WO2019160227A1 - Composition cosmétique de type eau dans huile présentant une durabilité améliorée et atténuant la sensation de sécheresse - Google Patents

Composition cosmétique de type eau dans huile présentant une durabilité améliorée et atténuant la sensation de sécheresse Download PDF

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Publication number
WO2019160227A1
WO2019160227A1 PCT/KR2018/015528 KR2018015528W WO2019160227A1 WO 2019160227 A1 WO2019160227 A1 WO 2019160227A1 KR 2018015528 W KR2018015528 W KR 2018015528W WO 2019160227 A1 WO2019160227 A1 WO 2019160227A1
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WO
WIPO (PCT)
Prior art keywords
oil
cosmetic composition
water
forming agent
film forming
Prior art date
Application number
PCT/KR2018/015528
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English (en)
Korean (ko)
Inventor
정은지
정지희
한종섭
Original Assignee
주식회사 엘지생활건강
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Priority to CN201880089396.8A priority Critical patent/CN111712224B/zh
Publication of WO2019160227A1 publication Critical patent/WO2019160227A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8117—Homopolymers or copolymers of aromatic olefines, e.g. polystyrene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention relates to a water-in-oil cosmetic composition, and more particularly to a water-in-oil cosmetic composition that can improve the sustainability while relieving dryness.
  • the present invention is to provide a water-in-oil cosmetic composition of high durability.
  • the inventors of the present invention try to solve the problem that the compatibility with other components in the water-in-oil cosmetic composition.
  • the present invention is to provide a new cosmetic composition that can alleviate the feeling of drying gradually increased with time after application to the skin.
  • the present invention is to provide a way to solve the drying feeling of the excellent cosmetic composition. That is, to provide a cosmetic composition excellent in durability and improved dry feeling.
  • the present invention is to provide a water-in-oil cosmetic composition having excellent adhesion.
  • the present invention relates to a water-in-oil cosmetic composition
  • a water-in-oil cosmetic composition comprising two or more types of film forming agents, characterized by comprising different film forming agents in the continuous phase and the dispersed phase.
  • the cosmetic composition for applying to the skin is to use a large amount of the oil film forming agent to improve the persistence, to recognize the problem that occurs at this time to complete the present invention.
  • the present invention has been completed in order to reduce the amount of oil film forming agent, to improve skin dryness, and to improve compatibility with other components, and usability.
  • the inventors of the present invention have for the first time realized that there are differences in achieving the effects of the present invention depending on the type and / or content of the aqueous film former used in the inner phase, and have completed the present invention.
  • the inventors of the present invention have been able to confirm by designing a specific experiment that the type of oil film forming agent used with the water film forming agent can also play an important role in achieving the object of the present invention.
  • a 'continuous phase' is a continuous phase.
  • a 'dispersed phase' is a phase dispersed in a continuous phase.
  • the emulsion is dispersed in the form of small droplets with a constant ratio without mixing the continuous phase and the dispersed phase, and forms a dispersion phase in the continuous phase.
  • Oil-in-water (O / W) emulsions are emulsions in which the continuous phase is water and oil in the dispersed phase
  • water-in-oil emulsions are emulsions in which the continuous phase oil and the dispersed phase are water.
  • the cosmetic composition of the present invention may be water-in-oil type, preferably an emulsion having a continuous oil phase, such as water-in-oil and oil-in-water emulsions.
  • the cosmetic composition may comprise 0.01 to 20% by weight of the oil film forming agent, preferably 1 to 15% by weight, more preferably 5 to 13% by weight, most preferably 8 to 10% by weight of oily A film former may be included.
  • the cosmetic composition of the present invention uses a small amount of the oil film forming agent and further includes a film forming agent in the dispersed phase, as described below, so that a small amount of the oil film forming agent can be used.
  • the present invention is to use a small amount of the oil film forming agent to provide a cosmetic composition with less skin dryness, excellent skin adhesion.
  • an 'aqueous' film forming agent may be used to mean both water soluble or water dispersible film forming agents.
  • an 'oil-based' film forming agent may be used to mean both oil-soluble or oil-dispersible film forming agents.
  • the cosmetic composition may include both an oily film former and an aqueous film former.
  • the cosmetic composition of the present invention may be a water-in-oil cosmetic composition containing both an oil film forming agent and an aqueous film forming agent.
  • the cosmetic composition of the present invention may be an oil-in-water type cosmetic composition containing both an oil film forming agent and an aqueous film forming agent.
  • the cosmetic composition of the present invention may include 20 wt% or less or 10 wt% or less of an oil film forming agent, and may further include an aqueous film forming agent.
  • the inventors of the present invention when used together with the oil film forming agent and the water film forming agent, can be expected to have excellent skin adhesion, longevity, feeling, in particular, it was possible to obtain the effect of improving the moisture retention and moisturizing power of the skin, skin dryness.
  • the oily film former is trimethylsiloxysilicate, acrylate / stearyl acrylate / dimethicone methacrylate copolymer polypropylsilsesquioxane, C30-45 alkyl dimethylsilyl polypropylsilsesquioxane, acrylate It may include one or more selected from the group consisting of / polytrimethylsiloxy methacrylate copolymer, acrylate / dimethicone copolymer, and phenylpropyl dimethylsiloxy silicate, preferably trimethylsiloxysilicate And / or acrylate / stearylacrylate / dimethicone methacrylate copolymers.
  • trimethylsiloxy silicate and / or acrylate / stearyl acrylate / dimethicone methacrylate copolymer were used, it was easy to stabilize the dispersed phase, and excellent skin moisturizing property and adhesion, and a flexible film film could be formed.
  • trimethylsiloxysilicate can form a strong coating, and acrylate / stearylacrylate / dimethicone methacrylate copolymer can form a flexible coating.
  • the aqueous coating agent may include one or more selected from the group consisting of sodium polystyrene sulfonate, hydroxypropyl guar, and hydroxyethyl cellulose, preferably hydrolyzed wheat protein / FIV crosspolymer, and And / or sodium polystyrenesulfonate, more preferably sodium polystyrenesulfonate.
  • sodium polystyrene sulfonate was used as an aqueous film forming agent, it was easy to stabilize the dispersed phase, and the skin's moisturizing power and adhesion were excellent.
  • the cosmetic composition is an oil coating agent, 0.01 to 20% by weight, preferably 1 to 18% by weight, more preferably 1 to 15% by weight, even more preferably 1 to 10% by weight, based on the total weight of the cosmetic composition, It may comprise 1 to 8% by weight.
  • One embodiment of the present invention may comprise an aqueous film forming agent 0.01 to 12% by weight, preferably 1 to 11% by weight, more preferably 10.5% by weight relative to the total weight of the cosmetic composition. If it is less than this content, there will be no effect of a film, and if it is more than this, a usability will become sticky and application property may fall. When having the above content range, it was excellent to maintain the skin moisturizing rate, it was excellent in improving the dry feeling. At the same time, it was advantageous to provide a feeling of formulation stability and a feeling of moisture.
  • the oily film forming agent included in the cosmetic composition may be acrylate / stearylacrylate / dimethicone methacrylate copolymer and / or trimethylsiloxysilicate, and the aqueous film forming agent may be sodium polystyrenesulfonate.
  • the oily film forming agent included in the cosmetic composition may be acrylate / stearylacrylate / dimethicone methacrylate copolymer and / or trimethylsiloxysilicate
  • the aqueous film forming agent may be sodium polystyrenesulfonate.
  • the cosmetic composition may have one or more formulations selected from the group consisting of foundation, concealer, makeup base, BB cream, lotion, cream, and wax, and may be preferably provided as a water-in-oil foundation.
  • the cosmetic composition of the present invention may be included without limitation so long as it can be included in conventional cosmetic compositions that can be included in the formulations listed above.
  • the cosmetic composition of the present invention may further include an organic / inorganic sunscreen.
  • the present invention can have an excellent effect especially when applied to a product to be used by storing the cosmetic composition in a sponge.
  • the cosmetic compositions of the present invention can be easily stored and provided in a sponge.
  • the cosmetic composition of the present invention provides excellent skin moisturizing and moisture retention.
  • a small amount of oil coating agent can be used through the cosmetic composition of the present invention.
  • the cosmetic composition of the present invention is excellent in the skin tightness, and the makeup breakdown rate is slow due to sebum and the like, and thus the makeup lasting power is excellent.
  • Cosmetic composition of the present invention can provide excellent feeling of use, skin adhesion.
  • the cosmetic composition of the present invention is easy to absorb and provide to a sponge.
  • the present invention can increase the affinity with the skin, further improve the poor persistence when using only an excessive amount of the oil-soluble film alone, and at the same time can improve the dryness, which was a disadvantage, to increase customer satisfaction.
  • the oil-soluble film can form a film to increase the sustainability, but the feeling of use such as tightness of the skin, dry feeling, and sticky feeling is not good. Can be.
  • the present invention can provide a cosmetic composition with improved stability.
  • 1 is a graph showing the results of the moisture retention improvement when using the oil film forming agent and the water film forming agent together.
  • Figure 3 shows the evaluation results for the oil bleeding degree and burying in water-in-oil makeup cosmetics. Comparative example 1, 2, 3, and Example 1 are shown in order from left.
  • Test Example 1 Water-in-oil makeup cosmetic formulation containing a water-soluble and oil-soluble film forming agent
  • Water-in-oil makeup cosmetics were prepared according to the following preparation method according to the ingredients and contents (wt%) shown in Table 1.
  • the moisturizing measurement was performed on the actual test subjects, and after 20 minutes of adaptation to a constant temperature room for the purpose of objective moisturizing measurement, the test was started using a corneometer.
  • the measurement method was measured based on 1 hour and 3 hours before and immediately after application, and the average value was calculated after each measurement three times, and the moisturizing improvement rate (%) was shown as compared with before application.
  • Example 2 also showed an excellent moisturizing improvement rate.
  • Example 1 has a more excellent moisturizing improvement rate.
  • the quantification was shown by quantifying the black portion of the artificial family where the cosmetic film was peeled off with ImagePro Plus software.
  • the cosmetic persistence may vary depending on the type of the water-soluble film forming agent.
  • each sample was uniformly pushed to the same thickness (60 ⁇ m) on a glass plate, and then dried at 30 ° C. for 1 hour. Subsequently, after dropping the same amount of artificial sebum in the middle portion, the degree of oil bleeding was confirmed after standing for 20 minutes at 30 degrees (°C). Thereafter, the artificial leather was placed on the sebum and rolled 10 times at a constant pressure (200 g weight) to confirm the amount of the sample buried in the artificial leather, and the degree of burial was shown in FIG. 3.
  • Comparative Example 1 As can be seen in Figure 3, in Comparative Example 1 it was confirmed that the degree of bleeding and staining of the oil is the most severe. Compared with Comparative Example 1, in Comparative Example 3 and Example 1, the oil was less smeared or smeared, and in particular, Example 1 which further contained sodium polystyrenesulfonate in the inner phase of the oil was compared to that of Comparative Examples 1 and 2. There was no bleeding phenomenon, it was confirmed that the least buried. Therefore, the present invention was found to be excellent in makeup persistence because it is not buried or erased due to external activities.
  • the manufacturing method was the same as the manufacturing method described in Test Example 1, and confirmed the sustainability, stability, and usability.
  • Persistence was evaluated in the same manner as in Test Example 1, and the stability was compared to the room temperature after storage for 2 weeks at 45 ° C (° C).
  • the sensory evaluation was conducted by sensory evaluation, and 20 consumers in their 20s and 40s evaluated the degree of feeling of moisture, and gave a score of 0-5 and averaged the scores.
  • Test Example 3 Water-in-oil type makeup cosmetic formulations containing different types of oil-soluble coatings
  • Trimethylsiloxysilicate was included in the oil phase to further evaluate the persistence.
  • Example 4 Oily ingredient Cyclopentasiloxane Remaining amount Remaining amount Phenyltrimethicone 3.00 3.00 Fiji-10 dimethicone 3.00 3.00 Disteadimonium hectorite 0.30 0.30 Trimethylsiloxysilicate 2.00 2.00 Spices 0.3 0.3 coloring agent Titanium dioxide 10.00 10.00 Yellow Iron Oxide, Red Iron Oxide, Black Iron Oxide 2.00 2.00 Water component Purified water Remaining amount Remaining amount Sodium chloride 0.50 0.50 Hydrolyzed Wheat Protein / FIV Crosspolymer 2.00 - Sodium Polystyrene Sulfonate - 2.00 antiseptic Quantity Quantity
  • the sodium polystyrene sulfonate was more excellent in sustainability than the hydrolyzed wheat protein / FIVpicross polymer.
  • the cosmetic composition using trimethylsiloxysilicate together with sodium polystyrene sulfonate was more excellent in moisturizing feeling, formulation stability, and the like than when using hydrolyzed wheat protein / FIV crosspolymer and trimethylsiloxysilicate.
  • the present invention can provide a water-in-oil cosmetic composition excellent in moisturizing power.
  • the cosmetic composition of the present invention can improve the dryness of the skin.
  • a cosmetic composition excellent in skin fit can be provided.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition cosmétique de type eau dans huile comprenant au moins deux agents filmogènes, les agents filmogènes, différents l'un de l'autre, étant respectivement présents dans une phase continue et dans une phase dispersée. En particulier, la composition cosmétique de la présente invention présente une durabilité supérieure et peut assurer un excellent effet d'hydratation.
PCT/KR2018/015528 2018-02-14 2018-12-07 Composition cosmétique de type eau dans huile présentant une durabilité améliorée et atténuant la sensation de sécheresse WO2019160227A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201880089396.8A CN111712224B (zh) 2018-02-14 2018-12-07 提高了持久力且改善了干燥感的油包水型化妆料组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2018-0018581 2018-02-14
KR1020180018581A KR101998776B1 (ko) 2018-02-14 2018-02-14 지속력이 향상되고 건조감이 개선된 유중수형 화장료 조성물

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WO2019160227A1 true WO2019160227A1 (fr) 2019-08-22

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PCT/KR2018/015528 WO2019160227A1 (fr) 2018-02-14 2018-12-07 Composition cosmétique de type eau dans huile présentant une durabilité améliorée et atténuant la sensation de sécheresse

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KR (1) KR101998776B1 (fr)
CN (1) CN111712224B (fr)
TW (1) TWI826417B (fr)
WO (1) WO2019160227A1 (fr)

Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
KR102165829B1 (ko) * 2020-04-02 2020-10-14 주식회사 한국화장품제조 우수한 피부 밀착력을 가지는 컨실러 화장료 조성물 및 이의 제조방법
KR102608661B1 (ko) * 2023-05-10 2023-12-04 애경산업(주) 유중수형 메이크업용 화장료 조성물

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06211629A (ja) * 1992-11-30 1994-08-02 Shiseido Co Ltd メーキャップ化粧料
KR20070004924A (ko) * 2004-04-30 2007-01-09 더 프록터 앤드 갬블 캄파니 장시간 유지형 화장 조성물
KR20110130451A (ko) * 2009-03-31 2011-12-05 이엘씨 매니지먼트 엘엘씨 마스카라 조성물 및 속눈썹을 처리하는 방법
KR20160012963A (ko) * 2014-07-25 2016-02-03 주식회사 에스티씨나라 보습력 및 지속력이 우수한 화장료 조성물 및 이의 제조방법
JP2018002677A (ja) * 2016-07-06 2018-01-11 日本メナード化粧品株式会社 乳化化粧料

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Publication number Priority date Publication date Assignee Title
US4965071A (en) * 1988-10-19 1990-10-23 The Gillette Company Wrinkle masking composition of sodium polystyrene sulfonate and process for use
US6503521B1 (en) * 2000-11-22 2003-01-07 L'ORéAL S.A. Fiber-containing base composition for use with mascara
JP2005263702A (ja) * 2004-03-19 2005-09-29 Kao Corp ケラチン繊維付着用化粧料
KR20170005874A (ko) * 2014-05-29 2017-01-16 에버레디 배터리 컴파니, 인크. 개선된 피부 외관을 위해 색상 유지력이 향상된 화장료 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06211629A (ja) * 1992-11-30 1994-08-02 Shiseido Co Ltd メーキャップ化粧料
KR20070004924A (ko) * 2004-04-30 2007-01-09 더 프록터 앤드 갬블 캄파니 장시간 유지형 화장 조성물
KR20110130451A (ko) * 2009-03-31 2011-12-05 이엘씨 매니지먼트 엘엘씨 마스카라 조성물 및 속눈썹을 처리하는 방법
KR20160012963A (ko) * 2014-07-25 2016-02-03 주식회사 에스티씨나라 보습력 및 지속력이 우수한 화장료 조성물 및 이의 제조방법
JP2018002677A (ja) * 2016-07-06 2018-01-11 日本メナード化粧品株式会社 乳化化粧料

Also Published As

Publication number Publication date
KR101998776B1 (ko) 2019-10-01
TW201936162A (zh) 2019-09-16
TWI826417B (zh) 2023-12-21
CN111712224A (zh) 2020-09-25
CN111712224B (zh) 2023-08-01

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