WO2019116901A1 - 液晶表示素子 - Google Patents

液晶表示素子 Download PDF

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Publication number
WO2019116901A1
WO2019116901A1 PCT/JP2018/043955 JP2018043955W WO2019116901A1 WO 2019116901 A1 WO2019116901 A1 WO 2019116901A1 JP 2018043955 W JP2018043955 W JP 2018043955W WO 2019116901 A1 WO2019116901 A1 WO 2019116901A1
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group
preferable
formula
general formula
liquid crystal
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PCT/JP2018/043955
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English (en)
French (fr)
Japanese (ja)
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平田　真一
求龍 姜
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Dic株式会社
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Priority to JP2019512334A priority Critical patent/JP6555450B1/ja
Priority to CN201880072452.7A priority patent/CN111315846A/zh
Priority to KR1020207013714A priority patent/KR20200096501A/ko
Publication of WO2019116901A1 publication Critical patent/WO2019116901A1/ja

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    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/12—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
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    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
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    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/14—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain
    • C09K19/16—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain the chain containing carbon-to-carbon double bonds, e.g. stilbenes
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    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/14—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain
    • C09K19/18—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a carbon chain the chain containing carbon-to-carbon triple bonds, e.g. tolans
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    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
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    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/24—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing nitrogen-to-nitrogen bonds
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    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
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    • C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
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    • C09K19/00—Liquid crystal materials
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    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/42—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
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    • C09K19/00—Liquid crystal materials
    • C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • C09K19/54—Additives having no specific mesophase characterised by their chemical composition
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
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    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • C09K19/3001—Cyclohexane rings
    • C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
    • C09K2019/3004—Cy-Cy
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    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • C09K19/3001—Cyclohexane rings
    • C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
    • C09K2019/3016—Cy-Ph-Ph

Definitions

  • the present invention relates to a liquid crystal composition and a liquid crystal display device using the liquid crystal composition.
  • Liquid crystal display devices are used in various household electric appliances, industrial measuring instruments, automobile panels, mobile phones, smart phones, notebook PCs, tablet PCs, televisions, etc., including watches and calculators.
  • Typical liquid crystal display methods include TN (twisted nematic), STN (super twisted nematic), GH (guest host), IPS (in-plane switching) and FFS (fringe field switching) types.
  • OCB optical compensated birefringence
  • ECB voltage controlled birefringence
  • VA vertical alignment
  • CSH color super homeotropic
  • FLC ferrroelectric liquid crystal
  • an active matrix (AM) method driven by static drive multiplex drive, simple matrix method, TFT (thin film transistor), TFD (thin film diode) or the like can be mentioned.
  • IPS type, FFS type, ECB type, VA type, CSH type, etc. use a liquid crystal composition (n type liquid crystal composition) having a negative dielectric anisotropy ( ⁇ ). It is known to exhibit advantageous properties.
  • Typical mainstream display systems using n-type liquid crystal compositions are VA-type or PSA (Polymer Sustained Alignment) -type or PSVA (Polymer Stabilized Vertival Alignment) -type in which alignment is controlled by polymerizing polymerizable compounds in liquid crystal phase.
  • Vertical alignment methods and horizontal alignment methods represented by IPS type and FFS type.
  • the vertical alignment method is characterized by a wide viewing angle, high transmittance, high contrast, and fast response speed, and is mainly used for large display devices such as TVs and monitors.
  • the horizontal alignment method is adopted in mobile devices such as smartphones and tablet PCs from the viewpoint of wide view angle, high transmittance, low power consumption and optimality with a touch panel, and further adopted to liquid crystal television. We are also moving forward.
  • a liquid crystal composition using liquid crystal compounds (A) and (B) (see Patent Document 1) having a 2,3-difluorophenylene skeleton as described below is disclosed as a liquid crystal composition having a negative ⁇ .
  • liquid crystal compounds (C) and (D) are used as liquid crystal compounds of which ⁇ is almost 0, but in liquid crystal compositions such as liquid crystal televisions that require high-speed response, viscosity is low enough. It has not been realized yet.
  • liquid crystal compound (I) having a large ⁇ n and a large bending elastic constant (K 33 )
  • a liquid crystal composition (see Patent Document 5) in which the above is combined is disclosed, but still faster response speed and high voltage holding ratio (VHR) have been required.
  • Patent Document 6 discloses that the response speed of a homeotropic liquid crystal cell is improved by using a liquid crystal material having a large index represented by (Expression 1). However, the liquid crystal material disclosed does not show sufficient performance.
  • Non-Patent Document 1 (Wherein K 33 represents an elastic constant, ⁇ n represents refractive index anisotropy, and ⁇ 1 represents rotational viscosity). Further, in Non-Patent Document 1, it is known that the response speed of the liquid crystal material is expressed by the following equation regardless of the driving method.
  • ⁇ off is the response speed when the voltage application state is changed to the voltage non-application state
  • ⁇ 1 is the rotational viscosity of the liquid crystal material
  • d is the thickness of the liquid crystal layer
  • k is the elastic constant. Therefore, it is understood that reduction of ⁇ 1 and increase of k are universally effective for reduction of response speed.
  • the front contrast ratio (hereinafter referred to as contrast) in the liquid crystal display device has a finite value (hereinafter referred to as black luminance) instead of the luminance in black display being zero
  • black luminance a finite value obtained by dividing luminance (hereinafter, white luminance) by black luminance. Therefore, the contrast can be increased by making the white luminance as large as possible and / or the black luminance as small as possible. In general, the contribution is larger if the black luminance is reduced.
  • the liquid crystal material is thermally moved to cause light scattering and to decrease the contrast by increasing the black luminance.
  • the factor that increases the black luminance referred to here is light leakage in the front direction of the liquid crystal display (in the direction perpendicular to the liquid crystal layer). This effect is generally greater in the horizontal alignment mode than in the vertical alignment mode.
  • I in the formula is the intensity of light leakage of the liquid crystal layer (transmittance observed when placed between crossed polarizers), S lc is the scattering index, ⁇ n is the refractive index anisotropy of the liquid crystal material, n e the extraordinary refractive index, n o is the ordinary refractive index, d is the thickness of the liquid crystal layer, K is means an average elastic constant can be expressed as (K 11 + K 22 + K 33) / 3.
  • K 11 represents an elastic constant of the elastic constants of the spread
  • K 22 is the elastic constant of torsion
  • the liquid crystal composition satisfies ⁇ n, n e and n o while satisfying (it is necessary to set ⁇ n ⁇ d to the value).
  • K is required, and by achieving this, the black luminance of the liquid crystal display element can be reduced and the contrast can be improved.
  • the nematic phase-isotropic liquid phase transition temperature (T NI ) is high, the solid phase-nematic phase transition temperature (T CN ) is low, and excellent low temperature storage stability is essential. Further, it is required that the rotational viscosity ( ⁇ 1 ) is sufficiently small, the refractive index anisotropy ( ⁇ n) is large, and the elastic constant (k or K) is large. It has been required to simultaneously achieve high response speed and high contrast.
  • the problem to be solved by the present invention is to provide a liquid crystal composition having improved response speed and contrast ratio while satisfying the various characteristics required for the liquid crystal composition, and to provide a liquid crystal display device using the same. It is.
  • the present inventors have found that the above-mentioned problems can be solved by examining various liquid crystal compounds and various chemical substances, and performing selection and adjustment of their contents, and have completed the present invention. .
  • the liquid crystal composition of the present invention has improved response speed and contrast ratio while satisfying various properties required for the liquid crystal composition, and has excellent display characteristics.
  • it is useful as an n-type liquid crystal composition containing an n-type compound having negative dielectric anisotropy.
  • the liquid crystal display device of the present invention using the liquid crystal composition of the present invention can provide a liquid crystal display device of VA type, FFS type or IPS type.
  • the liquid crystal display element is suitable for a mobile phone, a smartphone, a notebook PC, a tablet PC, an on-vehicle LCD, a PID (Public Information Display), a TV, a monitor or the like.
  • the liquid crystal composition of the present invention contains one or more compounds selected from the compounds represented by the formula (i) and the compounds represented by the general formula (L).
  • a L1 , A L2 and A L3 are each independently (A) 1,4-cyclohexylene group, (this is present in the group one -CH 2 - - or nonadjacent two or more -CH 2 may be replaced by -O-.)
  • the liquid crystal composition of the present invention contains one or more types of compounds represented by formula (L).
  • the compounds represented by the general formula (L) correspond to dielectric substantially neutral compounds (the value of ⁇ is ⁇ 2 to 2).
  • the compounds represented by formula (L) may be used alone or in combination.
  • the type of compound used is, for example, one type in one embodiment of the present invention. Or in another embodiment of the present invention, there are 2 types, 3 types, 4 types, 5 types, 5 types, 6 types, 7 types, 8 types, 9 types and 10 It is more than kind.
  • the content of the compound represented by the general formula (L) is low temperature solubility, transition temperature, electrical reliability, birefringence, process compatibility, dripping marks, image sticking, It is necessary to appropriately adjust according to the required performance such as dielectric anisotropy.
  • the compounds represented by formula (L) are so-called nonpolar compounds in which ⁇ is around zero. Therefore, the number of polar groups such as halogen atoms in the molecule is preferably 2 or less, preferably 1 or less, and 1 to improve the solubility with other liquid crystal compounds. It is preferable that it is not substituted, when paying attention to viscosity.
  • the lower limit value of the preferable content of the compound represented by the general formula (L) to the total amount of the composition of the present invention is 1%, 10%, 20%, 30%. 40%, 50%, 55%, 60%, 65%, 70%, 75%, 80%.
  • the upper limit value of the preferred content is 95%, 85%, 75%, 65%, 55%, 45%, 35%, 25%.
  • the lower limit of the preferable content of the compound represented by the general formula (i) and the general formula (L) to the total amount of the composition of the present invention is 1%, 10% and 20%. , 30%, 40%, 50%, 55%, 60%, 65%, 70%, 75%, 80%.
  • the upper limit value of the preferred content is 95%, 85%, 75%, 65%, 55%, 45%, 35%, 25%.
  • the above lower limit is high and the upper limit is high. Furthermore, when the composition of the present invention is required to keep Tni high and a composition having good temperature stability is required, it is preferable that the above lower limit value is high and the upper limit value is high. When it is desired to increase the dielectric anisotropy in order to keep the drive voltage low, it is preferable that the above lower limit value be low and the upper limit value be low.
  • both R L1 and R L2 are preferably alkyl groups, and when importance is given to reducing the volatility of the compound, alkoxy groups are preferable, and viscosity reduction is important When doing, at least one is preferably an alkenyl group.
  • the number of halogen atoms present in the molecule is preferably 0, 1, 2 or 3 and is preferably 0 or 1. When importance is attached to compatibility with other liquid crystal molecules, 1 is preferred.
  • R L1 and R L2 are, when the ring structure to which they are bonded is a phenyl group (aromatic), a linear alkyl group having 1 to 5 carbon atoms, a linear alkyl group having 1 to 4 carbon atoms Alkoxy groups and alkenyl groups having 4 to 5 carbon atoms are preferred, and in the case where the ring structure to which they are attached is a saturated ring structure such as cyclohexane, pyran and dioxane, a straight chain having 1 to 5 carbon atoms is preferred.
  • An alkyl group, a linear alkoxy group having 1 to 4 carbon atoms and a linear alkenyl group having 2 to 5 carbon atoms are preferable.
  • the total of carbon atoms and oxygen atoms, if present, is preferably 5 or less, preferably linear.
  • the alkenyl group is preferably selected from the groups represented by any one of formulas (R1) to (R5). (The black dot in each formula represents a carbon atom in the ring structure.)
  • n L1 is preferably 0 when importance is attached to the response speed, 2 or 3 is preferable to improve the upper limit temperature of the nematic phase, and 1 is preferable to balance them. Moreover, in order to satisfy the characteristics required as a composition, it is preferable to combine compounds of different values.
  • a L 1 , A L 2 and A L 3 are preferably aromatic when it is required to increase ⁇ n, and are preferably aliphatic to improve the response speed, and each of them is independently trans- 1,4-cyclohexylene group, 1,4-phenylene group, 2-fluoro-1,4-phenylene group, 3-fluoro-1,4-phenylene group, 3,5-difluoro-1,4-phenylene group , 1,4-cyclohexenylene group, 1,4-bicyclo [2.2.2] octylene group, piperidine-1,4-diyl group, naphthalene-2,6-diyl group, decahydronaphthalene-2,6 -Diyl group or 1,2,3,4-tetrahydronaphthalene-2,6-diyl group is preferable, and the following structure is more preferable,
  • it represents a trans-1,4-cyclohexylene group or a 1,4-phenylene group.
  • Z L1 and Z L2 be a single bond when the response speed is important.
  • the compound represented by formula (L) preferably has 0 or 1 halogen atoms in the molecule.
  • the compound represented by formula (L) is preferably a compound selected from the group of compounds represented by formulas (L-1) to (L-7).
  • the compounds represented by formula (L-1) are the following compounds.
  • R L11 and R L12 each independently represent the same meaning as R L1 and R L2 in general formula (L).
  • R L11 and R L12 are preferably linear alkyl groups having 1 to 5 carbon atoms, linear alkoxy groups having 1 to 4 carbon atoms, and linear alkenyl groups having 2 to 5 carbon atoms. .
  • the compounds represented by General Formula (L-1) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit value of the preferable content is 1%, 2%, 3%, 5%, 7%, 10% with respect to the total amount of the composition of the present invention.
  • the upper limit of the preferred content is 40%, 35%, 33%, 30%, and 25% based on the total weight of the composition of the present invention.
  • the above lower limit is high and the upper limit is high. Furthermore, when the composition of the present invention needs to have a high Tni and a composition having good temperature stability is required, it is preferable that the above lower limit value is medium and the upper limit value is medium. When it is desired to increase the dielectric anisotropy in order to keep the drive voltage low, it is preferable that the above lower limit value is low and the upper limit value is low. In order to improve the viewing angle characteristics, it is not preferable to increase the upper limit value.
  • the compound represented by General Formula (L-1) is preferably a compound selected from the group of compounds represented by General Formula (L-1-1).
  • the compound represented by General Formula (L-1-1) is a compound selected from the compound group represented by Formula (L-1-1.1) to Formula (L-1-1.3) It is preferable that it is a compound represented by the formula (L-1-1.2) or the formula (L-1-1.3), and in particular, it is represented by the formula (L-1-1.3) It is preferable that it is a compound.
  • the lower limit of the preferable content of the compound represented by the formula (L-1-1.3) to the total amount of the composition of the present invention is 1%, 2%, 3%, It is 5%, 7% and 10%.
  • the upper limit of the preferred content is 20%, 15%, 13%, 10%, 8%, 7%, based on the total weight of the composition of the present invention. %, 5% and 3%.
  • the compound represented by General Formula (L-1) is preferably a compound selected from the group of compounds represented by General Formula (L-1-2).
  • R L12 has the same meaning as in the general formula (L-1).
  • the lower limit of the preferable content of the compound represented by the formula (L-1-2) to the total amount of the composition of the present invention is 1%, 5%, 10%, 15% , 17%, 20%, 23%, 25%, 27%, 30%, 35%.
  • the upper limit of the preferred content is 60%, 55%, 50%, 45%, 42%, 40%, based on the total weight of the composition of the present invention. %, 35%, 33%, and 30%.
  • the compound represented by General Formula (L-1-2) is a compound selected from the group of compounds represented by Formula (L-1-2.1) to Formula (L-1-2.4)
  • the compound is preferably a compound represented by Formula (L-1-2.2) to Formula (L-1-2.4).
  • the compounds represented by the formula (L-1-2.2) are preferable because they particularly improve the response speed of the composition of the present invention.
  • Tni higher than the response speed it is preferable to use a compound represented by formula (L-1-2.3) or formula (L-1-2.4). It is not preferable to set the content of the compounds represented by Formula (L-1-2.3) and Formula (L-1-2.4) to 30% or more in order to improve the solubility at low temperature.
  • the lower limit of the preferable content of the compound represented by the formula (L-1-2.2) to the total amount of the composition of the present invention is 10%, 15%, 18%, 20%, 23%, 25%, 27%, 30%, 33%, 35%, 38%, 40%.
  • the upper limit of the preferred content is 60%, 55%, 50%, 45%, 43%, 40%, 60%, based on the total weight of the composition of the present invention. %, 35%, 32%, 30%, 27%, 25%, 22%.
  • Lower limit of preferable content of the total of the compound represented by the formula (L-1-1.3) and the compound represented by the formula (L-1-2.2) relative to the total amount of the composition of the present invention The values are 10%, 15%, 20%, 25%, 27%, 30%, 35%, 40%.
  • the upper limit of the preferred content is 60%, 55%, 50%, 45%, 43%, 40%, 60%, based on the total weight of the composition of the present invention. %, 35%, 32%, 30%, 27%, 25%, 22%.
  • the compound represented by formula (L-1) is preferably a compound selected from the group of compounds represented by formula (L-1-3).
  • L L13 and R L14 each independently represent an alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms.
  • R L13 and R L14 are preferably linear alkyl groups having 1 to 5 carbon atoms, linear alkoxy groups having 1 to 4 carbon atoms, and linear alkenyl groups having 2 to 5 carbon atoms. .
  • the lower limit of the preferable content of the compound represented by the formula (L-1-3) to the total amount of the composition of the present invention is 1%, 5%, 10%, 13% , 15%, 17%, 20%, 23%, 25%, 30%.
  • the upper limit of the preferred content is 60%, 55%, 50%, 45%, 40%, 37%, 35%, based on the total weight of the composition of the present invention. %, 33%, 30%, 27%, 25%, 23%, 20%, 17%, 15%, 13%, 10%. %.
  • the compound represented by General Formula (L-1-3) is a compound selected from the group of compounds represented by Formula (L-1-3.1) to Formula (L-1 -3.12)
  • the compound is preferably a compound represented by formula (L-1-3.1), formula (L-1-3.3) or formula (L-1-3.4).
  • the compound represented by the formula (L-1-3.1) is preferable in order to particularly improve the response speed of the composition of the present invention.
  • Tni higher than the response speed is to be determined.
  • the formula (L-1-3.3), the formula (L-1-3.4), the formula (L-1-3.11) and the formula (L-) are used. It is preferable to use the compound represented by 1-3.12).
  • the lower limit of the preferable content of the compound represented by the formula (L-1-3.1) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%, 10%, 13%, 15%, 18%, 20%.
  • the upper limit of the preferred content is 20%, 17%, 15%, 13%, 10%, 8%, or 20%, based on the total weight of the composition of the present invention. % And 6%.
  • the compound represented by Formula (L-1) is preferably a compound selected from the group of compounds represented by Formula (L-1-4) and / or (L-1-5).
  • R L15 and R L16 each independently represent an alkyl group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms.
  • R L15 and R L16 are preferably linear alkyl groups having 1 to 5 carbon atoms, linear alkoxy groups having 1 to 4 carbon atoms, and linear alkenyl groups having 2 to 5 carbon atoms. .
  • the lower limit of the preferable content of the compound represented by the formula (L-1-4) to the total amount of the composition of the present invention is 1%, 5%, 10%, 13% 15%, 17% and 20%.
  • the upper limit of the preferred content is 25%, 23%, 20%, 17%, 15%, 13%, 10%, based on the total weight of the composition of the present invention. %.
  • the lower limit of the preferable content of the compound represented by the formula (L-1-5) to the total amount of the composition of the present invention is 1%, 5%, 10%, 13% 15%, 17% and 20%.
  • the upper limit of the preferred content is 25%, 23%, 20%, 17%, 15%, 13%, 10%, based on the total weight of the composition of the present invention. %.
  • compounds represented by general formulas (L-1-4) and (L-1-5) are represented by formulas (L-1-4.1) to (L-1-5.3) It is preferable that it is a compound selected from the group of compounds, and it is preferable that it is a compound represented by Formula (L-1-4.2) or Formula (L-1-5.2).
  • the lower limit of the preferable content of the compound represented by the formula (L-1-4.2) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%, 10%, 13%, 15%, 18%, 20%.
  • the upper limit of the preferred content is 20%, 17%, 15%, 13%, 10%, 8%, or 20%, based on the total weight of the composition of the present invention. % And 6%.
  • R L17 and R L18 each independently represent a methyl group or a hydrogen atom.
  • the lower limit of the preferable content of the compound represented by the formula (L-1-6) to the total amount of the composition of the present invention is 1%, 5%, 10%, 15% , 17%, 20%, 23%, 25%, 27%, 30%, 35%.
  • the upper limit of the preferred content is 60%, 55%, 50%, 45%, 42%, 40%, based on the total weight of the composition of the present invention. %, 35%, 33%, and 30%.
  • the compound represented by General Formula (L-1-6) is a compound selected from the group of compounds represented by Formula (L-1-6.1) to Formula (L-1-6.3) Is preferred.
  • the compound represented by General Formula (L-1) is a compound represented by (L-1-1), (L-1-2) and / or (L-1-3) in order to secure a balance between response speed and reliability. Is preferred, and in particular (L-1-2) and / or (L-1-3) are preferred.
  • the compounds represented by formula (L-2) are the following compounds.
  • R L21 and R L22 each independently represent the same meaning as R L1 and R L2 in general formula (L).
  • R L21 is preferably an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms
  • R L22 is an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 4 to 5 carbon atoms or a carbon atom
  • the alkoxy groups of 1 to 4 are preferable.
  • the compounds represented by General Formula (L-2) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (L-2) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7% and 10%.
  • the upper limit of the preferred content is 20%, 15%, 13%, 10%, 8%, 7%, based on the total weight of the composition of the present invention. %, 5% and 3%.
  • the compound represented by General Formula (L-2) is preferably a compound selected from the group of compounds represented by Formula (L-2.1) to Formula (L-2.6),
  • the compound is preferably a compound selected from the group of compounds represented by (L-2.1), formula (L-2.3), formula (L-2.4) and formula (L-2.6),
  • the compound is preferably a compound selected from the group of compounds represented by Formula (L-2.3) and Formula (L-2.4).
  • the compounds represented by formula (L-3) are the following compounds.
  • R L31 and R L32 each independently represent the same meaning as R L1 and R L2 in general formula (L).
  • R L31 and R L32 are preferably each independently an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 4 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms.
  • the compounds represented by formula (L-3) can be used alone or in combination of two or more. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (L-3) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7% and 10%.
  • the upper limit of the preferred content is 20%, 15%, 13%, 10%, 8%, 7%, based on the total weight of the composition of the present invention. %, 5% and 3%.
  • the compound represented by General Formula (L-3) is preferably a compound selected from the group of compounds represented by Formula (L-3.1) to Formula (L-3.6), It is preferable that it is a compound selected from the compound group represented by (L-3.1), Formula (L-3.3), Formula (L-3.5) or Formula (L-3.6), It is preferable that it is a compound represented by Formula (L-3.1).
  • the compounds represented by formula (L-4) are the following compounds.
  • R L41 and R L42 each independently represent the same meaning as R L1 and R L2 in General Formula (L).
  • R L41 is preferably an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms
  • R L42 is an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 4 to 5 carbon atoms or a carbon atom
  • the alkoxy groups of 1 to 4 are preferable.
  • the compounds represented by formula (L-4) can be used alone or in combination of two or more compounds.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the content of the compound represented by the general formula (L-4) is low temperature solubility, transition temperature, electrical reliability, birefringence, process compatibility, dripping marks, It is necessary to appropriately adjust according to the required performance such as burn-in and dielectric anisotropy.
  • the lower limit of the preferable content of the compound represented by the formula (L-4) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7%, 10%, 14%, 16%, 20%, 23%, 26%, 30%, 35%, 40% .
  • the upper limit of the preferable content of the compound represented by the formula (L-4) to the total amount of the composition of the present invention is 50%, 40%, 35%, and 30%. 20%, 15%, 10% and 5%.
  • the compound represented by General Formula (L-4) is preferably a compound represented by Formula (L-4.1) to Formula (L-4.3), for example.
  • the compound represented by the formula (L-4.1) can be represented by the formula (L-4.1) Even if it contains the compound represented by -4.2), it contains both the compound represented by the formula (L-4.1) and the compound represented by the formula (L-4.2) Or all of the compounds represented by Formula (L-4.1) to Formula (L-4.3) may be contained.
  • the lower limit of the preferable content of the compound represented by the formula (L-4.1) or the formula (L-4.2) to the total amount of the composition of the present invention is 3%, 5% Yes, 7%, 9%, 11%, 12%, 13%, 18%, 21%, preferred upper limit is 45, 40% , 35%, 30%, 25%, 23%, 20%, 18%, 15%, 13%, 10%, 8% .
  • both the compound represented by the formula (L-4.1) and the compound represented by the formula (L-4.2) are contained, both compounds relative to the total amount of the composition of the present invention
  • the lower limit of the preferable content is 15%, 19%, 24%, 30%, and the preferable upper limit is 45, 40%, 35%, 30% Yes, 25%, 23%, 20%, 18%, 15%, 13%.
  • the compound represented by General Formula (L-4) is preferably a compound represented by Formula (L-4.4) to Formula (L-4.6), for example. It is preferable that it is a compound represented by these.
  • the compound represented by the formula (L-4.4) may be represented by the formula (L-4.4) Even if it contains the compound represented by -4.5), it contains both the compound represented by the formula (L-4.4) and the compound represented by the formula (L-4.5) May be
  • the lower limit of the preferable content of the compound represented by the formula (L-4.4) or the formula (L-4.5) to the total amount of the composition of the present invention is 3%, 5% Yes, 7%, 9%, 11%, 12%, 13%, 18%, 21%.
  • the preferred upper limit is 45, 40%, 35%, 30%, 25%, 23%, 20%, 18%, 15%, 13%. %, 10%, and 8%.
  • both the compound represented by the formula (L-4.4) and the compound represented by the formula (L-4.5) are contained, both compounds relative to the total amount of the composition of the present invention
  • the lower limit of the preferable content is 15%, 19%, 24%, 30%, and the preferable upper limit is 45, 40%, 35%, 30% Yes, 25%, 23%, 20%, 18%, 15%, 13%.
  • the compound represented by Formula (L-4) is preferably a compound represented by Formula (L-4.7) to Formula (L-4.10), and in particular, a compound represented by Formula (L-4.
  • the compound represented by 9) is preferable.
  • the compounds represented by General Formula (L-5) are the following compounds.
  • R L51 and R L52 each independently represent the same meaning as R L1 and R L2 in general formula (L).
  • R L51 is preferably an alkyl group or an alkenyl group having 2 to 5 carbon atoms having 1 to 5 carbon atoms
  • R L52 is an alkyl group, an alkenyl group or a carbon atom of the carbon atoms 4-5 of 1-5 carbon atoms
  • the alkoxy groups of 1 to 4 are preferable.
  • the compounds represented by General Formula (L-5) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the content of the compound represented by the general formula (L-5) is low temperature solubility, transition temperature, electrical reliability, birefringence, process compatibility, dripping marks, It is necessary to appropriately adjust according to the required performance such as burn-in and dielectric anisotropy.
  • the lower limit of the preferable content of the compound represented by the formula (L-5) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7%, 10%, 14%, 16%, 20%, 23%, 26%, 30%, 35%, 40% .
  • the upper limit of the preferable content of the compound represented by the formula (L-5) to the total amount of the composition of the present invention is 50%, 40%, 35%, and 30%. 20%, 15%, 10% and 5%
  • the compound represented by the general formula (L-5) is a compound represented by the formula (L-5.1) or the formula (L-5.2) It is preferable that it is a compound represented by these, and it is especially preferable that it is a compound represented by Formula (L-5.1).
  • the lower limit value of the preferable content of these compounds to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%.
  • the upper limit of the preferable content of these compounds is 20%, 15%, 13%, 10%, and 9%.
  • the compound represented by General Formula (L-5) is preferably a compound represented by Formula (L-5.3) or Formula (L-5.4).
  • the lower limit value of the preferable content of these compounds to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%.
  • the upper limit of the preferable content of these compounds is 20%, 15%, 13%, 10%, and 9%.
  • the compound represented by General Formula (L-5) is preferably a compound selected from the group of compounds represented by Formula (L-5.5) to Formula (L-5.7), and in particular It is preferable that it is a compound represented by L-5.7).
  • the lower limit value of the preferable content of these compounds to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%.
  • the upper limit of the preferable content of these compounds is 20%, 15%, 13%, 10%, and 9%.
  • the compounds represented by General Formula (L-6) are the following compounds.
  • R L61 and R L62 each independently represent the same as R L1 and R L2 in General Formula (L), and X L61 and X L62 each independently represent a hydrogen atom or a fluorine atom.
  • Each of R L61 and R L62 is preferably independently an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms, and one of X L61 and X L62 is a fluorine atom, and the other is a hydrogen atom Is preferred.
  • the compounds represented by formula (L-6) can be used alone or in combination of two or more compounds. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (L-6) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7%, 10%, 14%, 16%, 20%, 23%, 26%, 30%, 35%, 40% .
  • the upper limit of the preferable content of the compound represented by the formula (L-6) to the total amount of the composition of the present invention is 50%, 40%, 35%, and 30%. 20%, 15%, 10% and 5%.
  • the compound represented by General Formula (L-6) is preferably a compound represented by Formula (L-6.1) to Formula (L-6.9).
  • the compound represented by General Formula (L-6) is preferably a compound represented by Formula (L-6.10) to Formula (L-6.17), for example.
  • the compound represented by L-6.11) is preferred.
  • the lower limit value of the preferable content of these compounds to the total amount of the composition of the present invention is 1%, 2%, 3%, 5%, 7%.
  • the upper limit of the preferable content of these compounds is 20%, 15%, 13%, 10%, and 9%.
  • the compounds represented by General Formula (L-7) are the following compounds.
  • R L71 and R L72 each independently represent the same as R L1 and R L2 in the general formula (L), and A L71 and A L72 are each independently A L2 and A L2 in the general formula (L)
  • a hydrogen having the same meaning as A L3 is represented, but each of hydrogen atoms on A L71 and A L72 may be independently substituted by a fluorine atom
  • Z L71 has the same meaning as Z L2 in formula (L)
  • X L71 and X L72 each independently represent a fluorine atom or a hydrogen atom.
  • R L71 and R L72 are each independently an alkyl group having 1 to 5 carbon atoms, an alkenyl group or an alkoxy group having 1 to 4 carbon atoms of 2 to 5 carbon atoms preferably
  • a L71 and A L72 each independently 1,4-cyclohexylene group or a 1,4-phenylene group is preferably a hydrogen atom on a L71 and a L72 may be substituted by fluorine
  • the type of compound used is, for example, one type, two types, three types, and four types according to one embodiment of the present invention.
  • the content of the compound represented by the general formula (L-7) is low temperature solubility, transition temperature, electrical reliability, birefringence, process compatibility, dripping mark, It is necessary to appropriately adjust according to the required performance such as burn-in and dielectric anisotropy.
  • the lower limit of the preferable content of the compound represented by the formula (L-7) to the total amount of the composition of the present invention is 1%, 2%, 3%, 5% 7%, 10%, 14%, 16% and 20%.
  • the upper limit of the preferable content of the compound represented by the formula (L-7) to the total amount of the composition of the present invention is 30%, 25%, 23%, and 20%. 18%, 15%, 10% and 5%.
  • the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7.1) to Formula (L-7.4), and Formula (L-7. It is preferable that it is a compound represented by 2).
  • the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7.11) to Formula (L-7.13), and the compound represented by Formula (L-7. It is preferable that it is a compound represented by 11).
  • the compound represented by General Formula (L-7) is a compound represented by Formula (L-7.21) to Formula (L-7.23). It is preferable that it is a compound represented by Formula (L-7.21).
  • the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7. 31) to Formula (L-7. 34), and the compound represented by Formula (L-7. 31) or / and a compound represented by the formula (L-7. 32) is preferable.
  • the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7.41) to Formula (L-7.44), and the compound represented by Formula (L-7. 41) or / and a compound represented by the formula (L-7. 42) is preferable.
  • the compound represented by General Formula (L-7) is preferably a compound represented by Formula (L-7.51) to Formula (L-7.53).
  • R L 251 and R L 252 each independently represent the same meaning as R L 1 and R L 2 in General Formula (L), n 251 represents 0 or 1, but is represented by General Formula (i) Excluding compounds)) And the compounds represented are preferred.
  • the lower limit of the preferable content of the compound represented by the general formula (L-25) is 1%, 2%, 3%, 5%, 7%, 10% 13%, 15%, 18% and 20%.
  • the upper limit of the preferred content is 20%, 17%, 15%, 13%, 10%, 8%, or 20%, based on the total weight of the composition of the present invention. % And 6%.
  • Preferred compounds of the compounds represented by formula (L-25) are compounds represented by formulas (L-3) and (L-5).
  • composition of the present invention preferably contains a compound represented by the general formula (N-1d).
  • the compounds represented by the general formula (N-1d) correspond to dielectrically negative compounds (the sign of ⁇ is negative and the absolute value is larger than 2).
  • the compounds represented by the general formula (N-1d) are the following compounds.
  • R Nd11 and R Nd12 each independently represent an alkyl group having 1 to 8 carbon atoms, and one or two or more non-adjacent -CH 2 -in the alkyl group are each independently.
  • -CH CH-, -C ⁇ C-, -O-, -CO-, -COO- or -OCO-,
  • n Nd11 represents 1, 2 or 3.
  • the compound represented by General Formula (N-1d) may be used alone or in combination of two or more.
  • R Nd11 is an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or an alkenyl having 2 to 8 carbon atoms
  • An oxy group is preferable, and an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms or an alkenyloxy group having 2 to 5 carbon atoms is preferable.
  • an alkyl group of 1 to 5 or an alkenyl group of 2 to 5 carbon atoms is more preferable, an alkyl group of 2 to 5 carbon atoms or an alkenyl group of 2 to 3 carbon atoms is further preferable, and an alkenyl of 3 carbon atoms Groups (propenyl groups) are particularly preferred.
  • a linear alkyl group having 1 to 5 carbon atoms, a linear alkoxy group having 1 to 4 carbon atoms, and a linear alkenyl group having 2 to 5 carbon atoms are preferable.
  • the total of carbon atoms and oxygen atoms, if present is preferably 5 or less, preferably linear.
  • R Nd12 is preferably an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms, An alkyl group of 1 to 5, an alkoxy group of 1 to 5 carbon atoms, an alkenyl group of 2 to 5 carbon atoms or an alkenyloxy group of 2 to 5 carbon atoms is preferable, and an alkyl group of 1 to 5 carbon atoms or An alkenyl group having 2 to 5 carbon atoms is more preferable, an alkyl group having 2 to 5 carbon atoms or an alkenyl group having 2 to 3 carbon atoms is further preferable, and an alkenyl group having 3 carbon atoms (propenyl group) is particularly preferable.
  • a linear alkyl group having 1 to 5 carbon atoms, a linear alkoxy group having 1 to 4 carbon atoms, and a linear alkenyl group having 2 to 5 carbon atoms are preferable.
  • the total of carbon atoms and oxygen atoms, if present, is preferably 5 or less, preferably linear.
  • n Nd11 is preferably 1 or 2, and preferably contains both a compound in which n Nd11 is 1 and a compound in which n Nd11 is 2.
  • n Nd11 is 1
  • R Nd11 is used. It is preferable to use the same substituent.
  • n Nd 11 is 2
  • R Nd 12 is used. It is preferable to use the same substituent.
  • n Nd11 is 1 and a compound in which n Nd11 is 2 are used together, it is preferable to use more compounds in which n Nd11 is 2.
  • the compound represented by the general formula (N-1 d) is preferably a compound represented by the compound represented by the general formula (N-1-10) and the compound represented by the general formula (N-1-11) .
  • the compounds represented by the general formula (N-1-10) are the following compounds.
  • R N 1101 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group, a butyl group, a vinyl group or a 1-propenyl group.
  • R N 1102 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-10) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-10) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compound represented by General Formula (N-1-10) is a compound selected from the group of compounds represented by Formula (N-1-10.1) to Formula (N-1-10.21) Is preferably represented by the formulas (N-1-10.1) to (N-1-10.5), the formula (N-1-10.20) and the formula (N-1-10.21). It is preferable that it is a compound, and a formula (N-1-1. 1), a formula (N- 1- 10. 2), a formula (N- 1- 10. 20), and a formula (N- 1- 10. 21) And the compounds represented by the formula (N-1-10.1) and the formula (N-1-1. 2) are preferred, and the compounds represented by the formula (N-1-1. 2) Compounds are preferred.
  • the compounds represented by the formula (N-1-10.1), the formula (N-1-10.2), the formula (N-1-12.20) and the formula (N-1-10.21) can be used alone.
  • the lower limit of the preferred content of these compounds alone or in the total amount of the composition of the present invention is 3%, and 5%, although it is possible to use them in combination or in combination. 8%, 10%, 13% and 15%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %.
  • the compounds represented by the general formula (N-1-11) are the following compounds.
  • R N 1111 and R N 11 12 independently represents the same meaning as R N 11 and R N 12 in General Formula (N).
  • R N 1111 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group, a butyl group, a vinyl group or a 1-propenyl group.
  • R N 1112 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-11) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-11) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compound represented by General Formula (N-1-11) is a compound selected from the group of compounds represented by Formula (N-1-11.1) to Formula (N-1-11.14) And is preferably represented by the formula (N-1-11. 2), the formula (N-1 1-11.4), the formulas (N-1-11. 11) and (N-1-11. 14). It is preferable that it is a compound.
  • the composition of the present invention The lower limit value of the preferred content of these compounds alone or in the total amount of is 3%, 5%, 8%, 10%, 13%, 15%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • Formula (N-1-10.1), Formula (N-1-10.2), Formula (N-1-1-11.2), Formula (N-1-11.4), Formula (N-1-1-2) It is preferable to use three to six compounds selected from the compounds represented by formula (N-1-11.14) and formula (N-1-11.14), and it is preferable to use formula (N-1-10.1), formula (N-). It is preferable to use a combination of compounds represented by Formula 1-11.2) and Formula (N-1-11.4), Formula (N-1-10.1), Formula (N-1-10.2).
  • composition of the present invention preferably contains a compound represented by the general formula (N-1).
  • the compound represented by General Formula (N-1) may be used alone, or two or more kinds may be used.
  • the compounds represented by the general formula (N-1) correspond to dielectrically negative compounds (the sign of ⁇ is negative and the absolute value is larger than 2).
  • the compounds represented by the general formula (N-1) are the following compounds.
  • RN11 and RN12 are each independently an alkyl group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, or An alkenyloxy group having 2 to 8 carbon atoms is preferable, and an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or 2 to 5 carbon atoms is preferable.
  • an alkenyloxy group is preferable, an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms is further preferable, and an alkyl group having 2 to 5 carbon atoms or an alkenyl group having 2 to 3 carbon atoms is further added
  • an alkenyl group having 3 carbon atoms (propenyl group) is particularly preferred.
  • the ring structure to which it is bonded is a phenyl group (aromatic)
  • a linear alkyl group having 1 to 5 carbon atoms, a linear alkoxy group having 1 to 4 carbon atoms, and carbon Alkenyl group having 4 to 5 atoms is preferable
  • a linear alkyl group having 1 to 5 carbon atoms, a straight chain Preferred is an alkoxy group having 1 to 4 carbon atoms and a linear alkenyl group having 2 to 5 carbon atoms.
  • the total of carbon atoms and oxygen atoms, if present is preferably 5 or less, preferably linear.
  • the alkenyl group is preferably selected from the groups represented by any one of formulas (R1) to (R5). (The black dot in each formula represents a carbon atom in the ring structure.)
  • it is an alkyl group of 1 to 5 carbon atoms and an alkoxy group of 1 to 5 carbon atoms, and is a methyl group, an ethyl group, a propyl group, a methoxy group, an ethoxy group and a propoxy group.
  • a N11 and A N12 be each independently aromatic when it is required to increase ⁇ n, and in order to improve the response speed, it is preferable to be aliphatic, and trans-1,4 -Cyclohexylene group, 1,4-phenylene group, 2-fluoro-1,4-phenylene group, 3-fluoro-1,4-phenylene group, 3,5-difluoro-1,4-phenylene group, 2 ,, 3-difluoro-1,4-phenylene group, 1,4-cyclohexenylene group, 1,4-bicyclo [2.2.2] octylene group, piperidine-1,4-diyl group, naphthalene-2,6- It is preferable to represent a diyl group, decahydronaphthalene-2,6-diyl group or 1,2,3,4-tetrahydronaphthalene-2,6-diyl group, and more preferable to represent the following structure,
  • a trans-1,4-cyclohexylene group, a 1,4-cyclohexenylene group or a 1,4-phenylene group is preferable, and a trans-1,4-cyclohexylene group or a 1,4-phenylene group is more preferable.
  • Z N11 and Z N12 are each independently -CH 2 O -, - CF 2 O -, - CH 2 CH 2 -, - CF 2 CF 2 - or preferably a single bond, -CH 2 O-, More preferred is -CH 2 CH 2 -or a single bond, with -CH 2 O- or a single bond being particularly preferred.
  • n N11 + n N12 is preferably 1 or 2, in combination n N11 is 1 n N12 is 0, the combination n N11 is 2 n N12 is 0, n N11 is 1 in n N12 is 1 It is preferable that a certain combination be a combination in which n N11 is 2 and n N12 is 1.
  • the lower limit of the preferable content of the compound represented by General Formula (N-1) to the total amount of the composition of the present invention is 1%, 10%, 20%, 30% Yes, 40%, 50%, 55%, 60%, 65%, 70%, 75%, 80%.
  • the upper limit of the preferred content is 95%, 85%, 75%, 65%, 55%, 45%, 35%, 25%, 20% It is.
  • the lower limit of the preferable content of the total of the compound represented by General Formula (N-1d) and the compound represented by General Formula (N-1) with respect to the total amount of the composition of the present invention is 1% Yes, 10%, 20%, 30%, 40%, 50%, 55%, 60%, 65%, 70%, 75% Yes, 80%.
  • the upper limit of the preferred content is 95%, 85%, 75%, 65%, 55%, 45%, 35%, 25%, 20% It is.
  • the above lower limit is low and the upper limit is low. Furthermore, when the composition of the present invention is required to keep Tni high and a composition having good temperature stability is required, it is preferable that the above lower limit is low and the upper limit is low. When it is desired to increase the dielectric anisotropy in order to keep the driving voltage low, it is preferable that the above lower limit value be high and the upper limit value be high.
  • Examples of the compound represented by General Formula (N-1) include compounds represented by the following General Formulas (N-1a) to (N-1g).
  • R N11 and R N12 are as defined R N11 and R N12 in the general formula (N-1), n Na11 represents 0 or 1, n NB11 is 1 or 2, n NC11 is N Ne11 represents 1 or 2, n Nf11 represents 1 or 2, n Ng11 represents 1 or 2, and A Ne11 represents a trans-1,4-cyclohexylene group or 1,4, And A Ng11 represents a trans-1,4-cyclohexylene group, a 1,4-cyclohexenylene group or a 1,4-phenylene group, but at least one is a 1,4-cyclohexenylene group And Z Ne 11 represents a single bond or ethylene, but at least one represents ethylene). More specifically, the compound represented by General Formula (N-1) is a compound selected from the group of compounds represented by General Formulas (N-1-1) to (N-1-21) preferable.
  • the compounds represented by General Formula (N-1-1) are the following compounds.
  • R N111 and R N112 each independently represent the same meaning as R N11 and R N12 in the general formula (N).
  • R N 111 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably a propyl group, a pentyl group or a vinyl group.
  • RN 112 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group or butoxy group.
  • the compounds represented by General Formula (N-1-1) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-1) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17%, 20%, 23%, 25%, 27%, 30%, 33%, 35%.
  • the upper limit of the preferred content is 50%, 40%, 38%, 35%, 33%, 30%, or 50%, based on the total weight of the composition of the present invention. %, 25%, 23%, 20%, 18%, 15%, 13%, 10%, 8%, 7%, 6 %, 5% and 3%.
  • the compound represented by General Formula (N-1-1) is a compound selected from the group of compounds represented by Formula (N-1-1.1) to Formula (N-1-1.23) And the compounds represented by the formulas (N-1-1.1) to (N-1-1.4) are preferable, and the compounds represented by the formulas (N-1-1.1) and (N The compound represented by -1-1.3) is preferred.
  • the compounds represented by the formulas (N-1-1.1) to (N-1-1.22) may be used alone or in combination, but the composition of the present invention
  • the lower limit of the preferable content of these compounds alone or in the total amount is 5%, 10%, 13%, 15%, 17%, 20%, 23% 25%, 27%, 30%, 33% and 35%.
  • the upper limit of the preferred content is 50%, 40%, 38%, 35%, 33%, 30%, or 50%, based on the total weight of the composition of the present invention. %, 25%, 23%, 20%, 18%, 15%, 13%, 10%, 8%, 7%, 6 %, 5% and 3%.
  • the compounds represented by formula (N-1-2) are the following compounds.
  • R N121 and R N122 each independently represent the same meaning as R N11 and R N12 in general formula (N).
  • RN 121 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group, a butyl group or a pentyl group.
  • R N 122 is preferably an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 4 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, and a methyl group, a propyl group, a methoxy group, an ethoxy group or a propoxy group is preferable.
  • the compounds represented by General Formula (N-1-2) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-2) to the total amount of the composition of the present invention is 5%, 7%, 10%, 13% , 15%, 17%, 20%, 23%, 25%, 27%, 30%, 33%, 35%, 37% 40% and 42%.
  • the upper limit of the preferred content is 50%, 48%, 45%, 43%, 40%, 38%, 35%, based on the total weight of the composition of the present invention. %, 33%, 30%, 28%, 25%, 23%, 20%, 18%, 18%, 15%, 13%, 10%. %, 8%, 7%, 6%, 5%.
  • the compound represented by the general formula (N-1-2) is a compound selected from the group of compounds represented by formula (N-1-2.1) to formula (N-1-2.22) It is preferable that the formula (N-1-2.3) to the formula (N-1-2.7), the formula (N-1-2.10), the formula (N-1-2.11), the formula Preferred are the compounds represented by (N-1-2.13) and the formula (N-1-2.20), and in the case of emphasizing the improvement of .DELTA..epsilon.
  • N-1-2.7 is preferably a compound represented by the formula (N-1-2.7) from when emphasizing improvements in T NI formula (N-1-2.10), formula (N-1-2.11) And the compound represented by the formula (N-1-2.13), and in the case of focusing on the improvement of the response speed, the compound represented by the formula (N-1-2.20) Is preferred.
  • the compounds represented by the formula (N-1-2.1) to the formula (N-1-2.22) can be used alone or in combination, but the composition of the present invention
  • the lower limit of the preferred content of these compounds alone or in the total amount of these is 5%, 10%, 13%, 15%, 17%, 20%, 23 %, 25%, 27%, 30%, 33%, 35%.
  • the upper limit of the preferred content is 50%, 40%, 38%, 35%, 33%, 30%, or 50%, based on the total weight of the composition of the present invention. %, 25%, 23%, 20%, 18%, 15%, 13%, 10%, 8%, 7%, 6 %, 5% and 3%.
  • the compounds represented by formula (N-1-3) are the following compounds.
  • R N 131 and R N 132 each independently represent the same meaning as R N 11 and R N 12 in general formula (N).
  • R N 131 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • R N 132 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 3 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and 1-propenyl group, ethoxy group, propoxy group or butoxy group is preferable .
  • the compounds represented by General Formula (N-1-3) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-3) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compound represented by the general formula (N-1-3) is a compound selected from the group of compounds represented by the formula (N-1-3.1) to the formula (N-1-3-21) And the compounds represented by formulas (N-3.1) to (N-1-3.7) and formula (N-1-3.21) are preferable.
  • -1-3.1), the formula (N-1-3.2), the formula (N-1-3.3), the formula (N-1-3.4) and the formula (N-1-3.6) The compounds represented by) are preferred.
  • the compounds represented by the formulas (N-1-3.1) to (N-1-3.4), the formulas (N-1-3.6) and the formulas (N-1 3.21) can be used alone. Although it is possible to use in combination or in combination, a combination of formula (N-1-3.1) and formula (N-1-3.2), a formula (N-1-3.3) Or a combination of two or three selected from formula (N-1-3.4) and formula (N-1-3.6).
  • the lower limit of the preferred content of these compounds alone or in the total amount of the composition of the present invention is 5%, 10%, 13%, 15%, 17%, 20 %.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by the general formula (N-1-4) are the following compounds.
  • each of R N 141 and R N 142 independently represents the same meaning as R N 11 and R N 12 in General Formula (N).
  • R N141 and R N142 are each independently an alkyl group having 1 to 5 carbon atoms, an alkenyl group or an alkoxy group having 1 to 4 carbon atoms carbon atoms 4-5 preferably a methyl group, a propyl group, an ethoxy Preferred is a group or butoxy group.
  • the compounds represented by General Formula (N-1-4) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-4) to the total amount of the composition of the present invention is 3%, 5%, 7%, 10% 13%, 15%, 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15%, 13%, 11%, 10%, 8%.
  • the compound represented by General Formula (N-1-4) is a compound selected from the group of compounds represented by Formula (N-1 -4.1) to Formula (N-1 -4.14) And the compounds represented by formulas (N-1-4.1) to (N-1 -4.4) are preferable, and the compounds represented by formulas (N-1-4.1) and (N Preferred are the compounds represented by -1-4.2) and the formula (N-1-4.4).
  • the compounds represented by formulas (N-1-4.1) to (N-1-4.14) may be used alone or in combination, but the compounds of the present invention
  • the lower limit of the preferred content of these compounds alone or in the total amount is 3%, 5%, 7%, 10%, 13%, 15%, 17% And 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15%, 13%, 11%, 10%, 8%.
  • the compounds represented by General Formula (N-1-5) are the following compounds.
  • R N 151 and R N 152 each independently represent the same meaning as R N 11 and R N 12 in General Formula (N).
  • Each of R N151 and R N152 is independently an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 4 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, preferably an ethyl group, a propyl group or a butyl group Is preferred.
  • the compounds represented by General Formula (N-1-5) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-5) to the total amount of the composition of the present invention is 5%, 8%, 10%, 13% 15%, 17% and 20%.
  • the upper limit value of the preferred content is 35%, 33%, 30%, 28%, 25%, 23%, or 35%, based on the total weight of the composition of the present invention. %, 18%, 15% and 13%.
  • the compound represented by General Formula (N-1-5) is a compound selected from the group of compounds represented by Formula (N-1-5.1) to Formula (N-1-5.6)
  • the compounds represented by the formula (N-1-5.1), the formula (N-1-5.2) and the formula (N-1-5.4) are preferable.
  • the compounds represented by the formulas (N-1-5.1), (N-1-5.2) and (N-1-5.4) may be used alone or in combination.
  • the lower limit of the preferred content of these compounds alone or in the total amount of the composition of the present invention is 5%, 8%, 10%, 13%, although it is also possible. It is 15%, 17% and 20%.
  • the upper limit value of the preferred content is 35%, 33%, 30%, 28%, 25%, 23%, or 35%, based on the total weight of the composition of the present invention. %, 18%, 15% and 13%.
  • the compounds represented by the general formula (N-1-12) are the following compounds.
  • R N 1121 and R N1122 independently represents the same meaning as R N11 and R N12 in the general formula (N).
  • R N 1121 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • RN 1122 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-12) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-12) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by the general formula (N-1-13) are the following compounds.
  • R N1131 and R N1132 independently represents the same meaning as R N11 and R N12 in the general formula (N).
  • R N 1131 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • R N 1132 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-13) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-13) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by General Formula (N-1-14) are the following compounds.
  • R N 1141 and R N 114 2 independently represents the same meaning as R N 11 and R N 12 in General Formula (N).
  • R N 1141 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • RN 1142 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-14) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-14) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by the general formula (N-1-15) are the following compounds.
  • R N 1151 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • R N 1152 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-15) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-15) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by General Formula (N-1-16) are the following compounds.
  • R N 1161 and R N1162 independently represents the same meaning as R N11 and R N12 in the general formula (N).
  • R N 1161 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • R N 1162 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-16) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-16) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by General Formula (N-1-17) are the following compounds.
  • R N 1171 and R N1172 independently represents the same meaning as R N11 and R N12 in the general formula (N).
  • R N 1171 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • RN 1172 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-17) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-17) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by the general formula (N-1-18) are the following compounds.
  • R N 1181 is preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably a methyl group, an ethyl group, a propyl group or a butyl group.
  • R N 1182 is preferably an alkyl group of 1 to 5 carbon atoms, an alkenyl group of 4 to 5 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, and is preferably an ethoxy group, a propoxy group or a butoxy group.
  • the compounds represented by General Formula (N-1-18) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-18) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compound represented by General Formula (N-1-18) is a compound selected from the group of compounds represented by Formula (N-1-18.1) to Formula (N-1-18.5) And the compounds represented by formulas (N-1-18.1) to (N-1-11.3) are preferable, and the compounds represented by formulas (N-1-18.2) and (N- The compound represented by -1-18.3) is preferred.
  • the compounds represented by the general formula (N-1-20) are the following compounds.
  • R N1201 and R N1202 independently represents the same meaning as R N11 and R N12 in the general formula (N).
  • Each of R N1201 and R N1202 is independently preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • the compounds represented by General Formula (N-1-20) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-20) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by General Formula (N-1-21) are the following compounds.
  • each of R N 1211 and R N 12 12 independently represents the same meaning as R N 11 and R N 12 in general formula (N).
  • Each of R N1211 and R N1212 is independently preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • the compounds represented by General Formula (N-1-21) can be used alone, or two or more compounds can be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-21) to the total amount of the composition of the present invention is 5%, 10%, 13%, 15% 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15% and 13%.
  • the compounds represented by the general formula (N-1-22) are the following compounds.
  • R N1221 and R N1222 independently represents the same meaning as R N11 and R N12 in the general formula (N).
  • Each of R N1221 and R N1222 is independently preferably an alkyl group of 1 to 5 carbon atoms or an alkenyl group of 2 to 5 carbon atoms, and is preferably an ethyl group, a propyl group or a butyl group.
  • the compounds represented by General Formula (N-1-22) can be used alone, but two or more compounds can also be used in combination. There is no particular limitation on the types of compounds that can be combined, but they are used in appropriate combination according to the required performance such as solubility at low temperature, transition temperature, electrical reliability, birefringence and the like.
  • the type of the compound used is, for example, one type, two types, three types, four types, five types or more as one embodiment of the present invention.
  • the lower limit of the preferable content of the compound represented by the formula (N-1-21) to the total amount of the composition of the present invention is 1%, 5%, 10%, 13% 15%, 17% and 20%.
  • the upper limit of the preferred content is 35%, 30%, 28%, 25%, 23%, 20%, or 35%, based on the total weight of the composition of the present invention. %, 15%, 13%, 10%, 5%.
  • the compound represented by General Formula (N-1-22) is a compound selected from the group of compounds represented by Formula (N-1-22.1) to Formula (N-1-22.12) Are preferably compounds represented by formulas (N-1-22.1) to (N-1-22.5), and compounds represented by formulas (N-1-22.1) to (N- The compound represented by 1-22.4) is preferable.
  • the lower limit value of the preferable content of the total of the compound represented by General Formula (i) in the neutral compound (the compound represented by General Formula (i) and the compound represented by General Formula (L)) is 2 %, 4%, 6%, 8%, 10%, 12%, 14%, 16%.
  • the preferred upper limit is 30%, 25%, 20%, 18%, 16%, 14%, 12%.
  • the lower limit of the preferable content of the total of the compounds represented by the general formula (i) and the general formula (L) with respect to the total amount of the composition of the present invention is 5%, 10%, 15% 20% and 25%.
  • the upper limit value of the preferable content is 70%, 60%, 55%, 50%, 45%, 40%.
  • the upper limit of the preferable content of the total of the compound having an alkenyl group to the total amount of the composition of the present invention is 95%, 90%, 85%, 80%, 75% Yes, 70%, 65%, 60%, 55%, 50%, 45%, 40%, 40%, 35%, 30%, 25% Yes, 20%, 15%, 10%, 5%.
  • the upper limit of the preferable content of the total of the compound containing an alkenyl group to the total amount of the composition of the present invention is 30%, 25%, 20%, 15%, 13% 10%, 8%, 5%, 3%, 2%, 1%, and preferably substantially free.
  • the liquid crystal composition for liquid crystal display device applications is required to design appropriate physical property values as basic performance.
  • Examples include nematic phase-isotropic liquid phase transition temperature (T ni ), refractive index anisotropy ( ⁇ n), dielectric anisotropy ( ⁇ ), rotational viscosity ( ⁇ 1 ) and various elastic constants (spreading elasticity Constants: K 11 , elastic constant of torsion: K 22 , elastic constant of bending: K 33 , and their average value K ave .
  • T ni nematic phase-isotropic liquid phase transition temperature
  • ⁇ n refractive index anisotropy
  • ⁇ dielectric anisotropy
  • K 11 various elastic constants
  • K 11 elastic constant of torsion: K 22
  • elastic constant of bending K 33
  • K ave the average value K ave
  • the compound represented by General Formula (L-1-1) is a compound selected from the compound group represented by Formula (L-1-1.1) to Formula (L-1-1.3) It is preferable that it is a compound represented by the formula (L-1-1.2) or the formula (L-1-1.3), and in particular, it is represented by the formula (L-1-1.3) It is preferable that it is a compound.
  • the compound represented by General Formula (L-1-2) is a compound selected from the group of compounds represented by Formula (L-1-2.1) to Formula (L-1-2.4)
  • the compound represented by formula (L-1-2.2) to formula (L-1-2.4) is preferable.
  • the compounds represented by the formula (L-1-2.2) are preferable because they particularly improve the response speed of the composition of the present invention.
  • the compound represented by General Formula (L-1-3) is a compound selected from the group of compounds represented by Formula (L-1-3.1) to Formula (L-1 -3.12) And is preferably a compound represented by Formula (L-1-3.1), Formula (L-1-3.3) or Formula (L-1-3.4).
  • the compound represented by the formula (L-1-3.1) is preferable in order to particularly improve the response speed of the composition of the present invention.
  • the dielectric neutral compound exhibiting a large ⁇ n it is preferable to contain a compound represented by general formula (L-3) and / or general formula (L-5).
  • the compound represented by Formula (L-3) is preferably a compound selected from the group of compounds represented by Formula (L-3.1) to Formula (L-3.6), and A compound selected from the group of compounds represented by formula (L-3.3), formula (L-3.5) or formula (L-3.6), It is preferable that it is a compound represented by L-3.1).
  • the compound represented by Formula (L-5) is preferably a compound represented by Formula (L-5.1) or Formula (L-5.2), and in particular, a compound represented by Formula (L-5. It is preferable that it is a compound represented by 1).
  • a liquid crystal composition exhibiting an appropriate ⁇ it is preferable to contain an appropriate amount of a compound exhibiting a large ⁇ , in addition to the compound represented by General Formula (L-1) exhibiting a small ⁇ n.
  • the compound exhibiting a large ⁇ is preferably a compound represented by the general formula (N-1d) and / or the general formula (N-1), and is represented by the general formula (N-1-10), the general formula (N -11), general formula (N-1-1), general formula (N-1-2), general formula (N-1-3), general formula (N-1-4), general formula (N It is preferable to contain a compound represented by the formula (1-5), the general formula (N-1-18) and / or the general formula (N-1-22).
  • the compound represented by General Formula (N-1-10) is a compound selected from the group of compounds represented by Formula (N-1-10.1) to Formula (N-1-10.21) Are preferred, and compounds represented by formulas (N-1-10.1) to (N-1-10.5), formulas (N-1 to 10.20) and formulas (N-1 to 10.21) It is preferable that the formula (N-1-10.1), the formula (N-1-1.20), the formula (N-1-10.20) and the formula (N-1-10.21) Compounds are preferred, and compounds represented by formula (N-1-10.1) and formula (N-1-1.2) are preferred, and compounds represented by formula (N-1-10.2) Is preferred.
  • the compound represented by General Formula (N-1-11) is a compound selected from the group of compounds represented by Formula (N-1-11.1) to Formula (N-1-11.14) And the compounds represented by formulas (N-1-11.2), (N-1-11.4), (N-1-11. 11) and (N-1-11. 14.) Is preferred.
  • the compound represented by General Formula (N-1-1) is a compound selected from the compound group represented by Formula (N-1-1.1) to Formula (N-1-1.23) Are preferred, and compounds represented by formulas (N-1-1.1) to (N-1-1.4) are preferable, and formulas (N-1-1.1) and (N-1) are preferable.
  • the compound represented by -1.3) is preferred.
  • the compound represented by General Formula (N-1-2) is a compound selected from the group of compounds represented by Formula (N-1-2.1) to Formula (N-1-2.22) Formula (N-1-2.3) to Formula (N-1-2.7), Formula (N-1-2.10), Formula (N-1-2.11), Formula (N). It is preferable that it is a compound represented by -1-2.13) and a formula (N-1-2.20).
  • the compound represented by General Formula (N-1-3) is a compound selected from the group of compounds represented by Formula (N-1-3.1) to Formula (N-1-3-21) Are preferred, and compounds represented by formulas (N-1-3.1) to (N-1-3.7) and formula (N-1-3.21) are preferable, and compounds represented by formula (N-1) are preferable.
  • the compounds represented are preferred.
  • the compound represented by General Formula (N-1-4) is a compound selected from the group of compounds represented by Formula (N-1 -4.1) to Formula (N-1 -4.14) Are preferred, and compounds represented by formulas (N-1-4.1) to (N-1-4.4) are preferable, and formulas (N-1-4.1) and (N-1) are preferable.
  • the compounds represented by -4.2) and the formula (N-1-4.4) are preferred.
  • the compound represented by General Formula (N-1-5) is a compound selected from the compound group represented by Formula (N-1-5.1) to Formula (N-1-5.6)
  • the compounds represented by formula (N-1-5.1), formula (N-1-5.2) and formula (N-1-5.4) are preferable.
  • the compound represented by -18.3) is preferred.
  • the compound represented by General Formula (N-1-22) is a compound selected from the group of compounds represented by Formula (N-1-22.1) to Formula (N-1-22.12) Are preferred, and compounds represented by formulas (N-1-22.1) to (N-1-22.5) are preferred, and formulas (N-1-22.1) to (N-1-) are preferred.
  • the compound represented by 22.4) is preferable.
  • the upper limit of the preferable content of the total of the compound represented by General Formula (N-1d) and the compound represented by General Formula (N-1) and having an alkenyl group relative to the total amount of the composition of the present invention The values are 20%, 18%, 15%, 13%, 10%, 8%, 5%, 3%, 2%, 1% It is preferable not to contain substantially.
  • composition of the present invention preferably does not contain a compound having a structure in which oxygen atoms such as a peracid (—CO—OO—) structure are bonded to each other in the molecule.
  • the content of the compound having a carbonyl group is preferably 5% or less, more preferably 3% or less, based on the total mass of the composition. Preferably, it is more preferably 1% or less, and most preferably substantially free.
  • the content of the compound substituted with chlorine atoms is preferably 15% or less, preferably 10% or less, based on the total mass of the composition. % Is preferable, 5% or less is more preferable, 3% or less is preferable, and substantially no content is further preferable.
  • the content of compounds in which all ring structures in the molecule are six-membered rings is 80 based on the total mass of the composition. % Or more is preferable, 90% or more is more preferable, 95% or more is more preferable, and the composition is composed only of compounds in which all ring structures in the molecule are substantially 6-membered rings. Most preferred.
  • the content of the compound whose side chain is an alkyl group and an alkoxy group is It is preferably 85% or more, preferably 87% or more, preferably 90% or more, and more preferably 93% or more, preferably 95% or more based on the total mass of the composition. Is preferably 98% or more, and more preferably substantially 100%.
  • substantially 100% is meant 100%, excluding polymerizable compounds, stabilizers and additionally incorporated impurities.
  • the content of the compound having a cyclohexenylene group is the total mass of the composition.
  • it is preferably 10% or less, preferably 8% or less, more preferably 5% or less, preferably 3% or less, and even more preferably substantially non-containing.
  • the content of a compound having a 2-methylbenzene-1,4-diyl group in which the hydrogen atom may be substituted with a halogen in the molecule may be reduced.
  • the content of the compound having a 2-methylbenzene-1,4-diyl group in the molecule is preferably 10% or less, and more preferably 8% or less based on the total mass of the composition. And 5% or less is more preferable, 3% or less is preferable, and substantially no content is more preferable.
  • not substantially contained means that it is not contained except for unintentionally contained substances.
  • the number of carbon atoms of the alkenyl group is 2 to 5
  • the number of carbon atoms of the alkenyl group is preferably 4 to 5, and the unsaturated bond of the alkenyl group and benzene are directly bonded. Preferably not.
  • the average elastic constant (K AVG ) of the liquid crystal composition used in the present invention is preferably 10 to 25, but the lower limit is preferably 10, 10.5 is preferred, 11 is preferred and 11.5 is preferred.
  • 12 is preferable, 12.3 is preferable, 12.5 is preferable, 12.8 is preferable, 13 is preferable, 13.3 is preferable, 13.5 is preferable, 13.8 is preferable, 14 is preferable, 14 3 is preferable, 14.5 is preferable, 14.8 is preferable, 15 is preferable, 15.3 is preferable, 15.5 is preferable, 15.8 is preferable, 16 is preferable, 16.3 is preferable, 16 5 is preferable, 16.8 is preferable, 17 is preferable, 17.3 is preferable, 17.5 is preferable, 17.8 is preferable, and 18 is preferable, and the upper limit thereof is 25 is preferable, 24.5 is preferable, 24 is preferable, 23.5 is preferable, 23 is preferable, 22.8 is preferable, 22.5 is preferable, 22.3 is preferable, 22 is preferable, 21.8 is 2
  • K AVG When importance is given to reducing power consumption, it is effective to reduce the amount of light from the backlight, and it is preferable to improve the light transmittance of the liquid crystal display element. For that purpose, the value of K AVG should be set lower. preferable. When importance is attached to improvement of response speed and contrast, it is preferable to set the value of K AVG higher.
  • composition of the present invention one or more kinds of polymerization are carried out to prepare a liquid crystal display element such as vertical alignment type PSA mode, vertical alignment type PSVA mode, horizontal electric field type PSA mode or horizontal electric field type PSVA mode.
  • a liquid crystal display element such as vertical alignment type PSA mode, vertical alignment type PSVA mode, horizontal electric field type PSA mode or horizontal electric field type PSVA mode.
  • Compounds can be contained.
  • the liquid crystal composition of the present invention has a general formula (II)
  • R 201, R 202, R 203, R 204, R 205, R 206, R 207, R 208, R 209 and R 210 each independently, P 21 -S 21 -, fluorine atom And each represents an alkyl group having 1 to 18 carbon atoms which may be substituted, an alkoxy group having 1 to 18 carbon atoms which may be substituted on a fluorine atom, a fluorine atom or a hydrogen atom, P 21 independently represents each of Formula (R-1) to Formula (R-9)
  • each of R 11 , R 12 , R 13 , R 14 and R 15 independently represents an alkyl group having 1 to 5 carbon atoms, a fluorine atom or a hydrogen atom, and m r5 , m and each of r7 , n r5 and n r7 independently represents 0, 1 or 2.
  • a polymerizable group selected from S 21 represents a single bond or an alkylene group having 1 to 15 carbon atoms, and one or more of —CH 2 — in the alkylene group is —O—, — so that oxygen atoms are not directly adjacent to each other.
  • n 21 represents 0, 1 or 2;
  • a 21 is (A) 1,4-cyclohexylene group (this is present in the group one -CH 2 - or nonadjacent two or more -CH 2 - may be replaced by -O-.)
  • the number of P 21 -S 21- present in one molecule of the general formula (II) is preferably 1 or more and 4 or less, more preferably 1 or more and 3 or less, and the general formula (II) It is particularly preferable that the number of P 21 -S 21- in the molecule of the compound represented by is 2 or 3.
  • the compound represented by the general formula (II) has a structure in which at least two benzene rings and, if necessary, the ring A 21 are linked, P 21 -S 21- in these plural benzene rings and the ring A 21 Since the compound represented by the general formula (II) has at least one, the compound represented by the general formula (II) exhibits the function and effect as the polymerizable compound.
  • R 201 , R 202 , R 203 , R 204 , R 205 , R 206 , R 207 , R 208 , R 209 and R 210 If it is, R 201, R 202, R 204, R 207, R 209 or one or two or more either R 210 is P 21 -S 21 - - but P 21 -S 21 is preferably , R 201 and R 210 are P 21 -S 21 - is more preferable.
  • R 201 and R 210 each independently, P 21 -S 21 - is preferably, in this case, R 201 and R 210 identical P 21 -S 21 - in even different P 21 -S 21 - may be.
  • R 201, R 202, R 203, R 204, R 205, R 206, R 207, R 208, R 209 and R 210 each independently, P 21 -S 21 - And a C 1 to C 18 alkyl group which may be substituted by a fluorine atom, an alkoxy group having 1 to 18 carbon atoms which may be substituted by a fluorine atom, a fluorine atom or a hydrogen atom,
  • the preferred carbon atom number of the alkyl group and the alkoxy group is 1 to 16, more preferably 1 to 10, still more preferably 1 to 8, still more preferably 1 to 6, and further more preferably More preferably, it is 1 to 4, and particularly preferably 1 to 3.
  • the alkyl group and the alkoxy group may be linear or branched, and linear is particularly preferable.
  • R 202, R 203, R 204, R 205, R 206, R 207, R 208 and R 209 are each independently, P 21 -S 21 -, from 1 carbon atom 3 alkyl group, preferably a fluorine atom or a hydrogen atom, P 21 -S 21 -, more preferably a fluorine atom or a hydrogen atom, more preferably a fluorine atom or a hydrogen atom.
  • P 21 is preferably a formula (R-1), more preferably an acryl group or a methacryl group, and still more preferably a methacryl group.
  • S 21 is preferably a single bond or an alkylene group having 1 to 3 carbon atoms, and more preferably a single bond.
  • n 21 is preferably 0 or 1.
  • a 21 is preferably a 1,4-phenylene group or a naphthalene-2,6-diyl group, and more preferably a 1,4-phenylene group.
  • the total content of the polymerizable compound represented by the general formula (II) is 0.01 to 5% by mass, but the lower limit of the content is preferably 0.02% by mass, and preferably 0.03% by mass, 0.04 mass% is preferable, 0.05 mass% is preferable, 0.06 mass% is preferable, 0.07 mass% is preferable, 0.08 mass% is preferable, 0.09 mass% is preferable, 0.
  • 1% by mass is preferable, 0.15% by mass is preferable, 0.2% by mass is preferable, 0.25% by mass is preferable, 0.3% by mass is preferable, 0.35% by mass is preferable, and 0.4% by mass % Is preferable, 0.5 mass% is preferable, 0.55 mass% is preferable, the upper limit of the content is preferably 4.5 mass%, 4 mass% is preferable, 3.5 mass% is preferable, and 3 mass % Is preferable, 2.5 mass% is preferable, 2 mass Is preferable, 1.5% by mass is preferable, 1% by mass is preferable, 0.95% by mass is preferable, 0.9% by mass is preferable, 0.85% by mass is preferable, 0.8% by mass is preferable, and 0 .75 mass% is preferable, 0.7 mass% is preferable, 0.65 mass% is preferable, 0.6 mass% is preferable, and 0.55 mass% is preferable.
  • the compound represented by the general formula (II) according to the present invention is preferably a polymerizable compound represented by the general formula (IV).
  • R 7 and R 8 each independently represent any of the above formulas (R-1) to (R-9), and X 1 to X 8 are each independently And a trifluoromethyl group, a fluorine atom, a hydrogen atom or an alkoxy group having 1 to 5 carbon atoms.
  • R 7 and R 8 are preferably each independently a methacryl group or an acryl group.
  • the compound represented by the general formula (IV) is more preferably one or more selected from the group consisting of formulas (IV-11) to (IV-19), and 11), particularly preferably the formula (IV-16) and the formula (IV-17).
  • the compounds represented by the general formula (II) according to the present invention are, for example, preferably compounds represented by the formulas (XX-1) to (XX-21), and the formula (XX-1) Formula (XX-7) to Formula (XX-14) to Formula (XX-29) are more preferable.
  • Sp xx is an alkylene group having 1 to 8 carbon atoms or -O- (CH 2 ) s- (wherein, s is an integer of 1 to 7) And the oxygen atom is taken to be attached to the ring).
  • the hydrogen atom in the 1,4-phenylene group is further selected from -F, -Cl, -CF 3 , -CH 3 or a formula (R-1) And may be substituted by any of formulas (R-15).
  • the polymeric compound represented by Formula (M1)-Formula (M18) is preferable, for example.
  • polymerizable compounds such as those represented by formulas (M19) to (M34) are also preferable.
  • the hydrogen atoms in the 1,4-phenylene group and the naphthalene group in formulas (M19) to (M34) may be further substituted by -F, -Cl, -CF 3 or -CH 3 .
  • polymerizable compounds represented by the formulas (M35) to (M65) are also preferable.
  • the content of the polymerizable compound represented by Formula (M1) to Formula (M65) with respect to the entire liquid crystal composition is 0.01 to 5% by mass.
  • the lower limit of the content is preferably 0.02 mass%, preferably 0.03 mass%, preferably 0.04 mass%, preferably 0.05 mass%, and preferably 0.06 mass%, 0.07 mass%.
  • a polymerization initiator may be contained to accelerate the polymerization.
  • the polymerization initiator include benzoin ethers, benzophenones, acetophenones, benzyl ketals, and acyl phosphine oxides.
  • composition in the present invention can further contain a compound represented by General Formula (Q).
  • R Q represents a linear or branched alkyl group having 1 to 22 carbon atoms, and one or more CH 2 groups in the alkyl group are not directly adjacent to an oxygen atom
  • -CH CH-, -CO-, -OCO-, -COO-, -C ⁇ C-, -CF 2 O-, -OCF 2-
  • the hydrogen atom may be substituted with 4-hydroxy-3,5-di-t-butylphenyl group
  • M Q is a trans-1,4-cyclohexylene group, a 1,4-phenylene group or a single bond
  • one or two non-adjacent —CH 2 — in the trans-1,4-cyclohexylene group may be substituted by —O—.
  • the compound represented by General Formula (Q) is preferably a compound represented by General Formula (Q-a) to General Formula (Q-e) below.
  • R Q1 is preferably a linear alkyl group having 1 to 10 carbon atoms or a branched alkyl group
  • R Q2 is preferably a linear alkyl group having 1 to 20 carbon atoms or a branched alkyl group
  • R Q3 is A linear alkyl group having 1 to 8 carbon atoms, a branched alkyl group, a linear alkoxy group or a branched alkoxy group is preferable
  • L Q is preferably a linear alkylene group having 1 to 8 carbon atoms or a branched alkylene group .
  • compounds represented by general formula (Q-a) to general formula (Q-e) compounds represented by general formula (Q-a), general formula (Q-c) and general formula (Q-e) Is more preferred.
  • Formulas (Q-11) to (Q-15) are particularly preferable as specific compounds represented by formula (Q).
  • composition of the present invention it is preferable to contain one or two types of compounds represented by general formula (Q), more preferably to contain one to five types, and the lower limit value of the preferable content thereof 0.0001%, 0.0002%, 0.0005%, 0.001%, 0.002%, 0.005%, 0.01%, 0 .015%, 0.02%, 0.05%, 0.75% and 0.01%, and the upper limit of the preferred content is 1% and 1%. , 0.9%, 0.8%, 0.7%, 0.6%, 0.5%, 0.4%, 0.3%, and It is 0.25%, 0.2%, 0.19%, 0.18%, 0.17% and 0.16%, .15% der.
  • the liquid crystal composition of the present invention can also contain at least one or more compounds represented by General Formula (I-1).
  • R HS independently represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and a hydrogen atom is particularly preferable.
  • a hydrogen atom is particularly preferable.
  • it is an alkyl group, it preferably has 1 to 8 carbon atoms, preferably 1 to 5 carbon atoms, preferably 1 to 3 carbon atoms, and 1 carbon atom. More preferable.
  • two or more R HS exist they may be the same or different.
  • n HS represents an integer of 1 to 6, preferably 2 to 4.
  • the compound represented by General Formula (I-1) is a compound represented by General Formula (I-11), General Formula (I-12) or General Formula (I-13) Is preferred.
  • R H11 each independently represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms
  • M represents an alkylene group having 1 to 13 carbon atoms.
  • R H12 and R 112 each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms
  • each of R H13 and R 113 independently represents a hydrogen atom or an alkyl group having 1 to 30 carbon atoms.
  • n HS represents 2
  • the compound represented by General Formula (I-1) is preferably a compound represented by General Formula (I-2).
  • R H1 and R H2 each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms
  • M represents an alkylene group having 1 to 15 carbon atoms, but is present in M
  • One or more -CH 2 -is -O-, -CH CH-, -C ⁇ C-, -CO-, -OCO-, -COO-, trans-1, 4-cyclohexylene group, 1, It may be substituted by 4-phenylene group or naphthalene-2,6-diyl group.
  • R H1 and R H2 are particularly preferably hydrogen atoms.
  • M represents an alkylene group having 1 to 15 carbon atoms, but in consideration of the viscosity given to the liquid crystal composition and the volatility of itself, M is an alkylene having 2 to 10 carbon atoms.
  • alkylene having 4 to 8 carbon atoms is preferable, and alkylene having 6 or 8 carbon atoms is preferable.
  • compounds represented by the general formula (I-24), the general formula (I-26) and the general formula (I-28) can be mentioned.
  • R H1 and R H2 in these formulas are as described above.
  • the compounds represented by the general formula (I-24H), the general formula (I-26H) and the general formula (I-28H) may be mentioned, and the bis represented by the general formula (I-28H) (2,2,6,6-Tetramethyl-4-piperidyl) sebacate is most suitable.
  • the compound represented by General Formula (I-1) is preferably a compound represented by General Formula (I-3).
  • the compounds represented by the general formula (I-3) are compounds which act more effectively because the effective amine concentration is high. Further, in the compound represented by the general formula (I-1), one having a small molecular weight is adsorbed to the alignment film in the liquid crystal display element to induce display unevenness in many cases. Since the compound represented by 3) becomes large in molecular weight, induction of display unevenness can be prevented.
  • R H3 , R H4 and R H5 each independently represent a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.
  • N H1 and n H2 each independently represent 0 or 1
  • n H3 represents an integer of 1 to 4.
  • R H3 is 2, 3 or 4, and there are a plurality of R H5 , they may be the same or different.
  • R H3 , R H4 and R H5 are particularly preferably hydrogen atoms.
  • it is an alkyl group, it preferably has 1 to 8 carbon atoms, preferably 1 to 5 carbon atoms, preferably 1 to 3 carbon atoms, and 1 carbon atom. More preferable.
  • the compound represented by the general formula (I-1) is preferably contained as a lower limit value in the composition at 0.01% or more, preferably 0.02% or more, 0 .03% or more is preferable, 0.05% or more is preferable, 0.07% or more is preferable, 0.1% or more is preferable, and 0.15% or more Is preferably 0.2% or more, preferably 0.25% or more, preferably 0.3% or more, and preferably 0.5% or more. It is preferable to contain more than.
  • the upper limit thereof is preferably 5% or less, preferably 3% or less, preferably 1% or less, and preferably 0.5% or less, and 0.45% or less
  • the content is preferably 0.4% or less, preferably 0.35% or less, preferably 0.3% or less, and preferably 0.25% or less.
  • the content is preferably 2% or less, preferably 0.15% or less, preferably 0.1% or less, preferably 0.07% or less, and preferably 0.05% or less. Is preferable, and it is preferable to contain 0.03% or less.
  • the content is preferably 0.01 to 5% by mass, preferably 0.01 to 0.3% by mass, and more preferably 0.02 to 0.3% by mass, Particularly preferred is 0.05 to 0.25% by mass. More specifically, the content is preferably 0.01 to 0.1% by mass when importance is placed on the suppression of precipitation at low temperatures.
  • the liquid crystal composition of the present invention may further contain an antioxidant and / or a light stabilizer. More specifically, compounds represented by the following (III-1) to (III-38) are preferable.
  • the composition of the present invention is a compound represented by the general formula (Q), a compound represented by the general formula (I-1), and an antioxidant as represented by the general formulas (III-1) to (III-38).
  • a compound selected from an agent and / or a light stabilizer can be contained in combination.
  • the content of these additives is preferably 0.01% or more, preferably 0.02% or more, as a lower limit value in the composition, and preferably 0.03% or more.
  • the content is preferably 0.2% or more, preferably 0.25% or more, preferably 0.3% or more, and preferably 0.5% or more, preferably 1% or more. Is preferred.
  • the upper limit thereof is preferably 5% or less, preferably 3% or less, preferably 1% or less, and preferably 0.5% or less, and 0.45% or less.
  • the content is preferably 0.4% or less, preferably 0.35% or less, preferably 0.3% or less, and preferably 0.25% or less.
  • the content is preferably 2% or less, preferably 0.15% or less, preferably 0.1% or less, preferably 0.07% or less, and preferably 0.05% or less. Is preferable, and it is preferable to contain 0.03% or less.
  • the content is preferably 0.01 to 5% by mass, preferably 0.01 to 0.3% by mass, and more preferably 0.02 to 0.3% by mass, Particularly preferred is 0.05 to 0.25% by mass. More specifically, the content is preferably 0.01 to 0.1% by mass when importance is placed on the suppression of precipitation at low temperatures.
  • various parameters calculated from physical property values of the liquid crystal composition are used as a method of expressing the characteristics of the liquid crystal display element.
  • ⁇ 1 / K 33 or ⁇ 1 / K ave which is a parameter which governs the response speed
  • K 11 / K 33 which is a parameter which governs the steepness of the electro-optical effect
  • the liquid crystal composition of the present invention is a combination of high-speed response, low drive voltage, good low temperature storage stability, high transmittance and high contrast.
  • K ave is defined as the average value of K 11 and K 33 . Therefore, ⁇ 1 / K 33, which is a parameter that governs the response speed of the vertical alignment liquid crystal display element, is 10.
  • 0 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 9.8 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 9.5 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, and 9.2 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 9.0 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 8.8 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 8.6 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, and 8.4 mPa ⁇ s ⁇ pN ⁇ 1 or less is 8.2 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 8.0 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 7.8 mPa ⁇ s ⁇ pN
  • the parameter ⁇ 1 / K ave which controls the response speed of the horizontal alignment liquid crystal display element is 10. 0 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 9.8 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 9.5 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, and 9.2 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 9.0 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 8.8 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 8.6 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, and 8.4 mPa ⁇ s ⁇ pN ⁇ 1 or less is 8.2 mPa ⁇ s ⁇ pN ⁇ 1 or less is preferable, 8.0 mPa ⁇ s ⁇
  • K 11 / K 33 is preferably 1.30 or less is a parameter governing the steepness of the electro-optical effect in the vertical alignment liquid crystal display device, preferably 1.25 or less, preferably 1.20 or less, 1.18 or less
  • 1.15 or less is preferable
  • 1.12 or less is preferable
  • 1.10 or less is preferable
  • 1.08 or less is preferable
  • 1.06 or less is preferable
  • 1.04 or less is preferable
  • 1.02 or less is preferable 1.00 or less is particularly preferable.
  • is preferably from 6.0pN is preferably equal 5.9PN, less preferably 5.8PN, less preferably 5.7PN, 5 6 pN or less is preferable, 5.5 pN or less is preferable, 5.4 pN or less is preferable, 5.3 pN or less is preferable, 5.2 pN or less is preferable, 5.1 pN or less is preferable, 5.0 pN or less is preferable, 9 pN or less is preferable and 4.8 pN or less is particularly preferable.
  • 6.0 or less is preferable, 5.9 pN or less is preferable, 5.8 pN or less is preferable, 5.7 pN or less is preferable, and
  • 6 pN or less is preferable, 5.5 pN or less is preferable, 5.4 pN or less is preferable, 5.3 pN or less is preferable, 5.2 pN or less is preferable, 5.1 pN or less is preferable, 5.0 pN or less is preferable, 9 pN or less is preferable and 4.8 pN or less is particularly preferable.
  • K ave is preferably 10.0 pN or more, 10.5 pN or more is preferable, 11.0 pN or more is preferable, 11.5 pN or more is preferable, 12.0 pN or more is preferable, 12.5 pN or more is preferable, 13.0 pN or more is preferable, 13.0 pN or more is preferable, 14 15.0 pN or more is preferable, 14.2 pN or more is preferable, 14.4 pN or more is preferable, 14.6 pN or more is preferable, 14.8 pN or more is preferable, 15.0 pN or more is preferable, 15.2 pN or more is preferable, 4 pN or more is preferable, 15.6 pN or more is preferable, 15.8 pN or more is preferable, 16.0 pN or more is preferable, 16.2 pN or more is preferable, 16.4 pN or more is preferable, 16.6 p
  • a horizontally aligned liquid crystal display element which is not favorable for contrast
  • 16.0 pN or more is preferable
  • 16.2 pN or more is preferable
  • 16.4 pN or more is preferable
  • 16.6 pN or more is preferable
  • 16.8 pN or more is preferable
  • 0 pN or more is preferable
  • 17.2 pN or more is preferable
  • 17.4 pN or more is preferable
  • 17.6 pN or more is preferable
  • 17.8 pN or more is preferable
  • 18.0 pN or more is particularly preferable.
  • composition containing the polymerizable compound of the present invention is imparted with liquid crystal alignment ability by polymerizing the polymerizable compound contained therein by ultraviolet irradiation, and the transmitted light quantity of light is controlled using birefringence of the composition Used in liquid crystal display devices.
  • the liquid crystal display device using the composition of the present invention is useful in achieving both high-speed response and suppression of display defects, and is particularly useful for liquid crystal display devices for driving an active matrix.
  • the present invention can be applied to a liquid crystal display element for mode, IPS mode, FFS mode or ECB mode.
  • the liquid crystal composition of the present invention is, for example, Since the liquid crystal can be stably dropped over a long time with little influence on rapid pressure change and impact in the device, the yield of the liquid crystal display element can be kept high.
  • small liquid crystal display devices frequently used in recent smartphones are difficult to control the deviation from the optimum value within a certain range itself because the optimum liquid crystal injection amount is small, but the liquid crystal composition of the present invention By using a material, it is possible to realize a stable liquid crystal material discharge amount even in a small liquid crystal display element.
  • T ni Nematic phase-isotropic liquid phase transition temperature (° C.) ⁇ n: refractive index anisotropy at 293 K ⁇ : dielectric anisotropy at 293 K ⁇ 1 : rotational viscosity at 293 K (mPa ⁇ s) Elastic constant of spread (pN) at K 11 : 293 K Elastic constant of torsion (pN) at K 22 : 293 K K K 33 : elastic constant of bending at 293 K (pN) K ave. : Average elastic constant at 293 K (pN) In the Examples, the following abbreviations are used for the descriptions of compounds. (Ring structure)
  • the prepared liquid crystal composition is injected into a cell with ITO coated with a polyimide alignment film for inducing homeotropic alignment by a vacuum injection method to obtain vertical alignment (VA )
  • VA vertical alignment
  • the liquid crystal display device was obtained.
  • the electro-optical characteristics of the obtained VA liquid crystal display devices were measured, and the drive voltage, response speed, transmittance, contrast and the like were evaluated. The result was judged in three steps of “ ⁇ : problem-free level”, “ ⁇ : slightly insufficient and unacceptable level” and “ ⁇ : unacceptable level”.
  • a polymer stabilized horizontal alignment (PS-IPS or PS-FFS) liquid crystal display element was obtained by exposing for about 100 J without applying a voltage.
  • the electro-optical characteristics of the obtained liquid crystal display elements were measured, and the drive voltage, response speed, transmittance, contrast and the like were evaluated. The result was judged in three steps of “ ⁇ : problem-free level”, “ ⁇ : slightly insufficient and unacceptable level” and “ ⁇ : unacceptable level”.
  • Comparative Example 1 and Example 1 Liquid crystal compositions of LC-A as a comparative example and LC-1 as an example were prepared, and their physical property values were measured. The composition of the liquid crystal composition and the results of physical properties are shown below.
  • LC-1 (Example 1) and LC-A (Comparative Example 1) are parameters that control the response speed, ⁇ 1 / K ave. Is a sufficiently small parameter that governs the drive voltage
  • liquid crystal composition of the present invention is an excellent liquid crystal composition in which high speed response, low drive voltage, high transmittance, and high contrast can all be compatible.
  • Comparative Example 2 and Example 2 Liquid crystal compositions of LC-B as a comparative example and LC-2 as an example were prepared, and their physical property values were measured. The composition of the liquid crystal composition and the results of physical properties are shown below.
  • LC-2 (Example 2) and LC-B (Comparative Example 2) are parameters governing the drive voltage
  • LC-B is a parameter that governs drive voltage, response speed and contrast compared to LC-2, K ave. Is a small parameter that governs the response speed, ⁇ 1 / K ave. Was found to be larger.
  • the liquid crystal composition of the present invention is an excellent liquid crystal composition in which high speed response, low drive voltage, high transmittance, and high contrast can all be compatible.
  • Examples 3, 4 and 5 As an example, liquid crystal compositions of LC-3, LC-4 and LC-5 were prepared, and their physical property values were measured. The composition of the liquid crystal composition and the results of physical properties are shown below.
  • the liquid crystal composition of the present invention is an excellent liquid crystal composition in which high-speed response, low drive voltage, high transmittance, and high contrast can all be compatible in a liquid crystal display element.
  • Examples 6, 7 and 8 As an example, liquid crystal compositions of LC-6, LC-7 and LC-8 were prepared, and their physical property values were measured. The composition of the liquid crystal composition and the results of physical properties are shown below.
  • the liquid crystal composition of the present invention is an excellent liquid crystal composition in which high-speed response, low drive voltage, high transmittance, and high contrast can all be compatible in a liquid crystal display element.
  • a polymerizable compound represented by XX-2, XX-5, XX-15, and M65 is added as a polymerizable compound to the prepared liquid crystal compositions LC-1 to LC8 to form a polymerizable compound-containing liquid crystal composition MLC. -1 to MLC-32 (Examples 9 to 40) were prepared.
  • composition of the obtained polymerizable compound-containing liquid crystal composition is shown below.
  • the liquid crystal composition of the present invention is an excellent liquid crystal composition in which high-speed response, low drive voltage, high transmittance, and high contrast can all be compatible even in a polymer liquid crystal display element.

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