m, 6 ⁇ m, or the like.
- the thickness of the palladium layer 300 ranges from 0.1 ⁇ m to 0.3 ⁇ m. If the thickness of the palladium layer 300 is less than 0.1 ⁇ m, the diameter of the pores generated on the palladium layer 300 will be too large, exceeding the sealing capacity of the sealing film 400, and the corrosion resistance of the gold finger 10 will be reduced. If the thickness of the palladium layer 300 is greater than 0.3 ⁇ m, it is more difficult, resulting in increased cost. In this embodiment, the thickness of the nickel layer 200 is 0.2 ⁇ m. Of course, in other embodiments, the thickness of the nickel layer 200 may be 0.15 ⁇ m, 0.25 ⁇ m, or the like.
- the thickness of the sealing film 400 ranges from 0.02 ⁇ m to 0.03 ⁇ m. If the thickness of the sealing film 400 is less than 0.02 ⁇ m, it will lead to a phenomenon of poor sealing, such as missing sealing. If the thickness of the sealing film 400 is less than 0.03 ⁇ m, it will result in poor welding. In this embodiment, the thickness of the sealing film 400 is 0.025 ⁇ m. Of course, in other embodiments, the thickness of the sealing film 400 may be 0.02 ⁇ m, 0.03 ⁇ m, or the like. It should be noted that when the nickel layer 200 and/or the palladium layer 300 are formed by other methods that do not generate pores, the presence of the sealing film 400 can still improve the corrosion resistance of the gold finger 10.
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Abstract
Description
Claims (10)
- 一种金手指的制作方法,其特征在于,包括:形成导电层;在所述导电层上形成镍层;在所述镍层背向于所述导电层的一侧形成钯层;及在所述钯层背向于所述镍层的一侧形成封孔膜。
- 根据权利要求1所述的金手指的制作方法,其特征在于,步骤形成导电层之后,步骤在所述导电层上形成镍层之前,还包括步骤:对所述导电层进行微蚀、磨刷和/或喷砂。
- 一种电路板的制作方法,其特征在于,包括:在基板上形成导电图案,所述导电图案包括电连接的线路及导电层,所述导电图案划分有焊接区及非焊接区,其中,所述导电层及部分所述线路位于所 述焊接区,另一部分所述线路位于所述非焊接区;形成阻焊层,所述阻焊层覆盖所述非焊接区的导电图案;对所述焊接区的所述导电图案进行微蚀、磨刷和/或喷砂;对微蚀、磨刷和/或喷砂后的所述导电图案镀镍钯;及形成封孔膜,所述封孔膜覆盖镀镍钯后的所述导电图案,其中,覆盖有所述封孔膜的所述导电层形成金手指。
- 一种金手指,其特征在于,包括:导电层;镍层,设置于所述导电层上;钯层,设置于所述镍层背向于所述导电层的一侧;及封孔膜,设置于所述钯层背向于所述镍层的一侧。
- 根据权利要求6所述的金手指,其特征在于,所述导电层为铜层,所述镍层的厚度范围为3μm~8μm。
- 根据权利要求7所述的金手指,其特征在于,所述钯层的厚度范围为0.1μm~0.3μm。
- 根据权利要求8所述的金手指,其特征在于,所述封孔膜的厚度范围为0.02μm~0.03μm。
- 一种电路板,其特征在于,包括:基板;如权利要求6至9任一项所述的金手指,设置于所述基板上;及线路,设置于所述基板上,所述线路与所述金手指电连接。
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- 2019-04-04 CN CN201910272290.8A patent/CN110062523A/zh active Pending
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