WO2018198661A1 - Procédé de production d'un rouleau de verre et rouleau de verre - Google Patents

Procédé de production d'un rouleau de verre et rouleau de verre Download PDF

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Publication number
WO2018198661A1
WO2018198661A1 PCT/JP2018/013274 JP2018013274W WO2018198661A1 WO 2018198661 A1 WO2018198661 A1 WO 2018198661A1 JP 2018013274 W JP2018013274 W JP 2018013274W WO 2018198661 A1 WO2018198661 A1 WO 2018198661A1
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WO
WIPO (PCT)
Prior art keywords
film
glass
roll
glass film
winding
Prior art date
Application number
PCT/JP2018/013274
Other languages
English (en)
Japanese (ja)
Inventor
森 弘樹
Original Assignee
日本電気硝子株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日本電気硝子株式会社 filed Critical 日本電気硝子株式会社
Priority to CN201880025472.9A priority Critical patent/CN110520393B/zh
Priority to KR1020197022793A priority patent/KR102494452B1/ko
Publication of WO2018198661A1 publication Critical patent/WO2018198661A1/fr

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/002General methods for coating; Devices therefor for flat glass, e.g. float glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/06Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
    • C03C17/09Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the vapour phase
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/42Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B5/00Non-insulated conductors or conductive bodies characterised by their form
    • H01B5/14Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/15Deposition methods from the vapour phase
    • C03C2218/154Deposition methods from the vapour phase by sputtering

Definitions

  • the present invention relates to a glass roll composed of a glass film having a transparent conductive film formed on the surface and a method for producing the same.
  • thin display devices such as liquid crystal displays and organic EL displays
  • mobile devices such as smartphones and tablet PCs that are rapidly spreading in recent years are required to be lightweight. Therefore, as a glass substrate employed in these devices, a glass film thinned into a film is being used.
  • the glass film has a substantially rectangular shape at the final product stage, but is handled as a belt-like form at the previous manufacturing process and various processing steps.
  • this type of glass film has appropriate flexibility, it should be in the form of a glass roll wound around a core or the like in consideration of convenience during storage or transportation. Is customary. If the glass film is in the form of a glass roll, it is not only excellent in storage properties, but also can be easily cut out over a large number of glass films having a substantially rectangular shape.
  • a functional film is formed on the surface of the glass roll in order to provide various functions in various devices.
  • the glass film may be formed while heating.
  • a glass film (glass sheet) supplied from a substrate roll is heated using a can heated to 300 ° C. or more, and a transparent conductive film (for example, a sputtering film is formed on the surface of the glass film by a sputtering method, for example.
  • a method of forming indium tin oxide is disclosed.
  • the glass film is particularly suitable when performing the heating film formation as described above because it is excellent in heat resistance as compared with the resin film. On the other hand, since the glass film has low mechanical strength, it may be damaged when the film-coated glass film is pulled out of the glass roll having the above-described configuration to perform the manufacturing process of various devices.
  • the present invention has been made in view of the above circumstances, and an object of the present invention is to prevent damage to a glass roll formed of a glass film on which a transparent conductive film is formed.
  • the present invention is for solving the above-described problems, and is a method for producing a glass roll obtained by winding a belt-shaped glass film into a roll, and the glass film for feeding the belt-shaped first glass film in a predetermined direction
  • the second glass film is formed from the temporary glass roll configured by the temporary winding process and the temporary winding process for winding the second glass film after the film forming process into a roll shape.
  • the glass film can be protected by overlapping the protective film on the other surface of the glass film. Therefore, the glass roll which concerns on this invention can perform a predetermined
  • the transparent conductive film has a sheet resistance of 20 ⁇ / ⁇ or less when formed of a single layer, it can be suitably used for electrodes of various devices.
  • the glass film is preferably wound so that the protective film is on the outside. Thereby, it can prevent that the glass film of the state of a glass roll breaks.
  • FIG. 1 is a side view of a glass roll.
  • FIG. 2 is a side cross-sectional view showing a glass roll manufacturing apparatus.
  • FIG. 3 is a flowchart showing a method for manufacturing a glass roll.
  • FIG. 4 is a side sectional view showing a part of a glass roll manufacturing apparatus according to another embodiment.
  • FIG. 5 is a side view showing a part of a glass roll manufacturing apparatus.
  • FIG. 6 is a flowchart showing a method for manufacturing a glass roll.
  • or FIG. 3 shows 1st embodiment which concerns on the glass roll which concerns on this invention, and its manufacturing method.
  • the thickness of the glass film 2 is 500 ⁇ m or less, preferably 10 ⁇ m or more and 300 ⁇ m or less, and most preferably 30 ⁇ m or more and 200 ⁇ m or less.
  • the material of the glass film 2 silicate glass and silica glass are used, preferably borosilicate glass, soda lime glass, aluminosilicate glass, and chemically strengthened glass, and most preferably non-alkali glass is used. .
  • non-alkali glass a chemically stable glass can be obtained.
  • the alkali-free glass is a glass that does not substantially contain an alkali component (alkali metal oxide), and specifically, a glass having a weight ratio of the alkali component of 3000 ppm or less. is there.
  • the weight ratio of the alkali component in the present invention is preferably 1000 ppm or less, more preferably 500 ppm or less, and most preferably 300 ppm or less.
  • the thickness of the transparent conductive film 3 is preferably 10 nm or more and 1000 nm or less, more preferably 50 nm or more and 500 nm or less, and most preferably 100 nm or more and 300 nm or less.
  • the sheet resistance of the transparent conductive film 3 formed on the glass film 2 is preferably 20 ⁇ / ⁇ or less, and more preferably 15 ⁇ / ⁇ or less.
  • the material of the transparent conductive film 3 is not particularly limited as long as it has translucency and conductivity.
  • the transparent conductive film 3 is made of, for example, indium tin oxide (ITO), fluorine-doped tin oxide (FTO), indium zinc oxide (IZO), aluminum-doped zinc oxide (AZO), or the like.
  • the protective film 4 has one surface 4a as an adhesive surface.
  • the adhesive surface is in contact with the second surface 2 b of the glass film 2.
  • the adhesive strength of the adhesive surface is desirably set to such an extent that the glass roll 1 can be peeled off from the glass film 2 after manufacturing-related processing of various devices is performed on the glass roll 1.
  • the adhesive strength is preferably 0.001 N / 25 mm or more and 1.5 N / 25 mm or less, but is not limited to this range.
  • the thickness of the protective film 4 is preferably 10 ⁇ m or more and 1000 ⁇ m or less, and more preferably 20 ⁇ m or more and 500 ⁇ m or less.
  • the winding core 5 has a hollow cylindrical shape in this embodiment, but may be a solid columnar shape.
  • the material of the core 5 is not particularly limited.
  • metals such as aluminum alloy, stainless steel, manganese steel, and carbon steel, phenol resin, urea resin, melamine resin, unsaturated polyester resin, epoxy resin, Thermosetting resins such as polyurethane and direal terephthalate resin, thermoplastic resins such as polyethylene, polypropylene, polystyrene, AS resin, ABS resin, methacrylic resin, and vinyl chloride, or glass fibers for these thermosetting resins and thermoplastic resins Reinforced plastics, paper tubes and the like in which reinforcing fibers such as carbon fibers are mixed can be used.
  • the glass film serving as the base material is referred to as the first glass film 2A
  • the transparent glass film 3 formed on the first glass film 2A is referred to as the second glass film 2B
  • the laminated body laminated body which consists of the glass film 2, the transparent conductive film 3, and the protective film 4 with which the protective film 4 was piled up on the 2nd glass film 2B is called 3rd glass film 2C.
  • a base glass roll 1A obtained by winding the first glass film 2A into a roll shape with the core 5A is disposed.
  • the first glass film 2A drawn from the base glass roll 1A is supplied from the glass film supply chamber 9a to the film formation chamber 9b.
  • a film forming unit 10 for forming the transparent conductive film 3 on the first surface 2a of the first glass film 2A is disposed.
  • the film forming unit 10 can form the transparent conductive film 3 on the first glass film 2A by various film forming methods such as a sputtering method, a vapor deposition method, and a CVD method.
  • a sputtering method a vapor deposition method
  • a CVD method a case where an ITO film as the transparent conductive film 3 is formed by a sputtering method will be described.
  • the film forming unit 10 is constituted by an ion beam sputtering device, a magnetron sputtering device, or the like.
  • the film forming unit 10 as a sputtering apparatus mainly includes a sputtering source 11 including a target and a heating roller 12 that supports the first glass film 2A.
  • the sputter source 11 is arranged at a constant interval from the heating roller 12 so that sputter particles (ITO particles) scattered from the target adhere to the first surface 2a of the first glass film 2A.
  • the heating roller 12 includes a cylindrical roller body 13 that supports the first glass film 2 ⁇ / b> A and a heater 14 that heats the roller body 13.
  • the roller body 13 is made of glass or ceramics.
  • the roller body 13 is rotatably supported by the shaft portion 15.
  • the second glass film 2B is formed by forming the transparent conductive film 3 on the first glass film 2A by the film forming unit 10.
  • the 2nd glass film 2B is conveyed to the glass film collection
  • a core 5 for winding the third glass film 2C and a protective film supply device 8 are arranged in the glass film collection chamber 9c of the vacuum chamber 9.
  • the core 5 forms the glass roll 1 as a final form by winding up the third glass film 2C.
  • the base material glass roll 1A and the glass roll 1 are configured to continuously convey the glass films 2A to 2C by a roll-to-roll method.
  • the protective film supply device 8 includes a protective film roll 16, a guide roller 17, and a support mechanism 18 for the guide roller 17.
  • the guide roller 17 is composed of a single roller.
  • the guide roller 17 is configured to sandwich the third glass film 2 ⁇ / b> C and the protective film 4 together with the core 5 of the glass roll 1.
  • the guide roller 17 is disposed above the core 5 of the glass roll 1, but is not limited to this position.
  • the roller surface 17a of the guide roller 17 is made of a cushioning material.
  • the cushioning material is preferably composed of rubber or another elastic body.
  • the support mechanism 18 includes a support member 19 that rotatably supports the guide roller 17 and a support shaft 20 that rotatably supports the support member 19.
  • the guide roller 17 contacts a part of the glass roll 1 with an appropriate pressing force due to a moment acting around the support shaft 20 via the support member 19.
  • the guide roller 17 is supported by the support mechanism 18 so as to move following the increase in the outer diameter of the glass roll 1 during manufacture.
  • this method includes a glass film supply step, a film formation step, a protective film supply step, and a winding step.
  • the first glass film 2A is pulled out from the base glass roll 1A arranged in the glass film supply chamber 9a, and sent to the film forming unit 10 in the film forming chamber 9b on the downstream side.
  • the transparent conductive film 3 is formed by the film forming unit 10 on the first surface 2a of the first glass film 2A supplied from the glass film supply chamber 9a.
  • a predetermined vacuum degree is set by a vacuum pump (not shown) and an inert gas such as an argon gas is supplied.
  • the film forming unit 10 scatters sputtered particles (for example, ITO particles) from the sputter source 11 and sequentially adheres them to the first surface 2a of the first glass film 2A.
  • the roller body 13 of the heating roller 12 rotates in a predetermined direction (the direction of arrow R in FIG. 2) along the transport direction of the first glass film 2A by driving the shaft portion 15 by a drive source (not shown). .
  • a part of the roller body 13 is in contact with the second surface 2b of the first glass film 2A.
  • the roller body 13 guides the first glass film 2A to the downstream side (the glass film collection chamber 9c side) by its rotation.
  • the roller body 13 is heated to a predetermined temperature by the heater 14.
  • the temperature of the roller body 13 is set to, for example, 200 ° C. or more and 500 ° C. or less, but is not limited to this range.
  • the roller body 13 guides the first glass film 2A to the downstream side while heating.
  • the first glass film 2A is heated to 150 ° C. or higher by the roller body 13.
  • the first glass film 2A is preferably heated to 200 ° C. or higher, more preferably 250 ° C., and most preferably 300 ° C. or higher.
  • the ITO particles attached to the first glass film 2A are crystallized, and the transparent conductive film 3 having a low resistance (20 ⁇ / ⁇ or less) is formed.
  • the second glass film 2B is formed.
  • the protective film 4 is pulled out with the rotation of the core 21 of the protective film roll 16 in the protective film supply device 8.
  • the protective film 4 and the second glass film 2 ⁇ / b> B are sandwiched between the guide roller 17 and the core 5 of the glass roll 1. Thereby, one surface 4a (adhesion surface) of the protective film 4 is adhere
  • the third glass film 2 ⁇ / b> C formed through the protective film supplying process is immediately wound by the rotation of the winding core 5.
  • the glass roll 1 is formed around the core 5.
  • the glass roll 1 expands its outer diameter according to the rotation of the core 5.
  • the guide roller 17 of the protective film supply device 8 moves outward following the increase in the outer diameter of the glass roll 1.
  • the support member 19 of the support mechanism 18 rotates around the support shaft 20 (clockwise) in order to move the guide roller 17. That is, the guide roller 17 moves from the position indicated by the solid line in FIG. 2 to the position indicated by the two-dot chain line in accordance with the increase in the outer diameter of the glass roll 1. Thereby, the guide roller 17 makes the protective film 4 contact the 2nd glass film 2B reliably, without applying excessive pressing force to the glass roll 1.
  • the third glass film 2C is drawn from the glass roll 1, and a predetermined circuit pattern (for example, an electrode pattern) is formed on the transparent conductive film 3 by means such as photolithography.
  • a predetermined circuit pattern for example, an electrode pattern
  • the protective film 4 is removed (peeled) from the glass film 2.
  • the said glass film 2 can be protected by overlapping the protective film 4 on the glass film 2.
  • FIG. Thereby, the damage of the glass film 2 in the manufacture related process of various apparatuses can be prevented.
  • the second surface 2 b of the glass film 2 can be appropriately protected by the protective film 4.
  • the transparent conductive film 3 formed on the first surface 2a of the glass film 2 is formed by heating, it can realize a low resistance of 20 ⁇ / ⁇ or less and is suitably used for electrodes of various devices. obtain.
  • the production efficiency of the glass roll 1 can be improved by performing the protective film supply step in the vacuum chamber 9. Furthermore, by arranging the protective film supply device 8 in the vacuum chamber 9 of the film forming device 7, the manufacturing device 6 can be downsized.
  • the manufacturing apparatus 6 of the glass roll 1 is equipped with the film-forming apparatus 7 and the protective film supply apparatus 8 separately.
  • the vacuum chamber 9 of the film forming apparatus 7 includes a glass film supply chamber 9a, a film forming chamber 9b, and a glass film collection chamber 9c, as in the first embodiment.
  • the base glass roll 1A is disposed in the glass film supply chamber 9a, and the film forming unit 10 is provided in the film forming chamber 9b.
  • the protective film supply device 8 is not provided in the glass film collection chamber 9c.
  • a winding core 5B for winding the second glass film 2B is disposed in the glass film collection chamber 9c. When the winding core 5B winds up the second glass film 2B, the temporary glass roll 1B is formed around it.
  • Other configurations in the film forming apparatus 7 are the same as those in the first embodiment.
  • the protective film supply device 8 is disposed outside the vacuum chamber 9 in the film forming device 7 and in the vicinity of the film forming device 7. As shown in FIG. 5, the protective film supply device 8 includes a protective film roll 16 and a guide roller 17 that guides the protective film 4.
  • the protective film roll 16 is configured by winding the protective film 4 with the core 21.
  • the guide roller 17 is configured by a nip roller, but is not limited to this configuration.
  • the temporary glass roll 1 ⁇ / b> B and the glass roll 1 are connected by a roll-to-roll system, and the protective film roll 16 is disposed between the temporary glass roll 1 ⁇ / b> B and the glass roll 1.
  • the protective film supply device 8 contacts the protective film 4 drawn from the protective film roll 16 with the second glass film 2B drawn from the temporary glass roll 1B with the rotation of the core 5B via the guide roller 17.
  • the third glass film 2 ⁇ / b> C is continuously formed on the downstream side of the guide roller 17.
  • the winding core 5 winds the third glass film 2C to form the glass roll 1 around it.
  • the present method includes a first glass film supplying step for supplying the first glass film 2A, a film forming step for forming the transparent conductive film 3 on the first glass film 2A, and a first step after the film forming step.
  • a first winding process for collecting the two glass film 2B as the temporary glass roll 1B, a second glass film supplying process for drawing and supplying the second glass film 2B from the temporary glass roll 1B, and a protective film for the second glass film 2B. 4 is provided with a protective film supply step that forms the third glass film 2C by stacking 4 and a second winding step that collects the third glass film 2C as the glass roll 1.
  • the first glass film supplying step and the film forming step are the same as the glass film supplying step and the film forming step of the first embodiment, and the base glass disposed in the glass film supplying chamber 9a of the vacuum chamber 9 in the film forming apparatus 7.
  • the first glass film 2A is pulled out from the roll 1A and supplied to the film forming chamber 9b, and the film forming unit 10 forms the transparent conductive film 3 on the first surface 2a of the first glass film 2A. Thereby, the 2nd glass film 2B is formed.
  • the first winding step is a step (temporary winding step) of temporarily winding the second glass film 2B with another core 5B before winding the third glass film 2C with the core 5.
  • the second glass film 2B that has passed through the film forming chamber 9b is introduced into the glass film collecting chamber 9c and wound by the core 5B.
  • the winding core 5B is rotationally driven by a driving source (not shown) so as to wind up the second glass film 2B.
  • the temporary glass roll 1B is formed around the core 5B.
  • the temporary glass roll 1B gradually expands the outer diameter with the rotation of the core 5B.
  • the first winding process is completed. Thereafter, the temporary glass roll 1B is taken out from the glass film collection chamber 9c.
  • the second glass film 2B is drawn out from the temporary glass roll 1B taken out from the glass film collection chamber 9c and supplied to the downstream protective film supply device 8.
  • the third glass film 2C is wound up by the core 5.
  • the winding core 5 is rotationally driven by a driving source (not shown). Thereby, the glass roll 1 is formed around the core 5.
  • the glass roll 1 gradually increases the outer diameter as the winding core 5 rotates.
  • this invention is not limited to the structure of the said embodiment, It is not limited to the above-mentioned effect.
  • the present invention can be variously modified without departing from the gist of the present invention.
  • the base glass roll 1A is disposed in the vacuum chamber 9, and the transparent conductive film 3 is formed on the first glass film 2A by the roll-to-roll method.
  • the present invention is not limited to this configuration.
  • the transparent conductive film 3 may be formed on the glass film 2 by introducing the glass film 2 (first glass film 2 ⁇ / b> A) continuously formed by the overflow downdraw method into the vacuum chamber 9.
  • the second glass film 2B is formed without using the base glass roll 1A.
  • the heater 14 may be disposed in the vicinity of the first glass film 2 ⁇ / b> A in the film forming chamber 9 b of the vacuum chamber 9, and the first glass film 2 ⁇ / b> A may be heated by the heater 14.
  • the glass roll 1 in which the transparent conductive film 3 is formed only on the first surface 2a of the glass film 2 is exemplified, but the present invention is not limited thereto, and the transparent conductive material is formed on both surfaces 2a and 2b of the glass film 2.
  • a film 3 may be formed.
  • one surface 4a of the protective film 4 is used as an adhesive surface and adhered to the second surface 2b of the first glass film 2A
  • the present invention is not limited to this configuration.
  • the transparent conductive film 3 was formed in the inner side (1st surface 2a) of the glass film 2, and the protective film 4 was piled up on the outer side (2nd surface 2b), it illustrated.
  • the configuration is not limited to this.
  • the glass roll 1 in which the protective film 4 is superimposed on the inner side of the glass film 2 and the transparent conductive film 3 is formed on the outer side of the glass film 2 may be used.
  • the base glass roll 1A made only of the first glass film 2A (glass film 2) is exemplified, but the present invention is not limited to this configuration.
  • the base glass roll 1A may be formed by rolling a glass film 2 serving as a base material on which a band-shaped buffer film made of a resin such as PET is overlapped.
  • the first glass film 2A drawn out from the base glass roll 1A and the buffer film are separated, and the buffer film is separated from the glass film supply chamber 9a. It is desirable to wind up with a core or the like.
  • a band-shaped buffer film made of a resin such as PET may be appropriately stacked even when the temporary glass roll 1B is manufactured.
  • a leader for example, a belt-like resin film for connecting the cores 5, 5A, 5B and the glass film 2 (2A to 2C) is attached to the start and end portions of the belt-like glass film 2. Also good.

Abstract

L'invention concerne un procédé de production de rouleau de verre comprenant une étape d'alimentation en film de verre consistant à distribuer un premier film de verre 2A en forme de bande dans une direction prédéterminée, une étape de formation de film consistant à former à chaud un film 3 électroconducteur transparent sur une surface 2a du premier film de verre 2A pour former un deuxième film de verre 2B, une étape d'alimentation en film protecteur consistant à superposer, sur l'autre surface 2b du deuxième film de verre 2B, un film protecteur 4 en forme de bande présentant une surface adhésive, pour former un troisième film de verre 2C et une étape d'enroulement consistant à enrouler le troisième film de verre 2C en un rouleau.
PCT/JP2018/013274 2017-04-28 2018-03-29 Procédé de production d'un rouleau de verre et rouleau de verre WO2018198661A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201880025472.9A CN110520393B (zh) 2017-04-28 2018-03-29 玻璃卷筒的制造方法及玻璃卷筒
KR1020197022793A KR102494452B1 (ko) 2017-04-28 2018-03-29 유리롤의 제조 방법 및 유리롤

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017-089822 2017-04-28
JP2017089822A JP6900767B2 (ja) 2017-04-28 2017-04-28 ガラスロールの製造方法

Publications (1)

Publication Number Publication Date
WO2018198661A1 true WO2018198661A1 (fr) 2018-11-01

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US11746035B2 (en) 2019-07-11 2023-09-05 Nippon Electric Glass Co., Ltd. Manufacturing method and manufacturing device of glass roll
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KR20220010366A (ko) * 2020-07-17 2022-01-25 코닝 인코포레이티드 유리 롤

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CN110520393B (zh) 2022-10-28
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