WO2020123914A1 - Encres effaçables à sec et procédés et instruments d'écriture associés - Google Patents
Encres effaçables à sec et procédés et instruments d'écriture associés Download PDFInfo
- Publication number
- WO2020123914A1 WO2020123914A1 PCT/US2019/066179 US2019066179W WO2020123914A1 WO 2020123914 A1 WO2020123914 A1 WO 2020123914A1 US 2019066179 W US2019066179 W US 2019066179W WO 2020123914 A1 WO2020123914 A1 WO 2020123914A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ink formulation
- acrylate
- ink
- dry erase
- capsules
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K1/00—Nibs; Writing-points
- B43K1/01—Nibs; Writing-points with ink reservoirs, e.g. funnel-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K8/00—Pens with writing-points other than nibs or balls
- B43K8/02—Pens with writing-points other than nibs or balls with writing-points comprising fibres, felt, or similar porous or capillary material
- B43K8/03—Ink reservoirs; Ink cartridges
Definitions
- This disclosure generally relates to ink formulations, and associated methods and writing instruments, and more specifically relates to dry erase inks, and methods and writing instruments for using the same.
- Dry erase ink formulations are known, and can be made in a wide variety of colors.
- different color pigments have different chemical and physical properties, and thus different dry erase ink formulations are required for different colorants.
- These different formulations often result in different colors of dry erase inks having different properties. For example, some colors erase better than others, dry more quickly than others, have better cap-off time, etc. These varying properties often frustrate users.
- an ink formulation including a colorant encapsulated in a plurality of capsules, wherein the plurality of capsules include a release agent.
- the release agent may be covalently bonded to the plurality of capsules.
- a method of erasing ink including erasing an ink formulation from a whiteboard or other dry erase surface, wherein the ink formulation includes a colorant encapsulated in a plurality of capsules, wherein the plurality of capsules include a release agent.
- writing instruments including a writing tip portion connected to a tubular member or refdl, and an ink formulation including a colorant encapsulated in a plurality of capsules, wherein the plurality of capsules include a release agent.
- FIG. 1 illustrates a writing instrument according to an embodiment of the present disclosure.
- Dry erase ink formulations methods of using (e.g., erasing) dry erase ink formulations, and writing instruments including dry erase ink formulations are provided herein.
- colorant is used broadly to refer to a substance which imparts a desired color to an ink formulation.
- a colorant may be a dye or pigment.
- dry erase when used to modify an ink formulation or portion thereof is used broadly to indicate that the ink formulation or portion thereof is configured to be applied to a whiteboard or dry erase board, and then later erased by rubbing or wiping without the need to apply any solvent.
- the term“erased” is used broadly to indicate that at least a portion of the colored components of an ink formulation has been removed from a substrate, or have been rendered colorless or transparent.
- the phrase“substantially erased” is used broadly to indicate that substantially all of the colored components of an ink formulation have been removed from a substrate, or have been rendered colorless or transparent.
- encapsulated is used broadly to refer to a substance or core which is surrounded by a shell.
- encapsulated materials include, but are not limited to, materials which are completely surrounded by an acrylic shell, such that the materials are isolated from any surrounding environment by the acrylic shell.
- nanocapsules is used broadly to refer to capsules having a maximum diameter of less than 1000 nanometers.
- microcapsules is used broadly to refer to capsules having a maximum diameter of from 1000 nanometers to about 1000 micrometers.
- Dry erase ink formulations are disclosed herein.
- the ink formulation may contain one or more colorants encapsulated in a plurality of capsules.
- the ink formulations disclosed herein have a longer dry time than conventional dry erase markers. That is, when disposed on a surface, the ink formulations disclosed herein take longer to dry than comparative ink formulations wherein the colorant is not encapsulated in a plurality of capsules as described herein.
- the ink formulations have described herein have a dry time of from about 30 seconds to about 120 seconds, for example about 30 seconds, about 40 seconds, about 50 seconds, about 60 seconds, about 70 seconds, about 80 seconds, about 90 seconds, about 100 seconds, about 110 seconds, about 120 seconds, and any ranges therebetween.
- the ink formulations disclosed herein have a longer cap off time when disposed in a marker type writing instrument than conventional dry erase markers. That is, when disposed in a dry erase marker and the marker tip is left uncapped, the ink formulations disclosed herein will have a longer cap off time than dry erase markers containing comparative ink formulations wherein the colorant is not encapsulated in a plurality of capsules as described herein.
- the ink formulations when disposed in a writing instrument having a marker tip have an off cap time of more than 15 minutes, for example about 15 minutes, about 16 minutes, about 17 minutes, about 18 minutes, about 19 minutes, about 20 minutes, about 21 minutes, about 22 minutes, about 23 minutes, about 24 minutes, about 25 minutes, about 26 minutes, about 27 minutes, about 28 minutes, about 29 minutes, about 30 minutes, or any ranges therebetween.
- the colorants may include a solvent dye dissolved in an organic solvent.
- the colorants may include Solvent 70 dissolved in Magiesol Oil 52, leucodyes dissolved in a fluid with an activator and a solid state wax, for example Crystal Violet dissolved in a phenolic resin and bees wax.
- the colorants may include hydrophobically-treated colored pigments, such as hydrophobic carbon black, available from Degussa.
- the ink formulation contains the colorant in an amount of from about 3 wt.
- the plurality of capsules are acrylic capsules, melamine formaldehyde capsules, urea formaldehyde, ethyl cellulose, polyvinyl alcohol, gelatin, sodium alginate, or any combination thereof.
- the capsules are nanocapsules or microcapsules.
- the encapsulated colorant is formed by the methods disclosed in U.S. Patent No. 9,937,477, entitled“Encapsulation,” the disclosure of which is hereby incorporated by reference herein in its entirety. In some embodiments, the encapsulated colorant is formed by the methods disclosed in U.S. Patent Publication No. 2017/0165627, entitled“Microencapsulation process,” the disclosure of which is hereby incorporated by reference herein in its entirety. In some embodiments, to facilitate the formation of an insoluble wall, complementary catalytic curing agents such as tertiary amines, mercaptans, isocyanates, and phenols are used.
- complementary catalytic curing agents such as tertiary amines, mercaptans, isocyanates, and phenols are used.
- the encapsulation process involves cation chain polymerization, and complementary catalytic curing agents such as boron trifluoride complexes, complex aromatic salts of Lewis acids such as diaryl iodonium, triarylsulfonium, or arene diazonium are used.
- complementary catalytic curing agents such as boron trifluoride complexes, complex aromatic salts of Lewis acids such as diaryl iodonium, triarylsulfonium, or arene diazonium are used.
- these functional groups may be further reacted with alkoxysilanes with long chain carbons to attach the long alkyl functionalities covalently onto the surface of the capsules.
- the plurality of capsules include one or more release agents.
- the plurality of capsules include one or more release agents covalently bonded to a standard encapsulation material.
- the release agent may include an epoxy, a polyester, a polyether, a urethane, a 2-(2-ethoxy) group, a 2-phenoxy group, a tetrahydrofurfuryl group, an ortho-phenoxy group, pentaerythriol, cyclic trimethylolpropane, an isobornyl group, a benzyl group, a 3,3,5-trimethylcyclohexyl group, or any combinations thereof covalently bonded to an encapsulation material.
- the plurality of capsules include epoxy acrylate, polyester acrylate, polyether acrylate, urethane acrylate, 2-(2-ethoxyethoxy) ethylacrylate, 2-phenoxy ethyl acrylate, tetrahydrofurfuryl methacylate, ortho-phenoxy ethyl acrylate, pentaerythriol acrylate, cyclic trimethylolpropane formal acrylate, isobornyl acrylate, benzyl acrylate, 3,3,5-trimethylcyclohexyl acrylate, or any combinations thereof.
- the release agent is selected from: epoxy acrylate, polyester acrylate, polyether acrylate, and urethane acrylate release agents.
- a suitable release agent may be selected based on the hardness, elasticity, toughness, abrasion resistance, adhesion, viscosity range, chemical resistance, and reactivity of the release agent for the specific application.
- the release agents identified above may be further modified to be compatible with the encapsulation process.
- the release agent may include epoxy acrylate, polyester acrylate, polyether acrylate, or urethane acrylate modified with terminal epoxide functionalities.
- the ink formulation includes a resin.
- the resin may include a variety of synthetic resin emulsions, such as aqueous dispersions of polyacrylic acid esters, styrene-acrylate copolymers, polyvinyl acetate, ethylene- vinyl acetate copolymers, ethylene methacrylic acid copolymers, a-olefm-maleic acid copolymers, silicone resins, polyester and polyurethane, water-soluble resins such as polyvinyl alcohols, polyvinyl pyrrolidone and polyvinyl butyral, alkali-soluble resins such as styrene- maleic acid copolymers, ethylene-maleic acid copolymers and styrene-acrylate copolymers, oil- soluble resins such as ketone resins, ketone-formaldehyde resins, amide resins, alkyd resins, rosin-modified
- the resin is an acrylic resin.
- the acrylic resin is a water-based acrylic resin, for example Joncryl® 67, Joncryl® 678, Joncryl® 682, Joncryl® 683, or combinations thereof, which are all available from BASF®.
- the ink formulation includes the resin in an amount of from about 0 wt. % to about 50 wt.%, for example about 0 wt.%, about 10 wt.%, about 20wt.%, about 30 wt.%, about 40 wt.%, or about 50 wt.%.
- the ink formulation includes a solvent.
- the solvent is water.
- the solvent is one or more alcohols, for example, benzyl alcohol, ethanol, n-propanol, n-butanol, diacetone alcohol, or combinations thereof.
- the solvent is a water-soluble organic solvent, for example, ethanol, propanol, butanol, glycerin, sorbitol, triethanolamine, diethanolamine,
- monoethanolamine ethylene glycol, diethylene glycol, thiodi ethylene glycol, polyethylene glycol, propylene glycol, butylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ethers propylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, sulfolane, 2-pyrrolidone, N-methyl- 2-pyrrolidone and the like.
- the solvent is an organic solvent, for example, naphtha, VM&P naphtha, refined solvent naphtha, petroleum sprit, xylene, methylisobutyl ketone, or butyl propionate.
- organic solvent for example, naphtha, VM&P naphtha, refined solvent naphtha, petroleum sprit, xylene, methylisobutyl ketone, or butyl propionate.
- the ink formulation contains the solvent in an amount of from about 0 wt.% to about 80 wt.%, for example about 0 wt.%, about 10 wt.% solvent, about 20 wt.%, about 30 wt.%, about 40 wt.%, about 50 wt.%, about 60 wt.%, about 70 wt.%, about 80 wt.%, or any ranges therebetween.
- the ink formulation includes shear-thinning imparting agents, for example, nonionic surfactants having a specific HLB value, xanthan gum, welan gum, succinoglycan (organic acid-modified heteroglycan composed of glucose unit and galactose unit, having an average molecular weight of about 100 to 8,000,000), guar gum, locust bean gum, hydroxyethyl cellulose, alkyl alginates, polymers mainly composed of alkyl methacrylate and having a molecular weight of 100,000 to 150,000, glycomannan, hydrocarbons having a gelling ability and extracted from seaweed such as agar or carrageenan, benzylidenesorbitol or derivatives thereof, crosslinking acrylic acid polymers and the like, hydrophobically-modified ethoxylated urethane (HEUR) thickeners, alkalai-swellable emulsion (ASE) thickeners, hydrophobically-modified alkali
- HEUR hydrophobically
- the ink formulation only includes shear-thinning imparting agents in an amount suitable to perform as a wetting agent.
- the ink formulation includes other additives such as pigments, binders, viscosity modifiers, thixotropic agents, preservatives, lubricants, pH adjustors, antiseptics or fungicides, wetting agents, defoamers, dispersants, surfactants, humectants, biocides, and the like.
- the ink formulation may be configured to be delivered from a marker type writing instrument, such as an Expo® marker.
- any of the ink formulations described above is disposed on a whiteboard or dry erase surface (e.g., via contacting a writing instrument containing the ink formulation to the surface such that the ink is delivered from the instrument to the surface), and then the ink is removed by the surface by rubbing or wiping with an erasing instrument.
- the erasing instrument comprises dry cloth or felt.
- the ink formulations may be considered erased when each formulation would be considered erased by an average consumer.
- determining whether an ink formulation has been erased may involve a qualitative determination.
- the erasure of the ink formulations described herein may be evaluated using the Likert scale, wherein write test samples may be evaluated before and after attempted erasing on a 5-point scale. According to the Likert scale, 5 represents no color change, 4 represents slight discoloration, 3 represents moderate discoloration, 2 represents severe discoloration, and 1 represents complete color elimination. In some embodiments, the ink formulations may be considered erased when they are rated with a moderate discoloration, severe discoloration, or complete color elimination according to the Likert scale.
- the color of a surface with an ink formulation disposed thereon before and after erasure may be quantitatively evaluated with a color measurement instrument.
- the color measurement instrument may be a
- the color measurement instrument may be a spectrodensitometer.
- color differences may be identified using the Commission Internationale de TEclairage (CIE) L*a*b* coordinates, wherein L* indicates lightness, a* is the red/green coordinate, and b* is the yellow/blue coordinate.
- CIE Commission Internationale de TEclairage
- the color change of the ink formulation from its state before erasure (L*i, a* i, and b*i) and after erasure L*2, a* 2, and b*2 can be indicated by calculating AL*, Aa*, and Ab*, according to the formulas below:
- a positive AL* will indicate that the sample became lighter after erasure while a negative AL* will indicate that the sample became darker after erasure.
- a positive AL* when measuring the effect erasure on a colored dry erase ink on a white substrate may indicate that the dry erase ink was lightened by erasure.
- a positive Aa* will indicate that the sample became redder erasure, while a negative Aa* will indicate that the sample became greener after erasure.
- a positive Aa* when measuring the effect of erasure on a green dry erase ink on a white substrate may indicate that the green color of the dry erase ink was at least partially removed by erasure.
- a positive Ab* will indicate that the sample became yellower after erasure, while a negative Ab* will indicate that the sample became bluer after erasure.
- a positive Aa* when measuring the effect of erasure on a blue colored dry erase ink on a white substrate may indicate that the blue color of the dry erase ink was at least partially removed by erasure.
- measuring Aa* and Ab* may be particularly useful in evaluating the erasability of dry erase inks which are initially red or blue in color.
- the total color difference between all three coordinates L*, a*, and b* can be evaluated by calculating the total color difference, DE*, according to the formula below:
- the ink formulations may be considered erased when write test samples of the ink on a white substrate exhibit a DE* value of from about 40 to about 100, a AL* value of from about 1 to about 100, a Aa* value of from about +/-0.1 to about +/-90, a Ab* value of from about +/-0.1 to about +/-90, or any combination thereof, including any ranges therebetween.
- the ink formulations may be considered erased when write test samples of the ink on a white substrate exhibit a DE* value of from about 40 to about 50, from about 50 to about 80, about 50, about 60, about 70, about 80, about 90, about 95, about 100, or any ranges therebetween.
- the ink formulations may be considered erased when the write test samples of the ink on a white substrate exhibit a AL* value of from about 5 to about 40, from about 40 to about 60, from about 50 to about 95, about 1, about 10, about 20, about 30, about 40, about 50, about 60, about 70, about 80, about 90, about 95, about 100, or any ranges therebetween.
- the ink formulations may be considered erased when the write test samples of the ink on a white substrate exhibit a Aa* value of from about -60 to about 60, from about -60 to about -0.1, from about 0.1 to about 60, from about -25 to about -5, from about 5 to about 25, from about -60 to about -30, from about 30 to about 60, for example about -90, about -80, about -70, about -60, about -50, about -40, about -30, about -20, about -10, about 0, about 10, about 20, about 30, about 40, about 50, about 60, about 70, about 80, about 90, or any ranges therebetween.
- the ink formulations may be considered erased when the write test samples of the ink on a white substrate exhibit a Ab* value of from about-90 to about -50, about 50 to about 90, about -40 to about -20, about 20 to about 40, about -20 to about -0.1, about 0.1 to about 20, about -90, about - 80, about -70, about -60, about -50, about -40, about -30, about -20, about -10, about -0.1, about 0.1, about 10, about 20, about 30, about 40, about 50, about 60, about 70, about 80, about 90, or any ranges therebetween.
- the color of an ink formulation before and after erasure may be evaluated using the CIE L*C*h coordinates, where L* indicates lightness, C* indicates chroma, and h is the hue angle.
- the color change of the ink formulation from its state before erasure (L*i, C* i, and hi) and after erasure L*2, C* 2, and I12 can be indicated by calculating AL*, AC*, and Ah, according to the formulas below:
- the ink formulations may be considered erased when the ink disposed on a substrate before and after erasure exhibits a AL* value of from about 1 to about 100, AC* value of from about 0.1 to about 90, a Ah value of from about 1° to about 360°, or any combination thereof, including any ranges therebetween.
- the ink formulations may be considered erased when the write test samples of the ink on a white substrate exhibit a AL* value of from about 5 to about 40, from about 40 to about 60, from about 50 to about 95, about 1, about 10, about 20, about 30, about 40, about 50, about 60, about 70, about 80, about 90, about 95, about 100, or any ranges therebetween.
- the ink formulations may be considered erased when the write test samples of the ink on a white substrate exhibit a AC* value of 0.1 to about 20, about 25 to about 70, about 75 to about 90, about 0.1, about 10, about 20, about 30, about 40, about 50, about 60, about 70, about 80, about 90, or any ranges therebetween.
- the ink formulations may be considered erased when the write test samples of the ink on a white substrate exhibit a Ah value of about 1°, about 30°, about 60°, about 90°, about 120°, about 150°, about 180°, about 210°, about 240°, about 270°, about 300°, about 330°, about 360°, or any ranges therebetween.
- writing instalments are provided.
- the writing instruments include a writing tip portion connected to a tubular member or refill, and any of the ink formulations described above.
- the writing tip portion is a marker.
- FIG. 1 shows a partial cutaway view of an embodiment of a writing instrument 110 according to the present disclosure.
- the writing instrument 110 includes a tubular body 111, which surrounds a reservoir 112, which may house any of the ink formulations described above.
- the writing instrument further includes a writing tip 116, which extends into the reservoir 112 by a distance 122.
- the tubular body 111 further includes a second end 120, which is configured to receive a cap (not shown).
Abstract
La présente invention concerne des formulations d'encre effaçable à sec contenant au moins un colorant encapsulé dans une pluralité de capsules, les capsules comprenant un agent de libération ; des procédés d'effacement de formulations d'encre effaçable à sec ; et des instruments d'écriture comprenant une partie pointe d'écriture reliée à un élément tubulaire ou à une recharge et une formulation d'encre effaçable à sec.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA3123081A CA3123081A1 (fr) | 2018-12-14 | 2019-12-13 | Encres effacables a sec et procedes et instruments d'ecriture associes |
CN201980081757.9A CN113195653A (zh) | 2018-12-14 | 2019-12-13 | 干擦除油墨以及相关方法和书写工具 |
US17/413,159 US20220064464A1 (en) | 2018-12-14 | 2019-12-13 | Dry Erase Inks, and Associated Methods and Writing Instruments |
EP19897061.8A EP3894489A4 (fr) | 2018-12-14 | 2019-12-13 | Encres effaçables à sec et procédés et instruments d'écriture associés |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201862779541P | 2018-12-14 | 2018-12-14 | |
US62/779,541 | 2018-12-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2020123914A1 true WO2020123914A1 (fr) | 2020-06-18 |
Family
ID=71077029
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2019/066179 WO2020123914A1 (fr) | 2018-12-14 | 2019-12-13 | Encres effaçables à sec et procédés et instruments d'écriture associés |
Country Status (5)
Country | Link |
---|---|
US (1) | US20220064464A1 (fr) |
EP (1) | EP3894489A4 (fr) |
CN (1) | CN113195653A (fr) |
CA (1) | CA3123081A1 (fr) |
WO (1) | WO2020123914A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021067267A1 (fr) * | 2019-10-01 | 2021-04-08 | Sanford L.P. | Encres effaçables à sec et instruments d'écriture associés |
Citations (5)
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US3949132A (en) * | 1972-05-25 | 1976-04-06 | The Gillette Company | Marking boards and erasable ink compositions therefor |
US5304587A (en) * | 1991-12-19 | 1994-04-19 | Moore Business Forms, Inc. | Water resistant security ink composition |
US5655847A (en) * | 1993-12-06 | 1997-08-12 | Mitsubishi Pencil Kabushiki Kaisha | Ball-point pen |
US20100063186A1 (en) * | 2008-09-11 | 2010-03-11 | Sanford, L.P. | Washable ink compositions and writing instruments comprising same |
US7981210B2 (en) * | 2003-09-19 | 2011-07-19 | Sanford, L.P. | Capillary-action, glitter markers and ink compositions for same |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CA2229747C (fr) * | 1997-02-19 | 2006-07-18 | The Pilot Ink Co., Ltd. | Composition d'encre aqueuse de crayon marqueur pour tableau a ecrire |
KR100375741B1 (ko) * | 2000-04-26 | 2003-03-15 | 동아연필 주식회사 | 고형상 마이크로캡슐 잉크 |
JP2005132884A (ja) * | 2003-10-28 | 2005-05-26 | Pilot Ink Co Ltd | インキ用着色樹脂粒状体及びそれを用いた筆記具用インキ組成物 |
JP2006022213A (ja) * | 2004-07-08 | 2006-01-26 | Pilot Ink Co Ltd | 筆記板用消去性インキ組成物及びそれを内蔵した筆記具 |
JP5511259B2 (ja) * | 2009-08-18 | 2014-06-04 | パイロットインキ株式会社 | 可逆熱変色性水性インキ組成物及びそれを用いた筆記具、筆記具セット |
WO2013065653A1 (fr) * | 2011-10-31 | 2013-05-10 | ぺんてる株式会社 | Composition d'encre |
JP6171361B2 (ja) * | 2012-03-15 | 2017-08-02 | 株式会社リコー | トナー、現像剤、プロセスカートリッジ及び画像形成装置 |
JP6117051B2 (ja) * | 2013-08-12 | 2017-04-19 | 株式会社パイロットコーポレーション | 熱消色性筆記具インキ組成物及びそれを内蔵した筆記具 |
JP6231351B2 (ja) * | 2013-09-03 | 2017-11-15 | 三菱鉛筆株式会社 | マイクロカプセル色材及び筆記具用インク組成物 |
-
2019
- 2019-12-13 EP EP19897061.8A patent/EP3894489A4/fr active Pending
- 2019-12-13 US US17/413,159 patent/US20220064464A1/en active Pending
- 2019-12-13 WO PCT/US2019/066179 patent/WO2020123914A1/fr unknown
- 2019-12-13 CA CA3123081A patent/CA3123081A1/fr active Pending
- 2019-12-13 CN CN201980081757.9A patent/CN113195653A/zh active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US3949132A (en) * | 1972-05-25 | 1976-04-06 | The Gillette Company | Marking boards and erasable ink compositions therefor |
US5304587A (en) * | 1991-12-19 | 1994-04-19 | Moore Business Forms, Inc. | Water resistant security ink composition |
US5655847A (en) * | 1993-12-06 | 1997-08-12 | Mitsubishi Pencil Kabushiki Kaisha | Ball-point pen |
US7981210B2 (en) * | 2003-09-19 | 2011-07-19 | Sanford, L.P. | Capillary-action, glitter markers and ink compositions for same |
US20100063186A1 (en) * | 2008-09-11 | 2010-03-11 | Sanford, L.P. | Washable ink compositions and writing instruments comprising same |
Non-Patent Citations (1)
Title |
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See also references of EP3894489A4 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021067267A1 (fr) * | 2019-10-01 | 2021-04-08 | Sanford L.P. | Encres effaçables à sec et instruments d'écriture associés |
US11753558B2 (en) | 2019-10-01 | 2023-09-12 | Sanford, L.P. | Dry erase inks and associated writing instruments |
Also Published As
Publication number | Publication date |
---|---|
CN113195653A (zh) | 2021-07-30 |
EP3894489A1 (fr) | 2021-10-20 |
US20220064464A1 (en) | 2022-03-03 |
EP3894489A4 (fr) | 2022-08-24 |
CA3123081A1 (fr) | 2020-06-18 |
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