WO2023075149A1 - Composition cosmétique eau dans l'huile sans émulsifiant - Google Patents

Composition cosmétique eau dans l'huile sans émulsifiant Download PDF

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Publication number
WO2023075149A1
WO2023075149A1 PCT/KR2022/014020 KR2022014020W WO2023075149A1 WO 2023075149 A1 WO2023075149 A1 WO 2023075149A1 KR 2022014020 W KR2022014020 W KR 2022014020W WO 2023075149 A1 WO2023075149 A1 WO 2023075149A1
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WO
WIPO (PCT)
Prior art keywords
cosmetic composition
wax
inorganic powder
titanium dioxide
oil
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PCT/KR2022/014020
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English (en)
Korean (ko)
Inventor
김성욱
권하나
최경호
Original Assignee
화성코스메틱 주식회사
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Publication of WO2023075149A1 publication Critical patent/WO2023075149A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/0229—Sticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/61—Surface treated
    • A61K2800/62—Coated

Definitions

  • the present invention relates to an emulsifier-free water-in-oil cosmetic composition, and more specifically, to a water-in-oil cosmetic composition in which an emulsified formulation is implemented using inorganic powder instead of an emulsifier and formulated into a solid by adding wax.
  • W/O cosmetics have the advantage that they are not easily erased by water and sweat and have excellent durability. Regardless, it is used in various cosmetics.
  • Pickering emulsification technology has appeared to solve the problem of these emulsifiers.
  • Pickering emulsification means stabilizing the interface by using inorganic powder instead of emulsifier.
  • Using Pickering emulsification technology it is possible to stably implement an emulsified formulation without using an emulsifier.
  • Pickering emulsification technology lacks formulation stability compared to general emulsifiers, when applied to solid cosmetics, the solid formulation is not properly maintained, making it difficult to commercialize. Therefore, Pickering emulsification technology is generally used for the production of liquid formulations, and it is difficult to develop a technology that combines the excellent feeling of use of Pickering emulsification technology with solid cosmetics.
  • the present invention is to solve the above problems, to provide a water-in-oil cosmetic composition that stably implements a water-in-oil formulation without containing an emulsifier, and at the same time stably forms a solid state by wax and has an excellent feeling of use. for that purpose
  • a water-in-oil (W/O) cosmetic composition is provided.
  • the cosmetic composition oil phase (Oil phase); Water phase; and an inorganic powder emulsifying the oil phase and the aqueous phase, wherein the oil phase includes wax and may be formulated as a solid.
  • the inorganic powder is titanium dioxide, zinc oxide, silica, diatomaceous earth, zeolite, montmorillonite, kaolinite, bentonite, binchotan, coconut charcoal, bamboo charcoal. It may include at least one of hard charcoal, activated carbon, graphite, graphene, carbon, sunjit, fullerene, elvan, volcanic clusters, clay, white clay, kaolin, sericite, muscovite, phlogopite, biotite, mica, illite, and tourmaline. .
  • the inorganic powder is a composite powder in which titanium dioxide or zinc oxide is coated with a hydrophobic material, and the composite powder is titanium dioxide or zinc oxide, silica, glycerin, triethoxycaprylylsilane, aluminum hydroxide, At least one of alumina, aluminum stearate, stearic acid, dimethicone, methicone, and hydrogendimethicone may be coated.
  • the inorganic powder may be at least one of titanium dioxide/alumina/stearic acid and zinc oxide/triethoxycaprylyl selenium.
  • the inorganic powder may be included in an amount of 2 to 10% by weight based on the total weight of the composition.
  • the wax is one selected from the group consisting of polyethylene wax, synthetic candelilla wax, candelilla wax, carnauba wax, beeswax, synthetic beeswax, microcrystalline wax, ozokerite, multi-wax, and paraffin wax. may contain more than
  • the wax may be included in an amount of 10 to 18% by weight based on the total weight of the composition.
  • the cosmetic composition may have a cutting hardness of 80 to 290 gf/mm 2 .
  • the cosmetic composition may be formulated in a stick type.
  • the cosmetic composition of the present invention does not contain an emulsifier, it can impart a refreshing and refreshing feeling of use, and has excellent water resistance and excellent makeup lasting effect.
  • the present invention is a water-in-oil (W/O) cosmetic composition, comprising: an oil phase; Water phase; and an inorganic powder that emulsifies the oil phase and the water phase.
  • W/O water-in-oil
  • the oil phase dissolves the hydrophobic component and can adjust the overall viscosity, spreadability, and adhesion of the cosmetic composition.
  • the oil phase may be included in an amount of 20 to 60% by weight based on the total weight of the composition. However, it is not limited thereto. When the oil phase is included in less than 20% by weight or more than 60% by weight, a water-in-oil formulation may not be stably formed.
  • the wax is selected from the group consisting of polyethylene wax, synthetic candelilla wax, candelilla wax, carnauba wax, beeswax, synthetic beeswax, microcrystalline wax, ozokerite, multiwax and paraffin wax
  • polyethylene wax and synthetic candelilla wax may be included.
  • the cosmetic composition of the present invention can stably implement and maintain a solid formulation, and at the same time, it is possible to maintain a refreshing feeling unique to Pickering oil.
  • the wax may be included in an amount of 10 to 18% by weight based on the total weight of the composition.
  • the wax is included in an amount of less than 10% by weight, a solid formulation may not be properly formed and the formulation may not be stably maintained.
  • the wax is included in an amount of more than 18% by weight, the hardness is excessively high, and spreadability and thickness are excessively reduced during application, and thus the feeling of use may be deteriorated.
  • the oil phase may further include at least one of a skin conditioning agent and a spherical powder.
  • the skin conditioning agent can implement a fresh feeling of use in the cosmetic composition.
  • the spherical powder allows the cosmetic composition to be gently rolled and applied when applied, and can improve sebum adsorption.
  • the skin conditioning agent is diphenylsiloxyphenyltrimethicone, cyclopentasiloxane, lauroyl lysine, dibutylethylhexanoylglutamide, dibutyllauroylglutamide, disodium stearo It may include at least one selected from the group consisting of monoglutamate and hydrogenated lecithin.
  • the spherical powder is silica, methyl methacrylate crosspolymer, nylon-12, polymethyl methacrylate, polymethylsilsesquioxane, HDI / trimethylolhexyllactone crosspolymer, polymethyl methacrylate - It may include at least one selected from the group consisting of HDI/trimethylolhexyllactone crosspolymer and ethylene-acrylic acid copolymer. However, it is not limited thereto.
  • the aqueous phase may be included in an amount of 30 to 70% by weight based on the total weight of the composition. However, it is not limited thereto. When the aqueous phase is included in less than 30% by weight or more than 70% by weight, a water-in-oil formulation may not be stably formed.
  • the aqueous phase may include at least one of a moisturizing agent, an antiseptic agent, and a thickening agent.
  • a moisturizing agent for example, at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol, dipropylene glycol, sorbitol, and betaine may be used.
  • sodium dehydroacetate, clophenesin, o-cymen-5-ol, capryloylglycine, caprylhydroxyamic acid, hydroxyacetophenone, 1,2-hexanedi At least one selected from the group consisting of ol, 1,3-propanediol, potassium benzoate, phenoxyethanol, methylparaben, and clophenesin may be used.
  • water-soluble polymers more specifically, plant-based polymers, microbial-based polymers, animal-based polymers, starch-based polymers, arginic acid-based polymers, vinyl-based polymers, polyoxyethylene-based polymers, polyoxyethylene polyoxy At least one selected from the group consisting of a propylene copolymer-based polymer, an acryl-based polymer, and an inorganic water-soluble polymer may be used, and a carbomer may be preferably used. However, it is not limited thereto.
  • the inorganic powder is for emulsifying the oil phase and the water phase, and for example, the oil phase and the water phase can be emulsified using Pickering emulsification technology.
  • Pickering Emulsion technology refers to a technology in which an interface is stabilized by using inorganic powder instead of an emulsifier.
  • an emulsified formulation can be stably implemented without using an emulsifier.
  • the present invention can stably implement a water-in-oil (W/O) formulation without including an emulsifier through Pickering emulsification using inorganic powder, for example, titanium dioxide (TiO 2 ) powder. .
  • the inorganic powder is titanium dioxide, zinc oxide, silica, diatomaceous earth, zeolite, montmorillonite, kaolinite, bentonite, binchotan, coconut charcoal, bamboo charcoal.
  • At least one selected from the group consisting of charcoal, activated carbon, graphite, graphene, carbon, sunjit, fullerene, elvan, volcanic clusters, clay, white clay, kaolin, sericite, muscovite, phlogopite, biotite, mica, illite and tourmaline may contain substances. However, it is not limited thereto.
  • the inorganic powder may be a composite powder coated with a hydrophobic material on titanium dioxide or zinc oxide.
  • the composite powder is silica, glycerin, triethoxycaprylylsilane, aluminum hydroxide, alumina, aluminum stearate, stearic acid, dimethicone, methicone and hydrogen dimethicone in titanium dioxide or zinc oxide At least one material may be coated.
  • the inorganic powder may be at least one of titanium dioxide/alumina/stearic acid and zinc oxide/triethoxycaprylylselein.
  • the composite powder coated with a hydrophobic material on titanium dioxide or zinc oxide can stably implement and maintain a solid formulation when mixed with wax, and at the same time maintain a refreshing feeling unique to Pickering oil painting. However, it is not limited thereto.
  • the inorganic powder may be included in 2 to 10% by weight, preferably 2 to 7% by weight, based on the total weight of the composition.
  • the inorganic powder When the inorganic powder is included in an amount of less than 2% by weight, a solid formulation may not be stably formed, and formulation stability may be deteriorated at high temperatures.
  • the inorganic powder When the inorganic powder is included in an amount of more than 10% by weight, the hardness is excessively high, and thus spreadability and a feeling of thickness are excessively reduced during application, and thus the feeling of use may be deteriorated.
  • it is not limited thereto.
  • the inorganic powder may have a particle size of 10 to 100 nm. If the inorganic powder has a particle size of less than 10 nm, the cohesive force is very large, and it is difficult to agglomerate and it is difficult to exist uniformly, which can hinder stabilization. Since it is formed, it does not make the interface hard and does not properly perform its role as an emulsifier, but is not limited thereto.
  • the cosmetic composition is a conventional cosmetic composition such as oil, powder, thickener, pigment, film former, nutrient, volatile solubilizer, antioxidant, preservative, and fragrance within the range that does not impair the effect of the present invention.
  • Other active ingredients contained in may be further included. However, it is not limited thereto.
  • the cosmetic composition may have a cutting hardness of 80 to 290 gf/mm 2 .
  • the cutting hardness may be measured by filling a cosmetic composition with a diameter of 18 ⁇ container using a line rheometer (SUN, RHEOMETER; CR-100D) according to the method provided in the device manual.
  • SUN line rheometer
  • the cut hardness of the cosmetic composition is less than 80 gf/mm 2 , the solid formulation may not be stably implemented and maintained.
  • the cut hardness of the cosmetic composition exceeds 290 gf/mm 2 , spreadability and thickness during application are excessively reduced, resulting in a lack of feeling of use.
  • the cosmetic composition according to an embodiment of the present invention may be formulated into a solid.
  • a 'solid' dosage form is meant to include not only a solid type dosage form in which the dosage form is hard and hard, but also a semi-solid type dosage form to the extent that the dosage form is soft or does not have fluidity.
  • it can be formulated into a balm, cream, ointment, gel type, etc.
  • the cosmetic composition may be formulated into a stick type.
  • the stick form means a formulation in the form of a long rod.
  • the user can simply rotate the bottom of the stick-type cosmetic container to expose the solid cosmetic composition to the top, and then apply the cosmetic composition to the skin.
  • the cosmetic composition when it is a night formulation, it can be applied to the skin while being melted by skin temperature.
  • These stick-type formulations can be applied to the skin without applying cosmetics to the hands, enabling hygienic use, and are easy and convenient to use because they can be used without using or carrying a separate cosmetic tool.
  • the cosmetic composition of the present invention has the advantage of being able to provide convenience of use by being able to be molded into a solid stick formulation while having a refreshing feeling of use and excellent emulsion stability, which are characteristics of Pickering emulsion. However, it is not limited thereto.
  • the cosmetic composition may be a cosmetic composition for sunscreen.
  • the cosmetic composition may be formulated into a sun lotion, sun cream, sun milk, sun gel, sun spray, sun mist, or sun stick, and preferably into a sun stick.
  • it is not limited to this, and in addition to this, it is formulated into not only makeup products such as lip balm, blush, shading, highlighter, lipstick, makeup base, foundation, pact, concealer and skin cover, but also basic products such as toner and lotion. It can be.
  • the cosmetic composition of the present invention can be prepared through the following method. First, the oil phase and the inorganic powder may be heated and mixed, and the water phase may be heated and mixed. At this time, the oil phase may be warmed and mixed at a temperature of 80 to 90 ° C, and the water phase may be warmed and mixed at a temperature of 70 to 80 ° C. Thereafter, the aqueous phase is gradually added to the mixture of the oil phase and the inorganic powder, and the oil phase and the aqueous phase can be emulsified through Pickering emulsification. However, it is not limited thereto, and all known methods for preparing a water-in-oil cosmetic composition may be applied.
  • compositions according to the present invention were prepared using the ingredients listed in Table 1 below.
  • the unit of Table 1 component content is % by weight.
  • Examples 1 to 3 are cosmetic compositions in which the content of wax was changed within the scope of the examples of the present invention
  • Examples 4 to 7 are cosmetic compositions in which the content of titanium dioxide/alumina/stearic acid was changed within the scope of the examples of the present invention.
  • Compositions, Examples 8 to 12 are cosmetic compositions in which the content of zinc oxide/triethoxycaprylylsilane is changed within the scope of the examples of the present invention
  • Example 13 is a wax using ozokerite instead of polyethylene wax. It is the cosmetic composition used.
  • the oil phase and the inorganic powder are homogenized while heating to a temperature of 80 to 90 ° C, and the aqueous phase is homogenized while warming to a temperature of 70 to 80 ° C, and then the aqueous phase is gradually added to the mixture of the oil phase and the inorganic powder Examples 1 to 13 were prepared.
  • Comparative examples of cosmetic compositions according to the present invention were prepared using the ingredients listed in Table 2 below.
  • Comparative Examples 1 to 5 are cosmetic compositions in which the content of wax was changed outside the range of the examples of the present invention
  • Comparative Examples 6 to 9 are cosmetic compositions in which the content of titanium dioxide/alumina/stearic acid was changed outside the range of the examples of the present invention.
  • composition, and Comparative Examples 10 and 11 are cosmetic compositions using bentonite and carbon black instead of titanium dioxide/alumina/stearic acid as inorganic powder, respectively.
  • the specific manufacturing method is the same as in Examples 1 to 13.
  • Water-in-oil stick-type cosmetics were prepared using the compositions according to Examples 1 to 13 and Comparative Examples 1 to 11, and left at room temperature (23 ° C), 4 ° C, 37 ° C, and 45 ° C for 1 week to 1 month. After that, the separation state was visually evaluated and shown in Table 3, and the cutting hardness was measured using a line rheometer (SUN, RHEOMETER; CR-100D) according to the method provided in the machine manual and shown in Table 3. At this time, the stick-type cosmetics were measured by filling in a container with a diameter of 18 ⁇ . The unit of cut hardness in Table 3 is gf/mm 2 .
  • FIGS. 1a to 1c Representatively, cosmetics manufactured using the composition according to Comparative Example 3 are shown in FIGS. 1a to 1c, and cosmetics manufactured using the composition according to Comparative Example 9 are shown in FIG. 2 .
  • Examples 1 to 13 had a cutting hardness of 80 gf / mm 2 or more, which is a cutting hardness for stably forming a solid dosage form, and it was confirmed that the dosage form was stably maintained without separation.
  • Comparative Examples 1 and 2 having a high wax content the formulation itself was stably formed, but the cutting hardness was too high at 450 and 440, so as to be seen in Experimental Example 2, spreadability and thickness during application were excessively reduced.
  • Comparative Examples 3 and 4 with low wax content and Comparative Example 5 without wax the solid formulation was not stably formed, and the surface was dented or turned off.
  • Water-in-oil stick-type cosmetics were prepared using the compositions according to Examples 1 to 13 and Comparative Examples 1 to 11, and sensory evaluation was conducted on 20 women in their 20s to 40s, and the results are shown in Table 4. Comparative Examples 3 to 5 in which formulation molding was impossible, Comparative Examples 8 and 9 with very low formulation stability, and Comparative Examples 10 and 11 in which emulsification was not achieved were excluded from the evaluation.
  • the specific evaluation method is as follows. Samples of Examples and Comparative Examples were taken at 2 mg/cm 2 each , and applied to the back of the hand of the measurer in a width of 4 cm and a length of 4 cm as usual, and then the feeling of the evaluation item was evaluated in 10 steps as an evaluation scale, and the score was given on a scale of 10 on a scale of 1 according to each stage. The feeling of use was evaluated by excluding the deviation after obtaining the average value by summing the total scores.
  • Water-in-oil type stick-type cosmetics were prepared using the compositions according to Examples 1 to 13 and Comparative Examples 1 to 11, and water resistance was evaluated, and the results are shown in Table 5. Comparative Examples 10 and 11 in which emulsification was not performed were excluded from the evaluation.
  • the specific evaluation method is as follows. 50 mg each of the samples of Examples and Comparative Examples was evenly applied to a PMMA (Polymethyl Methacrylate) plate having a width of 5 cm and a length of 5 cm, and after air drying for 60 minutes, the weight of the plate was measured. Then, after obtaining the plate in purified water for 20 minutes, it is left outside the water for 20 minutes to dry naturally. After repeating the above procedure three times, the plate is naturally dried for 30 minutes, and then the weight loss is measured.
  • PMMA Polymethyl Methacrylate

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Selon un mode de réalisation de la présente invention, l'invention concerne une composition cosmétique eau dans l'huile (E/H). La composition cosmétique comprend : une phase huileuse ; une phase aqueuse ; et une poudre inorganique qui émulsifie la phase huileuse et la phase aqueuse, la phase huileuse pouvant comprendre de la cire et pouvant être formulée sous la forme d'un solide.
PCT/KR2022/014020 2021-10-26 2022-09-20 Composition cosmétique eau dans l'huile sans émulsifiant WO2023075149A1 (fr)

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KR10-2021-0143355 2021-10-26
KR1020210143355A KR20230059309A (ko) 2021-10-26 2021-10-26 유화제-프리 유중수형 화장료 조성물

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116370318A (zh) * 2023-05-09 2023-07-04 奥源新材料(广州)有限公司 一种无乳化剂的皮克林唇霜及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6620407B1 (en) * 1998-08-01 2003-09-16 Beiersdorf Ag Finely dispersed emulsifier-free systems of the oil-in-water and water-in-oil type
US6803048B2 (en) * 1997-03-25 2004-10-12 Beiersdorf Ag Emulsifier-free finely dispersed systems of the water-in-oil type
EP1083861B1 (fr) * 1998-06-12 2005-09-21 Beiersdorf Aktiengesellschaft Sticks aqueux a usage cosmetique ou pharmaceutique
KR20060080753A (ko) * 2005-01-06 2006-07-11 주식회사 코리아나화장품 고형 타입의 유중수형 부분 메이크업 화장료 조성물
KR20180103650A (ko) * 2017-05-24 2018-09-19 한국콜마주식회사 유화제 프리 자외선 차단용 화장료 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6803048B2 (en) * 1997-03-25 2004-10-12 Beiersdorf Ag Emulsifier-free finely dispersed systems of the water-in-oil type
EP1083861B1 (fr) * 1998-06-12 2005-09-21 Beiersdorf Aktiengesellschaft Sticks aqueux a usage cosmetique ou pharmaceutique
US6620407B1 (en) * 1998-08-01 2003-09-16 Beiersdorf Ag Finely dispersed emulsifier-free systems of the oil-in-water and water-in-oil type
KR20060080753A (ko) * 2005-01-06 2006-07-11 주식회사 코리아나화장품 고형 타입의 유중수형 부분 메이크업 화장료 조성물
KR20180103650A (ko) * 2017-05-24 2018-09-19 한국콜마주식회사 유화제 프리 자외선 차단용 화장료 조성물

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116370318A (zh) * 2023-05-09 2023-07-04 奥源新材料(广州)有限公司 一种无乳化剂的皮克林唇霜及其制备方法

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