WO2019181670A1 - 水素ガス発生装置 - Google Patents

水素ガス発生装置 Download PDF

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Publication number
WO2019181670A1
WO2019181670A1 PCT/JP2019/010144 JP2019010144W WO2019181670A1 WO 2019181670 A1 WO2019181670 A1 WO 2019181670A1 JP 2019010144 W JP2019010144 W JP 2019010144W WO 2019181670 A1 WO2019181670 A1 WO 2019181670A1
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WO
WIPO (PCT)
Prior art keywords
cylindrical case
hydrogen gas
hydrogen
space
water
Prior art date
Application number
PCT/JP2019/010144
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English (en)
French (fr)
Japanese (ja)
Inventor
和久 福岡
Original Assignee
エコモ・インターナショナル株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by エコモ・インターナショナル株式会社 filed Critical エコモ・インターナショナル株式会社
Publication of WO2019181670A1 publication Critical patent/WO2019181670A1/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/38—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the present invention relates to a hydrogen gas generator that can be charged into a drinking water container such as a plastic bottle to generate hydrogen gas in the container and convert the drinking water into hydrogen water.
  • Hydrogen water generation technology is already known, and hydrogen gas can be generated by reacting water with a mixed powder of a metal such as Al or Mg and a hydrogen generating agent such as Ca oxide or Ca hydroxide. Hydrogen water is produced
  • the hydrogen generating agent is stored in a non-woven sachet, the sachet is contained in a case of a certain shape, and the beverage is placed in a drinking water container such as a plastic bottle when drinking.
  • a drinking water container such as a plastic bottle when drinking.
  • the hydrogen generating agent bag is dipped in water in advance before being stored in the case, and the bag is moistened. And Thereafter, a bag of wet hydrogen generating agent is accommodated in the case. With the hydrogen gas generating reaction in the case, the case is put in a plastic bottle together with a bag of hydrogen generating agent.
  • the hydrogen generator in which the hydrogen generation bag is put in the case it is necessary to provide a check valve function that discharges hydrogen gas to the case but does not discharge drinking water so that the drinking water does not enter the case.
  • the material of the bag containing the hydrogen generating agent is devised. That is, as a material of the bag, water for reacting with the metal is easily penetrated, and a bag capable of releasing hydrogen gas generated in the bag is used, but metal ions are not emitted from the bag. Thus, it is necessary to provide a check function for blocking metal ions in the bag.
  • This metal ion block is an essential requirement for maintaining health.
  • the hydrogen generating agent and water can be directly contacted in the case to improve the hydrogen generation efficiency.
  • the structure of the device becomes complicated and difficult to use.
  • a bag of a hydrogen generating agent is accommodated in a case, and the case is placed in a plastic bottle so that hydrogen gas can be generated quickly, and the metal ion is not dissolved in the drinking water.
  • a hydrogen gas generator with a valve stop function.
  • a hydrogen gas generation space for containing a hydrogen generating agent is provided in a sealed cylindrical case to be put in a PET bottle, and water is passed through the end of the hydrogen gas generation space through which gas passes.
  • a narrow pipe for gas discharge having a check valve function that does not pass is provided, and the end of the thin pipe is used as a small hole for gas discharge, and the outer periphery of the thin pipe protruding inside the cylindrical case head and the inner periphery of the cylindrical case It is intended to provide a hydrogen gas generator characterized by a buoyant space in between.
  • the head of the cylindrical case is a cap body that is solidified to the cylindrical case body, and a buoyancy space is provided in the cap body.
  • the cylindrical case is formed of a flexible film material that can retain its form.
  • a jacket structure for heat insulation is provided between the hydrogen gas generation space and the outer wall of the cylindrical case.
  • the cylindrical case is characterized by having a bellows structure in the wall portion that causes a negative pressure inside and generates an external water suction force.
  • a hydrogen gas generation space for containing a hydrogen generating agent is provided in a sealed cylindrical case to be placed in a PET bottle, and gas is passed through the end of the hydrogen gas generation space.
  • a thin pipe for gas discharge having a check valve function that does not allow water to pass through is provided, and the end of the thin pipe is used as a small hole for gas discharge, and the outer periphery of the thin pipe protruding into the inside of the cylindrical case head and the cylindrical case
  • a buoyancy space is formed between the inner circumferences, and the cylindrical case of the hydrogen gas generator is used by being put into a plastic bottle.
  • hydrogen gas generated by the hydrogen generating agent is stored in the hydrogen gas generation space.
  • the gas passes through the narrow pipe, is released into the PET bottle from the gas discharge hole, and is dissolved in the drinking water in the PET bottle to generate hydrogen water.
  • the drinking water in the PET bottle does not enter the cylindrical case due to the check valve function by the thin pipe, and the water that has reacted to the hydrogen generating agent does not go out of the cylindrical case.
  • the cylindrical case of the hydrogen gas generator is put into the PET bottle, it floats on the drinking water in the PET bottle with the head up, so the small gas discharge hole at the end of the thin pipe is on the water surface.
  • the check valve function by the thin pipe it is possible to reliably prevent the drinking water from flowing back into the cylindrical case.
  • the head of the cylindrical case is a cap body that is solidified to the cylindrical case main body, and the cap body provided with a buoyancy space is a processing of a separate cap body that is solidified to the cylindrical case main body. Easy to remove and efficient.
  • a cylindrical case made of a flexible membrane material that can retain its form can be simplified as a whole, and can contribute to cost reduction. Moreover, since it can be crushed and discarded, it is suitable as a disposable structure.
  • the hydrogen gas generation space is insulated, without being adversely affected by the temperature of the drinking water in the plastic bottle, Hydrogen gas can be generated reliably.
  • the cylindrical case has a bellows structure on the wall that generates negative water pressure by generating a negative pressure inside the tube, so that it can easily suck water to generate hydrogen in the cylindrical case. Can be efficient.
  • FIG. 1 is a perspective view of an embodiment of a hydrogen gas generator according to the present invention. It is explanatory drawing which shows the state which injected
  • the gist of the present invention is that a hydrogen gas generation space for containing a hydrogen generating agent is provided in a sealed cylindrical case for entering a PET bottle, and gas is passed through the end of the hydrogen gas generation space.
  • a thin pipe for gas discharge having a check valve function that does not allow water to pass through is provided, and the end of the thin pipe is used as a small hole for gas discharge, and the outer periphery of the thin pipe protruding into the inside of the cylindrical case head and the cylindrical case
  • the head of the cylindrical case is a cap body that is solidified to the cylindrical case main body, and a hydrogen gas generator characterized by providing a buoyancy space in the cap body is provided.
  • the present invention is intended to provide a hydrogen gas generator characterized by forming a cylindrical case with a flexible membrane material that can retain its form.
  • the present invention is to provide a hydrogen gas generator characterized by providing a heat insulating jacket structure between the hydrogen gas generating space and the outer wall of the cylindrical case.
  • the cylindrical case is intended to provide a hydrogen gas generating device characterized in that the wall portion has a bellows structure that generates an external water suction force with a negative pressure inside.
  • FIG. 1 is a longitudinal sectional view
  • FIG. 2 is a perspective view
  • FIG. 3 is an explanatory view showing a state in which a hydrogen gas generator is put into a PET bottle.
  • 4A is a cross-sectional view taken along the line AA in FIG. 1
  • FIG. 4B is a cross-sectional view taken along the line BB.
  • the basic configuration of the hydrogen gas generator A is that the cap body 20 is fixed to the head of the cylindrical case body 30, and the bottom member 25 is fixed to the lower end of the cylindrical case body 30.
  • the cylindrical case 10 is tied.
  • the cylindrical case 10 is configured such that the cap body 20 is fitted and fixed to the head of the cylindrical case main body 30 via a seal member 21, and the bottom member 25 is formed at the lower end of the cylindrical case main body 30.
  • a bottomed cylindrical shape fitted and consolidated via a seal member 22 is formed.
  • a buoyancy space 23 is formed inside the cap body 20.
  • the sealing members 21 and 22 may be removed and bonded, or may be screwed together.
  • the upper and lower end portions of the cylindrical case 10 hit the inner peripheral wall of the plastic bottle when the cylindrical case 10 is put in the plastic bottle and do not turn upside down. .
  • the peripheral wall of the cylindrical case body 30 has a jacket structure 32. Therefore, the temperature of the drinking water outside the cylindrical case 10 is interrupted so that the temperature of the drinking water is not transmitted to the hydrogen generating agent accommodated in the cylindrical case 10, and the reaction heat from the hydrogen generating agent is also received by the cylindrical case.
  • the cylindrical case 10 is provided with a function of blocking transmission from the water to the drinking water.
  • the jacket structure 32 has a structure in which an inner wall 33 and an outer wall 34 are formed with a heat insulating space 35 between the inner and outer double walls.
  • the heat shielding effect can be improved as much as possible by forming the peripheral wall of the cylindrical case body 30 to be thick.
  • the reaction heat of the hydrogen generating agent is not transmitted to drinking water, the hydrogen generating reaction of the hydrogen generating agent is promoted, and the hydrogen generating agent can generate a large amount of hydrogen gas in a short time. It is said.
  • a vertically long space is formed inside the cylindrical case body 30.
  • a small bag of the hydrogen generating agent 4 in a vertically long bag can be stored in the space in the vertical direction.
  • FIG. 1 and FIG. 4 (b) show a state in which a vertically long bag of the hydrogen generating agent 4 is stored in a vertically long space of the cylindrical case body 30. That is, the vertically long space of the cylindrical case body 30 is a housing part for the hydrogen generating agent 4 and forms a hydrogen gas generating space 31.
  • the hydrogen generating agent 4 is composed of a bag formed of a nonwoven fabric having water permeability and gas permeability, and a generating agent that generates hydrogen by being stored inside the bag and reacting with water.
  • the generating agent is not particularly limited as long as it can generate hydrogen by reacting with water.
  • a mixed powder of Al, Mg, Ca oxide, Ca hydroxide, or the like is used.
  • the hydrogen generating agent 4 bag Before using the hydrogen generating agent 4 bag, that is, before storing it in the inside of the cylindrical case body 30, immerse it half in water and moisten it. As a result, the generating agent in the bag is brought into contact with water in advance to cause a hydrogen generation reaction.
  • the water that causes the hydrogen generation reaction may be, for example, drinking water in a plastic bottle P or tap water.
  • the cylindrical case 10 placed in the plastic bottle P is substantially upright with the upper end portion facing upward. It will float in a hanging position.
  • the cylindrical case 10 floats in a state where the gas discharge small holes 12 are always directed upward in the plastic bottle by the buoyancy of the case.
  • a narrow pipe 11 having a check valve function protrudes into the buoyancy space 23, and a gas discharge small hole is formed at the end of the thin pipe 11.
  • the gas discharge small hole 12 is always open in the upper space in the PET bottle P. Thereby, hydrogen gas is discharged to the upper part in the PET bottle P and reacts with the drinking water in the PET bottle P to generate hydrogen water.
  • the relationship between the internal pressures of the cylindrical case 10 and the PET bottle P is that the upper and lower case internal pressures are equal to or greater than the PET bottle internal pressures at the time of hydrogen gas generation.
  • the hydrogen gas inside the case heated by the heat shrinks or contracts, or when the plastic bottle P is strongly gripped, the upper and lower case internal pressure ⁇ the plastic bottle internal pressure.
  • the small hole 12 for gas discharge is opened in the upper space of the plastic bottle P, when it is thrown in, it prevents metal ions from entering the case by preventing drinking water from entering the case. It becomes possible to block elution into drinking water. Furthermore, since the thin pipe 11 performs the check valve function, drinking water outside the case cannot enter the hydrogen gas generation space 31.
  • the bag-like hydrogen generating agent 4 is dipped in the drinking water of the plastic bottle P and moistened, and then the hydrogen gas in the decomposed cylindrical case body 30 as shown in FIG. It is quickly stored in the generation space 31.
  • the cap body 20 is fitted into the cylindrical case body 30 and solidified.
  • the cylindrical case 10 is put into the plastic bottle P, the lid of the plastic bottle P is closed, and then the plastic bottle is shaken several tens of times.
  • the cylindrical case 10 is floating in the drinking water in a state where the small hole 12 for gas discharge is always directed upward in the plastic bottle and the substantially vertical posture is maintained.
  • the hydrogen generating agent 4 stored in the hydrogen gas generating space 31 of the cylindrical case body 30 by standing for 10 to 15 minutes reacts with water dampened the bag to generate hydrogen gas. That is, hydrogen gas bubbles are generated from the gas discharge small holes 12 of the cylindrical case 10.
  • the hydrogen generating agent 4 generates heat with the hydrogen gas generation reaction, but as shown in FIG. 4, this reaction heat is blocked by the jacket structure 32 formed on the peripheral wall of the cylindrical case body 30, and the outer peripheral wall of the case. Is not transmitted to the drinking water in the plastic bottle P.
  • Hydrogen gas generated from the hydrogen generating agent 4 is released into the PET bottle P outside the cylindrical case from the gas discharge small hole 12 through the fine pipe 11 as the internal pressure increases.
  • hydrogen gas is stored above the PET bottle P to form a hydrogen gas reservoir space H, and the hydrogen gas is dissolved into the drinking water by gradually increasing the internal pressure of the PET bottle.
  • the gas discharge small holes 12 in the hydrogen gas generation space 31 are directed upward in the hole opening direction by the float function of the upper half of the cylindrical case 10. That is, the gas discharge small hole 12 is opened in the hydrogen gas reservoir space H above the surface of the drinking water.
  • the hydrogen gas continuously generated from the hydrogen generating agent 4 by the hydrogen gas generation reaction causes the cylindrical case internal pressure to be higher than or equal to the PET bottle internal pressure, and the upper half of the cylindrical case 10. Since it floats by the float function, drinking water does not enter the cylindrical case from the gas discharge small hole 12.
  • the hydrogen gas in the hydrogen gas reservoir space H in the PET bottle is mixed with the drinking water by shaking the PET bottle P so that the hydrogen gas is forcibly dissolved in the drinking water.
  • the temperature inside the cylindrical case 10 decreases, and the internal pressure of the cylindrical case becomes lower than the internal pressure of the plastic bottle due to an increase in the internal pressure of the bottle due to the grip when shaking the plastic bottle.
  • drinking water may enter the case 10 and metal ions may elute from the intrusion path into the drinking water.
  • the fine pipe 11 having a check valve function performs a check valve function that blocks the metal ion water from leaking into the plastic bottle P.
  • the peripheral wall of the cylindrical case has a jacket structure, the reaction heat of the hydrogen generating agent is not absorbed by the drinking water and cooled. Therefore, the hydrogen gas generation reaction of the hydrogen generating agent is promoted, a large amount of hydrogen gas is generated in a relatively short time, and hydrogen water can be generated in a short time.
  • the hydrogen generation unit mainly composed of the upper and lower cases, it is possible to generate hydrogen gas quickly and to prevent the metal ions from being dissolved in the drinking water. It is possible to provide a hydrogen gas generator that can perform the function of a valve.
  • FIG. 5 is a longitudinal sectional view of a hydrogen gas generator according to another embodiment.
  • the same parts as those in the previous embodiment are denoted by the same reference numerals.
  • a thin-film bag-shaped cylindrical case body 30a is provided, and a fitting member 36 is fixed to the upper end opening of the cylindrical case body 30a to be fitted.
  • the cap body 20 is consolidated to the member 36.
  • a bag body 37 that forms the hydrogen gas generation space 31 is held downward from the fitting member 36.
  • the hydrogen generating agent 4 is stored in the bag body 37.
  • the buoyancy space 23 is formed inside the cap body 20, and the narrow pipe 11 and the gas discharge small hole 12 are provided as in the previous embodiment.
  • the small hole 12 for gas discharge is opened in the upper space of the plastic bottle P, when it is thrown in, it prevents the drinking water outside the case from entering the case, so that the metal ions are in the drinking water. It is possible to block elution into Furthermore, since the thin pipe 11 performs the check valve function, drinking water outside the case cannot enter the hydrogen gas generation space 31.
  • FIGStill another embodiment 6 and 7 show still another embodiment of the hydrogen gas generator according to the present invention.
  • the shape can be maintained, but is formed from a flexible film material.
  • a slightly flat outer case 13 and a hydrogen gas generation space 31 for containing the hydrogen generating agent 4 are constituted by an inner bag 38.
  • a gas release narrow pipe 11 having a check valve function that allows gas to pass but not water, and the end of the narrow pipe 11 serves as a gas discharge small hole 12.
  • a buoyancy space 23 is defined between the outer periphery of the thin pipe 11 protruding inside the cylindrical case head and the inner periphery of the cylindrical case.
  • the interior bag 38 and the space inside the cylindrical case 10 are communicated with each other through a small hole 38a, which is an escape when the internal pressure of the hydrogen gas generation space 31 is increased.
  • the hydrogen generating agent 4 can be inserted into the interior bag 38 of the hydrogen gas generating space 31 by expanding the gas discharge small hole 12. And since it is flexible as a whole, it can be folded and crushed and discarded, which is suitable as a disposable structure.
  • FIG. 8 and 9 show still another embodiment of the hydrogen gas generator according to the present invention.
  • the whole is integrally molded as a flexible resin.
  • a hydrogen gas generation space 31 for containing the hydrogen generating agent 4 is integrally formed in the exterior 14.
  • a gas release narrow pipe 11 having a check valve function that allows gas to pass but not water, and the end of the narrow pipe 11 serves as a gas discharge small hole 12.
  • a buoyancy space 23 is defined between the outer periphery of the thin pipe 11 protruding inside the cylindrical case head and the inner periphery of the cylindrical case.
  • the cylindrical case 10 is crushed and immersed in a container filled with water, and when the force is released, hydrogen gas is generated from the gas discharge small hole 12 through the thin pipe 11. Water can be put into the space 31.
  • FIG. 10 shows still another embodiment of the hydrogen gas generator according to the present invention.
  • the whole is integrally molded as a flexible resin, and the upper wall portion of the cylindrical case 10 has a negative pressure inside the cylindrical case to generate an external water suction force.
  • the structure 39 is used.
  • the sealed cylindrical case 10 for placing in a plastic bottle has a base portion forming a hydrogen gas generation space 31 for containing the hydrogen generating agent 4, and an upper wall portion of the hydrogen gas generation space 31 has A bellows structure 39 is provided, and a gas discharge narrow pipe 11 having a check valve function that allows gas to pass but does not allow water to pass therethrough, and a gas discharge small hole 12 is formed at the end of the thin pipe 11 to form a cylindrical case.
  • a buoyancy space 23 is defined between the outer periphery of the thin pipe 11 protruding inside the head and the inner periphery of the cylindrical case.
  • FIG. 10 (a) when the head of the cylindrical case 10 is pushed and the bellows structure 39 is crushed, it is immersed in a container filled with water, and when the force is removed, FIG. 10 (b) As shown, the bellows structure 39 extends so that water can be put into the hydrogen gas generation space 31 from the gas discharge small hole 12 through the thin pipe 11.
  • FIG. 11 shows still another embodiment of the hydrogen gas generator according to the present invention.
  • the entirety is integrally formed as a flexible resin, and the entire wall portion of the cylindrical case 10 has a bellows structure 39a.
  • the sealed cylindrical case 10 for placing in a plastic bottle has a base portion forming a hydrogen gas generation space 31 for containing the hydrogen generating agent 4, and the entire wall portion of the hydrogen gas generation space 31 has a bellows structure. 39a, and a gas discharge narrow pipe 11 having a check valve function that allows gas to pass but not water, and a gas discharge small hole 12 formed at the end of the thin pipe 11 to form a cylindrical case head
  • a buoyancy space 23 is defined between the outer periphery of the thin pipe 11 protruding inside the portion and the inner periphery of the cylindrical case.
  • FIG. 11 (a) when the head of the cylindrical case 10 is pushed and the bellows structure 39a is crushed, it is immersed in a container filled with water, and when the force is released, FIG. 11 (b) As shown, the bellows structure 39a extends to allow water to enter the hydrogen gas generation space 31 from the small gas discharge hole 12 through the thin pipe 11.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Medicinal Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Packages (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
PCT/JP2019/010144 2018-03-19 2019-03-13 水素ガス発生装置 WO2019181670A1 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2018-051776 2018-03-19
JP2018051776A JP7093993B2 (ja) 2018-03-19 2018-03-19 水素ガス発生装置および水素水の製造方法

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WO2019181670A1 true WO2019181670A1 (ja) 2019-09-26

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JP (1) JP7093993B2 (zh)
TW (1) TW201945275A (zh)
WO (1) WO2019181670A1 (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012176395A (ja) * 2011-02-01 2012-09-13 Hiromaito Co Ltd 水素水の調整方法及び生水器
WO2015156415A1 (ja) * 2014-04-11 2015-10-15 エコモ・インターナショナル株式会社 水素発生ユニット
JP2016210652A (ja) * 2015-05-11 2016-12-15 株式会社フクプランニング 水素発生剤収納体及び水素水生成セット
JP2017104842A (ja) * 2015-12-02 2017-06-15 ＭｉＺ株式会社 水素含有液体の生成装置及び方法
JP2018202378A (ja) * 2017-06-09 2018-12-27 エコモ・インターナショナル株式会社 水素ガス発生装置

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012176395A (ja) * 2011-02-01 2012-09-13 Hiromaito Co Ltd 水素水の調整方法及び生水器
WO2015156415A1 (ja) * 2014-04-11 2015-10-15 エコモ・インターナショナル株式会社 水素発生ユニット
JP2016210652A (ja) * 2015-05-11 2016-12-15 株式会社フクプランニング 水素発生剤収納体及び水素水生成セット
JP2017104842A (ja) * 2015-12-02 2017-06-15 ＭｉＺ株式会社 水素含有液体の生成装置及び方法
JP2018202378A (ja) * 2017-06-09 2018-12-27 エコモ・インターナショナル株式会社 水素ガス発生装置

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JP7093993B2 (ja) 2022-07-01
JP2019163188A (ja) 2019-09-26

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