WO2023113147A1 - Composition cosmétique pour lèvres comprenant une grande quantité de perle - Google Patents

Composition cosmétique pour lèvres comprenant une grande quantité de perle Download PDF

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Publication number
WO2023113147A1
WO2023113147A1 PCT/KR2022/013141 KR2022013141W WO2023113147A1 WO 2023113147 A1 WO2023113147 A1 WO 2023113147A1 KR 2022013141 W KR2022013141 W KR 2022013141W WO 2023113147 A1 WO2023113147 A1 WO 2023113147A1
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Prior art keywords
lips
cosmetic composition
weight
mica
iron oxide
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PCT/KR2022/013141
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English (en)
Korean (ko)
Inventor
김수혜
조선미
이준환
강수진
손지현
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한국콜마 주식회사
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Publication of WO2023113147A1 publication Critical patent/WO2023113147A1/fr

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips

Definitions

  • the present invention relates to a cosmetic composition for lips containing a large amount of pearls, and specifically, to a cosmetic composition containing at least one of polyacrylate crosspolymer-6 and hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer.
  • the present invention relates to a cosmetic composition for lips containing an agent, which stabilizes a large amount of pearls, and has excellent durability and moisturizing power.
  • Lips are the most mobile parts of the body, and since they are always exposed to the outside, they are affected by environmental factors such as atmospheric and climatic conditions, so they become easily dry or rapidly aging.
  • the skin structure of the lips has no sebum film and pores, and the stratum corneum is formed extremely thin, so the absolute amount of natural moisturizing factors and moisture is insufficient, and the rate of moisture evaporation is very fast. Since lip care products that protect lips are used repeatedly every day or over a long period of time in daily life, they must be safe in use and have no side effects.
  • lipstick is an oily formulation and is composed of wax, oil, pigment, and powder.
  • the wax maintains the appearance of the lipstick
  • the oil gives a rich feeling of use and a glossy feeling
  • the pigment expresses color as a pigment and/or dye
  • the powder improves application, adhesion, and durability and provides a matte feeling of use.
  • a water dispersion type cosmetic composition in the case of a water dispersion type cosmetic composition, it has a characteristic of having a moist feeling due to the inclusion of water, but due to the rapid evaporation of water, the feeling of moisture disappears over time, resulting in a dry feeling, and the glossiness increases with the evaporation of water. It has a weakening problem. In order to solve this problem, when the content of the polymer used as a conventional thickener is increased, there are problems such as stickiness and heavy feeling, so there is no satisfactory improvement.
  • Carbomer which is used as a thickening agent in most lip makeup for lips, has problems in that it dries quickly, exfoliates, and loses glossiness. Controversy over contamination and limited use in organic or natural cosmetics.
  • the inventors of the present invention have overcome the problems of the prior art as described above and have developed a cosmetic composition for lips that does not stick to a mask, has high durability and excellent moisturizing power, and has reached the present invention.
  • the present invention relates to a cosmetic composition for lips containing a large amount of pearls, and specifically, to a cosmetic composition containing at least one of polyacrylate crosspolymer-6 and hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer. It is an object of the present invention to provide a cosmetic composition for lips that stabilizes a large amount of pearls and has excellent durability and moisturizing power.
  • a cosmetic composition for lips containing a thickener containing at least one of polyacrylate crosspolymer-6 and hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer is provided do.
  • the thickener may be a cosmetic composition for lips comprising polyacrylate crosspolymer-6:hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer in a mixing ratio of 1:2 to 16.
  • the cosmetic composition for lips further comprises a pigment, based on the total weight of the cosmetic composition for lips, for lips comprising 0.1 to 2.0% by weight of the thickener, 10 to 40% by weight of the pigment and the balance of purified water. It may be a cosmetic composition.
  • the pigment may be a cosmetic composition for lips containing 20% to 35% by weight.
  • the pigment may be a cosmetic composition for lips that is a pearl powder.
  • the pigment is mica/yellow iron oxide/titanium dioxide, mica/titanium dioxide/red iron oxide, mica/red iron oxide/black iron oxide/titanium dioxide, mica/titanium dioxide/yellow iron oxide, mica/red iron oxide, mica/titanium dioxide / It may be a cosmetic composition for lips containing at least one selected from the group consisting of ferric ferrocyanide, mica/iron oxide, mica/titanium dioxide/iron oxide/carmine, and mica/titanium dioxide/carmine.
  • the cosmetic composition for lips may be a cosmetic composition for lips further comprising any one or more selected from the group consisting of a moisturizer, a film former, a powder, a water-soluble pigment and a preservative.
  • the cosmetic composition for lips based on the total weight of the cosmetic composition for lips, 0.1 to 2.0% by weight of the thickener, 10 to 40% by weight of the pigment, 8 to 15% by weight of the moisturizer, 1 to 2.5% by weight of the film former, and 1 to 2.5% by weight of the powder
  • the moisturizer may be a cosmetic composition for lips containing at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol and pentylene glycol.
  • the film former may be a cosmetic composition for lips containing at least one selected from the group consisting of acrylate copolymer, alkyl acrylate, acrylate/ethylhexyl acrylate copolymer and ammonium acrylate copolymer. there is.
  • the powder may be a cosmetic composition for lips containing at least one selected from the group consisting of synthetic fluorophlogopite, mica and silica.
  • the cosmetic composition for lips provided in the present invention includes a large amount of pearls to enhance gloss and color implementation, as well as polyacrylate crosspolymer-6 and hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer. Including one or more thickeners to stabilize a large amount of pearls while providing excellent durability and moisturizing effect.
  • the cosmetic composition for lips of the present invention maintains a stable formulation without separation of the formulation in various environments of low and high temperatures as well as at room temperature.
  • Example 1 is a view for explaining Tissue OFF test results of Example 1 and Comparative Example 3.
  • a hair loss functional component diluent; Surfactants; auxiliary surfactant; moisturizer; And there is provided a hair loss functional composition comprising an emulsifier.
  • a cosmetic composition for lips comprising a thickener containing at least one of polyacrylate crosspolymer-6 and hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer will be.
  • the thickener of the present invention is a material for adjusting the viscosity of the cosmetic composition for lips, polyacrylate crosspolymer-6: hydroxyethyl acrylate / sodium acryloyldimethyltaurate copolymer 1: 2 ⁇ 16 , 1: 3 to 13, 1: may be a cosmetic composition for lips comprising a mixing ratio of 4 to 8, preferably included in a mixing ratio of 4 to 8 in terms of improving viscosity and formulation stability.
  • the mixing ratio of the polyacrylate crosspolymer-6 and the hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer is less than 1:2, the durability and moisturizing power are reduced, and the formulation is not stably formed at high temperatures. Separation in the formulation may cause problems.
  • the mixing ratio of the polyacrylate crosspolymer-6 and the hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer exceeds 1:16, the sustaining power and moisturizing power are reduced, and a change in temperature occurs.
  • the formulation is unstable, and separation in the formulation occurs or pearl bands are formed, which may cause problems in commercialization.
  • the polyacrylate crosspolymer-6 is a copolymer of ammonium acryloyldimethyltaurate, dimethylacrylamide, lauryl methacrylate and laureth-4 methacrylate crosslinked with trimethylolpropane triacrylate. As a combination, it has a flexible and thick feeling, and has excellent gloss while minimizing moisture loss.
  • the polyacrylate crosspolymer-6 is the above It may be included in 0.1 to 0.5% by weight based on the total weight of the cosmetic composition for lips, but is not limited thereto.
  • the hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer is a copolymer component of sodium hydroxyethyl acrylate and acryloyldimethyl taurate monomer, which controls the viscosity of cosmetics when used as a cosmetic composition. It functions as a water-soluble thickener and can stabilize unstable emulsions of other immiscible ingredients.
  • the hydroxyethyl acrylate / sodium acryloyldimethyltaurate copolymer is 0.5 to 1.5 weight relative to the total weight of the cosmetic composition for lips in terms of improving the moisturizing power and durability while maintaining the function as a desired thickener %, but is not limited thereto,
  • the cosmetic composition for lips of the present invention further comprises a pigment, with respect to the total weight of the cosmetic composition for lips, for lips comprising 0.1 to 2.0% by weight of the thickener, 10 to 40% by weight of the pigment, and the balance of purified water. It may be a cosmetic composition.
  • the thickener may be, for example, a cosmetic composition for lips contained in 0.1 to 2.0% by weight, 0.3 to 2.0% by weight, 0.5 to 2.0% by weight based on the total weight of the cosmetic composition for lips.
  • the thickener When the thickener is included in less than 0.1% by weight based on the total weight of the cosmetic composition for lips, there is a problem in that the effect of improving viscosity and stability is significantly lowered, and when included in more than 2.0% by weight, the effect of the excess content There is no difference or the effect is reduced, so there may be problems with no practical benefit.
  • the pigment of the present invention for example, based on the total weight of the cosmetic composition for the lips, may be included in 10 to 40% by weight, 13 to 37% by weight, 15 to 35% by weight, the purpose of the cosmetic composition for the lips It is preferable to include 20% by weight to 35% by weight in terms of maintaining the viscosity.
  • the pigment of the present invention may be a cosmetic composition for lips that is a pearl powder in terms of achieving a desired gloss and color, but is not limited thereto.
  • the pigments of the present invention are mica/yellow iron oxide/titanium dioxide, mica/titanium dioxide/red iron oxide, mica/red iron oxide/black iron oxide/titanium dioxide, mica/titanium dioxide/yellow iron oxide, mica/red iron oxide, mica/titanium dioxide / It may be a cosmetic composition for lips containing at least one selected from the group consisting of ferric ferrocyanide, mica/iron oxide, mica/titanium dioxide/iron oxide/carmine, and mica/titanium dioxide/carmine.
  • the cosmetic composition for lips of the present invention may further include at least one selected from the group consisting of a moisturizer, a film former, a powder, a water-soluble pigment, and a preservative.
  • the cosmetic composition for lips of the present invention Based on the total weight of the cosmetic composition for lips of the present invention, 0.1 to 2.0% by weight of the thickener, 10 to 40% by weight of the pigment, 8 to 15% by weight of the moisturizer, 1 to 2.5% by weight of the film forming agent, and the powder It may be a cosmetic composition for lips comprising 3 to 5% by weight, 0.01 to 0.1% by weight of the water-soluble pigment, 0.3 to 0.6% by weight of the preservative, and the balance of purified water.
  • the moisturizing agent of the present invention may be a cosmetic composition for lips containing at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol and pentylene glycol, and is suitably in terms of improving moisturizing power It may be a cosmetic composition for lips containing at least one selected from the group consisting of glycerin and butylene glycol, but is not limited thereto.
  • the moisturizer in the present invention for example, with respect to the total weight of the cosmetic composition for the lips, may be included in 8 to 15% by weight, 9 to 14% by weight, preferably 10 to 13% by weight in terms of improving the moisturizing power It is preferable to include in %.
  • the film forming agent of the present invention may be a cosmetic composition for lips containing at least one selected from the group consisting of acrylate copolymer, alkyl acrylate, acrylate/ethylhexyl acrylate copolymer and ammonium acrylate copolymer. And, in terms of improving the durability of makeup, it may be the most suitable acrylate copolymer, but is not limited thereto.
  • the film former for example, based on the total weight of the cosmetic composition for the lips, may be included in 1 to 2.5% by weight, 1 to 2.3% by weight, suitably in terms of improving the durability of the makeup It is preferably included in 1.4 to 1.8% by weight.
  • the powder of the present invention may be a cosmetic composition for lips containing at least one selected from the group consisting of synthetic fluorophlogopite, mica, and silica, and is suitably synthesized in terms of viscosity and feeling of use of the desired cosmetic composition. It may be fluorophlogopite, but is not limited thereto.
  • the powder for example, based on the total weight of the cosmetic composition for the lips, may be included in 3 to 5% by weight, 3.2 to 4.8% by weight, suitable in terms of viscosity and feeling of use of the desired cosmetic composition It is preferably included in 3.5 to 4.5% by weight.
  • the water-soluble pigment is not limited thereto as long as it is a water-soluble pigment commonly used as a colorant, but is suitably red No. 227, red No. 104 (1), yellow in terms of implementing the desired color of the cosmetic composition for lips.
  • a water-soluble dye containing at least one selected from the group consisting of No. 4, Yellow No. 5, and Blue No. 1 may be used.
  • the water-soluble pigment for example, based on the total weight of the cosmetic composition for lips, may be included in 0.01 to 0.1% by weight, and is preferably 0.01 in terms of implementing the desired color of the cosmetic composition for lips. It is preferable to include from 0.07% to 0.07% by weight.
  • the preservative is not limited thereto as long as it is a commonly used preservative, but phenoxyethanol may be suitably used.
  • the preservative is, for example, based on the total weight of the cosmetic composition for lips, may be included in 0.3 to 0.6% by weight, preferably in terms of maintaining the function of the preservative in the cosmetic composition for lips 0.4 to 0.6% by weight. It is preferably included in 0.5% by weight.
  • the cosmetic composition for lips of the present invention may further include functional additives and components included in general cosmetic compositions.
  • Examples of the functional additive include water-soluble vitamins, oil-soluble vitamins, polymeric peptides, polymeric polysaccharides, sphingolipids and seaweed extracts, and components included in the general cosmetic composition include oil and fat components, moisturizers, emollients, and surfactants. , organic powders, ultraviolet absorbers, preservatives, bactericides, antioxidants, plant extracts, pH adjusters, alcohols, pigments, fragrances, blood circulation promoters, cooling agents, antiperspirants, and the like.
  • cosmetic composition means an article used on the human body to clean and beautify the human body to add charm, brighten the appearance, or maintain or promote the health of skin and hair.
  • the skin includes all skin areas of the body including the face, hands, arms, legs, feet, chest, stomach, back, buttocks and scalp.
  • the lip cosmetic composition may include cosmetic compositions such as lipstick, lip gloss, lip balm, lip tint, and lip pencil.
  • the content ratio of the thickener polyacrylate crosspolymer-6: hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer is different, and the content ratio of the thickener is different.
  • the type and content of cosmetic compositions for lips were prepared and shown in Examples 1 to 3 and Comparative Examples 1 to 4. .
  • the types and contents of other components are pigment (pearl powder) 24.40% by weight, moisturizer (glycerin and butylene glycol) 12.00% by weight, film forming agent (acrylate copolymer) 1.60% by weight, powder (synthetic fluorophore) Pite) 4.00% by weight, water-soluble pigments (Red No. 227 and Red No. 104 (1)) 0.05% by weight, preservative (phenoxyethanol) 0.45% by weight and the balance of purified water.
  • pigment pearl powder
  • moisturizer glycerin and butylene glycol
  • film forming agent acrylate copolymer
  • powder synthetic fluorophore
  • the moisturizing power evaluation of the cosmetic composition for lips prepared by including the blending ratio of the thickener in Table 1 was measured using a skin checker, and the moisturizing power before and after applying the cosmetic compositions for lips to the skin was measured in terms of skin moisture. expressed as (%).
  • the durability evaluation was performed on 20 women in their 20s to 40s, and the cosmetic compositions for lips were applied to the skin for durability: very good: 5 points, good: 4 points, normal: 3 points, bad: 2 points, very bad: evaluated according to the evaluation standard of 1 point.
  • the stability evaluation evaluated the cosmetic composition for lips after 1 month at each temperature with the naked eye.
  • Example 1 0.23% by weight of polyacrylate crosspolymer-6 and 1.17% by weight of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer were included in a ratio of about 1:5, before application and After that, the difference in moisturizing power was 33, and the durability was also confirmed to be the best with 5 points.
  • Example 2 contains 0.42% by weight of polyacrylate crosspolymer-6 and 0.98% by weight of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer at a ratio of about 1:2.3, and the moisturizing power before and after application It can be confirmed that the difference is excellent with 32 points and 4 points for durability. In addition, when compared with Example 1, it was found that the lower the ratio of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer, the lower the moisturizing power and durability.
  • Example 3 0.1% by weight of polyacrylate crosspolymer-6 and 1.3% by weight of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer were included in a ratio of about 1:13, and the moisturizing power before and after application It can be confirmed that the difference is excellent with 32 points and 5 points for durability. In addition, when compared with Example 1, it was found that the significant effect of moisturizing power and durability due to the increase in the ratio of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer did not appear.
  • Comparative Example 1 1.4% by weight of the hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer alone was included, and the difference in moisturizing power before and after application was 18, and the durability was 4 points, compared to the examples. It can be seen that the effect of persistence is reduced. Therefore, it was found that the effect of moisturizing power and durability was increased when polyacrylate crosspolymer-6 and hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer were used together as a thickener.
  • Comparative Example 3 0.7% by weight of polyacrylate crosspolymer-6 and 0.7% by weight of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer were included in a ratio of 1: 1. Difference in moisturizing power before and after application It was confirmed that the effects of moisturizing power and durability were significantly lowered compared to the examples with a score of 13 and durability of 3. Therefore, when comparing Example 2 and Comparative Example 3 including the thickeners at a ratio of 1: 2.3, it was found that the moisturizing effect and durability were excellent when included at a ratio of 1: 2 or more according to the present invention.
  • Comparative Example 4 included 0.08% by weight of polyacrylate crosspolymer-6 and 1.32% by weight of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer at a ratio of 1: 16.5, difference in moisturizing power before and after application It can be seen that the effect of moisturizing power is significantly lowered compared to the examples with a score of 9 and durability of 4 points. Therefore, comparing Example 3 and Comparative Example 4 including the thickeners at a ratio of 1: 13, it was found that the effect of moisturizing power and durability was excellent when included at a ratio of 1: 16 or less according to the present invention.
  • Example 1 to 3 prepared in the ratio range of 1: 2 to 16, which is the ratio of the polyacrylate crosspolymer-6 of the present invention and the hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer , Overall, it was confirmed that the moisturizing power and durability were excellent, and in the case of Example 1 prepared at a ratio of about 1: 5, it was confirmed that it was remarkably excellent.
  • the prepared cosmetic composition for lips was visually evaluated for stability after 1 month at each temperature.
  • Comparative Example 1 contained 1.4% by weight of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer alone, and it was confirmed that it was stable only at room temperature, and Comparative Example 2 was polyacrylate crosspolymer-6 In the case of containing only 1.4% by weight alone, it was confirmed through FIG. 3 that it was unstable at all temperatures, and pearl bands and separation occurred. Therefore, it was found that when the polyacrylate crosspolymer-6 and the hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer were used together as a thickener, the formulation was stable without being affected by any temperature or temperature change.
  • Comparative Example 3 includes 0.7% by weight of polyacrylate crosspolymer-6 and 0.7% by weight of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer in a ratio of 1: 1, at room temperature, low temperature and in cycles. Although it has a stable formulation, it can be confirmed that it is unstable at high temperatures, and it can be confirmed through FIG. 4 that separation occurs at high temperatures. Therefore, when comparing Comparative Example 3 with Examples, it was found that a stable formulation can be formed even at high temperatures when the ratio of 1: 2 or more according to the present invention is included.
  • Comparative Example 4 includes 0.08% by weight of polyacrylate crosspolymer-6 and 1.32% by weight of hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer at a ratio of 1: 16.5, at room temperature, high temperature and low temperature. Although it had a stable formulation, it was confirmed that it was unstable in CYCLE, and it was found through FIG. 5 that pearl bands occurred. Therefore, comparing Comparative Example 4 with Examples, it can be seen that the stability of the formulation is excellent when the ratio according to the present invention is 1: 16 or less, and when the ratio exceeds the range of 1: 16, a change in temperature occurs. It was found that the formulation was unstable and pearl bands occurred in the cycle.
  • Example 1 As shown in Table 5, in Example 1, the difference in moisturizing power before and after application was 33 and the durability was 5 points, whereas in Comparative Examples 5 to 8, the difference in moisturizing power before and after application was all 20 or less, and the durability was 3 points or less. there was.
  • Comparative Example 5 when polyacrylate crosspolymer-11 was used, the difference in moisturizing power before and after application was 13, and the durability was 3 points. was found to be remarkably low.
  • the thickener of the present invention polyacrylate crosspolymer-6 and hydroxyethyl acrylate/sodium acryloyldimethyltaurate copolymer, had excellent moisturizing power and durability.

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Abstract

La présente invention concerne une composition cosmétique pour lèvres comprenant une grande quantité de perle. En particulier, comme la composition cosmétique pour lèvres selon la présente invention comprend un épaississant contenant au moins un polymère réticulé de polyacrylate-6 et un copolymère d'acrylate d'hydroxyéthyle/acryloyldiméthyltaurate de sodium, la composition cosmétique a pour effets une excellente tenue et un excellent pouvoir hydratant tout en stabilisant la perle. De plus, la composition cosmétique pour lèvres de la présente invention maintient une formulation stable, sans séparation de la formulation, non seulement à température ambiante mais également dans divers environnements.
PCT/KR2022/013141 2021-12-15 2022-09-01 Composition cosmétique pour lèvres comprenant une grande quantité de perle WO2023113147A1 (fr)

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KR102436827B1 (ko) * 2021-12-15 2022-08-26 한국콜마주식회사 다량의 펄을 포함하는 입술용 화장료 조성물
KR102624282B1 (ko) * 2023-02-03 2024-01-15 주식회사 투슬래시포 흑색도 또는 청색도 향상용 조성물을 포함하는, 화장품

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KR20170064596A (ko) * 2015-12-01 2017-06-12 코스맥스 주식회사 수분산 타입 메이크업 화장료 조성물
KR20200102915A (ko) * 2017-12-22 2020-09-01 엘브이엠에이취 러쉐르쉐 입술 메이크업 및 관리용 수중유 에멀젼
KR20210032142A (ko) * 2019-09-16 2021-03-24 (주)아모레퍼시픽 가용화된 안료를 포함하는 화장료 조성물 및 이의 제조방법
KR102436827B1 (ko) * 2021-12-15 2022-08-26 한국콜마주식회사 다량의 펄을 포함하는 입술용 화장료 조성물

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