WO2020235752A1 - Composition cosmétique de mascara ayant une résistance de maquillage améliorée - Google Patents
Composition cosmétique de mascara ayant une résistance de maquillage améliorée Download PDFInfo
- Publication number
- WO2020235752A1 WO2020235752A1 PCT/KR2019/012902 KR2019012902W WO2020235752A1 WO 2020235752 A1 WO2020235752 A1 WO 2020235752A1 KR 2019012902 W KR2019012902 W KR 2019012902W WO 2020235752 A1 WO2020235752 A1 WO 2020235752A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cosmetic composition
- amodimethicone
- mascara
- trimethylsiloxysilicate
- mascara cosmetic
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
Definitions
- the present invention relates to a mascara cosmetic composition with improved makeup persistence, and more specifically, to a mascara cosmetic composition comprising trimethylsiloxysilicate and amodimethicone, which improves cleansing effect and curling retention while suppressing smear will be.
- the initial mascara was a solid mixture of sodium stearate and carbon black, and was applied with a brush soaked in water. It is a form of emulsifying by mixing vegetable ester-based wax or hydrocarbon-based wax with a highly safe polymer with appropriate plasticity. This is because the emulsified mascara is much more advantageous in giving the original functions of the mascara such as volume, curling power, and persistence.
- lashes In addition, consumers who want longer and thicker lashes have traditionally resorted to the use of artificial lashes, which are applied using an adhesive to the original lashes, or expensive lash extensions.
- a variety of mascara products were popular. Nonetheless, some eyelashes are too thin for any type of volume mascara to make it look more dramatic.
- women with thin lashes may want more intense results than their desired cosmetic effect using their favorite mascara.
- the expected features of a mascara product include the ability to darken, thicken, and lengthen lashes, with lashes that do not clump or fall off and have a richer appearance. It is also desirable that the product is water- and/or smear-resistant, but not difficult to remove.
- the cosmetics industry has responded to this need by providing mascara compositions containing fibers, waxes and/or bulking or filler agents; There is a limit to the amount of these ingredients that can be added to the formulation without reducing the processability of the formulation, or interfering with both loading the product on the brush and the delivery of the product from the brush to the eyelashes.
- cosmetic compositions that will better adhere to eyelashes and eyebrows.
- the mascara cosmetic composition of the present invention has high adhesion to keratin fibers (eyelashes/hair) and forms a uniform surface, has high curling retention, and It was confirmed that the effect of less bleeding was excellent, and the present invention was completed.
- One object of the present invention is to provide a cosmetic composition with improved curling retention and bleeding. Specifically, it is to provide a mascara cosmetic composition comprising trimethylsiloxysilicate and amodimethicone as active ingredients.
- the mascara cosmetic composition according to the present invention has high adhesion to keratin fibers (eyelashes/hair) and forms a uniform surface, has high curling retention power, has a low clumping and bleeding effect, and can also provide ease of cleansing, etc. have.
- FIG. 3 is a table and a photograph showing the curling reduction rate of Experimental Example 3, the spreading area of Experimental Examples 1 to 3, the spreading intensity, formulation stability, and spreading by artificial sebum.
- FIG. 4 is a photograph and table showing the spreading of a cosmetic composition prepared with trimethylsilocysilicate and amodimethicone at various mixing ratios.
- the present invention provides a mascara cosmetic composition comprising trimethylsiloxysilicate and amodimethicone as active ingredients.
- a cosmetic composition that improves clumping and bleeding after applying a mascara product, that is, improves curling retention to eyelashes and eyebrows while suppressing metastasis, thereby providing an effect of improving adhesion.
- trimethylsiloxysilicate and amodimethicone which are active ingredients of the mascara cosmetic composition, may serve as a coating agent.
- trimethylsiloxysilicate or/and rosin acid-based resin which is a kind of silicone
- the improvement of bleeding due to oil was not satisfactory.
- the mascara falls in powder form under the eyes because it is sticky in the feeling of use or the film is easily crushed after drying, and there is a limitation in that the drying speed is slow or difficulties in cleaning when the material is used excessively.
- by simultaneously including trimethylsiloxysilicate and amodimethicone as active ingredients it is possible to have resistance to oil as an amine group having hydrophilicity of amodimethicone, so that makeup persistence and spreading improvement effect can be provided. .
- the conventional mascara cosmetic composition used an electrostatic force to increase eyelash adhesion.
- Cationic polymer and binding polymer are used in anionic eyelashes to improve the adhesion of powder to maximize the volume and makeup effect of eyelashes.
- the present invention simultaneously contains trimethylsiloxysilicate and amodimethicone as active ingredients, so that the amine group of amodimethicone, which is a nonvolatile oil, is a keratin material, that is, ⁇ ionic attraction'' on the weakly acidic surface of the eyelash.
- the present invention can obtain a cosmetic composition having improved oil resistance, sebum resistance, and adhesion to eyelashes by simultaneously including trimethylsiloxysilicate and amodimethicone as active ingredients.
- Trimethylsiloxysilicate an oily coating agent used in the above conditions, is not limited thereto, and may be a coating agent (polymer/resin) derived from polydimethylsiloxane, and a polydimethylsiloxane-based coating agent (polymer/resin) and It does not matter if it is mixed and used.
- acrylate/dimethicone copolymer acrylate/polymethylsiloxymethacrylate copolymer (ACRYLATES/POLYTRIMETHYLSILOXYMETHACRYLATE COPOLYMER), dimethicone/silsequioxane copolymer (dimethicone/silsequioxane copolymer) ), trimethylsiloxysilicate (TRIMETHYLSILOXYSILICATE) (and) polypropylsilsesquioxane (POLYPROPYLSILSESQUIOXANE), acrylate/dimethicone copolymer (ACRYLATES/DIMETHICONE COPOLYMER), bis-vinyldimethicone/dimethicone copolymer C24-28 Alkyldimethyl siloxy trimethyl siloxy silicate (BIS-VINYL DIMETHICONE/DIMETHICONE COPOLYMER C24-28 Alkyldimethyl
- the coating properties may be weak, so that the coating agent may not be formed on the eyelashes, and when the content is high, it may not be easily erased, which may cause difficulties in cleansing.
- amodimethicone is not limited thereto, and an amodimethicone derivative may also be included, and it may be mixed and used.
- Acetamidoamodimethicone Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer, Amodimethicone Glycerocarbamate , Amodimethicone Hydroxystearate, Amodimethicone/Morpolysylmethylsilsesquioxane Copolymer, Amodimethicone/Morpholinomethyl Silsesquioxane Copolymer, Amodimethicone/Silsesquioxane Copolymer (Amodimethicone /Silsesquioxane Copolymer), bis-butyloxydimethicone/PEG-60 copolymer (Bis-Butyloxyamodimethicone/PEG-60 Copolymer), bis (C13-15 alkoxy)
- the trimethylsiloxysilicate and amodimethicone can achieve the object of the present invention through mixed use, but specifically, the effect can be maximized according to each weight ratio.
- trimethylsiloxysilicate and amodimethicone in the mascara cosmetic composition are not limited thereto, but may be included in a ratio of 95:5 to 70:30 (w/w). More specifically, it may be a 94:6 to 80:20 ratio (w/w), or a 93:7 to 85:15 ratio (w/w), and in one embodiment of the present invention, the weight ratio of 10:2 Experiments were conducted, and in other examples, it was confirmed that the spreading was most remarkably reduced at 85:15 (w/w).
- ISODODECANE as a solvent
- CERESIN as a wax
- MICROCRYSTALLINE WAX hydrogenated polycyclopentadiene
- POLYETHYLENE polyethylene
- COPERNICIA CERIFERA (CARNAUBA) WAX
- TOCOPHEROL Candelilla wax
- EUPHORBIA CERIFERA CANDELILLA
- PARAFFIN paraffin wax
- BEESWAX beeswax
- SYNTHETIC WAX synthetic waxes
- the solvent is one component that may be included in the mascara cosmetic composition of the present invention, but is not limited thereto, but may include oil having good volatility such as isododecane, isohexadecane, cyclopentasiloxane or dimethicone. Since the solvent is a volatile solvent, it may help to dry after applying mascara.
- the solvent may be 30 to 80% by weight based on the total weight.
- the wax is one component that may be included in the mascara cosmetic composition of the present invention, but is not limited thereto, but paraffin wax, ceresin, microcrystalline wax, hydrogenated polycyclopentadiene, polyethylene, carnauba wax, canda It may contain a hydro-based or ester-based wax, such as rela wax.
- the wax holds the formulation of the cosmetic composition and can affect the presentation of the cosmetic effect. In addition, it is possible to facilitate the toilet paper speed and feeling of use.
- the wax may be 5 to 30% by weight based on the total weight.
- the preservative is one component that may be included in the mascara cosmetic composition of the present invention, but is not limited thereto, but may include capryl glycol or ethyl hexyl glycol.
- the preservative is blended in the mascara cosmetic composition of the present invention to inhibit the proliferation of microorganisms contaminating the cosmetic product from the outside, thereby preventing product change.
- the preservative may be 0.01 to 1% by weight based on the total weight.
- the thickener is a component that can be included in the mascara cosmetic composition of the present invention, but is not limited thereto, but hydrogenated styrene/isoprene copolymer, dextrin palmitate/ethylhexanoate, polyamides, etc. Can include.
- the thickener can provide a low viscosity so that the contents do not flow on the skin, making it easier to use and to facilitate the feeling of use.
- the thickener may be 1 to 15% by weight based on the total weight.
- the defoaming agent is one component that may be included in the mascara cosmetic composition of the present invention, but is not limited thereto, but may include simethicone.
- the defoaming agent may act as a foam defoaming agent to allow the foam to be fused by changing the surface tension of the foam.
- the defoaming agent may be 0.01 to 1% by weight based on the total weight.
- the powder is a component that may be included in the mascara cosmetic composition of the present invention, but is not limited thereto, but may include methyl methacrylate crosspolymer as a spherical powder, talc or dimethicone as a plate powder.
- the spheroid powder can provide a soft feeling of use, and the plate powder can facilitate adhesion to the eyelashes.
- the weight of the spherical powder may be 0.1% to 5% by weight, and the plate-like powder may be 0.1% to 20% by weight.
- the mascara cosmetic composition of the present invention may further include ingredients contained in a conventional mascara composition such as nutrients, antioxidants, and pigments within a range that does not impair the effect of increasing curling retention and improving bleeding.
- the raw materials 1 to 6 in Table 1 were completely dissolved at 85°C, and then the 7 raw materials in Table 1 were added and completely dispersed. Thereafter, the raw materials 8 to 11 were sequentially added and then degassed and cooled.
- Example 1 Confirmation of mascara eyelash adhesion
- the weight change after external friction by applying Experimental Examples 1 and 3 prepared in the above Preparation Example to the hair And to check the surface damage.
- the specific experimental method is as follows.
- Experimental Example 2 prepared by the above Preparation Example contained only amodimethicone as an active ingredient, and the formulation was unstable due to stickiness and agglomeration of the samples, so the experiment was excluded from the final experiment.
- the mascara cosmetic composition of the present invention including both trimethylsiloxysilicate and amodimethicone as active ingredients has an effect of increasing adhesion to eyebrows and eyelashes.
- the mascara cosmetic composition of Experimental Example 3 prepared in Preparation Example 3 was applied to the nylon fiber, and the rate of change at a certain angle of the nylon fiber was to be checked.
- the specific experimental method is as follows.
- the mascara cosmetic composition of Experimental Example 3 was applied the same number of times, and 6 hours later, the angle change of the nylon fiber was measured.
- the mascara cosmetic composition of the present invention including both trimethylsiloxysilicate and amodimethicone as active ingredients, has a curling maintenance effect.
- the mascara cosmetic composition of Experimental Examples 1 to 3 prepared in the above Preparation Example was applied on the glass, and the bleeding property was checked after repeated movement with artificial sebum.
- the specific experimental method is as follows.
- Experimental Example 3 containing trimethylsiloxysilicate and amodimethicone at the same time was more than Experimental Example 1 including trimethylsiloxysilicate alone and Experimental Example 2 including amodimethicone alone. It was confirmed that the area of bleeding by artificial sebum was the smallest and the bleeding intensity was also the best (FIG. 3).
- the mascara cosmetic composition of the present invention including both trimethylsiloxysilicate and amodimethicone as active ingredients, has an effect of solving the problem of spreading under the eyes.
- Experimental Example 2 prepared according to Preparation Example contained only amodimethicone as an active ingredient, and was excluded from the experiment because the formulation was unstable due to stickiness and agglomeration of the sample.
- the mascara cosmetic composition of the present invention including both trimethylsiloxysilicate and amodimethicone as active ingredients has improved makeup persistence and excellent makeup effect.
- Example 5 Trimethylmethoxysilicate and amodimethicone mixture ratio test for the improvement of smearing effect
- the ratio of trimethylsiloxysilicate and amodimethicone was added and dissolved in various ratios as shown in FIG. 4 to prepare a cosmetic composition.
- the ratio of the mascara cosmetic composition of the present invention including both trimethylsiloxysilicate and amodimethicone of the present invention as an active ingredient has the best effect of improving bleeding at a ratio of about 95:5 to 75:25. .
- the mascara cosmetic composition of the present invention which contains both the trimethylsiloxysilicate and amodimethicone of the present invention as active ingredients, has the effect of improving by reducing smearing and improving curling retention and reducing aggregation. have.
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Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201980096320.2A CN113811285A (zh) | 2019-05-17 | 2019-10-02 | 化妆持久力得到改善的睫毛膏化妆料组合物 |
JP2021568345A JP2022533356A (ja) | 2019-05-17 | 2019-10-02 | 化粧持続力が改善されたマスカラ化粧料組成物 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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KR10-2019-0058254 | 2019-05-17 | ||
KR1020190058254A KR102350105B1 (ko) | 2019-05-17 | 2019-05-17 | 화장 지속력이 개선된 마스카라 화장료 조성물 |
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WO2020235752A1 true WO2020235752A1 (fr) | 2020-11-26 |
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Application Number | Title | Priority Date | Filing Date |
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PCT/KR2019/012902 WO2020235752A1 (fr) | 2019-05-17 | 2019-10-02 | Composition cosmétique de mascara ayant une résistance de maquillage améliorée |
Country Status (4)
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JP (1) | JP2022533356A (fr) |
KR (1) | KR102350105B1 (fr) |
CN (1) | CN113811285A (fr) |
WO (1) | WO2020235752A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024091736A3 (fr) * | 2022-10-26 | 2024-06-06 | Revlon Consumer Products Llc | Compositions cosmétiques colorées sans-craquement à long terme |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN116473876B (zh) * | 2022-11-25 | 2023-12-05 | 宁波爱诗化妆品有限公司 | 一种油性眼线液及其制备方法和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050265941A1 (en) * | 2002-09-12 | 2005-12-01 | Mateu Juan R | Water-resistant mascara composition having a high water content |
US20110008401A1 (en) * | 2008-03-04 | 2011-01-13 | Avon Products, Inc. | Cosmetic Compositions For Imparting Superhydrophobic Films |
KR20150108193A (ko) * | 2014-03-17 | 2015-09-25 | 주식회사 엘지생활건강 | 겔 타입의 아이라이너 조성물 |
US20170135946A1 (en) * | 2015-11-17 | 2017-05-18 | Avon Products, Inc. | Moldable Composition for Keratin Fibers |
KR20180067726A (ko) * | 2015-11-17 | 2018-06-20 | 이엘씨 매니지먼트 엘엘씨 | 마스카라 조성물 및 방법 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100513617B1 (ko) | 2004-05-21 | 2005-09-09 | 주식회사 태평양 | 마스카라 조성물 |
-
2019
- 2019-05-17 KR KR1020190058254A patent/KR102350105B1/ko active IP Right Grant
- 2019-10-02 WO PCT/KR2019/012902 patent/WO2020235752A1/fr active Application Filing
- 2019-10-02 JP JP2021568345A patent/JP2022533356A/ja active Pending
- 2019-10-02 CN CN201980096320.2A patent/CN113811285A/zh active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050265941A1 (en) * | 2002-09-12 | 2005-12-01 | Mateu Juan R | Water-resistant mascara composition having a high water content |
US20110008401A1 (en) * | 2008-03-04 | 2011-01-13 | Avon Products, Inc. | Cosmetic Compositions For Imparting Superhydrophobic Films |
KR20150108193A (ko) * | 2014-03-17 | 2015-09-25 | 주식회사 엘지생활건강 | 겔 타입의 아이라이너 조성물 |
US20170135946A1 (en) * | 2015-11-17 | 2017-05-18 | Avon Products, Inc. | Moldable Composition for Keratin Fibers |
KR20180067726A (ko) * | 2015-11-17 | 2018-06-20 | 이엘씨 매니지먼트 엘엘씨 | 마스카라 조성물 및 방법 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024091736A3 (fr) * | 2022-10-26 | 2024-06-06 | Revlon Consumer Products Llc | Compositions cosmétiques colorées sans-craquement à long terme |
Also Published As
Publication number | Publication date |
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JP2022533356A (ja) | 2022-07-22 |
KR20200132547A (ko) | 2020-11-25 |
KR102350105B1 (ko) | 2022-01-11 |
CN113811285A (zh) | 2021-12-17 |
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